Diffusion and Fluid Flow
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THE SOLUBILITY of GASES in LIQUIDS Introductory Information C
THE SOLUBILITY OF GASES IN LIQUIDS Introductory Information C. L. Young, R. Battino, and H. L. Clever INTRODUCTION The Solubility Data Project aims to make a comprehensive search of the literature for data on the solubility of gases, liquids and solids in liquids. Data of suitable accuracy are compiled into data sheets set out in a uniform format. The data for each system are evaluated and where data of sufficient accuracy are available values are recommended and in some cases a smoothing equation is given to represent the variation of solubility with pressure and/or temperature. A text giving an evaluation and recommended values and the compiled data sheets are published on consecutive pages. The following paper by E. Wilhelm gives a rigorous thermodynamic treatment on the solubility of gases in liquids. DEFINITION OF GAS SOLUBILITY The distinction between vapor-liquid equilibria and the solubility of gases in liquids is arbitrary. It is generally accepted that the equilibrium set up at 300K between a typical gas such as argon and a liquid such as water is gas-liquid solubility whereas the equilibrium set up between hexane and cyclohexane at 350K is an example of vapor-liquid equilibrium. However, the distinction between gas-liquid solubility and vapor-liquid equilibrium is often not so clear. The equilibria set up between methane and propane above the critical temperature of methane and below the criti cal temperature of propane may be classed as vapor-liquid equilibrium or as gas-liquid solubility depending on the particular range of pressure considered and the particular worker concerned. -
Pressure Diffusion Waves in Porous Media
Lawrence Berkeley National Laboratory Lawrence Berkeley National Laboratory Title Pressure diffusion waves in porous media Permalink https://escholarship.org/uc/item/5bh9f6c4 Authors Silin, Dmitry Korneev, Valeri Goloshubin, Gennady Publication Date 2003-04-08 eScholarship.org Powered by the California Digital Library University of California Pressure diffusion waves in porous media Dmitry Silin* and Valeri Korneev, Lawrence Berkeley National Laboratory, Gennady Goloshubin, University of Houston Summary elastic porous medium. Such a model results in a parabolic pressure diffusion equation. Its validity has been Pressure diffusion wave in porous rocks are under confirmed and “canonized”, for instance, in transient consideration. The pressure diffusion mechanism can pressure well test analysis, where it is used as the main tool provide an explanation of the high attenuation of low- since 1930th, see e.g. Earlougher (1977) and Barenblatt et. frequency signals in fluid-saturated rocks. Both single and al., (1990). The basic assumptions of this model make it dual porosity models are considered. In either case, the applicable specifically in the low-frequency range of attenuation coefficient is a function of the frequency. pressure fluctuations. Introduction Theories describing wave propagation in fluid-bearing porous media are usually derived from Biot’s theory of poroelasticity (Biot 1956ab, 1962). However, the observed high attenuation of low-frequency waves (Goloshubin and Korneev, 2000) is not well predicted by this theory. One of possible reasons for difficulties in detecting Biot waves in real rocks is in the limitations imposed by the assumptions underlying Biot’s equations. Biot (1956ab, 1962) derived his main equations characterizing the mechanical motion of elastic porous fluid-saturated rock from the Hamiltonian Principle of Least Action. -
Part Two Physical Processes in Oceanography
Part Two Physical Processes in Oceanography 8 8.1 Introduction Small-Scale Forty years ago, the detailed physical mechanisms re- Mixing Processes sponsible for the mixing of heat, salt, and other prop- erties in the ocean had hardly been considered. Using profiles obtained from water-bottle measurements, and J. S. Turner their variations in time and space, it was deduced that mixing must be taking place at rates much greater than could be accounted for by molecular diffusion. It was taken for granted that the ocean (because of its large scale) must be everywhere turbulent, and this was sup- ported by the observation that the major constituents are reasonably well mixed. It seemed a natural step to define eddy viscosities and eddy conductivities, or mix- ing coefficients, to relate the deduced fluxes of mo- mentum or heat (or salt) to the mean smoothed gra- dients of corresponding properties. Extensive tables of these mixing coefficients, KM for momentum, KH for heat, and Ks for salinity, and their variation with po- sition and other parameters, were published about that time [see, e.g., Sverdrup, Johnson, and Fleming (1942, p. 482)]. Much mathematical modeling of oceanic flows on various scales was (and still is) based on simple assumptions about the eddy viscosity, which is often taken to have a constant value, chosen to give the best agreement with the observations. This approach to the theory is well summarized in Proudman (1953), and more recent extensions of the method are described in the conference proceedings edited by Nihoul 1975). Though the preoccupation with finding numerical values of these parameters was not in retrospect always helpful, certain features of those results contained the seeds of many later developments in this subject. -
What Is High Blood Pressure?
ANSWERS Lifestyle + Risk Reduction by heart High Blood Pressure BLOOD PRESSURE SYSTOLIC mm Hg DIASTOLIC mm Hg What is CATEGORY (upper number) (lower number) High Blood NORMAL LESS THAN 120 and LESS THAN 80 ELEVATED 120-129 and LESS THAN 80 Pressure? HIGH BLOOD PRESSURE 130-139 or 80-89 (HYPERTENSION) Blood pressure is the force of blood STAGE 1 pushing against blood vessel walls. It’s measured in millimeters of HIGH BLOOD PRESSURE 140 OR HIGHER or 90 OR HIGHER mercury (mm Hg). (HYPERTENSION) STAGE 2 High blood pressure (HBP) means HYPERTENSIVE the pressure in your arteries is higher CRISIS HIGHER THAN 180 and/ HIGHER THAN 120 than it should be. Another name for (consult your doctor or immediately) high blood pressure is hypertension. Blood pressure is written as two numbers, such as 112/78 mm Hg. The top, or larger, number (called Am I at higher risk of developing HBP? systolic pressure) is the pressure when the heart There are risk factors that increase your chances of developing HBP. Some you can control, and some you can’t. beats. The bottom, or smaller, number (called diastolic pressure) is the pressure when the heart Those that can be controlled are: rests between beats. • Cigarette smoking and exposure to secondhand smoke • Diabetes Normal blood pressure is below 120/80 mm Hg. • Being obese or overweight If you’re an adult and your systolic pressure is 120 to • High cholesterol 129, and your diastolic pressure is less than 80, you have elevated blood pressure. High blood pressure • Unhealthy diet (high in sodium, low in potassium, and drinking too much alcohol) is a systolic pressure of 130 or higher,or a diastolic pressure of 80 or higher, that stays high over time. -
THE SOLUBILITY of GASES in LIQUIDS INTRODUCTION the Solubility Data Project Aims to Make a Comprehensive Search of the Lit- Erat
THE SOLUBILITY OF GASES IN LIQUIDS R. Battino, H. L. Clever and C. L. Young INTRODUCTION The Solubility Data Project aims to make a comprehensive search of the lit erature for data on the solubility of gases, liquids and solids in liquids. Data of suitable accuracy are compiled into data sheets set out in a uni form format. The data for each system are evaluated and where data of suf ficient accuracy are available values recommended and in some cases a smoothing equation suggested to represent the variation of solubility with pressure and/or temperature. A text giving an evaluation and recommended values and the compiled data sheets are pUblished on consecutive pages. DEFINITION OF GAS SOLUBILITY The distinction between vapor-liquid equilibria and the solUbility of gases in liquids is arbitrary. It is generally accepted that the equilibrium set up at 300K between a typical gas such as argon and a liquid such as water is gas liquid solubility whereas the equilibrium set up between hexane and cyclohexane at 350K is an example of vapor-liquid equilibrium. However, the distinction between gas-liquid solUbility and vapor-liquid equilibrium is often not so clear. The equilibria set up between methane and propane above the critical temperature of methane and below the critical temperature of propane may be classed as vapor-liquid equilibrium or as gas-liquid solu bility depending on the particular range of pressure considered and the par ticular worker concerned. The difficulty partly stems from our inability to rigorously distinguish between a gas, a vapor, and a liquid, which has been discussed in numerous textbooks. -
Pressure Vs. Volume and Boyle's
Pressure vs. Volume and Boyle’s Law SCIENTIFIC Boyle’s Law Introduction In 1642 Evangelista Torricelli, who had worked as an assistant to Galileo, conducted a famous experiment demonstrating that the weight of air would support a column of mercury about 30 inches high in an inverted tube. Torricelli’s experiment provided the first measurement of the invisible pressure of air. Robert Boyle, a “skeptical chemist” working in England, was inspired by Torricelli’s experiment to measure the pressure of air when it was compressed or expanded. The results of Boyle’s experiments were published in 1662 and became essentially the first gas law—a mathematical equation describing the relationship between the volume and pressure of air. What is Boyle’s law and how can it be demonstrated? Concepts • Gas properties • Pressure • Boyle’s law • Kinetic-molecular theory Background Open end Robert Boyle built a simple apparatus to measure the relationship between the pressure and volume of air. The apparatus ∆h ∆h = 29.9 in. Hg consisted of a J-shaped glass tube that was Sealed end 1 sealed at one end and open to the atmosphere V2 = /2V1 Trapped air (V1) at the other end. A sample of air was trapped in the sealed end by pouring mercury into Mercury the tube (see Figure 1). In the beginning of (Hg) the experiment, the height of the mercury Figure 1. Figure 2. column was equal in the two sides of the tube. The pressure of the air trapped in the sealed end was equal to that of the surrounding air and equivalent to 29.9 inches (760 mm) of mercury. -
High Blood Pressure: Weight Control
Sacramento Heart & Vascular Medical Associates February 18, 2012 500 University Ave. Sacramento, CA 95825 Page 1 916-830-2000 Fax: 916-830-2001 Patient Information For: Only A Test High Blood Pressure: Weight Control What is high blood pressure? Blood pressure is the force of blood against artery walls as the heart pumps blood through the body. High blood pressure (hypertension) is blood pressure that keeps being higher than normal. How is high blood pressure affected by weight? One of the most important causes of high blood pressure is overweight. An unhealthy weight puts stress on the heart and lungs, forcing them to work harder. Losing weight reduces the stress on your heart. It can also lower your blood pressure. What can I do to control my weight? Change your eating habits so that you lose 1 to 2 pounds a week until you reach a healthy weight. Even a modest weight loss of 5 to 10 pounds can help. Your diet needs to be low in fat, cholesterol, and salt. Be careful about serving sizes. Don't drink a lot of juice or soda. Also limit the amount of alcohol you drink. A regular, moderate exercise program can help you lose weight or keep a normal weight because it increases your metabolism and burns up calories. It reduces stress and promotes good health. Exercise also lowers your cholesterol and blood sugar levels. Ask your healthcare provider to recommend a diet and exercise program that is right for you. How long will the effects last? If you are overweight and have high blood pressure, you will need to control your blood pressure all of your life. -
Diffusion at Work
or collective redistirbution of any portion of this article by photocopy machine, reposting, or other means is permitted only with the approval of The Oceanography Society. Send all correspondence to: [email protected] ofor Th e The to: [email protected] Oceanography approval Oceanography correspondence POall Box 1931, portionthe Send Society. Rockville, ofwith any permittedUSA. articleonly photocopy by Society, is MD 20849-1931, of machine, this reposting, means or collective or other redistirbution article has This been published in hands - on O ceanography Oceanography Diffusion at Work , Volume 20, Number 3, a quarterly journal of The Oceanography Society. Copyright 2007 by The Oceanography Society. All rights reserved. Permission is granted to copy this article for use in teaching and research. Republication, systemmatic reproduction, reproduction, Republication, systemmatic research. for this and teaching article copy to use in reserved.by The 2007 is rights ofAll granted journal Copyright Oceanography The Permission 20, NumberOceanography 3, a quarterly Society. Society. , Volume An Interactive Simulation B Y L ee K arp-B oss , E mmanuel B oss , and J ames L oftin PURPOSE OF ACTIVITY or small particles due to their random (Brownian) motion and The goal of this activity is to help students better understand the resultant net migration of material from regions of high the nonintuitive concept of diffusion and introduce them to a concentration to regions of low concentration. Stirring (where variety of diffusion-related processes in the ocean. As part of material gets stretched and folded) expands the area available this activity, students also practice data collection and statisti- for diffusion to occur, resulting in enhanced mixing compared cal analysis (e.g., average, variance, and probability distribution to that due to molecular diffusion alone. -
What Is the Difference Between Osmosis and Diffusion?
What is the difference between osmosis and diffusion? Students are often asked to explain the similarities and differences between osmosis and diffusion or to compare and contrast the two forms of transport. To answer the question, you need to know the definitions of osmosis and diffusion and really understand what they mean. Osmosis And Diffusion Definitions Osmosis: Osmosis is the movement of solvent particles across a semipermeable membrane from a dilute solution into a concentrated solution. The solvent moves to dilute the concentrated solution and equalize the concentration on both sides of the membrane. Diffusion: Diffusion is the movement of particles from an area of higher concentration to lower concentration. The overall effect is to equalize concentration throughout the medium. Osmosis And Diffusion Examples Examples of Osmosis: Examples of osmosis include red blood cells swelling up when exposed to fresh water and plant root hairs taking up water. To see an easy demonstration of osmosis, soak gummy candies in water. The gel of the candies acts as a semipermeable membrane. Examples of Diffusion: Examples of diffusion include perfume filling a whole room and the movement of small molecules across a cell membrane. One of the simplest demonstrations of diffusion is adding a drop of food coloring to water. Although other transport processes do occur, diffusion is the key player. Osmosis And Diffusion Similarities Osmosis and diffusion are related processes that display similarities. Both osmosis and diffusion equalize the concentration of two solutions. Both diffusion and osmosis are passive transport processes, which means they do not require any input of extra energy to occur. -
Gas Exchange and Respiratory Function
LWBK330-4183G-c21_p484-516.qxd 23/07/2009 02:09 PM Page 484 Aptara Gas Exchange and 5 Respiratory Function Applying Concepts From NANDA, NIC, • Case Study and NOC A Patient With Impaired Cough Reflex Mrs. Lewis, age 77 years, is admitted to the hospital for left lower lobe pneumonia. Her vital signs are: Temp 100.6°F; HR 90 and regular; B/P: 142/74; Resp. 28. She has a weak cough, diminished breath sounds over the lower left lung field, and coarse rhonchi over the midtracheal area. She can expectorate some sputum, which is thick and grayish green. She has a history of stroke. Secondary to the stroke she has impaired gag and cough reflexes and mild weakness of her left side. She is allowed food and fluids because she can swallow safely if she uses the chin-tuck maneuver. Visit thePoint to view a concept map that illustrates the relationships that exist between the nursing diagnoses, interventions, and outcomes for the patient’s clinical problems. LWBK330-4183G-c21_p484-516.qxd 23/07/2009 02:09 PM Page 485 Aptara Nursing Classifications and Languages NANDA NIC NOC NURSING DIAGNOSES NURSING INTERVENTIONS NURSING OUTCOMES INEFFECTIVE AIRWAY CLEARANCE— RESPIRATORY MONITORING— Return to functional baseline sta- Inability to clear secretions or ob- Collection and analysis of patient tus, stabilization of, or structions from the respiratory data to ensure airway patency improvement in: tract to maintain a clear airway and adequate gas exchange RESPIRATORY STATUS: AIRWAY PATENCY—Extent to which the tracheobronchial passages remain open IMPAIRED GAS -
Quick Reference Guide on the Units of Measure in Hyperbaric Medicine
Quick Reference Guide on the Units of Measure in Hyperbaric Medicine This quick reference guide is excerpted from Dr. Eric Kindwall’s chapter “The Physics of Diving and Hyperbaric Pressures” in Hyperbaric Medicine Practice, 3rd edition. www.BestPub.com All Rights Reserved 25 THE PHYSICS OF DIVING AND HYPERBARIC PRESSURES Eric P. Kindwall Copyright Best Publishing Company. All Rights Reserved. www.BestPub.com INTRODUCTION INTRODUCTIONThe physics of diving and hyperbaric pressure are very straight forTheward physicsand aofr edivingdefi nanded hyperbaricby well-k npressureown a nared veryacce pstraightforwardted laws. Ga sandu narede r definedpres subyr ewell-knowncan stor eande nacceptedormous laws.ene rgGasy, underthe apressuremount scanof storewhi cenormoush are o fenergy,ten the samountsurprisin ofg. whichAlso, s arema loftenl chan surprising.ges in the pAlso,erce smallntage schangesof the inva rtheiou spercentagesgases use dofa there variousgrea gasestly m usedagni fareied greatlyby ch amagnifiednges in am byb ichangesent pre sinsu ambientre. The pressure.resultan t pTheh yresultantsiologic physiologiceffects d effectsiffer w idifferdely d ewidelypend idependingng on the onp rtheess upressure.re. Thus ,Thus,divi ndivingg or oorpe operatingrating a a hy- perbarichype rfacilitybaric f requiresacility re gainingquires gcompleteaining c oknowledgemplete kn ofow theled lawsge o finvolvedthe law stoin ensurevolved safety.to ensure safety. UNITS OF MEASURE UNITS OF MEASURE This is often a confusing area to anyone new to hyperbaric medicine as both Ameri- This is often a confusing area to anyone new to hyperbaric medicine as can and International Standard of Units (SI) are used. In addition to meters, centimeters, both American and International Standard of Units (SI) are used. In addition kilos,to pounds,meters, andcen feet,time someters, kpressuresilos, po uarend givens, an dinf atmosphereseet, some p rabsoluteessures andare millimetersgiven in of mercury.atmosph Tableeres 1a bgivessolu thete a exactnd m conversionillimeters factorsof me rbetweencury. -
Pressure and Fluid Statics
cen72367_ch03.qxd 10/29/04 2:21 PM Page 65 CHAPTER PRESSURE AND 3 FLUID STATICS his chapter deals with forces applied by fluids at rest or in rigid-body motion. The fluid property responsible for those forces is pressure, OBJECTIVES Twhich is a normal force exerted by a fluid per unit area. We start this When you finish reading this chapter, you chapter with a detailed discussion of pressure, including absolute and gage should be able to pressures, the pressure at a point, the variation of pressure with depth in a I Determine the variation of gravitational field, the manometer, the barometer, and pressure measure- pressure in a fluid at rest ment devices. This is followed by a discussion of the hydrostatic forces I Calculate the forces exerted by a applied on submerged bodies with plane or curved surfaces. We then con- fluid at rest on plane or curved submerged surfaces sider the buoyant force applied by fluids on submerged or floating bodies, and discuss the stability of such bodies. Finally, we apply Newton’s second I Analyze the rigid-body motion of fluids in containers during linear law of motion to a body of fluid in motion that acts as a rigid body and ana- acceleration or rotation lyze the variation of pressure in fluids that undergo linear acceleration and in rotating containers. This chapter makes extensive use of force balances for bodies in static equilibrium, and it will be helpful if the relevant topics from statics are first reviewed. 65 cen72367_ch03.qxd 10/29/04 2:21 PM Page 66 66 FLUID MECHANICS 3–1 I PRESSURE Pressure is defined as a normal force exerted by a fluid per unit area.