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Structure and Physical Properties of Hydrogrossular Mineral Series
STRUCTURE AND PHYSICAL PROPERTIES OF HYDROGROSSULAR MINERAL SERIES A THESIS IN PHYSICS Presented to the Faculty of the University of Missouri-Kansas City in Partial requirements for the degree MASTER OF SCIENCE By PUJA ADHIKARI M.Sc, Tribhuban University, Kathmandu, Nepal, 2010 Kansas City, Missouri 2015 ©2015 PUJA ADHIKARI ALL RIGHTS RESERVED Structure and physical properties of Hydrogrossular mineral series Puja Adhikari, Candidate for the Master of Science Degree University of Missouri-Kansas City, 2015 ABSTRACT The mineral hydrogrossular series (Ca3Al2(SiO4)3-x(OH) 4x; 0 ≤ x ≤ 3) are important water bearing minerals found in the upper and lower part of the Earth’s mantle. They are vital to the planet’s hydrosphere under different hydrothermal conditions. The composition and structure of this mineral series are important in geoscience and share many commonalities with cement and clay materials. Other than the end members of the series x = 0 (grossular) and x = 3 (katoite) which have a cubic garnet structure, the structure of the series is totally unknown. We used large-scale ab initio modeling to investigate the structures and properties for hydrogrossular series for x = 0, 0.5, 1, 1.5, 2, 2.5, 3. Results indicate that for x > 0 and x < 3, the structures are tetragonal. This shows that there is structural change related to the lowering of overall symmetry associated with the composition of SiO4 tetrahedra and AlO6 octahedra. Total Bond order also explains the reason behind the change in the compressibility of the series. The electronic structure, mechanical and optical properties of the hydrogrossular series are calculated and the results for grossular and katoite are in good agreement with the available experimental data. -
Magnetic Susceptibility Index for Gemstones ©2010 Kirk Feral Magnetic Responses Are Standardized to 1/2" X 1/2" N-52 Magnet Cylinders
Magnetic Susceptibility Index for Gemstones ©2010 Kirk Feral Magnetic responses are standardized to 1/2" X 1/2" N-52 magnet cylinders. Colorless and extremely pale stones of any species tend to be Inert (diamagnetic). Black opaque stones of many species are strongly magnetic and may Pick Up or Drag. Pick Up and Drag responses are weight-dependent. Direct responses on the Index apply to gems 1-4cts. Larger gems may be too heavy to Pick Up or Drag. Smaller non-Garnet gems with strong magnetism may Pick Up. Gemstone Response Range SI X 10 (-6) Range Cause of Color Actinolite Nephrite Jade (black) Strong to Drags 321-577 SI Iron Nephrite Jade (green) Moderate to Drags 91-343 Iron, Chromium Nephrite Jade (white, yellow) Inert < 0 (diamagnetic) Iron Pargasite (green) Inert < 0 (diamagnetic) Iron, Vanadium Pargasite (orangey brown) Weak 35 SI Iron Afghanite (blue) Inert < 0 (diamagnetic) Chromium, Vanadium Amber (any color) Inert < 0 (diamagnetic) Charge Transfer involving Organic Compounds Amblygonite-Montebrasite (blue, green) Inert < 0 (diamagnetic) Iron, Manganese Andalusite Inert to Weak < 0 -26 Iron-Oxygen-Titanium Charge Transfer Apatite Transparent blue, green, yellow Inert (Weak in rare cases) < 0 (diamagnetic) Mang., Rare-earth, Charge Transfer, Color Centers Cat's eye translucent yellow, yellowish brown Weak to Strong < 20 - >120 Rare-earth Metals Astrophyllite Strong 1146-1328 Iron, Manganese Axinite Drags 603-616 SI Iron Azurite (opaque) Strong 382 SI Copper Barite (pale brown, blue) Inert < 0 (diamagnetic) Color Centers Bastnasite -
An Exploration of Jade Maria Jones
Eastern Michigan University DigitalCommons@EMU Senior Honors Theses Honors College 2004 An Exploration of Jade Maria Jones Follow this and additional works at: http://commons.emich.edu/honors Recommended Citation Jones, Maria, "An Exploration of Jade" (2004). Senior Honors Theses. 85. http://commons.emich.edu/honors/85 This Open Access Senior Honors Thesis is brought to you for free and open access by the Honors College at DigitalCommons@EMU. It has been accepted for inclusion in Senior Honors Theses by an authorized administrator of DigitalCommons@EMU. For more information, please contact lib- [email protected]. An Exploration of Jade Abstract Abstract: This is a research paper studying the history of Jade carving during the Chinese Han Dynasty from 206 B.C to 220 A.D. The ap per explains the meaning of jade to the Chinese people and examines the origin of the precious stone for the Han people and other generations of dynasties. There is an accurate telling of Han beliefs followed by a descriptive passage on the history of religious influence on the Han people. There is an extensive study on the history of the Han people in general and a lengthy report on the different forms of jade and their functions for the Han people. Degree Type Open Access Senior Honors Thesis Department Art First Advisor Dr. Richard Rubenfeld Second Advisor Leslie Atzmon Keywords Jade art objects, Art objects, Chinese, Jade This open access senior honors thesis is available at DigitalCommons@EMU: http://commons.emich.edu/honors/85 AN EXPLORATION OFJ/\DL: by :'vlariaJones A St~nior ThcsIs Submitted to the !:astern tv1ichigan Umversny 1ionors Program In Partial Fulfillment of the Requiremems for Graduation With Honors in Fine Art: CcHJCcntratinnin Graphic Design 1 I I ! ~--'~""'-"""'- ,,=.. -
Mineralogy and Geochemistry of Nephrite Jade from Yinggelike Deposit, Altyn Tagh (Xinjiang, NW China)
minerals Article Mineralogy and Geochemistry of Nephrite Jade from Yinggelike Deposit, Altyn Tagh (Xinjiang, NW China) Ying Jiang 1, Guanghai Shi 1,* , Liguo Xu 2 and Xinling Li 3 1 State Key Laboratory of Geological Processes and Mineral Resources, China University of Geosciences, Beijing 100083, China; [email protected] 2 Geological Museum of China, Beijing 100034, China; [email protected] 3 Xinjiang Uygur Autonomous Region Product Quality Supervision and Inspection Institute, Xinjiang 830004, China; [email protected] * Correspondence: [email protected]; Tel.: +86-010-8232-1836 Received: 6 April 2020; Accepted: 6 May 2020; Published: 8 May 2020 Abstract: The historic Yinggelike nephrite jade deposit in the Altyn Tagh Mountains (Xinjiang, NW China) is renowned for its gem-quality nephrite with its characteristic light-yellow to greenish-yellow hue. Despite the extraordinary gemological quality and commercial significance of the Yinggelike nephrite, little work has been done on this nephrite deposit, due to its geographic remoteness and inaccessibility. This contribution presents the first systematic mineralogical and geochemical studies on the Yinggelike nephrite deposit. Electron probe microanalysis, X-ray fluorescence (XRF) spectrometry, inductively coupled plasma mass spectrometry (ICP-MS) and isotope ratio mass spectrometry were used to measure the mineralogy, bulk-rock chemistry and stable (O and H) isotopes characteristics of samples from Yinggelike. Field investigation shows that the Yinggelike nephrite orebody occurs in the dolomitic marble near the intruding granitoids. Petrographic studies and EMPA data indicate that the nephrite is mainly composed of fine-grained tremolite, with accessory pargasite, diopside, epidote, allanite, prehnite, andesine, titanite, zircon, and calcite. Geochemical studies show that all nephrite samples have low bulk-rock Fe/(Fe + Mg) values (0.02–0.05), as well as low Cr (0.81–34.68 ppm), Co (1.10–2.91 ppm), and Ni (0.52–20.15 ppm) contents. -
The Wittelsbach-Graff and Hope Diamonds: Not Cut from the Same Rough
THE WITTELSBACH-GRAFF AND HOPE DIAMONDS: NOT CUT FROM THE SAME ROUGH Eloïse Gaillou, Wuyi Wang, Jeffrey E. Post, John M. King, James E. Butler, Alan T. Collins, and Thomas M. Moses Two historic blue diamonds, the Hope and the Wittelsbach-Graff, appeared together for the first time at the Smithsonian Institution in 2010. Both diamonds were apparently purchased in India in the 17th century and later belonged to European royalty. In addition to the parallels in their histo- ries, their comparable color and bright, long-lasting orange-red phosphorescence have led to speculation that these two diamonds might have come from the same piece of rough. Although the diamonds are similar spectroscopically, their dislocation patterns observed with the DiamondView differ in scale and texture, and they do not show the same internal strain features. The results indicate that the two diamonds did not originate from the same crystal, though they likely experienced similar geologic histories. he earliest records of the famous Hope and Adornment (Toison d’Or de la Parure de Couleur) in Wittelsbach-Graff diamonds (figure 1) show 1749, but was stolen in 1792 during the French T them in the possession of prominent Revolution. Twenty years later, a 45.52 ct blue dia- European royal families in the mid-17th century. mond appeared for sale in London and eventually They were undoubtedly mined in India, the world’s became part of the collection of Henry Philip Hope. only commercial source of diamonds at that time. Recent computer modeling studies have established The original ancestor of the Hope diamond was that the Hope diamond was cut from the French an approximately 115 ct stone (the Tavernier Blue) Blue, presumably to disguise its identity after the that Jean-Baptiste Tavernier sold to Louis XIV of theft (Attaway, 2005; Farges et al., 2009; Sucher et France in 1668. -
Geology Club Mineral: Collecting Trip
Geology Club: Mineral Collecting Trip (10 October 2009) Trip Notes by Charles Merguerian STOP 1 – Grossular Garnet Locality, West Redding, Connecticut. [UTM Coordinates: 630.71E / 4575.38N, Bethel quadrangle]. Covering roughly 60 acres of land, this enigmatic massive fine-grained grossularite garnet + diopside rock in West Redding has made many mineral collectors and geologists take notice. Walk up the steep slope east of Simpaug Turnpike to see highly fractured, massive cinnamon-colored grossular garnet rock, part of a 0.6-km wide heart-shaped mass found at the faulted contact between the Stockbridge Marble (OCs) and injected muscovitic schist of the Rowe Schist member (OCr) of the Hartland Formation (Figure 1). According to Rodgers et al. (1985), we are very near Cameron’s Line (red and black line in Figure 1). Figure 1 – Geologic map of the area surrounding Stop 1 showing the Proterozoic gneissic rocks (Yg) and Cambrian Dalton Schist (Cd) to the west, the Stockbridge Marble (OCs), Cameron’s Line (CL in red), the injected schistose rocks of the Rowe Formation (OCr), and an Ordovician granitoid (Og) that may be responsible for this unusual Ca++-enriched skarn deposit. Note the NW-trending high-angle brittle faults that cut the region. (Adapted from Rodgers et al. 1985.) Two knolls at this locality are almost entirely composed of grossularite garnet (var. essonite) and lesser clinopyroxene. Mostly the garnet occurs alone with minor quartz and localized quartz veining has been observed. Chemical analysis of the garnet (SiO2 = 39.10%, CaO = 34.85%, Al2O3 = 19.61%, and total FeO+Fe2O3 = 5.44%), are quite similar to published analyses of grossular garnet, including the phenomenal grossular garnet crystals from Morelos, Mexico. -
Fluorian Garnets from the Host Rocks of the Skaergaard Intrusion: Implications for Metamorphic Fluid Composition
American Mineralogist, Volume 75, pages 859-873,1990 Fluorian garnets from the host rocks of the Skaergaard intrusion: Implications for metamorphic fluid composition CRAIG E. MANNING, * DENNIS K. BIRD Department of Geology, Stanford University, Stanford, California 94305, U.S.A. ABSTRACT Zoned, silica-deficient, calcic garnets containing up to 5 mol% F substitution for 0 formed during contact metamorphism of basalts by the Skaergaard intrusion in East Greenland. Fluorian calcic garnets occur as a retrograde alteration of prograde wollastonite and clinopyroxene that fills vesicles and vugs in lavas 30-70 m from the intrusion. Para- genetically equivalent phases include fluorite, wollastonite, calcic clinopyroxene, prehnite, quartz, and calcite. Electron microprobe analysis shows that the garnets are :::-:93mol% grossular-andradite (grandite) solid solutions and that the F content does not fully com- pensate for the silica deficiency, suggesting the presence of a hydrous component in the garnets. The garnets display discontinuous zoning with respect to Al and Fe, and increases in F, calculated OH, and the Si deficiency with increasing Al concentration are observed. The garnets formed at temperatures between 200 and 420°C based on the coexisting mineral assemblage, and stratigraphic reconstructions indicate pressures of ~ 1 kbar. Assessment of isobaric, isothermal phase relations in the system CaO-A1203-Si02-H20- HF allows estimation of fluid characteristics in equilibrium with fluorian grandite-bearing assemblages. The presence of fluorite, wollastonite, quartz, and calcite with these garnets combined with fluid inclusion data require that the activity (a) of H20 was ~ 1 and that aH.aF was 10-105 to 10-10.0in the coexisting hydrothermal solutions at 200-420 °C and 1 kbar. -
The Effect of Reduced Activity of Anorthite on the Reaction Grossular
AmericanMineralogist, Volume61, pages 889-896,1976 The effectof reducedactivity of anorthiteon thereaction grossular * quartz : anorthite* wollastonite:a modelfor plagioclasein the earth'slower crust anh upper mantle K. E. WrNnoMr AND A. L. BoerrcHrnl Department of Geosciences,The Pennsyluania State (lniuersity Uniuersity Park, Pennsyluania 16802 Abstract The reaction CasAlrSiaor, + SiO, : CaAlzSiros + 2 CaSiOg (erossular) (quartz) (anortbite) (wollastoDite) wasinvestigated at l10ooC,using intermediate-composition plagioclase to determinethe shift of the equilibriumpressure as a functionof compositionat pressureand temperaturecondi- tions representativeof the earth'slower crustand uppermantle. For compositionswithin the rangeAnro-,00, activity of the anorthitecomponent is equalto its molefraction. For composi- tions more albitic than about Anro,the activity of the anorthitecomponent equals its mole fractionmultiplied by a constantfactor of 1.2.This latter behavioris interpretedas a resultof anorthite-likedomains being in an energeticallyunfavorable environment for thesecomposi- tions. Applicationof the data obtainedfrom subsolidusexperiments to meltingbehavior indicates that plagioclaseliquids do not obey Raoult'sLaw, but havean activitycoefficient similar to crystallineplagioclase. This hypothesisis supportedby high-pressuremelting experiments for both anhydrousand hydroussystems. In parts of the lower crustcomposed of basicrock (e.g.gabbro), the calcicplagioclase will be consumedat relativelyshallow levels and over a narrow (2-3 km) -
Pearl Accessories Operator's Manual
Pearl® Trilogy Accessories Manual CE Marking: This product (model number 5700-DS) is a CE-marked product. For conformity information, contact LI-COR Support at http://www.licor.com/biotechsupport. Outside of the U.S., contact your local sales office or distributor. Notes on Safety LI-COR products have been designed to be safe when operated in the manner described in this manual. The safety of this product cannot be guaranteed if the product is used in any other way than is specified in this manual. The Pearl® Docking Station and Pearl Clean Box is intended to be used by qualified personnel. Read this entire manual before using the Pearl Docking Station and Pearl Clean Box. Equipment Markings: The product is marked with this symbol when it is necessary for you to refer to the manual or accompanying documents in order to protect against damage to the product. The product is marked with this symbol when a hazardous voltage may be present. Manual Markings: WARNING Warnings must be followed carefully to avoid bodily injury. CAUTION Cautions must be observed to avoid damaging your equipment. NOTE Notes contain additional information and useful tips. IMPORTANT Information of importance to prevent procedural mistakes in the operation of the equipment or related software. Failure to comply may result in a poor experimental outcome but will not cause bodily injury or equipment damage. Federal Communications Commission Radio Frequency Interference Statement WARNING: This equipment generates, uses, and can radiate radio frequency energy and if not installed in accordance with the instruction manual, may cause interference to radio communications. -
Thomas, R., Rericha, A., Pohl, WL, Davidson, P
Originally published as: Thomas, R., Rericha, A., Pohl, W. L., Davidson, P. (2018): Genetic significance of the 867 cm−1 out-of- plane Raman mode in graphite associated with V-bearing green grossular. - Mineralogy and Petrology, 112, 5, pp. 633—645. DOI: http://doi.org/10.1007/s00710-018-0563-1 1 Genetic significance of the 867 cm-1 out-of-plane Raman mode in graphite associated with V-bearing green grossular Rainer Thomasa Adolf Rerichab Walter L. Pohlc Paul Davidsond Paul Davidson [email protected] 0000-0002-6129-0748 a Helmholtz-Centre Potsdam, German Research Centre for Geoscience – GFZ, Section 4.3. Chemistry and Physics of Earth Materials, Telegrafenberg, D-14473 Potsdam, Germany b Alemannenstr. 4a, D-14612 Falkensee, Germany c Austrian Academy of Sciences, Dr. Ignaz Seipel-Platz 2, 1010 Vienna, Austria d ARC Centre of Excellence in Ore Deposits, University of Tasmania, Hobart 7001, Australia Keywords: Tsavorite Green V-grossular Graphite Raman scattering Fluid and melt inclusions Sulfur 2 Abstract SE Kenya is the world’s largest producer of green vanadium grossular gemstones (tsavorite). Samples from one of the mines near Mwatate, and of occurrences in Tanzania yielded remarkable new insights into the genesis of tsavorite. Graphite is intimately associated with V-grossular and is one of the keys to understanding its origin. In the course of this study we found five different types of graphite. Surprisingly, in one graphite type the “Raman- forbidden” and IR-active 867 cm-1 band was observed. In this communication, we attempt to find an explanation for this unusual phenomenon. -
Gem Wealth of Tanzania GEMS & GEMOLOGY Summer 1992 Fipe 1
By Dona M.Dirlarn, Elise B. Misiorowski, Rosemaiy Tozer, Karen B. Stark, and Allen M.Bassett The East African nation of Tanzania has he United Republic of Tanzania, the largest of the East great gem wealth. First known by Western- 1African countries, is composed of mainland Tanzania and ers for its diamonds, Tanzania emerged in the island of Zanzibar. 1t is regarded by many as the birthplace the 1960s as a producer of a great variety of of the earliest ancestors of Homo sapiens. To the gem indus- other gems such as tanzanite, ruby, fancy- try, however, Tanzania is one of the most promising fron- colored sapphire, garnet, and tourmaline; to date, more than 50 gem species and vari- tiers, with 50 gem species and varieties identified, to date, eties have been produced. As the 1990s from more than 200 occurrences. begin, De Beers has reinstated diamond "Modem" mining started in the gold fields of Tanzania in exploration in Tanzania, new gem materials the late 1890s (Ngunangwa, 19821, but modem diamond min- such as transparent green zoisite have ing did not start until 1925, and nearly all mining of colored appeared on the market, and there is stones has taken place since 1950. Even so, only a few of the increasing interest in Tanzania's lesser- gem materials identified have been exploited to any significant known gems such as scapolite, spinel, and extent: diamond, ruby, sapphire, purplish blue zoisite (tan- zircon. This overview describes the main zanite; figure l),and green grossular [tsavorite)and other gar- gems and gem resources of Tanzania, and nets. -
TUCSON 2018 Spinel—In Pink and Lavender Hues—In Suites and Sets As Customers Found the Scarcity and High Prices of Red Spinel Prohibitive
Contributing Editors Emmanuel Fritsch, University of Nantes, CNRS, Team 6502, Institut des Matériaux Jean Rouxel (IMN), Nantes, France (fritsch@cnrs- imn.fr) Gagan Choudhary, Gem Testing Laboratory, Jaipur, India ([email protected]) Christopher M. Breeding, GIA, Carlsbad ([email protected]) manite. Many dealers posted strong sales of pastel-colored spinel—in pink and lavender hues—in suites and sets as TUCSON 2018 customers found the scarcity and high prices of red spinel prohibitive. In a similar vein, Margit Thorndal of Madagas- Every February the gem and mineral world descends on car Imports reported strong demand for purple-lavender Tucson, transforming the downtown convention center spinel and purple sapphire from Madagascar, as well as teal and a great many of the city’s hotels into a fascinating col- hues of unheated Montana sapphire. lage of traders bearing goods from all over the planet (fig- We noted that electric blues, teals, hot pinks, hot yel- ures 1 and 2). low greens, and pastel-colored gems were quite popular. Many of the exhibitors we spoke with described 2018 Bill Larson of Pala International pointed to this trend and as the strongest year since 2008. Although traffic wasn’t showed us a number of spectacular examples from his in- especially heavy at the AGTA and GJX shows, most deal- ventory. Fine blue zircon from Cambodia was prominent, ers there enjoyed brisk sales and healthy demand for high- as was attractive sphene from Zimbabwe and Madagascar. quality goods. Some of the same trends from last year were Dave Bindra of B&B Fine Gems said his company was evident.