Summaries of FY 1993 Research in the Chemical Sciences
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1 ~~~~~~~~~~~~~~A W# I I~ I LI~ IL * I 0 0 6S~~~~~~~~~~~~~ 0~~~~l~rr 0~~~~~~~rl~ A S .~~~~~~~11 Available to DOE and DOE contractors from the Office of Scientific and Technical Information, P.O. Box 62, Oak Ridge, TN 37831; prices available from (615) 576-8401. Available to the public from the National Technical Information Service, U.S. Department of Commerce, 5285 Port Royal Rd., Springfield, VA 22161. DOE/ER--0144/11 (DE93011855) August 1993 Distribution Categories UC-400 and UC-401 Summaries of FY 1993 Research in the Chemical Sciences U.S. Department of Energy Office of Energy Research Division.of Chemical Sciences This report was compiled for the Office of Energy Research from project summaries contained in the Research-In-Progress (RIP) database of the Office of Scientific and Technical Information, Oak Ridge, Tennessee. The RIP database describes new and ongoing energy and energy-related research projects carried out or sponsored by the Department of Energy. Contents PREFACE vii Brandeis University 32 CHEMICAL SCIENCES DIVISION viii California Institute of Technology 32 PROGRAM SUMMARIES ix University of California, Berkeley 33 LABORATORY ADMINISTRATION xiii University of California, Irvine 33 University of California, Los Angeles 33 NATIONAL LABORATORIES University of California, Santa Barbara 34 Photochemical and Radiation Sciences Clemson University 34 Ames Laboratory 1 Colorado State University 34 Argonne National Laboratory 1 University of Colorado 35 Brookhaven National Laboratory 2 Columbia University 35 Lawrence Berkeley Laboratory 3 Dartmouth College 36 National Renewable Energy Laboratory 4 University of Houston 36 Notre Dame Radiation Laboratory 5 Marquette University 37 Chemical Physics Massachusetts Institute of Technology 37 Ames Laboratory 7 University of Massachusetts at Boston 37 Argonne National Laboratory 8 University of Minnesota 38 Brookhaven National Laboratory 9 National Institute of Standards and 38 Lawrence Berkeley Laboratory 10 Technology, Gaithersburg Lawrence Livermore National Laboratory 11 University of New Orleans 38 Pacific Northwest Laboratory 11 University of North Carolina at Chapel 39 Hill Sandia National Laboratories, Livermore 12University12 of North Carolina at Charlotte 39 Atomic Physics Northwestern University 39 Argonne National Laboratory 13Ohio Ohio State UniversityUniversity4 40 Lawrence Berkeley Laboratory 14 Pennsylvania State University, University 40 Oak Ridge National Laboratory 14 Park Sandia National Laboratories, 15 University of Pittsburgh 41 Albuquerque Portland State University 41 Chemical Energy University of Rochester 41 Ames Laboratory 16 Rutgers, The State University of New 42 Argonne National Laboratory 17 Jersey Brookhaven National Laboratory 18 Stanford University 42 Lawrence Berkeley Laboratory 19 University of Tennessee at Knoxville 43 Los Alamos National Laboratory 20 University of Texas at Austin 43 National Renewable Energy Laboratory 20 Tulane University 43 Oak Ridge National Laboratory 20 Washington State University 44 Pacific Northwest Laboratory 22 Wayne State University 44 Separations and Analysis Chemical Physics Ames Laboratory - 22 Aerospace Corporation 44 Argonne National Laboratory 23 University of Akron 45 Brookhaven National Laboratory 23 Arizona State University 45 Idaho National Engineering Laboratory 24 University of Arizona 45 Lawrence Berkeley Laboratory 24 University of California, Los Angeles 46 Oak Ridge National Laboratory 24 Catholic University of America 46 Pacific Northwest Laboratory 26 University of Chicago 46 Heavy Element Chemistry University of Colorado 47 Argonne National Laboratory 27 Columbia University 48 Lawrence Berkeley Laboratory 27 Cornell University 48 Los Alamos National Laboratory 28 Emory University -49 Oak Ridge National Laboratory 29 University of Georgia 50 Chemical Engineering Sciences Harvard University 50 Lawrence Berkeley Laboratory 29 University of Illinois at Chicago 51 Los Alamos National Laboratory 30 Johns Hopkins University 51 Sandia National Laboratories, Livermore 30 University of Kentucky 52 OFFSITE INSTITUTIONS Massachusetts Institute of Technology 52 Photochemical and Radiation Sciences University of Massachusetts at Amherst 52 University of Akron 31 University of Michigan 53 University of Alabama 31 University of Minnesota 53 Arizona State University 31 National Institute of Standards and 54 Boston University 32 Technology, Gaithersburg Research in Chemical Sciences iii CONTENTS University of New Orleans 54 University of Illinois at 75 University of North Carolina at Chapel 55 Urbana-Champaign Hill Indiana University 75 University of Oregon ,55 University of Iowa 76 Pennsylvania State University, University 55 Kansas State University 76 Park Lehigh University77 University of Pennsylvania 55Louisiana State University Louisiana State University 77 Princeton University 56 University of Louisville 78 Rensselaer Polytechnic Institute 57 University of Maryland at College Park 78 Rice University 57 Massachusetts Institute of Technology 78 University of Rochester 57 University of Massachusetts at Amherst 79 University of Southern California 58 University of Michigan 79 Stanford University 58 University of Minnesota 79 State University of New York at Stony 59 University of Missouri at Columbia 80 Brook University of North Carolina at Chapel 80 University of Utah 59 Hll University of Washington 59 Northwestern University 80 University of Wisconsin at Madison 59 University of Oklahoma 81 Atomic Physics Pennsylvania State University, University 82 California State University, Fullerton 60 ,Park Clark Atlanta University . 60 University of Pennsylvania 83 University of Colorado 61 University of Pittsburgh 84 University of Connecticut 61 Purdue University 84 Cornell University 62 Rensselaer Polytechnic Institute 85 Georgia Institute of Technology 62 University of Rochester 86 Harvard University 62 Rutgers, The State University of New 86 Kansas State University 62 Jersey University of Kansas 63 University of South Carolina 87 University of Kentucky 63 University of Southern California 87 University of Louisville 64 Southern Illinois University 87 Michigan Technological University 64 Stanford University 87 National Institute of Standards and 64 State University of New York at 88 Technology, Gaithersburg Binghamton University of Nebraska at Lincoln 64 State University of New York at Buffalo 88 University of Nevada at Reno 65 Syracuse University 88 University of New Mexico 65 Texas A & M University 89 of Notre Dame 65 University of Texas at Austin 89 University of Notre Dame 65 Pennsylvania State University, Lehman 65 Tulane University90 University of Pittsburgh 66 University of Utah 90 Rice University 66 Virginia Polytechnic Institute and State 91 University of Rochester66 University University of Southern California 67 University of Washington 91 Wayne State University 92 University of Tennessee at Knoxville 67 Wni tt niversity adin92 nTexas A & M University 67 University of Wisconsin at Madison 92 University of Wisconsin at Milwaukee 92 University of Texas at Austin 67Yale University93 University of Toledo 68 Separations and Analysis Tulane University 68sAuburn University 94 Vanderbilt University 68 Brigham Young University 94 University of Virginia 69Brown University94 Western Michigan University 69 Colorado School of Mines 94 The College of William and Mary 69 Columbia University 95 Chemical Energy University of Delaware 95 University of Arizona 70 Duke University 95 Auburn University 70 University of Florida 96 Boston College 70 The George Washington University 96 California Institute of Technology 71 Georgia Institute of Technology 97 University of California, Davis 71 Hampton University 97 University of California, Irvine 71 University of Houston 97 University of California, San Diego 72 University of Idaho 97 University of California, Santa Barbara 72 University of Illinois at 98 Carnegie-Mellon University 72 Urbana-Champaign Colorado State University 72 Kansas State University 98 University of Colorado 73 Lehigh University 98 Columbia University 73 Louisiana State University 98 University of Connecticut 73 Massachusetts Institute of Technology 99 University of Delaware 74 Michigan State University 99 Harvard University 74 University of Michigan 99 IV Research in Chemical Sciences CONTENTS University of Minnesota 99 Yale University 113 University of Missouri at Rolla 100 Advanced Battery Technology-National National Institute of Standards and 100 Laboratories Technology, Gaithersburg Brookhaven National Laboratory 113 University of North Carolina at Chapel 101 Lawrence Berkeley Laboratory 113 Hill Los Alamos National Laboratory 114 Purdue University 101 Oak Ridge National Laboratory 114 Rensselaer Polytechnic Institute 101 Sandia National Laboratories, 115 State University of New York at Buffalo 102 Albuquerque Syracuse University 102 Advanced Battery Technology-Offsite University of Tennessee at Knoxville 102 Institutions Texas A & M University 103 Arizona State University 115 Texas Tech University 103 Case Western Reserve University 115 University of Texas at Austin 104 Clark University 116 University of Utah 104 Electro Energy, Inc. 116 Virginia Commonwealth University 105 Giner, Inc. 116 Washington State University 106 Hughes Aircraft Company 116 University of Wyoming 106 University of Minnesota 116 Heavy Element Chemistry Pennsylvania State University, University 117 Florida State University 106 Park University of New Mexico 106 Rutgers, The State University of New 117 Ohio State University