SIMONETTI ET AL. CHAPTER 14: NONPROLIFERATION AND NUCLEAR FORENSICS: DETAILED, MULTI- ANALYTICAL INVESTIGATION OF TRINITITE POST-DETONATION MATERIALS Antonio Simonetti, Jeremy J. Bellucci, Christine Wallace, Elizabeth Koeman, and Peter C. Burns, Department of Civil and Environmental Engineering and Earth Sciences, University of Notre Dame, Notre Dame, Indiana, 46544, USA e-mail:
[email protected] INTRODUCTION (and ≤7% 240Pu), whereas it is termed “reactor fuel In 2010, the Joint Working Group of the grade” if the material consists >8% 240Pu. American Physical Society and the American Production of enriched U is costly and an energy- Association for the Advancement of Science defined intensive process, and the most widely used Nuclear Forensics as “the technical means by which processes are gaseous diffusion of UF6 (employed nuclear materials, whether intercepted intact or by the United States and France) and high- retrieved from post-explosion debris, are performance centrifugation of UF6 (e.g., Russia, characterized (as to composition, physical condition, Europe, and South Africa). The uranium processed age, provenance, history) and interpreted (as to under the “Manhattan Project” and used within the provenance, industrial history, and implications for device detonated over Hiroshima was produced by nuclear device design).” Detailed investigation of electromagnetic separation; the latter process was post-detonation material (PDM) is critical in ultimately abandoned in the late 1940s because of preventing and/or responding to nuclear-based its significant energy demands. The minimum terrorist activities/threats. However, accurate amount of fissionable material required for a nuclear identification of nuclear device components within reaction is termed its “critical mass”, and the value PDM typically requires a variety of instrumental depends on the isotope employed, properties of approaches and sample characterization strategies; materials, local environment, and weapon design the latter may include radiochemical separations, (Moody et al.