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United States Patent (19) 11 Patent Number: 4,514,290 Swiatkowski Et Al
United States Patent (19) 11 Patent Number: 4,514,290 Swiatkowski et al. 45 Date of Patent: Apr. 30, 1985 54 FLOTATION COLLECTOR COMPOSITION 4,206,045 6/1980 Wang et al.......................... 209/166 AND ITS USE 4,358,368 1/1982 Helsten et al........................ 252/61 4,425,229 1/1984 Baronet al. .......................... 252/61 (75) Inventors: Piotr Swiatkowski, Huddinge; Thomas Wiklund, Nacka, both of FOREIGN PATENT DOCUMENTS Sweden 1 155072 10/1963 Fed. Rep. of Germany ...... 209/167 73) Assignee: KenoGard AB, Stockholm, Sweden Primary Examiner-Bernard Nozick 21 Appl. No.: 471,006 Attorney, Agent, or Firm-Fred Philpitt 22 Filed: Mar. 1, 1983 57 ABSTRACT 30 Foreign Application Priority Data A flotation collector composition comprises a combina tion of fatty acids, amidocarboxylic acids or amidosul Mar. 5, 1982 SE Sweden ................................ 8201363 fonic acids and partial esters of phosphoric acid and 51 Int. Cl. ............................................... BO3D 1/14 alkoxylated alcohols. The collector composition is used 52 U.S. C. ....................................... 209/166; 252/61 for upgrading nonsulfide minerals containing alkaline 58) Field of Search ................... 252/61; 209/166, 167 earth metals by froth flotation. Minerals such as apatite, calcite, scheelite, fluorspar, magnesite and baryte can be 56) References Cited separated from the gangues using the collector compo U.S. PATENT DOCUMENTS sition. 2,297,664 9/1942 Tartaron ............................. 209/167 4,139,481 2/1979 Wang et al. ........................... 252A61 13 Claims, No Drawings 4,514,290 1. 2 The amidocarboxylic acids and the amidosulfonic FLOTATION COLLECTOR COMPOSITION AND acids which are used in the present collector combina ITS USE tions can be characterized by the general formula The present invention relates to a flotation collector R-X-(CH2)n-A, wherein x is the group composition comprising fatty acids, amido carboxylic acids or amidosulfonic acids and certain phosphate es R ters. -
Liroconite Cu2al(Aso4)(OH)4 • 4H2O C 2001-2005 Mineral Data Publishing, Version 1
Liroconite Cu2Al(AsO4)(OH)4 • 4H2O c 2001-2005 Mineral Data Publishing, version 1 Crystal Data: Monoclinic. Point Group: 2/m. Typically as crystals with a flattened octahedral or lenticular aspect, dominated by {110} and {011} and striated parallel to their intersections, also {001}, {010}, {100}, to 3.6 cm, alone and in sub-parallel groups. May be granular, massive. Physical Properties: Cleavage: On {110}, {011}, indistinct. Fracture: Uneven to conchoidal. Hardness = 2–2.5 D(meas.) = 2.94–3.01 D(calc.) = [3.03] Optical Properties: Transparent to translucent. Color: Sky-blue, bluish green, verdigris-green, emerald-green; pale blue to pale bluish green in transmitted light. Streak: Pale blue to pale green. Luster: Vitreous to resinous. Optical Class: Biaxial (–). Orientation: Y = b; Z ∧ a =25◦. Dispersion: r< v,moderate. α = 1.612(3) β = 1.652(3) γ = 1.675(3) 2V(meas.) = n.d. 2V(calc.) = 72(5)◦ Cell Data: Space Group: I2/a. a = 12.664(2) b = 7.563(2) c = 9.914(3) β =91.32(2)◦ Z=4 X-ray Powder Pattern: Cornwall, England. 6.46 (10), 3.01 (10), 5.95 (9), 2.69 (6), 3.92 (5), 2.79 (5), 2.21 (5) Chemistry: (1) (2) P2O5 3.73 As2O5 23.05 26.54 Al2O3 10.85 11.77 Fe2O3 0.98 CuO 36.38 36.73 H2O 25.01 24.96 Total 100.00 100.00 • (1) Cornwall, England. (2) Cu2Al(AsO4)(OH)4 4H2O. Occurrence: A rare secondary mineral in the oxidized zone of some copper deposits. Association: Olivenite, chalcophyllite, clinoclase, cornwallite, strashimirite, malachite, cuprite, “limonite”. -
Barite (Barium)
Barite (Barium) Chapter D of Critical Mineral Resources of the United States—Economic and Environmental Geology and Prospects for Future Supply Professional Paper 1802–D U.S. Department of the Interior U.S. Geological Survey Periodic Table of Elements 1A 8A 1 2 hydrogen helium 1.008 2A 3A 4A 5A 6A 7A 4.003 3 4 5 6 7 8 9 10 lithium beryllium boron carbon nitrogen oxygen fluorine neon 6.94 9.012 10.81 12.01 14.01 16.00 19.00 20.18 11 12 13 14 15 16 17 18 sodium magnesium aluminum silicon phosphorus sulfur chlorine argon 22.99 24.31 3B 4B 5B 6B 7B 8B 11B 12B 26.98 28.09 30.97 32.06 35.45 39.95 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 potassium calcium scandium titanium vanadium chromium manganese iron cobalt nickel copper zinc gallium germanium arsenic selenium bromine krypton 39.10 40.08 44.96 47.88 50.94 52.00 54.94 55.85 58.93 58.69 63.55 65.39 69.72 72.64 74.92 78.96 79.90 83.79 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 rubidium strontium yttrium zirconium niobium molybdenum technetium ruthenium rhodium palladium silver cadmium indium tin antimony tellurium iodine xenon 85.47 87.62 88.91 91.22 92.91 95.96 (98) 101.1 102.9 106.4 107.9 112.4 114.8 118.7 121.8 127.6 126.9 131.3 55 56 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 cesium barium hafnium tantalum tungsten rhenium osmium iridium platinum gold mercury thallium lead bismuth polonium astatine radon 132.9 137.3 178.5 180.9 183.9 186.2 190.2 192.2 195.1 197.0 200.5 204.4 207.2 209.0 (209) (210)(222) 87 88 104 105 106 107 108 109 110 111 112 113 114 115 116 -
Mineral Collecting Sites in North Carolina by W
.'.' .., Mineral Collecting Sites in North Carolina By W. F. Wilson and B. J. McKenzie RUTILE GUMMITE IN GARNET RUBY CORUNDUM GOLD TORBERNITE GARNET IN MICA ANATASE RUTILE AJTUNITE AND TORBERNITE THULITE AND PYRITE MONAZITE EMERALD CUPRITE SMOKY QUARTZ ZIRCON TORBERNITE ~/ UBRAR'l USE ONLV ,~O NOT REMOVE. fROM LIBRARY N. C. GEOLOGICAL SUHVEY Information Circular 24 Mineral Collecting Sites in North Carolina By W. F. Wilson and B. J. McKenzie Raleigh 1978 Second Printing 1980. Additional copies of this publication may be obtained from: North CarOlina Department of Natural Resources and Community Development Geological Survey Section P. O. Box 27687 ~ Raleigh. N. C. 27611 1823 --~- GEOLOGICAL SURVEY SECTION The Geological Survey Section shall, by law"...make such exami nation, survey, and mapping of the geology, mineralogy, and topo graphy of the state, including their industrial and economic utilization as it may consider necessary." In carrying out its duties under this law, the section promotes the wise conservation and use of mineral resources by industry, commerce, agriculture, and other governmental agencies for the general welfare of the citizens of North Carolina. The Section conducts a number of basic and applied research projects in environmental resource planning, mineral resource explora tion, mineral statistics, and systematic geologic mapping. Services constitute a major portion ofthe Sections's activities and include identi fying rock and mineral samples submitted by the citizens of the state and providing consulting services and specially prepared reports to other agencies that require geological information. The Geological Survey Section publishes results of research in a series of Bulletins, Economic Papers, Information Circulars, Educa tional Series, Geologic Maps, and Special Publications. -
Barite Baso4 C 2001-2005 Mineral Data Publishing, Version 1 Crystal Data: Orthorhombic
Barite BaSO4 c 2001-2005 Mineral Data Publishing, version 1 Crystal Data: Orthorhombic. Point Group: 2/m 2/m 2/m. Commonly in well-formed crystals, to 85 cm, with over 70 forms noted. Thin to thick tabular {001}, {210}, {101}, {011}; also prismatic along [001], [100], or [010], equant. As crested to rosettelike aggregates of tabular individuals, concretionary, fibrous, nodular, stalactitic, may be banded; granular, earthy, massive. Physical Properties: Cleavage: {001}, perfect; {210}, less perfect; {010}, imperfect. Fracture: Uneven. Tenacity: Brittle. Hardness = 3–3.5 D(meas.) = 4.50 D(calc.) = 4.47 May be thermoluminescent, may fluoresce and phosphoresce cream to spectral colors under UV. Optical Properties: Transparent to translucent. Color: Colorless, white, yellow, brown, gray, pale shades of red, green, blue, may be zoned, or change color on exposure to light; colorless or faintly tinted in transmitted light. Streak: White. Luster: Vitreous to resinous, may be pearly. Optical Class: Biaxial (+). Pleochroism: Weak. Orientation: X = c; Y = b; Z = a. Dispersion: r> v,weak. Absorption: Z > Y > X. α = 1.636 β = 1.637 γ = 1.648 2V(meas.) = 36◦–40◦ Cell Data: Space Group: P nma. a = 8.884(2) b = 5.457(3) c = 7.157(2) Z = 4 X-ray Powder Pattern: Synthetic. 3.445 (100), 3.103 (95), 2.121 (80), 2.106 (75), 3.319 (70), 3.899 (50), 2.836 (50) Chemistry: (1) (2) SO3 34.21 34.30 CaO 0.05 BaO 65.35 65.70 Total 99.61 100.00 (1) Sv´arov, Czech Republic. (2) BaSO4. Polymorphism & Series: Forms a series with celestine. -
Formation of Chrysocolla and Secondary Copper Phosphates in the Highly Weathered Supergene Zones of Some Australian Deposits
Records of the Australian Museum (2001) Vol. 53: 49–56. ISSN 0067-1975 Formation of Chrysocolla and Secondary Copper Phosphates in the Highly Weathered Supergene Zones of Some Australian Deposits MARTIN J. CRANE, JAMES L. SHARPE AND PETER A. WILLIAMS School of Science, University of Western Sydney, Locked Bag 1797, Penrith South DC NSW 1797, Australia [email protected] (corresponding author) ABSTRACT. Intense weathering of copper orebodies in New South Wales and Queensland, Australia has produced an unusual suite of secondary copper minerals comprising chrysocolla, azurite, malachite and the phosphates libethenite and pseudomalachite. The phosphates persist in outcrop and show a marked zoning with libethenite confined to near-surface areas. Abundant chrysocolla is also found in these environments, but never replaces the two secondary phosphates or azurite. This leads to unusual assemblages of secondary copper minerals, that can, however, be explained by equilibrium models. Data from the literature are used to develop a comprehensive geochemical model that describes for the first time the origin and geochemical setting of this style of economically important mineralization. CRANE, MARTIN J., JAMES L. SHARPE & PETER A. WILLIAMS, 2001. Formation of chrysocolla and secondary copper phosphates in the highly weathered supergene zones of some Australian deposits. Records of the Australian Museum 53(1): 49–56. Recent exploitation of oxide copper resources in Australia these deposits are characterized by an abundance of the has enabled us to examine supergene mineral distributions secondary copper phosphates libethenite and pseudo- in several orebodies that have been subjected to intense malachite associated with smaller amounts of cornetite and weathering. -
Moles & Chapman SGA2019 Abstract
Neoproterozoic microbial processes in chemical sediment diagenesis: evidence from the Aberfeldy barite deposits Moles, Norman R. School of Environment and Technology, University of Brighton, UK. Email: [email protected] Boyce, Adrian J. Scottish Universities Environmental Research Centre (SUERC), University of Glasgow, UK Abstract. Microbial- and diffusion-controlled diagenetic 2.1 Barite deposition and diagenetic alteration processes were significant in the formation of sulfide-, sulfate- and carbonate-rich stratiform mineralization In modern ocean sediments, barite is not prone to hosted by Neoproterozoic graphitic metasediments near diagenetic alteration after burial where oxic conditions Aberfeldy in Perthshire, Scotland. In 1-10m thick beds of prevail, but is soluble under reducing conditions barite rock, barite δ34S of +36 ±1.5 ‰ represents the especially in the presence of sulfate-reducing microbes isotopic composition of contemporaneous seawater and organic matter (e.g. Clark et al., 2004). Porewater sulfate. Pronounced vertical variations in δ34S (+30 to +41 sulfate reduction is ubiquitous in organic-rich sediments ‰) and δ18O (+8 to +21 ‰) occur on a decimetre-scale at containing barite (e.g. Torres et al., 1996). bed margins. These excursions are attributed to early Some studies of sedimentary exhalative (sedex) barite diagenetic alteration, while the barite sediment was fine- deposits have proposed that barite precipitation occurred grained and porous, due to pulsed infiltration of in the water column with finely crystalline barite deposited isotopically diverse porefluids into the marginal barite. on the seabed (e.g. Lyons et al., 2006). However, in a Fluid-mediated transfer of barium and sulfate into study of non-hydrothermal sediment-hosted stratiform adjacent sediments contributed to barium enrichment and barite deposits worldwide, Johnson et al. -
The Hydrothermal Alteration of Carbonatite in the Fen Complex, Norway: Mineralogy, Geochemistry, and Implications for Rare-Earth Element Resource Formation
Mineralogical Magazine, May 2018, Vol. 82(S1), pp. S115–S131 The hydrothermal alteration of carbonatite in the Fen Complex, Norway: mineralogy, geochemistry, and implications for rare-earth element resource formation * C. MARIEN ,A.H.DIJKSTRA AND C. WILKINS School of Geography, Earth and Environmental Sciences, Plymouth University, Fitzroy Building, Drake Circus, Plymouth PL4 8AA, UK [Received 3 March 2017; Accepted 5 September 2017; Associate Editor: Nigel Cook] ABSTRACT The Fen Complex in Norway consists of a ∼583 Ma composite carbonatite-ijolite-pyroxenite diatreme intrusion. Locally, high grades (up to 1.6 wt.% total REE) of rare-earth elements (REE) are found in a hydrothermally altered, hematite-rich carbonatite known as rødbergite. The progressive transformation of primary igneous carbonatite to rødbergite was studied here using scanning electron microscopy and inductively coupled plasma-mass spectrometry trace-element analysis of 23 bulk samples taken along a key geological transect. A primary mineral assemblage of calcite, dolomite, apatite, pyrite, magnetite and columbite with accessory quartz, baryte, pyrochlore, fluorite and REE fluorocarbonates was found to have transformed progressively into a secondary assemblage of dolomite, Fe-dolomite, baryte, Ba-bearing phlogopite, hematite with accessory apatite, calcite, monazite-(Ce) and quartz. Textural evidence is presented for REE fluorocarbonates and apatite breaking down in igneous carbonatite, and monazite-(Ce) precipitating in rødbergite. The importance of micro-veins, interpreted as feeder fractures, containing secondary monazite and allanite, is highlighted. Textural evidence for included relics of primary apatite-rich carbonatite are also presented. These acted as a trap for monazite-(Ce) precipitation, a mechanism predicted by physical-chemical experiments. The transformation of carbonatite to rødbergite is accompanied by a 10- fold increase in REE concentrations. -
Pseudomalachite Cu5(PO4)2(OH)4 C 2001-2005 Mineral Data Publishing, Version 1
Pseudomalachite Cu5(PO4)2(OH)4 c 2001-2005 Mineral Data Publishing, version 1 Crystal Data: Monoclinic. Point Group: 2/m. Crystals are rare, to 6 mm, typically rough and rounded, with prominent {110}, {201}, {311}, {100}, {001}, and others. Commonly compact radiating and spherical, may be fibrous, in paintlike crusts and films, botryoidal, massive. Twinning: On {100}. Physical Properties: Cleavage: Perfect on {100}. Fracture: Splintery. Hardness = 4.5–5 D(meas.) = 4.15–4.35 D(calc.) = 4.34 Optical Properties: Translucent. Color: Dark emerald-green, dark green, blackish green, bluish green; green to bluish green in transmitted light. Streak: Pale green to pale bluish green. Luster: Vitreous to resinous. Optical Class: Biaxial (–), may be biaxial (+). Pleochroism: Weak; X = bluish green to pale green; Y = yellowish green; Z = deep bluish green to blue-green. Orientation: Z = b;X∧ c =21◦–23◦. Dispersion: r< v,strong; may be r> v.α= 1.789–1.80 β = 1.835–1.86 γ = 1.845–1.88 2V(meas.) = 46◦–50◦ Cell Data: Space Group: P 21/a. a = 17.02–17.08 b = 5.75–5.77 c = 4.47–4.50 β =90◦570−91◦320 Z=2 X-ray Powder Pattern: Ehl and Rheinbreitbach, Germany. 4.48 (10), 2.39 (8), 2.42 (6), 3.46 (5), 2.32 (5), 2.23 (5), 1.728 (5) Chemistry: (1) (2) P2O5 23.86 24.65 FeO 0.19 CuO 69.25 69.09 H2O 6.76 6.26 Total 100.06 100.00 (1) Rheinbreitbach, Germany; corresponds to (Cu4.98Fe0.02)Σ=5.00(PO4)1.93(OH)4.30. -
Topographical Index
997 TOPOGRAPHICAL INDEX EUROPE Penberthy Croft, St. Hilary: carminite, beudantite, 431 Iceland (fsland) Pengenna (Trewethen) mine, St. Kew: Bondolfur, East Iceland: pitchsbone, beudantite, carminite, mimetite, sco- oligoclase, 587 rodite, 432 Sellatur, East Iceland: pitchs~one, anor- Redruth: danalite, 921 thoclase, 587 Roscommon Cliff, St. Just-in-Peuwith: Skruthur, East Iceland: pitchstonc, stokesite, 433 anorthoclase, 587 St. Day: cornubite, 1 Thingmuli, East Iceland: andesine, 587 Treburland mine, Altarnun: genthelvite, molybdenite, 921 Faroes (F~eroerne) Treore mine, St. Teath: beudantite, carminite, jamesonite, mimetite, sco- Erionite, chabazite, 343 rodite, stibnite, 431 Tretoil mine, Lanivet: danalite, garnet, Norway (Norge) ilvaite, 921 Gryting, Risor: fergusonite (var. risSrite), Wheal Betsy, Tremore, Lanivet: he]vine, 392 scheelite, 921 Helle, Arendal: fergusonite, 392 Wheal Carpenter, Gwinear: beudantite, Nedends: fergusonite, 392 bayldonite, carminite, 431 ; cornubite, Rullandsdalen, Risor: fergusonite, 392 cornwallite, 1 Wheal Clinton, Mylor, Falmouth: danal- British Isles ire, 921 Wheal Cock, St. Just-in- Penwith : apatite, E~GLA~D i~D WALES bertrandite, herderite, helvine, phena- Adamite, hiibnerite, xliv kite, scheelite, 921 Billingham anhydrite mine, Durham: Wheal Ding (part of Bodmin Wheal aph~hitalite(?), arsenopyrite(?), ep- Mary): blende, he]vine, scheelite, 921 somite, ferric sulphate(?), gypsum, Wheal Gorland, Gwennap: cornubite, l; halite, ilsemannite(?), lepidocrocite, beudantite, carminite, zeunerite, 430 molybdenite(?), -
Sphalerite Composition in Relation to Deposition and Metamorphism of the Foss Stratiform Ba-Zn-Pb Deposit, Aberfeldy, Scotland
MINERALOGICAL MAGAZINE, DECEMBER 1983, VOL. 47, PP. 487-500 Sphalerite composition in relation to deposition and metamorphism of the Foss stratiform Ba-Zn-Pb deposit, Aberfeldy, Scotland NORMAN R. MOLES Grant Institute of Geology, University of Edinburgh, West Mains Road, Edinburgh EH9 3JW ABSTRACT. Sphalerite is a common constituent of the deposit, which is the westerly of the two major mineralized rocks and host metasediments of the Foss deposits at Aberfeldy, in both of which sphalerite is baryte-base metal deposit, located near Aberfeldy in widespread and locally abundant. the central Scottish Highlands. Microprobe analyses of sphalerite show a wide range in minor element content (0-17 mol. ~o FeS, 0-3 mol. ~o MnS), and sphalerites of contrasting composition are often found in the same rock. N 4~ _ ~==~S ~ This suggests that equilibrium domains in some rocks ~--'~-t-.---..~t ~o ~ ~ ~ --~-ff -- .~1(..~.""~'-- Pitloch ry were minute (< 1 ram), during regional metamorphism. -1- Pressures derived from the selective application of the / E,o,e. sphalerite geobarometer are consistent with other minera- _L~a%~ Forroclon ~ 56040 , f logical evidence of peak metamorphic pressures in the I Jlf HIIF toch range 7-10 kbar, at 540-580 ~ However, there is FOSS jrandt u ily~-~ considerable evidence of partial retrograde re-equilibration DEPOSIT of sphalerite, by continued buffering with pyrite+ pyrrhotine and by outward diffusion of iron. Marginal "~- loY 0 Miles 3 depletion of Fe and Mn in sphalerite within coarse carbonate rocks is attributed to partitioning reactions following recrystallization. Sphalerite which has retained FIG. l. Map of the central Scottish Highlands showing its pre-metamorphic composition shows systematic varia- location of the Aberfeldy deposits. -
Determination of the Constituents and Suitability of Azara Barytes for Industrial Applications
Chemsearch Journal 1(1): 1 - 3 Received: October, 2009 Accepted: May, 2010 Publication of Chemical Society of Nigeria, Kano Chapter DETERMINATION OF THE CONSTITUENTS AND SUITABILITY OF AZARA BARYTES FOR INDUSTRIAL APPLICATIONS Abdullahi, Y. and Lawal, A.O. Department of Applied Science, Kaduna Polytechnic, Kaduna ABSTRACT Azara baryte was analyzed and had an average specific gravity of 4.3g/cm3 and loss on ignition of 1.71wt%. Atomic Absorption spectrometery was used to determine the Fe2O3,Al2O3 and BaO contents. SiO2 and SO3 were determined by gravimetry while CaO, MgO, Na2O and K2O were determined by flame photometry. The percentage average values for the chemical oxides in the baryte samples were BaO (57.29wt%), SO3(25.99wt%), CaO(1.40wt%), MgO(0.40wt%), Fe2O3(3.46wt%), Al2O3(0.97wt%), Na2O(2.82wt%), K2O(0.30wt%) and SiO2(6.23wt%). These results indicate that Azara baryte lies within the range for use in glass production and as a filler or extender in paint and rubber production, but will require further beneficiation in order to be a suitable component of oil drill mud. Keywords: Azara Baryte, Specific gravity, Gravimetery, Atomic Absorption Spectrometery. Flame photometry. INTRODUCTION found in Lefin in Cross River State and Ibi and Dungel Baryte (heavy spar) is the naturally occurring mineral in Taraba State. Smith (1978) estimated that the of barium sulphate (BaSO4). Baryte is soft with clear Azara baryte deposit has a proven reserve of about white colour, but can vary with the presence of 731,000 tonnes with about 71,000 tonnes of good impurities (such as iron oxides , hydroxides, sulphides quality barytes.