Hindawi Publishing Corporation International Journal of Electrochemistry Volume 2012, Article ID 462197, 34 pages doi:10.1155/2012/462197 Review Article Simple Ion Transfer at Liquid|Liquid Interfaces L.J.SanchezVallejo,J.M.Ovejero,R.A.Fernandez,´ and S. A. Dassie Instituto de Investigaciones en Fisicoqu´ımica de Cordoba´ (INFIQC), CONICET y Departamento de Fisicoqu´ımica, Facultad de Ciencias Qu´ımicas, Universidad Nacional de Cordoba,´ Ciudad Universitaria, Cordoba´ X5000HUA, Argentina Correspondence should be addressed to S. A. Dassie,
[email protected] Received 17 February 2012; Accepted 14 March 2012 Academic Editor: Shen-Ming Chen Copyright © 2012 L. J. Sanchez Vallejo et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The main aspects related to the charge transfer reactions occurring at the interface between two immiscible electrolyte solutions (ITIES) are described. The particular topics to be discussed involve simple ion transfer. Focus is given on theoretical approaches, numerical simulations, and experimental methodologies. Concerning the theoretical procedures, different computational simu- lations related to simple ion transfer are reviewed. The main conclusions drawn from the most accepted models are described and analyzed in regard to their relevance for explaining different aspects of ion transfer. We describe numerical simulations implemen- ting different approaches for solving the differential equations associated with the mass transport and charge transfer. These nume- rical simulations are correlated with selected experimental results; their usefulness in designing new experiments is summarized. Finally, many practical applications can be envisaged regarding the determination of physicochemical properties, electroanalysis, drug lipophilicity, and phase-transfer catalysis.