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Alternative Effects on Emissions and Contrails

Dr. Bruce Anderson Senior Research Scientist NASA Langley Research Center Hampton Virgi

#SerdpEstcp2018 DISTRIBUTION A. Approved for public release: distribution unlimited. What are the Environmental Impacts of Aviation?

• Aerosol and gas-phase emissions effect air quality near airports • NOx emissions effect background Ozone concentrations at altitude • Aerosols affect air quality and influence cloud formation and radiative properties • Contrails, Black Carbon, Ozone

and CO2 can enhance climate impacts

Military accounts for >10% of U.S. Jet Fuel Consumption, is Partially Responsible for Impacts

2 #SerdpEstcp2018 DISTRIBUTION A. Approved for public release: distribution unlimited. Military Aircraft have Special Emissions Problems

• Still using older engine technologies, such as turbo-jet engines shown above • Aircraft designed to optimize performance over economy and emissions--i.e., low-bypass engines with augmenters used on fighters and bombers • Many military have special properties to meet mission requirements

3 #SerdpEstcp2018 DISTRIBUTION A. Approved for public release: distribution unlimited. Inflight Measurements Show Fuel S and are Large Sources of PM Emissions

17 10 8 6

4

2

16 10 8 6

4

nvPMEmissions (#/kg) 2

15 10 70 80 90 100 Engine (%) • Fighter aircraft emit 5-10 times more soot than commercial aircraft • operations increase soot emissions by 10 to 20 • Fuel sulfur increases total PM emissions by 10 to 100

4 #SerdpEstcp2018 DISTRIBUTION A. Approved for public release: distribution unlimited. CO2 emissions a major concern for commercial aviation as air travel is growing 2-3% per year CO2 and Clouds from Aviation Already Account for 5% of Anthropogenic Climate Impacts

Bonus: Sustainable jet fuels should also produce lower soot and sulfate emissions

ICAO goal is to reduce aircraft

CO2 emissions 50% by 2050

5 #SerdpEstcp2018 DISTRIBUTION A. Approved for public release: distribution unlimited. U.S. Federal Agencies are Collaborating to Develop Alt Fuels

Economic and environmental sustainability analysis across entire supply chain

Feedstock Feedstock Conversion Fuel Testing/Approval Fuel Process Scale- Fuel Environment Enable End User/ Logistics Production Conversion up/Integration Performance Assmt Production Buyer

USDA     ------ --- DOC ------ ---

DOE     ---   ---

DoD  ---     ---  FAA, DOD and EPA ------  --- NASA Primarily Focusing on FAA ------  ---  Aviation Fuels NASA ------  ------6 #SerdpEstcp2018 DISTRIBUTION A. Approved for public release: distribution unlimited. NASA is Leading Effort to Assess Effects on Emissions and Contrails

Year Project Location Test Article Fuels 2008 PW308 West Palm Pratt PW308 Jet A, FT, 50% FT

2009 AAFEX-1 Palmdale DC-8 Jet A, FT (gas), FT (coal), 50% blends

2011 AAFEX-2 Palmdale DC-8 Jet A, HEFA, 50% HEFA, FT (gas) 2013 *ACCESS-1 Palmdale DC-8 Jet A, 50% HEFA

2014 *ACCESS-2 Palmdale DC-8 Jet A, 50% HEFA

2015 CONEX Cleveland APU Jet A, Alt Fuels, Blends

2015 *ECLIF-1 Manching DLR A320 2 Jet A ref fuels, 4 Blends

2018 *NDMAX ECLIF Ramstein DLR A320 Jet A ref fuels, 3 Blends

* Flight Projects with Ground Measurements 7 #SerdpEstcp2018 DISTRIBUTION A. Approved for public release: distribution unlimited. Alternative Fuels Studied in NASA Tests, most obtain from AFRL

Coal FT Natural Gas FT Shell ~35% C10 & C11 Fuels Vary 0.4% ~60% C & C ~48% C9 & C10 12.0% 10 11 Considerably in 46.7% 87.6% i-paraffins 53.3% n-paraffins cycloparaffins i-paraffins Composition aromatics

High degree branching Mild degree branching Alternative Fuels contain < 0.5% Petroleum Animal Fat or Plant Oil JP-8 HRJ Aromatics and < 20 5% 15% ppm Sulfur 18.7% 19.0% n-paraffins n-paraffins i-paraffins 31.0% 31.3% i-paraffins cycloparaffins cycloparaffins aromatics 80%

8 #SerdpEstcp2018 DISTRIBUTION A. Approved for public release: distribution unlimited. Alternative Experiment (AAFEX-1) Multi-Agency Collaboration to Study Fischer-Tropsch Fuels

Huge Reductions in nvPM Number, Mass and Particle Size seen when Burning Alternative Fuels Objectives • Create gaseous and particulate emission profiles as a function of fuel-type and engine power; • Investigate the factors that control volatile aerosol formation and growth • Establish aircraft APU emission characteristics and examine their dependence on fuel composition

9 #SerdpEstcp2018 DISTRIBUTION A. Approved for public release: distribution unlimited. Systematic Tests with APU Show Soot Emissions Vary Directly with Fuel Aromatic Content, Inversely with %H

15 4.0x10 500

3.5 400 3.0 300 2.5 200 2.0

1.5 100 nvPMNumber EI (#/kg) Red=SAK; Green=AR100; Blue=AFBlend nvPMMass EI (mg/kg) Red=SAK; Green=AR100; Blue=AFBlend 1.0 0 0 5 10 15 20 25 0 5 10 15 20 25 Percent Aromatic Additive Percent Aromatic Additive

• Added different SAKs to pure alternative fuel (Sasol) • Varied SAK percentage from 0 to 24% • nvPM (soot) number, mass and size increased directly with aromatics, inversely with %H content • nvPM emissions increase with naphthalene fraction

10 #SerdpEstcp2018 DISTRIBUTION A. Approved for public release: distribution unlimited. Motivation for Flight Experiments

14 13 12 • Almost 90% of Jet fuel burned during flight 11 10 9 • Cruise-level power settings are very poorly simulated in 8

7 ground tests 6 Fuel Burn

Altitude (km) 5 4 • Particle emission parameters are very temperature 3 2 dependent--ground-level tests cannot replicate the cold, dry 1 0 5 10 15 20 25 30 conditions present at flight altitudes % Fuel Consumption • Emission impacts on contrails cannot be assessed at ground 14 13 12 level 11 10 • Very little data available to relate ground-based PM emission

Altitude (km) Altitude 9 8

7 NOx parameters to cruise altitude emissions; data for black carbon 6

Altitude (km) 5 Emissions mass/number emissions are particularly lacking 4 3 2 • Very little data available to relate aircraft PM emissions to 1 0 5 10 15 20 25 30 contrail formation and microphysical characteristics % NOx Emissions 11 #SerdpEstcp2018 DISTRIBUTION A. Approved for public release: distribution unlimited. Sampling Platforms

DLR Falcon 20 ACCESS-II, ECLIF-1 Falcons slow, but can sample up close; DC-8 fast, but has to sample >5 km NASA Falcon HU-25C ACCESS-I, ACCESS-II

NASA DC-8 NDMAX/ECLIF

12 #SerdpEstcp2018 DISTRIBUTION A. Approved for public release: distribution unlimited. Source Aircraft

DLR A320 Advanced Technology Research Aircraft V2527-A5 engines 26,600 lbs thrust ECLIF-1, NDMAX/ECLIF

NASA DC-8-72 CFM56-2C Engines 22,000 lbs thrust each AAFEX-1, AAFEX-2, ACCESS-I, ACCESS-II

13 #SerdpEstcp2018 DISTRIBUTION A. Approved for public release: distribution unlimited. Sample Platforms Equipped with Probes and Inlets

Gas/Aerosol Inlets Measured aerosols and trace gases CVI Inlet using cabin-mounted instruments; Cloud particles measured with open-path sensors on wings Counter-Flow Virtual Trace-Gas Impactor Inlet Inlets H2O(v) Inlet

FFSSP Cloud Probe Aerosol Inlets

#SerdpEstcp2018 DISTRIBUTION A. Approved for14 public release: distribution unlimited. Example Research Flight from ACCESS-2

15 #SerdpEstcp2018 DISTRIBUTION A. Approved for public release: distribution unlimited. Time Series for Typical Set of ACCESS-2 Maneuvers

16 #SerdpEstcp2018 DISTRIBUTION A. Approved for public release: distribution unlimited. Combined Mission Accomplishments

ACCESS-II, 2014 • 8 flights, 25 hours, 3 fuels • Near-field emissions, very few contrail observations • 1 ground test, 3-hour DC-8 runtime

ECLIF-1, 2015 • 9 flights, 35 hours, 6 fuels • Near-field emissions, good contrail observations • 10 ground tests, 8-hour A320 runtime

NDMAX/ECLIF, 2018 • 8 flights, ~40 hours, 4 fuels • 1 Emission survey flight, 6 hrs • Very good contrail observations • 9 ground tests, 10-hour A320 runtime

17 #SerdpEstcp2018 DISTRIBUTION A. Approved for public release: distribution unlimited. ACCESS-2 Results Show that 50% Blends Reduce nvPM Emissions by 30 to 70% at Cruise

Blend nvPM emissions are also smaller, and more spherical in shape

Moore et al., NATURE, 2017

18 #SerdpEstcp2018 DISTRIBUTION A. Approved for public release: distribution unlimited. ECLIF A320 Ground Emissions Consistent with APU Test Results

15 500 7x10 14.6 FuelContent Hydrogen 14.6 FuelContent Hydrogen Engine 2 6 Number 400 14.4 14.4 5 Soot number, 14.2 14.2 300 4 mass and size 14.0 14.0 200 3 decrease with 13.8 13.8 100

2 BCMass EI (mg/kg) increasing nvPMNumber EI (#/kg) MassEngine 2 1 0 alternative- 20 30 40 50 60 70 80 20 30 40 50 60 70 80 Thrust (N1) fuel fraction Thrust (N1) Schripp et al., Environ. Sci. Technol. 2018, 52, 4969−4978

50 100 14.6 %Hydrogen Content %Hydrogen

14.6 Content Hydrogen % 45 90 14.4 14.4 40 14.2 14.2 80 35 14.0 14.0 70 30 13.8 13.8 Engine 2 Number-Size 60 25 MassEngine-Size 2

20 Volume MeanDiameter (nm) 50 Geometric MeanDiameter (nm) 20 30 40 50 60 70 80 20 30 40 50 60 70 80 Thrust (N1) 19 Thrust (N1) #SerdpEstcp2018 DISTRIBUTION A. Approved for public release: distribution unlimited. NDMAX Confirms that Soot Regulates EI_ice

4E+15 4E+15

3E+15 3E+15 Data Courtesy -1 -1 of C. Voigt, DLR

/ kg / 2E+15 kg / 2E+15

ice ice

EI EI

1E+15 1E+15

0E+00 0E+00 Blend 1 Blend 2 Ref 3 Blend 1 Blend 2 Ref 3 24/01/2018 23/01/2018 29/01/2018 24/01/2018 23/01/2018 29/01/2018 Results very preliminary Median RHi 116 % 107 % 111 % Median RHi 109 % 108 % 111 % StdDev RHi 9.9 % 7.0 % 13.1 % StdDev RHi 8.8 % 6.9 % 8.5 %

Flight Level 380, Mach Number 0.76 Flight Level 380, Mach Number 0.8

20 #SerdpEstcp2018 DISTRIBUTION A. Approved for public release: distribution unlimited. Summary of Results So Far

 Aircraft performance at cruise not affected by burning 50% Alt fuel blends

 No discernable difference in NOx and CO emissions between fuels, even for pure Alt fuels versus standard Jet A  nvPM number and mass emissions and particle size varies linearly with fuel C:H ratio, inversely with %H  50% blends reduce nvPM number and mass emissions by ~30 to 80% on ground and at cruise  Contrail ice concentrations proportional to soot emissions-- may be possible to greatly reduce contrail visibility and lifetime using pure alt fuels or engines with lower PM emissions Note: U.S. Air Force has reached goal of certifying their aircraft to burn 50% blends of alt fuels

21 #SerdpEstcp2018 DISTRIBUTION A. Approved for public release: distribution unlimited. Questions?

22 #SerdpEstcp2018 DISTRIBUTION A. Approved for public release: distribution unlimited. What are the Benefits of Burning Alternative Fue

• Fuels can be produced from renewable feed stocks, can reduce GHG accumulation in the atmosphere and acidification of oceans • Fuels can be designed to burn much cleaner, can mitigate AQ problems in EPA non- attainment areas • Fuels can be produced domestically, reduce dependence on foreign suppliers • Possible that fuels can be produced at costs competitive with , could give US economy time to transition to other more efficient, less environmentally damaging energy sources • For aircraft, lower soot- and sulfuric acid-producing fuels may reduce condensation trail formation and decrease aviation climate impacts. U.S. Air Force has already reached goal of certifying all their aircraft to burn 50% blends of alt fuels

23 #SerdpEstcp2018 DISTRIBUTION A. Approved for public release: distribution unlimited.