(12) United States Patent (10) Patent No.: US 8,893,711 B2 Kennedy (45) Date of Patent: Nov
US008893711B2 (12) United States Patent (10) Patent No.: US 8,893,711 B2 Kennedy (45) Date of Patent: Nov. 25, 2014 (54) HIGH TEMPERATURE SOLAR SELECTIVE 4,252,865 A * 2/1981 Gilbert et al. ................. 428,611 COATINGS (Continued) (75) Inventor: Cheryl E. Kennedy, Lafayette, CO (US) FOREIGN PATENT DOCUMENTS (73) Assignee: Alliance for Sustainable Energy, LLC, CN 2004O10097.125 12, 2004 Golden, CO (US) JP 2004266O23 9, 2004 (*) Notice: Subject to any disclaimer, the term of this WO 2005 121389 12/2005 patent is extended or adjusted under 35 OTHER PUBLICATIONS U.S.C. 154(b) by 1223 days. G.L. Harding, Sputtered metal carbide Solar-selective absorbing Sur (21) Appl. No.: 12/745,319 faces, J. Vac. Sci. Technol., 13, No. 5, 1070 (1976). (22) PCT Filed: Oct. 18, 2007 (Continued) (86). PCT No.: PCT/US2007/081838 Primary Examiner — Avinash Savani S371 (c)(1), (74) Attorney, Agent, or Firm — John C. Stolpa; Michael A. (2), (4) Date: Sep. 1, 2010 McIntyre (87) PCT Pub. No.: WO2009/051595 PCT Pub. Date: Apr. 23, 2009 (57) ABSTRACT Improved Solar collectors (40) comprising glass tubing (42) (65) Prior Publication Data attached to bellows (44) by airtight seals (56) enclose solar US 2010/0313875 A1 Dec. 16, 2010 absorber tubes (50) inside an annular evacuated space (54. The exterior surfaces of the solar absorber tubes (50) are (51) Int. Cl. coated with improved solar selective coatings {48} which F24, 2/50 (2006.01) provide higher absorbance, lower emittance and resistance to F24, 2/48 (2006.01) atmospheric oxidation at elevated temperatures. The coatings F24, 2/05 (2006.01) are multilayered structures comprising Solar absorbent layers F24, 2/46 (2006.01) (26) applied to the meta surface of the absorber tubes (50), GO2B5/28 (2006.01) typically stainless steel, topped with antireflective Savers (28) (52) U.S.
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