Solid Earth Discuss., https://doi.org/10.5194/se-2018-12 Manuscript under review for journal Solid Earth Discussion started: 7 March 2018 c Author(s) 2018. CC BY 4.0 License. Constraints on Alpine Fault (New Zealand) Mylonitization Temperatures and Geothermal Gradient from Ti-in-quartz Thermobarometry Steven Kidder1, Virginia Toy2, Dave Prior2, Tim Little3, Colin MacRae 4 5 1Department of Earth and Atmospheric Science, City College New York, New York, 10031, USA 2Department of Geology, University of Otago, Dunedin, New Zealand 3School of Geography, Environment and Earth Sciences, Victoria University of Wellington, Wellington, New Zealand 4CSIRO Mineral Resources, Microbeam Laboratory, Private Bag 10, 3169 Clayton South, Victoria, Australia Correspondence to: Steven B. Kidder (
[email protected]) 10 Abstract. We constrain the thermal state of the central Alpine Fault using approximately 750 Ti-in-quartz SIMS analyses from a suite of variably deformed mylonites. Ti-in-quartz concentrations span more than an order of magnitude from 0.24 to ~5 ppm, suggesting recrystallization of quartz over a 300° range in temperature. Most Ti-in-quartz concentrations in mylonites, protomylonites, and the Alpine Schist protolith are between 2 and 4 ppm and do not vary as a function of grain size or bulk rock composition. Analyses of 30 large, inferred-remnant quartz grains (>250 µm), as well as late, cross-cutting, chlorite-bearing 15 quartz veins also reveal restricted Ti concentrations of 2-4 ppm. These results indicate that the vast majority of Alpine Fault mylonitization occurred within a restricted zone of pressure-temperature conditions where 2-4 ppm Ti-in-quartz concentrations are stable.