Phosphorus Processing—Potentials for Higher Efficiency
Total Page:16
File Type:pdf, Size:1020Kb
Load more
Recommended publications
-
Global Availability of Phosphorus and Its Implications for Global Food Supply: an Economic Overview by Markus Heckenmüller, Daiju Narita, Gernot Klepper
Global Availability of Phosphorus and Its Implications for Global Food Supply: An Economic Overview by Markus Heckenmüller, Daiju Narita, Gernot Klepper No. 1897 | January 2014 Kiel Institute for the World Economy, Hindenburgufer 66, 24105 Kiel, Germany Kiel Working Paper No. 1897 | January 2014 Global Availability of Phosphorus and Its Implications for Global Food Supply: An Economic Overview Markus Heckenmüller, Daiju Narita, Gernot Klepper Abstract: Being of crucial importance for agricultural production and also having experienced significant price volatility, phosphate and its future availability have drawn growing attention from both academics and the public over the last years. This paper overviews the recent literature and data on the availability of phosphorus and discusses the economic aspects of phosphate scarcity by describing major price determinants of the global phosphate market. We show that past price fluctuations of phosphate rock and phosphate fertilizers are not a reflection of physical phosphate rock depletion but rather attributable to numerous other demand- and supply-side factors. Given the current reserve estimates for phosphate rock, neither an exhaustion of global reserves nor a peak event is likely to occur within this century. However, these estimates are subject to a significant degree of uncertainty. Moreover, the global distribution of phosphate production and reserves is highly skewed and has the potential to pose a threat to food security in developing countries through factors such as the volatility -
Peak Phosphorus – the Next Inconvenient Truth
Peak Phosphorus – The Next Inconvenient Truth Arno Rosemarin Stockholm Environment Institute Phosphorus Seminar Gamla Stan May 19, 2010 The linear path of phosphorus in modern times (Princeton Univ.) Vaccari, 2009 countries as well, mainly in the north; so th the north; so well, mainly in countries as Sulfuric acid which is usedin 90% of the Phosphorus Reserves are in 90% ofthePhosphorus 5 Countries extracting the phosphorus is extracting ere are several geopolitical us challenges ahead of ere are several found in a limited number of a found in Caldwell, SEI, based on USGS, 2009 Phosphate Rock Economic Reserves, 1997-2009 (from USGS summaries) 20 000 000 18 000 000 16 000 000 China k 14 000 000 12 000 000 China Moroc c o & W. Sahara osphate roc South Africa hh 10 000 000 United States Morocco/West Sahara Jordan 8 000 000 Other countries 00 tonnes p 00 1 6 000 000 4 000 000 2 000 000 0 1997 1998 1999 2000 2001 2002 2003 2004 2005 2006 2007 2008 2009 The definition of economic rock reserves is not standardised. China has changed the definition twice after joining the WTO in 2003. In 2009 they downgraded their economic reserve by 30%. There is a need for a world standard and global governance – still non-existent. Depletion of Global Economic Phosphorus Reserves 16000000 14000000 12000000 10000000 years from 2008 tons cc reserve (2% scenario) 8000000 2% annual increase in extraction reserve (1% scenario) 00 metri 00 1% annual increase in extraction 1 6000000 4000000 010 22 2000000 rin, SEI n USGS data aa oo 0 Rosem Based 1 4 7 10131619222528313437404346495255586164 -
Phosphate Rock in Wyoming
Phosphate Rock in Wyoming Jacob D. Carnes Report of Investigations No. 68 • 2015 WYOMING STATE GEOLOGICAL SURVEY Thomas A. Drean, Director and State Geologist Director and State Geologist Thomas A. Drean Editing by: Sarah R. Garlick Design and layout by: James R. Rodgers Photomicrograph of phosphate rock from the Poison Creek trench in Lincoln County, Wyo., showing the concentric structure of ap- atite grains commonly found in phosphorites of the Phosphoria Formation. Photomicrograph by Jacob Carnes, 2015. Cover photo: Outcrop of the Meade Peak Member of the Phosphoria Formation along U.S. Hwy 26, approximately 3 miles southwest of Hoback Junction, in Teton County, Wyo. Photo by Jacob Carnes, 2015. Phosphate Rock in Wyoming Wyoming State Geological Survey (WSGS) Report of Investigations No. 68, 2015 Suggested citation: Carnes, J.D., 2015, Phosphate rock in Wyoming: Wyoming State Geological Survey Report of Investigations No. 68, 34 p. The WSGS encourages fair use of its material. We request that credit be expressly given to the “Wyoming State Geological Survey” when citing information from this publication. Please contact the WSGS at 307- 766-2286, ext. 224, or by email at [email protected], if you have any questions about citing materials, preparing acknowledgments, or extensive use of this material. We appreciate your cooperation. Any use of trade, product, or firm names in this publication is for descriptive purposes only and does not imply endorsement or approval by the State of Wyoming or the WSGS. Individuals with disabilities who require an alternate form of this publication should contact the WSGS. TTY relay operator 800-877-9975. -
Phosphate Rocks!
Essay By: Jacob Kollen Phosphate Rocks! INTRODUCTION On approximately two thirds of the world’s arable land, phosphorus is a plant growth limiting nutrient (Lambers et al., 2013). Agriculture utilizes roughly 80% of the mined phosphate rock as fertilizer, with the remaining 20% being utilized in products such animal feed supplements, food preservatives, pesticides, fungicides, herbicides, water treatments, cosmetics, and metallurgy (Sattari, 2012). Currently we derive approximately 63% of our phosphorus fertilizer from phosphate rock, with the remainder being derived from animal manure, sewage sludge, and guano (Rittman, 2011). Phosphate rock reserves are finite, which leads to a predicament: we will run out of phosphate rock eventually. The concept, stressed by peak resource theory, is that once global reserves are depleted by half, economic factors will drive resource prices high and unattainable by many (Cordell and White, 2013). Phosphorus does not have a substitute in biomass production. Unlike energy resources, we cannot look to other resources to mitigate our dependency upon phosphate rock (Gilbert, 2009). Phosphorus has potential to be recycled (Rittman, 2011). On a large scale, if agriculture gears itself to derive phosphorus fertilizer from recycled phosphorus we can avoid phosphorus resource scarcity. BACKGROUND Low levels of phosphorus in soils results in phosphorus deficiencies in crops which will grow poorly and can be diagnosed by observing leaves turning a blue-green color. Farmers apply phosphorus fertilizers to agricultural soils to mitigate crop growth limitation by phosphorus. Known global phosphate rock reserves are concentrated in just a handful of countries. Phosphate rock reserves that contain at least 8.5 x 1013 tons of phosphate rock are located in Morocco, China, Algeria, Syria, Jordan, South Africa, the United States and Russia (Jasinski, 2013). -
Capturing the Lost Phosphorus
Marquette University e-Publications@Marquette Civil and Environmental Engineering Faculty Civil, Construction, and Environmental Research and Publications Engineering, Department of 8-2011 Capturing the Lost Phosphorus Bruce E. Rittmann Arizona State University at the Tempe Campus Brooke Mayer Marquette University, [email protected] Paul Westerhoff Arizona State University at the Tempe Campus Mark Edwards Arizona State University at the Polytechnic Campus Follow this and additional works at: https://epublications.marquette.edu/civengin_fac Part of the Civil and Environmental Engineering Commons Recommended Citation Rittmann, Bruce E.; Mayer, Brooke; Westerhoff, Paul; and Edwards, Mark, "Capturing the Lost Phosphorus" (2011). Civil and Environmental Engineering Faculty Research and Publications. 34. https://epublications.marquette.edu/civengin_fac/34 Marquette University e-Publications@Marquette Civil, Construction and Environmental Engineering Faculty Research and Publications/College of Engineering This paper is NOT THE PUBLISHED VERSION; but the author’s final, peer-reviewed manuscript. The published version may be accessed by following the link in the citation below. Chemosphere, Vol. 84, No. 6 (August 2011): 846-853. DOI. This article is © Elsevier and permission has been granted for this version to appear in e-Publications@Marquette. Elsevier does not grant permission for this article to be further copied/distributed or hosted elsewhere without the express permission from Elsevier. Capturing the Lost Phosphorus Bruce E. Rittmann -
Peak Phosphorus
Peak Phosphorus A Potential Food Security Crisis TARIEL MÓRRÍGAN Global Climate Change, Human Security, and Democracy Global & International Studies University of California Social Sciences & Media Studies Building, Room 2006 Santa Barbara, CA 93106-7065 [email protected] ~ February 21, 2010 Peak Phosphorus “There are no substitutes for phosphorus in agriculture.” ~ United States Geological Survey, 2009 Summary • Phosphorus is an element necessary for all life . Phosphorus is one of the three major nutrients required for plant growth: nitrogen (N), phosphorus (P), and potassium (K). • Global phosphorus production most likely peaked in 1989 . If global phosphorus production has not yet peaked, it will likely do so by 2033. • The quality of remaining phosphate rock is decreasing and the production costs are increasing. • Global reserves will start to run out within 50–100 years . • Once phosphorus supplies are exhausted, phosphorus will need to be recovered and reused in order to avoid a massive global food security crisis . There are no substitutes for phosphorus in agriculture . • In 2007–2008, the price of phosphate rock increased dramatically worldwide due to increased agricultural demand and limited supplies of phosphate rock. The average U.S. price in 2008 was more than double that of 2007, and was four-times greater than that of 2004. Average spot prices from North Africa and other exporting regions increased more than five-times the average price in 2007. • Most of the world's farms do not have or do not receive adequate amounts of phosphorus . Feeding the world's increasing population will accelerate the rate of depletion of phosphate reserves. -
Missing Global Governance of a Critical Resource Preliminary Findings from 2 Years of Doctoral Research
Paper prepared for SENSE Earth Systems Governance, Amsterdam, 24th-31st August, 2008 The Story of Phosphorus: missing global governance of a critical resource Preliminary findings from 2 years of doctoral research Dana Cordell PhD Candidate [email protected] Institute for Sustainable Futures, University of Technology Sydney, Australia and Department of Water and Environmental Studies, Linköping University, Sweden Abstract Phosphorus is a critical resource for food production in the form of fertilizers, yet current global phosphate reserves could be depleted this century. More concerning is a global peak in phosphorus production – peak phosphorus – based on current official estimates of world resources, is estimated to occur around 2030, only decades after the likely peak in oil production. The situation for phosphorus is worse than for oil however, as there is no substitute for phosphorus in food production. Demand for phosphorus will increase over the next 50 years as the world population is projected to increase by 50% and with changing diets. While the exact timing of peak production might be disputed, it is widely known within the industry that the quality of remaining phosphate rock is decreasing, and costs are increasing. The price of phosphate rock has increased 700% in 14 months alone. Yet unlike water, energy and nitrogen, there is no international organisation which has taken on responsibility for the long-term stewardship or management of phosphorus resources for global food security. Institutional arrangements surrounding the global phosphorus cycle are fragmented and phosphorus sustainability is perceived quite differently by different stakeholders. In the absence of any deliberate international oversight, phosphorus resources are governed by the forces of the international market and national interest. -
From Waste to Plate: Examining the Role of Urban Biosolids in Recycling Phosphorus
FROM WASTE TO PLATE: EXAMINING THE ROLE OF URBAN BIOSOLIDS IN RECYCLING PHOSPHORUS A THESIS PRESENTED TO THE FACULTY OF ARCHITECTURE, PLANNING, AND PRESERVATION COLUMBIA, UNIVERSITY Submitted IN partial FULFILLMENT OF THE REQUIREMENT FOR THE DEGREE MASTER OF SCIENCE IN URBAN PLANNING MARLA WEINSTEIN May, 2013 ABSTRACT Phosphorus, a nutrient found in soil, is vital to plant life and therefore essential to our global food supply. Naturally recycled by ecosystem services, human cities have interrupted this cycle as phosphorus now accumulates in urban areas rather than returning to the land. In turn, we have turned to mined phosphates to supplement fertilizers and ensure our global food supply. As phosphorus deposits are a limited resource, however, we face future phosphorus shortages and threats to the security of our food supply. Biosolids, or treated waste, is a byproduct of our sewage treatment system and represent an opportunity for phosphorus recovery and recycling. This research (1) examines the role of biosolids in replenishing the natural phosphorus cycle and reducing our dependence on mined-phosphates by (2) examining the case study of NYC biosolid management in order to gain insight that can be extracted and applied to other global cities. Ultimately findings suggest biosolids can relink the natural cycle, framing biosolids as a resource, rather than a waste, for urban areas and recommend cities promote biosolid demand through contracting, land application siting, and investments in nutrient recovery technologies. ACKnowledgements A special thanks to: Professor Elliott Sclar, Thesis Advisor Professor Steve Cohen, Thesis Reader Michael, Nancy, & Bethany Weinstein Rebecca Kuss, Samantha Lazar, & Lorie Grushka EXECUTIVE SUMMARY 5 BACKGROUND 6 METHODOLOGY 13 FINDINGS 14 ANALYSIS 17 CONCLUSIONS 20 EXECUTIVE SUMMARY Simply stated, ecosystem services are the benefits we receive from healthy functioning ecosystems. -
URANIUM from PHOSPHATES in the UNITED ARAB REPUBLIC
URANIUM from PHOSPHATES in the UNITED ARAB REPUBLIC In response to a request from the UAR Govern Zabal) by the usual sulphuric acid process, with a ment, IAEA sent Professor B. V. Nevsky, a Soviet yieldof simple superphosphate (totalling up to 200 000 expert, to make an on-the-spot study of data on the tons a year), with a content of assimilated P90. of mining and processing of phosphates in the UAR and approximately 15-17 per cent. Imported pyrite is to examine the possibility of recovering uranium from the raw material used to produce sulphuric acid. the phosphate ores. In his report to the IAEA Director General, he has listed the following conclusions: Under the five year plan it is intended also to pro duce triple superphosphate, in quantities up to 100 000 1. The uranium content of run-of-the-mine phosphor tons by 1962-1963 (with a content of assimilated P2O5 ic ores in the United Arab Republic is very low and of approximately 45 - 48 per cent). This product will the recovery of uranium from them is therefore hardly be for export. The advantages of exporting triple likely to be an economic proposition. superphosphate are lower transport costs and the possibility of using lower-grade phosphorites. The 2. It is essential to press on with prospecting work method of producing triple superphosphate has not yet in order to discover richer uranic deposits and re been finally decided. If the "wet" method (with sul gions of phosphoritic ores. phuric acid) of producing the phosphoric acid needed to obtain triple superphosphate is used, the plant can 3. -
Phosphate Occurrence and Potential in the Region of Afghanistan, Including Parts of China, Iran, Pakistan, Tajikistan, Turkmenistan, and Uzbekistan
Phosphate Occurrence and Potential in the Region of Afghanistan, Including Parts of China, Iran, Pakistan, Tajikistan, Turkmenistan, and Uzbekistan By G.J. Orris, Pamela Dunlap, and John C. Wallis With a section on geophysics by Jeff Wynn Open-File Report 2015–1121 U.S. Department of the Interior U.S. Geological Survey U.S. Department of the Interior SALLY JEWELL, Secretary U.S. Geological Survey Suzette M. Kimball, Acting Director U.S. Geological Survey, Reston, Virginia: 2015 For more information on the USGS—the Federal source for science about the Earth, its natural and living resources, natural hazards, and the environment—visit http://www.usgs.gov or call 1–888–ASK–USGS For an overview of USGS information products, including maps, imagery, and publications, visit http://www.usgs.gov/pubprod To order this and other USGS information products, visit http://store.usgs.gov Suggested citation: Orris, G.J., Dunlap, Pamela, and Wallis, J.C., 2015, Phosphate occurrence and potential in the region of Afghanistan, including parts of China, Iran, Pakistan, Tajikistan, Turkmenistan, and Uzbekistan, with a section on geophysics by Jeff Wynn: U.S. Geological Survey Open-File Report 2015-1121, 70 p., http://dx.doi.org/10.3133/ofr20151121. Any use of trade, product, or firm names is for descriptive purposes only and does not imply endorsement by the U.S. Government. Although this report is in the public domain, permission must be secured from the individual copyright owners to reproduce any copyrighted material contained within this report. Contents -
The Current Peak Oil Crisis
PEAK ENERGY, CLIMATE CHANGE, AND THE COLLAPSE OF GLOBAL CIVILIZATION _______________________________________________________ The Current Peak Oil Crisis TARIEL MÓRRÍGAN PEAK E NERGY, C LIMATE C HANGE, AND THE COLLAPSE OF G LOBAL C IVILIZATION The Current Peak Oil Crisis TARIEL MÓRRÍGAN Global Climate Change, Human Security & Democracy Orfalea Center for Global & International Studies University of California, Santa Barbara www.global.ucsb.edu/climateproject ~ October 2010 Contact the author and editor of this publication at the following address: Tariel Mórrígan Global Climate Change, Human Security & Democracy Orfalea Center for Global & International Studies Department of Global & International Studies University of California, Santa Barbara Social Sciences & Media Studies Building, Room 2006 Mail Code 7068 Santa Barbara, CA 93106-7065 USA http://www.global.ucsb.edu/climateproject/ Suggested Citation: Mórrígan, Tariel (2010). Peak Energy, Climate Change, and the Collapse of Global Civilization: The Current Peak Oil Crisis . Global Climate Change, Human Security & Democracy, Orfalea Center for Global & International Studies, University of California, Santa Barbara. Tariel Mórrígan, October 2010 version 1.3 This publication is protected under the Creative Commons (CC) "Attribution-NonCommercial-ShareAlike 3.0 Unported" copyright. People are free to share (i.e, to copy, distribute and transmit this work) and to build upon and adapt this work – under the following conditions of attribution, non-commercial use, and share alike: Attribution (BY) : You must attribute the work in the manner specified by the author or licensor (but not in any way that suggests that they endorse you or your use of the work). Non-Commercial (NC) : You may not use this work for commercial purposes. -
Some Aspects of Phosphorus in Precambrian Sedimentation
ARKIV FÖR MINERALOGI OCH GEOLOGI Band 3 nr 9 Read 14 February 1962 Some aspects of phosphorus in Precamhrian sedimentation By PER GEIJER ABSTRACT The first appearance of phosphorite in sediments, at the time transitional between the Precam brian and the Cambrian, coincided with the first appearance of animals with hard parts containing calcium phosphate. At the same geological time a great change took place with regard to the phosphorus content of sedimentary iron ores, those of the Phanerozoic systems carrying normally about ten times more of this element than the Precambrian ones. Before, all during the Precam brian, the only possible sources of phosphorus in non-detrital sediments were abiotic precipitation and processes connected with the decay of the soft tissues of animals and plants. Together these sources were not adequate to produce any phosphorite deposit, or even, with extremely few excep tions, to leave more than insignificant marks in iron ores formed in an environment favourable also for phosphate deposition. With regard to abiotic precipitation, conditions must have been essentially the same in Phanerozoic sedimentation as they were during the Precambrian. The conclusion that, in the latter case, this source was of but little importance, therefore appears to be on the whole applicable also to the Phanerozoic. In the case of soft organic tissues as a source of phosphatic sediments, a similar conclusion seems justified when considering such forms of Iife as were in existence already at the time when the phosphorus-poor sediments of the Precambrian were deposited, but it is doubtful whether it may be extended also higher up on the evolutionary scale.