PROGRAMME SUNDAY 14th JULY

Time Amphitheater F 9.30 Welcome coffee

10.00 Short course 1: Chiroptical spectroscopy methods for structural analysis of chiral molecules

Teachers: Giovanna LONGHI, University of Brescia, Italy Prasad POLAVARAPU, Vanderbilt University, USA

12.30 Lunch

13.30 Short courses 2 : Materials

Teachers: Anja PALMANS, Eindhoven University of Technology, The Netherlands Gil MARKOVICH, University of Tel Aviv, Israel

Amphitheater 1

16.00 Opening ceremony

Reiko ODA, Research director, Univ. of Bordeaux / CNRS / Bordeaux INP Jeanne CRASSOUS, Research director, University of Rennes / CNRS Jérôme LACOUR, Research director, University of Geneva, Switzerland Philippe MORETTO, Vice president for Research, University of Bordeaux Erick DUFOURC, Deputy Scientific Director, Institute of Chemistry (INC) Leon GHOSEZ, Emeritus Professor UCL, University of Bordeaux, France

16.30 Award lecture: Laurence A. NAFIE, Syracuse University, USA Vibrational optical activity: discovery, development and future challenges

17.45 Chirality medal ceremony

18.00 Welcome reception

20.00 End Plenary PROGRAMME Keynote MONDAY 15th JULY AM Oral presentation AM Time Amphitheater 1 Amphitheater 2 AM

8:45 Donald HILVERT, ETH Zurich, Switzerland Chair: 9:30 Design and evolution of artificial metalloenzymes K. Saigo

Polymer / materials 1 Spectroscopy 1 Chair: E. Hillard Chair: C. Merten

Eiji YASHIMA, Nagoya University, Japan 9:30 Giovanna LONGHI, University of Brescia, Italy Control of macromolecular helicity for the 9:55 Circularly polarized luminescence of twisted conjugated systems development of unique chiral materials

Tiziana BENINCORI, University of Insubria, Italy 9:55 Prasad POLAVARAPU, Vanderbilt University, USA The «inherent chirality» concept: a very simple tool for designing materials 10:15 Dissymmetry factor spectral analysis can be a useful diastereomer discrimination tool with impressive enantiodiscrimination ability Xinhua WAN, Peking University, China 10:15 Christian JOHANNESSEN, University of Antwerp, Belgium Induced circular dichroism of isotactic poly(2-vinylpyridine) with diverse 10:35 Resonance raman optical activity as a tool in structural biology: tales from the cold North and tunable «sergeants-and-soldiers» type chiral amplification Jochen BRANDT, Imperial College London, United Kingdom Tadashi MORI, Osaka University, Japan 10:35 Towards circularly polarized electroluminescence with Is there any meaningful correlation between emission and absorption 10:55 a high dissymmetry factor from chiral emitters dissymmetry factor values?

Coffee break Coffee break

Fundamentals Supramolecular 1 Chair: V. Rodriguez Chair: E. Yashima

11:15 Cornelia MEINERT, University of Côte d’Azur, France Jay SIEGEL, Tianjin University, China 11:40 The Asymmetry of life Chirality and corannulene

Yukata OKAZAKI, Kyoto University, Japan 11:40 Eric GRELET, CRPP, University of Bordeaux, France Detection of chiralized monoatomic anions using molecular assembled nanohelices as 12:00 Chirality-controlled self-assembly via topological defects UV-transparent chiral template Donato MONTI, University of Rome Tor Vergata, Italy 12:00 Maxwell CROSSLEY, University of Sydney, Australia Supramolecular chirality and morphological features of homo and 12:20 The last fundamental form of stereoisomerism revealed ! heteroaggregates of zinc (l)- and (d)-proline-porphyrin derivatives. 12:20 David GONZALEZ RODRIGUEZ, University of Madrid, Spain Oliver TRAPP, Ludwig-Maximilians University, Germany * 12:40 Helically chiral self-assembled nanotubes through hierarchical Emergence of evolution and homochirality on a molecular level 12:45* coupling of cooperative interactions

Lunch Lunch PROGRAMME Plenary th Keynote MONDAY 15 JULY PM Oral presentation PM

13:30 Poster session 1 (even numbers) Poster session 1 (even numbers) 14:50

Time Amphitheater 1 Amphitheater 2 Asymmetric 1 Chirality at nano 1 Chair : J. Canary Chair : B. Kauffmann Shinobu TAKISAWA, Osaka University, Japan Gil MARKOVICH, Tel Aviv University, Israel 14:50 Facile enantioselective synthesis of hetero[9]helicenes Spontaneous and directed symmetry breaking in the formation 15:10 using redox/acid cooperative catalysts of chiral lanthanide phosphate nanocrystals Jon ANTILLA, Tianjin University, China Zhifeng HUANG, Hong Kong Baptist University, China 15:10 Chiral phosphoric acid and metal chiral phosphate catalysis: double asymmetric Intrinsically chiral nanoparticles with sub-10 nm pitch: 15:30 catalytic reaction (dacr) and the arylation of indolyl methanols fabrication, characterization and applications Francesco TASSINARI, Weizmann Institute of Science, Israel Andrew GELLMAN, Carnegie Mellon University, USA 15:30 Enantioselective reduction of camphorsulphonic acid Surface structure sensitive enantioselectivity: 15:50 using a spin-polarized electrode quantification across chiral surface orientations

Joanna WENCEL-DELORD, University of Strasbourg, France Shunai CHE, Shangaï Jiao Tong University, China 15:50 Sulfoxide as a new solution for accessing original chiral molecules Chirally mesostructured inorganic materials with optical activity 16:15 via C-H activation

Coffee break Coffee break

Supramolecular (bio) Physical computational Chair: G. Guichard Chair: T. Asahi Lucile FISCHER, University of Bordeaux, France 16:35 Inbal TUVI-ARAD, The Open University of Israel Chirality induction in oligoamide aromatic foldamers interacting 16:55 Protein chirality spectrum and chiral ramachandran plots with protein surfaces Nathan VAN ZEE, Eindhoven University of Technology, The Netherlands 16:55 Jiri KESSLER, Czech Academy of Sciences, Czech Republic Exploiting monomeric water in apolar environments to control the structure 17:15 Modeling of resonance-induced enhancement of solvent raman optical activity of supramolecular polymers

17:15 Jonathan CLAYDEN, University of Bristol, United Kingdom* Shira YOCHELIS, The Hebrew University of Jerusalem, Israel 17:35 Communicating chirality using molecular conformation Chirality and the electron spin 17:40*

Michinori SUGINOME, Kyoto University, Japan Chair: 17:40 Asymmetric catalysis with chirality-amplifiable N. Berova 18:35 dynamic helical macromolecular catalysts

Free evening Free evening Plenary PROGRAMME Keynote TUESDAY 16th JULY AM Oral presentation AM Time Amphitheater 1 Amphitheater 2

8:45 Virginie SIMONET, CNRS / Grenoble Alpes University, France 9:30 Magnetic chirality Chair: P. Rosa

Supramolecular 2 Chiral resolution Chair: D. Walba Chair: C. Welch

Jérôme LACOUR, University of Geneva, Switzerland Jun SHEN, Harbin Engineering University, China 9:30 Supramolecular chemistry and chiroptical spectroscopy Controlled synthesis and enantioseparation ability of polysaccharide 9:55 of readily prepared chiral macrocycles derivatives bearing various functional pendants

Minghua LIU, Institute of Chemistry, China 9:55 Reiko KURODA, Chubu University, Japan Circularly polarized luminescence from supramolecular nanoassemblies 10:15 Spontaneous optical resolution in the crystalline state of pi-conjugated gelators Yann MAIRESSE, University of Bordeaux, France 10:15 Stephen GOLDUP, University of Southampton, United Kingdom Real-time determination of enantiomeric and isomeric content 10:35 Mechanical chirality and mechanical motion using photoelectron elliptical dichroism Chunhong ZHANG, Harbin Engineering University, China 10:35 Aya TANATANI, Ochanomizu University, Japan Synthesis of helical poly(phenylacetylene)s bearing l-proline dipeptide derivatives 10:55 Development of helical structures based on the aromatic squaramides with different sequences as pendants and their chiral recognition abilities

Coffee break Coffee break

Spectroscopy 2 Asymmetric 2 Chair: L. Guy Chair: S. Nlate

Chiara CAPPELLI, Scuola Normale Superiore, Italy 11:15 Jieping ZHU, EPFL, Switzerland A fully polarizable embedding model for chiroptical spectroscopy 11:40 Ion-pairing in catalytic enantioselective rearrangements of complexsystems: status and perspectives

Christian MERTEN, Ruhr-University Bochum, Germany Takanori SHIBATA, Waseda University, Japan 11:40 VCD spectroscopy as tool to investigate substrate binding Enantioselective construction of saddle-shaped chirality in 12:00 in asymmetric catalysts benzene-fused heteroatom-containing medium ring systems Reilly SONSTROM, University of Virginia, USA Christophe MICHON, University of Lille, France 12:00 Chiral analysis of molecules with multiple chiral center Development of chiral C -Symmetric N-Heterocyclic carbene Rh(I) catalysts through 12:20 2 using chiral tag rotational spectroscopy control of their steric properties

12:20 Lorenzo DI BARI, University of Pisa, Italy* Erika BENEDETTI, Paris Descartes University, France 12:40 Discrimination of circularly polarized light based on molecular, Highly enantioselective asymmetric transfer hydrogenation: a practical 12:45* supramolecular and mesoscopic chirality and scalable method to efficiently access planar chiral [2.2]paracyclophanes * Registration mandatory

Lunch Vendor Lunch* Lunch Vendor Lunch* Plenary PROGRAMME Keynote TUESDAY 16th JULY PM Oral presentation PM

13:45 Poster session 2 (odd numbers) Poster session 2 (odd numbers) 14:50

Time Amphitheater 1 Amphitheater 2 Asymmetric 3 Polymer / materials 2 Chair: J. Lacour Chair: N. Avarvari

Keiji MARUOKA, Kyoto University, Japan 14:50 Anja PALMANS Eindhoven University, The Netherlands Design of new, high-performance organocatalysts 15:15 From molecular to supramolecular chirality and back with privileged structures for asymmetric catalysis

Timothée CADART, Charles University, Czech Republic 15:15 Max HIRSCHMANN, Technische Universität Darmstadt, Germany Synthesis of enantioenriched helical bispiroindeno[2,1-c]fluorenes 15:35 Thermo- and magnetoresponsive polyaspartates via an enantioselective [2+2+2] cyclotrimerization step Mohamed AMEDJKOUH, University of Oslo, Norway Girish LAKHWANI, University of Sydney, Australia 15:35 Remote asymmetric amplification in synergistic Hierarchical self-assembly of chiral Perylene Imide based 15:55 and responsive autocatalytic systems organogelators explained Marine MICHEL, Imperial College London, United Kingdom 15:55 Yannick GEIGER, IPCM Strasbourg, France Enantioselective polymeric membranes for chiral separation: 16:15 First observation of hyperpositive non-linear effects in asymmetric catalysis comparison of pressure driven separation, pertraction and preferential sorption Coffee break Coffee break Enantioseparation Chirality at Nano 2 Chair: C. Villani Chair: E. Pouget

16:35 Pilar FRANCO, Chiral Technologies, France Nathalie KATSONIS University of Twente, The Netherlands 17:00 Chirality in chromatography: where should innovation go ? Chirality-derived motion of protocells

17:00 Ashraf GHANEM, University of Canberra, Australia Davy GERARD, University of Troyes, France 17:20 Chirality at the dried blood spot: enantioselective analysis of pharmaceuticals Probing optical chirality in the near-field of plasmonic nanostructures on sub two micron columns with photosensitive azobenzene-containing polymers Ben SLATER, Imperial College London, United Kingdom 17:20 Ventsislav VALEV, University of Bath, United Kingdom Mechanistic detail of enantioselective adsorption 17:40 First observation of optical activity in hyper-rayleigh scattering in a chiral metal organic framework KENJI HAMASE, Kyushu University, Japan 17:40 Ignacio GARZON, University of Mexico, Mexico Multi-dimensional HPLC analysis of chiral α-amino acids 18:00 Chirality in bare and ligand-protected metal nanoparticles and carboxylic acids in extraterrestrial materials

Zachary BREITBACH, AbbVie Inc., USA Hirotaka IHARA, University of Kumamoto, Japan 18:00 Evaluation of newly commercialized sub-2 µm chiral stationary phases Strong and tunable circularly polarized luminescence induced 18:25 in SFC and HPLC by chiral supramolecular gel

18:45 Departure for gala dinner at Chateau Smith Haut Lafitte Departure for gala dinner at Chateau Smith Haut Lafitte PROGRAMME Plenary th Keynote WEDNESDAY 17 JULY AM Oral presentation AM

Time Amphitheater 1 Amphitheater 2

8:45 Nicholas KOTOV, University of Michigan, USA Chair: 9:30 Chiral Inorganic Nanostructures W. Lindner

Spectroscopy 3 Polymer / Materials 3 Chair: L. Di Bari Chair: I. Azumaya

9:30 Petr BOUR, University of Prague, Czech Republic Narcis AVARVARI, University of Angers, France 9:55 Interpretation of optical activity spectra of proteins Chiral materials based on tetrathiafulvalene and metal-dithiolene complexes

Wada TAKEHIKO, Tohoku University, Japan Karl-Heinz ERNST, Swiss Federal Laboratories for Materials Science and 9:55 Development of high sensitive and high time-resolved circular dichroism (CD) Technology, Switzerland 10:15 measurement system “Toward the analyses of biomolecular interactions and On-surface topochemistry of helicenes their dynamics“ Anne ZEHNACKER, Institut des Sciences Moléculaires d’Orsay, France 10:15 Félix FREIRE, University of Santiago de Compostela, Spain Vibrational circular dichroism study of the solid-state organisation of ring- 10:35 Sergeants and soldiers effect in chiral dynamic helical copolymers containing peptides Sergio ABBATE, University of Brescia, Italy Katsuhiro MAEDA, Kanazawa University, Japan 10:35 How to deal with anharmonicities in various circumstances to obtain safe Synthesis of a single-handed helical poly(diphenylacetylene) derivative based on 10:55 conformational and configurational information from VCD spectra helicity induction and memory effect and its conformational analysis

Coffee break Coffee break

Supramolecular 4 Asymmetric 4 Chair: T. Brotin Chair: Y. Landais Tsuneomi KAWASAKI, Tokyo University of Science, Japan 11:15 Kim JI-YOUNG, University of Michigan, USA Asymmetric Strecker-type synthesis by using chiral amine arising from hydrogen 11:35 Circularly polarized light driven chiral assembly of gold nanoparticles isotope substitution 11:35 Stéphane LE GAC, University of Rennes 1, France Wim NOORDUIN, AMOLF Institute, The Netherlands 12:00 Towards chiroptical sensing from Möbius-type receptors Physicochemical routes to enantiomeric purity Kazushi KINBARA, Tokyo Institute of Technology, Japan 12:00 Takeo KAWABATA, Kyoto University, Japan Design of synthetic chiral receptor molecules inspired 12:20 5Å-Hypothesis for remote asymmetric induction by structure and function of membrane proteins

12:20 Matthieu RAYNAL, Sorbonne University, France Stephen FLETCHER, University of Oxford, United Kingdom* 12:40 Dynamic asymmetric catalysis by tuning the structure Asymmetric additions to racemates 12:45* of supramolecular helices

Lunch Lunch PROGRAMME WEDNESDAY 17th JULY PM

Time Amphitheater 1 Chair: O.Trapp

13:45 Yunjie XU, University of Alberta, Canada 14:30 Conformational landscapes and non-covalent interactions of chiral molecules: chirality recognition/transfer/amplification

14:30 Alexander KUHN, University of Bordeaux / CNRS / Bordeaux INP, France 15:15 Chiral biomimetic metal electrodes for enantioselective analysis, separation and synthesis

15:15 Poster awards - Closing remarks 16:00 Presentation of CHIRALITY 2020

End