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The Identification of Ignitable Liquids in the Presence of Pyrolysis Products: Generation of a Pyrolysis Product Database

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The Identification of Ignitable Liquids in the Presence of Pyrolysis Products: Generation of a Pyrolysis Product Database University of Central Florida STARS Electronic Theses and Dissertations, 2004-2019 2008 The Identification Of Ignitable Liquids In The Presence Of Pyrolysis Products: Generation Of A Pyrolysis Product Database Joseph Castelbuono University of Central Florida Part of the Chemistry Commons, and the Forensic Science and Technology Commons Find similar works at: https://stars.library.ucf.edu/etd University of Central Florida Libraries http://library.ucf.edu This Masters Thesis (Open Access) is brought to you for free and open access by STARS. It has been accepted for inclusion in Electronic Theses and Dissertations, 2004-2019 by an authorized administrator of STARS. For more information, please contact [email protected]. STARS Citation Castelbuono, Joseph, "The Identification Of Ignitable Liquids In The Presence Of Pyrolysis Products: Generation Of A Pyrolysis Product Database" (2008). Electronic Theses and Dissertations, 2004-2019. 3626. https://stars.library.ucf.edu/etd/3626 THE IDENTIFICATION OF IGNITABLE LIQUIDS IN THE PRESENCE OF PYROLYSIS PRODUCTS: GENERATION OF A PYROLYSIS PRODUCT DATABASE by JOSEPH CASTELBUONO B.S. University of Central Florida, 2008 A thesis submittted in partial fulfillment of the requirements for the degree of Master of Science in the Department of Chemistry in the College of Sciences at the University of Central Florida Orlando, Florida Fall Term 2008 © 2008 Joseph Castelbuono ii ABSTRACT The fire debris analyst is often faced with the complex problem of identifying ignitable liquid residues in the presence of products produced from pyrolysis and incomplete combustion of common building and furnishing materials[1]. The purpose of this research is to investigate a modified destructive distillation methodology provided by the Florida Bureau of Forensic Fire and Explosive Analysis to produce interfering product chromatographic patterns similar to those observed in fire debris case work. The volatile products generated during heating of substrate materials are extracted from the fire debris by passive headspace adsorption and subsequently analyzed by GC-MS. Low density polyethylene (LDPE) is utilized to optimize the modified destructive distillation method to produce the interfering products commonly seen in fire debris. The substrates examined in this research include flooring and construction materials along with a variety of materials commonly analyzed by fire debris analysts. These substrates are also burned in the presence of a variety of ignitable liquids. Comparisons of ignitable liquids, pyrolysis products, and products from pyrolysis in the presence of an ignitable liquid are performed by comparing the summed ion spectra from the GC-MS data. Pearson correlation was used to determine if substrates could be discriminated from one another. A pyrolysis products database and GC-MS database software based on comparison of summed ion spectra are shown to be useful tools for the evaluation of fire debris. iii This thesis is dedicated to my mom and dad. If not for their guidance and dedication I would never have been able accomplish all that I have done. iv ACKNOWLEDGEMENTS Members of the committee: Dr. Michael Sigman Dr. Barry Fookes Dr. Andres Campiglia Colleagues and friends: Mary Williams Carl Chasteen Douglass Clark Candice Bridge Katie Steele Jessica Frisch Erin McIntee Jeniffer Molina Christopher Moody Kimberly Painter Joseph Colca Ashley Walker Neil Christiana Jr. Angela Fischer Kelly McHugh v TABLE OF CONTENTS LIST OF FIGURES ........................................................................................................... ix LIST OF TABLES ............................................................................................................ xv CHAPTER ONE: INTRODUCTION ................................................................................. 1 Purpose of the Research .............................................................................................................. 1 Brief Synopsis ............................................................................................................................. 1 Arson ........................................................................................................................................... 2 CHAPTER TWO: BACKGROUND .................................................................................. 4 Ignitable Liquids .......................................................................................................................... 4 Classification System .............................................................................................................. 4 Mass Spectral Analysis of Ignitable Liquids ........................................................................... 6 Criteria for Identification ......................................................................................................... 6 Weathering .............................................................................................................................. 8 Concepts of Combustion and Pyrolysis ..................................................................................... 14 CHAPTER THREE: COLLECTION AND PREPARATION OF FIRE DEBRIS .......... 16 Sample Collection ..................................................................................................................... 16 Sample Preparation Methods ..................................................................................................... 17 Distillation ............................................................................................................................. 18 Solvent Extraction ................................................................................................................. 18 Direct Headspace ................................................................................................................... 19 Solid-Phase Microextraction ................................................................................................. 19 Dynamic Headspace (purge and trap) ................................................................................... 19 Passive Headspace ................................................................................................................. 20 CHAPTER FOUR: METHODOLOGY ........................................................................... 21 Research Method ....................................................................................................................... 21 vi Instrumental Parameters ............................................................................................................ 23 Covariance Mapping and Summed Ion Method ........................................................................ 23 Statistical Comparison Method ................................................................................................. 27 CHAPTER FIVE: VARIABILITY TESTING ................................................................. 30 Method Variability Testing ....................................................................................................... 30 Applied Heat .......................................................................................................................... 30 Distance of Flame .................................................................................................................. 32 Size and Mass of Substrate .................................................................................................... 32 Heating Time ......................................................................................................................... 34 Volume of Ignitable Liquid ................................................................................................... 36 Summary ............................................................................................................................... 38 CHAPTER SIX: PYROLYSIS OF SUBSTRATES ......................................................... 40 Substrate Comparisons .............................................................................................................. 40 Introduction ........................................................................................................................... 40 Carpets, Carpet blends, and Padding ..................................................................................... 41 Hardwoods and Softwoods .................................................................................................... 44 Vinyl and Linoleum Flooring ................................................................................................ 48 Laminate Hardwood Flooring ............................................................................................... 50 Miscellaneous Substrates....................................................................................................... 53 Substrates in the Presence of Ignitable Liquids ......................................................................... 57 CHAPTER SEVEN: CONCLUSION ............................................................................... 62 Conclusion ................................................................................................................................. 62 Future Direction .................................................................................................................... 63 APPENDIX: SUBSTRATE TOTAL ION CHROMATOGRAMS AND
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