Unit 3 PERIODIC CLASSIFICATION OF ELEMENTS "An awareness of the Learning Objectives periodic table is essential to anyone who wishes to After studying this unit, students disentangle the word and see will be able to how it is built up from the fundamental building blocks • recognise the development of of the chemistry, the chemical the periodic table elements " - Glenn T. Seaborg • explain the work of Mosley's and modern periodic law • outline the concept of grouping elements • name the elements with atomic number greater than 100 using IUPAC nomenclature • classify the elements into s, p, d and f blocks • recognise the periodic trends and describe qualitatively the variation in periodic properties such as atomic radius, ionisation energy etc. Glenn T. Seaborg Glenn Th eodore Seaborg • explain the anomalies in the expected trend in received Nobel Prize in 1951 in the periodic properties chemistry for the discoveries of trans-uranium elements. • calculate the effective nuclear charge using He was the co-discoverer of Slater's rule plutonium and other trans- uranium elements. He along with • calculate the ionic radius using Pauling's his colleagues has discovered method over a hundred isotopes of other elements. He demonstrated that • predict the probable position for a given actinide elements are analogues element in the periodic table to rare earth series of lanthanide elements. • explain the anomalous properties of second period elements and the diagonal relationship 68 Introduction metallic elements earthy elements lime (calcium There are millions of chemical cobalt, mercury, tin oxide) compounds existing in nature with magnesia (magne- different compositions and properties, copper, nickel, iron formed from less than 100 naturally sium oxide) barytes (barium occurring elements. gold, lead, silver, zinc sulphate) The discovery of elements is linked argilla (aluminium manganese, tungten with human civilization. In stone age man oxide) has used some metals to suit his needs silex (silicon diox- platina (platinum) without knowing that they are elements. ide) Soon he learnt to extract elements from ores and fashion them into his daily life. 3.1 Classification of Elements Over the years, more and more elements th were discovered. In 1789, Lavoisier from During the 19 century, scientists France, published the first list of chemical have isolated several elements and the list elements containing 23 elements after of known elements increased. Currently, several experimental investigations. we have 118 known elements. Out of 118 elements, 92 elements with atomic Antoine Lavoisier classified the numbers 1 to 92 are found in nature. substances into four groups of elements Scientists have found out there are some namely acid-making elements, gas-like similarities in properties among certain elements, metallic elements and earthy elements. This observation has led to the elements idea of classification of elements based on their properties. In fact, classification will Table 3.1 Lavoisier table be beneficial for the effective utilization of these elements. Several attempts were acid-making gas-like elements made to classify the elements. However, elements classification based on the atomic weights sulphur light led to the construction of a proper form of periodic table. phosphorus caloric (heat) In 1817, J. W. Döbereiner classified charcoal (carbon) oxygen some elements such as chlorine, bromine azote (nitrogen) and iodine with similar chemical properties hydrogen into the group of three elements called as triads. In triads, the atomic weight of the middle element nearly equal to the arithmetic mean of the atomic weights of the remaining two elements. However, only a limited number of elements can be grouped as triads. 69 Table 3.2 Döbereiner Triads Elements in the Atomic weight of Average atomic weight of the remaining S. No. Triad middle element elements 7+39 1 Li, Na, K 23 = 23 2 35.5+127 2 Cl, Br, I 80 = 81.25 2 40+137 3 Ca, Sr, Ba 88 = 88.5 2 This concept can not be extended eighth element are similar to the properties to some triads which have nearly same of the first element. This law holds good atomic masses such as [Fe, Co, Ni], [Ru, for lighter elements up to calcium. Rh, Pd] and [Os, Ir, Pt]. Table 3.3 Newlands’ Octaves In 1862, A. E. B. de Chancourtois 7 9 11 12 14 16 19 reported a correlation between the Li Be B C N O F properties of the elements and their atomic 23Na 24Mg 27Al 29Si 31P 32S 35.5Cl weights. He said ‘the properties of bodies are the properties of numbers’. He intended 39K 40Ca the term numbers to mean the value of atomic weights. He designed a helix by 3.1.1 Mendeleev's Classification tracing at an angle 45˚ to the vertical axis of a cylinder with circumference of 16 units. In 1868, Lothar Meyer had He arranged the elements in the increasing developed a table of the elements that atomic weights along the helix on the closely resembles the modern periodic surface of this cylinder. One complete table. He plotted the physical properties turn of a helix corresponds to an atomic such as atomic volume, melting point and weight increase of 16. Elements which lie boiling point against atomic weight and on the 16 equidistant vertical lines drawn observed a periodical pattern. on the surface of cylinder shows similar During same period Dmitri properties. This was the first reasonable Mendeleev independently proposed attempt towards the creation of periodic that “the properties of the elements are table. However, it did not attract much the periodic functions of their atomic attention. weights” and this is called periodic law. In 1864, J. Newland made an attempt Mendeleev listed the 70 known elements to classify the elements and proposed the at that time in several vertical columns in law of octaves. On arranging the elements order of increasing atomic weights. Thus, in the increasing order of atomic weights, Mendeleev constructed the first periodic he observed that the properties of every table based on the periodic law. 70 Series Group of Elements 0 1 II III IV V VI VII VIII 1 Hydrogen - H -- - 1.0008 2 Heitum Lithium Beryllium Boron Carbon Nitrogen Oxygen Fluorine Ge Li Be B C N O F 4.0 7.03 9.1 11.0 12.0 14.04 16.00 19.0 3NeonSodium Magnesium Aluminium Silicon Phosphorus Sulphur Chlorine Ne Na Mg Al Si P S Cl 19.9 23.5 24.3 27.0 28.04 31.0 32.06 35.45 4 Argon Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Nickel Table 3.4 Mendeleev's periodic table 3.4Mendeleev's Table Ar K Ca Sc Ti V Cr Mn Fe Co (Ni (Cu 38 39.1 40.1 44.1 48.1 51.4 51.99 55.0 55.9 59 59 5 Copper Zinc Gallium Germanium Arsenic Selenium Bromine Cu Zn Ga Ge As Se Br 63.6 65.4 70.0 72.3 75 79 79.95 6KryptonRubidium Strontium Yttrium Zirconium Niobium Molybdenum - Ruthenium Rhodium Palladium Kr Rb Sr Y Zr Nb Mo Ru Rh (Pd (Ag 81.8 85.4 87.6 89.0 90.6 94.0 96.0 101.7 106.5 71 7SilverCadmium Indium Tin Antimony Tellurium Iodine Ag Cd In Sn Sb Te I 107.9 112.4 114.0 119.0 120.0 127.6 126.9 8XenonCaesium Barium Lanthanum Cerium -- - - Xe Cs Ba La Ce 128 132.9 137.4 139 140 9----- - - - - 10 Ytterbium Tantalum Tungsten Osmium Iridium Platinum -- -Yb - Ta W - Os Ir (Pt (Au 173 183 184 191 193 194.9 11 Gold Mercury Thallium Lead Bismuth -- Au Hg Tl Pb Bi 197.2 200.0 204.1 206.9 208 12 Radium Thorium Uranium --Ra - Th - U 224 232 239 Higher Saline Oxides RRORO RO R O RO R O 2 2 3 2 2 5 3 2 7 RO Higher Gaseous Hydrogen Compounds 4 RH4 RH3 RH2 RH As shown in the periodic table, he left some blank spaces since there were no known elements with the appropriate properties at that time. He and others predicted the physical and chemical properties of the missing elements. Eventually these missing elements were discovered and found to have the predicted properties. For example, Gallium (Ga) of group III and germanium (Ge) of group IV were unknown at that time. But Mendeleev predicted their existence and properties. He referred the predicted elements as eka-aluminium and eka-silicon. After discovery of the actual elements, their properties were found to match closely to those predicted by Mendeleev (Table 3.4 ). Table 3.5 Properties predicted for Eka-aluminium and Eka-silicon Eka-aluminium Gallium Eka-silicon Germanium S.No. Property (Predicted) (Observed) (Predicted) (Observed) 1. Atomic weight 68 70 72 72.59 2. Density (g/cm3) 5.9 5.94 5.5 5.35 3. Melting point low 29.78°C High 947°C 4. Formula of oxide E2O3 Ga2O3 EO2 GeO2 Formula of 5. ECl GaCl ECl GeCl chloride 3 3 4 4 3.1.2 Anomalies of Mendeleev’s Periodic Table Some elements with similar properties were placed in different groups and those with dissimilar properties were placed in same group. Example: Tellurium (127.6) was placed in VI group but Iodine (127.0) was placed in VII group. Similarly elements with higher atomic weights were placed before lower atomic 59 weights based on their properties in contradiction to his periodic law. Example Co27 was 58.7 placed before Ni28 3.2 Moseley's Work and Modern Periodic Law In 1913, Henry Moseley studied the characteristic X-rays spectra of several elements by bombarding them with high energy electrons and observed a linear correlation between atomic number and the frequency of X-rays emitted which is given by the following expression.