Safety data sheet Issue Date 21-Mar-2018 Revision Date 21-Mar-2018 Version 2
1. IDENTIFICATION
Product identifier Product Name Formalin 37-7 HM - US
Other means of identification Synonyms Formaldehyde solution
Pure substance/mixture Substance
Recommended use of the chemical and restrictions on use Application Chemical intermediate
Uses advised against Consumer use.
Details of the supplier of the safety data sheet Manufacturer Address
Perstorp Polyols, Inc. 600 Matzinger Road Toledo, Ohio 43612 Phone: 419-729-5448 800-537-0280 Fax: 419-729-3291 www.perstorp.com
E-mail address [email protected]
Emergency telephone number USA (+)1 866 519 4752 (contract no: 334101)
2. HAZARDS IDENTIFICATION
Classification of the substance or mixture This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200): Acute toxicity - Oral - Category 3 Acute toxicity - Dermal - Category 3 Acute toxicity - Inhalation (Vapors) - Category 2 Skin corrosion/irritation - Category 1 Sub-category B Serious eye damage/eye irritation - Category 1 Skin sensitization - Category 1A Germ cell mutagenicity - Category 2 Carcinogenicity - Category 1A Specific target organ toxicity (single exposure) Category 1; optic nerve, - central nervous system Specific target organ toxicity (single exposure) - Category 3 Flammable liquids - Category 4
Label elements Symbols/Pictograms
______
Page 1 / 12 AGHS - EN Formalin 37-7 HM - US Revision Date 21-Mar-2018 ______
Signal word Danger
Hazard statements Fatal if inhaled Toxic if swallowed Toxic in contact with skin Causes severe skin burns and eye damage May cause cancer Suspected of causing genetic defects May cause an allergic skin reaction Causes damage to organs if swallowed; optic nerve, central nervous system May cause respiratory irritation Combustible liquid
Precautionary Statements Obtain special instructions before use Do not breathe dust/fume/gas/mist/vapors/spray Wear protective gloves/protective clothing/eye protection/face protection IF SWALLOWED: Immediately call a POISON CENTER or doctor IF INHALED: Remove person to fresh air and keep comfortable for breathing IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Immediately call a POISON CENTER or doctor Store in a well-ventilated place. Keep container tightly closed
Contains: Formaldehyde 37.0-37.5%, Methanol 6.5 – 7.5%
Supplemental information No information available
Hazards not otherwise classified (HNOC) Toxic to aquatic life.
Unknown Acute Toxicity 44.5 % of the mixture consists of ingredient(s) of unknown toxicity
3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance Chemical Name CAS No Weight-% Formaldehyde 50-00-0 37.0-37.5 Methanol 67-56-1 6.5 – 7.5
4. FIRST AID MEASURES
Description of first aid measures
General advice First aid personnel should pay attention to their own safety. If unconscious place in recovery position and seek medical advice. Remove/Take off immediately all contaminated clothing. Remove breathing equipment only after contaminated clothing have been completely removed. If breathing is irregular or stopped, administer artificial respiration.
Inhalation Remove to fresh air. Call a physician or poison control center immediately. Oxygen or artificial respiration if needed. If unconscious place in recovery position and seek medical advice.
Skin contact Important! Immediately flush skin with water for at least 15 minutes. Use lukewarm water if possible. Remove contaminated clothing and shoes. Get medical attention immediately. Cover wound with a sterile dressing.
Eye contact Important! Immediately flush eyes, also under eyelids, with water for at least 15 minutes.
______
Page 2 / 12 AGHS - EN Formalin 37-7 HM - US Revision Date 21-Mar-2018 ______
Use lukewarm water if possible. Get medical attention immediately.
Ingestion Rinse mouth then drink plenty of water. Do NOT induce vomiting. Seek immediate medical attention/advice.
Self-protection of the first aider Do not breathe gas/fumes/vapor/spray. Avoid contact with skin, eyes or clothing. Use personal protective equipment as required.
Most important symptoms and effects, both acute and delayed Exposure may cause watery eyes, nausea, coughing, chest tightness, wheezing, skin rashes, allergenic reactions, and burning sensations in the eyes, nose, and throat. Formaldehyde is corrosive on skin and may cause permanent clouding of the cornea after only one exposure. Subsequent exposures can produce symptoms more quickly and at lower concentrations. Symptoms of exposure may include coughing, eye or skin irritation, allergic reactions, vomiting, and diarrhoea. Formaldehyde has been shown to cause cancer in laboratory animals and may cause cancer in humans. It is toxic if swallowed, inhaled, or absorbed though skin or mucous membranes. Contains: Methanol. Methanol poisoning has a number of symptoms. These include bizarre behavior, extreme dizziness, severe headaches, and coma. Methanol poisoning can cause permanent damage to the optic nerve and central and peripheral nervous system with just a single acute exposure. The digestive system starts to immediately reject methanol and symptoms may include severe stomach pain, nausea, and diarrhea. Methanol also disrupts liver and pancreatic function. Even with treatment, methanol poisoning can cause permanent liver damage. Signs of systemic poisoning may be delayed 8-36 hours after initial exposure. The substance is as well a mild eye, respiratory tract, and mucous membrane irritant and acts defattening on skin which cauese the skin to become dry and cracked.
Indication of any immediate medical attention and special treatment needed Note: Contains: 7-8% Methanol
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media Carbon dioxide (CO2). Extinguishing powder. Water spray (fog).
Unsuitable extinguishing media Do not use a solid water stream as it may scatter and spread fire.
Specific hazards arising from the chemical Vapors may form explosive mixtures with air. Thermal decomposition can lead to release of irritating and toxic gases and vapors. In the event of fire and/or explosion do not breathe fumes.
Protective equipment and precautions for firefighters Wear self-contained breathing apparatus and protective suit. Use personal protective equipment as required.
Additional information Cool containers with flooding quantities of water until well after fire is out. Prevent fire extinguishing water from contaminating surface water or the ground water system.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures Personal precautions Keep unprotected persons away. Wear full protective clothing and self contained breathing apparatus. Remove all sources of ignition. Ensure adequate ventilation, especially in confined areas.
Environmental precautions Do not allow into any sewer, on the ground or into any body of water. Local authorities should be advised if significant spillages cannot be contained. See Section 12 for additional ecological information.
Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Small spill Dilute with water and wipe up or absorb with inert material. Large spill Contact the rescue service.
Methods for cleaning up Clean contaminated surface thoroughly. Flush area with flooding quantities of water.
______
Page 3 / 12 AGHS - EN Formalin 37-7 HM - US Revision Date 21-Mar-2018 ______
Reference to other sections See Section 7,8,13 for more information.
7. HANDLING AND STORAGE
Precautions for safe handling Use only with adequate ventilation and in closed systems. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Not to be used by pregnant workers and workers who have recently given birth or who are breastfeeding.
General Hygiene Considerations When using do not eat, drink or smoke. Regular cleaning of equipment, work area and clothing is recommended.
Conditions for safe storage, including any incompatibilities Store in a locked area. Storage at low temperatures (below 20°C) will lead to the formation of a paraformaldehyde as a white precipitate, and this polymerization reaction is enhanced as the temperature reduces. Storage facilities should be equipped with ventilation at high level.
Suitable container/equipment material Suitable container/equipment material: Stainless steel 304 or 316, High density polyethylene (HDPE), Low density polyethylene (LDPE), aluminum.
Unsuitable container/equipment material Unsuitable container/equipment material: Paper, Board, Glass.
Additional information Keep container tightly closed
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters Exposure Guidelines Users are advised to consider national Occupational Exposure Limits or other equivalent values.
Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH Formaldehyde STEL: 0.3 ppm TWA: 0.75 ppm IDLH: 20 ppm 50-00-0 TWA: 0.1 ppm (vacated) TWA: 3 ppm unless Ceiling: 0.1 ppm 15 min specified in 1910.1048 TWA: 0.016 ppm (vacated) STEL: 10 ppm 30 min unless specified in 1910.1048 (vacated) Ceiling: 5 ppm unless specified in 1910.1048 STEL: 2 ppm see 29 CFR 1910.1048 Methanol STEL: 250 ppm TWA: 200 ppm IDLH: 6000 ppm 67-56-1 TWA: 200 ppm TWA: 260 mg/m3 TWA: 200 ppm S* (vacated) TWA: 200 ppm TWA: 260 mg/m3 (vacated) TWA: 260 mg/m3 STEL: 250 ppm (vacated) STEL: 250 ppm STEL: 325 mg/m3 (vacated) STEL: 325 mg/m3 (vacated) S* Formic acid STEL: 10 ppm TWA: 5 ppm IDLH: 30 ppm 64-18-6 TWA: 5 ppm TWA: 9 mg/m3 TWA: 5 ppm (vacated) TWA: 5 ppm TWA: 9 mg/m3 (vacated) TWA: 9 mg/m3
NIOSH IDLH Immediately Dangerous to Life or Health
Appropriate engineering controls Showers Eyewash stations Ventilation systems
Individual protection measures, such as personal protective equipment Eye/face protection Tight sealing safety goggles. Hand Protection Ensure that the breakthrough time of the glove material is not exceeded. Refer to glove supplier for information on breakthrough time for specific gloves.
______
Page 4 / 12 AGHS - EN Formalin 37-7 HM - US Revision Date 21-Mar-2018 ______
Duration of contact material Glove thickness Break through time Remarks Suitable materials also with Nitrile rubber, NBR Butyl >480 min prolonged, direct contact rubber (corresponding > 480 minutes of permeation time): Skin and body protection Body protection must be chosen depending on activity and possible exposure, e.g. apron, chemical resistant boots, chemical-protection suit. Respiratory protection Wear positive pressure self-contained breathing apparatus (SCBA).
9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties Appearance liquid colorless Odor Pungent Odor threshold 0.2-1 ppm
Property Value Remarks • Method pH 2 - 4 @ 20°C (68 °F) Melting point / freezing point Not determined Boiling point / boiling range 94 - 100 °C / 202 - 212 °F (@ 760 mmHg) Flash point 68 °C / 154 °F Evaporation rate Not determined Flammability (solid, gas) Not applicable Explosive limits Upper explosive limits 73 Vol-% No information available Lower explosive limits 7 Vol-% (100% FA) Vapor pressure 39-42 mmHg @ 37.8°C (100 °F) Vapor density Not applicable Relative density No information available Water solubility Fully miscible. Solubility(ies) No information available Partition coefficient -1 log POW Autoignition temperature ca 430 °C / ca 806 °F Decomposition temperature Not determined Kinematic viscosity No information available Dynamic viscosity No information available Explosive properties Not explosive. No information available Oxidizing properties Not oxidizing. No information available Density 1.08 – 1.13 g/cm³ (9.013 – 9.43 No information available lbs/gal) Bulk density No information available
Other Information The flashpoint data apply to Formalin 37-7 HM - US. The rest of the physical data apply to 37% concentration of FA.
10. STABILITY AND REACTIVITY
Reactivity The substance is a strong reducing agent, especially in the presence of alkalis. The substance reacts violently with nitrous oxides at about 356°F, performic acid, nitromethane, manganese carbonate and hydrogen peroxide. The substance reacts with strong oxidizers and acids.
Chemical stability The product is stable under normal conditions of use and storage. However, it is normal for formaldehyde solutions to form paraformaldehyde (white precipitate or cloudy solutions) at temperatures below 68°F. Formaldehyde will sIowly oxidize in contact with air to give formic acid.
Possibility of Hazardous Reactions The substance reacts violently with nitrous oxides at about 356°F, performic acid, nitromethane, manganese carbonate and hydrogen peroxide. Risk of run-away reactions between formaldehyde and phenol. Reaction with hydrochloric acid may form bis-chloromethyl ether (carcinogenic).
Conditions to avoid
______
Page 5 / 12 AGHS - EN Formalin 37-7 HM - US Revision Date 21-Mar-2018 ______
Keep away from heat and sources of ignition.
Incompatible materials See above.
Hazardous decomposition products Thermal decomposition may release noxious, toxic or corrosive gases or vapours.
11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure Inhalation. Dermal. Oral.
Symptoms related to the physical, chemical and toxicological characteristics See Section 4 for more information.
Numerical measures of toxicity
ATEmix (oral) 225.00 mg/kg ATEmix (dermal) 674.00 mg/kg ATEmix (inhalation-vapor) 1.00 mg/l Unknown Acute Toxicity 44.5 % of the mixture consists of ingredient(s) of unknown toxicity
Acute toxicity Fatal if inhaled. Toxic in contact with skin and if swallowed.
Formaldehyde (50-00-0) Method Species Exposure route Effective dose Remarks OECD Test No. 401: Acute Rat Oral 640 LD50 (lethal dose) Oral Toxicity mg/kg OECD Test No. 403: Acute Rat Inhalation Vapor <463 LD50 (lethal dose) 4h, Inhalation Toxicity ppm
Methanol (67-56-1) Method Species Exposure route Effective dose Remarks Not defined Rat Oral 7000-9000 LD50 (lethal dose) mg/kg Not defined Rabbit Dermal 17100 LD50 (lethal dose) mg/kg Not defined Rat Inhalation 128.2 LC50 4h mg/l
Skin corrosion/irritation Causes burns.
Formaldehyde (50-00-0) Method Species Exposure route Results: OECD Test No. 404: Acute Dermal Rabbit Dermal Corrosive Irritation/Corrosion
Methanol (67-56-1) Method Species Exposure route Results: Not defined Rabbit Dermal Non-irritant
Serious eye damage/eye irritation Causes burns. Risk of serious damage to eyes.
Formaldehyde (50-00-0) Method Species Exposure route Results: Unknown Rat Eye Corrosive
Methanol (67-56-1)
______
Page 6 / 12 AGHS - EN Formalin 37-7 HM - US Revision Date 21-Mar-2018 ______
Method Species Exposure route Results: Not defined Rabbit Eye Non-irritant
Respiratory or skin sensitization May cause sensitization by skin contact.
Formaldehyde (50-00-0) Method Species Exposure route Results: OECD Test No. 429: Skin Mouse Skin Sensitizing Sensitization: Local Lymph Node Assay Unknown Mouse Inhalation Not sensitizing. Not defined human data Inhalation Not sensitizing.
Methanol (67-56-1) Method Species Exposure route Results: OECD Test No. 406: Skin Guinea pig Skin Not sensitizing. Sensitization
Germ cell mutagenicity May cause heritable genetic damage.
Formaldehyde (50-00-0) Method Species Results: OECD Test No. 471: Bacterial Reverse in vitro Positive Mutation Test OECD Test No. 476: In vitro Mammalian Cell in vitro Positive Gene Mutation Test OECD Test No. 479: Genetic Toxicology: In in vitro Positive vitro Sister Chromatid Exchange Assay in Mammalian Cells OECD Test No. 484: Genetic Toxicology: in vivo Negative Mouse Spot Test OECD Test No. 474: Mammalian Erythrocyte in vivo Negative Micronucleus Test Other in vivo Positive
Methanol (67-56-1) Method Species Results: OECD Test No. 471: Bacterial Reverse in vitro Negative Mutation Test OECD Test No. 476: In vitro Mammalian Cell in vitro Negative Gene Mutation Test OECD Test No. 474: Mammalian Erythrocyte in vivo Negative Micronucleus Test
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen.
Chemical Name IARC NTP Formaldehyde Group 1 Monograph 100F [2012] Known (Twelfth ed.) Group 1 Monograph 88 [2006] Group 1 Monograph 62 [1995] Group 1 Supplement 7 [1987] IARC (International Agency for Research on Cancer) Group 1 - Carcinogenic to Humans NTP (National Toxicology Program) Known - Known Carcinogen
Formaldehyde (50-00-0) Method Species Exposure route Effective dose Remarks OECD Test No. 453: Mouse Inhalation 15 NOAEC ppm May
______
Page 7 / 12 AGHS - EN Formalin 37-7 HM - US Revision Date 21-Mar-2018 ______
Combined Chronic cause cancer by Toxicity/Carcinogenicity inhalation Studies OECD Test No. 453: Rat Oral 82-109 NOAEL mg/kg bw/day Combined Chronic No carcinogenic effects Toxicity/Carcinogenicity have been observed. Studies OECD Test No. 451: Rat Oral - No carcinogenic effects Carcinogenicity Studies have been observed.
Methanol (67-56-1) Method Species Exposure route Effective dose Remarks OECD Test No. 453: Mouse Inhalation >1.3 NOAEC mg/l Not Combined Chronic considered to be Toxicity/Carcinogenicity carcinogen. Studies
Reproductive toxicity This product does not contain any known or suspected reproductive hazards.
Formaldehyde (50-00-0) Method Species Exposure route Effective dose Remarks Effects on fertility Not applicable Toxicokinetics, metabolism and distribution To Formic acid OECD Test No. 414: Prenatal Mouse Oral 185 NOAEL mg/kg bw/day Development Toxicity Study Developmental Toxicity OECD Test No. 414: Prenatal Rat Inhalation 10 NOAEC ppm Development Toxicity Study Developmental Toxicity
Methanol (67-56-1) Method Species Exposure route Effective dose Remarks OECD Test No. 416: Rat Inhalation 1.3 NOAEC mg/l P Two-Generation Reproduction Toxicity OECD Test No. 416: Rat Inhalation 0.13 NOAEC mg/l F1 Two-Generation Reproduction Toxicity OECD Test No. 416: Rat Inhalation 0.13 NOAEC mg/l F2 Two-Generation Reproduction Toxicity
STOT - single exposure Methanol; May cause damage to the following organs if swallowed: Eyes, central nervous system
Formaldehyde (50-00-0) Method Species Exposure route Effective dose Remarks Unknown Inhalation - Irritating to respiratory system
Methanol (67-56-1) Method Species Exposure route Effective dose Remarks Unknown human data Oral - Causes damage to the following organs if swallowed: Eyes central nervous system
STOT - repeated exposure
Formaldehyde (50-00-0) Method Species Exposure route Effective dose Remarks OECD Test No. 453: Rat Oral 15 NOAEL mg/kg bw/day
______
Page 8 / 12 AGHS - EN Formalin 37-7 HM - US Revision Date 21-Mar-2018 ______
Combined Chronic Toxicity/Carcinogenicity Studies
Methanol (67-56-1) Method Species Exposure route Effective dose Remarks Unknown Monkey Oral 2340 LOAEL mg/kg bw/day 3d OECD Test No. 412: Rat Inhalation 6.66 NOAEC mg/l Subacute Inhalation Toxicity: 28-Day Study OECD Test No. 453: Mouse Inhalation 1.3 NOAEC mg/l Combined Chronic Toxicity/Carcinogenicity Studies
Aspiration hazard No information available.
12. ECOLOGICAL INFORMATION
Toxicity 0% of the mixture consists of components(s) of unknown hazards to the aquatic environment
Formaldehyde (50-00-0) Method Species Exposure route Effective dose Exposure time Remarks Unknown Morone saxatilis Freshwater 6.7 96h LC50 (lethal concentration) mg/l OECD Test No. 202: Daphnia pulex Freshwater 5.8 48h EC50 (effective Daphnia sp. Acute concentration) mg/l Immobilization Test OECD Test No. 201: Scenedesmus Freshwater 4.9 72h EC50 (effective Freshwater Alga and subspicatus concentration) mg/l Cyanobacteria, Growth Inhibition Test OECD Test No. 215: Fish, Oryzias latipes Freshwater >48 28d NOEC mg/l Juvenile Growth Test (Ricefish) OECD Test No. 212: Fish, Brachydanio rerio Freshwater 6.9 144h LC50 (lethal Short-term Toxicity Test concentration) mg/l on Embryo and Sac-Fry Stages OECD Test No. 209: Freshwater 19 3h EC50 (effective Activated Sludge, concentration) mg/l Respiration Inhibition Test (Carbon and Ammonium Oxidation)
Methanol (67-56-1) Method Species Exposure route Effective dose Exposure time Remarks EPA-660/3-75-009 Lepomis Freshwater 15400 96h LC50 (lethal macrochirus concentration) mg/l OECD Test No. 202: Daphnia magna Freshwater 18260 96h EC50 (effective Daphnia sp. Acute concentration) mg/l Immobilization Test OECD Test No. 201: Pseudokirchneriell Freshwater 22000 96h EC50 (effective Freshwater Alga and a subcapitata concentration) mg/l Cyanobacteria, Growth Inhibition Test OECD Test No. 209: Bacteria toxicity Freshwater >1000 3h IC50 mg/l Activated Sludge, Respiration Inhibition Test (Carbon and Ammonium Oxidation)
______
Page 9 / 12 AGHS - EN Formalin 37-7 HM - US Revision Date 21-Mar-2018 ______
OECD Test No. 207: Eisenia fetida >1 48h LC50 (lethal Earthworm, Acute Toxicity concentration) Tests
Persistence and degradability Readily biodegradable
Formaldehyde (50-00-0) Method Value Exposure time Results: OECD Test No. 301D: Ready 90% 28d Readily biodegradable Biodegradability: Closed Bottle Test (TG 301 D)
Methanol (67-56-1) Method Value Exposure time Results: Unknown 95% 20d Readily biodegradable Unknown 97% 20d Readily biodegradable
Bioaccumulative potential Based on the partition coefficients of the ingredients the product is not expected to bioaccumulate in organisms.
Chemical Name Partition coefficient Bioconcentration factor (BCF) Formaldehyde 0.35 Methanol -0.77
Mobility in soil The substance is not expected to adsorb to a high degree to suspended solids and sediment based upon the log Pow.
Chemical Name Log Koc Formaldehyde 1.202 Other adverse effects Emissions to water lowers the pH. This may cause local damage to fish and aquatic organisms in the discharge area.
13. DISPOSAL CONSIDERATIONS
Disposal methods Disposal should be in accordance with applicable regional, national and local laws and regulations.
US EPA Waste Number U122 U154
Chemical Name RCRA RCRA - Basis for Listing RCRA - D Series Wastes RCRA - U Series Wastes Formaldehyde - 50-00-0 U122 Included in waste streams: Not available U122 K009, K010, K038, K040, K156, K157 Methanol - 67-56-1 Not available Included in waste stream: Not available U154 F039 Formic acid - 64-18-6 U123 Included in waste streams: Not available U123 K009, K010
This product contains one or more substances that are listed with the State of California as a hazardous waste.
Chemical Name California Hazardous Waste Status Formaldehyde Toxic Ignitable Methanol Toxic Ignitable Contaminated packaging Not applicable.
14. TRANSPORT INFORMATION
______
Page 10 / 12 AGHS - EN Formalin 37-7 HM - US Revision Date 21-Mar-2018 ______
DOT Road transport UN/ID no UN2209 UN proper shipping name Formaldehyde solution Proper Shipping Description UN2209 FORMALDEHYDE SOLUTION , 8, III Transport hazard class(es) 8 Packing Group III
RID Rail transport UN number UN2209 UN proper shipping name Formaldehyde solution Proper Shipping Description UN2209 FORMALDEHYDE SOLUTION , 8, III Transport hazard class(es) 8 Packing Group III ADR Hazard Id (Kemmler 80 Number)
IMDG Sea transport UN number UN2209 UN proper shipping name Formaldehyde solution Proper Shipping Description UN2209 FORMALDEHYDE SOLUTION , 8, III Transport hazard class(es) 8 Packing Group III EmS-No F-A, S-B Limited quantity (LQ) 5 L Transport in bulk according to No information available Annex II of MARPOL 73/78 and the IBC Code
IATA Air transport UN number UN2209 UN proper shipping name Formaldehyde solution Proper Shipping Description UN2209 FORMALDEHYDE SOLUTION , 8, III Transport hazard class(es) 8 Packing Group III ERG Code 8i Limited quantity (LQ) 1 L
15. REGULATORY INFORMATION
Safety, health and environmental regulations/legislation specific for the substance or mixture
International Regulations IARC (International Agency for Research on Cancer): Group 1 - Carcinogenic to Humans.
US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 Chemical Name SARA 313 - Threshold Values % Formaldehyde - 50-00-0 0.1 Methanol - 67-56-1 1.0
CWA (Clean Water Act) This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42)
______
Page 11 / 12 AGHS - EN Formalin 37-7 HM - US Revision Date 21-Mar-2018 ______
Chemical Name CWA - Reportable CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Quantities Substances Formaldehyde 100 lb Not available Not available X 50-00-0
CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302)
Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ) Formaldehyde 100 lb 100 lb RQ 100 lb final RQ 50-00-0 RQ 45.4 kg final RQ Methanol 5000 lb Not available RQ 5000 lb final RQ 67-56-1 RQ 2270 kg final RQ
TSCA Inventory All components are listed on the TSCA Inventory.
US State Regulations California Proposition 65 This product contains the following Proposition 65 chemicals
Chemical Name California Proposition 65 Formaldehyde - 50-00-0 Carcinogen Methanol - 67-56-1 Developmental U.S. State Right-to-Know Regulations
Chemical Name New Jersey Massachusetts Pennsylvania Water Not available Not available X 7732-18-5 Formaldehyde X X X 50-00-0 Methanol X X X 67-56-1
16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OF THE LAST REVISION
NFPA Health hazards 3 Flammability 2 Instability 0 Physical and Chemical Properties Not available HMIS Health hazards 3 Flammability 2 Physical hazards 0 Personal protection X
Key or legend to abbreviations and acronyms used in the safety data sheet Not applicable
Issue Date 21-Mar-2018 Revision Date 21-Mar-2018
Revision Note SDS sections updated; 1 Uses advised against, 2 Classification, 11 Toxicity data, 15 TSCA
This safety data sheet complies with the requirements of: OSHA Hazard Communication Standard (29 CFR 1910.1200).
Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.
End of Safety Data Sheet
______
Page 12 / 12 AGHS - EN