Uniting the Wave and the Particle in Quantum Mechanics
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Path Integrals in Quantum Mechanics
Path Integrals in Quantum Mechanics Dennis V. Perepelitsa MIT Department of Physics 70 Amherst Ave. Cambridge, MA 02142 Abstract We present the path integral formulation of quantum mechanics and demon- strate its equivalence to the Schr¨odinger picture. We apply the method to the free particle and quantum harmonic oscillator, investigate the Euclidean path integral, and discuss other applications. 1 Introduction A fundamental question in quantum mechanics is how does the state of a particle evolve with time? That is, the determination the time-evolution ψ(t) of some initial | i state ψ(t ) . Quantum mechanics is fully predictive [3] in the sense that initial | 0 i conditions and knowledge of the potential occupied by the particle is enough to fully specify the state of the particle for all future times.1 In the early twentieth century, Erwin Schr¨odinger derived an equation specifies how the instantaneous change in the wavefunction d ψ(t) depends on the system dt | i inhabited by the state in the form of the Hamiltonian. In this formulation, the eigenstates of the Hamiltonian play an important role, since their time-evolution is easy to calculate (i.e. they are stationary). A well-established method of solution, after the entire eigenspectrum of Hˆ is known, is to decompose the initial state into this eigenbasis, apply time evolution to each and then reassemble the eigenstates. That is, 1In the analysis below, we consider only the position of a particle, and not any other quantum property such as spin. 2 D.V. Perepelitsa n=∞ ψ(t) = exp [ iE t/~] n ψ(t ) n (1) | i − n h | 0 i| i n=0 X This (Hamiltonian) formulation works in many cases. -
Schrödinger Equation)
Lecture 37 (Schrödinger Equation) Physics 2310-01 Spring 2020 Douglas Fields Reduced Mass • OK, so the Bohr model of the atom gives energy levels: • But, this has one problem – it was developed assuming the acceleration of the electron was given as an object revolving around a fixed point. • In fact, the proton is also free to move. • The acceleration of the electron must then take this into account. • Since we know from Newton’s third law that: • If we want to relate the real acceleration of the electron to the force on the electron, we have to take into account the motion of the proton too. Reduced Mass • So, the relative acceleration of the electron to the proton is just: • Then, the force relation becomes: • And the energy levels become: Reduced Mass • The reduced mass is close to the electron mass, but the 0.0054% difference is measurable in hydrogen and important in the energy levels of muonium (a hydrogen atom with a muon instead of an electron) since the muon mass is 200 times heavier than the electron. • Or, in general: Hydrogen-like atoms • For single electron atoms with more than one proton in the nucleus, we can use the Bohr energy levels with a minor change: e4 → Z2e4. • For instance, for He+ , Uncertainty Revisited • Let’s go back to the wave function for a travelling plane wave: • Notice that we derived an uncertainty relationship between k and x that ended being an uncertainty relation between p and x (since p=ћk): Uncertainty Revisited • Well it turns out that the same relation holds for ω and t, and therefore for E and t: • We see this playing an important role in the lifetime of excited states. -
Path Probabilities for Consecutive Measurements, and Certain "Quantum Paradoxes"
Path probabilities for consecutive measurements, and certain "quantum paradoxes" D. Sokolovski1;2 1 Departmento de Química-Física, Universidad del País Vasco, UPV/EHU, Leioa, Spain and 2 IKERBASQUE, Basque Foundation for Science, Maria Diaz de Haro 3, 48013, Bilbao, Spain (Dated: June 20, 2018) Abstract ABSTRACT: We consider a finite-dimensional quantum system, making a transition between known initial and final states. The outcomes of several accurate measurements, which could be made in the interim, define virtual paths, each endowed with a probability amplitude. If the measurements are actually made, the paths, which may now be called "real", acquire also the probabilities, related to the frequencies, with which a path is seen to be travelled in a series of identical trials. Different sets of measurements, made on the same system, can produce different, or incompatible, statistical ensembles, whose conflicting attributes may, although by no means should, appear "paradoxical". We describe in detail the ensembles, resulting from intermediate measurements of mutually commuting, or non-commuting, operators, in terms of the real paths produced. In the same manner, we analyse the Hardy’s and the "three box" paradoxes, the photon’s past in an interferometer, the "quantum Cheshire cat" experiment, as well as the closely related subject of "interaction-free measurements". It is shown that, in all these cases, inaccurate "weak measurements" produce no real paths, and yield only limited information about the virtual paths’ probability amplitudes. arXiv:1803.02303v3 [quant-ph] 19 Jun 2018 PACS numbers: Keywords: Quantum measurements, Feynman paths, quantum "paradoxes" 1 I. INTRODUCTION Recently, there has been significant interest in the properties of a pre-and post-selected quan- tum systems, and, in particular, in the description of such systems during the time between the preparation, and the arrival in the pre-determined final state (see, for example [1] and the Refs. -
Physical Quantum States and the Meaning of Probability Michel Paty
Physical quantum states and the meaning of probability Michel Paty To cite this version: Michel Paty. Physical quantum states and the meaning of probability. Galavotti, Maria Carla, Suppes, Patrick and Costantini, Domenico. Stochastic Causality, CSLI Publications (Center for Studies on Language and Information), Stanford (Ca, USA), p. 235-255, 2001. halshs-00187887 HAL Id: halshs-00187887 https://halshs.archives-ouvertes.fr/halshs-00187887 Submitted on 15 Nov 2007 HAL is a multi-disciplinary open access L’archive ouverte pluridisciplinaire HAL, est archive for the deposit and dissemination of sci- destinée au dépôt et à la diffusion de documents entific research documents, whether they are pub- scientifiques de niveau recherche, publiés ou non, lished or not. The documents may come from émanant des établissements d’enseignement et de teaching and research institutions in France or recherche français ou étrangers, des laboratoires abroad, or from public or private research centers. publics ou privés. as Chapter 14, in Galavotti, Maria Carla, Suppes, Patrick and Costantini, Domenico, (eds.), Stochastic Causality, CSLI Publications (Center for Studies on Language and Information), Stanford (Ca, USA), 2001, p. 235-255. Physical quantum states and the meaning of probability* Michel Paty Ëquipe REHSEIS (UMR 7596), CNRS & Université Paris 7-Denis Diderot, 37 rue Jacob, F-75006 Paris, France. E-mail : [email protected] Abstract. We investigate epistemologically the meaning of probability as implied in quantum physics in connection with a proposed direct interpretation of the state function and of the related quantum theoretical quantities in terms of physical systems having physical properties, through an extension of meaning of the notion of physical quantity to complex mathematical expressions not reductible to simple numerical values. -
Quantum Computing Joseph C
Quantum Computing Joseph C. Bardin, Daniel Sank, Ofer Naaman, and Evan Jeffrey ©ISTOCKPHOTO.COM/SOLARSEVEN uring the past decade, quantum com- underway at many companies, including IBM [2], Mi- puting has grown from a field known crosoft [3], Google [4], [5], Alibaba [6], and Intel [7], mostly for generating scientific papers to name a few. The European Union [8], Australia [9], to one that is poised to reshape comput- China [10], Japan [11], Canada [12], Russia [13], and the ing as we know it [1]. Major industrial United States [14] are each funding large national re- Dresearch efforts in quantum computing are currently search initiatives focused on the quantum information Joseph C. Bardin ([email protected]) is with the University of Massachusetts Amherst and Google, Goleta, California. Daniel Sank ([email protected]), Ofer Naaman ([email protected]), and Evan Jeffrey ([email protected]) are with Google, Goleta, California. Digital Object Identifier 10.1109/MMM.2020.2993475 Date of current version: 8 July 2020 24 1527-3342/20©2020IEEE August 2020 Authorized licensed use limited to: University of Massachusetts Amherst. Downloaded on October 01,2020 at 19:47:20 UTC from IEEE Xplore. Restrictions apply. sciences. And, recently, tens of start-up companies have Quantum computing has grown from emerged with goals ranging from the development of software for use on quantum computers [15] to the im- a field known mostly for generating plementation of full-fledged quantum computers (e.g., scientific papers to one that is Rigetti [16], ION-Q [17], Psi-Quantum [18], and so on). poised to reshape computing as However, despite this rapid growth, because quantum computing as a field brings together many different we know it. -
Assignment 2 Solutions 1. the General State of a Spin Half Particle
PHYSICS 301 QUANTUM PHYSICS I (2007) Assignment 2 Solutions 1 1. The general state of a spin half particle with spin component S n = S · nˆ = 2 ~ can be shown to be given by 1 1 1 iφ 1 1 |S n = 2 ~i = cos( 2 θ)|S z = 2 ~i + e sin( 2 θ)|S z = − 2 ~i where nˆ is a unit vector nˆ = sin θ cos φ ˆi + sin θ sin φ jˆ + cos θ kˆ, with θ and φ the usual angles for spherical polar coordinates. 1 1 (a) Determine the expression for the the states |S x = 2 ~i and |S y = 2 ~i. 1 (b) Suppose that a measurement of S z is carried out on a particle in the state |S n = 2 ~i. 1 What is the probability that the measurement yields each of ± 2 ~? 1 (c) Determine the expression for the state for which S n = − 2 ~. 1 (d) Show that the pair of states |S n = ± 2 ~i are orthonormal. SOLUTION 1 (a) For the state |S x = 2 ~i, the unit vector nˆ must be pointing in the direction of the X axis, i.e. θ = π/2, φ = 0, so that 1 1 1 1 |S x = ~i = √ |S z = ~i + |S z = − ~i 2 2 2 2 1 For the state |S y = 2 ~i, the unit vector nˆ must be pointed in the direction of the Y axis, i.e. θ = π/2 and φ = π/2. Thus 1 1 1 1 |S y = ~i = √ |S z = ~i + i|S z = − ~i 2 2 2 2 1 1 2 (b) The probabilities will be given by |hS z = ± 2 ~|S n = 2 ~i| . -
Path Integrals in Quantum Mechanics
Path Integrals in Quantum Mechanics Emma Wikberg Project work, 4p Department of Physics Stockholm University 23rd March 2006 Abstract The method of Path Integrals (PI’s) was developed by Richard Feynman in the 1940’s. It offers an alternate way to look at quantum mechanics (QM), which is equivalent to the Schrödinger formulation. As will be seen in this project work, many "elementary" problems are much more difficult to solve using path integrals than ordinary quantum mechanics. The benefits of path integrals tend to appear more clearly while using quantum field theory (QFT) and perturbation theory. However, one big advantage of Feynman’s formulation is a more intuitive way to interpret the basic equations than in ordinary quantum mechanics. Here we give a basic introduction to the path integral formulation, start- ing from the well known quantum mechanics as formulated by Schrödinger. We show that the two formulations are equivalent and discuss the quantum mechanical interpretations of the theory, as well as the classical limit. We also perform some explicit calculations by solving the free particle and the harmonic oscillator problems using path integrals. The energy eigenvalues of the harmonic oscillator is found by exploiting the connection between path integrals, statistical mechanics and imaginary time. Contents 1 Introduction and Outline 2 1.1 Introduction . 2 1.2 Outline . 2 2 Path Integrals from ordinary Quantum Mechanics 4 2.1 The Schrödinger equation and time evolution . 4 2.2 The propagator . 6 3 Equivalence to the Schrödinger Equation 8 3.1 From the Schrödinger equation to PI’s . 8 3.2 From PI’s to the Schrödinger equation . -
1 the Principle of Wave–Particle Duality: an Overview
3 1 The Principle of Wave–Particle Duality: An Overview 1.1 Introduction In the year 1900, physics entered a period of deep crisis as a number of peculiar phenomena, for which no classical explanation was possible, began to appear one after the other, starting with the famous problem of blackbody radiation. By 1923, when the “dust had settled,” it became apparent that these peculiarities had a common explanation. They revealed a novel fundamental principle of nature that wascompletelyatoddswiththeframeworkofclassicalphysics:thecelebrated principle of wave–particle duality, which can be phrased as follows. The principle of wave–particle duality: All physical entities have a dual character; they are waves and particles at the same time. Everything we used to regard as being exclusively a wave has, at the same time, a corpuscular character, while everything we thought of as strictly a particle behaves also as a wave. The relations between these two classically irreconcilable points of view—particle versus wave—are , h, E = hf p = (1.1) or, equivalently, E h f = ,= . (1.2) h p In expressions (1.1) we start off with what we traditionally considered to be solely a wave—an electromagnetic (EM) wave, for example—and we associate its wave characteristics f and (frequency and wavelength) with the corpuscular charac- teristics E and p (energy and momentum) of the corresponding particle. Conversely, in expressions (1.2), we begin with what we once regarded as purely a particle—say, an electron—and we associate its corpuscular characteristics E and p with the wave characteristics f and of the corresponding wave. -
Path Integral Quantum Monte Carlo Study of Coupling and Proximity Effects in Superfluid Helium-4
Path Integral Quantum Monte Carlo Study of Coupling and Proximity Effects in Superfluid Helium-4 A Thesis Presented by Max T. Graves to The Faculty of the Graduate College of The University of Vermont In Partial Fullfillment of the Requirements for the Degree of Master of Science Specializing in Materials Science October, 2014 Accepted by the Faculty of the Graduate College, The University of Vermont, in partial fulfillment of the requirements for the degree of Master of Science in Materials Science. Thesis Examination Committee: Advisor Adrian Del Maestro, Ph.D. Valeri Kotov, Ph.D. Frederic Sansoz, Ph.D. Chairperson Chris Danforth, Ph.D. Dean, Graduate College Cynthia J. Forehand, Ph.D. Date: August 29, 2014 Abstract When bulk helium-4 is cooled below T = 2.18 K, it undergoes a phase transition to a su- perfluid, characterized by a complex wave function with a macroscopic phase and exhibits inviscid, quantized flow. The macroscopic phase coherence can be probed in a container filled with helium-4, by reducing one or more of its dimensions until they are smaller than the coherence length, the spatial distance over which order propagates. As this dimensional reduction occurs, enhanced thermal and quantum fluctuations push the transition to the su- perfluid state to lower temperatures. However, this trend can be countered via the proximity effect, where a bulk 3-dimensional (3d) superfluid is coupled to a low (2d) dimensional su- perfluid via a weak link producing superfluid correlations in the film at temperatures above the Kosterlitz-Thouless temperature. Recent experiments probing the coupling between 3d and 2d superfluid helium-4 have uncovered an anomalously large proximity effect, leading to an enhanced superfluid density that cannot be explained using the correlation length alone. -
Matter-Wave Diffraction of Quantum Magical Helium Clusters Oleg Kornilov * and J
s e r u t a e f Matter-wave diffraction of quantum magical helium clusters Oleg Kornilov * and J. Peter Toennies , Max-Planck-Institut für Dynamik und Selbstorganisation, Bunsenstraße 10 • D-37073 Göttingen • Germany. * Present address: Chemical Sciences Division, Lawrence Berkeley National Lab., University of California • Berkeley, CA 94720 • USA. DOI: 10.1051/epn:2007003 ack in 1868 the element helium was discovered in and named Finally, helium clusters are the only clusters which are defi - Bafter the sun (Gr.“helios”), an extremely hot environment with nitely liquid. This property led to the development of a new temperatures of millions of degrees. Ironically today helium has experimental technique of inserting foreign molecules into large become one of the prime objects of condensed matter research at helium clusters, which serve as ultra-cold nano-containers. The temperatures down to 10 -6 Kelvin. With its two very tightly bound virtually unhindered rotations of the trapped molecules as indi - electrons in a 1S shell it is virtually inaccessible to lasers and does cated by their sharp clearly resolved spectral lines in the infrared not have any chemistry. It is the only substance which remains liq - has been shown to be a new microscopic manifestation of super - uid down to 0 Kelvin. Moreover, owing to its light weight and very fluidity [3], thus linking cluster properties back to the bulk weak van der Waals interaction, helium is the only liquid to exhib - behavior of liquid helium. it one of the most striking macroscopic quantum effects: Today one of the aims of modern helium cluster research is to superfluidity. -
Relativistic Quantum Mechanics 1
Relativistic Quantum Mechanics 1 The aim of this chapter is to introduce a relativistic formalism which can be used to describe particles and their interactions. The emphasis 1.1 SpecialRelativity 1 is given to those elements of the formalism which can be carried on 1.2 One-particle states 7 to Relativistic Quantum Fields (RQF), which underpins the theoretical 1.3 The Klein–Gordon equation 9 framework of high energy particle physics. We begin with a brief summary of special relativity, concentrating on 1.4 The Diracequation 14 4-vectors and spinors. One-particle states and their Lorentz transforma- 1.5 Gaugesymmetry 30 tions follow, leading to the Klein–Gordon and the Dirac equations for Chaptersummary 36 probability amplitudes; i.e. Relativistic Quantum Mechanics (RQM). Readers who want to get to RQM quickly, without studying its foun- dation in special relativity can skip the first sections and start reading from the section 1.3. Intrinsic problems of RQM are discussed and a region of applicability of RQM is defined. Free particle wave functions are constructed and particle interactions are described using their probability currents. A gauge symmetry is introduced to derive a particle interaction with a classical gauge field. 1.1 Special Relativity Einstein’s special relativity is a necessary and fundamental part of any Albert Einstein 1879 - 1955 formalism of particle physics. We begin with its brief summary. For a full account, refer to specialized books, for example (1) or (2). The- ory oriented students with good mathematical background might want to consult books on groups and their representations, for example (3), followed by introductory books on RQM/RQF, for example (4). -
Lecture 3: Wave Properties of Matter
3 WAVE PROPERTIES OF MATTER 1 3 Wave properties of matter In Lecture 1 we mapped out some of the principal interactions between photons and matter (elec- trons). At the quantum level, individual photons and electrons are described as particles in the various relationships used to describe phenomena such as the photo{electric effect and Compton scattering. We are building up a map of quantum interactions (Table 1). Under certain circum- particle wave electron Thomson's experiment Photo{electric effect Compton effect low{energy photon photo{electric effect interference diffraction high{energy photon Compton effect Pair production Table 1: A simple map of quantum behaviour. stances, low energy photons can act as particles or as waves. Importantly, such photons never display both wave{like and particle{like properties in the same experiment (Two-slit experiment). The blank spaces in Table 1 provide the directions we must investigate in order to complete our simple quantum map: can high energy photons, X{ and γ{rays, act as waves, and can electrons { classically viewed as matter particles { also act in a wave{like manner? • X{ray diffraction { high energy photons can behave as waves. • De Broglie suggests a relationship between momentum (mass) and wavelength { a wave{like description of matter? • Electron scattering and transmission electron diffraction photography confirm wave phenom- ena in electrons. • A wave mechanics primer. • The uncertainty principle derived using wave physics. • Bohr's complementarity principle and an introduction to the two slit experiment. • The Copenhagen interpretation of quantum theory. • A wave description of a particle in a box leads to quantised energy states.