"Boron Halides"
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United States Patent (19) (11) 4,161,571 Yasui Et Al
United States Patent (19) (11) 4,161,571 Yasui et al. 45 Jul. 17, 1979 (54) PROCESS FOR PRODUCTION OF THE 4,080,493 3/1978 Yasui et al. .......................... 260/879 MALE CANHYDRDE ADDUCT OF A 4,082,817 4/1978 Imaizumi et al. ...................... 526/46 LIQUID POLYMER 4,091,198 5/1978 Smith ..................................... 526/56 75 Inventors: Seimei Yasui, Takarazuka; Takao FOREIGN PATENT DOCUMENTS Oshima, Sonehigashi, both of Japan 2262677 2/1975 France ....................................... 526/56 73) Assignee: Sumitomo Chemical Company, 44-1989 1/1969 Japan ......................................... 526/56 Limited, Osaka, Japan Primary Examiner-William F. Hamrock Attorney, Agent, or Firm-Birch, Stewart, Kolasch and 21 Appl. No.: 843,311 Birch 22 Filed: Oct. 18, 1977 57 ABSTRACT Related U.S. Application Data A process for production of the maleic anhydride ad duct of a liquid polymer having a maleic anhydride 62 Division of Ser. No. 733,914, Oct. 19, 1976, Pat, No. addition amount of 2 to 70% by weight, which com 4,080,493. prises reacting a liquid polymer having a molecular 51 Int. C.’................................................ CO8F 8/46 weight of 150 to 5,000 and a viscosity of 2 to 50,000 cp (52) U.S. C. ...................................... 526/90; 526/192; at 30 C. in the presence of at least one compound, as a 526/209; 526/213; 526/193; 526/195; 526/226; gelation inhibitor, selected from the group consisting of 526/233; 526/237; 526/238; 526/272; 525/285; imidazoles, thiazoles, metallic salts of mercapto 525/249; 525/251; 525/255; 525/245; 525/248 thiazoles, urea derivatives, naphthylamines, nitrosa (58) Field of Search ................ -
LOUISIANA SCIENTIST Vol. 1A No. 3
LOUISIANA SCIENTIST THE NEWSLETTER of the LOUISIANA ACADEMY OF SCIENCES Volume 1A, No. 3 (2007 Annual Meeting Abstracts) Published by THE LOUISIANA ACADEMY OF SCIENCES 15 June 2012 Louisiana Academy of Sciences Abstracts of Presentations 2007 Annual Meeting Southern University and A&M College Baton Rouge, Louisiana 16 March 2007 Table of Contents Division/Section Page Division of Agriculture, Forestry, and Wildlife . 5 Division of Biological Sciences . 11 Botany Section . 11 Environmental Sciences Section . 11 Microbiology Section . 17 Molecular and Biomedical Biology Section . 21 Zoology Section . 23 Division of Physical Sciences . 28 Chemistry Section . 28 Computer Science Section . 34 Earth Sciences Section . 41 Materials Science and Engineering Section . 43 Mathematics and Statistics Section . 46 Physics Section . 49 Division of Science Education . 52 Higher Education Section . 52 K-12 Education Section . 55 Division of Social Sciences . 57 Acknowledgement . 64 2 The following abstracts of oral and poster presentations represent those received by the Abstract Editor. Authors’ affiliations are abbreviated as follows: ACHRI Arkansas Children’s Hospital Research Institute ARS Agriculture Research Services, Little Rock, AR AVMA-PLIT American Veterinary Medical BGSU Bowling Green State University BNL Brookhaven National Laboratory, Upton, NY BRCC Baton Rouge Community College CC Centenary College CIT California Institute of Technology CL Corrigan Laboratory, Baton Rouge, LA CTF Cora Texas Manufacturing CU Clemson University DNIRI Delta -
Aldrich Organometallic, Inorganic, Silanes, Boranes, and Deuterated Compounds
Aldrich Organometallic, Inorganic, Silanes, Boranes, and Deuterated Compounds Library Listing – 1,523 spectra Subset of Aldrich FT-IR Library related to organometallic, inorganic, boron and deueterium compounds. The Aldrich Material-Specific FT-IR Library collection represents a wide variety of the Aldrich Handbook of Fine Chemicals' most common chemicals divided by similar functional groups. These spectra were assembled from the Aldrich Collections of FT-IR Spectra Editions I or II, and the data has been carefully examined and processed by Thermo Fisher Scientific. Aldrich Organometallic, Inorganic, Silanes, Boranes, and Deuterated Compounds Index Compound Name Index Compound Name 1066 ((R)-(+)-2,2'- 1193 (1,2- BIS(DIPHENYLPHOSPHINO)-1,1'- BIS(DIPHENYLPHOSPHINO)ETHAN BINAPH)(1,5-CYCLOOCTADIENE) E)TUNGSTEN TETRACARBONYL, 1068 ((R)-(+)-2,2'- 97% BIS(DIPHENYLPHOSPHINO)-1,1'- 1062 (1,3- BINAPHTHYL)PALLADIUM(II) CH BIS(DIPHENYLPHOSPHINO)PROPA 1067 ((S)-(-)-2,2'- NE)DICHLORONICKEL(II) BIS(DIPHENYLPHOSPHINO)-1,1'- 598 (1,3-DIOXAN-2- BINAPH)(1,5-CYCLOOCTADIENE) YLETHYNYL)TRIMETHYLSILANE, 1140 (+)-(S)-1-((R)-2- 96% (DIPHENYLPHOSPHINO)FERROCE 1063 (1,4- NYL)ETHYL METHYL ETHER, 98 BIS(DIPHENYLPHOSPHINO)BUTAN 1146 (+)-(S)-N,N-DIMETHYL-1-((R)-1',2- E)(1,5- BIS(DI- CYCLOOCTADIENE)RHODIUM(I) PHENYLPHOSPHINO)FERROCENY TET L)E 951 (1,5-CYCLOOCTADIENE)(2,4- 1142 (+)-(S)-N,N-DIMETHYL-1-((R)-2- PENTANEDIONATO)RHODIUM(I), (DIPHENYLPHOSPHINO)FERROCE 99% NYL)ETHYLAMIN 1033 (1,5- 407 (+)-3',5'-O-(1,1,3,3- CYCLOOCTADIENE)BIS(METHYLD TETRAISOPROPYL-1,3- IPHENYLPHOSPHINE)IRIDIUM(I) -
Ep 2508506 A1
(19) & (11) EP 2 508 506 A1 (12) EUROPEAN PATENT APPLICATION (43) Date of publication: (51) Int Cl.: 10.10.2012 Bulletin 2012/41 C07C 67/343 (2006.01) C07C 227/08 (2006.01) C07F 5/02 (2006.01) C07C 229/34 (2006.01) (21) Application number: 11161611.6 (22) Date of filing: 08.04.2011 (84) Designated Contracting States: (72) Inventor: The designation of the inventor has not AL AT BE BG CH CY CZ DE DK EE ES FI FR GB yet been filed GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR (74) Representative: Kunic Tesovic, Barbara Designated Extension States: Lek Pharmaceuticals d.d. BA ME Sandoz Development Center Slovenia - Patents Verovskova 57 (71) Applicant: LEK Pharmaceuticals d.d. 1526 Ljubljana (SI) 1526 Ljubljana (SI) (54) Preparation of sitagliptin intermediates (57) The invention relates to the preparation of chiral compounds, in particular to the preparation of chiral compounds which may be used as intermediates for the preparation of anti-diabetic agents, preferably sitagliptin. EP 2 508 506 A1 Printed by Jouve, 75001 PARIS (FR) EP 2 508 506 A1 Description Field of the Intention 5 [0001] The present invention relates to the preparation of chiral compounds, in particular to the preparation of chiral compounds which may be used as intermediates for the preparation of anti-diabetic agents, preferably sitagliptin. Background prior art 10 [0002] Type II diabetes mellitus (T2DM) is a global epidemic. Therefore, the research is oriented in the development of selective inhibitors of the enzyme DPP-IV as a promising new treatment for the type II diabetes. -
Chapter 2 Atoms, Molecules and Ions
Chapter 2 Atoms, Molecules and Ions PRACTICING SKILLS Atoms:Their Composition and Structure 1. Fundamental Particles Protons Electrons Neutrons Electrical Charges +1 -1 0 Present in nucleus Yes No Yes Least Massive 1.007 u 0.00055 u 1.007 u 3. Isotopic symbol for: 27 (a) Mg (at. no. 12) with 15 neutrons : 27 12 Mg 48 (b) Ti (at. no. 22) with 26 neutrons : 48 22 Ti 62 (c) Zn (at. no. 30) with 32 neutrons : 62 30 Zn The mass number represents the SUM of the protons + neutrons in the nucleus of an atom. The atomic number represents the # of protons, so (atomic no. + # neutrons)=mass number 5. substance protons neutrons electrons (a) magnesium-24 12 12 12 (b) tin-119 50 69 50 (c) thorium-232 90 142 90 (d) carbon-13 6 7 6 (e) copper-63 29 34 29 (f) bismuth-205 83 122 83 Note that the number of protons and electrons are equal for any neutral atom. The number of protons is always equal to the atomic number. The mass number equals the sum of the numbers of protons and neutrons. Isotopes 7. Isotopes of cobalt (atomic number 27) with 30, 31, and 33 neutrons: 57 58 60 would have symbols of 27 Co , 27 Co , and 27 Co respectively. Chapter 2 Atoms, Molecules and Ions Isotope Abundance and Atomic Mass 9. Thallium has two stable isotopes 203 Tl and 205 Tl. The more abundant isotope is:___?___ The atomic weight of thallium is 204.4 u. The fact that this weight is closer to 205 than 203 indicates that the 205 isotope is the more abundant isotope. -
Growth and Characterization of Bn Thin Films Deposited by Pacvd
GROWTH AND CHARACTERIZATION OF BN THIN FILMS DEPOSITED BY PACVD A thesis for the degree of Ph.D. Presented to DUBLIN CITY UNIVERSITY by MD. ZIAUL KARIM, M. Sc.(EEE) SCHOOL OF ELECTRONIC ENGINEERING DUBLIN CITY UNIVERSITY RESEARCH SUPERVISOR DR. DAVID C. CAMERON February, 1993. TO THE DEAREST MEMBERS OF SHAPBNIL LODGE MUM, DAD PIAS, LUCKY, SOHAIL & BIPLAB DECLARATION I hereby certify that this material, which I now submit for the assessment on the programme of study leading to the award of Ph.D. is entirely my own work and has not been taken from the work of others save and to the extent that such work has been cited and acknowledged within the text of my work. Signed: Date: February 2, 1993. ACKNOWLEDGEMENTS I am greatly indebted to Dr. David Cameron for his guidance and tuition in the course of this work. Without his enthusiasm and continual drive to increase our understanding of plasma technology, we would not have acquired such an in-depth knowledge of plasma techniques. To Professor M. S. J. Hashmi, a special word of appreciation and gratitude for his guidance and enthusiasm and for affording me the opportunity to pursue this work. I must also acknowledge the help of my fellow Mend, Michael Murphy for his continuous cooperation throughout the last few years and for helping me in writing this thesis. Without the continued assistance of both Hafizur Rahman and Rowshan Hafiz in preparing this thesis, it would not have been possible to complete it for me in the present time scale just after my glandular fever. -
WO 2013/089962 Al 20 June 2013 (20.06.2013) W P O P C T
(12) INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (19) World Intellectual Property Organization International Bureau (10) International Publication Number (43) International Publication Date WO 2013/089962 Al 20 June 2013 (20.06.2013) W P O P C T (51) International Patent Classification: (81) Designated States (unless otherwise indicated, for every B01J 31/04 (2006.01) B01J 31/18 (2006.01) kind of national protection available): AE, AG, AL, AM, B01J 31/14 (2006.01) B01J 31/22 (2006.01) AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DK, DM, (21) Number: International Application DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, PCT/US20 12/065285 HN, HR, HU, ID, IL, IN, IS, JP, KE, KG, KM, KN, KP, (22) International Filing Date: KR, KZ, LA, LC, LK, LR, LS, LT, LU, LY, MA, MD, 15 November 2012 (15.1 1.2012) ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, (25) Filing Language: English RW, SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, (26) Publication Language: English TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW. (30) Priority Data: 13/323,328 12 December 201 1 (12. 12.201 1) US (84) Designated States (unless otherwise indicated, for every kind of regional protection available): ARIPO (BW, GH, (71) Applicant (for all designated States except US): CHEV¬ GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, SZ, TZ, RON PHILLIPS CHEMICAL COMPANY LP UG, ZM, ZW), Eurasian (AM, AZ, BY, KG, KZ, RU, TJ, [US/US]; 10001 Six Pines Drive, The Woodlands, Texas TM), European (AL, AT, BE, BG, CH, CY, CZ, DE, DK, 77380 (US). -
Safety Data Sheet Acc
Page 1/6 Safety Data Sheet acc. to OSHA HCS Printing date 01/23/2014 Reviewed on 01/07/2010 1 Identification Product identifier Product name: Boron triiodide Stock number: 87220 CAS Number: 13517-10-7 EC number: 236-857-4 Relevant identified uses of the substance or mixture and uses advised against. Identified use: SU24 Scientific research and development Details of the supplier of the safety data sheet Manufacturer/Supplier: Alfa Aesar, A Johnson Matthey Company Johnson Matthey Catalog Company, Inc. 30 Bond Street Ward Hill, MA 01835-8099 Tel: 800-343-0660 Fax: 800-322-4757 Email: [email protected] www.alfa.com Information Department: Health, Safety and Environmental Department Emergency telephone number: During normal hours the Health, Safety and Environmental Department at (800) 343-0660. After normal hours call Carechem 24 at (866) 928-0789. 2 Hazard(s) identification Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 GHS05 Corrosion Skin Corr. 1B H314 Causes severe skin burns and eye damage. Eye Dam. 1 H318 Causes serious eye damage. Classification according to Directive 67/548/EEC or Directive 1999/45/EC C; Corrosive R34: Causes burns. R14: Reacts violently with water. Information concerning particular hazards for human and environment: Not applicable Hazards not otherwise classified Reacts violently with water. Label elements Labelling according to Regulation (EC) No 1272/2008 The substance is classified and labeled according to the CLP regulation. Hazard pictograms GHS05 Signal word Danger Hazard statements H314 Causes severe skin burns and eye damage. Precautionary statements P280 Wear protective gloves/protective clothing/eye protection/face protection. -
Hazardous Substances (Chemicals) Transfer Notice 2006
16551655 OF THURSDAY, 22 JUNE 2006 WELLINGTON: WEDNESDAY, 28 JUNE 2006 — ISSUE NO. 72 ENVIRONMENTAL RISK MANAGEMENT AUTHORITY HAZARDOUS SUBSTANCES (CHEMICALS) TRANSFER NOTICE 2006 PURSUANT TO THE HAZARDOUS SUBSTANCES AND NEW ORGANISMS ACT 1996 1656 NEW ZEALAND GAZETTE, No. 72 28 JUNE 2006 Hazardous Substances and New Organisms Act 1996 Hazardous Substances (Chemicals) Transfer Notice 2006 Pursuant to section 160A of the Hazardous Substances and New Organisms Act 1996 (in this notice referred to as the Act), the Environmental Risk Management Authority gives the following notice. Contents 1 Title 2 Commencement 3 Interpretation 4 Deemed assessment and approval 5 Deemed hazard classification 6 Application of controls and changes to controls 7 Other obligations and restrictions 8 Exposure limits Schedule 1 List of substances to be transferred Schedule 2 Changes to controls Schedule 3 New controls Schedule 4 Transitional controls ______________________________ 1 Title This notice is the Hazardous Substances (Chemicals) Transfer Notice 2006. 2 Commencement This notice comes into force on 1 July 2006. 3 Interpretation In this notice, unless the context otherwise requires,— (a) words and phrases have the meanings given to them in the Act and in regulations made under the Act; and (b) the following words and phrases have the following meanings: 28 JUNE 2006 NEW ZEALAND GAZETTE, No. 72 1657 manufacture has the meaning given to it in the Act, and for the avoidance of doubt includes formulation of other hazardous substances pesticide includes but -
Single-Crystal Calcium Hexaboride Nanowires: Synthesis And
NANO LETTERS 2004 Single-Crystal Calcium Hexaboride Vol. 4, No. 10 Nanowires: Synthesis and 2051-2055 Characterization Terry T. Xu,† Jian-Guo Zheng,‡ Alan W. Nicholls,§ Sasha Stankovich,† Richard D. Piner,† and Rodney S. Ruoff*,† Department of Mechanical Engineering, Northwestern UniVersity, EVanston, Illinois 60208, NUANCE Center, Northwestern UniVersity, EVanston, Illinois 60208, and Research Resource Center, UniVersity of Illinois at Chicago, Chicago, Illinois 60612 Received August 17, 2004 ABSTRACT Catalyst-assisted growth of single-crystal calcium hexaboride (CaB6) nanowires was achieved by pyrolysis of diborane (B2H6) over calcium oxide (CaO) powders at 860−900 °C and ∼155 mTorr in a quartz tube furnace. TEM electron diffraction and Raman spectroscopy indicate that the nanowires are single-crystal CaB6 and have a preferred [001] growth direction. Analysis of TEM/EDX/EELS data proves the nanowires consist of CaB6 cores and thin (1−2 nm) amorphous oxide shell material. The CaB6 nanowires have diameters of ∼15−40 nm, and lengths of ∼1−10 µm. -2 22 Calcium hexaboride (CaB6), one of the divalent alkaline- (CaCO3) and boron carbide (B4C) at 1400 °C and 10 Pa, earth cubic hexaborides, has low density (2.45 g/cm3), high by reduction of calcium oxide (CaO) with B at 1200-1800 3 melting point (2235 °C), high hardness (Knoop: 2600 kg/ °C in vacuum, and by reaction of calcium chloride (CaCl2) 2 mm ), high Young’s modulus (379 GPa), and high chemical with sodium borohydride (NaBH4)at500°C in an autoclave 1,2 23 stability. CaB6 has found application as a high-temperature for8h. The finest crystalline CaB6 powders synthesized material, is used for surface protection, and as a wear resistant so far have an average size of 180 nm.23 1,2 material. -
CHEM Safety Manual
Department of Chemistry Safety Manual October 2018 Safety Committee Department of Chemistry Hong Kong University of Science and Technology Table of Contents 1.0 Introduction 2.0 Safety Policy and Responsibility for Safety 2.1 Department Head 2.2 Department of Chemistry Safety Committee 2.3 Laboratory Supervisors 2.4 Researchers 2.5 HSEO 3.0 Information, Training, Safety Clearance, and Safety Clearance at Termination 3.1 Initial Training 3.2 Information on Hazardous Substances 3.3 Additional Safety Information 3.4 Safety Clearance at Termination 4.0 Personal Protective Equipment and Safety Engineering Controls 4.1 Eye Protection 4.2 Protective Apparel 4.3 Respirators 4.4 Laboratory Fume Cupboards 4.5 Fire Extinguishers, Safety Showers, and Eyewash Facilities 5.0 Standard Operating Procedures for Work with Hazardous Substances 5.1 Classes of Hazardous Substances 5.2 General Procedures for Work with Toxic Substances 5.3 General Procedures for Work with Flammable and Explosive Substances 6.0 Procedures for Work with Particularly Hazardous Substances 6.1 Identification and Classification of Particularly Hazardous Substances 6.2 Designated Areas 6.3 General Procedures for Work with Substances of Moderate to High Chronic or High Acute Toxicity 6.4 Additional Procedures for Work with Substances of Known High Chronic Toxicity 6.5 Specific Handling Procedures for Some Common Particularly Hazardous Substances 7.0 Proper Planning of Laboratory Work 7.1 Recognition and Assessment 7.2 Planning for the Unexpected: What Could Go Wrong? 7.3 Site Selection -
Low-Temperature Synthesis of Boride Powders by Controlling Microstructure in Precursor Using Organic Compounds
Journal of the Ceramic Society of Japan 126 [8] 602-608 2018 -Japan DOI http://doi.org/10.2109/jcersj2.18093 JCS SPECIAL ARTICLE The 72th CerSJ Awards for Advancements in Ceramic Science and Technology: Review Low-temperature synthesis of boride powders by controlling microstructure in precursor using organic compounds Masaki KAKIAGE1,³ 1 Institute for Fiber Engineering, Shinshu University (IFES), Interdisciplinary Cluster for Cutting Edge Research (ICCER), Shinshu University, 3–15–1 Tokida, Ueda, Nagano 386–8567, Japan The carbothermal reduction of boron oxide (B2O3) is an important process for the synthesis of boride powders. As a low-temperature synthesis method for boron carbide (B4C) powder by carbothermal reduction, we focused on an approach using a condensed product prepared from boric acid (H3BO3) and an organic compound with a number of hydroxyl groups (a polyol) such as glycerin, mannitol, or poly(vinyl alcohol). A borate ester bond was formed by the dehydration condensation of H3BO3 and a polyol, leading to the homogeneous dispersion of the boron and carbon sources at the molecular level. The thermal decomposition of a condensed H3BO3-polyol product in air was performed to control the amount of carbon to the stoichiometric C/B2O3 ratio required for carbothermal reduction. Within the thermally decomposed product consisting of B2O3 and carbon compo- nents (B4C precursor), a B2O3/carbon structure at the nanometer scale was formed. The improved dispersibility and homogeneity of the B2O3/carbon microstructure accelerated the B4C formation at a lower temperature. Consequently, crystalline B4C powder with little free carbon was synthesized by heat treatment at a low temperature of 1200°C in an Ar flow.