DOCSLIB.ORG

Complete List of Chemicals These Chemicals Are Stored in an Adjacent Area

Total Page：16

File Type：pdf, Size：1020Kb

Download full-text PDF Read full-text
Complete List of Chemicals These Chemicals Are Stored in an Adjacent Area Possible Hazards for FSCI - 210 Finger Print Dust (pulverized volcanic rock) Cyanoacrylate (super glue) Dried blood smears (human and canine) Hydrogen peroxide drops Ethyl alcohol drops Phenolphthalein drops Complete List of Chemicals These chemicals are stored in an adjacent area. Any could be used for another course in the same lab room as FSCI - 210 but at a different time. Exposure is possible but not probable. Acetanilide Ammonium Dichromate Acetic Acid, Glacial Ammonium Hydroxide Acetic Acid, 0.01M, 0.1M, 1M Ammonium Nitrate Acetic Anhydride Ammonium Nitrate, 0.1M Acetone Ammonium Oxalate Acrylic Acid Monohydrate Adhesive Side Powder, Dark Ammonium Persulfate Albumin, Egg Amyl Alcohol Alka-Seltzer Argon Spectrum Tubes All-Purpose Cleaner Arsenic Trioxide Aluminum (Foil) Ascorbic Acid (Vitamin C) Aluminum (Wire) Aspirin (Acetylsalicylic Acid) Aluminum Nitrate – 9-hydrate Barium Chloride-anhydrous Aminobenzoic Acid, 3- Barium Chloride-2-hydrate Ammonia (household) Barium Hydroxide – Anhydrous Ammonia Tablets #1, #2 Barium Hydroxide – 8-hydrate Ammonium Acetate Barium Nitrate Ammonium Acetate, 0.1M Basic Yellow Ammonium Bicarbonate Benzil Ammonium Chloride Benzoic Acid Benzophenone Copper(II) Nitrate–2½-hydrate Bleach Copper(II) Sulfate–Anhydrous Bogen Universal Indicator Copper(II) Sulfate–5-hydrate Boiling Chips, pumice Cyanoacrylate Cyclohexane Boric Acid Cyclohexanol Boric Acid, 0.1M Cyclohexanone Brass Cyclohexene Bromcresol Green Indicator Deet (N,N-diethyl-m-toluamide) Bromoethane (Ethyl Bromide) Dessicant Bromothymol Blue Dichlorobenzene-p (PDB) Diethyl Ether, anhydrous Buffer solutions, pH4,pH7,pH10 (Ether) Butyl Alcohol-n Diethylamine Butyl Alcohol-tert Dimethoxybenzaldehyde, 3,4- Caffeine Dimethylformamide, N,N- Caffeine Dimethylglyoxime Calcium Granules Dinitrobenzoic Acid-3,5 Calcium Turnings Diphenylaminesulfonic Acid Calcium Acetate Dodecyl Alcohol Calcium Carbonate EDTA Calcium Chloride – Anhydrous Ethyl Acetate Calcium Chloride – 2-hydrate Ethyl Alcohol Calcium Hydroxide (Lime) Ethyl Alcohol, 95% Calcium Nitrate – 4-hydrate Ethyl Bromide (Bromoethane) Calcium Oxide Ethylenediamine Calcium Sulfate – 2-hydrate Ferric Tartrate Camphor-dl Fluorene Carbon (Charcoal) Formaldehyde Casein Formic Acid Casting Plaster– Footprint Fructose Catechol (Pyrocatechol) Furfural Celite (Diatomaceous Earth) Gallium Chlorobeneze Glass Beads Chlorobenzoic Acid-p Glycerin Chloroform Gold Chromium Tablet Helium Spectrum Tubes Citric Acid – Anhydrous Hexamethylenediamine Club Soda (Carbonic Acid) Hexanes Cobalt Chloride – 6-hydrate Hydrochloric Acid Cobalt Nitrate – 6-hydrate Hydrogen Spectrum Tubes Congo Red Hydrogen Peroxide, 3% Copper solid Hydrogen Peroxide, 30% Copper(II) Chloride–2-hydrate Indanone, 1- MIKROSIL Casting Compound Iodine solid MIKROSIL Catalyst Iodine Solution Molybdic Acid Iodine Spectrum Tubes Naphthalene Iodoacetophenone, 4’ Neon Spectrum Tubes Iodophenol, 4 Nickel (II) Chloride – 6-hydrate Nickel Nitrate – 6-hydrate Iron (Filings) Ninhydrin – monohydrate Iron (III) Chloride – 6-hydrate Ninhydrin Spray Iron (III) Nitrate – 9-hydrate Nitric Acid Iron (II) Sulfate – 7-hydrate Nitrogen Spectrum Tubes Iron (II) Sulfide – Anhydrous Oleic Acid Isoamyl Alcohol Oxalic Acid Iso-butanol Oxygen Spectrum Tubes Isopropyl Alcohol Palladium (II) Chloride Krypton Spectrum Tubes Phenol Latent Print Powder, Magnetic Phenolphthalein Latent Print Powder, Silk Black Phenylboronic Acid Latex liquid Phosphoric Acid Lead Phthalic Acid Lead Chloride Phthalic anhydride Lead Nitrate Polyvinyl Alcohol Lithium Chloride Potassium Acid Phthalate Lycopodium Potassium Bromide Lye (Sodium Hydroxide) Potassium Carbonate – anhydrous Magnesium Metal Ribbon Magnesium Chloride – 6- Potassium Chlorate hydrate Potassium Chloride Manganese Sulfate Potassium Chromate monohydrate Potassium Citrate – Magnesium Sulfate – Monohydrate anhydrous Potassium Dichromate Malonic Acid Potassium Ferrocyanide– Manganese Chloride–4-hydrate 3hydrate Manganese Dioxide Potassium Hydroxide Manganese Sulfate Potassium Iodate monohydrate Potassium Iodide Mercury Spectrum Tubes Potassium Nitrate Methyl Alcohol (Methanol) Potassium Oxalate– Methyl Ethyl Ketone Monohydrate Methyl Formate Potassium Permanganate Potassium Phosphate– Methyl Orange Sodium Salt Monobasic Methyl Orange Indicator Potassium Thiocyanate Methylene Chloride Propyl Alcohol-n Pyrocatechol (Catechol) Thyionyl Chloride Salicylamide Tin solid Salicylic Acid Tin (II) Chloride – 2-hydrate Sebacoyl Chloride Toluene Silver Toluic Acid-m Silver Nitrate Toluic Acid-p Small Particle Reagent, Dark Trichloroethylene Sodium Acetate – Anhydrous Urea Sodium Acetate – 3-hydrate Vanillin Sodium Bicarbonate Vegetable Oil Sodium Bisulfate Xenon Spectrum Tubes Sodium Bisulfite Xylene Sodium Borohydride Zinc solid Sodium Bromide Zinc Chloride Sodium Carbonate–Anhydrous Zinc Nitrate – 6-hydrate Octyl Alcohol Sodium Carbonate– Monohydrate Sodium Chloride Sodium Dichromate – Dihydrate Sodium Hydroxide Sodium Iodide Sodium Nitrate Sodium Nitrite Sodium Phosphate Monohydrate Sodium Phosphate 7-hydrate Sodium Phosphate 12-hydrate Sodium Sulfate Anhydrous Sodium Sulfate 10-hydrate Sodium Sulfide 9-hydrate Sodium Sulfite Anhydrous Sodium Tetraborate (Borax) Sodium Thiosulfate Anhydrous Starch, Potato Steel Shots Strontium Chloride – 6-hydrate Strontium Nitrate Sucrose Sulfur, Flowers of (sublimed) Sulfuric Acid Tannic Acid Thiamine Hydrochloride Thioacetamide .
Load more

Recommended publications
  • Potassium Iodide (KI): Instructions for Children
    Potassium Iodide (KI): Instructions for Children The thyroid gland in children is very sensitive to the effects of radioactive iodine. In the event of a nuclear emergency, it is important for adults to understand how to prepare the proper dosage of potassium iodide (KI) for young children. The following information will help you to give KI to your children properly. Children over 12 years to 18 years 2 tablets (whole or crushed) (130 mg) (who weigh at least 150 pounds) Children over 12 years to 18 years 1 tablet (whole or crushed) or 8 teaspoons (65 mg) (who weigh less than 150 pounds) Children over 3 years to 12 years 1 tablet (whole or crushed) or 8 teaspoons (65 mg) Children over 1 month to 3 years 4 teaspoons (32.5 mg) Babies at birth to 1 month 2 teaspoons (16.25 mg) Tablets can be crushed and mixed in many liquids. To take the tablet in liquid solution, use dosing directions under “Making a Potassium Iodide Liquid Mixture.” Take KI only as directed by public officials. Do not take more than 1 dose in 24 hours. More will not help you. Too much medicine may increase the chances of side effects. Making a Potassium Iodide Liquid Mixture 1. Put one 65 mg KI tablet into a small bowl and grind it into a fine powder using the back of a metal teaspoon against the inside of the bowl. The powder should not have any large pieces. 2. Add 4 teaspoons of water to the crushed KI powder in the bowl and mix until the KI powder is dissolved in the water.
    [Show full text]
  • Determination of Iodate in Iodised Salt by Redox Titration
    College of Science Determination of Iodate in Iodised Salt by Redox Titration Safety • 0.6 M potassium iodide solution (10 g solid KI made up to 100 mL with distilled water) • 0.5% starch indicator solution Lab coats, safety glasses and enclosed footwear must (see below for preparation) be worn at all times in the laboratory. • 250 mL volumetric flask Introduction • 50 mL pipette (or 20 and 10 mL pipettes) • 250 mL conical flasks New Zealand soil is low in iodine and hence New Zealand food is low in iodine. Until iodised salt was • 10 mL measuring cylinder commonly used (starting in 1924), a large proportion • burette and stand of school children were reported as being affected • distilled water by iodine deficiency – as high as 60% in Canterbury schools, and averaging 20 − 40% overall. In the worst cases this deficiency can lead to disorders such as Method goitre, and impaired physical and mental development. 1. Preparation of 0.002 mol L−1 sodium thiosulfate In earlier times salt was “iodised” by the addition of solution: Accurately weigh about 2.5 g of solid potassium iodide; however, nowadays iodine is more sodium thiosulfate (NaS2O3•5H2O) and dissolve in commonly added in the form of potassium iodate 100 mL of distilled water in a volumetric flask. (This gives a 0.1 mol L−1 solution). Then use a pipette to (KIO3). The Australia New Zealand Food Standards Code specifies that iodised salt must contain: “equivalent to transfer 10 mL of this solution to a 500 mL volumetric no less than 25 mg/kg of iodine; and no more than 65 flask and dilute by adding distilled water up to the mg/kg of iodine”.
    [Show full text]
  • 2-‐Bromobutane
    Practice Questions 1. What is true about the reaction between (R)-2-bromobutane and potassium cyanide as shown below? Br KCN a) The product is a racemic mixture. b) The product is (S)-2-cyanobutane. c) The mechanism proceeds through a stable intermediate. d) The mechanism proceeds through a single transition state step. e) Answers a and c. f) Answers b and d. 2. The following reaction goes through an SN2 mechanism. - - CH3CH2CH2Br + OH à CH3CH2CH2OH + Br At constant temperature, what is the effect on the rate of the reaction by simultaneously doubling the concentration of propyl bromide and OH- ion? a) It would increase the rate by six. b) It would double the rate. c) It would triple the rate. d) It would increase the rate by four. e) It would have no effect on the rate. 3. Which is the minor substitution product in the following reaction? a) I b) II c) III d) Equal amounts of I and II e) None of these products 4. What is the major product of the following reaction? a) I b) II c) III d) IV e) Equal amount of I and III 5. Consider the reaction between 2-bromo-2,4-dimethylpentane and sodium iodide, NaI, in acetone. Br NaI I acetone At constant temperature, what is the effect on the reaction rate if one simultaneously double the concentration of 2-bromo-2,4-dimethylpentane and sodium iodide? a) It would double the reaction rate. b) It would triple the reaction rate. c) It would quadruple the reaction rate. d) It would increase the reaction rate by 5.
    [Show full text]
  • Sodium Iodide Spotlight 352 Compiled by Vinícius Rangel Campos Vinícius Rangel Campos Was Born in Niterói/RJ, Brazil in 1986
    1186 SPOTLIGHT SYNLETT Sodium Iodide Spotlight 352 Compiled by Vinícius Rangel Campos Vinícius Rangel Campos was born in Niterói/RJ, Brazil in 1986. He This feature focuses on a re- received his Chemistry degree from the Universidade Federal Fluminense (UFF), Niterói/RJ, Brazil in 2009. He is currently in the agent chosen by a postgradu- final stages of his MSc. studies under the supervision of Professors ate, highlighting the uses and Anna Claudia Cunha and Vitor Francisco Ferreira in Organic preparation of the reagent in Chemistry at the Universidade Federal Fluminense. His research in- current research terest is focused on the design and synthesis of new bioactive com- pounds, such as quinone and 1,2,3-triazole derivatives. Instituto de Química, Universidade Federal Fluminense, UFF, CEP: 24020-141 Niterói, Rio de Janeiro, Brazil E-mail: [email protected] Introduction NaI R–I NaX + R–X acetone Sodium iodide (NaI) occurs as colorless, odorless or as a X = Cl or Br white crystalline solid; it is slightly hygroscopic, and a commercially available reagent. It is soluble in water, Scheme 1 alcohols, acetone, and other organic solvents and stable This reaction has been expanded to include the conversion under normal temperature and pressure (mp: 651 °C, of alcohols into alkyl halides by first converting the alco- d = 3.67 g/cm3).1 On a laboratory scale, sodium iodide hol into a sulfonate ester (tosylates or mesylates are usu- may be prepared by neutralizing a solution of sodium hy- ally used), and then performing the substitution.6 Other droxide or sodium carbonate with hydriodic acid.2 Sodi- applications using sodium iodide as reagent in organic um iodide is a very useful and versatile reagent for the synthesis have been reported.
    [Show full text]
  • Revision of KS4 the Periodic Table for KS5 Chemistry - Worksheet
    Revision of KS4 The Periodic Table for KS5 Chemistry - Worksheet 1. On the copy of the periodic table (next page) label the following: a. metals and non metals b. groups (with numbers) c. periods (with numbers) d. transition elements 2. How are elements in the periodic table ordered? 3. Find two examples where the mass number does not increase. 4. How many electrons does Magnesium have in its highest energy level? 5. How many electrons does Oxygen have in its highest energy level? 6. What do elements in the same group have in common? 7. What happens to reactivity in group 1 as you go down the group? 8. What happens to reactivity in group 7 as you go down the group? 9. Name 1 similarity and 1 difference between group 1&2 metals and the transition elements. 10. Write a word and symbol equation to show how sodium reacts with water. 11. If identical pieces of lithium and potassium were dropped into a bowl of water at the same time describe how their reactions would differ. 12. Complete the table with ticks to show which reaction will happen. Fluorine Chlorine Bromine Iodine Sodium fluoride Sodium chloride Sodium bromide Sodium iodide Extension Question Research the appearance and state of group 7 elements, use this knowledge to predict observation for the reaction in question 12. Revision of KS4 The Periodic Table for KS5 Chemistry Image credit to LeVanHan https://commons.wikimedia.org/wiki/File:Periodic-table.jpg Revision of KS4 The Periodic Table for KS5 Chemistry Revision of KS4 The Periodic Table for KS5 Chemistry - Worksheet (Answers) 1.
    [Show full text]
  • The Summer Assignment Will Receive a GRADE on the First Day of Class – August 9
    Bishop Moore AP Chemistry Summer Assignment June 2017 Future AP Chemistry Student, Welcome to AP Chemistry. In order to ensure the best start for everyone next fall, I have prepared a summer assignment that reviews basic chemistry concepts some of which you may have forgotten you learned. For those topics you need help with there are a multitude of tremendous chemistry resources available on the Internet. With access to hundreds of websites either in your home or at the local library, I am confident that you will have sufficient resources to prepare adequately for the fall semester. The reference text book as part of AP course is “Chemistry: The Central Science” by Brown LeMay 14th Edition for AP. Much of the material in this summer packet will be familiar to you. It will be important for everyone to come to class the first day prepared. While I review throughout the course, extensive remediation is not an option as we work towards our goal of being 100% prepared for the AP Exam in early May. There will be a test covering the basic concepts included in the summer packet during the first or second week of school. You may contact me by email: ([email protected]) this summer. I will do my best to answer your questions ASAP. I hope you are looking forward to an exciting year of chemistry. You are all certainly excellent students, and with plenty of motivation and hard work you should find AP Chemistry a successful and rewarding experience. Finally, I recommend that you spread out the summer assignment.
    [Show full text]
  • Potassium Iodide (KI) Preparation and Dosing Instructions for Use During a Nuclear Emergency to Make KI Solution (Liquid Form), Using Two 65 Mg KI Tablets
    Potassium Iodide (KI) Preparation and Dosing Instructions for Use During a Nuclear Emergency To Make KI Solution (Liquid Form), using two 65 mg KI Tablets If government authorities declare that a radiation emergency has occurred, you may have been exposed to radioactive iodine. Potassium iodide can prevent thyroid cancer in people who have been exposed to radioactive iodine. Potassium iodide is also known as KI. Children who have been exposed to radioactive iodine have a greater risk of thyroid cancer than adults do. You may need to make a KI solution (liquid form) for anyone who cannot swallow tablets. This sheet explains how to make and give the KI solution. FDA-approved KI tablets come in 65 mg and 130 mg strengths. Instructions for preparing the KI solution using two 65 mg tablets are given below. To Make the Potassium Iodide (KI) Solution You Will Need: Two 65 mg KI tablets Teaspoon Small bowl Four teaspoons of water Four teaspoons of a drink. We recommend any one of the following: ■ White milk ■ Chocolate milk ■ Orange juice ■ Soda (For example, cola) ■ Infant formula ■ Raspberry syrup ■ Water Directions for Making the Potassium Iodide (KI) Solution: Step 1. Soften the KI tablets: Put two 65 mg KI tablets into a small bowl. Add four teaspoons of water. Soak the tablets for one minute. Step 2. Crush the softened KI tablets: Use the back of the teaspoon to crush the tablets in the water. At the end of this step, there should not be any large pieces of KI. This makes the KI and water mixture.
    [Show full text]
  • Potassium Iodate, 0.00564N (0.00094M) Safety Data Sheet According to Federal Register / Vol
    Potassium Iodate, 0.00564N (0.00094M) Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Date of issue: 04/15/2015 Revision date: 02/08/2018 Supersedes: 02/08/2018 Version: 1.1 SECTION 1: Identification 1.1. Identification Product form : Mixtures Product name : Potassium Iodate, 0.00564N (0.00094M) Product code : LC19600 1.2. Recommended use and restrictions on use Use of the substance/mixture : For laboratory and manufacturing use only. Recommended use : Laboratory chemicals Restrictions on use : Not for food, drug or household use 1.3. Supplier LabChem Inc Jackson's Pointe Commerce Park Building 1000, 1010 Jackson's Pointe Court Zelienople, PA 16063 - USA T 412-826-5230 - F 724-473-0647 [email protected] - www.labchem.com 1.4. Emergency telephone number Emergency number : CHEMTREC: 1-800-424-9300 or 011-703-527-3887 SECTION 2: Hazard(s) identification 2.1. Classification of the substance or mixture GHS-US classification Not classified 2.2. GHS Label elements, including precautionary statements Not classified as a hazardous chemical. Other hazards not contributing to the : None under normal conditions. classification 2.4. Unknown acute toxicity (GHS US) Not applicable SECTION 3: Composition/Information on ingredients 3.1. Substances Not applicable 3.2. Mixtures Name Product identifier % GHS -US classification Water (CAS-No.) 7732-18-5 99.98 Not classified Potassium Iodate (CAS-No.) 7758-05-6 0.02 Ox. Sol. 3, H272 Full text of hazard classes and H-statements : see section 16 SECTION 4: First-aid measures 4.1.
    [Show full text]
  • TITRATIONS with POTASSIUM IODATE Potassium Iodate Is a Fairly
    TITRATIONS WITH POTASSIUM IODATE Potassium iodate is a fairly strong oxidizing agent that may be used in the assay of a number of pharmaceutical substances, for instance : benzalkonium chloride, cetrimide, hydralazine hydrochloride, potassium iodide, phenylhydrazine hydrochloride, semicarbazide hydrochloride and the like. Under appropriate experimental parameters the iodate reacts quantitatively with both iodides and iodine. It is, however, interesting to observe here that the iodate titrations may be carried out effectively in the presence of saturated organic acids, alcohol and a host of other organic substances. The oxidation-reduction methods with potassium iodate invariably based on the formation of iodine monochloride (ICl) in a medium of strong hydrochloric acid solution. Preparation of 0.05 M Potassium Iodate Potassium iodate is dried to a constant weight at 110°C to make it completely free from moisture and then brought to room temperature in a desiccator. It is pertinent to mention here that KIO3 is a very stable salt and may be obtained in a very pure form. Therefore, it is possible to prepare the standard solutions of KIO3 by dissolving the calculated weight of the salt in water and diluting the same to an approximate volume. Since, the normality of iodate solution varies significantly depending on the nature of the reaction, therefore, in usual practice standard iodate solutions of known molarity are used. The reduction of potassium iodate to iodide is usually not feasible in a direct titrimetric method (unlike the reduction of potassium bromate to bromide) and hence, has no viable application in the official procedures ...........................(a) In this type of reaction, 1 mol of KIO3 is 6 equivalent and a 0.05 M solution would be 0.3 N.
    [Show full text]
  • Elephant Toothpaste Lab
    Elephant Toothpaste Lab This is a guideline to help you write up a formal lab report. This is not to be used as the formals lab report. You do not have to turn this in. Purpose: To break down a compound and release the maximum amount of substance in an elemental form. Background: (Sample) Hydrogen peroxide is an extremely reactive substance with the symbol H2O2 (water is H2O). That extra oxygen atom makes hydrogen peroxide a powerful oxidizer and it is widely used in strong concentrations as an industrial bleaching agent. It is corrosive to human skin in concentrations above 8% but very useful as an antiseptic at lower concentrations such as 3%. Hydrogen peroxide readily decomposes into water (H2O) and oxygen gas (O2) in the presence of even trace amounts of a proper catalyst. Catalysts are chemicals that increase the rate of a reaction. It this case, the catalyst is being used to increase the rate of breakdown of H2O2. Just a few grams of the catalyst potassium iodide (KI) causes nearly all of the hydrogen peroxide in a 30% solution to rapidly decompose. Significant quantities of heat and oxygen gas are released during decomposition making this an exothermic (heat releasing) reaction that should be handled with care. A squirt of detergent lowers the solutions surface tension so that the oxygen produced forms tiny bubbles which combine to make a very large volume of foam. Add something about the strength of catalysts. You will need to look this up before coming to class. Question: Which catalyst concentration will supply the most oxygen, 2M or saturated potassium iodide solution? Hypothesis: I hypothesize _______________________________________________________ because _____________________________________________________________________________.
    [Show full text]
  • SN2 Reactions of Alkyl Halides
    SN 2 Reactions of Alkyl Halides OBJECTIVE To examine factors affecting the relative rates of the SN2 reaction of alkyl halides such as: • alkyl halide structure • nature of the leaving group • properties of the nucleophile • steric hindrance INTRODUCTION The alkyl halides play an important role in organic synthesis. They can be easily prepared from alcohols or alkenes, among other starting materials. They in turn can be used in the synthesis of a large number of functional groups. These syntheses are often carried out by nucleophilic substitution reactions in which the halide is replaced by some nucleophile. These substitution reactions can occur in one smooth step, or in two discrete steps, depending primarily on the structure of the alkyl group. These mechanisms are known as SN2 and SN1: In this laboratory period we will spend some time looking at SN2 reactions. To get started, let's propose a mechanism for the reaction: − − CH3Br + HO ! CH3OH + Br (1) • The rate of this reaction is directly proportional to the concentration of both methyl bromide and sodium hydroxide. − Rate = k[CH3Br][OH ] (2) • The reaction proceeds with inversion of configuration. Any ideas? This mechanism was initially elucidated by Sir Christopher Ingold and Edward Hughes, in the 1930s. They interpreted the second-order kinetic behavior to mean that the rate-determining step is a bimolecular, concerted process. δ− δ− − − HO + CH3Br ! HO − − CH3 − − Br ! CH3OH + Br (3) transition state c 2011-2013 Advanced Instructional Systems, Inc. and Maria Gallardo-Williams 1 Therefore the following mechanism was proposed | the backside attack of the nucleophile, with the leaving group leaving in a concerted step.
    [Show full text]
  • Chlorotrimethylsilane and Sodium Iodide
    View metadata, citation and similar papers at core.ac.uk brought to you by CORE provided by Archive Ouverte en Sciences de l'Information et de la Communication Chlorotrimethylsilane and Sodium Iodide: A Remarkable Metal-Free Association for the Desulfurization of Benzylic Dithioketals under Mild Conditions Guangkuan Zhao, Ling-Zhi Yuan, Mouad Alami, Olivier Provot To cite this version: Guangkuan Zhao, Ling-Zhi Yuan, Mouad Alami, Olivier Provot. Chlorotrimethylsilane and Sodium Iodide: A Remarkable Metal-Free Association for the Desulfurization of Benzylic Dithioketals under Mild Conditions. Advanced Synthesis and Catalysis, Wiley-VCH Verlag, 2018, 360 (13), pp.2522-2536. 10.1002/adsc.201800437. hal-02394255 HAL Id: hal-02394255 https://hal.archives-ouvertes.fr/hal-02394255 Submitted on 4 Dec 2019 HAL is a multi-disciplinary open access L’archive ouverte pluridisciplinaire HAL, est archive for the deposit and dissemination of sci- destinée au dépôt et à la diffusion de documents entific research documents, whether they are pub- scientifiques de niveau recherche, publiés ou non, lished or not. The documents may come from émanant des établissements d’enseignement et de teaching and research institutions in France or recherche français ou étrangers, des laboratoires abroad, or from public or private research centers. publics ou privés. FULL PAPER DOI: 10.1002/adsc.201((will be filled in by the editorial staff)) Chlorotrimethylsilane and Sodium Iodide: A Remarkable Metal- Free Association for the Desulfurization of Benzylic Dithioketals under Mild Conditions Guangkuan Zhao, Ling-Zhi Yuan, Mouad Alami* and Olivier Provot* BioCIS, Equipe Labellisée Ligue Contre le Cancer, Univ Paris-Sud, CNRS, University Paris Saclay, 92290, Châtenay- Malabry, France France Fax: (+33) 146-83-58-87, E-mail: [email protected] or [email protected] d: ((will be filled in by the editorial staff)) Supporting information for this article is available on the WWW under http://dx.doi.org/10.1002/adsc.201######.((Please delete if not appropriate)) Abstract.
    [Show full text]