See Phenacetin

STP838-EB/May 1984

Index

Bayer, G., 107 Barrall,E.M.,l A (see Anthracene) Beidellite, 134 Accuracy, 6, 13, 22-23, 31-38, 40, Benzamide, 52, 55-56, 59-60, 142 47-49,141-142 Benzene, 25, 90-105, 142 Acetone, 41 Bell Laboratories, 1 Acetonitrile, 25 Benzoic acid, 6-7 Acetophenetidin {see Phenacetin) Bias {see Accuracy) Activity, 92 Biotite, 131 Adiabatic calorimetry {see Calorime- Bismuth, 76-77 try, adiabatic) Blaine, Roger L., editor, 1, 17, 21, 29, Admixtures, 123 141 Alloys, 76-80, 86, 142 Boric anhyride, 76 Aluminum, 130, 133 Brennan, William, P., 2, 5, 21, Aluminum oxide, 76, 122, 125 141-142 American Cyanamid, 21 Brick clay {see Ceramic clay) American Society for Testing and Mate Bridge, Mueller, 96 rials, 1-2,16,19,21,24,29,31, 141, 143 Aminobenzoic acid {see Para-aminobenzoic acid) Calciostrontiaite series, 133 Ammonia, 76-77 Calcite, 124-125, 128-129 Ankerite, 130-131 Calcium, 128 Annealing, 76 Calcium carbonate, 125 Antimony, 76-77 Calorimetry, adiabatic, 90, 92-95, 97, Anthracene, 61, 63-70, 142 99-100,142 Aragonites, 130 Carbon dioxide, 123 Arsenates, 136 Carbonates, 122-124, 143 Arsenic, 76-77 Ceramic clay, 124-125, 143 Assay, 26 Cerussites, 130 ASTM {see American Society for Test Chalcocite, 128-129 ing and Materials) Chalcogenides, 136 Azeotrope, 96 Chlorites, 122, 134-135, 143 Azobenzene, 112-117, 119 Chloroform, 41 Cholestane, 42 Chromatography {see Gas chromatog B raphy. Liquid chromatography. Barium, 124, 130 Thin layer chromatography)

145

Chromium, 82, 131, 135, 143 Dolomite, 123, 128-130 Circuitry, 96 Dopant, 52-53, 56 Clay {see Ceramic clay. Zeolites) Drugs {see Pharmaceuticals) Clinochlor, 135 Drying, 27 Colorimetry {see Spectrophotometry) DSC {see Differential scanning calo Composition, equivalent {see Equiva rimetry) lent composition) DTA {see Differential thermal analysis) Computer, 13, 23, 40, 108, 111 Du Pont Company {see E. I. du Pont de Concentration, 93 Nemours) Conductivity, electrical, 86 Dyes, 117 Copper, 78, 93, 128 Copper sulfide, 128-129 E Correction factor, 52 E. I. du Pont de Nemours, 1,17-21,24, Cryoscopy, 90-91, 96, 107, 142 31-30,40,42 Cryoscopic constant, 51, 59, 93, 99, BE {see Ethinyl estradiol) 107 ECG {see Equal G curve) Crystal defects, 122-123 Elder, J. P., 2, 21, 50, 142 Crystallization, 62,66-67,96-97,123, Electromotive force, 78-79, 81-82, 133 Curie temperature, 123, 131, 133 86-87, 142 Electron scattering {see Scattering, Current, % electron) D EMF {see Electromotive force) Data acquisition rate, 31, 35-36, 53 Encapsulation, 9-10 Decomposition, 123 Enthalpy of fusion, 7-8,30,49,51-52, Degradation 26, 31 56,65,68,92-93,99,107,113, Dehyroxylation, 123, 130, 133-134 118 Digenite, 128-129 Equal G curve, 67 Dibromobenzene, 66 Equivalent composition, 79-81 Dichlorobenzene, 66 Error, 6, 43, 48, 51, 81-82, 99 Differential Estrone, 41 Estrone methyl ether, 41 Scanning calorimetry, 5-15, 29, 39-40, 42-49, 50-51, 55, Ethinyl estradiol, 40-41, 43, 46-49 59-60, 61, 63, 65, 67-70, Ethinyl estradiol methy ether, 41 107-109, 112-115, 117-120, Eutectic,51,55,61-62,107-108,113, 141-143 132 Thermal analysis, 52, 121-136, 143 Dimethyl Formamide, 25 Fermi energy, 87-88 Sulfoxide, 25 Ferrillo, Rosalie G., 21 Dimethylnaphthalene, 61, 63-70, 142 Ferromagnetism, 131 Distribution coefficient, 61-62, 65 Ferrous {see Iron) DiVito, MichaelP.,5 Fisher Scientific Company, 18, 41 Djurleite, 128-129 Fraction melted {see Melt fraction) DMD {see Dimethylenaphthalene) Fraction, mole, 61, 65, 99, 107-108 INDEX 147

Fractional crystallization, 91, 142 Humidity, 23, 134 Freezing Hunter, John E.,m, 2, 29, 141 Curve, 91, 96 Hydroxides, 123, 143 Point, 62, 92 Hydrozincites, 130 Furukawa, George T., 2, 90, 142 Hygroscopicity, 27 Fyans, Richard L., 5 Hyperbolic function, 84

Gallagher, P.K., 1 Ice, 76-77, 100 Gam, Paul, 21 IBM {see International Business Ma chines) Gas chromatography, 6, 27, 40, 42-46, 49, 63, 142 ICTA {see International Conference on Thermal Analysis) GC {see Gas chromatography) Geochemical laws, 132 Ideality, 104-105 Germanium, 76 Identity, 40 Gibbs-Duhem equation, 92 lUites, 134 Gill, Philip S., 21 Impurity level, 24, 32-35, 56, 82 Goethite, 130-131, 133 Impurities, 76, 80, 82, 107, 121-123, Gold, 95 141 Graphite, 76 Inclusions, 122 Indium, 49 Gray, A. P., 5-8, 10, 12-13, 15, 141 Guttman, Charles M., 1-2, 16, 21, 31, Infrared spectrophotometry, 27, 122 141 Institute of Crystallography and Gypsum, 124-125 Petrography, 107 Integration limits, 12 Interlaboratory tests, 17-20, 23 H International Business Machines, 1 International Conference on Thermal Heat capacity, 7, 11, 56, 93, 97-100 Analysis, 17, 24 Heat of fusion {see Enthalpy of fusion) International Practical Temperature Heater, 95-96 Scale, 81, 96 Heating rate, 7, 9-11, 23, 32-35, 42, International Union of Pure and Ap 48-49, 65, 110, 122 plied Chemistry, 91-92 Hectorite, 134 Iron, 82, 128-130, 133, 135 Helium, 100 Isomers, 112-113, 119 Heptane, 91, 96-97, 104-105, 142 Isomerization, 117 Hewlett Packard, 25, 40, 111 Isothermal Step Purity Method, 19-20, History, thermal, 12 25, 51, 55-58, 142 Hoffman-LaRochelnc, 1, 18, 20-21, lUPAC {see International Union of 24 Pure and Applied Chemistry) Homogeneity, 23, 26, 28 Hot stage microscopy {see Thermo- microscopy) HPLC {see Liquid chromatography) Jacobson, Harold, 21 148 INDEX

K Temperature, 6-8, 51, 65-66, 70, Kalmmererites, 135-136 107-108, 113, 143 Kotschubeites, 135-136 Menis, O., 1, 21 Mestranol, 40, 43, 45, 47 Metals, 76,78, 80, 83-85, 88-89, 142 Methanol, 41-42 Lead, 76-77 Mettler Instruments Corporation, Lepidocrocite, 131 18-19, 63, 65, 107, 110, 122 Light, 23 Microcomputers (see Computers) Monochromatic, 112-113 Microscopy (see Thermomicroscopy) Polychromatic, 112-113 Mill, 25 Lim, Ofelia, 2, 39, 141 Minerals, 121-136, 142-143 Limits, integration (see Integration Mirabilite, 126 limits) Mixer, 25 Limonite, 131-132 MLR (see Multiple hnear regression) Linear regression (see Multiple linear Mole fraction (see Fraction, mole) regression) Molecular volume, 62 Liquid Monel, 94, 95 Chromatography, 25, 40, 42-43, 49 Monsanto Company, 21 Crystals, 112, 117 Montmorillonite, 134 Liquidus, 62, 65, 68 Moros, Stephen A., 1, 2, 18, 20-21, Lithium methoxide, 25 22, 141 MS (see Mass spectrometry) Multiple linear regression, 110-111 M Maghemite, 131 Magnesium, 128-129, 135 Magnesium oxide, 135 N Magnetic transition {see Curie tem National Bureau of Standards, 1, 16, perature) 21,25, 31,49,90-92,95-97 Magnetite, 131, 133 National Physical Laboratory, 112 Manganese, 82, 129, 131 NBS (see National Bureau of Stan Mass spectrometry, 27, 122, 126 dards) Materials, standard (see Standard ma NET (see Norethindrone) terials) Nickel, 81 Matthiessen's rule, 83 Nicolet Company, 25 Matrix, 24 Nitrogen, 41-42, 100 McGhie, Andrew R., 2, 61, 142 Nitric acid, 76 MEE (see Mestranol) NMR (see Nuclear magnetic reso Melt fraction, 8, 51, 58, 93, 102-103 nance) Melting Noise, 34, 36, 48 Curve, 7, 11, 23, 90-91 Nontronite, 134 Point (see Melting temperature) Norandrostendione, 41 Point depression, 7-8, 47-49, 50, Norethindrone, 41, 43-44, 47 107-108 Norethinyl testasterone, 41 INDEX 149

Norethynodrel, 41 Princeton Applied Research, 25 Norsethite, 124 Protocol, experimental, 17 Nuclear magnetic resonance, 25 PRS {see Standard materials) PRT {see Platinum resistance ther mometer) O Pump, 94, 95, 97 Oil, 76-78 Purity, 6, 23, 40, 75 Oliver, E., 39, 141 Pyrrhotite, 125, 121 Ortho Pharmaceutical, 39 Oxygen, 76 R Ramsland, Arnold, 25 Raoult's law, 91 Reference materials {see Standard ma Palermo, Eugene, 17 terials) Palygorskites, 134 Regression analysis {see Multiple lin PAMA (^see Para-aminobenzoic acid) ear regression) Para-aminobenzoic acid, 17, 24—28, Reilly, Martin L., 90 31, 52-57, 60, 141-142 Relative standard deviation {see Stan Partition coefficient, 59 dard deviation) Peak shape, 6-7 Resistance Pennwalt Corporation, 21 Electrical, 77-78, 80-81, 83, Perkin-Elmer Corporation, 5-6, 10, 85-87, 142 18-19, 21, 25, 40 Thermal, 9-11, 13, 83 Peritectic, 62, 68 Rhodochrosite, 131 Pharmaceuticals, 117 Riesen, R., 107 Pharmacopeia {see United States Phar Ripidolite, 135 macopeia) Round robin tests {see Interlaboratory Phase diagram, 61-67, 69, 122 tests) Phase solubility, 6, 19-20, 40 RSD {see Standard deviation) PHEN {see Phenacetin) Phenacetin, 17, 24-28, 31, 52-58, 60, 141 Phosphates, 136 Saponite, 134 Photomicrography, 28, 116, 119 Sapphire, 108, 112 Phyllosilicate, 134 Scanning rate {see Heating rate) Piccirelli, Jeanette H., 90 Scattering, electron, 87 Platinum, 122 Schaumann, Charles W., 21 Platinum resistance thermometer, 81, Scott, Charles E., 21 95-96, 142 Seals, vacuum, 95 Polarity, 83 Sepiolites, 134 Pollock, Daniel D., 2, 75, 142 Serpentines, 134 Potency, 40 Siderite, 130-131 Potential, electromotive, 96 Silicates, 135 Precision, 6, 13, 22, 35-37, 47-49, Silver, 76-77, 79, 82, 86, 142 141-142 Sintering, 123 150 INDEX

Size Thermal lag {see Resistance, thermal) Particle, 27-28 Thermal resistance {see Resistance, Specimen, 9-10, 31-35, 42 thermal) Smectites, 12, 134 Thermocouple, 76, 78, 82-83, 86, 94, Smykatz-Kloss, Werner, 2, 121, 143 95, 110, 122 Sodium sulfate (see Thenardites) Thermoelectric effect, 76, 78 Solid solution, 28, 61-62, 64-67, 70, Thermogravimetry, 52, 122, 126 91, 92, 107, 122, 132, 142 Thermometer, platinum resistance Solidus, 62-63, 65-66, 69 {see Platinum resistance ther Solute, 62 mometer) Sondack correction method, 54-56, Thermomicroscopy, 63, 107-108, 113, 60, 110-111 116-117, 142-143 Specific heat {see Heat capacity) Thin layer chromatography, 6, 19-20 Spectroscopy, 76 Thymol blue, 25 SPRT {see Thermometer, platinum re Tin, 76-77, 95 sistance) Titanium, 131 Squibb Research and Development, 21 Titration, 25 SRM {see Standard materials) TLC {see Thin layer chromatography) SRS {see Standard materials) Toxicity, 24 Stability, 26, 119 Triple point, 92-93, 98-100, 102-103 Standard Deviation, 18-19, 25, 43, 47-48 Materials, 6, 16, 19, 22, 40-41, 43, U 47, 117, 141-142 Ultraviolet spectrometry, 40, 42-44, Reference materials {see Standard 46, 49, 63, 142 materials) United States Pharmacopeia, 20, 40, Standards {see Standard materials) 42-46, 142 State University of New York, 75 University of Akron, 21 Stearic acid, 120 University of Karlsruhe, 121 Step method {see Isothermal step pu University of Kentucky, 21, 50 rity method) University of Pennsylvania, 61 Steroids, 39-40, 47, 141 USP {see United States Pharmacopeia) Strontianite, 124, 133-134 UV spectroscopy {see Ultraviolet Strontium, 124, 130 spectrometry) Strontium carbonate, 124-125 Sulfides, 125-126, 136, 143 Sulfur, 125-126, 128 Vacuum, 93, 97 Valence, 78, 81 Temperature coefficient, 76, 79-81, Validation, 22-23 83, 85, 142 Vanadates, 136 Tetratriacontane, 112, 117-118, 120 Van't Hoff equation, 7-8, 10, 12-13, TG {see Thermogravimetry) 16-17, 30, 51, 70, 90, Thenardites, 126-128 107-108, 110 INDEX 151

Vapor pressure, 92, 112, 119 Witherite, 124 Varian Instruments Company, 25, 40 Words/Numbers Processing Corpora Voltage (see Electromotive force) tion, 90 Volume, molecular {see Molecular volume)

W X-ray crystallography, 60, 117, 122-123, 126, 129, 131 Water, 43, 76-77, 96, 123-124, 126 Waters Associates, 40 Wax, 95 Wiedemann, Hans G., 2, 107, 137, Zeolites, 124 142 Zinnwaldite, 131-132 Wire, 76-77 Zone refining, 28, 62-63, 113, 117