Delayed-Choice Experiments and the Metaphysics of Entanglement
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Configuration Interaction Study of the Ground State of the Carbon Atom
Configuration Interaction Study of the Ground State of the Carbon Atom María Belén Ruiz* and Robert Tröger Department of Theoretical Chemistry Friedrich-Alexander-University Erlangen-Nürnberg Egerlandstraße 3, 91054 Erlangen, Germany In print in Advances Quantum Chemistry Vol. 76: Novel Electronic Structure Theory: General Innovations and Strongly Correlated Systems 30th July 2017 Abstract Configuration Interaction (CI) calculations on the ground state of the C atom are carried out using a small basis set of Slater orbitals [7s6p5d4f3g]. The configurations are selected according to their contribution to the total energy. One set of exponents is optimized for the whole expansion. Using some computational techniques to increase efficiency, our computer program is able to perform partially-parallelized runs of 1000 configuration term functions within a few minutes. With the optimized computer programme we were able to test a large number of configuration types and chose the most important ones. The energy of the 3P ground state of carbon atom with a wave function of angular momentum L=1 and ML=0 and spin eigenfunction with S=1 and MS=0 leads to -37.83526523 h, which is millihartree accurate. We discuss the state of the art in the determination of the ground state of the carbon atom and give an outlook about the complex spectra of this atom and its low-lying states. Keywords: Carbon atom; Configuration Interaction; Slater orbitals; Ground state *Corresponding author: e-mail address: [email protected] 1 1. Introduction The spectrum of the isolated carbon atom is the most complex one among the light atoms. The ground state of carbon atom is a triplet 3P state and its low-lying excited states are singlet 1D, 1S and 1P states, more stable than the corresponding triplet excited ones 3D and 3S, against the Hund’s rule of maximal multiplicity. -
Quantum Field Theory*
Quantum Field Theory y Frank Wilczek Institute for Advanced Study, School of Natural Science, Olden Lane, Princeton, NJ 08540 I discuss the general principles underlying quantum eld theory, and attempt to identify its most profound consequences. The deep est of these consequences result from the in nite number of degrees of freedom invoked to implement lo cality.Imention a few of its most striking successes, b oth achieved and prosp ective. Possible limitation s of quantum eld theory are viewed in the light of its history. I. SURVEY Quantum eld theory is the framework in which the regnant theories of the electroweak and strong interactions, which together form the Standard Mo del, are formulated. Quantum electro dynamics (QED), b esides providing a com- plete foundation for atomic physics and chemistry, has supp orted calculations of physical quantities with unparalleled precision. The exp erimentally measured value of the magnetic dip ole moment of the muon, 11 (g 2) = 233 184 600 (1680) 10 ; (1) exp: for example, should b e compared with the theoretical prediction 11 (g 2) = 233 183 478 (308) 10 : (2) theor: In quantum chromo dynamics (QCD) we cannot, for the forseeable future, aspire to to comparable accuracy.Yet QCD provides di erent, and at least equally impressive, evidence for the validity of the basic principles of quantum eld theory. Indeed, b ecause in QCD the interactions are stronger, QCD manifests a wider variety of phenomena characteristic of quantum eld theory. These include esp ecially running of the e ective coupling with distance or energy scale and the phenomenon of con nement. -
1 the LOCALIZED QUANTUM VACUUM FIELD D. Dragoman
1 THE LOCALIZED QUANTUM VACUUM FIELD D. Dragoman – Univ. Bucharest, Physics Dept., P.O. Box MG-11, 077125 Bucharest, Romania, e-mail: [email protected] ABSTRACT A model for the localized quantum vacuum is proposed in which the zero-point energy of the quantum electromagnetic field originates in energy- and momentum-conserving transitions of material systems from their ground state to an unstable state with negative energy. These transitions are accompanied by emissions and re-absorptions of real photons, which generate a localized quantum vacuum in the neighborhood of material systems. The model could help resolve the cosmological paradox associated to the zero-point energy of electromagnetic fields, while reclaiming quantum effects associated with quantum vacuum such as the Casimir effect and the Lamb shift; it also offers a new insight into the Zitterbewegung of material particles. 2 INTRODUCTION The zero-point energy (ZPE) of the quantum electromagnetic field is at the same time an indispensable concept of quantum field theory and a controversial issue (see [1] for an excellent review of the subject). The need of the ZPE has been recognized from the beginning of quantum theory of radiation, since only the inclusion of this term assures no first-order temperature-independent correction to the average energy of an oscillator in thermal equilibrium with blackbody radiation in the classical limit of high temperatures. A more rigorous introduction of the ZPE stems from the treatment of the electromagnetic radiation as an ensemble of harmonic quantum oscillators. Then, the total energy of the quantum electromagnetic field is given by E = åk,s hwk (nks +1/ 2) , where nks is the number of quantum oscillators (photons) in the (k,s) mode that propagate with wavevector k and frequency wk =| k | c = kc , and are characterized by the polarization index s. -
The Heisenberg Uncertainty Principle*
OpenStax-CNX module: m58578 1 The Heisenberg Uncertainty Principle* OpenStax This work is produced by OpenStax-CNX and licensed under the Creative Commons Attribution License 4.0 Abstract By the end of this section, you will be able to: • Describe the physical meaning of the position-momentum uncertainty relation • Explain the origins of the uncertainty principle in quantum theory • Describe the physical meaning of the energy-time uncertainty relation Heisenberg's uncertainty principle is a key principle in quantum mechanics. Very roughly, it states that if we know everything about where a particle is located (the uncertainty of position is small), we know nothing about its momentum (the uncertainty of momentum is large), and vice versa. Versions of the uncertainty principle also exist for other quantities as well, such as energy and time. We discuss the momentum-position and energy-time uncertainty principles separately. 1 Momentum and Position To illustrate the momentum-position uncertainty principle, consider a free particle that moves along the x- direction. The particle moves with a constant velocity u and momentum p = mu. According to de Broglie's relations, p = }k and E = }!. As discussed in the previous section, the wave function for this particle is given by −i(! t−k x) −i ! t i k x k (x; t) = A [cos (! t − k x) − i sin (! t − k x)] = Ae = Ae e (1) 2 2 and the probability density j k (x; t) j = A is uniform and independent of time. The particle is equally likely to be found anywhere along the x-axis but has denite values of wavelength and wave number, and therefore momentum. -
Changes to the Standard to Implement the Safer Choice Label (Pdf)
Changes to the Standard to Implement the Safer Choice Label 2/10/15 Implementation of a New Label for the DfE Safer Product Labeling Program and Supporting Modifications to the DfE Standard for Safer Products, now to be known as the “Safer Choice Standard,” including the Designation of a Fragrance-Free Label This document explains several important changes to EPA’s Safer Product Labeling Program (SPLP), as well as a number of conforming changes to the program’s Standard for Safer Products, including: a new label1 and name for the EPA SPLP; an associated fragrance-free label; and related changes to the standard that qualifies products for the label. With this document EPA is finalizing the new label for immediate use. While effective immediately, the Agency is requesting comment on the other changes described in this document, including a new, optional fragrance-free certification. Redesigned Label The EPA Design for the Environment (DfE) Safer Product Labeling Program has redesigned its label to better communicate the program’s human health and environmental protection goals, increase consumer and institutional/industrial purchaser understanding and recognition of products bearing the label, and encourage innovation and the development of safer chemicals and chemical-based products. The label’s new name “Safer Choice,” with the accompanying wording (or “tagline”) “Meets U.S. EPA Safer Product Standards” (which is part of the label), and design were developed over many months based on input and feedback from a diverse set of stakeholders and the general public. This input and feedback included more than 1700 comments on EPA’s website, six consumer focus group sessions in three geographic markets, and a national online survey. -
8 the Variational Principle
8 The Variational Principle 8.1 Approximate solution of the Schroedinger equation If we can’t find an analytic solution to the Schroedinger equation, a trick known as the varia- tional principle allows us to estimate the energy of the ground state of a system. We choose an unnormalized trial function Φ(an) which depends on some variational parameters, an and minimise hΦ|Hˆ |Φi E[a ] = n hΦ|Φi with respect to those parameters. This gives an approximation to the wavefunction whose accuracy depends on the number of parameters and the clever choice of Φ(an). For more rigorous treatments, a set of basis functions with expansion coefficients an may be used. The proof is as follows, if we expand the normalised wavefunction 1/2 |φ(an)i = Φ(an)/hΦ(an)|Φ(an)i in terms of the true (unknown) eigenbasis |ii of the Hamiltonian, then its energy is X X X ˆ 2 2 E[an] = hφ|iihi|H|jihj|φi = |hφ|ii| Ei = E0 + |hφ|ii| (Ei − E0) ≥ E0 ij i i ˆ where the true (unknown) ground state of the system is defined by H|i0i = E0|i0i. The inequality 2 arises because both |hφ|ii| and (Ei − E0) must be positive. Thus the lower we can make the energy E[ai], the closer it will be to the actual ground state energy, and the closer |φi will be to |i0i. If the trial wavefunction consists of a complete basis set of orthonormal functions |χ i, each P i multiplied by ai: |φi = i ai|χii then the solution is exact and we just have the usual trick of expanding a wavefunction in a basis set. -
Existentialism
TOPIC FOR- SEM- III ( PHIL-CC 10) CONTEMPORARY WESTERN PHILOSOPHY BY- DR. VIJETA SINGH ASSISTANT PROFESSOR P.G. DEPARTMENT OF PHILOSOPHY PATNA UNIVERSITY Existentialism Existentialism is a philosophy that emphasizes individual existence, freedom and choice. It is the view that humans define their own meaning in life, and try to make rational decisions despite existing in an irrational universe. This philosophical theory propounds that people are free agents who have control over their choices and actions. Existentialists believe that society should not restrict an individual's life or actions and that these restrictions inhibit free will and the development of that person's potential. History 1 Existentialism originated with the 19th Century philosopher Soren Kierkegaard and Friedrich Nietzsche, but they did not use the term (existentialism) in their work. In the 1940s and 1950s, French existentialists such as Jean- Paul Sartre , Albert Camus and Simone de Beauvoir wrote scholarly and fictional works that popularized existential themes, such as dread, boredom, alienation, the absurd, freedom, commitment and nothingness. The first existentialist philosopher who adopted the term as a self-description was Sartre. Existentialism as a distinct philosophical and literary movement belongs to the 19th and 20th centuries, but elements of existentialism can be found in the thought (and life) of Socrates, in the Bible, and in the work of many pre-modern philosophers and writers. Noted Existentialists: Soren Kierkegaard (1813-1855) Nationality Denmark Friedrich Nietzsche(1844-1900) Nationality Germany Paul Tillich(1886-1965) Nati…United States, Germany Martin Heidegger ( 1889-1976) Nati…Germany Simone de Beauvior(1908-1986) Nati…France Albert Camus (1913-1960) Nati….France Jean Paul Sartre (1905-1980) Nati….France 2 What does it mean to exist ? To have reason. -
Does Choice Mean Freedom and Well-Being?
Swarthmore College Works Psychology Faculty Works Psychology 8-1-2010 Does Choice Mean Freedom And Well-Being? H. R. Markus Barry Schwartz Swarthmore College, [email protected] Follow this and additional works at: https://works.swarthmore.edu/fac-psychology Part of the Psychology Commons Let us know how access to these works benefits ouy Recommended Citation H. R. Markus and Barry Schwartz. (2010). "Does Choice Mean Freedom And Well-Being?". Journal Of Consumer Research. Volume 37, Issue 2. 344-355. DOI: 10.1086/651242 . https://works.swarthmore.edu/fac-psychology/5 This work is brought to you for free by Swarthmore College Libraries' Works. It has been accepted for inclusion in Psychology Faculty Works by an authorized administrator of Works. For more information, please contact [email protected]. Journal of Consumer Research, Inc. Does Choice Mean Freedom and Well‐Being? Author(s): Hazel Rose Markus and Barry Schwartz Reviewed work(s): Source: Journal of Consumer Research, Vol. 37, No. 2 (August 2010), pp. 344-355 Published by: The University of Chicago Press Stable URL: http://www.jstor.org/stable/10.1086/651242 . Accessed: 23/01/2012 20:55 Your use of the JSTOR archive indicates your acceptance of the Terms & Conditions of Use, available at . http://www.jstor.org/page/info/about/policies/terms.jsp JSTOR is a not-for-profit service that helps scholars, researchers, and students discover, use, and build upon a wide range of content in a trusted digital archive. We use information technology and tools to increase productivity and facilitate new forms of scholarship. For more information about JSTOR, please contact [email protected]. -
Recent Experimental Progress of Fractional Quantum Hall Effect: 5/2 Filling State and Graphene
Recent Experimental Progress of Fractional Quantum Hall Effect: 5/2 Filling State and Graphene X. Lin, R. R. Du and X. C. Xie International Center for Quantum Materials, Peking University, Beijing, People’s Republic of China 100871 ABSTRACT The phenomenon of fractional quantum Hall effect (FQHE) was first experimentally observed 33 years ago. FQHE involves strong Coulomb interactions and correlations among the electrons, which leads to quasiparticles with fractional elementary charge. Three decades later, the field of FQHE is still active with new discoveries and new technical developments. A significant portion of attention in FQHE has been dedicated to filling factor 5/2 state, for its unusual even denominator and possible application in topological quantum computation. Traditionally FQHE has been observed in high mobility GaAs heterostructure, but new materials such as graphene also open up a new area for FQHE. This review focuses on recent progress of FQHE at 5/2 state and FQHE in graphene. Keywords: Fractional Quantum Hall Effect, Experimental Progress, 5/2 State, Graphene measured through the temperature dependence of I. INTRODUCTION longitudinal resistance. Due to the confinement potential of a realistic 2DEG sample, the gapped QHE A. Quantum Hall Effect (QHE) state has chiral edge current at boundaries. Hall effect was discovered in 1879, in which a Hall voltage perpendicular to the current is produced across a conductor under a magnetic field. Although Hall effect was discovered in a sheet of gold leaf by Edwin Hall, Hall effect does not require two-dimensional condition. In 1980, quantum Hall effect was observed in two-dimensional electron gas (2DEG) system [1,2]. -
Human Visual Motion Perception Shows Hallmarks of Bayesian Structural Inference Sichao Yang1,2,6*, Johannes Bill3,4,6*, Jan Drugowitsch3,5,7 & Samuel J
www.nature.com/scientificreports OPEN Human visual motion perception shows hallmarks of Bayesian structural inference Sichao Yang1,2,6*, Johannes Bill3,4,6*, Jan Drugowitsch3,5,7 & Samuel J. Gershman4,5,7 Motion relations in visual scenes carry an abundance of behaviorally relevant information, but little is known about how humans identify the structure underlying a scene’s motion in the frst place. We studied the computations governing human motion structure identifcation in two psychophysics experiments and found that perception of motion relations showed hallmarks of Bayesian structural inference. At the heart of our research lies a tractable task design that enabled us to reveal the signatures of probabilistic reasoning about latent structure. We found that a choice model based on the task’s Bayesian ideal observer accurately matched many facets of human structural inference, including task performance, perceptual error patterns, single-trial responses, participant-specifc diferences, and subjective decision confdence—especially, when motion scenes were ambiguous and when object motion was hierarchically nested within other moving reference frames. Our work can guide future neuroscience experiments to reveal the neural mechanisms underlying higher-level visual motion perception. Motion relations in visual scenes are a rich source of information for our brains to make sense of our environ- ment. We group coherently fying birds together to form a fock, predict the future trajectory of cars from the trafc fow, and infer our own velocity from a high-dimensional stream of retinal input by decomposing self- motion and object motion in the scene. We refer to these relations between velocities as motion structure. -
Quantum Mechanics by Numerical Simulation of Path Integral
Quantum Mechanics by Numerical Simulation of Path Integral Author: Bruno Gim´enezUmbert Facultat de F´ısica, Universitat de Barcelona, Diagonal 645, 08028 Barcelona, Spain.∗ Abstract: The Quantum Mechanics formulation of Feynman is based on the concept of path integrals, allowing to express the quantum transition between two space-time points without using the bra and ket formalism in the Hilbert space. A particular advantage of this approach is the ability to provide an intuitive representation of the classical limit of Quantum Mechanics. The practical importance of path integral formalism is being a powerful tool to solve quantum problems where the analytic solution of the Schr¨odingerequation is unknown. For this last type of physical systems, the path integrals can be calculated with the help of numerical integration methods suitable for implementation on a computer. Thus, they provide the development of arbitrarily accurate solutions. This is particularly important for the numerical simulation of strong interactions (QCD) which cannot be solved by a perturbative treatment. This thesis will focus on numerical techniques to calculate path integral on some physical systems of interest. I. INTRODUCTION [1]. In the first section of our writeup, we introduce the basic concepts of path integral and numerical simulation. Feynman's space-time approach based on path inte- Next, we discuss some specific examples such as the har- grals is not too convenient for attacking practical prob- monic oscillator. lems in non-relativistic Quantum Mechanics. Even for the simple harmonic oscillator it is rather cumbersome to evaluate explicitly the relevant path integral. However, II. QUANTUM MECHANICS BY PATH INTEGRAL his approach is extremely gratifying from a conceptual point of view. -
Observables in Inhomogeneous Ground States at Large Global Charge
IPMU18-0069 Observables in Inhomogeneous Ground States at Large Global Charge Simeon Hellerman1, Nozomu Kobayashi1,2, Shunsuke Maeda1,2, and Masataka Watanabe1,2 1Kavli Institute for the Physics and Mathematics of the Universe (WPI),The University of Tokyo Institutes for Advanced Study, The University of Tokyo, Kashiwa, Chiba 277-8583, Japan 2Department of Physics, Faculty of Science, The University of Tokyo, Bunkyo-ku, Tokyo 133-0022, Japan Abstract As a sequel to previous work, we extend the study of the ground state configu- ration of the D = 3, Wilson-Fisher conformal O(4) model. In this work, we prove that for generic ratios of two charge densities, ρ1=ρ2, the ground-state configuration is inhomogeneous and that the inhomogeneity expresses itself towards longer spatial periods. This is the direct extension of the similar statements we previously made for ρ =ρ 1. We also compute, at fixed set of charges, ρ ; ρ , the ground state en- 1 2 1 2 ergy and the two-point function(s) associated with this inhomogeneous configuration 3=2 on the torus. The ground state energy was found to scale (ρ1 + ρ2) , as dictated by dimensional analysis and similarly to the case of the O(2) model. Unlike the case of the O(2) model, the ground also strongly violates cluster decomposition in the large-volume, fixed-density limit, with a two-point function that is negative definite at antipodal points of the torus at leading order at large charge. arXiv:1804.06495v1 [hep-th] 17 Apr 2018 Contents 1 Introduction3 2 Goldstone counting and the (in)homogeneity of large-charge ground states5 1 A comment on helical symmetries and chemical potentials .