Chapter 3 Feynman Path Integral
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Unit 1 Old Quantum Theory
UNIT 1 OLD QUANTUM THEORY Structure Introduction Objectives li;,:overy of Sub-atomic Particles Earlier Atom Models Light as clectromagnetic Wave Failures of Classical Physics Black Body Radiation '1 Heat Capacity Variation Photoelectric Effect Atomic Spectra Planck's Quantum Theory, Black Body ~diation. and Heat Capacity Variation Einstein's Theory of Photoelectric Effect Bohr Atom Model Calculation of Radius of Orbits Energy of an Electron in an Orbit Atomic Spectra and Bohr's Theory Critical Analysis of Bohr's Theory Refinements in the Atomic Spectra The61-y Summary Terminal Questions Answers 1.1 INTRODUCTION The ideas of classical mechanics developed by Galileo, Kepler and Newton, when applied to atomic and molecular systems were found to be inadequate. Need was felt for a theory to describe, correlate and predict the behaviour of the sub-atomic particles. The quantum theory, proposed by Max Planck and applied by Einstein and Bohr to explain different aspects of behaviour of matter, is an important milestone in the formulation of the modern concept of atom. In this unit, we will study how black body radiation, heat capacity variation, photoelectric effect and atomic spectra of hydrogen can be explained on the basis of theories proposed by Max Planck, Einstein and Bohr. They based their theories on the postulate that all interactions between matter and radiation occur in terms of definite packets of energy, known as quanta. Their ideas, when extended further, led to the evolution of wave mechanics, which shows the dual nature of matter -
Quantum Theory of the Hydrogen Atom
Quantum Theory of the Hydrogen Atom Chemistry 35 Fall 2000 Balmer and the Hydrogen Spectrum n 1885: Johann Balmer, a Swiss schoolteacher, empirically deduced a formula which predicted the wavelengths of emission for Hydrogen: l (in Å) = 3645.6 x n2 for n = 3, 4, 5, 6 n2 -4 •Predicts the wavelengths of the 4 visible emission lines from Hydrogen (which are called the Balmer Series) •Implies that there is some underlying order in the atom that results in this deceptively simple equation. 2 1 The Bohr Atom n 1913: Niels Bohr uses quantum theory to explain the origin of the line spectrum of hydrogen 1. The electron in a hydrogen atom can exist only in discrete orbits 2. The orbits are circular paths about the nucleus at varying radii 3. Each orbit corresponds to a particular energy 4. Orbit energies increase with increasing radii 5. The lowest energy orbit is called the ground state 6. After absorbing energy, the e- jumps to a higher energy orbit (an excited state) 7. When the e- drops down to a lower energy orbit, the energy lost can be given off as a quantum of light 8. The energy of the photon emitted is equal to the difference in energies of the two orbits involved 3 Mohr Bohr n Mathematically, Bohr equated the two forces acting on the orbiting electron: coulombic attraction = centrifugal accelleration 2 2 2 -(Z/4peo)(e /r ) = m(v /r) n Rearranging and making the wild assumption: mvr = n(h/2p) n e- angular momentum can only have certain quantified values in whole multiples of h/2p 4 2 Hydrogen Energy Levels n Based on this model, Bohr arrived at a simple equation to calculate the electron energy levels in hydrogen: 2 En = -RH(1/n ) for n = 1, 2, 3, 4, . -
Vibrational Quantum Number
Fundamentals in Biophotonics Quantum nature of atoms, molecules – matter Aleksandra Radenovic [email protected] EPFL – Ecole Polytechnique Federale de Lausanne Bioengineering Institute IBI 26. 03. 2018. Quantum numbers •The four quantum numbers-are discrete sets of integers or half- integers. –n: Principal quantum number-The first describes the electron shell, or energy level, of an atom –ℓ : Orbital angular momentum quantum number-as the angular quantum number or orbital quantum number) describes the subshell, and gives the magnitude of the orbital angular momentum through the relation Ll2 ( 1) –mℓ:Magnetic (azimuthal) quantum number (refers, to the direction of the angular momentum vector. The magnetic quantum number m does not affect the electron's energy, but it does affect the probability cloud)- magnetic quantum number determines the energy shift of an atomic orbital due to an external magnetic field-Zeeman effect -s spin- intrinsic angular momentum Spin "up" and "down" allows two electrons for each set of spatial quantum numbers. The restrictions for the quantum numbers: – n = 1, 2, 3, 4, . – ℓ = 0, 1, 2, 3, . , n − 1 – mℓ = − ℓ, − ℓ + 1, . , 0, 1, . , ℓ − 1, ℓ – –Equivalently: n > 0 The energy levels are: ℓ < n |m | ≤ ℓ ℓ E E 0 n n2 Stern-Gerlach experiment If the particles were classical spinning objects, one would expect the distribution of their spin angular momentum vectors to be random and continuous. Each particle would be deflected by a different amount, producing some density distribution on the detector screen. Instead, the particles passing through the Stern–Gerlach apparatus are deflected either up or down by a specific amount. -
The Union of Quantum Field Theory and Non-Equilibrium Thermodynamics
The Union of Quantum Field Theory and Non-equilibrium Thermodynamics Thesis by Anthony Bartolotta In Partial Fulfillment of the Requirements for the degree of Doctor of Philosophy CALIFORNIA INSTITUTE OF TECHNOLOGY Pasadena, California 2018 Defended May 24, 2018 ii c 2018 Anthony Bartolotta ORCID: 0000-0003-4971-9545 All rights reserved iii Acknowledgments My time as a graduate student at Caltech has been a journey for me, both professionally and personally. This journey would not have been possible without the support of many individuals. First, I would like to thank my advisors, Sean Carroll and Mark Wise. Without their support, this thesis would not have been written. Despite entering Caltech with weaker technical skills than many of my fellow graduate students, Mark took me on as a student and gave me my first project. Mark also granted me the freedom to pursue my own interests, which proved instrumental in my decision to work on non-equilibrium thermodynamics. I am deeply grateful for being provided this priviledge and for his con- tinued input on my research direction. Sean has been an incredibly effective research advisor, despite being a newcomer to the field of non-equilibrium thermodynamics. Sean was the organizing force behind our first paper on this topic and connected me with other scientists in the broader community; at every step Sean has tried to smoothly transition me from the world of particle physics to that of non-equilibrium thermody- namics. My research would not have been nearly as fruitful without his support. I would also like to thank the other two members of my thesis and candidacy com- mittees, John Preskill and Keith Schwab. -
Lecture 3: Particle in a 1D Box
Lecture 3: Particle in a 1D Box First we will consider a free particle moving in 1D so V (x) = 0. The TDSE now reads ~2 d2ψ(x) = Eψ(x) −2m dx2 which is solved by the function ψ = Aeikx where √2mE k = ± ~ A general solution of this equation is ψ(x) = Aeikx + Be−ikx where A and B are arbitrary constants. It can also be written in terms of sines and cosines as ψ(x) = C sin(kx) + D cos(kx) The constants appearing in the solution are determined by the boundary conditions. For a free particle that can be anywhere, there is no boundary conditions, so k and thus E = ~2k2/2m can take any values. The solution of the form eikx corresponds to a wave travelling in the +x direction and similarly e−ikx corresponds to a wave travelling in the -x direction. These are eigenfunctions of the momentum operator. Since the particle is free, it is equally likely to be anywhere so ψ∗(x)ψ(x) is independent of x. Incidently, it cannot be normalized because the particle can be found anywhere with equal probability. 1 Now, let us confine the particle to a region between x = 0 and x = L. To do this, we choose our interaction potential V (x) as follows V (x) = 0 for 0 x L ≤ ≤ = otherwise ∞ It is always a good idea to plot the potential energy, when it is a function of a single variable, as shown in Fig.1. The TISE is now given by V(x) V=infinity V=0 V=infinity x 0 L ~2 d2ψ(x) + V (x)ψ(x) = Eψ(x) −2m dx2 First consider the region outside the box where V (x) = . -
The Quantum Mechanical Model of the Atom
The Quantum Mechanical Model of the Atom Quantum Numbers In order to describe the probable location of electrons, they are assigned four numbers called quantum numbers. The quantum numbers of an electron are kind of like the electron’s “address”. No two electrons can be described by the exact same four quantum numbers. This is called The Pauli Exclusion Principle. • Principle quantum number: The principle quantum number describes which orbit the electron is in and therefore how much energy the electron has. - it is symbolized by the letter n. - positive whole numbers are assigned (not including 0): n=1, n=2, n=3 , etc - the higher the number, the further the orbit from the nucleus - the higher the number, the more energy the electron has (this is sort of like Bohr’s energy levels) - the orbits (energy levels) are also called shells • Angular momentum (azimuthal) quantum number: The azimuthal quantum number describes the sublevels (subshells) that occur in each of the levels (shells) described above. - it is symbolized by the letter l - positive whole number values including 0 are assigned: l = 0, l = 1, l = 2, etc. - each number represents the shape of a subshell: l = 0, represents an s subshell l = 1, represents a p subshell l = 2, represents a d subshell l = 3, represents an f subshell - the higher the number, the more complex the shape of the subshell. The picture below shows the shape of the s and p subshells: (notice the electron clouds) • Magnetic quantum number: All of the subshells described above (except s) have more than one orientation. -
Path Integral and Asset Pricing
Path Integral and Asset Pricing Zura Kakushadze§†1 § Quantigicr Solutions LLC 1127 High Ridge Road #135, Stamford, CT 06905 2 † Free University of Tbilisi, Business School & School of Physics 240, David Agmashenebeli Alley, Tbilisi, 0159, Georgia (October 6, 2014; revised: February 20, 2015) Abstract We give a pragmatic/pedagogical discussion of using Euclidean path in- tegral in asset pricing. We then illustrate the path integral approach on short-rate models. By understanding the change of path integral measure in the Vasicek/Hull-White model, we can apply the same techniques to “less- tractable” models such as the Black-Karasinski model. We give explicit for- mulas for computing the bond pricing function in such models in the analog of quantum mechanical “semiclassical” approximation. We also outline how to apply perturbative quantum mechanical techniques beyond the “semiclas- sical” approximation, which are facilitated by Feynman diagrams. arXiv:1410.1611v4 [q-fin.MF] 10 Aug 2016 1 Zura Kakushadze, Ph.D., is the President of Quantigicr Solutions LLC, and a Full Professor at Free University of Tbilisi. Email: [email protected] 2 DISCLAIMER: This address is used by the corresponding author for no purpose other than to indicate his professional affiliation as is customary in publications. In particular, the contents of this paper are not intended as an investment, legal, tax or any other such advice, and in no way represent views of Quantigic Solutions LLC, the website www.quantigic.com or any of their other affiliates. 1 Introduction In his seminal paper on path integral formulation of quantum mechanics, Feynman (1948) humbly states: “The formulation is mathematically equivalent to the more usual formulations. -
Critical Notice: the Quantum Revolution in Philosophy (Richard Healey; Oxford University Press, 2017)
Critical notice: The Quantum Revolution in Philosophy (Richard Healey; Oxford University Press, 2017) DAVID WALLACE Richard Healey’s The Quantum Revolution in Philosophy is a terrific book, and yet I disagree with nearly all its main substantive conclusions. The purpose of this review is to say why the book is well worth your time if you have any interest in the interpretation of quantum theory or in the general philosophy of science, and yet why in the end I think Healey’s ambitious project fails to achieve its full goals. The quantum measurement problem is the central problem in philosophy of quantum mechanics, and arguably the most important issue in philosophy of physics more generally; not coincidentally, it has seen some of the field’s best work, and some of its most effective engagement with physics. Yet the debate in the field largely now appears deadlocked: the last few years have seen developments in our understanding of many of the proposed solutions, but not much movement in the overall dialectic. This is perhaps clearest with a little distance: metaphysicians who need to refer to quantum mechanics increasingly tend to talk of “the three main interpretations” (they mean: de Broglie and Bohm’s hidden variable theory; Ghirardi, Rimini and Weber’s (‘GRW’) dynamical-collapse theory; Everett’s many- universes theory) and couch their discussions so as to be, as much as possible, equally valid for any of those three. It is not infrequent for philosophers of physics to use the familiar framework of underdetermination of theory by evidence to discuss the measurement problem. -
Quantum Chaos in Rydberg Atoms In.Strong Fields by Hong Jiao
Experimental and Theoretical Aspects of Quantum Chaos in Rydberg Atoms in.Strong Fields by Hong Jiao B.S., University of California, Berkeley (1987) M.S., California Institute of Technology (1989) Submitted to the Department of Physics in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the MASSACHUSETTS INSTITUTE OF TECHNOLOGY February 1996 @ Massachusetts Institute of Technology 1996. All rights reserved. Signature of Author. Department of Physics U- ge December 4, 1995 Certified by.. Daniel Kleppner Lester Wolfe Professor of Physics Thesis Supervisor Accepted by. ;AssAGiUS. rrS INSTITU It George F. Koster OF TECHNOLOGY Professor of Physics FEB 1411996 Chairman, Departmental Committee on Graduate Students LIBRARIES 8 Experimental and Theoretical Aspects of Quantum Chaos in Rydberg Atoms in Strong Fields by Hong Jiao Submitted to the Department of Physics on December 4, 1995, in partial fulfillment of the requirements for the degree of Doctor of Philosophy Abstract We describe experimental and theoretical studies of the connection between quantum and classical dynamics centered on the Rydberg atom in strong fields, a disorderly system. Primary emphasis is on systems with three degrees of freedom and also the continuum behavior of systems with two degrees of freedom. Topics include theoret- ical studies of classical chaotic ionization, experimental observation of bifurcations of classical periodic orbits in Rydberg atoms in parallel electric and magnetic fields, analysis of classical ionization and semiclassical recurrence spectra of the diamagnetic Rydberg atom in the positive energy region, and a statistical analysis of quantum manifestation of electric field induced chaos in Rydberg atoms in crossed electric and magnetic fields. -
The Path Integral Approach to Quantum Mechanics Lecture Notes for Quantum Mechanics IV
The Path Integral approach to Quantum Mechanics Lecture Notes for Quantum Mechanics IV Riccardo Rattazzi May 25, 2009 2 Contents 1 The path integral formalism 5 1.1 Introducingthepathintegrals. 5 1.1.1 Thedoubleslitexperiment . 5 1.1.2 An intuitive approach to the path integral formalism . .. 6 1.1.3 Thepathintegralformulation. 8 1.1.4 From the Schr¨oedinger approach to the path integral . .. 12 1.2 Thepropertiesofthepathintegrals . 14 1.2.1 Pathintegralsandstateevolution . 14 1.2.2 The path integral computation for a free particle . 17 1.3 Pathintegralsasdeterminants . 19 1.3.1 Gaussianintegrals . 19 1.3.2 GaussianPathIntegrals . 20 1.3.3 O(ℏ) corrections to Gaussian approximation . 22 1.3.4 Quadratic lagrangians and the harmonic oscillator . .. 23 1.4 Operatormatrixelements . 27 1.4.1 Thetime-orderedproductofoperators . 27 2 Functional and Euclidean methods 31 2.1 Functionalmethod .......................... 31 2.2 EuclideanPathIntegral . 32 2.2.1 Statisticalmechanics. 34 2.3 Perturbationtheory . .. .. .. .. .. .. .. .. .. .. 35 2.3.1 Euclidean n-pointcorrelators . 35 2.3.2 Thermal n-pointcorrelators. 36 2.3.3 Euclidean correlators by functional derivatives . ... 38 0 0 2.3.4 Computing KE[J] and Z [J] ................ 39 2.3.5 Free n-pointcorrelators . 41 2.3.6 The anharmonic oscillator and Feynman diagrams . 43 3 The semiclassical approximation 49 3.1 Thesemiclassicalpropagator . 50 3.1.1 VanVleck-Pauli-Morette formula . 54 3.1.2 MathematicalAppendix1 . 56 3.1.3 MathematicalAppendix2 . 56 3.2 Thefixedenergypropagator. 57 3.2.1 General properties of the fixed energy propagator . 57 3.2.2 Semiclassical computation of K(E)............. 61 3.2.3 Two applications: reflection and tunneling through a barrier 64 3 4 CONTENTS 3.2.4 On the phase of the prefactor of K(xf ,tf ; xi,ti) .... -
The Emergence of Chaos in Quantum Mechanics
S S symmetry Article The Emergence of Chaos in Quantum Mechanics Emilio Fiordilino Dipartimento di Fisica e Chimica—Emilio Segrè, Università degli Studi di Palermo, Via Archirafi 36, 90123 Palermo, Italy; emilio.fi[email protected] Received: 4 April 2020; Accepted: 7 May 2020; Published: 8 May 2020 Abstract: Nonlinearity in Quantum Mechanics may have extrinsic or intrinsic origins and is a liable route to a chaotic behaviour that can be of difficult observations. In this paper, we propose two forms of nonlinear Hamiltonian, which explicitly depend upon the phase of the wave function and produce chaotic behaviour. To speed up the slow manifestation of chaotic effects, a resonant laser field assisting the time evolution of the systems causes cumulative effects that might be revealed, at least in principle. The nonlinear Schrödinger equation is solved within the two-state approximation; the solution displays features with characteristics similar to those found in chaotic Classical Mechanics: sensitivity on the initial state, dense power spectrum, irregular filling of the Poincaré map and exponential separation of the trajectories of the Bloch vector s in the Bloch sphere. Keywords: nonlinear Schrödinger equation; chaos; high order harmonic generation 1. Introduction The theory of chaos gained the role of a new paradigm of Science for explaining a large variety of phenomena by introducing the concept of unpredictability within the perimeter of Classical Physics. Chaos occurs when the trajectory of a particle is sensitive to the initial conditions and is produced by a nonlinear equation of motion [1]. As examples we quote the equation for the Duffing oscillator (1918) 3 mx¨ + gx˙ + rx = F cos(wLt) (1) or its elaborated form 3 mx¨ + gx˙ + kx + rx = F cos(wLt) (2) that are among the most studied equation of mathematical physics [1,2] and, as far as we know, cannot be analytically solved. -
Signatures of Quantum Mechanics in Chaotic Systems
entropy Article Signatures of Quantum Mechanics in Chaotic Systems Kevin M. Short 1,* and Matthew A. Morena 2 1 Integrated Applied Mathematics Program, Department of Mathematics and Statistics, University of New Hampshire, Durham, NH 03824, USA 2 Department of Mathematics, Christopher Newport University, Newport News, VA 23606, USA; [email protected] * Correspondence: [email protected] Received: 6 May 2019; Accepted: 19 June 2019; Published: 22 June 2019 Abstract: We examine the quantum-classical correspondence from a classical perspective by discussing the potential for chaotic systems to support behaviors normally associated with quantum mechanical systems. Our main analytical tool is a chaotic system’s set of cupolets, which are highly-accurate stabilizations of its unstable periodic orbits. Our discussion is motivated by the bound or entangled states that we have recently detected between interacting chaotic systems, wherein pairs of cupolets are induced into a state of mutually-sustaining stabilization that can be maintained without external controls. This state is known as chaotic entanglement as it has been shown to exhibit several properties consistent with quantum entanglement. For instance, should the interaction be disturbed, the chaotic entanglement would then be broken. In this paper, we further describe chaotic entanglement and go on to address the capacity for chaotic systems to exhibit other characteristics that are conventionally associated with quantum mechanics, namely analogs to wave function collapse, various entropy definitions, the superposition of states, and the measurement problem. In doing so, we argue that these characteristics need not be regarded exclusively as quantum mechanical. We also discuss several characteristics of quantum systems that are not fully compatible with chaotic entanglement and that make quantum entanglement unique.