Temperature Cycling and Fatigue in Electronics
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Sn95/Sb5 – Organic Acid 3% Core
Technical Data Sheet Sn95/Sb5 – Organic Acid 3% Core NOMINAL COMPOSITION Tin 94% Min Lead 0.1% Max Arsenic 0.01% Max Antimony 4.5% 5.5 Cadmium 0.005% Max Iron 0.04% Max Copper 0.08% Max Aluminum 0.005% Max Zinc 0.005% Max Silver 0.015% Max Bismuth 0.15% Max Flux – 3% Organic Acid Core by weight PHYSICAL PROPERTIES Solder Alloy Color White Melting Point (Solidus) 450°F (233°C) Flow Point (Liquidus) 464°F (240°C) Specific Gravity 7.26 Density (Lbs/in3) 0.263 Bulk Room Temperature Tensile Strength (PSI) 5,900 Flux Type Water Soluble Organic Acid Physical State Solid Melting Point 250°F (120°C) Chloride Content 4% SOLDERING CHARACTERISTICS Sn95/Sb5 is a general-purpose solder used in applications involving soldering of copper and copper alloys and/or ferrous base alloys where use of lead containing solder is not permitted. This soft solder may be used in applications involving higher service temperatures. Typical applications for this alloy include copper components in air conditioning industry. This alloy is also recommended in applications involving food handling or drinking water components where use of lead containing alloys is not permitted. Antimony bearing alloys are not recommended in soldering of brass parts due to formation of a brittle Sb-Zn inter-metallic. This flux-cored solder can be used on difficult to solder materials where rosin based fluxes and electronic grade organic fluxes are not strong enough. It has been used effectively in many non-electronic applications such as lamps, fuses, and jewelry. The flux is active on copper, brass, bronze, steel, nickel, and stainless steel. -
Low Melting Temperature Sn-Bi Solder
metals Review Low Melting Temperature Sn-Bi Solder: Effect of Alloying and Nanoparticle Addition on the Microstructural, Thermal, Interfacial Bonding, and Mechanical Characteristics Hyejun Kang, Sri Harini Rajendran and Jae Pil Jung * Department of Materials Science and Engineering, University of Seoul, 163, Seoulsiripdae-ro, Dongdaemun-gu, Seoul 02504, Korea; [email protected] (H.K.); [email protected] (S.H.R.) * Correspondence: [email protected] Abstract: Sn-based lead-free solders such as Sn-Ag-Cu, Sn-Cu, and Sn-Bi have been used extensively for a long time in the electronic packaging field. Recently, low-temperature Sn-Bi solder alloys attract much attention from industries for flexible printed circuit board (FPCB) applications. Low melting temperatures of Sn-Bi solders avoid warpage wherein printed circuit board and electronic parts deform or deviate from the initial state due to their thermal mismatch during soldering. However, the addition of alloying elements and nanoparticles Sn-Bi solders improves the melting temperature, wettability, microstructure, and mechanical properties. Improving the brittleness of the eutectic Sn-58wt%Bi solder alloy by grain refinement of the Bi-phase becomes a hot topic. In this paper, literature studies about melting temperature, microstructure, inter-metallic thickness, and mechanical properties of Sn-Bi solder alloys upon alloying and nanoparticle addition are reviewed. Keywords: low-temperature solder; Sn-58wt%Bi; melting temperature; microstructure; mechani- Citation: Kang, H.; Rajendran, S.H.; cal property Jung, J.P. Low Melting Temperature Sn-Bi Solder: Effect of Alloying and Nanoparticle Addition on the Microstructural, Thermal, Interfacial Bonding, and Mechanical 1. Introduction Characteristics. Metals 2021, 11, 364. -
Major Causes of Solder Cracks Applications and Boards That Specially Require Solder Crack Countermeasures Comparison of 2 Soluti
Solder Crack Countermeasures in MLCCs Outline This page introduces major causes and countermeasures of solder crack in MLCCs (Multilayer Fig. 1: Appearance of a solder crack Ceramic Chip Capacitors). (cross-section) Major causes of solder cracks Solder cracks on MLCCs developed from severe usage conditions after going on the market and during manufacturing processes such as soldering. Applications and boards that specially require solder crack countermeasures Solder cracks occur mainly because of thermal fatigue due to thermal shock or temperature cycles or the use of lead-free solder, which is hard and fragile. TDK offers following MLCC products as solder crack countermeasures. 1) Metal terminals “disperse” thermal shock : 2) Equipped with resin layers that absorb stress applied on solder MEGACAP joints and resistant to dropping: Soft termination Comparison of 2 solutions: Summary of “Solder Crack Countermeasures in MLCCs” Major causes of solder cracks Solder cracks on MLCCs developed from severe usage conditions Fig. 2: Major causes of solder cracks and their impact after going on the market and during manufacturing processes such as soldering. The following causes can be listed as the major cause of solder cracks. (1) Thermal shock (heat shock), heat fatigue caused by temperature cycle Solder cracks occur when heat stress is applied to a solder joint due to the difference in the thermal coefficients of the MLCC and PCB, in an environment in which changes between high temperatures and low temperatures are repeated. In addition, it can also occur when temperature control is insufficient during the process of soldering. (2) Lead-free solder Lead-free solder, which started to be used due to environmental considerations, has properties of being rigid and fragile, and has a higher risk of solder cracks compared to conventional eutectic solder; therefore, caution is required when using it. -
Isothermal Fatigue Properties of Sn--Ag--Cu Alloy Evaluated By
Materials Transactions, Vol. 46, No. 11 (2005) pp. 2309 to 2315 Special Issue on Lead-Free Soldering in Electronics III #2005 The Japan Institute of Metals Isothermal Fatigue Properties of Sn–Ag–Cu Alloy Evaluated by Micro Size Specimen Yoshiharu Kariya1, Tomokazu Niimi2;*, Tadatomo Suga3 and Masahisa Otsuka4 1Ecomaterials Center, National Institute for Materials Science, Tsukuba 305-0044, Japan 2Graduate School of Shibaura Institute of Technology, Tokyo 108-8548, Japan 3Department of Precision Engineering, School of Engineering, The University of Tokyo, Tokyo 113-8656, Japan 4Materials Science and Engineering Department, Shibaura Institute of Technology, Tokyo 108-8548, Japan Micro-bulk fatigue testing developed to investigate the fatigue lives and damage mechanisms of Sn–3.0Ag–0.5Cu and Sn–37Pb solder alloys. The fatigue life of micro-bulk solder obeyed Manson–Coffin’s empirical law, and the fatigue ductility exponents were about 0.5 for both Sn–Ag–Cu and Sn–Pb alloys. The fatigue life of Sn–3.0Ag–0.5Cu alloy was 10 times longer than that of Sn–37Pb alloy under symmetrical cycling at 298 K, although fatigue resistance of Sn–3.0Ag–0.5Cu alloy was not very superior under asymmetrical wave and elevated temperature condition. The fatigue crack was developed from extrusion and intrusion of slip band in Sn–3.0Ag–0.5Cu alloy, while the crack was observed at colony boundary and grain boundary in Sn–37Pb alloy. The difference in damage mechanism may affect the susceptibility to fatigue life test condition of reversibility. (Received May 23, 2005; Accepted October 11, 2005; Published November 15, 2005) Keywords: solder, lead-free solder, fatigue life, miniature testing, tin–silver–copper, tin-lead, damage mechanism, crack initiation, micro-bulk 1. -
Soldering to Gold Films
Soldering to Gold Films THE IMPORTANCE OF LEAD-INDIUM ALLOYS Frederick G. Yost Sandia Laboratories, Albuquerque, New Mexico, U.S.A. Reliable solder joints can be made on gold metallised microcircuits using lead-indium solders providing certain important conditions are understood and carefully controlled. This paper reviews the three fundamental concepts of scavenging, wetting, and ageing, which are relevant when soldering to gold films. Alloys containing indium have been used for solder- sition and a body centred tetragonal space lattice. ing electronic components to thin gold films and wires Although considerable work has been addressed for at least 14 years. Braun (1, 2) investigated the to the question of clustering and phase separation potential of several multicomponent alloys based in the a field below 20°C (7, 8, 9) the practical signifi- upon the lead-tin-indium ternary alloy system. cance of this phenomenon has not yet materialised. More recently, work on lead-indium binary alloys The most commonly used alloy is the 50 weight has been reported by Jackson (3) and Yost, et al per cent indium composition which has a liquidus (4, 5, 6). In this paper we intend to define, to discuss, temperature of approximately 210°C and a solidus and to illustrate three fundamental concepts relevant temperature of approximately 185°C. Alloys in the to soldering to gold films using lead-indium solders. lead rich phase field, a, freeze dendritically by The lead-indium phase diagram, shown in Figure forming lead rich stalks. The formation of these 1, contains a wealth of useful solder alloys having dendrites causes a surface rumpling which gives the solidus temperatures which range from 156.6°C solder surface a somewhat frosty rather than a shiny (pure indium) to 327.5 °C (pure lead). -
Gold Embrittlement of Solder Joints 2018.Pages
Gold Embrittlement of Solder Joints Ed Hare, PhD - SEM Lab, Inc 425.335.4400 [email protected] Introduction Gold embrittlement of solder joints has been written about for at least four decades [1 – 3]. Nevertheless, gold embrittlement related solder joint failures have been analyzed in this laboratory as recently as July 2009. Gold embrittlement can be avoided by careful solder joint design and knowledge of the causes of this condition. The purpose of this paper is to provide a detailed account of material and process parameters that can lead to gold embrittlement in electronic assemblies. There are a variety of reasons that designers might want to solder to gold or gold plating. One reason is that some designs involve wire bonding and soldering operations on the same assembly. Another reason would be to include gold contact pads (e.g. for dome keypad contacts) or card edge contacts (e.g. PC cards). The wire bond pads or contact pads can be selectively gold plated, but the selective plating process can be expensive. The electronics industry currently recognizes a threshold level for gold that can be dissolved into eutectic tin-lead solder above which the solder is likely to become embrittled. This threshold is ~ 3 wt% gold. It will be shown in the paragraphs below that embrittlement of solder joints can develop at significantly lower bulk gold concentrations. Metallurgical Description of Gold Embrittlement The most important soldering alloy in the electronics industry is the eutectic tin-lead alloy, 63%Sn – 37%Pb. This may change in the near future as lead-free soldering takes its hold on the industry. -
Here's a Summary of How to Make the Perfect Solder Joint
Here's a summary of how to make the perfect solder joint. 1. All parts must be clean and free from dirt and grease. 2. Try to secure the work firmly. 3. "Tin" the iron tip with a small amount of solder. Do this immediately, with new tips being used for the first time. 4. Clean the tip of the hot soldering iron on a damp sponge. 5. Many people then add a tiny amount of fresh solder to the cleansed tip. 6. Heat all parts of the joint with the iron for under a second or so. 7. Continue heating, then apply sufficient solder only, to form an adequate joint. 8. Remove and return the iron safely to its stand. 9. It only takes two or three seconds at most, to solder the average p.c.b. joint. 10. Do not move parts until the solder has cooled. Troubleshooting Guide 11. Solder won't "take" - grease or dirt present - desolder and clean up the parts. Or, material may not be suitable for soldering with lead/tin solder (eg aluminium). 12. Joint is crystalline or grainy-looking - has been moved before being allowed to cool, or joint was not heated adequately - too small an iron/ too large a joint. 13. Solder joint forms a "spike" - probably overheated, burning away the flux. First Aid If you are unlucky enough to receive burns which require treatment, here's what to do :- 14. Immediately cool the affected area with cold running water for several minutes. 15. Remove any rings etc. before swelling starts. -
Board Level Reliability Assessment of Thick Fr-4 Qfn
BOARD LEVEL RELIABILITY ASSESSMENT OF THICK FR-4 QFN ASSEMBLIES UNDER THERMAL CYCLING by TEJAS SHETTY Presented to the Faculty of the Graduate School of The University of Texas at Arlington in Partial Fulfillment of the Requirements for the Degree of MASTER OF SCIENCE IN MECHANICAL ENGINEERING THE UNIVERSITY OF TEXAS AT ARLINGTON DECEMBER 2014 Copyright © by Tejas Shetty 2014 All Rights Reserved ii DEDICATION This thesis is dedicated to my family. I also dedicate this thesis to my teachers from whom I have learnt so much. iii ACKNOWLEDGEMENTS I would like use this opportunity to express my gratitude to Dr. Dereje Agonafer for giving me a chance to work at EMNSPC and for his continuous guidance during that time. It has been a wonderful journey working with him in research projects and an experience to learn so much from the several conference visits. I also thank him for serving as the committee chairman. I would like to thank Dr. A. Haji-Sheikh and Dr. Kent Lawrence for serving on my committee and providing numerous learning opportunities. I would like to extend a special appreciation to Fahad Mirza, who was not only the PhD mentor but also a good friend who helped me throughout my thesis and academics. I want to thank all the people I met at EMNSPC and for their support during my time. Special thanks to Sally Thompson, Debi Barton, Catherine Gruebbel and Louella Carpenter for assisting me in almost everything. You all have been wonderful. I would like to thank Alok Lohia and Marie Denison for their expert inputs while working on the SRC funded project, the result of which is part of this thesis. -
Safe Flo® Silver Lead Free Plumbing Solder
SAFE FLO ® SILVER LEAD FREE PLUMBING SOLDER TECHNICAL SPECIFICATION: Oatey Safe Flo Silver Lead Free Plumbing Solder is recommended for use on potable water systems for sweating joints in a copper water distribution system. Safe Flo Silver Lead Free Solder is also effective on stainless steel, brass alloys, chrome alloys, galvanized steel and cast iron piping. Safe-Flo Solder complies with CA & VT lead content regulations. PRECAUTIONS Read all cautions and directions carefully before using this product. Apply flux with brush- do not apply with fingers. Wash hands thoroughly after use and before eating. Wear safety glasses with side shields and rubber gloves. EYE AND SKIN IRRITANT. HARMFUL IF SWALLOWED. VAPOR MAY BE HARMFUL. Use only in well ventilated area. Eye or skin contact may cause intense irritation and injury. In case of contact with eyes or skin, flush with water and seek medical attention immediately. If inhaled, get fresh air and seek medical attention if ill feelings persist. KEEP OUT OF REACH OF CHILDREN. Refer to material safety data sheet for more information. For emergency first aid help, call 1-877-740-5015. PHYSICAL/CHEMICAL PROPERTIES COMMON APPLICATIONS Alloy composition Tin, Copper, Bismuth, Silver Oatey Safe Flo Silver Lead Free Plumbing Solder is recommended Appearance Silver Solid Wire for use on potable water systems for sweating joints in a copper Melting Range 420° F to 460° F water distribution system. DIRECTIONS FOR USE Cut the pipe to the exact length required using a tube Consult Oatey Technical Department for applications not cutter. Be sure the pipe is cut square. -
Challenges in Supply of Ultralow Alpha Emitting Solder Materials
Indium Corporation Tech Paper Challenges in Supply of Ultralow Alpha Emitting Solder Materials Authored by: Andy C. Mackie, PhD, MSC and Olivier Lauzeral, iRoc Technologies. The names of high-energy subatomic present in the active device layers of a particles such as alpha, beta, gamma, semiconductor chip. DR. ANDY C. MACKIE x-rays and cosmic rays will be well An alpha particle is an ionized heavy known to every high-school student. particle emitted spontaneously from the Table 1 shows some of the most nucleus of a specific isotope of a high common types of particles and a atomic weight (usually >200 Daltons) description of them. atom. Of particular interest and Particle Name Description concern to semiconductor fabricators Alpha Helium (He4) are the elements uranium (U) and nucleus (2 protons thorium (Th), both of which decay to + 2 neutrons) give stable isotopes of lead (Pb), but Beta Electron or positron which, by decaying, give rise to alpha Gamma, X-rays Electromagnetic particles. The potential energy of the Andy C. Mackie, PhD, MSc, Senior (photon) particle depends on the nucleus from Product Manager, Semiconductor and Advanced Assembly Materials for Thermal Neutron Uncharged nuclear which it is emitted. Figure 2 shows Indium Corporation, has over 20 years particle the decay series (only alpha emissions experience in wafer fabrication and semiconductor packaging materials Cosmic rays Mixture of mostly shown) for the isotope Thorium 232. and manufacturing. beta, with alpha, As can be readily seen, the highest Dr. Mackie is an industry expert in gamma and other energies correlate with greater nuclear physical chemistry, rheology and types materials science. -
Solders and Soldering : 1
WFR:WHS:MPC UNITED STATES Letter VIII-3 NATIONAL Circular LC-761 (Supersedes LC-701, LC-493 and LC-343) Many requests Bureau of Standards for information on solders and sold circular has been prepared to give essen- tial information a condensed form in answer to such inquiries. The term "soldering" is generally understood to mean the joining of ^t^o met&l surfaces by means of another metal or alloy which . to hold is applied in the molt&n)/condition The metal which serves as the bond the others together is the solder. Pure metals may be used as solders, but practically all solders in common use are alloys. To form a satisfactory soldered joint it is necessary to heat the metals where they are to be joined at least to a temperature at which the solder is entirely molten. One of the distinctions between a soldered joint and a welded joint is that in the former the metals to be joined are not heated to a temper- ature high enough to melt them. Consequently, one of the requisites for a solder is that its melting point must be lower than that of the metals being joined. It is generally believed that satisfactory adhesion of the solder can be at- tained most easily if the solder, or one of its constituents, forms an alloy with the metals which it is to join. While it has been shown that satisfactory adhesion can be obtained without actual alloying of solder and basis metal, an extremely clean initial surface and its maintenance throughout the soldering operation is required and such a condition is extremely hard to meet in practice. -
Thermal Fatigue Assessment of Lead-Free Solder Joints Qiang Yu, M
Thermal Fatigue Assessment of Lead-Free Solder Joints Qiang Yu, M. Shiratori To cite this version: Qiang Yu, M. Shiratori. Thermal Fatigue Assessment of Lead-Free Solder Joints. THERMINIC 2005, Sep 2005, Belgirate, Lago Maggiore, Italy. pp.204-211. hal-00189474 HAL Id: hal-00189474 https://hal.archives-ouvertes.fr/hal-00189474 Submitted on 21 Nov 2007 HAL is a multi-disciplinary open access L’archive ouverte pluridisciplinaire HAL, est archive for the deposit and dissemination of sci- destinée au dépôt et à la diffusion de documents entific research documents, whether they are pub- scientifiques de niveau recherche, publiés ou non, lished or not. The documents may come from émanant des établissements d’enseignement et de teaching and research institutions in France or recherche français ou étrangers, des laboratoires abroad, or from public or private research centers. publics ou privés. Thermal Fatigue Assessment of Lead-Free Solder Joints Qiang YU and Masaki SHIRATORI Department of Mechanical Engineering and Materials Science Yokohama National University Tokiwadai 79-5, Hodogaya-ku, Yokohama, 240-8501, Japan Phone:+81-45-339-3862 FAX: +81-45-331-6593 E-mail: [email protected] ABSTRACT attracted attention. In this study, the relationship between the In this paper the authors have investigated the thermal fatigue voids and fatigue strength of solder joints was examined using reliability of lead-free solder joints. They have focused their mechanical shear fatigue test. Using the mechanical shear attention to the formation of the intermetallic compound and fatigue test, the effect of the position and size of voids on its effect on the initiation and propagation behaviors of fatigue fatigue crack initiation and crack propagation has been cracks.