DOCSLIB.ORG

Polyolefin Catalyst Market Overview

Total Page：16

File Type：pdf, Size：1020Kb

Download full-text PDF Read full-text
Polyolefin Catalyst Market Overview Technical & Commercial Progress in the Global Catalyti c Process Industries THE CATALYST REVIEW April 2014 A Publicati on of The Catalyst Group Resources, Inc. Volume 27, Issue 4 Polyolefi n Catalyst Market Overview InsideIndustry Media Rumors: Review: U.S. Carbon Energy Capture...Policy. The Catalyst Review April 2014 1 Jennifer Wilcox CONTENTS THE CATALYST REVIEW (ISSN 0898-3089) April 2014, Volume 27, Number 4 The Catalyst Review is designed to provide readers with a Published by The Catalyst Group global overview of events impacting the $23 billion catalyst industry, Resources, Inc., 750 Bethlehem Pike, through selected abstracts, company interviews, and original Lower Gwynedd, PA 19002, USA articles. There is also a special "Industry Rumors" column that gives +1-215-628-4447 Fax +1-215-628-2267 a view of what's going on behind the scenes, too. Reader questions [email protected] and comments are welcomed, to provide an additional value to subscribers. This POSTMASTER: Send address changes to: The Catalyst Group Resources, Inc. reinforces the purpose of The Catalyst Review, which is to provide a timely line on 750 Bethlehem Pike key news and research, in an easy-to-digest format. Lower Gwynedd, PA 19002, USA For more information or to request a trial subscription, please call The Catalyst Group Copyright 2014 The Catalyst Group Resources at +1-215-628-4447, or e-mail [email protected]. Resources, Inc. All rights reserved. Legal Disclaimer. Copyright Clearance Center. The Catalyst Group Resources, Inc. is a division of The Catalyst Group, Inc., a worldwide techni- In This Issue cal & commercial consultancy specializing in Commercial News chemical process-driven change. The Catalyst Group Resources, Inc. is dedicated to helping Shale Gas to Drive New Capacity Wave. .................................................................2 clients understand the business impacts of technology change. Enhance Competitiveness of China’s Propylene Oxide Industry through Innovation and Industrial Chain Extension. ............................................................2 CEO Clyde F. Payn JX Nippon Oil & Energy HS-FCC Technology Demonstrated. ..................................2 PRESIDENT GTL Joint Venture ................................................................................................... 3 John J. Murphy ExxonMobil Chemical Opens World-Scale Production Plant for Synthetic MANAGinG EDITOR Mark V. Wiley Base Stocks ............................................................................................................. 3 CONTRIBUTORS Johnson Matthey Davy Technologies Ltd. and Rennovia, Inc. to Develop and Eugene F. McInerney, PhD Commercialize Production Technology for Bio-based Glucaric Acid and Adipic Salvatore Ali, PhD Robert Rioux, PhD Acid. ........................................................................................................................ 3 Norman Deschamps, MASc Board OF ADVISORS Process News Salvatore Ali, PhD Michele Aresta, PhD Siluria Technologies Unveils New Development Unit for Liquid Fuels from Miguel A. Banares, PhD Natural Gas Based on OCM and ETL Technologies. ................................................4 Carlos A. Cabrera, MBA Arthur Chester, PhD Custom Catalyst Resists Oxidation..........................................................................4 Gabriele Centi, PhD Media Review Avelino Corma, PhD Frits Dautzenberg, PhD Carbon Capture ...................................................................................................... 5 Burtron Davis, PhD George Huber, PhD Special Feature Phil Kowalski, MBA Warren S. Letzsch, MS Polyolefin Catalyst Market Overview......................................................................7 Joseph Porcelli, DEngSci Gadi Rothenberg, PhD Experimental LAYOUT & desiGN Meda Spence Effect of CO2 on the DeNOx Activity of a Small Pore Zeolite Copper Catalyst ADVertisinG for NH3/SCR ............................................................................................................15 For information about advertising in The Catalyst Review, contact Oligomerization of Ethylene to α-Olefins: Discovery and Development of the +1 215-628-4447 or Shell Higher Olefin Process (SHOP) ........................................................................16 [email protected] Heterogeneous Catalysis of C–O Bond Cleavage for Cellulose Deconstruction: The Catalyst Review provides busy executives, A Potential Pathway for Ethanol Production ..........................................................17 researchers, and production managers with a timely update on catalysis and process advances Movers and Shakers in the petroleum, petrochemical, environmental, and specialty chemical industries. Robert (Rob) M. Rioux, PhD....................................................................................18 Copyright ©2014 by The Catalyst Group Resources, Inc. All rights reserved. Words in all capital letters are either tradenames or acronyms for company names. Readers are advised that tradenames are registered marks protected by applicable law. Reproduction and copying in any form without written permission is prohibited. Subscribers may quote one or two articles per issue if the publisher is notified in writing and the source is cited. Information of this subscription is provided as a service. Subscribers agree that the use of this information is solely at their own discretion. No warranty or guarantee is provided by the publishers. Subscribers agree to indemnify and hold harmless the publishers on any use including loss or damages. The publisher’s sole responsibility is to publish corrections upon notification. The2 CatalystThe Review Catalyst Review April 2014 Jennifer Wilcox COMMERCIAL NEWS Synthetic Biology Axens, Total and IFPEN launch Atol™, an Company Launches Innovative Technology for Bio-Ethylene JV to Commercialize Production Through Dehydration of Bio- Gas-to-Liquids Ethanol... Bioconversion; Atol™ is a technology for the most profitable production of polymer grade bio-ethylene by dehydration of 1G and 2G-renewable ethanol. The bio-ethylene produced can be Isobutanol First integrated in existing downstream polymerization installations such as polyethylene Target... (PE), polystyrene (PS), polyethylene teraphthalate (PET), polyvinylchloride (PVC) and In This Issue acrylonitrile-butadiene-styrene (ABS) without need for modifications. Atol™ is the result of a partnership between Total, IFP Energies Nouvelles (IFPEN) and its affiliate Axens Commercial News Synthetic biology company Intrexon Corporation has formed Intrexon Energy that started in 2011. Within this cooperation, Total developed a high performance Shale Gas to Drive New Capacity Wave. .................................................................2 Partners (IEP), a joint venture with a catalyst formulation at its research Center in Feluy, Belgium, IFPEN scaled up catalyst Enhance Competitiveness of China’s Propylene Oxide Industry through group of external investors, to optimize performance within a heat recovery innovative process while Axens industrialized the Innovation and Industrial Chain Extension. ............................................................2 and to scale-up Intrexon’s gas-to-liquids catalyst formulation and finalized the process scheme with particular focus on energy- efficiency. Total and IFPEN are the co-owners of the technology and Axens is now in JX Nippon Oil & Energy HS-FCC Technology Demonstrated. ..................................2 (GTL) bioconversion platform. IEP’s first target product is isobutanol for gasoline charge of commercializing Atol™ by providing all process licensing related services and GTL Joint Venture ................................................................................................... 3 blending. Intrexon’s natural gas upgrading catalyst manufacturing. Atol™ is the first of a series of technologies, for the production of other olefinic monomers by processing bio-derived higher alcohols, to be developed ExxonMobil Chemical Opens World-Scale Production Plant for Synthetic program is targeting the development in parallel based on Atol’s technology platform. Source: Axens, Total, IFP Energies Base Stocks ............................................................................................................. 3 of an engineered microbial cell line for industrial-scale bioconversion of natural Nouvelles (IFPEN), 3/25/2014. Johnson Matthey Davy Technologies Ltd. and Rennovia, Inc. to Develop and gas to chemicals, lubricants and fuels, as Commercialize Production Technology for Bio-based Glucaric Acid and Adipic opposed to employing standard chemical Acid. ........................................................................................................................ 3 Braskem Seeks Larger U.S. Footprint via routes. Intrexon says it has already achieved initial proof of concept with an Acquisitions... Process News engineered microbial host converting Brazil’s Braskem is setting its sights on further expansion in the Americas – through Siluria Technologies Unveils New Development Unit for Liquid Fuels from methane into isobutanol in a laboratory- organic projects, creative collaborations, and mergers and acquisitions (M&A). The Natural Gas Based on OCM and ETL Technologies. ................................................4 scale bioreactor. Intrexon says that its Ascent (Appalachian Shale Cracker Enterprise) project in West Virginia, U.S. – planned Custom
Load more

Recommended publications
  • CO2 Derivatives of Molecular Tin Compounds. Part 1: † Hemicarbonato and Carbonato Complexes
    inorganics Review CO2 Derivatives of Molecular Tin Compounds. Part 1: y Hemicarbonato and Carbonato Complexes Laurent Plasseraud Institut de Chimie Moléculaire de l’Université de Bourgogne (ICMUB), UMR-CNRS 6302, Université de Bourgogne Franche-Comté, 9 avenue A. Savary, F-21078 Dijon, France; [email protected] Paper dedicated to Professor Georg Süss-Fink on the occasion of his 70th birthday. y Received: 31 March 2020; Accepted: 24 April 2020; Published: 29 April 2020 Abstract: This review focuses on organotin compounds bearing hemicarbonate and carbonate ligands, and whose molecular structures have been previously resolved by single-crystal X-ray diffraction analysis. Most of them were isolated within the framework of studies devoted to the reactivity of tin precursors with carbon dioxide at atmospheric or elevated pressure. Alternatively, and essentially for the preparation of some carbonato derivatives, inorganic carbonate salts such as K2CO3, Cs2CO3, Na2CO3 and NaHCO3 were also used as coreagents. In terms of the number of X-ray structures, carbonate compounds are the most widely represented (to date, there are 23 depositions in the Cambridge Structural Database), while hemicarbonate derivatives are rarer; only three have so far been characterized in the solid-state, and exclusively for diorganotin complexes. For each compound, the synthesis conditions are first specified. Structural aspects involving, in particular, the modes of coordination of the hemicarbonato and carbonato moieties and the coordination geometry around tin are then described and illustrated (for most cases) by showing molecular representations. Moreover, when they were available in the original reports, some characteristic spectroscopic data are also given for comparison (in table form).
    [Show full text]
  • Of Grignard Reagent Formation. the Surface Nature of the Reaction
    286 Ace. Chem. Res. 1990,23, 286-293 Mechanism of Grignard Reagent Formation. The Surface Nature of the Reaction H. M. WALBORSKY Dittmer Laboratory of Chemistry, Florida State University, Tallahassee, Florida 32306 Received February 23, 1990 (Revised Manuscript Received May 7, 1990) The reaction of organic halides (Br, C1, I) with mag- Scheme I nesium metal to yield what is referred to today as a Kharasch-Reinmuth Mechanism for Grignard Reagent Grignard reagent has been known since the turn of the Formation century,' The name derives from its discoverer, Nobel (1)(Mg0)AMg*)2y + RX 4 [(M~'~(MQ')~~-,('MQX)+ R.] + laureate Victor Grignard. How this reagent is formed, (Mgo)x-2(MQ')2~MgX)(MgR) that is, how a magnesium atom is inserted into a car- bon-halogen bond, is the subject of this Account. ('4 (Ms0),-*(M9')2~MgX)(MgR) + + (Mg0)x-dMg*)2y+2 + 2RMgX RX + Mg - RMgX Kharasch and Reinmuth,, persuaded by the work of late under the same conditions gave Itl = 6.2 X s-l. Another system that meets the above criterion is the Gomberg and Bachmad as well as by product analyses of many Grignard formation reactions that existed in vinyl system. The lack of reactivity of vinyl halides toward SN1reactions is well-known and is exemplified the literature prior to 1954,speculated that the reaction involved radicals and that the radical reactions might by the low solvolysis rate of 2-propenyl triflate5 in 80% involve "surface adherent radicals, at least in part". The ethanol at 25 OC, kl being 9.8 X s-l.
    [Show full text]
  • Submitted to the Requirements For
    THE SYNTIIE$IS OP C LABELLED 2, 4-DICI LOROi-EENOÇYAGETIC ACID by ERNEST GEORGE AWORSKI A THESIS submitted to OREGON STA1 COLLEGE in partial fulfillment or the requirements for the degree of MAS2R 0F SCIENCE June 1950 PROVED: professor ot Clie'thlstry Department In Charge of Major Head of Department of' Chemistry Chairman of School Graduate Conimittee Dean of Graduate School Date thesis is presented Typed by Clara Homyar ACNOWLEDGMNTS The author wishes to express his appreciation to Dr. oseph S. Butts for his eneouragem.ent and generous direction in r4laking this work possible. Grateful aoknowledgnient is given to Dr. Albert V. Logan for his assistance in methodical diff i- culties. This research project was supported by an Atoniic inergy Commission grant carried under Navy contract N7-onr-3 7602. TABLE OF CONTENTS Page I. INTRODUCTION I II. STNTHESI OF ALPHA METH'LENB LABELLED2,14-D . , * 4 A. Apparatus ......*,*., B Method . 7 C. Analysis and }hysica1 Constants 3.7 In. StfliSIs OF C CABBOXTh LABELLED 2LD 19 A. Apparatus . 19 B )kethoc3. , , , , , 23. C. Analysis and PhjsLoa3. Constants 26 Iv DISCUSSION . , , . , , V. SUL2&RY . e e . 30 LTTERATUREOITED .......... 31 I1N1)I. 3 2 THE SYNTHESIS OF C LABELLED 2, 4-DICHLOROHENOXThCETIC ACID I. INTRODUCTION The synthesis or C labelled 2,4-dichlorophen- oxyacetic acid (hereafter referred to as 2,4V-D) was undertaken In order to study the process by which lt exerts its selective herbicidal effect on soiae noxious plants. Should this method prove fruitful, it would be useful for a more systematic approach to the study of ooitounds having potential herbicidal properties.
    [Show full text]
  • Part I. Inversion of Secondary Cyclic Grignard Reagents
    This dissertation has been , 69-11,692 microfilmed exactly as received PECHHOLD, Engelbert, 1933- STUDIES OF THE BEHAVIOR AND GENERATION OF GARB ANIONS: PART I. INVERSION OF SECONDARY CYCLIC GRIGNARD REAGENTS. PART II. FRAGMENTATION OF AZOFORMATE SALTS AND ACYLAZO COMPOUNDS WITH BASES. The Ohio State University, Ph.D., 1968 Chemistry, organic University Microfilms, Inc., Ann Arbor, Michigan ©Copyright "by- Engelbert Pechhold 1969 STUDIES OF THE BEHAVIOR MD GENERATION OF CARBANIONS PART I. INVERSION OF SECONDARY CYCLIC GRIGNARD REAGENTS PART II. FRAGMENTATION OF AZOFORMATE SADIS AND ACYLAZO COMPOUNDS WITH BASES DISSERTATION Presented in Partial Fulfillment of the Requirements for the Degree Doctor of Philosophy in the Graduate School of The Ohio State University By Engelbert Pechhold * # # * * # The Ohio State University 1968 Approved by •pV-gpa.-t— Adviser Department of Chemistry DEDICATION To my wife, Ingrid, and my parents, whose love, understanding, and encouragement have made this venture possible. ii ACKNOWLEDaEMElWS I -wish to express my deepest appreciation to Professor Gideon Fraenkel for suggestinf^ this problem, and for his guidance and encouragement throughout the course of this research. His assistance in the preparation of this dissertation is gratefully acknowledged. It is an understatement to say that without his un­ usual courage of conviction and high standards for academic perfor­ mance, this work could not have come into being. I owe special debt of gratitude to my colleagues for many suimtü-ating discussions of chemical matters and otherwise. In particular, I wish to express my gratitute to Dr. Don Dix, Dr. Dave Mams, and James Morton, who gave me much insight in ny research.
    [Show full text]
  • Carbonation of a Grignard Preparation of Benzoic Acid
    CARBONATION OF A GRIGNARD PREPARATION OF BENZOIC ACID INTRODUCTION The Grignard is one of the most versatile reactions in organic chemistry. It was used to produce 2-methyl-2-hexanol from bromobutane and acetone. Carboxylic acids may also be prepared by the Grignard reagent. The “Grignard” is an organometallic compound that contains one the most powerful nucleophiles. This carbanion is capable of reacting with something that is only slightly basic like carbon dioxide. This reaction will convert bromobenzene to benzoic acid. The bromobenzene is converted to the Grignard and then added to solid carbon dioxide. The carbon dioxide acts as a reactant and as the means to keep the reaction cold. The Grignard is prepared by the process of reflux with addition. In this reaction the glassware and reactants must be kept absolutely dry, as the presence of water will inhibit the reaction. Reactions: Br MgBr Ether + Mg MgBr COOH + H3O + CO2 Week One PROCEDURE 1. PREPARATION OF THE GRIGNARD REAGENT Add 0.1 mole of Mg metal ( 2.43 grams ) to a 100 ml round bottom flask and add 30 ml of anhydrous ether to cover the metal. Clamp the flask to the grid at a height that will allow enough room for heating and cooling. Add 0.1 mole of bromobenzene to a separatory funnel. Attach a Claisen adapter to the round bottom flask and fit the adapter just above with a water cooled column. Attach the separatory funnel to the other connection. Prepare an ice/water bath and position it so that the reaction mixture may be cooled by raising the bath to the round bottom with a lab jack.
    [Show full text]
  • US20100160506A1.Pdf
    US 2010.0160506A1 (19) United States (12) Patent Application Publication (10) Pub. No.: US 2010/0160506 A1 Wu et al. (43) Pub. Date: Jun. 24, 2010 (54) PRODUCTION OFSYNTHETIC Publication Classification HYDROCARBON FLUIDS, PLASTICIZERS (51) Int. Cl. AND SYNTHETICLUBRICANT BASE CSK 5/55 (2006.01) STOCKS FROM RENEWABLE FEEDSTOCKS CSK 5/109 (2006.01) C07D 30/03 (2006.01) (76) Inventors: Margaret May-Som Wu, Skillman, C07D 31 7/24 (2006.01) NJ (US); Karla Schall Colle, C07C I/207 (2006.01) Houston, TX (US); Ramzi Yanni (52) U.S. Cl. ......... 524/114; 524/280; 549/523: 549/229; Saleh, Baton Rouge, LA (US); 585/327 Allen D. Godwin, Seabrook, TX (57) ABSTRACT (US); John Edmond Randolph This disclosure is directed to an integrated method for making Stanat, Houston, TX (US) synthetic hydrocarbon fluids, plasticizers and polar synthetic lubricant base stocks from a renewable feedstock. More par Correspondence Address: ticularly, the disclosure is directed to a metathesis reaction of ExxonMobil Research & Engineering Company natural oil or its derivative ester and ethylene in the presence P.O. Box 900, 1545 Route 22 East of an effective amount of a metathesis catalyst to form linear Annandale, NJ 08801-0900 (US) alpha-olefins, internal olefins and reduced chain length trig lycerides. The linear alpha-olefins and/or internal olefins are polymerized to produce synthetic hydrocarbon fluids in the (21) Appl. No.: 12/633,742 presence of a suitable catalyst. The reduced chain length triglycerides are converted into polar synthetic lubricant base (22) Filed: Dec. 17, 2009 stocks or plasticizers by hydrogenation, isomerization, fol lowed by hydrogenations, or by hydroisomerization pro cesses.
    [Show full text]
  • Performance Evaluation of Precast Reinforced Concrete After Early-Age Carbonation Curing
    Performance Evaluation of Precast Reinforced Concrete after Early-Age Carbonation Curing Duo Zhang Department of Civil Engineering and Applied Mechanics McGill University, Montreal July 2016 A thesis submitted to McGill University in partial fulfillment of the requirements of the degree of Doctor of Philosophy in Engineering © Duo Zhang, 2016 All Rights Reserved This page is intentionally left blank ABSTRACT Early carbonation curing of precast concrete accelerates early strength and promotes carbon dioxide utilization. Reinforced concrete represents the majority of precast concrete products and thus the application of early-age carbonation technology in reinforced concrete curing is able to enhance the carbon dioxide utilization potential by concrete products for emission reduction and performance improvement. This thesis aims to develop a special carbonation process suitable to high slump precast concrete. The performance of both ordinary Portland cement (OPC) concrete and fly ash-OPC concretes were evaluated. Early carbonation behavior was assessed by carbon uptakes, pH values, compressive strength and process shrinkage. The effect of early carbonation curing on cement reaction, pozzolanic reaction and pore structure was also examined to interpret the mechanisms of durability performance including freeze-thaw resistance, chloride penetration and weathering carbonation. It was found that carbonation curing had reduced both pore volume and pore size. Gel pores became dominant which were responsible for the improved resistance to permeation and freeze-thaw damage. Chemically cement reaction was accelerated in the early age by carbonation curing and concrete pH values could be compensated by subsequent re-hydration. It was concluded that the carbonation curing was suited to the precast reinforced concrete with or without fly ash incorporation in order to gain improved early strength, enhanced durability and permanent carbon dioxide sequestration as an added-value for environmental benefit.
    [Show full text]
  • Mineral Carbonation and Industrial Uses of Carbon Dioxide 319 7
    Chapter 7: Mineral carbonation and industrial uses of carbon dioxide 319 7 Mineral carbonation and industrial uses of carbon dioxide Coordinating Lead Author Marco Mazzotti (Italy and Switzerland) Lead Authors Juan Carlos Abanades (Spain), Rodney Allam (United Kingdom), Klaus S. Lackner (United States), Francis Meunier (France), Edward Rubin (United States), Juan Carlos Sanchez (Venezuela), Katsunori Yogo (Japan), Ron Zevenhoven (Netherlands and Finland) Review Editors Baldur Eliasson (Switzerland), R.T.M. Sutamihardja (Indonesia) 320 IPCC Special Report on Carbon dioxide Capture and Storage Contents EXECUTIVE SUMMARY 321 7.3 Industrial uses of carbon dioxide and its emission reduction potential 330 7.1 Introduction 322 7.3.1 Introduction 330 7.3.2 Present industrial uses of carbon dioxide 332 7.2 Mineral carbonation 322 7.3.3 New processes for CO2 abatement 332 7.2.1 Definitions, system boundaries and motivation 322 7.3.4 Assessment of the mitigation potential of CO2 7.2.2 Chemistry of mineral carbonation 323 utilization 333 7.2.3 Sources of metal oxides 324 7.3.5 Future scope 334 7.2.4 Processing 324 7.2.5 Product handling and disposal 328 References 335 7.2.6 Environmental impact 328 7.2.7 Life Cycle Assessment and costs 329 7.2.8 Future scope 330 Chapter 7: Mineral carbonation and industrial uses of carbon dioxide 321 EXECUTIVE SUMMARY This Chapter describes two rather different options for carbon and recycled using external energy sources. The resulting dioxide (CO2) storage: (i) the fixation of CO2 in the form of carbonated solids must be stored at an environmentally suitable inorganic carbonates, also known as ‘mineral carbonation’ or location.
    [Show full text]
  • The Synthesis and Properties of Some Metallocene
    THE SYNTHESIS AND PROPERTIES OF SOME METALLOCENE CONTAINING MACROCYCLES AND THEIR ANALOGUES by JONATHAN PAUL KNYCHALA A Thesis presented for the Degree of DOCTOR OF PHILOSOPHY in the Faculty of Science of the UNIVERSITY OF LONDON Bedford College, London ProQuest Number: 10098532 All rights reserved INFORMATION TO ALL USERS The quality of this reproduction is dependent upon the quality of the copy submitted. In the unlikely event that the author did not send a complete manuscript and there are missing pages, these will be noted. Also, if material had to be removed, a note will indicate the deletion. uest. ProQuest 10098532 Published by ProQuest LLC(2016). Copyright of the Dissertation is held by the Author. All rights reserved. This work is protected against unauthorized copying under Title 17, United States Code. Microform Edition © ProQuest LLC. ProQuest LLC 789 East Eisenhower Parkway P.Q. Box 1346 Ann Arbor, Ml 48106-1346 CONTENTS Page ABSTRACT 7 ACKNOWLEDGEMENTS 9 INTRODUCTION 11 CHAPTER 1 . CROWN-ETHERS AND CRYPTANDS 1 1 1 .1 Introduction 1 1 1 .2 Synthesis 12 1 .3 Structure and selective ion-binding 16 1 .4 The effect of the ligand on the 23 properties of the cation CHAPTER 2. A REVIEW OF THE CURRENT LITERATURE 26 ON THE USES OF CROWN-ETHERS AND CRYPTANDS 2.1 Chemical 26 2.2 Biochemical 47 DISCUSSION CHAPTER 3. DISCUSSION 56 3.1 Aims of the project 56 3.2(i) Structure and physical properties of 58 ferrocene and ruthenocene 3.2(ii) Electrochemistry 61 3.3 The design of ferrocene and ruthenocene 65 macrocycles containing ion-binding ligands Page CHAPTER 4.
    [Show full text]
  • Nanoporous Materials As New Engineered Catalysts for the Synthesis of Green Fuels
    Molecules 2015, 20, 5638-5666; doi:10.3390/molecules20045638 OPEN ACCESS molecules ISSN 1420-3049 www.mdpi.com/journal/molecules Review Nanoporous Materials as New Engineered Catalysts for the Synthesis of Green Fuels Ioana Fechete 1,* and Jacques C. Vedrine 2,* 1 Institut de Chimie et Procédés pour l’Energie, l’Environnement et la Santé—ICPEES, UMR 7515 CNRS, Université de Strasbourg, 25 rue Becquerel, 67087 Strasbourg Cedex 2, France 2 Laboratoire de Réactivité de Surface, UMR-CNRS 7197, Université P. & M. Curie-Paris 06, Sorbonne Universités, 4 Place Jussieu, 75252 Paris, France * Authors to whom correspondence should be addressed; E-Mails: [email protected] (I.F.); [email protected] (J.C.V.); Tel.: +33-0-368852756 (I.F.); +33-0-668536212 (J.C.V.); Fax: +33-0-368852761 (I.F.); +33-0-144276510 (J.C.V.). Academic Editor: Geoffrey L. Price Received: 4 February 2015 / Accepted: 23 March 2015 / Published: 31 March 2015 Abstract: This review summarizes the importance of nanoporous materials and their fascinating structural properties with respect to the catalytic and photocatalytic reduction of CO2 to methane, toward achieving a sustainable energy supply. The importance of catalysis as a bridge step for advanced energy systems and the associated environmental issues are stressed. A deep understanding of the fundamentals of these nanoporous solids is necessary to improve the design and efficiency of CO2 methanation. The role of the support dominates the design in terms of developing an efficient methanation catalyst, specifically with respect to ensuring enhanced metal dispersion and a long catalyst lifetime. Nanoporous materials provide the best supports for Ni, Ru, Rh, Co, Fe particles because they can prevent sintering and deactivation through coking, which otherwise blocks the metal surface as carbon accumulates.
    [Show full text]
  • View a Complete List of Ph.D Degrees
    1913 1. CLARK, Clinton Willard. (Title not Available). 2. CLARK, Hugh. An Improved Method for the Manufacture of Hydrogen and Lamp Black. 3. CORLISS, Harry Percival. The Distribution of Colloidal Arsenic Trisulfide between the Phases in the System Ether, Water, and Alcohol. 4. PRATT, Lester Albert. Studies in the Field of Petroleum. 5. SHIVELY, Robert Rex. A Study of Magnesia Cements. 1914 6. UHLINGER, Roy H. The Formation of Utilizable Products from Natural Gas. 1915 7. DUNPHY, Raymond Augustine. Theory of Distillation and the Laws of Henry and Raoult. 8. LIEBOVITZ, Sidney. Study of Dynamics of Esterification. 9. MORTON, Harold Arthur. Study of the Specific Rotatory Power of Organic Substances in Solution. 10. WITT, Joshua Chitwood. Oxidation and Reduction Without the Addition of Acid. I. The Reaction between Ferrous Sulfate and Potassium Dichromate. II. The Reaction Between Stanous Chloride and Potassium Dichromate. (Neidle) 1917 11. COLEMAN, Arthur Bert. Tetraiodofluorescein, Tetraiodoeosin, Tetraiodoerythrosin and Some of Their Derivatives. (Pratt) 12. MILLER, Rolla Woods. On the Mechanism of the Potassium Chlorate-Manganese Dioxide Reaction. 13. PERKINS, Granville Akers. Phthalic Anhydride and Some of Its Derivatives. (Pratt) 14. SHUPP, Asher Franklin. Phenoltetraiodophthalein and Some of Its Derivatives. (Pratt) 1919 15. CURME, Henry R. Butadiine (Diacetylene). II. Analysis of Gas Mixtures by Distillation at Low Temperatures and Low Pressures. III. The Precise Analytical Determination of Acetylene, Ethylene, and Methyl Acetylene in Hydrocarbon Gas Mixtures. 16. DROGIN, Isaac. The Effect of Potassium Chloride on the Inversion of Cane Sugar by Formic Acid. 17. YOUNG, Charles Otis. Tetrabromophthalic Acid and Its Condensation with Some Primary Amines. 1 1920 18.
    [Show full text]
  • Some Organometallic Compounds Containing Reactive Functional Groups Burt Frederick Hofferth Iowa State College
    Iowa State University Capstones, Theses and Retrospective Theses and Dissertations Dissertations 1950 Some organometallic compounds containing reactive functional groups Burt Frederick Hofferth Iowa State College Follow this and additional works at: https://lib.dr.iastate.edu/rtd Part of the Organic Chemistry Commons Recommended Citation Hofferth, Burt Frederick, "Some organometallic compounds containing reactive functional groups " (1950). Retrospective Theses and Dissertations. 13966. https://lib.dr.iastate.edu/rtd/13966 This Dissertation is brought to you for free and open access by the Iowa State University Capstones, Theses and Dissertations at Iowa State University Digital Repository. It has been accepted for inclusion in Retrospective Theses and Dissertations by an authorized administrator of Iowa State University Digital Repository. For more information, please contact [email protected]. INFORMATION TO USERS This manuscript has been reproduced from the microfiim master. UMI films the text directly from the original or copy submitted. Thus, some thesis and dissertation copies are in typewriter face, while others may be from any type of computer printer. The quality of this reproduction is dependent upon the quality of the copy submitted. Broken or indistinct print, colored or poor quality illustrations and photographs, print bleedthrough, substandard margins, and improper alignment can adversely affect reproduction. In the unlikely event that the author did not send UMI a complete manuscript and there are missing pages, these will be noted. Also, if unauthorized copyright material had to be removed, a note will indicate the deletion. Oversize materials (e.g., maps, drawings, charts) are reproduced by sectioning the original, beginning at the upper left-hand comer and continuing from left to right in equal sections with small overlaps.
    [Show full text]