THE STAR FORMATION NEWSLETTER an Electronic Publication Dedicated to Early Stellar Evolution and Molecular Clouds
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The Messenger
10th anniversary of VLT First Light The Messenger The ground layer seeing on Paranal HAWK-I Science Verification The emission nebula around Antares No. 132 – June 2008 –June 132 No. The Organisation The Perfect Machine Tim de Zeeuw a groundbased spectroscopic comple thousand each semester, 800 of which (ESO Director General) ment to the Hubble Space Telescope. are for Paranal. The User Portal has Italy and Switzerland had joined ESO in about 4 000 registered users and 1981, enabling the construction of the the archive contains 74 TB of data and This issue of the Messenger marks the 3.5m New Technology Telescope with advanced data products. tenth anniversary of first light of the Very pioneering advances in active optics, Large Telescope. It is an excellent occa crucial for the next step: the construction sion to look at the broader implications of the Very Large Telescope, which Winning strategy of the VLT’s success and to consider the received the green light from Council in next steps. 1987 and was built on Cerro Paranal in The VLT opened for business some five the Atacama desert between Antofagasta years after the Keck telescopes, but the and Taltal in Northern Chile. The 8.1m decision to take the time to build a fully Mission Gemini telescopes and the 8.3m Subaru integrated system, consisting of four telescope were constructed on a similar 8.2m telescopes and providing a dozen ESO’s mission is to enable scientific dis time scale, while the Large Binocular Tele foci for a carefully thoughtout comple coveries by constructing and operating scope and the Gran Telescopio Canarias ment of instruments together with four powerful observational facilities that are now starting operations. -
The Influence of Electronegativity on Linear and Triangular Three-Centre Bonds
The Free Internet Journal Review for Organic Chemistry Archive for Arkivoc 2020, part iv, 12-24 Organic Chemistry The influence of electronegativity on linear and triangular three-centre bonds Christopher A. Ramsden Lennard-Jones Laboratories, School of Chemical and Physical Sciences, Keele University, Keele, Staffordshire ST5 5BG, United Kingdom Email: [email protected] Received 03-24-2020 Accepted 04-19-2020 Published on line 04-30-2020 Abstract Electronegativity differences between bonding atoms have major effects on the strengths of chemical bonds but they affect two-centre and three-centre bonds in different ways and with different consequences. The effect on two-centre bonds was recognised almost 100 years ago but the influence of electronegativity difference on three-centre bonding has received less attention. Molecular orbital models of three-centre bonding are discussed and their application to the understanding of the properties of three-centre bonded species illustrated. -2.5 X -3.0 + Y Y Ea -3.5 -4.0 -4.5 X Binding Energy Binding + -5.0 Y Y -5.5 -6.0 -4 -2 0 2 4 h (b units) Keywords: Three-centre bonding, electronegativity, hypervalent, nonclassical carbocations, 2-norbornyl cation, xenon difluoride DOI: https://doi.org/10.24820/ark.5550190.p011.203 Page 12 ©AUTHOR(S) Arkivoc 2020, iv, 12-24 Ramsden, C. A. Table of Contents 1. Introduction 2. Linear Three-Centre Bonds (Hypervalent Bonds) (X-Y-X) X 3. Triangular Three-Centre Bonds (Y Y) 4. The Localised Bond Model of Two- and Three-Centre Bonds 5. Conclusions References -
Galaxies and Cosmology (2011)
Galaxien und Kosmologie / Galaxies and Cosmology (2011) Refereed Papers Adams, J. J., K. Gebhardt, G. A. Blanc, M. H. Fabricius, G. J. Hill, J. D. Murphy, R. C. E. van den Bosch and G. van de Ven: The central dark matter distribution of NGC 2976. The Astrophysical Journal 745, id. 92 (2011) Aihara, H., C. Allende Prieto, D. An, S. F. Anderson, É. Aubourg, E. Balbinot, T. C. Beers, A. A. Berlind, S. J. Bickerton, D. Bizyaev, M. R. Blanton, J. J. Bochanski, A. S. Bolton, J. Bovy, W. N. Brandt, J. Brinkmann, P. J. Brown, J. R. Brownstein, N. G. Busca, H. Campbell, M. A. Carr, Y. Chen, C. Chiappini, J. Comparat, N. Connolly, M. Cortes, R. A. C. Croft, A. J. Cuesta, L. N. da Costa, J. R. A. Davenport, K. Dawson, S. Dhital, A. Ealet, G. L. Ebelke, E. M. Edmondson, D. J. Eisenstein, S. Escoffier, M. Esposito, M. L. Evans, X. Fan, B. Femenía Castellá, A. Font-Ribera, P. M. Frinchaboy, J. Ge, B. A. Gillespie, G. Gilmore, J. I. González Hernández, J. R. Gott, A. Gould, E. K. Grebel, J. E. Gunn, J.-C. Hamilton, P. Harding, D. W. Harris, S. L. Hawley, F. R. Hearty, S. Ho, D. W. Hogg, J. A. Holtzman, K. Honscheid, N. Inada, I. I. Ivans, L. Jiang, J. A. Johnson, C. Jordan, W. P. Jordan, E. A. Kazin, D. Kirkby, M. A. Klaene, G. R. Knapp, J.-P. Kneib, C. S. Kochanek, L. Koesterke, J. A. Kollmeier, R. G. Kron, H. Lampeitl, D. Lang, J.-M. Le Goff, Y. -
Bun)Mo(Pme3)(Η -C2H4) (6) Through Etmgbr Reduction of (Arn)( Bun)Mocl2(DME) in the Presence of Pme3
Synthesis, Catalysis and Stoichiometric Reactivity of Mo Imido Complexes Nicolas A. McLeod BSc. in Chemistry Chemistry Thesis submitted to the Faculty of Graduate Studies In the partial fulfillment of the requirements For the MSc. degree in chemistry Chemistry Department Faculty of Mathematics and Science Brock University St. Catharines, Ontario © Nicolas A. McLeod, 2014 Abstract The current thesis describes the syntheses, catalytic reactivity and mechanistic investigations of novel Mo(IV) and Mo(VI) imido systems. Attempts at preparing mixed bis(imido) Mo(IV) complexes of the type (RN)(R′N)Mo(PMe3)n (n = 2 or 3) derived from the t mono(imido) complexes (RN)Mo(PMe3)3(X)2 (R = Bu (1) or Ar (2); X = Cl2 or HCl, Ar=2,6- i Pr2C6H3) are also described. The addition of lithiated silylamides to 1 or 2 results in the 2 unexpected formation of the C-H activated cyclometallated complexes (RN)Mo(PMe3)2(η - t CH2PMe2)(X) (R = Ar, X = H (3); R = Bu, X = Cl (4)). Complexes 3 and 4 were used in the activation of R′E-H bonds (E = Si, B, C, O, P; R′ = alkyl or aryl), which typically give products of addition across the M-C bond of the type (RN)Mo(PMe3)3(ER′)(X) (4). In the case of 2,6- dimethylphenol, subsequent heating of 4 (R = Ar, R′ = 2,6-Me2C6H3, E = O) to 50 °C results in 2 C-H activation to give the cyclometallated complex (ArN)Mo(PMe3)3(κ -O,C-OPh(Me)CH2) (5). An alternative approach was developed in synthesizing the mixed imido complex t 2 t (ArN)( BuN)Mo(PMe3)(η -C2H4) (6) through EtMgBr reduction of (ArN)( BuN)MoCl2(DME) in the presence of PMe3. -
Übersicht NGC-Objektauswahl Cepheus Zur Übersichtskarte
NGC-Objektauswahl Cepheus NGC 40 NGC 7055 NGC 7354 NGC 188 NGC 7076 NGC 7380 NGC 1184 NGC 7129 NGC 7419 NGC 1544 NGC 7139 NGC 7423 NGC 2276 NGC 7142 NGC 7429 NGC 2300 NGC 7160 NGC 7510 NGC 6939 NGC 7226 NGC 7538 NGC 6949 NGC 7235 NGC 7708 NGC 6951 NGC 7261 NGC 7762 NGC 7023 NGC 7281 NGC 7822 Sternbild- Übersicht Zur Objektauswahl: Nummer anklicken Zur Übersichtskarte: Objekt anklicken Sternbildübersicht Auswahl NGC 40_7708 Aufsuchkarte Auswahl NGC 188_Aufsuchkarte 2 UMi 2 Auswahl NGC 1184 Aufsuchkarte Auswahl NGC 1544_2276_2300 Aufsuchkarte Auswahl NGC 6939 Aufsuchkarte Auswahl NGC 6949_6951 Aufsuchkarte Auswahl NGC 7023 Aufsuchkarte Auswahl NGC 7055 Aufsuchkarte Auswahl NGC 7076 Aufsuchkarte Auswahl NGC 7129_7142 Aufsuchkarte Auswahl NGC 7139_7160 Aufsuchkarte Auswahl NGC 7226_7235 Aufsuchkarte Auswahl N 7261_7281 Aufsuchkarte Auswahl NGC 7354_7419_7429_7510_7538 Aufsuchkarte Auswahl NGC 7380_7423 Aufsuchkarte Auswahl NGC 7762_7822 Aufsuchkarte Auswahl NGC 40 Übersichtskarte Aufsuch- Auswahl karte NGC 188 Übersichtskarte Aufsuch- Auswahl karte NGC 1184 Übersichtskarte Aufsuch- Auswahl karte NGC 1544 Übersichtskarte Aufsuch- Auswahl karte N 2276_N 2300 Übersichtskarte Aufsuch- Auswahl karte NGC 6939 Übersichtskarte Aufsuch- Auswahl karte NGC 6949 Übersichtskarte Aufsuch- Auswahl karte NGC 6951 Übersichtskarte Aufsuch- Auswahl karte NGC 7023 Übersichtskarte Aufsuch- Auswahl karte NGC 7055 Übersichtskarte Aufsuch- Auswahl karte NGC 7076 Übersichtskarte Aufsuch- Auswahl karte NGC 7129_7142 Übersichtskarte Aufsuch- Auswahl karte NGC 7139 -
Preliminary JIRAM Results from Juno Polar Observations: 2. Analysis Of
PUBLICATIONS Geophysical Research Letters RESEARCH LETTER Preliminary JIRAM results from Juno polar observations: 10.1002/2017GL072905 + 2. Analysis of the Jupiter southern H3 emissions Special Section: and comparison with the north aurora Early Results: Juno at Jupiter A. Adriani1 , A. Mura1 , M. L. Moriconi2 , B. M. Dinelli2 , F. Fabiano2,3 , F. Altieri1 , G. Sindoni1 , S. J. Bolton4 , J. E. P. Connerney5 , S. K. Atreya6, F. Bagenal7 , Key Points: + 8 1 1 1 1 1 • H3 intensity, column density, and J.-C. M. C. Gérard , G. Filacchione , F. Tosi , A. Migliorini , D. Grassi , G. Piccioni , temperature maps of the Jupiter R. Noschese1, A. Cicchetti1 , G. R. Gladstone4, C. Hansen9 , W. S. Kurth10 , S. M. Levin11 , southern aurora are derived from B. H. Mauk12 , D. J. McComas13 , A. Olivieri14, D. Turrini1 , S. Stefani1 , and M. Amoroso14 Juno/JIRAM data collected on the first orbit 1INAF-Istituto di Astrofisica e Planetologia Spaziali, Rome, Italy, 2CNR-Istituto di Scienze dell’Atmosfera e del Clima, Bologna, • Emissions from southern aurora are 3 4 more intense than from the North Italy, Dipartimento di Fisica e Astronomia, Università di Bologna, Bologna, Italy, Space Science Department, Southwest • Derived temperatures are in the range Research Institute, San Antonio, Texas, USA, 5Solar System Exploration Division, Planetary Magnetospheres Laboratory, 600°K to 1400°K NASA Goddard Space Flight Center, Greenbelt, Maryland, USA, 6Planetary Science Laboratory, University of Michigan, Ann Arbor, Michigan, USA, 7Laboratory for Atmospheric and Space Physics, University of Colorado Boulder, Boulder, Colorado, USA, 8Laboratoire de Physique Atmosphérique et Planétaire, University of Liège, Liège, Belgium, 9Planetary Science 10 Correspondence to: Institute, Tucson, Arizona, USA, Jet Propulsion Laboratory, California Institute of Technology, Pasadena, California, USA, 11 12 A. -
List of Bright Nebulae Primary I.D. Alternate I.D. Nickname
List of Bright Nebulae Alternate Primary I.D. Nickname I.D. NGC 281 IC 1590 Pac Man Neb LBN 619 Sh 2-183 IC 59, IC 63 Sh2-285 Gamma Cas Nebula Sh 2-185 NGC 896 LBN 645 IC 1795, IC 1805 Melotte 15 Heart Nebula IC 848 Soul Nebula/Baby Nebula vdB14 BD+59 660 NGC 1333 Embryo Neb vdB15 BD+58 607 GK-N1901 MCG+7-8-22 Nova Persei 1901 DG 19 IC 348 LBN 758 vdB 20 Electra Neb. vdB21 BD+23 516 Maia Nebula vdB22 BD+23 522 Merope Neb. vdB23 BD+23 541 Alcyone Neb. IC 353 NGC 1499 California Nebula NGC 1491 Fossil Footprint Neb IC 360 LBN 786 NGC 1554-55 Hind’s Nebula -Struve’s Lost Nebula LBN 896 Sh 2-210 NGC 1579 Northern Trifid Nebula NGC 1624 G156.2+05.7 G160.9+02.6 IC 2118 Witch Head Nebula LBN 991 LBN 945 IC 405 Caldwell 31 Flaming Star Nebula NGC 1931 LBN 1001 NGC 1952 M 1 Crab Nebula Sh 2-264 Lambda Orionis N NGC 1973, 1975, Running Man Nebula 1977 NGC 1976, 1982 M 42, M 43 Orion Nebula NGC 1990 Epsilon Orionis Neb NGC 1999 Rubber Stamp Neb NGC 2070 Caldwell 103 Tarantula Nebula Sh2-240 Simeis 147 IC 425 IC 434 Horsehead Nebula (surrounds dark nebula) Sh 2-218 LBN 962 NGC 2023-24 Flame Nebula LBN 1010 NGC 2068, 2071 M 78 SH 2 276 Barnard’s Loop NGC 2149 NGC 2174 Monkey Head Nebula IC 2162 Ced 72 IC 443 LBN 844 Jellyfish Nebula Sh2-249 IC 2169 Ced 78 NGC Caldwell 49 Rosette Nebula 2237,38,39,2246 LBN 943 Sh 2-280 SNR205.6- G205.5+00.5 Monoceros Nebula 00.1 NGC 2261 Caldwell 46 Hubble’s Var. -
Review Article Star Formation Histories of Dwarf Galaxies from the Colour-Magnitude Diagrams of Their Resolved Stellar Populations
Hindawi Publishing Corporation Advances in Astronomy Volume 2010, Article ID 158568, 25 pages doi:10.1155/2010/158568 Review Article Star Formation Histories of Dwarf Galaxies from the Colour-Magnitude Diagrams of Their Resolved Stellar Populations Michele Cignoni1, 2 and Monica Tosi2 1 Astronomy Department, Bologna University, Via Ranzani 1, 40127 Bologna, Italy 2 Osservatorio Astronomico di Bologna, INAF, Via Ranzani 1, 40127 Bologna, Italy Correspondence should be addressed to Michele Cignoni, [email protected] Received 5 May 2009; Accepted 12 August 2009 Academic Editor: Ulrich Hopp Copyright © 2010 M. Cignoni and M. Tosi. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. In this tutorial paper we summarize how the star formation (SF) history of a galactic region can be derived from the colour- magnitude diagram (CMD) of its resolved stars. The procedures to build synthetic CMDs and to exploit them to derive the SF histories (SFHs) are described, as well as the corresponding uncertainties. The SFHs of resolved dwarf galaxies of all morphological types, obtained from the application of the synthetic CMD method, are reviewed and discussed. To summarize: (1) only early-type galaxies show evidence of long interruptions in the SF activity; late-type dwarfs present rather continuous, or gasping, SF regimes; (2) a few early-type dwarfs have experienced only one episode of SF activity concentrated at the earliest epochs, whilst many others show extended or recurrent SF activity; (3) no galaxy experiencing now its first SF episode has been found yet; (4) no frequent evidence of strong SF bursts is found; (5) there is no significant difference in the SFH of dwarf irregulars and blue compact dwarfs, except for the current SF rates. -
NGC 602: Taken Under the “Wing” of the Small Magellanic Cloud
National Aeronautics and Space Administration NGC 602 www.nasa.gov NGC 602: Taken Under the “Wing” of the Small Magellanic Cloud The Small Magellanic Cloud (SMC) is one of the closest galaxies to the Milky Way. In this composite image the Chandra data is shown in purple, optical data from Hubble is shown in red, green and blue and infrared data from Spitzer is shown in red. Chandra observations of the SMC have resulted in the first detection of X-ray emission from young stars with masses similar to our Sun outside our Milky Way galaxy. The Small Magellanic Cloud (SMC) is one of the Milky Way’s region known as NGC 602, which contains a collection of at least closest galactic neighbors. Even though it is a small, or so-called three star clusters. One of them, NGC 602a, is similar in age, dwarf galaxy, the SMC is so bright that it is visible to the unaided mass, and size to the famous Orion Nebula Cluster. Researchers eye from the Southern Hemisphere and near the equator. have studied NGC 602a to see if young stars—that is, those only a few million years old—have different properties when they have Modern astronomers are also interested in studying the SMC low levels of metals, like the ones found in NGC 602a. (and its cousin, the Large Magellanic Cloud), but for very different reasons. The SMC is one of the Milky Way’s closest galactic Using Chandra, astronomers discovered extended X-ray emission, neighbors. Because the SMC is so close and bright, it offers an from the two most densely populated regions in NGC 602a. -
A New Method for the Production of Protonated Hydrogen 29 June 2021
A new method for the production of protonated hydrogen 29 June 2021 + cosmos. This ionized molecule, H 3 (also known as the trihydrogen ion) is made up of three protons and two electrons, and takes the form of an equilateral triangle. Owing to its highly reactive nature, protonated hydrogen promotes the formation of more complex hydrocarbons. It is therefore regarded as an important catalyst for the synthesis of organic, carbon-based molecules that form the basis of life as we know it. + Up until now, H 3 has only been synthesized on Earth from preformed organic compounds or in highly energized hydrogen plasmas. Laser Trihydrogen ions (H+ ) can be formed by subjecting physicists have now discovered a new route for the 3 + water molecules adsorbed to nanoparticles to intense synthesis of H 3 on nanoparticles—in a system that laser light. The experiments mimic the conditions found effectively reproduces conditions under which the in outer space. Credit: Ali Alnaser, AUS molecule can be formed in space. Their findings thus provide new insights into the formation of trihydrogen ions under extraterrestrial conditions. A research group led by Prof. Matthias Kling of the In the experiments, water molecules adsorbed on Max Planck Institute for Quantum Optics (MPQ) the surface of silicon dioxide nanoparticles were and the Ludwig-Maximilian University in Munich irradiated with extremely powerful, ultrashort (LMU), in cooperation with the American University femtosecond laser pulses, essentially mimicking in Sharjah, has discovered a new method for the the effect of the high-energy radiation to which + production of protonated hydrogen (H 3). -
407 a Abell Galaxy Cluster S 373 (AGC S 373) , 351–353 Achromat
Index A Barnard 72 , 210–211 Abell Galaxy Cluster S 373 (AGC S 373) , Barnard, E.E. , 5, 389 351–353 Barnard’s loop , 5–8 Achromat , 365 Barred-ring spiral galaxy , 235 Adaptive optics (AO) , 377, 378 Barred spiral galaxy , 146, 263, 295, 345, 354 AGC S 373. See Abell Galaxy Cluster Bean Nebulae , 303–305 S 373 (AGC S 373) Bernes 145 , 132, 138, 139 Alnitak , 11 Bernes 157 , 224–226 Alpha Centauri , 129, 151 Beta Centauri , 134, 156 Angular diameter , 364 Beta Chamaeleontis , 269, 275 Antares , 129, 169, 195, 230 Beta Crucis , 137 Anteater Nebula , 184, 222–226 Beta Orionis , 18 Antennae galaxies , 114–115 Bias frames , 393, 398 Antlia , 104, 108, 116 Binning , 391, 392, 398, 404 Apochromat , 365 Black Arrow Cluster , 73, 93, 94 Apus , 240, 248 Blue Straggler Cluster , 169, 170 Aquarius , 339, 342 Bok, B. , 151 Ara , 163, 169, 181, 230 Bok Globules , 98, 216, 269 Arcminutes (arcmins) , 288, 383, 384 Box Nebula , 132, 147, 149 Arcseconds (arcsecs) , 364, 370, 371, 397 Bug Nebula , 184, 190, 192 Arditti, D. , 382 Butterfl y Cluster , 184, 204–205 Arp 245 , 105–106 Bypass (VSNR) , 34, 38, 42–44 AstroArt , 396, 406 Autoguider , 370, 371, 376, 377, 388, 389, 396 Autoguiding , 370, 376–378, 380, 388, 389 C Caldwell Catalogue , 241 Calibration frames , 392–394, 396, B 398–399 B 257 , 198 Camera cool down , 386–387 Barnard 33 , 11–14 Campbell, C.T. , 151 Barnard 47 , 195–197 Canes Venatici , 357 Barnard 51 , 195–197 Canis Major , 4, 17, 21 S. Chadwick and I. Cooper, Imaging the Southern Sky: An Amateur Astronomer’s Guide, 407 Patrick Moore’s Practical -
The Astronomy of the Kamilaroi and Euahlayi Peoples and Their Neighbours
The Astronomy of the Kamilaroi and Euahlayi Peoples and Their Neighbours By Robert Stevens Fuller A thesis submitted to the Faculty of Arts at Macquarie University for the degree of Master of Philosophy November 2014 © Robert Stevens Fuller i I certify that the work in this thesis entitled “The Astronomy of the Kamilaroi and Euahlayi Peoples and Their Neighbours” has not been previously submitted for a degree nor has it been submitted as part of requirements for a degree to any other university or institution other than Macquarie University. I also certify that the thesis is an original piece of research and it has been written by me. Any help and assistance that I have received in my research work and the preparation of the thesis itself has been appropriately acknowledged. In addition, I certify that all information sources and literature used are indicated in the thesis. The research presented in this thesis was approved by Macquarie University Ethics Review Committee reference number 5201200462 on 27 June 2012. Robert S. Fuller (42916135) ii This page left intentionally blank Contents Contents .................................................................................................................................... iii Dedication ................................................................................................................................ vii Acknowledgements ................................................................................................................... ix Publications ..............................................................................................................................