Applications of Metal-Organic Frameworks in Heterogeneous Supramolecular Catalysis
Chemical Society Reviews Applications of Metal -Organic Frameworks in Heterogeneous Supramolecular Catalysis Journal: Chemical Society Reviews Manuscript ID: CS-REV-02-2014-000094.R1 Article Type: Review Article Date Submitted by the Author: 07-May-2014 Complete List of Authors: Liu, Jiewei; Sun Yat-Sen University, Chen, Lianfen; Sun Yat-Sen University, Cui, Hao; Sun Yat-Sen University, Zhang, Jianyong; Sun Yat-Sen University, School of Chemistry and Chemical Engineering Zhang, Li; Sun Yat-sen University, School of chemistry and chemical engineering Su, Cheng-Yong; Sun Yat-Sen University, School of Chemistry and Chemical Engineering Page 1 of 52 Chemical Society Reviews Journal Name RSC Publishing ARTICLE Applications of Metal-Organic Frameworks in Heterogeneous Supramolecular Catalysis Cite this: DOI: 10.1039/x0xx00000x Jiewei Liu, Lianfen Chen, Hao Cui, Jianyong Zhang, Li Zhang* and Cheng-Yong Su* Received 00th January 2012, Accepted 00th January 2012 This review summarizes the use of metal-organic frameworks (MOFs) as a versatile supramolecular platform to develop heterogeneous catalysts for a variety of organic reactions, DOI: 10.1039/x0xx00000x especially in liquid-phase reactions. Following a background introduction about catalytic www.rsc.org/ relevance to various metal-organic materials, crystal engineering of MOFs, characterization and evaluation methods of MOF catalysis, we categorize catalytic MOFs based on the types of active sites, including coordinatively unsaturated metal sites (CUMs), metalloligands, functional organic sites (FOS), as well as metal nanoparticles (MNPs) embedded in the cavities. Throughout the review, we emphasize the incidental or deliberate formation of active sites, the stability, heterogeneity and shape/size selectivity for MOF catalysis. Finally, we briefly introduce their relevance to photo- and biomimetic catalysis, and compare MOFs with other typical porous solids such as zeolites and mesoporous silica with regard to their different attributes, and provide our view on future trends and developments of MOF-based catalysis.
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