52nd Lunar and Planetary Science Conference 2021 (LPI Contrib. No. 2548) 2585.pdf LASER ABLATION MOLECULAR ISOTOPIC SPECTROMETRY AND TIME-RESOLVED LASER- INDUCED BREAKDOWN SPECTROSCOPY: IMPLICATIONS FOR PLANETARY EXPLORATION. M. Konstantinidis1,2, E. A. Lalla1, G. Lopez-Reyes3, E. A. Lymer1, J. Freemantle1, M. G. Daly1. 1Department of Earth & Space Science & Engineering, Lassonde School of Engineering, York University, Toronto, Ontario, Canada, (
[email protected]). 2Dalla Lana School of Public Health, University of Toronto, 155 College St. Toronto, Canada. 3Unidad Asociada Universidad de Valladolid-CSIC-CAB, C/Francisco Valles 8, 47151 Boecillo, Valladolid, Spain Introduction: The LIBS Raman Sensor (LiRS) capabilities are particularly important features for the instrument [1,2] is a breadboard design for future identification and possible quantification of isotopes – planetary exploration missions. It features two laser Carbon-12 (12C) and Carbon-13 (13C). sources – 1064 nm for Laser-induced Breakdown LAMIS: Laser Ablation Molecular Isotopic Spectroscopy (LIBS), and 266 nm for Raman Spectrometry (LAMIS) is a form of spectrometry by Spectroscopy, Laser-induced Fluorescence which laser-induced plasma emissions can be used for Spectroscopy (LIF), and Time-resolved LIF (TR-LIF). isotopic inferences. The characterization of isotopic These combined techniques allow for an in-depth behaviours is based on isotopic shifts (isotopologues) geochemical and biochemical characterization of from molecular emissions due to the association of free surface and sub-surface samples both in situ and for molecules in the “plasma afterglow” [4]. By quantifying sample return missions similar to OSIRIS-REx and the spectral intensity and shift, it is possible to estimate Mars2020. In particular, the LiRS instrument has been the relative abundance between elemental isotopes (e.g., found to provide 1) elemental identification, 2) 13C/12C).