Quantum Mechanics (Schrodinger Equation)
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Path Integrals in Quantum Mechanics
Path Integrals in Quantum Mechanics Dennis V. Perepelitsa MIT Department of Physics 70 Amherst Ave. Cambridge, MA 02142 Abstract We present the path integral formulation of quantum mechanics and demon- strate its equivalence to the Schr¨odinger picture. We apply the method to the free particle and quantum harmonic oscillator, investigate the Euclidean path integral, and discuss other applications. 1 Introduction A fundamental question in quantum mechanics is how does the state of a particle evolve with time? That is, the determination the time-evolution ψ(t) of some initial | i state ψ(t ) . Quantum mechanics is fully predictive [3] in the sense that initial | 0 i conditions and knowledge of the potential occupied by the particle is enough to fully specify the state of the particle for all future times.1 In the early twentieth century, Erwin Schr¨odinger derived an equation specifies how the instantaneous change in the wavefunction d ψ(t) depends on the system dt | i inhabited by the state in the form of the Hamiltonian. In this formulation, the eigenstates of the Hamiltonian play an important role, since their time-evolution is easy to calculate (i.e. they are stationary). A well-established method of solution, after the entire eigenspectrum of Hˆ is known, is to decompose the initial state into this eigenbasis, apply time evolution to each and then reassemble the eigenstates. That is, 1In the analysis below, we consider only the position of a particle, and not any other quantum property such as spin. 2 D.V. Perepelitsa n=∞ ψ(t) = exp [ iE t/~] n ψ(t ) n (1) | i − n h | 0 i| i n=0 X This (Hamiltonian) formulation works in many cases. -
Key Concepts for Future QIS Learners Workshop Output Published Online May 13, 2020
Key Concepts for Future QIS Learners Workshop output published online May 13, 2020 Background and Overview On behalf of the Interagency Working Group on Workforce, Industry and Infrastructure, under the NSTC Subcommittee on Quantum Information Science (QIS), the National Science Foundation invited 25 researchers and educators to come together to deliberate on defining a core set of key concepts for future QIS learners that could provide a starting point for further curricular and educator development activities. The deliberative group included university and industry researchers, secondary school and college educators, and representatives from educational and professional organizations. The workshop participants focused on identifying concepts that could, with additional supporting resources, help prepare secondary school students to engage with QIS and provide possible pathways for broader public engagement. This workshop report identifies a set of nine Key Concepts. Each Concept is introduced with a concise overall statement, followed by a few important fundamentals. Connections to current and future technologies are included, providing relevance and context. The first Key Concept defines the field as a whole. Concepts 2-6 introduce ideas that are necessary for building an understanding of quantum information science and its applications. Concepts 7-9 provide short explanations of critical areas of study within QIS: quantum computing, quantum communication and quantum sensing. The Key Concepts are not intended to be an introductory guide to quantum information science, but rather provide a framework for future expansion and adaptation for students at different levels in computer science, mathematics, physics, and chemistry courses. As such, it is expected that educators and other community stakeholders may not yet have a working knowledge of content covered in the Key Concepts. -
Schrödinger Equation)
Lecture 37 (Schrödinger Equation) Physics 2310-01 Spring 2020 Douglas Fields Reduced Mass • OK, so the Bohr model of the atom gives energy levels: • But, this has one problem – it was developed assuming the acceleration of the electron was given as an object revolving around a fixed point. • In fact, the proton is also free to move. • The acceleration of the electron must then take this into account. • Since we know from Newton’s third law that: • If we want to relate the real acceleration of the electron to the force on the electron, we have to take into account the motion of the proton too. Reduced Mass • So, the relative acceleration of the electron to the proton is just: • Then, the force relation becomes: • And the energy levels become: Reduced Mass • The reduced mass is close to the electron mass, but the 0.0054% difference is measurable in hydrogen and important in the energy levels of muonium (a hydrogen atom with a muon instead of an electron) since the muon mass is 200 times heavier than the electron. • Or, in general: Hydrogen-like atoms • For single electron atoms with more than one proton in the nucleus, we can use the Bohr energy levels with a minor change: e4 → Z2e4. • For instance, for He+ , Uncertainty Revisited • Let’s go back to the wave function for a travelling plane wave: • Notice that we derived an uncertainty relationship between k and x that ended being an uncertainty relation between p and x (since p=ћk): Uncertainty Revisited • Well it turns out that the same relation holds for ω and t, and therefore for E and t: • We see this playing an important role in the lifetime of excited states. -
Motion and Time Study the Goals of Motion Study
Motion and Time Study The Goals of Motion Study • Improvement • Planning / Scheduling (Cost) •Safety Know How Long to Complete Task for • Scheduling (Sequencing) • Efficiency (Best Way) • Safety (Easiest Way) How Does a Job Incumbent Spend a Day • Value Added vs. Non-Value Added The General Strategy of IE to Reduce and Control Cost • Are people productive ALL of the time ? • Which parts of job are really necessary ? • Can the job be done EASIER, SAFER and FASTER ? • Is there a sense of employee involvement? Some Techniques of Industrial Engineering •Measure – Time and Motion Study – Work Sampling • Control – Work Standards (Best Practices) – Accounting – Labor Reporting • Improve – Small group activities Time Study • Observation –Stop Watch – Computer / Interactive • Engineering Labor Standards (Bad Idea) • Job Order / Labor reporting data History • Frederick Taylor (1900’s) Studied motions of iron workers – attempted to “mechanize” motions to maximize efficiency – including proper rest, ergonomics, etc. • Frank and Lillian Gilbreth used motion picture to study worker motions – developed 17 motions called “therbligs” that describe all possible work. •GET G •PUT P • GET WEIGHT GW • PUT WEIGHT PW •REGRASP R • APPLY PRESSURE A • EYE ACTION E • FOOT ACTION F • STEP S • BEND & ARISE B • CRANK C Time Study (Stopwatch Measurement) 1. List work elements 2. Discuss with worker 3. Measure with stopwatch (running VS reset) 4. Repeat for n Observations 5. Compute mean and std dev of work station time 6. Be aware of allowances/foreign element, etc Work Sampling • Determined what is done over typical day • Random Reporting • Periodic Reporting Learning Curve • For repetitive work, worker gains skill, knowledge of product/process, etc over time • Thus we expect output to increase over time as more units are produced over time to complete task decreases as more units are produced Traditional Learning Curve Actual Curve Change, Design, Process, etc Learning Curve • Usually define learning as a percentage reduction in the time it takes to make a unit. -
Exercises in Classical Mechanics 1 Moments of Inertia 2 Half-Cylinder
Exercises in Classical Mechanics CUNY GC, Prof. D. Garanin No.1 Solution ||||||||||||||||||||||||||||||||||||||||| 1 Moments of inertia (5 points) Calculate tensors of inertia with respect to the principal axes of the following bodies: a) Hollow sphere of mass M and radius R: b) Cone of the height h and radius of the base R; both with respect to the apex and to the center of mass. c) Body of a box shape with sides a; b; and c: Solution: a) By symmetry for the sphere I®¯ = I±®¯: (1) One can ¯nd I easily noticing that for the hollow sphere is 1 1 X ³ ´ I = (I + I + I ) = m y2 + z2 + z2 + x2 + x2 + y2 3 xx yy zz 3 i i i i i i i i 2 X 2 X 2 = m r2 = R2 m = MR2: (2) 3 i i 3 i 3 i i b) and c): Standard solutions 2 Half-cylinder ϕ (10 points) Consider a half-cylinder of mass M and radius R on a horizontal plane. a) Find the position of its center of mass (CM) and the moment of inertia with respect to CM. b) Write down the Lagrange function in terms of the angle ' (see Fig.) c) Find the frequency of cylinder's oscillations in the linear regime, ' ¿ 1. Solution: (a) First we ¯nd the distance a between the CM and the geometrical center of the cylinder. With σ being the density for the cross-sectional surface, so that ¼R2 M = σ ; (3) 2 1 one obtains Z Z 2 2σ R p σ R q a = dx x R2 ¡ x2 = dy R2 ¡ y M 0 M 0 ¯ 2 ³ ´3=2¯R σ 2 2 ¯ σ 2 3 4 = ¡ R ¡ y ¯ = R = R: (4) M 3 0 M 3 3¼ The moment of inertia of the half-cylinder with respect to the geometrical center is the same as that of the cylinder, 1 I0 = MR2: (5) 2 The moment of inertia with respect to the CM I can be found from the relation I0 = I + Ma2 (6) that yields " µ ¶ # " # 1 4 2 1 32 I = I0 ¡ Ma2 = MR2 ¡ = MR2 1 ¡ ' 0:3199MR2: (7) 2 3¼ 2 (3¼)2 (b) The Lagrange function L is given by L('; '_ ) = T ('; '_ ) ¡ U('): (8) The potential energy U of the half-cylinder is due to the elevation of its CM resulting from the deviation of ' from zero. -
Uniting the Wave and the Particle in Quantum Mechanics
Uniting the wave and the particle in quantum mechanics Peter Holland1 (final version published in Quantum Stud.: Math. Found., 5th October 2019) Abstract We present a unified field theory of wave and particle in quantum mechanics. This emerges from an investigation of three weaknesses in the de Broglie-Bohm theory: its reliance on the quantum probability formula to justify the particle guidance equation; its insouciance regarding the absence of reciprocal action of the particle on the guiding wavefunction; and its lack of a unified model to represent its inseparable components. Following the author’s previous work, these problems are examined within an analytical framework by requiring that the wave-particle composite exhibits no observable differences with a quantum system. This scheme is implemented by appealing to symmetries (global gauge and spacetime translations) and imposing equality of the corresponding conserved Noether densities (matter, energy and momentum) with their Schrödinger counterparts. In conjunction with the condition of time reversal covariance this implies the de Broglie-Bohm law for the particle where the quantum potential mediates the wave-particle interaction (we also show how the time reversal assumption may be replaced by a statistical condition). The method clarifies the nature of the composite’s mass, and its energy and momentum conservation laws. Our principal result is the unification of the Schrödinger equation and the de Broglie-Bohm law in a single inhomogeneous equation whose solution amalgamates the wavefunction and a singular soliton model of the particle in a unified spacetime field. The wavefunction suffers no reaction from the particle since it is the homogeneous part of the unified field to whose source the particle contributes via the quantum potential. -
1 the Principle of Wave–Particle Duality: an Overview
3 1 The Principle of Wave–Particle Duality: An Overview 1.1 Introduction In the year 1900, physics entered a period of deep crisis as a number of peculiar phenomena, for which no classical explanation was possible, began to appear one after the other, starting with the famous problem of blackbody radiation. By 1923, when the “dust had settled,” it became apparent that these peculiarities had a common explanation. They revealed a novel fundamental principle of nature that wascompletelyatoddswiththeframeworkofclassicalphysics:thecelebrated principle of wave–particle duality, which can be phrased as follows. The principle of wave–particle duality: All physical entities have a dual character; they are waves and particles at the same time. Everything we used to regard as being exclusively a wave has, at the same time, a corpuscular character, while everything we thought of as strictly a particle behaves also as a wave. The relations between these two classically irreconcilable points of view—particle versus wave—are , h, E = hf p = (1.1) or, equivalently, E h f = ,= . (1.2) h p In expressions (1.1) we start off with what we traditionally considered to be solely a wave—an electromagnetic (EM) wave, for example—and we associate its wave characteristics f and (frequency and wavelength) with the corpuscular charac- teristics E and p (energy and momentum) of the corresponding particle. Conversely, in expressions (1.2), we begin with what we once regarded as purely a particle—say, an electron—and we associate its corpuscular characteristics E and p with the wave characteristics f and of the corresponding wave. -
Quantum Mechanics
Quantum Mechanics Richard Fitzpatrick Professor of Physics The University of Texas at Austin Contents 1 Introduction 5 1.1 Intendedaudience................................ 5 1.2 MajorSources .................................. 5 1.3 AimofCourse .................................. 6 1.4 OutlineofCourse ................................ 6 2 Probability Theory 7 2.1 Introduction ................................... 7 2.2 WhatisProbability?.............................. 7 2.3 CombiningProbabilities. ... 7 2.4 Mean,Variance,andStandardDeviation . ..... 9 2.5 ContinuousProbabilityDistributions. ........ 11 3 Wave-Particle Duality 13 3.1 Introduction ................................... 13 3.2 Wavefunctions.................................. 13 3.3 PlaneWaves ................................... 14 3.4 RepresentationofWavesviaComplexFunctions . ....... 15 3.5 ClassicalLightWaves ............................. 18 3.6 PhotoelectricEffect ............................. 19 3.7 QuantumTheoryofLight. .. .. .. .. .. .. .. .. .. .. .. .. .. 21 3.8 ClassicalInterferenceofLightWaves . ...... 21 3.9 QuantumInterferenceofLight . 22 3.10 ClassicalParticles . .. .. .. .. .. .. .. .. .. .. .. .. .. .. 25 3.11 QuantumParticles............................... 25 3.12 WavePackets .................................. 26 2 QUANTUM MECHANICS 3.13 EvolutionofWavePackets . 29 3.14 Heisenberg’sUncertaintyPrinciple . ........ 32 3.15 Schr¨odinger’sEquation . 35 3.16 CollapseoftheWaveFunction . 36 4 Fundamentals of Quantum Mechanics 39 4.1 Introduction .................................. -
Path Integral Quantum Monte Carlo Study of Coupling and Proximity Effects in Superfluid Helium-4
Path Integral Quantum Monte Carlo Study of Coupling and Proximity Effects in Superfluid Helium-4 A Thesis Presented by Max T. Graves to The Faculty of the Graduate College of The University of Vermont In Partial Fullfillment of the Requirements for the Degree of Master of Science Specializing in Materials Science October, 2014 Accepted by the Faculty of the Graduate College, The University of Vermont, in partial fulfillment of the requirements for the degree of Master of Science in Materials Science. Thesis Examination Committee: Advisor Adrian Del Maestro, Ph.D. Valeri Kotov, Ph.D. Frederic Sansoz, Ph.D. Chairperson Chris Danforth, Ph.D. Dean, Graduate College Cynthia J. Forehand, Ph.D. Date: August 29, 2014 Abstract When bulk helium-4 is cooled below T = 2.18 K, it undergoes a phase transition to a su- perfluid, characterized by a complex wave function with a macroscopic phase and exhibits inviscid, quantized flow. The macroscopic phase coherence can be probed in a container filled with helium-4, by reducing one or more of its dimensions until they are smaller than the coherence length, the spatial distance over which order propagates. As this dimensional reduction occurs, enhanced thermal and quantum fluctuations push the transition to the su- perfluid state to lower temperatures. However, this trend can be countered via the proximity effect, where a bulk 3-dimensional (3d) superfluid is coupled to a low (2d) dimensional su- perfluid via a weak link producing superfluid correlations in the film at temperatures above the Kosterlitz-Thouless temperature. Recent experiments probing the coupling between 3d and 2d superfluid helium-4 have uncovered an anomalously large proximity effect, leading to an enhanced superfluid density that cannot be explained using the correlation length alone. -
Matter-Wave Diffraction of Quantum Magical Helium Clusters Oleg Kornilov * and J
s e r u t a e f Matter-wave diffraction of quantum magical helium clusters Oleg Kornilov * and J. Peter Toennies , Max-Planck-Institut für Dynamik und Selbstorganisation, Bunsenstraße 10 • D-37073 Göttingen • Germany. * Present address: Chemical Sciences Division, Lawrence Berkeley National Lab., University of California • Berkeley, CA 94720 • USA. DOI: 10.1051/epn:2007003 ack in 1868 the element helium was discovered in and named Finally, helium clusters are the only clusters which are defi - Bafter the sun (Gr.“helios”), an extremely hot environment with nitely liquid. This property led to the development of a new temperatures of millions of degrees. Ironically today helium has experimental technique of inserting foreign molecules into large become one of the prime objects of condensed matter research at helium clusters, which serve as ultra-cold nano-containers. The temperatures down to 10 -6 Kelvin. With its two very tightly bound virtually unhindered rotations of the trapped molecules as indi - electrons in a 1S shell it is virtually inaccessible to lasers and does cated by their sharp clearly resolved spectral lines in the infrared not have any chemistry. It is the only substance which remains liq - has been shown to be a new microscopic manifestation of super - uid down to 0 Kelvin. Moreover, owing to its light weight and very fluidity [3], thus linking cluster properties back to the bulk weak van der Waals interaction, helium is the only liquid to exhib - behavior of liquid helium. it one of the most striking macroscopic quantum effects: Today one of the aims of modern helium cluster research is to superfluidity. -
Zero-Point Energy and Interstellar Travel by Josh Williams
;;;;;;;;;;;;;;;;;;;;;; itself comes from the conversion of electromagnetic Zero-Point Energy and radiation energy into electrical energy, or more speciÞcally, the conversion of an extremely high Interstellar Travel frequency bandwidth of the electromagnetic spectrum (beyond Gamma rays) now known as the zero-point by Josh Williams spectrum. ÒEre many generations pass, our machinery will be driven by power obtainable at any point in the universeÉ it is a mere question of time when men will succeed in attaching their machinery to the very wheel work of nature.Ó ÐNikola Tesla, 1892 Some call it the ultimate free lunch. Others call it absolutely useless. But as our world civilization is quickly coming upon a terrifying energy crisis with As you can see, the wavelengths from this part of little hope at the moment, radical new ideas of usable the spectrum are incredibly small, literally atomic and energy will be coming to the forefront and zero-point sub-atomic in size. And since the wavelength is so energy is one that is currently on its way. small, it follows that the frequency is quite high. The importance of this is that the intensity of the energy So, what the hell is it? derived for zero-point energy has been reported to be Zero-point energy is a type of energy that equal to the cube (the third power) of the frequency. exists in molecules and atoms even at near absolute So obviously, since weÕre already talking about zero temperatures (-273¡C or 0 K) in a vacuum. some pretty high frequencies with this portion of At even fractions of a Kelvin above absolute zero, the electromagnetic spectrum, weÕre talking about helium still remains a liquid, and this is said to be some really high energy intensities. -
Relativistic Quantum Mechanics 1
Relativistic Quantum Mechanics 1 The aim of this chapter is to introduce a relativistic formalism which can be used to describe particles and their interactions. The emphasis 1.1 SpecialRelativity 1 is given to those elements of the formalism which can be carried on 1.2 One-particle states 7 to Relativistic Quantum Fields (RQF), which underpins the theoretical 1.3 The Klein–Gordon equation 9 framework of high energy particle physics. We begin with a brief summary of special relativity, concentrating on 1.4 The Diracequation 14 4-vectors and spinors. One-particle states and their Lorentz transforma- 1.5 Gaugesymmetry 30 tions follow, leading to the Klein–Gordon and the Dirac equations for Chaptersummary 36 probability amplitudes; i.e. Relativistic Quantum Mechanics (RQM). Readers who want to get to RQM quickly, without studying its foun- dation in special relativity can skip the first sections and start reading from the section 1.3. Intrinsic problems of RQM are discussed and a region of applicability of RQM is defined. Free particle wave functions are constructed and particle interactions are described using their probability currents. A gauge symmetry is introduced to derive a particle interaction with a classical gauge field. 1.1 Special Relativity Einstein’s special relativity is a necessary and fundamental part of any Albert Einstein 1879 - 1955 formalism of particle physics. We begin with its brief summary. For a full account, refer to specialized books, for example (1) or (2). The- ory oriented students with good mathematical background might want to consult books on groups and their representations, for example (3), followed by introductory books on RQM/RQF, for example (4).