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Noncovalent Bonds Through Sigma and Pi-Hole Located on the Same Molecule. Guiding Principles and Comparisons
molecules Review Noncovalent Bonds through Sigma and Pi-Hole Located on the Same Molecule. Guiding Principles and Comparisons Wiktor Zierkiewicz 1,* , Mariusz Michalczyk 1,* and Steve Scheiner 2 1 Faculty of Chemistry, Wrocław University of Science and Technology, Wybrzeze˙ Wyspia´nskiego27, 50-370 Wrocław, Poland 2 Department of Chemistry and Biochemistry, Utah State University Logan, Logan, UT 84322-0300, USA; [email protected] * Correspondence: [email protected] (W.Z.); [email protected] (M.M.) Abstract: Over the last years, scientific interest in noncovalent interactions based on the presence of electron-depleted regions called σ-holes or π-holes has markedly accelerated. Their high directionality and strength, comparable to hydrogen bonds, has been documented in many fields of modern chemistry. The current review gathers and digests recent results concerning these bonds, with a focus on those systems where both σ and π-holes are present on the same molecule. The underlying principles guiding the bonding in both sorts of interactions are discussed, and the trends that emerge from recent work offer a guide as to how one might design systems that allow multiple noncovalent bonds to occur simultaneously, or that prefer one bond type over another. Keywords: molecular electrostatic potential; halogen bond; pnicogen bond; tetrel bond; chalcogen bond; cooperativity Citation: Zierkiewicz, W.; Michalczyk, M.; Scheiner, S. Noncovalent Bonds through Sigma and Pi-Hole Located on the Same 1. Introduction Molecule. Guiding Principles and The concept of the σ-hole, introduced to a wide audience in 2005 at a conference in Comparisons. Molecules 2021, 26, Prague by Tim Clark [1], influenced a way of thinking about noncovalent interactions 1740. -
University at Buffalo, Chemical and Biological Engineering February 2, 2021
University at Buffalo, Chemical and Biological Engineering February 2, 2021 CURRICULUM VITAE Gang Wu, Ph. D., Professor Department of Chemical and Biological Engineering University at Buffalo (UB), The State University of New York (SUNY), Buffalo, New York, USA E-mail: [email protected]; Phone: 716-645-8618 (office) ; 803-338-4924 (cell) Web: www.cbe.buffalo.edu/wu Education • 2004. Ph.D.: Environmental Engineering, Harbin Institute of Technology, Harbin, China. • 1999. M.S.: Applied Chemistry, Harbin Institute of Technology, Harbin, China. • 1997. B.S: Electrochemical Engineering, Harbin Institute of Technology, Harbin, China. Employment History • Aug 2020- present, Professor, University at Buffalo, SUNY, USA • Aug 2018-Aug 2020, Associate Professor, University at Buffalo, SUNY, USA • Aug 2014-Aug 2018, Assistant Professor, University at Buffalo, SUNY, USA • May 2010-Aug 2014, Staff Scientist, Los Alamos National Laboratory (LANL), USA • Jan 2008-May 2010, Postdoc, Los Alamos National Laboratory, USA • Feb 2006-Jan 2008, Postdoc, University of South Carolina, USA • Jan 2004-Jan 2006, Postdoc, Tsinghua University, Beijing, China Major Research Interest • Electrochemical Science and Engineering for Energy Technologies; • Electrocatalysis and photocatalysis for clean energy conversion: fuel cells, electrolyzers, CO2 reduction; electrosynthesis; • Electrochemical energy power sources for energy storage: batteries and supercapacitors; • Renewable fuel: NH3 (electrosynthesis, oxidation, and carking for H2 generation). Key Achievements and Recognition • Dr. Wu is internationally recognized as the leading researcher in the field of fuel cells and other sustainable electrochemical energy technologies. • Awarded more than $5.0 M in grant funding from federal agencies (DOE and NSF) since joining UB in August 2014. Those 14 projects (3 NSF and 11 DOE) focus on the development of advanced materials for electrochemical energy conversion and storage technologies such as fuel cells, water splitting, batteries, and renewable fuel (e.g., NH3). -
Bayesian Analysis of the Astrobiological Implications of Life's
Bayesian analysis of the astrobiological implications of life's early emergence on Earth David S. Spiegel ∗ y, Edwin L. Turner y z ∗Institute for Advanced Study, Princeton, NJ 08540,yDept. of Astrophysical Sciences, Princeton Univ., Princeton, NJ 08544, USA, and zInstitute for the Physics and Mathematics of the Universe, The Univ. of Tokyo, Kashiwa 227-8568, Japan Submitted to Proceedings of the National Academy of Sciences of the United States of America Life arose on Earth sometime in the first few hundred million years Any inferences about the probability of life arising (given after the young planet had cooled to the point that it could support the conditions present on the early Earth) must be informed water-based organisms on its surface. The early emergence of life by how long it took for the first living creatures to evolve. By on Earth has been taken as evidence that the probability of abiogen- definition, improbable events generally happen infrequently. esis is high, if starting from young-Earth-like conditions. We revisit It follows that the duration between events provides a metric this argument quantitatively in a Bayesian statistical framework. By (however imperfect) of the probability or rate of the events. constructing a simple model of the probability of abiogenesis, we calculate a Bayesian estimate of its posterior probability, given the The time-span between when Earth achieved pre-biotic condi- data that life emerged fairly early in Earth's history and that, billions tions suitable for abiogenesis plus generally habitable climatic of years later, curious creatures noted this fact and considered its conditions [5, 6, 7] and when life first arose, therefore, seems implications. -
ANTY 513.01: Seminar in Bioarchaeology and Skeletal Biology
University of Montana ScholarWorks at University of Montana Syllabi Course Syllabi Spring 1-2016 ANTY 513.01: Seminar in Bioarchaeology and Skeletal Biology Corey Ragsdale University of Montana, Missoula Follow this and additional works at: https://scholarworks.umt.edu/syllabi Let us know how access to this document benefits ou.y Recommended Citation Ragsdale, Corey, "ANTY 513.01: Seminar in Bioarchaeology and Skeletal Biology" (2016). Syllabi. 4657. https://scholarworks.umt.edu/syllabi/4657 This Syllabus is brought to you for free and open access by the Course Syllabi at ScholarWorks at University of Montana. It has been accepted for inclusion in Syllabi by an authorized administrator of ScholarWorks at University of Montana. For more information, please contact [email protected]. Anthropology 513 Bioarchaeology Seminar Instructor: Dr. Corey Ragsdale Office: Social Science 217 Email: [email protected] Office hours: TR 2:00 to 3:30 Course Description Bioarchaeology allows us to ‘people’ the past. To do this, bioarchaeologists follow two general rules of thumb. First, they contextualize human remains in physical space, cultural milieu, and pre-historic time. That is, skeletonized and mummified bodies are never examined without also considering their associated archaeological materials. Second, bioarchaeologists regard ancient bodies as bio-cultural phenomena. Human biology is impacted directly by culture, and vice versa. With these two ideas in hand, we will explore bioarchaeology’s history, development, major topical concerns, and debates. We will also engage critically with categories and assumptions about race, sex/gender, age, ethnicity, disease and disability, violence, and body parts. To conclude the semester, we will reflect upon bioarchaeology’s relevance in contemporary politics. -
2017 Journal Impact Factor (JCR)
See discussions, stats, and author profiles for this publication at: https://www.researchgate.net/publication/317604703 2017 Journal Impact Factor (JCR) Technical Report · June 2017 CITATIONS READS 0 12,350 1 author: Pawel Domagala Pomeranian Medical University in Szczecin 34 PUBLICATIONS 326 CITATIONS SEE PROFILE All content following this page was uploaded by Pawel Domagala on 20 June 2017. The user has requested enhancement of the downloaded file. 1 , I , , 1 1 • • I , I • I : 1 t ( } THOMSON REUTERS - Journal Data Filtered By: Selected JCR Year: 2016 Selected Editions: SCIE,SSCI Selected Category Scheme: WoS Rank Full Journal Title Journal Impact Factor 1 CA-A CANCER JOURNAL FOR CLINICIANS 187.040 2 NEW ENGLAND JOURNAL OF MEDICINE 72.406 3 NATURE REVIEWS DRUG DISCOVERY 57.000 4 CHEMICAL REVIEWS 47.928 5 LANCET 47.831 6 NATURE REVIEWS MOLECULAR CELL BIOLOGY 46.602 7 JAMA-JOURNAL OF THE AMERICAN MEDICAL ASSOCIATION 44.405 8 NATURE BIOTECHNOLOGY 41.667 9 NATURE REVIEWS GENETICS 40.282 10 NATURE 40.137 11 NATURE REVIEWS IMMUNOLOGY 39.932 12 NATURE MATERIALS 39.737 13 Nature Nanotechnology 38.986 14 CHEMICAL SOCIETY REVIEWS 38.618 15 Nature Photonics 37.852 16 SCIENCE 37.205 17 NATURE REVIEWS CANCER 37.147 18 REVIEWS OF MODERN PHYSICS 36.917 19 LANCET ONCOLOGY 33.900 20 PROGRESS IN MATERIALS SCIENCE 31.140 21 Annual Review of Astronomy and Astrophysics 30.733 22 CELL 30.410 23 NATURE MEDICINE 29.886 24 Energy & Environmental Science 29.518 25 Living Reviews in Relativity 29.300 26 MATERIALS SCIENCE & ENGINEERING R-REPORTS 29.280 27 NATURE -
Socit Chimique De France 2014 Prize Winners
Angewandte. Angewandte News Chemie Socit Chimique de France 2014 Prize Nazario Martn (Universidad Complutense de Winners Madrid) is the winner of the Prix franco-espagnol Awarded … Miguel Cataln–Paul Sabatier. Martn was featured The Socit Chimique de France has announced its here when he was awarded the 2012 EuCheMS 2014 prize winners. We congratulate all the awar- Lectureship.[4a] Martn is on the International dees and feature our authors and referees here. Advisory Boards of Chemistry—An Asian Journal, Max Malacria (Institut de Chimie des Substan- ChemPlusChem, and ChemSusChem. His report on ces Naturelles; ICSN) is the winner of the Prix modified single-wall nanotubes was recently fea- Joseph Achille Le Bel, which is awarded to tured on the cover of Chemistry—A European recognize internationally recognized research. Mal- Journal.[4b] acria studied at the Universit Aix-Marseille III, Michael Holzinger (Universit Joseph Four- where he completed his PhD under the supervision nier, Grenoble 1; UJF) is the winner of the Prix M. Malacria of Marcel Bertrand in 1974. From 1974–1981, he jeune chercheur from the Analytical Chemistry was matre-assistant with Jacques Gore at the Division. Holzinger carried out his PhD at the Universit Claude Bernard Lyon 1 (UCBL), and Friedrich-Alexander-Universitt Erlangen-Nrn- from 1981–1983, he carried out postdoctoral berg. After postdoctoral research at the Universit research with K. Peter C. Vollhardt at the Univer- Montpellier 2 (UM2) and the Max Planck Institute sity of California, Berkeley. He returned to the for Solid-State Research, and working at Robert UCBL as matre de conferences in 1983, and was Bosch, he joined Serge Cosniers group at the UJF made professor at the Universit Pierre et Marie as a CNRS charg de recherche. -
JOURNAL LIST Total Journals: 3751
Journal Format For Print Page: ISI 页码,1/62 SCIENCE CITATION INDEX - JOURNAL LIST Total journals: 3751 1. AAPG BULLETIN Monthly ISSN: 0149-1423 AMER ASSOC PETROLEUM GEOLOGIST, 1444 S BOULDER AVE, PO BOX 979, TULSA, USA, OK, 74119-3604 1. Science Citation Index 2. Science Citation Index Expanded 3. Current Contents - Physical, Chemical & Earth Sciences 2. ABDOMINAL IMAGING Bimonthly ISSN: 0942-8925 SPRINGER, 233 SPRING ST, NEW YORK, USA, NY, 10013 1. Science Citation Index 2. Science Citation Index Expanded 3. Current Contents - Clinical Medicine 4. BIOSIS Previews 3. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY Semiannual ISSN: 0065- 7727 AMER CHEMICAL SOC, 1155 16TH ST, NW, WASHINGTON, USA, DC, 20036 1. Science Citation Index 2. Science Citation Index Expanded 3. BIOSIS Previews 4. BIOSIS Reviews Reports And Meetings 4. ACADEMIC EMERGENCY MEDICINE Monthly ISSN: 1069-6563 WILEY-BLACKWELL, 111 RIVER ST, HOBOKEN, USA, NJ, 07030-5774 1. Science Citation Index 2. Science Citation Index Expanded 3. Current Contents - Clinical Medicine 5. ACADEMIC MEDICINE Monthly ISSN: 1040-2446 LIPPINCOTT WILLIAMS & WILKINS, 530 WALNUT ST, PHILADELPHIA, USA, PA, 19106- 3621 1. Science Citation Index 2. Science Citation Index Expanded 3. Current Contents - Clinical Medicine 6. ACCOUNTS OF CHEMICAL RESEARCH Monthly ISSN: 0001-4842 AMER CHEMICAL SOC, 1155 16TH ST, NW, WASHINGTON, USA, DC, 20036 1. Science Citation Index 2. Science Citation Index Expanded 3. Current Contents - Life Sciences 4. Current Contents - Physical, Chemical & Earth Sciences 7. ACI MATERIALS JOURNAL Bimonthly ISSN: 0889-325X AMER CONCRETE INST, 38800 COUNTRY CLUB DR, FARMINGTON HILLS, USA, MI, 48331 1. Science Citation Index 2. -
MIJST Is Covered and Cited by Science Citation Index Expanded
Journal Information Maejo International Journal of Science and Technology (ISSN 1905-7873 © 2011), the international journal for preliminary communications in Science and Technology is the first peerrefereed scientific journal of Maejo University (www.mju.ac.th). Intended as a medium for communication, discussion, and rapid dissemination of important issues in Science and Technology, articles are initially published online in an open access format, which thereby gives authors the chance to communicate with a wide range of readers in an international community. Publication Information MIJST is published triannually. Articles are available online and can be accessed free of charge at http://www.mijst.mju.ac.th. Printed and bound copies of each volume are produced and distributed to authors and selected groups or individuals. This journal and the individual contributions contained in it are protected under the copyright by Maejo University. Abstracting/Indexing Information MIJST is covered and cited by Science Citation Index Expanded, SCOPUS, Journal Citation Reports/Science Edition, Zoological Record, Chemical Abstracts Service (CAS), SciFinder Scholar, Directory of Open Access Journals (DOAJ) and Google Scholar. Contact Information Editorial office: Maejo International Journal of Science and Technology (MIJST), 1st floor, Orchid Building, Maejo University, San Sai, Chiang Mai 50290, Thailand Tel: +66-53-87-3880 E-mails: [email protected] MAEJO INTERNATIONAL JOURNAL MAEJO INTERNATIONAL JOURNAL OF SCIENCE AND TECHNOLOGY OF SCIENCE AND TECHNOLOGY Editor Duang Buddhasukh, Maejo University, Thailand. The International Journal for the Rapid Publication of Preliminary Associate Editors Communications in Science and Technology Jatuphong Varith, Maejo University, Thailand. Wasin Charerntantanakul, Maejo University, Thailand. Morakot Sukchotiratana, Chiang Mai University, Thailand. -
PUBLICATIONS 11 May 2021
ROBERT H. COWIE – PUBLICATIONS 11 May 2021 Google Scholar metrics Citations – 8939 (3794 since 2016), h-index – 47 (32 since 2016), i10-index – 109 (65 since 2016) Books (5) Joshi, R.C., Cowie, R.H. & Sebastian, L.S. (eds.) 2017. Biology and Management of Invasive Apple Snails. Philippine Rice Research Institute, Muñoz, Nueva Ecija. xvii + 405 p. Cowie, R.H., Rundell, R.J. & Yeung, N.W. 2017. Samoan Land Snails and Slugs – An Identification Guide. Department of Marine and Wildlife Resources, American Samoa Government. viii + 71 p. Cowie, R.[H.] 2014. Journey to a Waterfall. A Biologist in Africa. Lulu, Raleigh. x + 279 p. Staples, G.W. & Cowie, R.H. (eds.) 2001. Hawai‘i’s Invasive species. A guide to invasive plants and animals in the Hawaiian Islands. Mutual Publishing & Bishop Museum Press, Honolulu. xii + 116 p. Cowie, R.H., Evenhuis, N.L. & Christensen, C.C. 1995. Catalog of the native land and freshwater molluscs of the Hawaiian Islands. Backhuys Publishers, Leiden. vi + 248 p. Journal articles (136) 2021 Gerlach, J., Barker, G.M., Bick, C.S., Bouchet, P., Brodie, G., Christensen, C.C., Collins, T., Coote, T., Cowie, R.H., Fiedler, G.C., Griffiths, O.L., Florens, F.B.V, Hayes, K.A., Kim, J., Meyer, J.-Y., Meyer, W.M., III, Richling, I., Slapcinsky, J.D., Winsor, L. & Yeung, N.W. 2021. Negative impacts of the invasive predators Euglandina ‘rosea’ (Mollusca: Spiraxidae) and Platydemus manokwari (Platyhelminthes: Geoplanidae) when used as biological control agents against the pest snail Lisschatina fulica (Mollusca: Achatinidae). Biological Invasions 23(4): 997-1031. Rollins, R.L., Cowie, R.H., Echaluse, M.V. -
Spotlights on Our Sister Journals: Chemistryopen 5
On these pages, we feature aselection computer,click on any of the items to of the excellent work that has recently read the full article. Otherwise please been published in our sister journals. see the DOIs for easy online access If you are reading these pages on a through Wiley Online Library. Iodine Adducts A. Reinholdt, T. Vosch, J. Bendix* Modification of s-Donor Properties of TerminalCarbideLigands Investigated Through Carbide–Iodine AdductFormation To give and take:terminal ruthenium carbidecomplexes [(Cy P) X Ru C] (1;X= halide or pseudohalide), form charge-transfer 3 2 2 adducts with I2 exhibitinglarge variation in bond lengths and stretching frequencies. This showsthat the auxiliary ligand sphere on rutheniumenables control over the s-donor properties of car- bide ligands, elucidating their isolobal relationship with carbon monoxide. Angew.Chem. Int. Ed. DOI: 10.1002/anie.201606551 Density Functional Theory J. I. Schweizer, L. Meyer,A.Nadj, M. Diefenbach, M. C. Holthausen* Unraveling the Amine-Induced Disproportionation Reaction of Perchlorinated Silanes—A DFT Study Aneo twist:ADFT study on the amine-induceddisproportionation reactionofSi2Cl6 to neo-Si5Cl12 discloses astepwise rather than a concerted silylene insertion mechanism, which was generally ac- cepted for over half acentury. The resulting pictureappears gener- alizabletothe relatedchloride-induced chemistry recently explored (see graphic). Chem. Eur.J. DOI: 10.1002/chem.201602724 Aza-Diels–Alder Reactions Y. Kumatabara, S. Kaneko, S. Nakata,S.Shirakawa,* K. Maruoka Hydrogen-BondingCatalysis of TetraalkylammoniumSalts in an Aza-Diels–Alder Reaction Under observation:Apiperidine-derived tetraalkylammoniumsalt with anon-coordinating counteranion worked as an effective hydro- gen-bonding catalyst in an aza-Diels–Alder reactionofimines anda Danishefskydiene. -
Amatore CV English Personnal Data
C. Amatore, HonFRSC, HonFCSC Scientific Curriculum Vitæ French, Born December 1951, married, two Children 1. Academic Training o Education: • Undergraduate studies (1971-1974): Chemistry, Physics, Physical-Chemistry ; Ecole Normale Supérieure and University Paris 6, Paris, France, • Agrégation of Chemistry (1974) (highest professional professorship degree in France), o Doctorat d’Etat (1975-1979; cumulative grade equivalent to Ph.D. plus Habilitation; defended in December 1979); University Paris 7, Paris; performed under the guidance of Prof. Jean-Michel Savéant. o Post-Doctorate (1982-1983): Professor Jay K. Kochi, Indiana University at Bloomington, USA. 2. French Professorships 1974-1975 Research assistant, Department of Chemistry, Ecole Normale Supérieure (ENS), 1975-1984 CNRS Assistant Professor (AR, then CR), CNRS and University Paris 7, 1984-1990 CNRS Full Professor, first rank (DR2), CNRS and Department of Chemistry, ENS, 1990-2000 CNRS Full Professor, second rank (DR1), CNRS and Department of Chemistry, ENS, 2000-present CNRS Full Professor, first exceptional rank (DRCE1), CNRS and ENS, 2001-2004 Full Professor (former Louis Pasteur’s position), exceptional rank (PRCE1), University Pierre et Marie Curie (UPMC) and ENS, 2004-2007 Full Professor (former Louis Pasteur’s position), highest exceptional rank (PRCE2), University Pierre and Marie Curie (UPMC) and ENS, 2007-2017 Full Professor of the highest exceptional rank (DRCE CNRS) at ENS and UPMC, 2017-present Emeritus Professor of the highest exceptional rank (DRCE CNRS) at ENS -
The Kelvin and Temperature Measurements
Volume 106, Number 1, January–February 2001 Journal of Research of the National Institute of Standards and Technology [J. Res. Natl. Inst. Stand. Technol. 106, 105–149 (2001)] The Kelvin and Temperature Measurements Volume 106 Number 1 January–February 2001 B. W. Mangum, G. T. Furukawa, The International Temperature Scale of are available to the thermometry commu- K. G. Kreider, C. W. Meyer, D. C. 1990 (ITS-90) is defined from 0.65 K nity are described. Part II of the paper Ripple, G. F. Strouse, W. L. Tew, upwards to the highest temperature measur- describes the realization of temperature able by spectral radiation thermometry, above 1234.93 K for which the ITS-90 is M. R. Moldover, B. Carol Johnson, the radiation thermometry being based on defined in terms of the calibration of spec- H. W. Yoon, C. E. Gibson, and the Planck radiation law. When it was troradiometers using reference blackbody R. D. Saunders developed, the ITS-90 represented thermo- sources that are at the temperature of the dynamic temperatures as closely as pos- equilibrium liquid-solid phase transition National Institute of Standards and sible. Part I of this paper describes the real- of pure silver, gold, or copper. The realiza- Technology, ization of contact thermometry up to tion of temperature from absolute spec- 1234.93 K, the temperature range in which tral or total radiometry over the tempera- Gaithersburg, MD 20899-0001 the ITS-90 is defined in terms of calibra- ture range from about 60 K to 3000 K is [email protected] tion of thermometers at 15 fixed points and also described.