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Formalin 37-7 HM - US Safety data sheet Issue Date 21-Mar-2018 Revision Date 21-Mar-2018 Version 2 1. IDENTIFICATION Product identifier Product Name Formalin 37-7 HM - US Other means of identification Synonyms Formaldehyde solution Pure substance/mixture Substance Recommended use of the chemical and restrictions on use Application Chemical intermediate Uses advised against Consumer use. Details of the supplier of the safety data sheet Manufacturer Address Perstorp Polyols, Inc. 600 Matzinger Road Toledo, Ohio 43612 Phone: 419-729-5448 800-537-0280 Fax: 419-729-3291 www.perstorp.com E-mail address [email protected] Emergency telephone number USA (+)1 866 519 4752 (contract no: 334101) 2. HAZARDS IDENTIFICATION Classification of the substance or mixture This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200): Acute toxicity - Oral - Category 3 Acute toxicity - Dermal - Category 3 Acute toxicity - Inhalation (Vapors) - Category 2 Skin corrosion/irritation - Category 1 Sub-category B Serious eye damage/eye irritation - Category 1 Skin sensitization - Category 1A Germ cell mutagenicity - Category 2 Carcinogenicity - Category 1A Specific target organ toxicity (single exposure) Category 1; optic nerve, - central nervous system Specific target organ toxicity (single exposure) - Category 3 Flammable liquids - Category 4 Label elements Symbols/Pictograms ___________________________________________________________________________________________ Page 1 / 12 AGHS - EN Formalin 37-7 HM - US Revision Date 21-Mar-2018 ___________________________________________________________________________________________ Signal word Danger Hazard statements Fatal if inhaled Toxic if swallowed Toxic in contact with skin Causes severe skin burns and eye damage May cause cancer Suspected of causing genetic defects May cause an allergic skin reaction Causes damage to organs if swallowed; optic nerve, central nervous system May cause respiratory irritation Combustible liquid Precautionary Statements Obtain special instructions before use Do not breathe dust/fume/gas/mist/vapors/spray Wear protective gloves/protective clothing/eye protection/face protection IF SWALLOWED: Immediately call a POISON CENTER or doctor IF INHALED: Remove person to fresh air and keep comfortable for breathing IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Immediately call a POISON CENTER or doctor Store in a well-ventilated place. Keep container tightly closed Contains: Formaldehyde 37.0-37.5%, Methanol 6.5 – 7.5% Supplemental information No information available Hazards not otherwise classified (HNOC) Toxic to aquatic life. Unknown Acute Toxicity 44.5 % of the mixture consists of ingredient(s) of unknown toxicity 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance Chemical Name CAS No Weight-% Formaldehyde 50-00-0 37.0-37.5 Methanol 67-56-1 6.5 – 7.5 4. FIRST AID MEASURES Description of first aid measures General advice First aid personnel should pay attention to their own safety. If unconscious place in recovery position and seek medical advice. Remove/Take off immediately all contaminated clothing. Remove breathing equipment only after contaminated clothing have been completely removed. If breathing is irregular or stopped, administer artificial respiration. Inhalation Remove to fresh air. Call a physician or poison control center immediately. Oxygen or artificial respiration if needed. If unconscious place in recovery position and seek medical advice. Skin contact Important! Immediately flush skin with water for at least 15 minutes. Use lukewarm water if possible. Remove contaminated clothing and shoes. Get medical attention immediately. Cover wound with a sterile dressing. Eye contact Important! Immediately flush eyes, also under eyelids, with water for at least 15 minutes. ___________________________________________________________________________________________ Page 2 / 12 AGHS - EN Formalin 37-7 HM - US Revision Date 21-Mar-2018 ___________________________________________________________________________________________ Use lukewarm water if possible. Get medical attention immediately. Ingestion Rinse mouth then drink plenty of water. Do NOT induce vomiting. Seek immediate medical attention/advice. Self-protection of the first aider Do not breathe gas/fumes/vapor/spray. Avoid contact with skin, eyes or clothing. Use personal protective equipment as required. Most important symptoms and effects, both acute and delayed Exposure may cause watery eyes, nausea, coughing, chest tightness, wheezing, skin rashes, allergenic reactions, and burning sensations in the eyes, nose, and throat. Formaldehyde is corrosive on skin and may cause permanent clouding of the cornea after only one exposure. Subsequent exposures can produce symptoms more quickly and at lower concentrations. Symptoms of exposure may include coughing, eye or skin irritation, allergic reactions, vomiting, and diarrhoea. Formaldehyde has been shown to cause cancer in laboratory animals and may cause cancer in humans. It is toxic if swallowed, inhaled, or absorbed though skin or mucous membranes. Contains: Methanol. Methanol poisoning has a number of symptoms. These include bizarre behavior, extreme dizziness, severe headaches, and coma. Methanol poisoning can cause permanent damage to the optic nerve and central and peripheral nervous system with just a single acute exposure. The digestive system starts to immediately reject methanol and symptoms may include severe stomach pain, nausea, and diarrhea. Methanol also disrupts liver and pancreatic function. Even with treatment, methanol poisoning can cause permanent liver damage. Signs of systemic poisoning may be delayed 8-36 hours after initial exposure. The substance is as well a mild eye, respiratory tract, and mucous membrane irritant and acts defattening on skin which cauese the skin to become dry and cracked. Indication of any immediate medical attention and special treatment needed Note: Contains: 7-8% Methanol 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Carbon dioxide (CO2). Extinguishing powder. Water spray (fog). Unsuitable extinguishing media Do not use a solid water stream as it may scatter and spread fire. Specific hazards arising from the chemical Vapors may form explosive mixtures with air. Thermal decomposition can lead to release of irritating and toxic gases and vapors. In the event of fire and/or explosion do not breathe fumes. Protective equipment and precautions for firefighters Wear self-contained breathing apparatus and protective suit. Use personal protective equipment as required. Additional information Cool containers with flooding quantities of water until well after fire is out. Prevent fire extinguishing water from contaminating surface water or the ground water system. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Keep unprotected persons away. Wear full protective clothing and self contained breathing apparatus. Remove all sources of ignition. Ensure adequate ventilation, especially in confined areas. Environmental precautions Do not allow into any sewer, on the ground or into any body of water. Local authorities should be advised if significant spillages cannot be contained. See Section 12 for additional ecological information. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Small spill Dilute with water and wipe up or absorb with inert material. Large spill Contact the rescue service. Methods for cleaning up Clean contaminated surface thoroughly. Flush area with flooding quantities of water. ___________________________________________________________________________________________ Page 3 / 12 AGHS - EN Formalin 37-7 HM - US Revision Date 21-Mar-2018 ___________________________________________________________________________________________ Reference to other sections See Section 7,8,13 for more information. 7. HANDLING AND STORAGE Precautions for safe handling Use only with adequate ventilation and in closed systems. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Not to be used by pregnant workers and workers who have recently given birth or who are breastfeeding. General Hygiene Considerations When using do not eat, drink or smoke. Regular cleaning of equipment, work area and clothing is recommended. Conditions for safe storage, including any incompatibilities Store in a locked area. Storage at low temperatures (below 20°C) will lead to the formation of a paraformaldehyde as a white precipitate, and this polymerization reaction is enhanced as the temperature reduces. Storage facilities should be equipped with ventilation at high level. Suitable container/equipment material Suitable container/equipment material: Stainless steel 304 or 316, High density polyethylene (HDPE), Low density polyethylene (LDPE), aluminum. Unsuitable container/equipment material Unsuitable container/equipment material: Paper, Board, Glass. Additional information Keep container tightly closed 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines Users are advised to consider national Occupational Exposure Limits or other equivalent
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