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PROGRAMME SUNDAY 14Th JULY PROGRAMME SUNDAY 14th JULY Time Amphitheater F 9.30 Welcome coffee 10.00 Short course 1: Chiroptical spectroscopy methods for structural analysis of chiral molecules Teachers: Giovanna LONGHI, University of Brescia, Italy Prasad POLAVARAPU, Vanderbilt University, USA 12.30 Lunch 13.30 Short courses 2 : Materials Teachers: Anja PALMANS, Eindhoven University of Technology, The Netherlands Gil MARKOVICH, University of Tel Aviv, Israel Amphitheater 1 16.00 Opening ceremony Reiko ODA, Research director, Univ. of Bordeaux / CNRS / Bordeaux INP Jeanne CRASSOUS, Research director, University of Rennes / CNRS Jérôme LACOUR, Research director, University of Geneva, Switzerland Philippe MORETTO, Vice president for Research, University of Bordeaux Erick DUFOURC, Deputy Scientific Director, Institute of Chemistry (INC) Leon GHOSEZ, Emeritus Professor UCL, University of Bordeaux, France 16.30 Award lecture: Laurence A. NAFIE, Syracuse University, USA Vibrational optical activity: discovery, development and future challenges 17.45 Chirality medal ceremony 18.00 Welcome reception 20.00 End Plenary PROGRAMME Keynote MONDAY 15th JULY AM Oral presentation AM Time Amphitheater 1 Amphitheater 2 AM 8:45 Donald HILVERT, ETH Zurich, Switzerland Chair: 9:30 Design and evolution of artificial metalloenzymes K. Saigo Polymer / materials 1 Spectroscopy 1 Chair: E. Hillard Chair: C. Merten Eiji YASHIMA, Nagoya University, Japan 9:30 Giovanna LONGHI, University of Brescia, Italy Control of macromolecular helicity for the 9:55 Circularly polarized luminescence of twisted conjugated systems development of unique chiral materials Tiziana BENINCORI, University of Insubria, Italy 9:55 Prasad POLAVARAPU, Vanderbilt University, USA The «inherent chirality» concept: a very simple tool for designing materials 10:15 Dissymmetry factor spectral analysis can be a useful diastereomer discrimination tool with impressive enantiodiscrimination ability Xinhua WAN, Peking University, China 10:15 Christian JOHANNESSEN, University of Antwerp, Belgium Induced circular dichroism of isotactic poly(2-vinylpyridine) with diverse 10:35 Resonance raman optical activity as a tool in structural biology: tales from the cold North and tunable «sergeants-and-soldiers» type chiral amplification Jochen BRANDT, Imperial College London, United Kingdom Tadashi MORI, Osaka University, Japan 10:35 Towards circularly polarized electroluminescence with Is there any meaningful correlation between emission and absorption 10:55 a high dissymmetry factor from chiral emitters dissymmetry factor values? Coffee break Coffee break Fundamentals Supramolecular 1 Chair: V. Rodriguez Chair: E. Yashima 11:15 Cornelia MEINERT, University of Côte d’Azur, France Jay SIEGEL, Tianjin University, China 11:40 The Asymmetry of life Chirality and corannulene Yukata OKAZAKI, Kyoto University, Japan 11:40 Eric GRELET, CRPP, University of Bordeaux, France Detection of chiralized monoatomic anions using molecular assembled nanohelices as 12:00 Chirality-controlled self-assembly via topological defects UV-transparent chiral template Donato MONTI, University of Rome Tor Vergata, Italy 12:00 Maxwell CROSSLEY, University of Sydney, Australia Supramolecular chirality and morphological features of homo and 12:20 The last fundamental form of stereoisomerism revealed ! heteroaggregates of zinc (l)- and (d)-proline-porphyrin derivatives. 12:20 David GONZALEZ RODRIGUEZ, University of Madrid, Spain Oliver TRAPP, Ludwig-Maximilians University, Germany * 12:40 Helically chiral self-assembled nanotubes through hierarchical Emergence of evolution and homochirality on a molecular level 12:45* coupling of cooperative interactions Lunch Lunch PROGRAMME Plenary th Keynote MONDAY 15 JULY PM Oral presentation PM 13:30 Poster session 1 (even numbers) Poster session 1 (even numbers) 14:50 Time Amphitheater 1 Amphitheater 2 Asymmetric 1 Chirality at nano 1 Chair : J. Canary Chair : B. Kauffmann Shinobu TAKISAWA, Osaka University, Japan Gil MARKOVICH, Tel Aviv University, Israel 14:50 Facile enantioselective synthesis of hetero[9]helicenes Spontaneous and directed symmetry breaking in the formation 15:10 using redox/acid cooperative catalysts of chiral lanthanide phosphate nanocrystals Jon ANTILLA, Tianjin University, China Zhifeng HUANG, Hong Kong Baptist University, China 15:10 Chiral phosphoric acid and metal chiral phosphate catalysis: double asymmetric Intrinsically chiral nanoparticles with sub-10 nm pitch: 15:30 catalytic reaction (dacr) and the arylation of indolyl methanols fabrication, characterization and applications Francesco TASSINARI, Weizmann Institute of Science, Israel Andrew GELLMAN, Carnegie Mellon University, USA 15:30 Enantioselective reduction of camphorsulphonic acid Surface structure sensitive enantioselectivity: 15:50 using a spin-polarized electrode quantification across chiral surface orientations Joanna WENCEL-DELORD, University of Strasbourg, France Shunai CHE, Shangaï Jiao Tong University, China 15:50 Sulfoxide as a new solution for accessing original chiral molecules Chirally mesostructured inorganic materials with optical activity 16:15 via C-H activation Coffee break Coffee break Supramolecular (bio) Physical computational Chair: G. Guichard Chair: T. Asahi Lucile FISCHER, University of Bordeaux, France 16:35 Inbal TUVI-ARAD, The Open University of Israel Chirality induction in oligoamide aromatic foldamers interacting 16:55 Protein chirality spectrum and chiral ramachandran plots with protein surfaces Nathan VAN ZEE, Eindhoven University of Technology, The Netherlands 16:55 Jiri KESSLER, Czech Academy of Sciences, Czech Republic Exploiting monomeric water in apolar environments to control the structure 17:15 Modeling of resonance-induced enhancement of solvent raman optical activity of supramolecular polymers 17:15 Jonathan CLAYDEN, University of Bristol, United Kingdom* Shira YOCHELIS, The Hebrew University of Jerusalem, Israel 17:35 Communicating chirality using molecular conformation Chirality and the electron spin 17:40* Michinori SUGINOME, Kyoto University, Japan Chair: 17:40 Asymmetric catalysis with chirality-amplifiable N. Berova 18:35 dynamic helical macromolecular catalysts Free evening Free evening Plenary PROGRAMME Keynote TUESDAY 16th JULY AM Oral presentation AM Time Amphitheater 1 Amphitheater 2 8:45 Virginie SIMONET, CNRS / Grenoble Alpes University, France 9:30 Magnetic chirality Chair: P. Rosa Supramolecular 2 Chiral resolution Chair: D. Walba Chair: C. Welch Jérôme LACOUR, University of Geneva, Switzerland Jun SHEN, Harbin Engineering University, China 9:30 Supramolecular chemistry and chiroptical spectroscopy Controlled synthesis and enantioseparation ability of polysaccharide 9:55 of readily prepared chiral macrocycles derivatives bearing various functional pendants Minghua LIU, Institute of Chemistry, China 9:55 Reiko KURODA, Chubu University, Japan Circularly polarized luminescence from supramolecular nanoassemblies 10:15 Spontaneous optical resolution in the crystalline state of pi-conjugated gelators Yann MAIRESSE, University of Bordeaux, France 10:15 Stephen GOLDUP, University of Southampton, United Kingdom Real-time determination of enantiomeric and isomeric content 10:35 Mechanical chirality and mechanical motion using photoelectron elliptical dichroism Chunhong ZHANG, Harbin Engineering University, China 10:35 Aya TANATANI, Ochanomizu University, Japan Synthesis of helical poly(phenylacetylene)s bearing l-proline dipeptide derivatives 10:55 Development of helical structures based on the aromatic squaramides with different sequences as pendants and their chiral recognition abilities Coffee break Coffee break Spectroscopy 2 Asymmetric 2 Chair: L. Guy Chair: S. Nlate Chiara CAPPELLI, Scuola Normale Superiore, Italy 11:15 Jieping ZHU, EPFL, Switzerland A fully polarizable embedding model for chiroptical spectroscopy 11:40 Ion-pairing in catalytic enantioselective rearrangements of complexsystems: status and perspectives Christian MERTEN, Ruhr-University Bochum, Germany Takanori SHIBATA, Waseda University, Japan 11:40 VCD spectroscopy as tool to investigate substrate binding Enantioselective construction of saddle-shaped chirality in 12:00 in asymmetric catalysts benzene-fused heteroatom-containing medium ring systems Reilly SONSTROM, University of Virginia, USA Christophe MICHON, University of Lille, France 12:00 Chiral analysis of molecules with multiple chiral center Development of chiral C -Symmetric N-Heterocyclic carbene Rh(I) catalysts through 12:20 2 using chiral tag rotational spectroscopy control of their steric properties 12:20 Lorenzo DI BARI, University of Pisa, Italy* Erika BENEDETTI, Paris Descartes University, France 12:40 Discrimination of circularly polarized light based on molecular, Highly enantioselective asymmetric transfer hydrogenation: a practical 12:45* supramolecular and mesoscopic chirality and scalable method to efficiently access planar chiral [2.2]paracyclophanes * Registration mandatory Lunch Vendor Lunch* Lunch Vendor Lunch* Plenary PROGRAMME Keynote TUESDAY 16th JULY PM Oral presentation PM 13:45 Poster session 2 (odd numbers) Poster session 2 (odd numbers) 14:50 Time Amphitheater 1 Amphitheater 2 Asymmetric 3 Polymer / materials 2 Chair: J. Lacour Chair: N. Avarvari Keiji MARUOKA, Kyoto University, Japan 14:50 Anja PALMANS Eindhoven University, The Netherlands Design of new, high-performance organocatalysts 15:15 From molecular to supramolecular chirality and back with privileged structures for asymmetric catalysis Timothée CADART, Charles University,
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