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Nazar Delegan | Curriculum Vitae 500 Rue Verdure – Brossard J4W1R3 – QC Canada

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Nazar Delegan | Curriculum Vitae 500 Rue Verdure – Brossard J4W1R3 – QC Canada Nazar Delegan | Curriculum Vitae 500 rue Verdure – Brossard J4W1R3 – QC Canada Æ +1 (514) 996 7665 • Q [email protected] ¯ www.linkedin.com/in/nazar-delegan Objective: Achieve a positive impact via innovative research and fruitful collaborations. Have fun doing it. Doctoral thesis Title: Codoped titanium dioxide thin-films for visible light fueled applications: fabrication, characterization, and optimization. Supervisor: Prof. My Ali El Khakani (INRS-EMT) Abstract: Radio-frequency magnetron sputtering was used to synthesize visible-light active nanoscale TiO2:N films. This introduction of NO species formed new VBM-straddling Eg states, lowering the effective optical-gap from 3.2 eV to values as low as 2.2 eV, while maintaining desired crystallinity. Un- fortunately, VO-defect density was seen to increase as a result of this, leading to decreased photocharge lifetimes. To remedy this, an acceptor-donor charge passivated TiO2:WN were developed and synthe- sized. The optimized codoped films were shown to have increased VO formation energies, improved photocharge lifetimes, and decreased lattice strain. The improvement of these properties directly re- sulted in TiO2:WN photoanodes showing a ∼300 % increase in 1.5AM-light driven electro-photocatalytic degradation rates of real-life pollutants when compared to pristene TiO2. Education Ph.D. in Materials and Energy 2014–2018 INRS - Energy, Materials, and Telecommunications, 4.3/4.3 Montreal Acceptor-donor defect passivated, visible-light active TiO2 for electro-photocatalytic applications. M.Sc. in Materials and Energy 2012–2014 INRS - Energy, Materials, and Telecommunications, 4.15/4.3 Montreal Development and optimisation of nitrogen doped TiO2 films for visible light fueled applications. B. Eng. of Engineering Physics 2008–2012 École Polytechnique de Montréal Montreal Minor: Technological Innovation Experience Vocational................................................................................................................. Ph.D. Researcher in Materials and Energy 2014–2018 INRS-EMT NanoMat Montreal Synthesis and characterization of novel semiconductor materials for visible light applications. Writing of scientific articles and presenting of findings at conferences. Research Intern 01/2012–05/2012 NanoMat (Prof. M.A. El Khakani) Varennes Semi-conductor/metal thin-film synthesis and characterisation. Engineering Intern 05/2010–09/2010 Institut National d’Optique Quebec Intern with the modeling and simulation group assigned to the development of a surface-to-stratosphere spectral interference modeling software in MatLab. Miscellaneous........................................................................................................... Tutor 2014–Present Succès Scolaire Montreal Mathematics, physics, and chemistry tutor for high-school, CEGEP, and university students. Accomplishments & Awards PBCSE scholarship for scientific stay abroad 2017 INRS-EMT & Okayama University Okayama, Japan INRS-CRSNG excellence scholarship for conference participation 2016 Institut National de la Recherche Scientifique - Énergie, Matériaux, et Télécommunications Best presentation award & prize 2015 Advanced Materials and Processes for Environment, Energy, and Health Québec City ”Matériaux photo-actifs à base de TiO2 pour des applications électro-photo-catalytiques.” Best presentation award & scholarship 2014 Plasma Quebec Montreal ”Déposition par pulvérisation-magnétron réactive de couches minces de TiO2 dopées in-situ à l’azote pour des applications électro-photo-catalytiques.” Best scientific poster award & scholarship 2013 Plasma Quebec Montreal ”Déposition, dopage in-situ et propriétés optoélectroniques de films de TiO2:N par unprocédé de pulvérisation magnétron réactive” Student ambassador of the INRS-EMT, with scholarship 2014–2016 Institut National de la Recherche Scientifique - Énergie, Matériaux, et Télécommunications Varennes Ambassador for recruitment and outreach programs representing the INRS. Student association president 2013–2015 Institut National de la Recherche Scientifique - Énergie, Matériaux, et Télécommunications Varennes Student association administrative council 2015–2018 Institut National de la Recherche Scientifique - Énergie, Matériaux, et Télécommunications Varennes Technical & Experimental skills Material deposition Material characterization + RF-Magnetron sputtering + X-ray/UV photoelectron spectroscopy + Pulsed laser deposition + X-ray diffraction + Thermal evaporation + UV-Vis. and fourier transform IR spectroscopy + Physical/chemical vapor deposition (general) + Spectroscopic ellipsometry + Photoluminescence spectroscopy + Scanning/Transmission electron microscopy + Raman spectroscopy + High-frequency dielectric spectroscopy + Time-resolved microwave conductivity + Atomic force and scanning tunneling microscopy Data acquisition and analysis....................................................................................... Hardware: Good operational knowledge and troubleshooting/repair capabilities of above mentionned set-ups, and others. Software: MatLab, OriginPro, LATEX, CasaXPS, Python, Excel (Office), etc. Laboratory environment: Experience working with hazardous materials, nanofabrication tools, clean- rooms, high-vaccum systems, electro-optical set-ups, etc. Languages................................................................................................................. English: Fluent French: Fluent Ukrainian: Fluent Russian: Good command Personal profile & Hobbies + Training and teaching of Brazilian Jiu-Jitsu; betterment trough a good challenge. + Intrinsically ’geeky’ with an innate fascination with science, space exploration, puzzles, and novel concepts. + Dissemination of science-based knowledge to varied audiences. Presentations & Posters 2017: “In-situ (W,N) co-doping of RF-sputtered TiO2 thin films for use as photoanodes for the electro- photocatalytic degradation of pollutants under sunlight.” Advanced in Functional Materials 2017, University of California, Los Angeles, USA. 2017: “Fabrication et codopage in-situ (W,N) des couches minces de TiO2 par pulvérisation magnétron pour la dégradation des polluants sous lumière visible.” Plasma Quebec 2017, Montreal, Canada. 2016: “Déposition de couches minces de TiO2:W,N par un procédé de co-pulvérisation-magnétron réactive pour le développement de photoanodes actives sous lumière visible.” Plasma Quebec 2016, Montreal, Canada. 2015: “Matériaux photo-actifs à base de TiO2 pour des applications électro-photo-catalytiques.” PAEES 2015, Québec City, Canada. 2015: “Matériaux photo-actifs à base de TiO2 pour des applications électro-photo-catalytiques.” Plasma Québec 2015, Montreal, Canada. 2014: “Déposition par pulvérisation-magnétron réactive de couches minces de TiO2 dopées in-situ à l’azote pour des applications électro-photo-catalytiques.” Plasma Québec 2014, Montreal, Canada. 2013: “Déposition, dopage in-situ et propriétés optoélectroniques de films de TiO2:N par unprocédé de pulvérisation magnétron réactive” Plasma Québec 2013, Montreal, Canada. Publications, GoogleScholar h-index : 9 N. Delegan, R. Pandiyan, S. Johnston, A. Dirany, S. Komtchou, P. Drogui, and M. A. El Khakani. Lifetime Enhancement of Visible Light Induced Photocharges in Tungsten and Nitrogen in-situ Codoped TiO2:WN Thin Films. The Journal of Physical Chemistry C, 122(10):5411–5419, mar 2018. N Delegan, R Pandiyan, S Komtchou, A Dirany, P Drogui, and M. A. El Khakani. In-situ co-doping of sputter-deposited TiO2:WN films for the development of photoanodes intended for visible-light electro-photocatalytic degradation of emerging pollutants. Journal of Applied Physics, 123(20):205101, may 2018. N. Delegan, R. Daghrir, P. Drogui, and M.A. El Khakani. Bandgap tailoring of in-situ nitrogen-doped TiO2 sputtered films intended for electrophotocatalytic applications under solar light. Journal of Applied Physics, 116(15):153510, oct 2014. R. Pandiyan, N. Delegan, A. Dirany, P. Drogui, and M.A. El Khakani. Probing the Electronic Surface Properties and Bandgap Narrowing of in situ N, W, and (W,N) Doped Magnetron-Sputtered TiO2 Films Intended for Electro-Photocatalytic Applications. The Journal of Physical Chemistry C, 120(1):631–638, jan 2016. R. Pandiyan, N. Delegan, A. Dirany, P. Drogui, and M.A. El Khakani. Correlation of sp2 carbon bonds content in magnetron-sputtered amorphous carbon films to their electrochemical H2O2 production for water decontamination applications. Carbon, 94:988–995, nov 2015. B.A. Gonfa, M.R. Kim, N. Delegan, A.C. Tavares, R. Izquierdo, N. Wu, M.A. El Khakani, and D. Ma. Towards high efficiency air-processed near-infrared responsive photovoltaics: bulk heterojunction solar cells based on PbS/CdS core–shell quantum dots and TiO2 nanorod arrays. Nanoscale, 7(22):10039–10049, 2015. L.-A. Gautier, V. Le Borgne, N. Delegan, R. Pandiyan, and M.A. El Khakani. Field electron emission enhancement of graphenated MWCNTs emitters following their decoration with Au nanoparticles by a pulsed laser ablation process. Nanotechnology, 26(4):045706, jan 2015. S. Komtchou, A. Dirany, P.Drogui, N. Delegan, M.A. El Khakani, D. Robert, and P.Lafrance. Degradation of atrazine in aqueous solution with electrophotocatalytic process using TiO2−x photoanode. Chemosphere, 157:79–88, aug 2016. R. Daghrir, P. Drogui, N. Delegan, and M.A. El Khakani. Removal of chlortetracycline from spiked municipal wastewater using a photoelectrocatalytic process operated under sunlight irradiations. The Science of the total environment, 466-467:300–5, jan 2014. R. Daghrir, P. Drogui, J. Tshibangu, N. Delegan, and M.A. El Khakani. Electrochemical treatment of domestic wastewater using boron-doped diamond and nanostructured amorphous carbon electrodes. Environmental Science and Pollution Research, 21(10):6578–6589, may 2014. R. Daghrir, P.Drogui, N. Delegan, and M.A. El Khakani. Electrochemical degradation of chlortetracycline using N-doped Ti/TiO2 photoanode under sunlight irradiations. Water Research, 47(17):6801–6810, nov 2013..
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