Water Quality Monitoring Data for Pesticides on Long Island, Ny
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2,4-Dichlorophenoxyacetic Acid
2,4-Dichlorophenoxyacetic acid 2,4-Dichlorophenoxyacetic acid IUPAC (2,4-dichlorophenoxy)acetic acid name 2,4-D Other hedonal names trinoxol Identifiers CAS [94-75-7] number SMILES OC(COC1=CC=C(Cl)C=C1Cl)=O ChemSpider 1441 ID Properties Molecular C H Cl O formula 8 6 2 3 Molar mass 221.04 g mol−1 Appearance white to yellow powder Melting point 140.5 °C (413.5 K) Boiling 160 °C (0.4 mm Hg) point Solubility in 900 mg/L (25 °C) water Related compounds Related 2,4,5-T, Dichlorprop compounds Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) 2,4-Dichlorophenoxyacetic acid (2,4-D) is a common systemic herbicide used in the control of broadleaf weeds. It is the most widely used herbicide in the world, and the third most commonly used in North America.[1] 2,4-D is also an important synthetic auxin, often used in laboratories for plant research and as a supplement in plant cell culture media such as MS medium. History 2,4-D was developed during World War II by a British team at Rothamsted Experimental Station, under the leadership of Judah Hirsch Quastel, aiming to increase crop yields for a nation at war.[citation needed] When it was commercially released in 1946, it became the first successful selective herbicide and allowed for greatly enhanced weed control in wheat, maize (corn), rice, and similar cereal grass crop, because it only kills dicots, leaving behind monocots. Mechanism of herbicide action 2,4-D is a synthetic auxin, which is a class of plant growth regulators. -
July 6, 2020 OPP Docket Environmental Protection Agency Docket Center (EPA/DC), (28221T) 1200 Pennsylvania Ave. NW Washington
July 6, 2020 OPP Docket Environmental Protection Agency Docket Center (EPA/DC), (28221T) 1200 Pennsylvania Ave. NW Washington, DC 20460-000 Docket ID # EPA-HQ-OPP-2014-0167 Re. Clopyralid, Case Number 7212 Dear Madam/Sir: These comments are submitted on behalf of Beyond Pesticides, Beyond Toxics, Center for Food Safety, Hawai’i Alliance for Progressive Action, Hawai'i SEED, LEAD for Pollinators, Maine Organic Farmers and Gardeners Association, Maryland Pesticide Education Network, Northeast Organic Farming Association—Massachusetts Chapter, Northwest Center for Alternatives to Pesticides, People and Pollinators Action Network, Real Organic Project, Sierra Club, Toxic Free NC, Women’s Voices for the Earth. Founded in 1981 as a national, grassroots, membership organization that represents community-based organizations and a range of people seeking to bridge the interests of consumers, farmers and farmworkers, Beyond Pesticides advances improved protections from pesticides and alternative pest management strategies that reduce or eliminate a reliance on pesticides. Our membership and network span the 50 states and the world. EPA’s proposed interim decision (PID) on the weed killer clopyralid is inadequate to protect property, nontarget plants, and pollinators from exposure to the chemical. Clopyralid poses unreasonable adverse effects that cannot be remedied by EPA’s proposed fixes. It should not be reregistered. Clopyralid has a long history of causing environmental and property damage through drift, runoff, use of treated plant material (such as straw or grass clippings) for mulch or compost, contaminated irrigation water, and urine or manure from animals consuming treated vegetation. Clopyralid (3,6-dichloro-2-pyridinecarboxylic acid) is an herbicide used to control broadleaf weeds on nonresidential lawns and turf, range, pastures, right-of ways and on several crops. -
U.S. EPA, Pesticide Product Label, CLOPYRALID MEA+2,4-D, 07/07/2008
'f-;) 7 S-O - 'ta- \ ENVIRONMENTAL PROTECTION u.s. EPA Reg, Nwnber: Date of Issuance: AGENCY Office of Pesticide Programs 42750-92 Registration Division (7505P) -- 7 JtJL 2DOB Ariel Rios, Building 1200 Pennsylvania Ave., NW Washington, D.C, 20460 NOTICE OF PESTICIDE: Term of Issuance: _ Registration -X Reregistration Name of Pesticide Product: (under FIFRA, as amended) Clopyralid MEA+ 2,4- D Name and Address of Registrant (include ZIP Code): Albaugh, Inc. 121 NE 18th Street Ankeny, IA 50021 N o~e: C.h~nge,~itiIflb~ljllgl,~i:t1~1i~~J9~~~1?~!iUiC~,fJqnf.th~i.:~G~~t~4j#'qqHriet£i~riw,ii4;tl}is, :' ',' ,,',: " registratio"n ~4stl>e ,s~Drriittedto,aPQjl,~9:~pt~qby 'theRe,gi~ttatipn pivisi()i1 prior t9 ':tI~.~"Qn~~)*~eI , ,~:~~~~r:::~.~:;~~:1~~jJ:r~,2t.edf.~,~.&.~~lt;'~I~\~i,~tfl%~~~i;m)~t~~:;'~~/~~·?~~:,)~·¥'t·.'~~~i,~j~:~:i)~.:,;" ,.".;,' "' On the basis of information furnished by the registrant, the above named pesticide is hereby registered/reregistered under the Federal Insecticide, Fungicide and Rodenticide Act. Registration is in no way to be construed as an endorsement or recommendation of this product by the Agency. In order to protect health and the environment, the Administrator, on his motion, may at any time suspend or cancel the registration of a pesticide in accordance with the Act. The acceptance of any name in connection with the registration of a product under this Act is not to be construed as giving the registrant a right to exclusive use of the name or to its use ifit has been covered by others. This product is reregistered in accordance with FIFRA sec. -
Response of Multiple Herbicide Resistant Strain of Diazotrophic Cyanobacterium, Anabaena Variabilis , Exposed to Atrazine and DCMU
Indian Journal of Experimental Biology Vol. 49, April 2011, pp.298-303 Response of multiple herbicide resistant strain of diazotrophic cyanobacterium, Anabaena variabilis , exposed to atrazine and DCMU Surendra Singh, Pallavi Datta * & Archna Tirkey Algal Biotechnology Laboratory, Department of Biological Sciences, Rani Durgavati University, Jabalpur 482 001, India Received 1 June 2010; revised 24 January 2011 Effect of two photosynthetic inhibitor herbicides, atrazine (both purified and formulated) and [3-(3,4-dichlorophenyl)- 1,1-dimethyl urea] (DCMU), on the growth, macromolecular contents, heterocyst frequency, photosynthetic O 2 evolution and dark O 2 uptake of wild type and multiple herbicide resistant (MHR) strain of diazotrophic cyanobacterium A. variabilis was studied. Cyanobacterial strains showed gradual inhibition in growth with increasing dosage of herbicides. Both wild type and MHR strain tolerated < 6.0 mg L -1 of atrazine (purified), < 2.0 mg L -1 of atrazine (formulated) and < 0.4 mg L -1 of DCMU indicating similar level of herbicide tolerance. Atrazine (pure) (8.0 mg L -1) and 4.0 mg L -1 of atrazine (formulated) were growth inhibitory concentrations (lethal) for both wild type and MHR strain indicating formulated atrazine was more toxic than the purified form. Comparatively lower concentrations of DCMU were found to be lethal for wild type and MHR strain, respectively. Thus, between the two herbicides tested DCMU was more growth toxic than atrazine. At sublethal dosages of herbicides, photosynthetic O 2 evolution showed highest inhibition followed by chlorophyll a, phycobhiliproteins and heterocyst differentiation as compared to carotenoid, protein and respiratory O 2 uptake. Keyword s: Atrazine, Cyanobacteria, DCMU, Herbicides, Mutants, Photosynthesis In modern agriculture weed control by herbicides is a tolerate or resist toxic actions of various rice field common practice to increase in crop productivity 1. -
Corn and Soybean Mode of Action Herbicide Chart
By Premix Corn and Soybean This chart lists premix herbicides alphabetically by their trade names so you can identify the premix’s component herbicides and their respective site of action groups. Refer Herbicide Chart to the Mode of Action chart for more information. Component Repeated use of herbicides with the same Site of Premix Trade Active Action site of action can result in the development of Trade Name ® Name ® Ingredient Group* herbicide-resistant weed populations. Authority First ............... Spartan sulfentrazone 14 FirstRate cloransulam 2 Axiom ........................... Define flufenacet 15 This publication was designed for commercial printing, color shifts may occur on other printers and on-screeen. Sencor metribuzin 5 Basis . ........................... Resolve rimsulfuron 2 Harmony GT thifensulfuron 2 By Mode of Action (effect on plant growth) Bicep II Magnum .......... Dual II Magnum s-metolachlor 15 AAtrex atrazine 5 This chart groups herbicides by their modes of action to assist Bicep Lite II Magnum .... Dual II Magnum s-metolachlor 15 AAtrex atrazine 5 you in selecting herbicides 1) to maintain greater diversity in Boundary ...................... Dual Magnum s-metolachlor 15 herbicide use and 2) to rotate among herbicides with different Sencor metribuzin 5 Breakfree ATZ ............... Breakfree acetochlor 15 sites of action to delay the development of herbicide resistance. atrazine atrazine 5 Breakfree ATZ Lite ........ Breakfree acetochlor 15 Number of atrazine atrazine 5 resistant weed Buctril + Atrazine ......... Buctril bromoxynil 6 atrazine atrazine 5 species in U.S. Bullet ............................ Micro-Tech alachlor 15 Site of Chemical Active atrazine atrazine 5 Action Product Examples Camix ........................... Callisto mesotrione 28 Group* Site of Action Family Ingredient (Trade Name ®) Dual II Magnum s-metolachlor 15 Lipid Canopy DF .................. -
Herbicide Mode of Action Table High Resistance Risk
Herbicide Mode of Action Table High resistance risk Chemical family Active constituent (first registered trade name) GROUP 1 Inhibition of acetyl co-enzyme A carboxylase (ACC’ase inhibitors) clodinafop (Topik®), cyhalofop (Agixa®*, Barnstorm®), diclofop (Cheetah® Gold* Decision®*, Hoegrass®), Aryloxyphenoxy- fenoxaprop (Cheetah®, Gold*, Wildcat®), fluazifop propionates (FOPs) (Fusilade®), haloxyfop (Verdict®), propaquizafop (Shogun®), quizalofop (Targa®) Cyclohexanediones (DIMs) butroxydim (Factor®*), clethodim (Select®), profoxydim (Aura®), sethoxydim (Cheetah® Gold*, Decision®*), tralkoxydim (Achieve®) Phenylpyrazoles (DENs) pinoxaden (Axial®) GROUP 2 Inhibition of acetolactate synthase (ALS inhibitors), acetohydroxyacid synthase (AHAS) Imidazolinones (IMIs) imazamox (Intervix®*, Raptor®), imazapic (Bobcat I-Maxx®*, Flame®, Midas®*, OnDuty®*), imazapyr (Arsenal Xpress®*, Intervix®*, Lightning®*, Midas®* OnDuty®*), imazethapyr (Lightning®*, Spinnaker®) Pyrimidinyl–thio- bispyribac (Nominee®), pyrithiobac (Staple®) benzoates Sulfonylureas (SUs) azimsulfuron (Gulliver®), bensulfuron (Londax®), chlorsulfuron (Glean®), ethoxysulfuron (Hero®), foramsulfuron (Tribute®), halosulfuron (Sempra®), iodosulfuron (Hussar®), mesosulfuron (Atlantis®), metsulfuron (Ally®, Harmony®* M, Stinger®*, Trounce®*, Ultimate Brushweed®* Herbicide), prosulfuron (Casper®*), rimsulfuron (Titus®), sulfometuron (Oust®, Eucmix Pre Plant®*, Trimac Plus®*), sulfosulfuron (Monza®), thifensulfuron (Harmony®* M), triasulfuron (Logran®, Logran® B-Power®*), tribenuron (Express®), -
Greenhouse and Field Evaluation of Isoxaflutole for Weed Control In
www.nature.com/scientificreports OPEN Greenhouse and field evaluation of isoxaflutole for weed control in maize in China Received: 27 June 2017 Ning Zhao, Lan Zuo, Wei Li, Wenlei Guo, Weitang Liu & Jinxin Wang Accepted: 18 September 2017 Greenhouse and field studies were conducted to provide a reference for pre-emergence (PRE) Published: xx xx xxxx application of isoxaflutole on maize in China. In greenhouse study, the isoxaflutole PRE application at 30 g active ingredient (a.i.) ha−1 could effectively control large numbers of weeds, especially some large-seeded broadleaves, tested in this study. The tolerance results indicated 21 maize hybrids showed different responses to isoxaflutole under greenhouse conditions. In 2015 and 2016, field experiments were conducted to determine and compare the weed control efficacy and safety to Zhengdan 958 maize with 6 herbicide treatments. In both years, isoxaflutole PRE at 100 to 250 g a.i. ha−1 was sufficient to provide satisfactory full-season control of the dominant common broadleaf and grass weeds in the field. Temporary injury to maize was observed with isoxaflutole treatments of 125, 150, and 250 g a.i. ha−1 in both years, but plants recovered within 4 to 6 wk. To maximize maize yield and provide satisfactory weed control, a range of 100 to 150 g a.i. ha−1 of isoxaflutole is recommended, depending on the soil characteristics, weather, and weed species present at the experimental site. Based on the results, isoxaflutole PRE has good potential for weed control in maize in China. Maize was planted on more hectares than any other crops in China from 2010 to 2014, with an average of 35 million ha planted per year and yield averaging 5,779 kg per ha per year1. -
Exposure to Herbicides in House Dust and Risk of Childhood Acute Lymphoblastic Leukemia
Journal of Exposure Science and Environmental Epidemiology (2013) 23, 363–370 & 2013 Nature America, Inc. All rights reserved 1559-0631/13 www.nature.com/jes ORIGINAL ARTICLE Exposure to herbicides in house dust and risk of childhood acute lymphoblastic leukemia Catherine Metayer1, Joanne S. Colt2, Patricia A. Buffler1, Helen D. Reed3, Steve Selvin1, Vonda Crouse4 and Mary H. Ward2 We examine the association between exposure to herbicides and childhood acute lymphoblastic leukemia (ALL). Dust samples were collected from homes of 269 ALL cases and 333 healthy controls (o8 years of age at diagnosis/reference date and residing in same home since diagnosis/reference date) in California, using a high-volume surface sampler or household vacuum bags. Amounts of agricultural or professional herbicides (alachlor, metolachlor, bromoxynil, bromoxynil octanoate, pebulate, butylate, prometryn, simazine, ethalfluralin, and pendimethalin) and residential herbicides (cyanazine, trifluralin, 2-methyl-4- chlorophenoxyacetic acid (MCPA), mecoprop, 2,4-dichlorophenoxyacetic acid (2,4-D), chlorthal, and dicamba) were measured. Odds ratios (OR) and 95% confidence intervals (CI) were estimated by logistic regression. Models included the herbicide of interest, age, sex, race/ethnicity, household income, year and season of dust sampling, neighborhood type, and residence type. The risk of childhood ALL was associated with dust levels of chlorthal; compared to homes with no detections, ORs for the first, second, and third tertiles were 1.49 (95% CI: 0.82–2.72), 1.49 (95% CI: 0.83–2.67), and 1.57 (95% CI: 0.90–2.73), respectively (P-value for linear trend ¼ 0.05). The magnitude of this association appeared to be higher in the presence of alachlor. -
40 CFR Ch. I (7–1–18 Edition) § 455.61
§ 455.61 40 CFR Ch. I (7–1–18 Edition) from: the operation of employee show- § 455.64 Effluent limitations guidelines ers and laundry facilities; the testing representing the degree of effluent of fire protection equipment; the test- reduction attainable by the applica- ing and emergency operation of safety tion of the best available tech- showers and eye washes; or storm nology economically achievable water. (BAT). (d) The provisions of this subpart do Except as provided in 40 CFR 125.30 not apply to wastewater discharges through 125.32, any existing point from the repackaging of microorga- source subject to this subpart must nisms or Group 1 Mixtures, as defined achieve effluent limitations rep- under § 455.10, or non-agricultural pes- resenting the degree of effluent reduc- ticide products. tion attainable by the application of the best available technology economi- § 455.61 Special definitions. cally achievable: There shall be no dis- Process wastewater, for this subpart, charge of process wastewater pollut- means all wastewater except for sani- ants. tary water and those wastewaters ex- § 455.65 New source performance cluded from the applicability of the standards (NSPS). rule in § 455.60. Any new source subject to this sub- § 455.62 Effluent limitations guidelines part which discharges process waste- representing the degree of effluent water pollutants must meet the fol- reduction attainable by the applica- lowing standards: There shall be no dis- tion of the best practicable pollut- charge of process wastewater pollut- ant control technology (BPT). ants. Except as provided in 40 CFR 125.30 through 125.32, any existing point § 455.66 Pretreatment standards for existing sources (PSES). -
Reduction of Nitroaromatic Pesticides with Zero-Valent Iron
Chemosphere 54 (2004) 255–263 www.elsevier.com/locate/chemosphere Reduction of nitroaromatic pesticides with zero-valent iron Young-Soo Keum, Qing X. Li * Department of Molecular Biosciences and Bioengineering, University of Hawaii, 1955 East-West Road, Ag Sci 218, Honolulu, HI 96822, USA Received 5 February 2003; received in revised form 4 June 2003; accepted 4 August 2003 Abstract Reduction of eleven nitroaromatic pesticides was studied with zero-valent iron powder. Average half-lives ranged from 2.8 to 6.3 h and the parent compounds were completely reduced after 48–96 h. The di-nitro groups of the 2,6- dinitroaniline herbicides were rapidly reduced to the corresponding diamines, with a negligible amount of partially reduced monoamino or nitroso products. Low levels of de-alkylated products were observed after 10 days. The nitro group of the organophosphorus insecticides was reduced dominantly to the monoamines but in a slower rate than the 2,6-dinitroanilines. A trace amount of oxon products was found. Reduction of nitro to amino was also the predominant reaction for the diphenyl ether herbicides. Aromatic de-chlorination and de-alkylation were minor reactions. These amine products were more stable than the parent compounds and 60% or more of the amines were detected after two weeks. Humic acid decreased the reduction rates of pendimethalin, and dichlone (a known quinone redox mediator) counteracted the effect of humic acid on the reactivity. Storage of iron powder under air decreased the reactivity very rapidly due to iron oxidation. Repeated use of iron powder also showed similar results. The reduced activity of air- oxidized iron was recovered by purging with hydrogen, but not nitrogen. -
U.S. Geological Survey National Water-Quality Assessment Program
U.S. Geological Survey National Water-Quality Assessment Program Stream water-quality analytes Major ions and trace elementsschedule 998 (20 constituents) Pesticides schedule 2437 (229 compounds) Alkalinity 1H1,2,4Triazole Arsenic 2,3,3Trichloro2propene1sulfonic acid (TCPSA) Boron 2,4D Calcium 2(1Hydroxyethyl)6methylaniline Chloride 2[(2Ethyl6methylphenyl)amino]1propanol Fluoride 2AminoNisopropylbenzamide Iron 2Aminobenzimidazole Lithium 2Chloro2',6'diethylacetanilide 2Chloro4,6diaminostriazine {CAAT} Magnesium (Didealkylatrazine) pH 2Chloro4isopropylamino6aminostriazine Potassium 2Chloro6ethylamino4aminostriazine {CEAT} Total dissolved solids 2ChloroN(2ethyl6methylphenyl)acetamide Selenium 2Hydroxy4isopropylamino6aminostriazine 2Hydroxy4isopropylamino6ethylaminostriazin Silica e {OIET} Sodium 2Hydroxy6ethylamino4aminostriazine Specific conductance 2Isopropyl6methyl4pyrimidinol Strontium 3,4Dichlorophenylurea Sulfate 3Hydroxycarbofuran Turbidity 3Phenoxybenzoic acid Vanadium 4(Hydroxymethyl)pendimethalin 4Chlorobenzylmethyl sulfoxide Suspended sediment 4Hydroxy molinate 4Hydroxychlorothalonil Nutrientsschedule 2430 (18 constituents) 4Hydroxyhexazinone A Inorganic carbon, suspended Acephate Dissolved inorganic carbon Acetochlor ammonia + organic nitrogen (unfilteredKjeldahl) Acetochlor oxanilic acid ammonia + organic nitrogen (filteredKjeldahl) Acetochlor sulfonic acid Ammonia as N, filtered Acetochlor sulfynilacetic acid nitrite, filtered Alachlor -
PUBLIC WATER SUPPLY SAMPLING PLAN for Contaminants with a Vermont Health Advisory – May 2020
PROPOSED PUBLIC WATER SUPPLY SAMPLING PLAN For Contaminants with a Vermont Health Advisory – May 2020 Vermont Department of Environmental Conservation Drinking Water & Groundwater Protection Division A Plan to Sample for Chemicals with a Vermont Health Advisory As required by Act 21 (2019), Section 10(b), the Secretary of the Agency of Natural Resources, on or before January 1, 2020, must publish for public review and comment a plan to collect data for contaminants in drinking water from public community water systems and all non-transient non-community water systems, for which a health advisory has been established, but no Maximum Contaminant Level has been adopted. These health advisories are referred to as Vermont Health Advisories (VHAs) in this document. 1 | P a g e TABLE OF CONTENTS I. Executive Summary …………………………………………………………………………………………..Page 3 II. Background ……………………………………………………………………………………………………… Page 4 III. Determining the VHA contaminants for sampling at public water systems ………..Page 6 IV. Sampling Considerations …..…………………………………………………………………………….. Page 10 V. Proposed Sampling Plan ………………………………………………………………………….………..Page 12 Attachments Table 1 Complete List of Vermont Health Advisories (VHAs) …………………………………………..Page 13 Table 2 Proposed List of VHAs with Potential Concern ……………………………………………………Page 18 2 | P a g e I. Executive Summary The Secretary of the Agency of Natural Resources was tasked with developing a sampling plan for public review, for certain drinking water contaminants that have an established health advisory, also known as the Vermont Health Advisory (VHA) but have no Maximum Contaminant Level (MCL). This Sampling Plan (Plan) is targeted to public community and public non- transient non-community water systems. To provide context for public water system regulation, and standards that apply, a discussion of how VHAs and MCLs are determined is given.