Geological Survey

Total Page:16

File Type:pdf, Size:1020Kb

Geological Survey DEPARTMENT OF THE INTERIOR BULLETIN OF THE UNITED STATES GEOLOGICAL SURVEY No. 13 A CRYSTALLOGRAPHIC STUDY OF THE THINOLITE OF LAKE LAHONTAN. WASHINGTON GOVERNMENT PRINTING OFFICE 1884 A.3DVBRTISBMBNT. (Bulletin No. 12.) The publications of the United States Geological Survey are issued in accordance with the statute approved March 3,1879, which declares that " The publications of the Geological Survey shall consist of the annual report of operations, geo-. logical and economic maps illustrating the resources and classifications of the lands, and reports upon general and economic geology and paleontology. The annual report of operations of the Geological Survey shall accompany the annual report of the Secretary o the Interior. AU special memoirs and reports of said Survey shall be issued in uniform quarto series if deemed necessary by the Director, but otherwise in ordinary octavos. Three thousand copies of each shall be p'ablished for scientific exchanges and for sale at the price of publication; and all literary and cartographic materials received in exchange shall be the property of the United States and form a part of the library of the organ­ ization. And the money resulting from the sale of such publications shall be covered into the Treas­ ury of the United States." . On July 7, 1882, the following joint resolution, referring to all Government publications, was passed by Congress: 1 ' That whenever any document or report shall be ordered printed by Congress, there shall be printed, in addition to the number in each case stated; the " usual number " (1,900) of copies for binding and distribution among those entitled to receive them." Under these general laws it will be seen that none of the Survey publications are furnished to it for gratuitous distribution. The 3,000 copies of the Annual^Beport are distributed through the document- rooms of Congress. The 1,900 copies of each of the publications are distributed to the officers, of the legislative and executive departments, and to stated depositories throughout the United States. Except, therefore, in those cases where an extra number of any publication is supplied to this office by special resolution of Congress, as has been done in the case of the second, third, fourth and fifth Annual Beports, or where a number has been ordered for its use by the Secretary of the Interior, as in the case of "Williams's Mineral Eesources, the Survey has no copies of any of its publications for gratuitous dis­ tribution. ANNUAL REPORTS. Of the Annual Keports there have been already published: X First Annual Eeport to the Hon. Carl Schnrz, by Clarence King. 1880. 8°. 79 pp. 1 map. A preliminary report describing plan of organization and publications. H. Eeport of the Director of the United States Geological Survey for 1880-'81, by J. W. Powell. 1882. 8°. Iv, 588 pp. 61 pi., 1 map. m. Third Annual Eeport of the United States Geological Survey, 1881-'82, by J. W. Powell. 1883. 8°. xviii, 564 pp. 67 pi. and maps. , l IV. Fourth Annual Eeport of the United States Geological Survey, 1882^83, by J. W. Powell. 1884. 8°. xii, 473 pp. 85 pi. and maps. ) The Fifth Annual Keport is in press. '. MONOGRAPHS. So far as already determined upon, the list of the Monographs is as follows: I. The Precious Metals, by Clarence King. In preparation. n. Tertiary History of the Grand Canon District, with atlas, by Capt. C. E. Dutton. Published, m. Geology of the Comstock Lode and Washoe District, with atlas, by George F. Beoker. Pub­ lished. TV. Comstock Mining and'Miners, by Eliot Lord. Published. V. Copper-bearing Books of Lake Superior, by Prof. E. D. Irving. Published. VI. Older Mesozoic Flora of Virginia, by Prof. William M. Fontaine. Published. VII. Silver-lead Deposits of Eureka, Nevada, by Joseph S. Curtis. Published. VLtr. Paleontology of the Eureka District, Nevada, by Charles D. "Walcott. In press. IX. Brachiopoda and Lamellibranchiata of the Earitan Clays and Green sand Marls of New Jersey, by E. P. Whitfield. In press. ADVERTISEMENT. Geology and Mining Industry of Leadville, with atlas, by S. F. Bmmons. In preparation. Geology of the Eureka Mining District, Nevada, with atlas, by Arnold Hague. In preparation. Lake Bonneville, by G. K. Gilbert. In preparation. Dinocerata: A Monograph on an Extinct Order of Ungulates, by Prof. 0. C. Marsh. In preparation. Sauropoda, by Prof. 0. C. Marsh. In preparation. Stegosauria, by Prof. 0. C. Marsh. In preparation. Of these Monographs, Nos. II, III, IV, V, VI, and VII are now published, viz: II. Tertiary History of the Grand Canon District, with atlas, by C. E. Dutton, Capt. IT. S. A. 1882. 4°. 264 pp. 42 pi. and atlas of 26 double sheets folio. Price, $10.12. HI. Geology of the Comstock Lode and Washoe District, with atlas, by G. F. Beoker. 1882. 4°. xv, 422 pp. 7 pi. and atlas of 21 sheets folio. Price, $11. IV. Comstock Mining and Miners, by Eliot Lord. 1883. 4°. xiv, 451pp. 3 pi. Price, $1.50. V. Copper-bearing Rocks of Lake Superior, by Prof. R. D. Irving. 1883. 4°. xvi, 464 pp. 29 pi. Price, $1.85. VI. Contributions to the Knowledge of the Older Mesozoio Flora of Virginia, by William M. Fontaine. 1883. 4°. xix, 128 pp. 54 11., 54 pi. Price, $1.05. VLI. Silver-lead Deposits of Eureka, Nevada, by Joseph S. Curtis. 1884. 4°. xii, 200 pp. 15 pi. Price, $1.20. Nos. VILT and IX are in press and will soon appear. The others, to which numbers are not assigned, are in preparation. BULLETINS. The Bulletins of the Survey will contain such papers relating to the general purpose of its work as do not properly come under the heads of ANNUAL REPORTS or MONOGRAPHS. Each of these Bulletins will contain but one paper, and be complete in itself. They will, however, be numbered in a continuous series, and will in time be united into volumes of convenient size. To facilitate this each Bulletin will have two paginations, one proper to itself and another which be­ longs to it as part of the volume. Of this series of Bulletins Nos. 1,2,3,4,5,6,7,8,9,10,11, and 12 are already published, viz: 1. Ou Hypersthene-Andesite and on Triclinic Pyroxene in Augitic Rocks, by Whitman Cross, with & Geological Sketch of Buffalo Peaks, Colorado, by S. F. Emmons. 1883. 8°. 42 pp. 2 pi. Price, 10 cents. 2. Gold and Silver Conversion Tables, giving, the Coining Value of Troy Ounces of Fine Metal, &c.,by Albert Williams, jr. 1883. 8°. ii, 8 pp. Price, 5 cents. 3. On the Fossil Faunas of the Upper Devonian along the Meridian of 76° 30', from Tompkins County, New York, to Bradford County, Pennsylvania, by Henry S.Williams. 1884. 8°. 36pp. Price, 5 cents. 4. On Mesozoic Fossils, by Charles A. White. 1884. 8°. 36 pp. 9 pi. Price, 5 cents. 5. A Dictionary of Altitudes in the United States, compiled by Henry Gannett. 1884. 8°. 325pp. Price, 20 cents. 6. Elevations in the Dominion of Canada, by J. W. Spencer. 1884. 8°. 43 pp. Price, 5 cents. 7. Mapoteca Geologica Americana. A Catalogue of Geological Maps of America (North and South), 17524881, by JulesMarcou and John BelknapMarcou. 1884. 8°. 184pp. Price, 10 cents. 8. On Secondary Enlargements of Mineral Fragments in Certain Rocks, by R. D. Irving and C. R. Vanhise. 1884. 8°. 56 pp. Price 10 cents. 9. A Report of the Work done in the Washington Laboratory during the fiscal year 1883-'84. F. W. Clarke, chief chemist; T. M. Chatard, assistant. 1884. 8°. 40pp. Price 5 cents. 10. On the Cambrian Faunas of North America. Preliminary studies by Charles Doolittle Walcott. 1884. 8° 74pp. Price 5 cents. 11. On the Quaternary and Recent Mollusca of the Great Basin; with Descriptions of New Forms, by R. Ellsworth.Call; introduced by a sketch of the Quaternary Lakes of the Great Basin, by G. K. Gilbert. 1884. 8°. 66 pp. Price, 5 cents. 12. A Crystallographic Study of the Thinolite of Lake Lahontan, by Edward S. Dana. 1884. 8°. 34 pp. Price, 5 cents. STATISTICAL PAPERS. A fourth series of publications, having special reference to the mineral resources of the United States, is contemplated. Of that series the first has been published, viz: Mineral Resources of the United States, by Albert Williams, jr. 1883. 8°. xvii, 813 pp. Price, 50 cents. Correspondence relating to the publications of the Survey, and all remittances, which must be by postal note or money-order, should be addressed to the DIRECTOR OP THE UNITED STATES GEOLOGICAL SURVEY, Washington, D. 0. WASHINGTON, D. C., September 30,1884. DEPARTMENT OP THE INTERIOB BULLETIN OF THE UNITED STATES GEOLOGICAL SURVEY No. 13 WASHINGTON GOVERNMENT PRINTING OFFICE 1884 U. S. GEOLOGICAL SURVEY BULLETIN NO. 12 PL. I THINOLITE. UNITED STATES GEOLOGICAL SURVEY J. W. POWELL DIRECTOR A. CRYSTALLOGRAPHY STUDY OF THE THINOLITE OF LAKE LAHONTAN BY EDWARD S. DANA WASHINGTON GOVERNMENT PRINTING OFFICE 1884 LETTER OF TRANSMITTAL. 'UNITED STATES GEOLOGICAL SURVEY, DIVISION OF THE GREAT BASIN, Washington, Z>. (7., September 16, 1884. SIR: I have the honor to transmit herewith, for publication, a paper on Thinolite, by Prof. Edward S. Dana, of New Haven. The calcareous pseudomorph to which Mr, Clarence King gave the name "thinolite" has been referred by him and others to the mineral gaylussite, and the history of its conversion to calcite was believed to afford the key to the history of the oscillations of Lake Lahontan. Mr. Eussell's later and fuller investigations demonstrated the physical im­ possibility of the lake-history deduced by Eing, and the question of the' origin of the thinolite was thus reopened.
Recommended publications
  • Mineral Processing
    Mineral Processing Foundations of theory and practice of minerallurgy 1st English edition JAN DRZYMALA, C. Eng., Ph.D., D.Sc. Member of the Polish Mineral Processing Society Wroclaw University of Technology 2007 Translation: J. Drzymala, A. Swatek Reviewer: A. Luszczkiewicz Published as supplied by the author ©Copyright by Jan Drzymala, Wroclaw 2007 Computer typesetting: Danuta Szyszka Cover design: Danuta Szyszka Cover photo: Sebastian Bożek Oficyna Wydawnicza Politechniki Wrocławskiej Wybrzeze Wyspianskiego 27 50-370 Wroclaw Any part of this publication can be used in any form by any means provided that the usage is acknowledged by the citation: Drzymala, J., Mineral Processing, Foundations of theory and practice of minerallurgy, Oficyna Wydawnicza PWr., 2007, www.ig.pwr.wroc.pl/minproc ISBN 978-83-7493-362-9 Contents Introduction ....................................................................................................................9 Part I Introduction to mineral processing .....................................................................13 1. From the Big Bang to mineral processing................................................................14 1.1. The formation of matter ...................................................................................14 1.2. Elementary particles.........................................................................................16 1.3. Molecules .........................................................................................................18 1.4. Solids................................................................................................................19
    [Show full text]
  • Alamosite Pbsio3 C 2001 Mineral Data Publishing, Version 1.2 ° Crystal Data: Monoclinic
    Alamosite PbSiO3 c 2001 Mineral Data Publishing, version 1.2 ° Crystal Data: Monoclinic. Point Group: 2=m: Crystals ¯brous [010]; as radiating aggregates and balls, to 7.5 cm. k Physical Properties: Cleavage: Perfect on 010 . Hardness = 4.5 D(meas.) = 6.488(3) D(calc.) = [6.30] f g Optical Properties: Transparent to translucent. Color: Colorless to white, cream, or light gray. Luster: Adamantine. Optical Class: Biaxial ({). Orientation: Y = b. Dispersion: r < v; strong, weak inclined. ® = 1.945{1.947 ¯ = 1.955{1.961 ° = 1.959{1.968 2V(meas.) = 65± Cell Data: Space Group: P 2=n: a = 12.247 b = 7.059 c = 11.236 ¯ = 113:12± Z = 12 X-ray Powder Pattern: Tsumeb, Namibia. 3.34 (100), 3.56 (95), 3.53 (75), 2.300 (75), 3.23 (70), 2.987 (70), 3.25 (60) Chemistry: (1) (2) (3) SiO2 21.11 20.01 21.21 Al2O3 0.09 FeO 0.09 0.18 MnO 0.02 PbO 78.13 78.95 78.79 CaO trace 0.09 insol: 0.61 Total 99.94 99.34 100.00 (1) Alamos, Mexico. (2) Tsumeb, Namibia; by electron microprobe. (3) PbSiO3: Occurrence: As a rare secondary mineral in the oxidized zone of lead-bearing base metal deposits. Association: Wulfenite, leadhillite, cerussite (Alamos, Mexico); leadhillite, anglesite, melanotekite, °eischerite, kegelite, hematite (Tsumeb, Namibia); diaboleite, phosgenite, cerussite, wulfenite, willemite (Tiger, Arizona, USA); melanotekite, shattuckite, wickenburgite (Rawhide mine, Arizona, USA). Distribution: From Mexico, in Sonora, at Alamos, and the San Pascual mine, near Zimap¶an, Hidalgo. In the USA, from Arizona, in the Mammoth-St.
    [Show full text]
  • Infrare D Transmission Spectra of Carbonate Minerals
    Infrare d Transmission Spectra of Carbonate Mineral s THE NATURAL HISTORY MUSEUM Infrare d Transmission Spectra of Carbonate Mineral s G. C. Jones Department of Mineralogy The Natural History Museum London, UK and B. Jackson Department of Geology Royal Museum of Scotland Edinburgh, UK A collaborative project of The Natural History Museum and National Museums of Scotland E3 SPRINGER-SCIENCE+BUSINESS MEDIA, B.V. Firs t editio n 1 993 © 1993 Springer Science+Business Media Dordrecht Originally published by Chapman & Hall in 1993 Softcover reprint of the hardcover 1st edition 1993 Typese t at the Natura l Histor y Museu m ISBN 978-94-010-4940-5 ISBN 978-94-011-2120-0 (eBook) DOI 10.1007/978-94-011-2120-0 Apar t fro m any fair dealin g for the purpose s of researc h or privat e study , or criticis m or review , as permitte d unde r the UK Copyrigh t Design s and Patent s Act , 1988, thi s publicatio n may not be reproduced , stored , or transmitted , in any for m or by any means , withou t the prio r permissio n in writin g of the publishers , or in the case of reprographi c reproductio n onl y in accordanc e wit h the term s of the licence s issue d by the Copyrigh t Licensin g Agenc y in the UK, or in accordanc e wit h the term s of licence s issue d by the appropriat e Reproductio n Right s Organizatio n outsid e the UK. Enquirie s concernin g reproductio n outsid e the term s state d here shoul d be sent to the publisher s at the Londo n addres s printe d on thi s page.
    [Show full text]
  • New Mineral Names*
    American Mineralogist, Volume 71, pages 227-232, 1986 NEW MINERAL NAMES* Pers J. Dulw, Gsoncr Y. CHao, JonN J. FrrzperRrcr, RrcHeno H. LaNcr-nv, MIcHeer- FrerscHnn.aNo JRNBIA. Zncznn Caratiite* sonian Institution. Type material is at the Smithsonian Institu- tion under cataloguenumbers 14981I and 150341.R.H.L. A. M. Clark, E. E. Fejer, and A. G. Couper (1984) Caratiite, a new sulphate-chlorideofcopper and potassium,from the lavas of the 1869 Vesuvius eruption. Mineralogical Magazine, 48, Georgechaoite* 537-539. R. C. Boggsand S. Ghose (1985) GeorgechaoiteNaKZrSi3Or' Caratiite is a sulphate-chloride of potassium and copper with 2HrO, a new mineral speciesfrom Wind Mountain, New Mex- ideal formula K4Cu4Or(SO4).MeCl(where Me : Na and,zorCu); ico. Canadian Mineralogist, 23, I-4. it formed as fine greenacicular crystalsin lava of the 1869 erup- S. Ghose and P. Thakur (1985) The crystal structure of george- tion of Mt. Vesuvius,Naples, Italy. Caratiite is tetragonal,space chaoite NaKZrSi3Or.2HrO. Canadian Mineralogist, 23, 5-10. group14; a : 13.60(2),c : a.98(l) A, Z:2.The strongestlines of the powder partern arc ld A, I, hkll: 9.61(l00Xl l0); Electron microprobe analysis yields SiO, 43.17, 7-xO229.51, 6.80(80X200); 4.296(60X3 I 0); 3.0I 5( 100b)(a 20,32r); 2.747 (7 0) NarO 7.42,IGO I1.28, HrO 8.63,sum 100.010/0,corresponding (4 I t); 2.673(60X5 I 0); 2.478(60)(002); 2. 3 8 8(70Xa 3 l, 50I ); to empirical formula Na, orl(oru(Zro rrTio o,Feo o,)Si, or Oe' 2.
    [Show full text]
  • EB Dacortr, Richf'eld
    WHERRYITE, A NEW MINERAL FROM THE MAMMOTH MINE, ARIZONAT Richf'eld, Josern J. Fannv, tI . S. GeologicalSurvey; E. B. Dacortr, [Jtah; lNo S.cMunr.G. Gonnow, The Academy oJ l{atural Sciences oJ PhiladelPhia. Aesrnacl A new mineral from the Mammoth Mine, Arizona, having the formula Pbcos'2Pbsor .Pb(cl, oH)z.cuo is named in honor of Dr. Edgar Theodore wherry. The indices of re- fraction are a:1.942, P:2.01O and 1:2.924, and 2V:50' (calculated)' The specific gravity is 6.45. Wherryite was found in a vug just above the 760-foot level associated with chrysocolla, diabol6ite, and paralaurionite' IurnolucrroN In May of 1943 one of the authors, E. B. Daggett, then mining en- gineer at the Mammoth Mine, discovered a small vug of leadhillite crystals associatedwith cerussite, anglesite, phosgenite, paralaurionite, hydrocerussite, diabol6ite, bol6ite, matlockite' and quartz. Within the cavity was some friable chalcocite with a relict structure of the galena which it has replaced. The massive wall of the vug consisted ol a light-green fine granular mineral enclosing some bluish chrysocolla, and at the cavity some blue diabol6ite and greenishparalaurionite. This green matrix was up to five cm. in thickness and extended to the silicified wall of the vein-an altered qrartz monzonite. The minerals of this remarkable vug, and the crystallography of the leadhillite will be d.escribedin a later paper; some observations on the paragenesiswill be given here in order to describe the occurrenceoi the green matrix which has proven to be a new mineral. The name wherryite is given to this new mineral in honor of Dr' Edgar Theodore wherry, first editor of the American Minerologist, formerly curator of mineralogy at the U.
    [Show full text]
  • Cosmetic Minerals of Ancient Egypt
    Cosmetic Minerals of Ancient Egypt Minerals have been used for adornment for millennia. The Egyptians made an extensive use of many familiar minerals, and, according to recent discoveries, synthesized other compounds using relatively sophisticated chemical techniques. Egyptians were fond of eye and face coloration of white, green and black. Generally these were mineral powders mixed into pastes with fats. Minerals commonly used to make black powders were galena (PbS), manganese oxides such as pyrolusite, magnetite (iron oxide), cuprite and tenorite (copper oxides), and stibnite (antimony sulfide). Green eye paints used malachite (copper carbonate) and chrysocolla (hydrated copper silicate). White face paint often came often from cerussite (lead carbonate). One might speculate on the health effects of spreading such poisonous compounds thickly over one's face! The above mentioned minerals are common in deposits accessible to the Egyptians. Recent work on cosmetic powders preserved in their original containers and stored in the Louvre has turned up several rare minerals used as pigments. These minerals were either very rare or are unknown in Egyptian deposits. These are phosgenite (a lead chlorocarbonate) and laurionite( a lead chlor-hydroxide). Both would be suitable for white pigments, if found in quantity. Laurionite is a famous mineral from the ancient deposits at Laurium Greece, where it formed by the action of salty water on slags. It also occurs rarely in other oxidized zones over ore deposits, such as in Cornwall, England. Phosgenite is a bit more common, and can form with laurionite and other minerals in oxidized zones. The conditions of preservation of these minerals in Egyptian cosmetics make it unlikely that they are the effects of subsequent weathering of the cosmetics, but were originally pigment components.
    [Show full text]
  • Tasmanian Museum and Art Gallery
    Mineral Resources Tasmania TASMANIA DEVELOPMENT REPORT 1993/21 AND RESOURCES Mineralogical examination of some mineral samples from Tasmania, for the Tasmanian Museum and Art Gallery by R. S. Bottrill and R. N. Woolley The following samples. from the Petterd collection held by phosgenite in appearance, but was not tested due to its high the Tasmanian Museum and Art Gallery, Hobart, were quality. The cerussite was confirmed by XRD. examined to confirm the presence of several rare minerals reported in Tasmania (Department of Mines. 1970). The X1115: "Phosgenite, Dundas, Tasmania" samples were examined stereomicroscopically and by This sample varies from white to a moderate purplish X-ray diffraction (XRD, with a Philips PW 17 IOIPW 1050 brown in colour. It is largely a coarse-grained crystalline automated X-ray powder diffractometer). The results of aggregate, with crystals in vughs varying from bladed to these examinations are given below. fibrous aggregates. Much of the sample is smooth and etched or waterworn, and there is a partial red-brown X160: "Native lead, Mt Dundas, Tasmania" limonitic coating on some crystals. XRD indicates the This sample is grey and irregular to dendritic, and partly sample to be cerussite. decomposed. XRD indicated only litharge and minor hydrocerussite, but the sample is slightly malleable and X1116: "Phosgenite, Magnet, Tasmania" there is probably lead metal present in its core. There is no The sample actually consists of two quite different matrix, and it is not possible to confirm the natural specimens. One (Specimen A) contains a large grey, occurrence of the sample. glassy, blocky, partly broken crystal in a cavity in fine-grained, massive galena, with some massive to X624: "Matlockite on galena, Magnet, Tasmania" crystallised cerussite.
    [Show full text]
  • Matlockite Pbfcl C 2001-2005 Mineral Data Publishing, Version 1
    Matlockite PbFCl c 2001-2005 Mineral Data Publishing, version 1 Crystal Data: Tetragonal. Point Group: 4/m 2/m 2/m. Tabular crystals, to 5 cm, flattened on {001}, with {110}, {011}, and {111} modifications, may be equant, rounded. In subparallel aggregates, rosettelike, radiating, hemispherical; lamellar, cleavable massive. Physical Properties: Cleavage: {001}, perfect. Fracture: Uneven to subconchoidal. Tenacity: Brittle. Hardness = 2.5–3 D(meas.) = 7.12 D(calc.) = 7.16 Optical Properties: Transparent. Color: Colorless, pale yellow, amber-yellow, yellow-orange; colorless in transmitted light. Luster: Adamantine, pearly on {001}. Optical Class: Uniaxial (–); rarely biaxial due to strain. ω = 2.145 = 2.006 2V(meas.) = Small. Cell Data: Space Group: P 4/nmm (synthetic). a = 4.1104(2) c = 7.2325(5) Z = 2 X-ray Powder Pattern: Synthetic. 3.574 (100), 2.906 (45), 3.617 (40), 2.265 (40), 2.715 (35), 1.781 (25), 2.055 (20) Chemistry: (1) (2) (3) Pb 79.55 78.92 79.19 F 7.11 7.25 7.26 Cl 13.44 13.57 13.55 Total 100.10 [99.74] 100.00 (1) Cromford, England. (2) Tiger, Arizona, USA; original total given as 99.67%. (3) PbFCl. Occurrence: In the oxide zone of some lead-bearing mineral deposits. Association: Phosgenite, anglesite, cerussite, galena, sphalerite, barite, fluorite (Cromford, England); diaboleite, boleite, caledonite, leadhillite (Tiger, Arizona, USA). Distribution: Large crystals from the Bage and Wallclose mines, about 2.5 km south of Matlock, Derbyshire, England. In slag, at Laurium, Greece. In slag, along Baratti Beach and one km north of Campiglia, Tuscany, Italy.
    [Show full text]
  • Raman Spectroscopy of the Minerals Boleite, Cumengeite, Diaboleite and Phosgenite-Implications for the Analysis of Cosmetics of Antiquity
    COVER SHEET Frost, Ray and Martens, Wayde and Williams, Peter (2003) Raman spectroscopy of the minerals boléite, cumengéite, diaboléite and phosgenite –implications for the analysis of cosmetics of antiquity. Mineralogical Magazine 61(1):pp. 103-111. Accessed from http://eprints.qut.edu.au Copyright 2003 The Mineralogical Society RAMAN SPECTROSCOPY OF SOME BASIC CHLORIDE CONTAINING MINERALS OF LEAD AND COPPER RAY L. FROST•, WAYDE MARTENS and PETER A. WILLIAMS* Inorganic Materials Research Program, School of Physical and Chemical Sciences, Queensland University of Technology, GPO Box 2434, Brisbane Queensland 4001, Australia. *School of Science, Food and Horticulture, University of Western Sydney, Locked Bag 1797, Penrith South DC NSW 1797, Australia Endnote file: boléite, laurionite, pseudomalachite ABSTRACT Raman spectroscopy has been used to characterise several lead and mixed cationic-lead minerals including mendipite, perite, laurionite, diaboléite, boléite, pseudoboléite, chloroxiphite, and cumengéite. Raman spectroscopy enables their vibrational spectra to be compared. The low wavenumber region is characterised by the bands assigned to cation-chloride stretching and bending modes. Phosgenite is a mixed chloride-carbonate mineral and a comparison is made with the molecular structure of the aforementioned minerals. Each mineral shows different hydroxyl- stretching vibrational patterns, but some similarity exists in the Raman spectra of the hydroxyl deformation modes. Raman spectroscopy lends itself to the study of these types of minerals in complex mineral systems involving secondary mineral formation. Keywords: boléite, cumengéite, diaboleite, lead, copper, chloride, phosgenite, Raman spectroscopy INTRODUCTION The use of these compounds of lead for pharmaceutical and cosmetic purposes in antiquity have been known for some considerable time (Lacroix 1911; Lacroix and de Schulten 1908).
    [Show full text]
  • Topotaxy Relationships in the Transformation Phosgenite-Cerussite
    Topotaxy relationships in the transformation phosgenite-cerussite a, a C.M. Pina * , L. Femandez-Diaz , M. Prieto b a Departamento de Cristalografiay Mineralogia, Universidad Complutense de Madrid, £-28040 Madrid, Spain b Departamento de Geologia, Uniuersidad de Oviedo (JUQOM), £-33005 Oviedo, Spain Abstract The crystallization of phosgenite (Pb2CI2C03) and cerussite (PbC03) has been carried out by counter diffusion in a silica hydrogel at 25°C. The crystallization of both phases is strongly controlled by the pH of the medium. Under certain conditions the physicochemical evolution of the system determines that phosgenite crystals become unstable and transform into cerussite. The transformation is structurally controlled and provides an interesting example of topotaxy. The orientational relationships are (I JO)ph 11 [001 ter. ( I JO)ph 11 [IOO]cer' and (OOi)Ph 11 (0I0)cer' In this paper. a study of the topotactic transformation and the crystal morphology is worked out. The topotactic relationships are interpreted on the ground of geometrical and structural considerations. 1. Introduction for some polymorphic transformations. Crystal growth experiments in a porous silica gel transport Phosgenite (Pb2CI2C03) and cerussite (PbC03) medium allows us to reproduce the conditions of are two secondary lead minerals that form in super­ phosgenite and cerussite crystallization in nature and genic deposits as an alteration product of galene and monitor the transformation process. The develop­ anglesite. The crystallization of phosgenite and ment of the transformation is strongly controlled by cerussite is strongly controlled by the pH of the the structural elements that both phases have in medium. Phosgenite crystallizes at pH values around common, providing an interesting example of 5, while cerussite nucleation requires a basic pH [I].
    [Show full text]
  • Minerals of Arizona Report
    MINERALS OF ARIZONA by Frederic W. Galbraith and Daniel J. Brennan THE ARIZONA BUREAU OF MINES Price One Dollar Free to Residents of Arizona Bulletin 181 1970 THE UNIVERSITY OF ARIZONA TUCSON TABLE OF CONT'ENTS EIements .___ 1 FOREWORD Sulfides ._______________________ 9 As a service about mineral matters in Arizona, the Arizona Bureau Sulfosalts ._. .___ __ 22 of Mines, University of Arizona, is pleased to reprint the long-standing booklet on MINERALS OF ARIZONA. This basic journal was issued originally in 1941, under the authorship of Dr. Frederic W. Galbraith, as Simple Oxides .. 26 a bulletin of the Arizona Bureau of Mines. It has moved through several editions and, in some later printings, it was authored jointly by Dr. Gal­ Oxides Containing Uranium, Thorium, Zirconium .. .... 34 braith and Dr. Daniel J. Brennan. It now is being released in its Fourth Edition as Bulletin 181, Arizona Bureau of Mines. Hydroxides .. .. 35 The comprehensive coverage of mineral information contained in the bulletin should serve to give notable and continuing benefits to laymen as well as to professional scientists of Arizona. Multiple Oxides 37 J. D. Forrester, Director Arizona Bureau of Mines Multiple Oxides Containing Columbium, February 2, 1970 Tantaum, Titanium .. .. .. 40 Halides .. .. __ ____ _________ __ __ 41 Carbonates, Nitrates, Borates .. .... .. 45 Sulfates, Chromates, Tellurites .. .. .. __ .._.. __ 57 Phosphates, Arsenates, Vanadates, Antimonates .._ 68 First Edition (Bulletin 149) July 1, 1941 Vanadium Oxysalts ...... .......... 76 Second Edition, Revised (Bulletin 153) April, 1947 Third Edition, Revised 1959; Second Printing 1966 Fourth Edition (Bulletin 181) February, 1970 Tungstates, Molybdates.. _. .. .. .. 79 Silicates ...
    [Show full text]
  • Journal of the Russell Society: Contents List
    JOURNAL OF THE RUSSELL SOCIETY CONTENTS LIST: VOLUMES 1–22 (1982–2019) VOLUME 1, PART 1 (1982) Editorial: R.J. King. Articles and Notes • Baryte and other minerals from the Isle of Sheppey, Kent. P.K. Monk. (1982), 1-1, 5–7. • Metal mines of the British Isles No. 1 – Dylife. N.J.M. Moreton. (1982), 1-1, 8. • A new occurrence of scarbroite in Britain. R.J. King. (1982), 1-1, 9–18. • A new find of nickeloan hydrozincite in Parc Mine, North Wales. R.E. Bevins, P. O'Brien, S. Turgoose and P.A. Williams. (1982), 1-1, 19–21. • The content of rare earth elements in English fluorites: A preliminary study. R.A. Howie, E. Pegram and J.N. Walsh. (1982), 1-1, 22–25. • The mineralogy of Fall Hill Quarry, Ashover, Derbyshire. M.E. Smith. (1982), 1-1, 26–32. • An occurrence of nickel minerals in the Hilton Mine, Scordale, Cumbria. T.F. Bridges. (1982), 1-1, 33– 39. • First British occurrence of cumengeite. A.C. Dean. (1982), 1-1, 40–41. • The care of minerals Section 1: The cleaning of minerals. R.J. King. (1982), 1-1, 42–53. VOLUME 1, PART 2 (1983) Editorial: R.J. King. Obituaries • Richard Agabeg (A. Fisher). (1983), 1-2, 4. • Richard (Dick) W. Barstow (J.A. Jones). (1983), 1-2, 4. • Roger S. Harker (J.A. Jones). (1983), 1-2, 5. Articles and Notes • Phosgenite and matlockite in Derbyshire (Part 1). T. Bridges and M.E. Smith. (1983), 1-2, 7–15. • On the occurrence of millerite at Ecton Hill, Staffordshire.
    [Show full text]