6.007 Lecture 5: Electrostatics (Gauss's Law and Boundary
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Gauss's Law II
Gauss’s law II If a lightning bolt strikes a car (unless it is a convertible), electrons would quickly (in the order of nano seconds) move to the surface, so it is almost an ideal conductive shell that you can hide inside during a lightning storm! Reading: Mazur 24.7-25.2 Deriving Gauss’s law Applying Gauss’s law Electric potential energy Electrostatic work LECTURE 7 1 24.7 Deriving Gauss’s law Gauss’s law states that the flux through a closed surface is proportional to the enclosed charge, �"#$, such that �"#$ Φ& = �) LECTURE 7 2 Question: 24.7-1 (Flux from point charge) Consider a spherical Gaussian surface of radius � with a point charge � at the center. � 1 ⃗ The flux through a surface is given by Φ& = ∮1 � ⋅ ��. Using this definition for flux and Coulomb's law, calculate the flux through the Gaussian surface in terms of �, �, � and any constants. LECTURE 7 3 Question: 24.7-1 (Flux from point charge) answer Consider a spherical Gaussian surface of radius � with a point charge � at the center. � 1 ⃗ The flux through a surface is given by Φ& = ∮1 � ⋅ ��. Using this definition for flux and Coulomb's law, calculate the flux through the Gaussian surface in terms of �, �, � and any constants. The electric field is always normal to the Gaussian surface and has equal magnitude at all points on the surface. Therefore 1 1 1 � Φ = 3 � ⋅ ��⃗ = 3 ��� = � 3 �� = � 4��6 = � 4��6 = 4��� & �6 1 1 1 7 From Gauss’s law Φ& = 89 7 : Therefore Φ& = = 4���, and �) = 89 ;<= LECTURE 7 4 Reading quiz (Problem 24.70) There is a Gauss's law for gravity analogous to Gauss's law for electricity. -
Polyelectrolyte Assisted Charge Titration Spectrometry: Applications to Latex and Oxide Nanoparticles
Polyelectrolyte assisted charge titration spectrometry: applications to latex and oxide nanoparticles F. Mousseau1*, L. Vitorazi1, L. Herrmann1, S. Mornet2 and J.-F. Berret1* 1Matière et Systèmes Complexes, UMR 7057 CNRS Université Denis Diderot Paris-VII, Bâtiment Condorcet, 10 rue Alice Domon et Léonie Duquet, 75205 Paris, France. 2Institut de Chimie de la Matière Condensée de Bordeaux, UPR CNRS 9048, Université Bordeaux 1, 87 Avenue du Docteur A. Schweitzer, Pessac cedex F-33608, France. Abstract: The electrostatic charge density of particles is of paramount importance for the control of the dispersion stability. Conventional methods use potentiometric, conductometric or turbidity titration but require large amount of samples. Here we report a simple and cost-effective method called polyelectrolyte assisted charge titration spectrometry or PACTS. The technique takes advantage of the propensity of oppositely charged polymers and particles to assemble upon mixing, leading to aggregation or phase separation. The mixed dispersions exhibit a maximum in light scattering as a function of the volumetric ratio �, and the peak position �!"# is linked to the particle charge density according to � ~ �!�!"# where �! is the particle diameter. The PACTS is successfully applied to organic latex, aluminum and silicon oxide particles of positive or negative charge using poly(diallyldimethylammonium chloride) and poly(sodium 4-styrenesulfonate). The protocol is also optimized with respect to important parameters such as pH and concentration, and to the polyelectrolyte molecular weight. The advantages of the PACTS technique are that it requires minute amounts of sample and that it is suitable to a broad variety of charged nano-objects. Keywords: charge density – nanoparticles - light scattering – polyelectrolyte complex Corresponding authors: [email protected] [email protected] To appear in Journal of Colloid and Interface Science leading to their condensation and to the formation of the electrical double layer [1]. -
Chapter 2 Introduction to Electrostatics
Chapter 2 Introduction to electrostatics 2.1 Coulomb and Gauss’ Laws We will restrict our discussion to the case of static electric and magnetic fields in a homogeneous, isotropic medium. In this case the electric field satisfies the two equations, Eq. 1.59a with a time independent charge density and Eq. 1.77 with a time independent magnetic flux density, D (r)= ρ (r) , (1.59a) ∇ · 0 E (r)=0. (1.77) ∇ × Because we are working with static fields in a homogeneous, isotropic medium the constituent equation is D (r)=εE (r) . (1.78) Note : D is sometimes written : (1.78b) D = ²oE + P .... SI units D = E +4πP in Gaussian units in these cases ε = [1+4πP/E] Gaussian The solution of Eq. 1.59 is 1 ρ0 (r0)(r r0) 3 D (r)= − d r0 + D0 (r) , SI units (1.79) 4π r r 3 ZZZ | − 0| with D0 (r)=0 ∇ · If we are seeking the contribution of the charge density, ρ0 (r) , to the electric displacement vector then D0 (r)=0. The given charge density generates the electric field 1 ρ0 (r0)(r r0) 3 E (r)= − d r0 SI units (1.80) 4πε r r 3 ZZZ | − 0| 18 Section 2.2 The electric or scalar potential 2.2 TheelectricorscalarpotentialFaraday’s law with static fields, Eq. 1.77, is automatically satisfied by any electric field E(r) which is given by E (r)= φ (r) (1.81) −∇ The function φ (r) is the scalar potential for the electric field. It is also possible to obtain the difference in the values of the scalar potential at two points by integrating the tangent component of the electric field along any path connecting the two points E (r) d` = φ (r) d` (1.82) − path · path ∇ · ra rb ra rb Z → Z → ∂φ(r) ∂φ(r) ∂φ(r) = dx + dy + dz path ∂x ∂y ∂z ra rb Z → · ¸ = dφ (r)=φ (rb) φ (ra) path − ra rb Z → The result obtained in Eq. -
Influence of Polyelectrolyte Multilayer Properties on Bacterial Adhesion
polymers Article Influence of Polyelectrolyte Multilayer Properties on Bacterial Adhesion Capacity Davor Kovaˇcevi´c 1, Rok Pratnekar 2, Karmen GodiˇcTorkar 2, Jasmina Salopek 1, Goran Draži´c 3,4,5, Anže Abram 3,4,5 and Klemen Bohinc 2,* 1 Department of Chemistry, Faculty of Science, University of Zagreb, Zagreb 10000, Croatia; [email protected] (D.K.); [email protected] (J.S.) 2 Faculty of Health Sciences, Ljubljana 1000, Slovenia; [email protected] (R.P.); [email protected] (K.G.T.) 3 Jožef Stefan Institute, Ljubljana 1000, Slovenia; [email protected] (G.D.); [email protected] (A.A.) 4 National Institute of Chemistry, Ljubljana 1000, Slovenia 5 Jožef Stefan International Postgraduate School, Ljubljana 1000, Slovenia * Correspondence: [email protected]; Tel.: +386-1300-1170 Academic Editor: Christine Wandrey Received: 16 August 2016; Accepted: 14 September 2016; Published: 26 September 2016 Abstract: Bacterial adhesion can be controlled by different material surface properties, such as surface charge, on which we concentrate in our study. We use a silica surface on which poly(allylamine hydrochloride)/sodium poly(4-styrenesulfonate) (PAH/PSS) polyelectrolyte multilayers were formed. The corresponding surface roughness and hydrophobicity were determined by atomic force microscopy and tensiometry. The surface charge was examined by the zeta potential measurements of silica particles covered with polyelectrolyte multilayers, whereby ionic strength and polyelectrolyte concentrations significantly influenced the build-up process. For adhesion experiments, we used the bacterium Pseudomonas aeruginosa. The extent of adhered bacteria on the surface was determined by scanning electron microscopy. The results showed that the extent of adhered bacteria mostly depends on the type of terminating polyelectrolyte layer, since relatively low differences in surface roughness and hydrophobicity were obtained. -
Surface Polarization Effects in Confined Polyelectrolyte Solutions
Surface polarization effects in confined polyelectrolyte solutions Debarshee Bagchia , Trung Dac Nguyenb , and Monica Olvera de la Cruza,b,c,1 aDepartment of Materials Science and Engineering, Northwestern University, Evanston, IL 60208; bDepartment of Chemical and Biological Engineering, Northwestern University, Evanston, IL 60208; and cDepartment of Physics and Astronomy, Northwestern University, Evanston, IL 60208 Contributed by Monica Olvera de la Cruz, June 24, 2020 (sent for review April 21, 2020; reviewed by Rene Messina and Jian Qin) Understanding nanoscale interactions at the interface between ary conditions (18, 19). However, for many biological settings two media with different dielectric constants is crucial for con- as well as in supercapacitor applications, molecular electrolytes trolling many environmental and biological processes, and for confined by dielectric materials, such as graphene, are of interest. improving the efficiency of energy storage devices. In this Recent studies on dielectric confinement of polyelectrolyte by a contributed paper, we show that polarization effects due to spherical cavity showed that dielectric mismatch leads to unex- such dielectric mismatch remarkably influence the double-layer pected symmetry-breaking conformations, as the surface charge structure of a polyelectrolyte solution confined between two density increases (20). The focus of the present study is the col- charged surfaces. Surprisingly, the electrostatic potential across lective effects of spatial confinement by two parallel surfaces -
Semester II, 2015-16 Department of Physics, IIT Kanpur PHY103A: Lecture # 5 Anand Kumar
Semester II, 2017-18 Department of Physics, IIT Kanpur PHY103A: Lecture # 8 (Text Book: Intro to Electrodynamics by Griffiths, 3rd Ed.) Anand Kumar Jha 19-Jan-2018 Summary of Lecture # 7: • Electrostatic Boundary Conditions E E = Electric Field: = above below E − E = 00 above− below � 0 above − below Electric Potential: V V = 0 above − below • Basic Properties of Conductors (1) The electric field = 0 inside a conductor, always. = 0 = = 0 (2) The charge density inside a conductor. This is because . (3) Any net charge resides on the surface. Why? To minimize the energy. 0 ⋅ (4) A conductor is an equipotential. (5) is perpendicular to the surface, just outside the conductor. 2 Summary of Lecture # 7: Prob. 2.36 (Griffiths, 3rd Ed. ): - Surface charge ? = = − 2 - Surface charge ? 4 + - Surface charge ? = − 2 4 1 2 - ( ) ? = 4 out 2 1 0 � - ( ) ? = 4 out 2 10 �+ - ( ) ? =4 out out 2 � - Force on ? 0 40 - Force on ? 0 3 Summary of Lecture # 7: Prob. 2.36 (Griffiths, 3rd Ed. ): - Surface charge ? = Same ª = − 2 Same - Surface charge ? 4 ª + - Surface charge ? = − 2 Changes � 4 1 2 = - ( ) ? 4 Same ª out 2 1 0 � = 4 - ( ) ? Same ª out 2 � 10 + Changes � - ( ) ? =4 out out 2 - Force on ? 0 0 � 4 Same ª Bring in a third - Force on ? 0 Same ª charge 4 Surface Charge and the Force on a Conductor: What is the electrostatic force on the patch? Force per unit area on the patch is: = (? ) = other = + , above other patch above = + 2 other 0 � = + , below other patch below 1 = = + 2 2 other − � other above below 0 But, inside a metal, = , so = 0 below = = + = 2 2 other � above other � � 5 0 0 0 Surface Charge and the Force on a Conductor: What is the electrostatic force on the patch? Force per unit area on the patch is: = (? ) = other = = 2 other � above � Force per unit0 area on the patch is: 0 = = 2 2 other � Force per unit area is pressure.0 So, the electrostatic pressure is: = = 2 2 20 2 6 0 Capacitor: Two conductors with charge and . -
Ion Current Rectification in Extra-Long Nanofunnels
applied sciences Article Ion Current Rectification in Extra-Long Nanofunnels Diego Repetto, Elena Angeli * , Denise Pezzuoli, Patrizia Guida, Giuseppe Firpo and Luca Repetto Department of Physics, University of Genoa, via Dodecaneso 33, 16146 Genoa, Italy; [email protected] (D.R.); [email protected] (D.P.); [email protected] (P.G.); giuseppe.fi[email protected] (G.F.); [email protected] (L.R.) * Correspondence: [email protected] Received: 29 April 2020; Accepted: 25 May 2020; Published: 28 May 2020 Abstract: Nanofluidic systems offer new functionalities for the development of high sensitivity biosensors, but many of the interesting electrokinetic phenomena taking place inside or in the proximity of nanostructures are still not fully characterized. Here, to better understand the accumulation phenomena observed in fluidic systems with asymmetric nanostructures, we study the distribution of the ion concentration inside a long (more than 90 µm) micrometric funnel terminating with a nanochannel. We show numerical simulations, based on the finite element method, and analyze how the ion distribution changes depending on the average concentration of the working solutions. We also report on the effect of surface charge on the ion distribution inside a long funnel and analyze how the phenomena of ion current rectification depend on the applied voltage and on the working solution concentration. Our results can be used in the design and implementation of high-performance concentrators, which, if combined with high sensitivity detectors, could drive the development of a new class of miniaturized biosensors characterized by an improved sensitivity. Keywords: nanofunnel; FEM simulation; ionic current rectification; micro-nano structure interface 1. -
Maxwell's Equations
Maxwell’s Equations Matt Hansen May 20, 2004 1 Contents 1 Introduction 3 2 The basics 3 2.1 Static charges . 3 2.2 Moving charges . 4 2.3 Magnetism . 4 2.4 Vector operations . 5 2.5 Calculus . 6 2.6 Flux . 6 3 History 7 4 Maxwell’s Equations 8 4.1 Maxwell’s Equations . 8 4.2 Gauss’ law for electricity . 8 4.3 Gauss’ law for magnetism . 10 4.4 Faraday’s law . 11 4.5 Ampere-Maxwell law . 13 5 Conclusion 14 2 1 Introduction If asked, most people outside a physics department would not be able to identify Maxwell’s equations, nor would they be able to state that they dealt with electricity and magnetism. However, Maxwell’s equations have many very important implications in the life of a modern person, so much so that people use devices that function off the principles in Maxwell’s equations every day without even knowing it. 2 The basics 2.1 Static charges In order to understand Maxwell’s equations, it is necessary to understand some basic things about electricity and magnetism first. Static electricity is easy to understand, in that it is just a charge which, as its name implies, does not move until it is given the chance to “escape” to the ground. Amounts of charge are measured in coulombs, abbreviated C. 1C is an extraordi- nary amount of charge, chosen rather arbitrarily to be the charge carried by 6.41418 · 1018 electrons. The symbol for charge in equations is q, sometimes with a subscript like q1 or qenc. -
Beryllium Desorption from Minerals and Organic Ligands Over Time
Chemical Geology 439 (2016) 52–58 Contents lists available at ScienceDirect Chemical Geology journal homepage: www.elsevier.com/locate/chemgeo Beryllium desorption from minerals and organic ligands over time Vanessa Boschi ⁎,JaneK.Willenbring Department of Earth and Environmental Science, University of Pennsylvania, 251 Hayden Hall, 240 South 33rd Street, Philadelphia, PA 19104, USA article info abstract Article history: Beryllium isotopes sorbed to sediments have provided useful tools in the field of geochronology and geomor- Received 13 April 2016 phology over the last few decades. The use of beryllium isotopes relies on the premise that beryllium sorbed to Received in revised form 3 June 2016 sediments is unaltered over large timescales. Changes in the environmental chemistry, either in-situ or en Accepted 10 June 2016 route from soil to fluvial system, to the ocean, can cause beryllium desorption and may preclude some beryllium Available online 11 June 2016 isotopic applications. Keywords: Four mechanisms were tested to determine the relative desorption potential of beryllium including a reduction Beryllium in pH, an increase in ionic strength (NaCl) and complexation by soluble organic (malonic acid) and inorganic spe- Desorption cies (NaF). To assess the relative effect of each mechanism on beryllium desorption from both organic and min- Minerals eral fractions, we prepared separate solutions of beryllium bound to minerals and organic compounds and Organic ligands measured beryllium concentrations in solution before and after each chemical perturbation. We conclude a re- Inner and outer sphere complexation duction in pH resulted in the greatest amount of desorption among the four treatments, removing 97% and 75% of sorbed beryllium from illite and montmorillonite, respectively, and none from the organic ligands tested. -
Symmetry • the Concept of Flux • Calculating Electric Flux • Gauss's
Topics: • Symmetry • The Concept of Flux • Calculating Electric Flux • Gauss’s Law • Using Gauss’s Law • Conductors in Electrostatic Equilibrium PHYS 1022: Chap. 28, Pg 2 1 New Topic PHYS 1022: Chap. 28, Pg 3 For uniform field, if E and A are perpendicular, define If E and A are NOT perpendicular, define scalar product General (surface integral) Unit of electric flux: N . m2 / C Electric flux is proportional to the number of field lines passing through the area. And to the total change enclosed PHYS 1022: Chap. 28, Pg 4 2 + + PHYS 1022: Chap. 28, Pg 5 + + PHYS 1022: Chap. 28, Pg 6 3 r + ½r + 2r PHYS 1022: Chap. 28, Pg 7 r + ½r + 2r PHYS 1022: Chap. 28, Pg 8 4 A metal block carries a net positive charge and put in an electric field. 1) 0 What is the electric field inside? 2) positive 3) Negative 4) Cannot be determined If there is an electric field inside the conductor, it will move the charges in the conductor to where each charge is in equilibrium. That is, net force = 0 therefore net field = 0! PHYS 1022: Chap. 28, Pg 9 A metal block carries a net charge and 1) All inside the conductor put in an electric field. Where does 2) All on the surface the net charge reside ? 3) Some inside the conductor, some on the surface The net field = 0 inside, and so the net flux through any surface drawn inside the conductor = 0. Therefore the net charge inside = 0! PHYS 1022: Chap. 28, Pg 10 5 PHYS 1022: Chap. -
A Problem-Solving Approach – Chapter 2: the Electric Field
chapter 2 the electric field 50 The Ekelric Field The ancient Greeks observed that when the fossil resin amber was rubbed, small light-weight objects were attracted. Yet, upon contact with the amber, they were then repelled. No further significant advances in the understanding of this mysterious phenomenon were made until the eighteenth century when more quantitative electrification experiments showed that these effects were due to electric charges, the source of all effects we will study in this text. 2·1 ELECTRIC CHARGE 2·1·1 Charginl by Contact We now know that all matter is held together by the aurae· tive force between equal numbers of negatively charged elec· trons and positively charged protons. The early researchers in the 1700s discovered the existence of these two species of charges by performing experiments like those in Figures 2·1 to 2·4. When a glass rod is rubbed by a dry doth, as in Figure 2-1, some of the electrons in the glass are rubbed off onto the doth. The doth then becomes negatively charged because it now has more electrons than protons. The glass rod becomes • • • • • • • • • • • • • • • • • • • • • , • • , ~ ,., ,» Figure 2·1 A glass rod rubbed with a dry doth loses some of iu electrons to the doth. The glau rod then has a net positive charge while the doth has acquired an equal amount of negative charge. The total charge in the system remains zero. £kctric Charge 51 positively charged as it has lost electrons leaving behind a surplus number of protons. If the positively charged glass rod is brought near a metal ball that is free to move as in Figure 2-2a, the electrons in the ball nt~ar the rod are attracted to the surface leaving uncovered positive charge on the other side of the ball. -
21. Maxwell's Equations. Electromagnetic Waves
University of Rhode Island DigitalCommons@URI PHY 204: Elementary Physics II -- Slides PHY 204: Elementary Physics II (2021) 2020 21. Maxwell's equations. Electromagnetic waves Gerhard Müller University of Rhode Island, [email protected] Robert Coyne University of Rhode Island, [email protected] Follow this and additional works at: https://digitalcommons.uri.edu/phy204-slides Recommended Citation Müller, Gerhard and Coyne, Robert, "21. Maxwell's equations. Electromagnetic waves" (2020). PHY 204: Elementary Physics II -- Slides. Paper 46. https://digitalcommons.uri.edu/phy204-slides/46https://digitalcommons.uri.edu/phy204-slides/46 This Course Material is brought to you for free and open access by the PHY 204: Elementary Physics II (2021) at DigitalCommons@URI. It has been accepted for inclusion in PHY 204: Elementary Physics II -- Slides by an authorized administrator of DigitalCommons@URI. For more information, please contact [email protected]. Dynamics of Particles and Fields Dynamics of Charged Particle: • Newton’s equation of motion: ~F = m~a. • Lorentz force: ~F = q(~E +~v ×~B). Dynamics of Electric and Magnetic Fields: I q • Gauss’ law for electric field: ~E · d~A = . e0 I • Gauss’ law for magnetic field: ~B · d~A = 0. I dF Z • Faraday’s law: ~E · d~` = − B , where F = ~B · d~A. dt B I dF Z • Ampere’s` law: ~B · d~` = m I + m e E , where F = ~E · d~A. 0 0 0 dt E Maxwell’s equations: 4 relations between fields (~E,~B) and sources (q, I). tsl314 Gauss’s Law for Electric Field The net electric flux FE through any closed surface is equal to the net charge Qin inside divided by the permittivity constant e0: I ~ ~ Qin Qin −12 2 −1 −2 E · dA = 4pkQin = i.e.