DOCSLIB.ORG

FTIR Flame-Retardants News 01/2005En

Total Page：16

File Type：pdf, Size：1020Kb

Download full-text PDF Read full-text
FTIR Flame-Retardants News 01/2005En APPLICATION Shimadzu News 1/2005 Identification of brominated flame- r FTIR-Spectroscopy – Method for compliance with the RoHS directive Figure 1: Structural formulae of brominated biphenyls he RoHS* directive trations of 5 % up to 10 %. RoHS other brominated BDE’s), the GCMS is highly suitable as all (Restriction of the use of restricts the use of compounds PBDE content will exceed the brominated compounds can be Tcertain Hazardous Sub- such as tetrabrominated biphenyl RoHS threshold value of 1,000 ppm. separated and detected down to the stances in electrical and electronic A (TBBA), brominated poly- trace level. GCMS, on the other equipment) regulates the restric- styrene and brominated aromatic FTIR spectroscopy – hand, is more time consuming with tion of the use of brominated triazine. fast, non-destructive, simple respect to sample preparation and flame-retardants in electrical and data analysis. electronic devices as of July 2006. Figure 1 presents the structural In order to comply with the requi- Consequently, polybrominated formulae of brominated biphenyls. rements of the RoHS directive, In general, it is recommended to biphenyls (PBB) and polybromi- first the total bromine content of carry out an overall pre-screening nated diphenylethers (PBDE) can According to RoHS, the following a sample is determined. If this via energy-dispersive X-ray no longer be used as flame-retar- compounds are considered haz- exceeds 5 % after the preliminary fluorescence (EDX). Using this dants in polymers unless their con- ardous: pentabrominated diphenyl examination using the EDX sys- analytical method the total concen- centrations are lower than 1,000 ether (PentaBDE) and octabromi- tems, infrared spectroscopy is tration of elemental bromine in the ppm. The objective of the RoHS nated diphenyl ether (OctaBDE). recommended as this will enable sample is detected, although it is directive is the protection of hu- OctaBDE has been used in poly- identification of compounds. not possible to distinguish which man health and the environment mers such as ABS and PS. Current- This simple and non-destructive compound actually contains from hazardous effects. During ly, decaBDE is largely being used method quickly leads to useful bromine. When more than 5 % of recycling of electronics waste, as a flame retardant in PS, PE, ABS results. Compound identification total bromine is detected, FTIR contamination by brominated and polyester. DecaBDE has not is possible as the flame-retardants, can be used for further identifica- compounds should therefore be yet been included in the RoHS di- were present up to now in poly- tion of bromine compounds. When reduced. rective. Commercial decaBDE mers in concentrations of higher less than 5 % bromine is detected, however consists of a mixture of than 5 %. This level is still detect- GCMS analysis can be implement- Polybrominated biphenyls are approximately 97 % - 98 % able in polymer mixtures using ed for separation and identifica- classified as health hazards. PBB decaBDE and 0.3 % up to 3 % of FTIR. Concentrations that appro- tion. and PBDE are chemicals that have, other BDE’s. Therefore, when a ach the detection limit, however, in the past, been used as flame- polymer contains 10 % decaBDE must be measured using other ana- Fast and straightforward IR-analy- retardants in polymers in concen- (containing 1 % contamination of lytical methods. In this case, sis of polymers is possible since Thermoplastic Polymers Brominated Flame Retardants ABS PS PP PE PC PC/ABS Poly amide Polyester PVC S-PS S-PU Tetrabromobisphenol A ȜȜ Ȝ Decabromodiphenyl Ether ȜȜȜȜ ȜȜȜ ȜȜȜȜ Octabromodiphenyl Ether ȜȜȜȜ Brominated Aromatic Triazine ȜȜȜȜ ȜȜ Ȝ Brominated Polystyrene ȜȜȜȜȜȜȜ Ȝ Thermoplastic Polymers Others Brominated Flame Retardants Epoxy Unsaturated Polyester Phenol Elastomer Adhesive · Paint Fiber Woody Tetrabromobisphenol A ȜȜȜ Ȝ Decabromodiphenyl Ether ȜȜȜȜȜ Ȝ Octabromodiphenyl Ether ȜȜ Brominated Aromatic Triazine Brominated Polystyrene Table 1**: Typical polymers and their flame-retardants. Listing of brominated flame-retardants and their use in polymers. (ABS = acrylonitrile-butadiene-styrene, PS = polystyrene, PP = polypropylene, PE = polyethylene, PC = polycarbonate, PVC = polyvinylchloride, PU = polyurethane) 10 Shimadzu News 1/2005 APPLICATION ominated flame- retardants in polymers 1.0 DBDPE (Decabromodiphenyl ether) Polystyrene with TBBPA 0.8 (Tetrabromobisphenol A) 0.6 Polystyrene with DBDPE ABS DBDPE 0.4 ABS Polystyrene with brominated PS with 5 % DBDPE DBDPE Bands aromatic Triazine 0.2 pure PS pure Polystyrene 0.0 400 350 300 250 200 175 150 125 100 75 50 4000 3500 3000 2500 2000 1750 1500 1250 1000 750 DBDPE measured with the single-reflection ATR method (diamond/KRS-5) 1/cm 1/cm Figure 2: Polystyrene spectra with and without flame-retardant as well as the Figure 3: IR spectra of polystyrene with several flame-retardants IR spectrum of the flame-retardant decabrominated diphenyl ether. brominated biphenyls exhibit their identification of brominated flame- state. The diamond sample surface (approximately 1 min.) and is eval- own very characteristic infrared retardants, where clear differences enables the application of high uated automatically according to spectra. The polystyrene example between the spectra can be seen. pressures to ensure that the sample RoHS guidelines. exhibits three spectra: DBDPE, Based on this information, an ana- is positioned tightly on the crystal PS with DBDPE and pure PS. The lytical method for fast identifica- so that optimum penetration of the To validate analysis results, the range in the IR fingerprint, where tion of brominated flame-retar- sample by the IR beam is guaran- spectrum is compared subsequently DBDPE in PS identification is pos- dants and polymers has been teed. The beam penetrates the sam- with a library of polymer spectra. sible, is clearly discernible (Figure developed using Shimadzu’s ple surface to a depth of approxi- For polymer identification, a 2). Figure 3 shows polystyrene FTIR-8400S in combination with mately 2 µm. database already containing 41 with other brominated flame- a single-reflection accessory. polymers (see table 2) is used. This retardant additives. As RoHS specifies a homogeneous database contains logical associa- In the present example, a diamond sample material, this depth of tions and the Distinction Software Fast identification of ATR unit with KRS-5 crystal was penetration is sufficient in order to tests for plausibility, for instance brominated flame-retardants used as single-reflection accessory. completely characterise the sample. by evaluation of signal ratios. A diamond as sample surface is Using this measuring configura- The fingerprint region of 1500 cm-1 recommended as the polymer can tion, the spectrum is acquired The decision criterion includes - 1000 cm-1 is important for the be present in a flexible or solid within a very short time interval warning messages that range from “Identification of the polymer not Abbreviation Polymer Abbreviation Polymer possible” to “Applied pressure not ABS Acrylonitrile-butadiene-styrene PI Polyimide sufficient” and finally to the con- ABS+PBDE ABS containing PBDE PMMA Polymethyl methacrylate clusion “O.K.” or “Not O.K.”. EVA Ethylene-vinylacetate copolymer PMMA+PBDE PMMA containing PBDE These FTIR analysis results can be NYLON Nylon POM Polyoxymethylene (acetal) considered as unambiguous when NYLON+PBDE Nylon containing PBDE POM+PBDE POM containing PBDE combined with the pre-analysis PBT Poly(butylene terephthalate) PP Polypropylene from the EDX System. PBT+PBDE PBT containing PBDE PP+PBDE PP containing PBDE PC Polycarbonate PPS Poly(phenylen sulfide) Infrared spectrometry can there- ȜȜȜȜ PC+PBDE PC containing PBDF PPS+PBDE PPS containing PBDE fore be regarded as a fast and sim- PC+TBBPA PC containing TBBPA (Tetrabromobisphenol A) PS Polystyrene ple alternative solution to the pre- PCTFE Polychlorotrifluoroethylene PS+PBDE PS containing PBDE selection of polymers. Minimal PCTFE+PBDE PCTFE containing PBDE PS+TBBPA PSPS containing TBBPA sample pretreatment is necessary PE Polyethylene PS+Triazine PS (containing brominated aromatic triazine) and fast results are obtained via PE+PBDE Polyethylene containing PBDE PU Polyurethane predefined methods. PEEK Polyether-ether-ketone PVA Poly(vinyl alcohol) PEEK+PBDE PEEK containing PBDE PVC Poly(vinyl chloride) * Directive 2002/95/EC of the European PEI Polyetherimide PVDF Poly(vinylidene fluoride) Parliament and of the council of 27 January PES Polyester PVDF+PBDE PVDF containing PBDE 2003 on the restriction of the use of certain PES+PBDE PES containing PBDE SBS Styrene-butadiene-styrene copolymer hazardous substances in electrical and PET Poly(ethylene terephthalate) SBS+PBDE SBS containing PBDE electronic equipment PET+PBDE PET containing PBDE ** Flame retardants chemicals association Table 2: Overview of 41 polymers and polymer mixtures in an expandable database of Japan (FRCJ) We will gladly send you further information. Please note the appropriate number on your reader reply card. Info 297 11.
Load more

Recommended publications
  • Scientific Committee on Toxicity, Ecotoxicity and the Environment
    EUROPEAN COMMISSION DIRECTORATE-GENERAL HEALTH AND CONSUMER PROTECTION Directorate C - Scientific Opinions Unit C2 – Management of Scientific Committees; scientific co-operation and networks Scientific Committee on Toxicity, Ecotoxicity and the Environment Brussels,C2/AST/csteeop/Octabromo Hum & Env 31102002/D(02) SCIENTIFIC COMMITTEE ON TOXICITY, ECOTOXICITY AND THE ENVIRONMENT (CSTEE) Opinion on the results of the Risk Assessment of: Diphenyl ether, octabromo derivative Environmental and Human Health Part CAS No.: 32536-52-0 EINECS No.: 251-087-9 Carried out in the framework of Council Regulation (EEC) 793/93 on the evaluation and control of the risks of existing substances1 1 Regulation 793/93 provides a systematic framework for the evaluation of the risks to human health and the environment of those substances if they are produced or imported into the Community in volumes above 10 tonnes per year. The methods for carrying out an in-depth Risk Assessment at Community level are laid down in Commission Regulation (EC) 1488/94, which is supported by a technical guidance document. 2 Terms of reference In the context of regulation 793/93 (Existing Substances Regulation) and on the basis of the examination of the Risk Assessment Report provided by the European Chemicals Bureau, The CSTEE is invited to examine the following issues. RISK TO THE ENVIRONMENT The risk assessment report concludes that: 1 There is a need for limiting the risks with regard to secondary poisoning concerns for the hexabromodiphenyl ether (hexa-BDE) component that is present in the commercial octa- BDE product. 2. As concerns secondary poisoning concerning octa-BDE and its debromination products, there is a need for further information and/or testing, although risk reduction measures should be considered in the absence of adequate scientific knowledge.
    [Show full text]
  • An Overview of Alternatives to Tetrabromobisphenol a (TBBPA) and Hexabromocyclododecane (HBCD)
    An Overview of Alternatives to Tetrabromobisphenol A (TBBPA) and Hexabromocyclododecane (HBCD) By Gregory Morose A Publication Of the Lowell Center For Sustainable Production Prepared for The Jennifer University of Massachusetts Altman Foundation Lowell March 2006 Purpose of this Study The Jennifer Altman Foundation has commissioned the Lowell Center for Sustainable Production (LCSP) of the University of Massachusetts Lowell to conduct a study of potential alternatives to TBBPA and HBCD. The Lowell Center for Sustainable Production The Lowell Center for Sustainable Production develops, studies, and promotes environmentally sound systems of production, healthy work environments, and economically viable work organizations. The Center operates on the premise that environmental quality, safe and healthy workplaces, and social accountability can be achieved while at the same time enhancing the economic life of firms and communities. This is accomplished by broadening the fundamental design criteria for all productive activities to include an explicit and comprehensive commitment to sustainability. The Center is composed of faculty and staff at the University of Massachusetts Lowell who work directly with industrial firms, social services institutions, citizen organizations, and government agencies to promote sustainable production. The LCSP is based at the University of Massachusetts Lowell, where it works closely with the Massachusetts Toxics Use Reduction Institute (TURI) and the Department of Work Environment. An Overview of Alternatives to Tetrabromobisphenol A (TBBPA) and Hexabromocyclododecane (HBCD) March, 2006 Prepared for: The Jennifer Altman Foundation By Gregory Morose A Publication of the Lowell Center for Sustainable Production University of Massachusetts Lowell One University Avenue Lowell, MA 01854 978-934-2980 Table of Contents INTRODUCTION........................................................................................
    [Show full text]
  • OCTABROMODIPHENYL ETHER – PORPHYROGENICITY AFTER REPEATED ADMINISTRATION to RATS ELŻBIETA BRUCHAJZER, BARBARA FRYDRYCH, and JADWIGA A
    ORIGINAL PAPERS International Journal of Occupational Medicine and Environmental Health 2012;25(4):392 – 403 DOI 10.2478/S13382-012-0055-1 OCTABROMODIPHENYL ETHER – PORPHYROGENICITY AFTER REPEATED ADMINISTRATION TO RATS ELŻBIETA BRUCHAJZER, BARBARA FRYDRYCH, and JADWIGA A. SZYMAŃSKA Medical University of Łódź, Łódź, Poland Department of Toxicology Abstract Objectives: Octabromodiphenyl ether (OctaBDE) is a flame retardant which has been withdrawn from common use due to its negative effect on the environment. The literature data regarding its toxicity addresses its effect on liver function, the endocrine and reproductive systems, as well as its developmental toxicology aspects. The aim of this study was to investigate the effect of repeated administration of OctaBDE on heme biosynthesis in rats. Materials and Methods: The study was per- formed on female Wistar rats. OctaBDE was administered intragastrically at four different doses (2, 8, 40 or 200 mg/kg/day) for 7, 14, 21 or 28 days. The following measures of heme synthesis disturbance were used: urinary excretion of porphyrins, liver concentration of porphyrins, the activity of delta-aminolevulinate synthase (ALA-S) and delta-aminolevulinate dehy- dratase (ALA-D) in the liver. Results: After 28 days of exposure, lower ALA-S and ALA-D activity was observed in the liver. Additionally, increased concentrations of high carboxylated porphyrins (octa- and heptacarboxyporphyrins) were found in the liver: from 2- to 10-fold after the 2 mg/kg/day doses and from 4- to 14-fold after the 8–200 mg/kg/day doses. The porphyrogenic effect of OctaBDE was also evidenced by augmented, dose-dependent and exposure time-dependent, concentrations of total porphyrins in urine (2–7.5-fold increase) and their urinary excretion (2–9-fold increase).
    [Show full text]
  • Polybrominated Diphenyl Ethers (Pbdes)
    DRAFT FOR ÉBAUCHE POUR PUBLIC COMMENTS COMMENTAIRES DU PUBLIC Canadian Environmental Protection Act, 1999 Environmental Screening Assessment Report on Polybrominated Diphenyl Ethers (PBDEs) February 2004 Environment Canada where x + y = 1 to 10 Figure 1. PBDE structure Introduction The Canadian Environmental Protection Act, 1999 (CEPA 1999) requires the Minister of the Environment and the Minister of Health to conduct screening assessments of substances that meet the categorization criteria set out in the Act and Regulations to determine, in an expeditious manner, whether substances present or may present a risk to the environment or to human health. Based on the results of a screening assessment, the Ministers can propose taking no further action with respect to the substance, adding the substance to the Priority Substances List (PSL) for further assessment, or recommending that the substance be added to the List of Toxic Substances in Schedule 1 and, where applicable, the implementation of virtual elimination. A screening assessment involves an analysis of a substance using conservative assumptions to determine whether the substance is “toxic” or capable of becoming “toxic” as defined in CEPA 1999. This environmental screening assessment examines various supporting information and develops conclusions based on a weight of evidence approach as required under Section 76.1 of CEPA 1999. The screening assessment does not present an exhaustive review of all available data; rather, it presents the most critical studies and lines of evidence supporting the conclusions. One line of evidence includes consideration of risk quotients to identify potential for ecological effects. However, other concerns that affect current or potential risk, such as persistence, bioaccumulation, chemical transformation and trends in ambient concentrations, are also examined in this report.
    [Show full text]
  • Octabromodiphenyl Ether Risk Reduction Strategy
    Risk Reduction Strategy and Analysis of Advantages and Drawbacks for Octabromodiphenyl Ether Final Report Prepared for Department for Environment, Food and Rural Affairs Contract Reference: 16/13/33 RPA June 2002 OCTABROMODIPHENYL ETHER RISK REDUCTION STRATEGY AND ANALYSIS OF ADVANTAGES AND DRAWBACKS FINAL REPORT June 2002 prepared for Department for Environment, Food and Rural Affairs by Risk & Policy Analysts Limited, Farthing Green House, 1 Beccles Road, Loddon, Norfolk, NR14 6LT, UK Tel: +44 1508 528465 Fax: +44 1508 520758 Email: [email protected] Web: www.rpaltd.co.uk RPA REPORT - ASSURED QUALITY Project: Ref/Title J355I/Octa Approach: In accordance with tender specification, RPA proposal and Steering Group input Report Status: Final Report Prepared by: Caspar Corden, Consultant Meg Postle, Director Approved for issue by: Meg Postle, Director Date: 24 June 2002 If printed by RPA, this report will be printed on 100% recycled, chlorine-free paper Risk & Policy Analysts EXECUTIVE SUMMARY 1. Introduction Under Regulation 793/93/EEC, octabromodiphenyl ether is a priority substance for risk assessment and, where necessary, risk management, at the European Union level. The UK and France are jointly responsible for addressing the risks associated with octabromodiphenyl ether (for the environment and human health respectively). Both the human health and environmental risk assessments have identified areas where there is a need for risk reduction. Furthermore, both have identified areas where there is a need for further information and/or testing and, given the uncertainties, where there may be a need for precautionary action to be taken to reduce the risks. The Department for Environment, Food and Rural Affairs (DEFRA) has contracted Risk & Policy Analysts Limited (RPA) to develop the risk reduction strategy for octabromodiphenyl ether.
    [Show full text]
  • European Union Risk Assessment Report
    N Br H N N COMMISSIO 403 E Br Br Br Br INT RESEARCH CENTRE EINECS No: 251-087-9 EUR 20 EUROPEA JO Br H O l ether, octabromo deriv. y n Br Br he p di CAS No: 32536-52-0 European Union Risk Assessment Report Protection 16 : Substances Priority List st European Institute for Health and Consumer 1 Bureau Chemicals Existing Volume European Chemicals Bureau European Union Risk Assessment Report CAS: 32536-52-0 EC: 251-087-9 diphenyl ether, octabromo derivative 16 PL-1 European Union Risk Assessment Report DIPHENYL ETHER, OCTABROMO DERIVATIVE CAS No: 32536-52-0 EINECS No: 251-087-9 RISK ASSESSMENT LEGAL NOTICE Neither the European Commission nor any person acting on behalf of the Commission is responsible for the use which might be made of the following information A great deal of additional information on the European Union is available on the Internet. It can be accessed through the Europa Server (http://europa.eu.int). Cataloguing data can be found at the end of this publication Luxembourg: Office for Official Publications of the European Communities, 2003 © European Communities, 2003 Reproduction is authorised provided the source is acknowledged. Printed in Italy DIPHENYL ETHER, OCTABROMO DERIVATIVE CAS No: 32536-52-0 EINECS No: 251-087-9 RISK ASSESSMENT Final Report, 2003 France and United Kingdom This document has been prepared by the French and UK rapporteurs on behalf of the European Union. The scientific work on the environmental part was prepared by the Building Research Establishment Ltd (BRE), under contract to the UK rapporteur.
    [Show full text]
  • Polybrominated Diphenyl Ethers (Pbdes): Sources, Pathways and Environmental Data October 2019
    Polybrominated diphenyl ethers (PBDEs): sources, pathways and environmental data October 2019 We are the Environment Agency. We protect and improve the environment. We help people and wildlife adapt to climate change and reduce its impacts, including flooding, drought, sea level rise and coastal erosion. We improve the quality of our water, land and air by tackling pollution. We work with businesses to help them comply with environmental regulations. A healthy and diverse environment enhances people's lives and contributes to economic growth. We can’t do this alone. We work as part of the Defra group (Department for Environment, Food & Rural Affairs), with the rest of government, local councils, businesses, civil society groups and local communities to create a better place for people and wildlife. Published by: © Environment Agency 2019 Environment Agency All rights reserved. This document may be Horizon House, Deanery Road, reproduced with prior permission of the Bristol BS1 5AH Environment Agency. www.gov.uk/environment-agency © Environment Agency copyright and / or database right 2009. All rights reserved. Maps included in this document contain data supplied under licence from: © Crown Copyright and database right 2009. All rights reserved. Ordnance Survey licence number 100026380. Further copies of this report are available from our publications catalogue: http://www.gov.uk/government/publications or our National Customer Contact Centre: 03708 506 506 Email: enquiries@environment- agency.gov.uk 2 of 33 Executive summary Polybrominated diphenyl ethers (PBDEs) are a group of man-made organobromine compounds. They have been used as flame retardants in a wide range of products including electrical and electronic equipment, textiles and foams.
    [Show full text]
  • Polybrominated Diphenyl Ethers (Pbdes)
    Biomonitoring | Polybrominated Diphenyl Ethers (PBDEs) Polybrominated Diphenyl Ethers (PBDEs) Polybrominated diphenyl ethers (PBDEs) are a group of brominated flame retardant chemicals that have been incorporated into a variety of manufactured products, including foam cushioning used in furniture and plastics used in televisions and computers. Flame retardants are intended to slow the rate of ignition and fire growth, allowing more time for people to escape from a fire or extinguish it. All PBDEs have a common structure of a diphenyl ether molecule, which may have from 1–10 bromine atoms attached; each particular PBDE variant is referred to as a congener. In theory, there could be as many as 209 PBDE congeners, but a much smaller number of congeners are commonly found in the commercial PBDE mixtures and in measurements of PBDEs in humans and the environment. Three commercial PBDE mixtures have been used in manufactured products since the 1960s and 1970s, when these chemicals came into use,1 with each mixture made up of congeners with varying degrees of bromination. The commercial pentabromodiphenyl ether (pentaBDE) and octabromodiphenyl ether (octaBDE) mixtures have not been manufactured or imported in the United States since 2004. The pentaBDE mixture, made up primarily of four- and five- bromine congeners, was used almost entirely in flexible polyurethane foam in furniture, mattresses, carpet padding, and automobile seats; and the octaBDE mixture, made up primarily of seven- and eight-bromine congeners, was used in acrylonitrile-butadiene-styrene (ABS) plastic for certain electric and electronic devices. A third product, the commercial decabromodiphenyl ether (decaBDE) mixture, is still manufactured and used in the United States.
    [Show full text]
  • Acenaphthene 83-32-9 5000 N 45000 N 100000 L 110 N 530 N Acephate 30560-19-1 110 N 980 N 2100 N 0.11 N 24 N Acetaldehyde 75-07-0
    Table A-6: 2021 Screening Levels Soil Exposure Ground Water Vapor Exposure Chemical Direct Contact Soil MTG Tap Ground Water Indoor Air Residential Com/Ind Excavation Residential Residential Residential Com/Industrial Residential Com/Ind Name CASRN (mg/kg) (mg/kg) (mg/kg) (mg/kg) (ug/L) (ug/L) (ug/L) (ug/m3) (ug/m3) Acenaphthene 83-32-9 5000 N 45000 N 100000 L 110 N 530 N Acephate 30560-19-1 110 N 980 N 2100 N 0.11 N 24 N Acetaldehyde 75-07-0 110 N 340 N 1900 N 0.077 N 19 N 9.4 N 39 N Acetochlor 34256-82-1 1800 N 16000 N 34000 N 5.6 N 350 N Acetone 67-64-1 85000 N 100000 L 100000 L 57 N 14000 N 32000 N 140000 N Acetone Cyanohydrin 75-86-5 100000 L 100000 L 100000 L 2.1 N 8.8 N Acetonitrile 75-05-8 1100 N 3400 N 19000 N 0.54 N 130 N 63 N 260 N Acetophenone 98-86-2 2500 S 2500 S 2500 S 12 N 1900 N Acetylaminofluorene, 2- 53-96-3 2 C 6 C 320 C 0.015 C 0.16 C 0.022 C 0.094 C Acrolein 107-02-8 0.2 N 0.6 N 3.4 N 0.00017 N 0.042 N 0.021 N 0.088 N Acrylamide 79-06-1 3.4 C 46 C 2400 C 0.0021 C 0.5 C 0.1 C 1.2 C Acrylic Acid 79-10-7 140 N 420 N 2300 N 0.0085 N 2.1 N 1 N 4.4 N Acrylonitrile 107-13-1 3.5 C 11 C 370 N 0.0023 C 0.52 C 0.41 C 1.8 C Adiponitrile 111-69-3 100000 L 100000 L 100000 L 6.3 N 26 N Alachlor 15972-60-8 140 C 410 C 18000 N 0.033 M 2 M Aldicarb 116-06-3 88 N 820 N 1800 N 0.015 M 3 M Aldicarb Sulfone 1646-88-4 88 N 820 N 1800 N 0.0088 M 2 M Aldicarb sulfoxide 1646-87-3 0.018 M 4 M Aldrin 309-00-2 0.55 C 1.8 C 59 N 0.03 C 0.0092 C 0.0057 C 0.025 C Allyl Alcohol 107-18-6 4.9 N 15 N 83 N 0.00086 N 0.21 N 0.1 N 0.44 N Allyl Chloride
    [Show full text]
  • Commercial Octabromodiphenyl Ether
    Stockholm Convention on Persistent Organic Pollutants Persistent Organic Pollutants Review Committee (POPRC) DRAFT RISK MANAGEMENT EVALUATION for Commercial octabromodiphenyl ether Draft prepared by: The ad hoc working group on commercial octabromodiphenyl ether April, 2008 Draft Risk Management Evaluation for Commercial octabromodiphenyl ether Note: In accordance with the procedure laid down in Article 8 of the Stockholm Convention, this draft was prepared by the Persistent Organic Review Committee (POPRC) during its intersessional work. Parties and observers to the Stockholm Convention are invited to provide technical and substantive comments on this draft. Comments received will be considered by the ad hoc working group and the revised draft will be made available for the fourth meeting of the POPRC (13-17 October 2008 in Geneva). Please submit your comments to the Secretariat of the Stockholm Convention preferably by e-mail no later than 18 May, 2008 to: Secretariat of the Stockholm Convention POPs Review Committee 11-13 chemin des Anémones CH-1219, Châtelaine, Geneva, Switzerland Fax: (+41 22) 917 80 98 E-mail: [email protected] ___________________________________________________________________________________ Ad hoc working group on commercial octabromodiphenyl ether Chair: Ms. Jacqueline Alvarez (Uruguay) Drafter: Mr. Sylvain Bintein (France) Members: Ms. Anahit Aleksandryan (Armenia), Prof. Ian Rae (Australia), Dr. Robert Chénier (Canada), Mr. Jianxin Hu (China), Dr. Alfredo Cueva (Ecuador) Chair from May, Mr. Sylvain Bintein (France)**, Prof. Masaru Kitano (Japan), Dr. Mohammed Khashashneh (Jordan), Ms. Evelin Fabjan (Slovenia)*, Dr. José V. Tarazona (Spain), Prof. Bo Wahlström, Ms. Maria Delvin (Sweden), Ms. Bettina Hitzfeld (Switzerland)**, Ms. Leena Ylä- Mononen (United Kingdom), Ms. Jacqueline Alvarez (Uruguay)* Chair until May, Dr.
    [Show full text]
  • SIAM 16, 27-30 May 2003 FR + UK:Eu SIDS INITIAL ASSESSMENT
    SIAM 16, 27-30 May 2003 FR + UK:eu SIDS INITIAL ASSESSMENT PROFILE CAS No. 32536-52-0 Chemical Name Diphenyl ether, octabromo derivative e.g. Br Br Br Br Structural Formula Br Br Br H H Br SUMMARY CONCLUSIONS OF THE SIAR Human Health Animal data show an absorption of Octabromodiphenyl ether (OBDPE) by oral or inhalation route with an accumulation of the parent compound or its metabolites in the liver and also in the adipose tissue and the lung following inhalation administration. The extent of absorption and elimination cannot be assessed from the data available. No information on the metabolism of OBDPE is available. Following oral administration, OBDPE is an inducer of xenobiotic metabolism. There are no measured data on OBDPE dermal absorption. However based on OBDPE physicochemical properties and analogy with PCBs, a dermal absorption of 4.5% may be estimated. Evidence from humans indicates that OBDPE, HxBDPE, HpBDPE and NonaBDPE which are components of commercial OBDPE can be absorbed into the body and distributed into the blood. Distribution to the adipose tissue was evidenced at least for OBDPE and HxBDPE. There are no data available on the rate of elimination or on bioaccumulation of OBDPE from human adipose tissue neither for PeBDPO but given the high lipophilicity of these compounds and the adipose tissue accumulation observed in rats following oral or inhalation routes, it can be assumed that in humans OBDPE might bioaccumulate in these tissues as well. Following pregnancy HxBDPE and others PBDPEs such as TeBDPE and PeBDPEs are excreted in the breast milk. Unfortunately, such measurements were not carried out on OBDPE.
    [Show full text]
  • Decabde Study: a Review of Available Scientific Research
    217/782-3397 January 25, 2006 The Honorable Rod R. Blagojevich Governor of Illinois 207 State House Springfield, Illinois 62706 Dear Governor Blagojevich: On July 1, 2005, you signed House Bill 2572 into law, creating the Brominated Fire Retardant Prevention Act (P.A. 94-100). Through this Act, the General Assembly stated its desire for the state to develop a precautionary approach regarding the production, use, storage, and disposal of products containing brominated fire retardants (BFRs). BFRs are chemicals that are widely used in the United States by manufacturers in order to meet stringent fire standards. BFRs are added to a multitude of products including plastic housings of electronics and computers, circuit boards, and the foam and textiles used in furniture. Polybrominated diphenyl ether (PBDE), which is a subcategory of BFRs, has the potential to disrupt thyroid hormone balance and contribute to a variety of developmental deficits, including low intelligence and learning disabilities. PBDE may also have the potential to cause cancer. P.A. 94-100 requires the Illinois EPA to submit to the General Assembly and the Governor a report that reviews the latest available scientific research to address the following issues regarding decabromodiphenyl ether (decaBDE): • levels of bio-accumulation in humans and the environment; • health effects resulting from human exposure; • health effects resulting from degradation products; and • available effective alternatives. To that end, enclosed is a copy of “DecaBDE Study: A Review of Available Scientific Research.” If you have any questions or comments, please contact me or Tom Hornshaw, Manager, Toxicity Assessment Unit, at 217/785-0832. Very truly yours, Douglas P.
    [Show full text]