Quantum Mathematics
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Quantum Mathematics by Peter J. Olver University of Minnesota Table of Contents 1. Introduction .................... 3 2. Hamiltonian Mechanics ............... 3 Hamiltonian Systems ................ 3 Poisson Brackets ................. 7 Symmetries and First Integrals ........... 9 Hamilton-Jacobi Theory .............. 11 3. Geometric Optics and Wave Mechanics ....... 25 The Wave Equation ................ 25 Maxwell’s Equations ................ 27 High Frequency Limit and Quantization ........ 29 4. Basics of Quantum Mechanics ........... 36 Phase space ....................36 Observables ....................37 Schr¨odinger’s Equation ............... 38 Spectrum .....................39 The Uncertainty Principle ............. 43 5. Linear Operators and Their Spectrum ....... 44 Hilbert Space and Linear Operators ......... 44 The Spectral Theorem ............... 46 Spectrum of Operators ............... 48 Dispersion and Stationary Phase ........... 55 6. One–Dimensional Problems ............. 59 The Harmonic Oscillator .............. 63 Scattering and Inverse Scattering .......... 65 Isopectral Flows ..................75 9/9/21 1 c 2021 Peter J. Olver 7. Symmetry in Quantum Mechanics ......... 77 Why is Symmetry Important? ............ 77 Group Representations ............... 79 Lie Algebra Representations ............. 81 Representations of the Orthogonal Group ....... 83 The Hydrogen Atom ................ 91 The Zeeman Effect ................. 96 Addition of Angular Momenta ............ 97 Intensities and Selection Rules ............104 Parity ......................106 Spin .......................107 Systems of Identical Particles ............113 Representation Theory of Finite Groups . .116 Representations of the Symmetric Group . .119 Symmetry Classes of Tensors ............122 Tensor Products ..................126 Plethysm .....................128 Orbital–Spin and Total Angular Momentum Coupling . 128 8. Relativistic Quantum Mechanics ..........132 The Lorentz Group .................133 The Dirac Equation ................136 Clifford Algebras ..................137 Clifford Groups and Spinors .............142 Representations of the Lorentz Group .. .. .. .146 Relativistic Spinors ................149 Lorentz–Invariant Equations ............150 Symmetries of the Dirac Equation ..........151 Relativistic Spin ..................152 Particle in an Electromagnetic Field .. .. .. .152 Solutions of the Dirac Equation ...........153 Spherically Symmetric Potential ...........154 Non-relativistic Limit ...............155 References .....................157 9/9/21 2 c 2021 Peter J. Olver 1. Introduction. These are the lecture notes that I prepared for a graduate level course on the basics of mathematical quantum mechanics that I gave in the academic year 1989–90 at the University of Minnesota. The original notes were typed in Microsoft Word and hence never distributed widely. After 15 years elapsed, I was finally inspired to convert them to TEX. Aside from minor editing, corrections, reordering of some of the material, and updating the references, they are the same as were distributed to the students in the class. The goal was to provide a broad overview of mathematical techniques used in quan- tum mechanics. While applications appear throughout, the emphasis is on the fundamental mathematical tools used in the physical theory. Techniques include Hamiltonian mechan- ics, quantization, operator theory, stationary phase, inverse scattering and solitons, group representation theory, Clifford algebras, and much more. I hope that you, as reader, will find them of use and as enjoyable as when I first prepared them and gave the course. 2. Hamiltonian Mechanics. References: [4], [16], [23], [25], [27], [40]. The fundamental insight of Schr¨odinger’s approach to quantum mechanics was that the quantum mechanical counterparts to the equations of classical mechanics are most easily found by writing the latter in Hamiltonian form. Indeed, Hamilton himself could, in direct analogy with the correspondence between geometric optics and wave optics — the prototype of wave/particle duality — have straightforwardly written down the equa- tions of “wave mechanics”, and thus anticipated quantum mechanics by almost a century. However, the lack of any physical motivation for taking this conceptual leap prevented such a mathematical advance occurring before its time. We thus begin our study with an overview of basic Hamiltonian mechanics. Hamiltonian Systems We consider a system of first order ordinary differential equations on the phase space 2n M = R , with canonical local coordinates (p, q)=(p1,...,pn, q1,...,qn). The system is called Hamiltonian if there is a smooth function H(p, q) such that it can be written in the form dp ∂H dq ∂H i = , i = , i =1,...,n. (2.1) dt − ∂qi dt ∂pi Typically the q’s represent the coordinates of the particles in the system, the p’s the corresponding momenta, and H is the physical energy. Essentially, Hamilton’s equations provide a convenient canonical form for writing the equations of conservative classical mechanics. A good example is the motion of masses in a potential force field. Here the q’s represent the positions of the masses. Let U(t, q) be the potential function, so the corresponding force 9/9/21 3 c 2021 Peter J. Olver field is its negative spatial gradient: F = U = ( ∂U/∂q1,..., ∂U/∂qn). Newton’s equations are −∇ − − 2 d qi ∂U mi 2 = , i =1,...,n, dt − ∂qi th where mi is the i mass. (For three-dimensional motion, n =3m, and the positions and masses are labelled accordingly.) To put these equations in Hamiltonian form, we let pi = mi qi, be the ith momentum, and the Newtonian dot notation is used for time derivatives: q = dq/dt. We define the Hamiltonian function n n 2 1 2 pi H = mi qi + U(t, q) = + U(t, q) 2 2mi iX=1 iX=1 to be the total energy (kinetic + potential). Then Hamilton’s equations (2.1) are dp ∂U dq p i = , i = i , i =1,...,n, dt − ∂qi dt mi and are clearly equivalent to Newton’s equations of motion. The system of differential equations governing the solutions to any (first order) vari- ational problem in one independent variable can always be put into Hamiltonian form. Indeed, consider the problem of minimizing b [q ] = L(t,q, q),dt q(a) = a, q(b) = b, (2.2) I Za where the Lagrangian L is a smooth function of t, qi, and qi = dqi/dt. Sufficiently smooth minima must satisfy the associated Euler-Lagrange equations d ∂L ∂L Ei(L) = + =0, i =1,...,n. (2.3) − dt ∂qi ∂qi To see this, suppose q(t) is a smooth minimizer of (2.2). Then for smooth perturbations h(t) satisfying h(a) = h(b) = 0 so as to preserve the boundary conditions, we must have d b n ∂L ∂L dh 0 = [q + εh] = h (t) + i dt dε I ∂q i ∂q dt ε=0 Za i=1 i i X b n ∂L d ∂L = h (t) dt, ∂q − dt ∂q i a i=1 i i Z X where we integrated the second set of summands by parts and used the boundary condi- tions on h to eliminate the boundary terms. Since the function h(t) is arbitrary, an easy argument (the so-called duBois–Reymond Lemma) shows that the quantities in brackets must vanish, implying (2.3). 9/9/21 4 c 2021 Peter J. Olver In general, we define the momenta via the Legendre transformation ∂L pi = , (2.4) ∂qi and impose the nondegeneracy assumption ∂2L det =0, (2.5) ∂qi∂qj ! 6 which, by the Implicit Function Theorem, allows us to locally solve (2.4) for q as a function of t, p, q: qi = ϕi(t, p, q). (2.6) Define the Hamiltonian function to be n H(t, p, q) = p q L(t,q, q), (2.7) i i − i=1 X where we use (2.6) to replace q. Then the Euler-Lagrange equations (2.3) are equivalent to Hamilton’s equations (2.1). The easiest way to see this is to use differentials: ∂H ∂H ∂H dH = dt + dqi + dpi. ∂t ∂qi ∂pi But, using (2.7), (2.4), ∂L ∂L ∂L ∂L ∂L dH = pidqi + qidpi dt dqi dqi = qidpi dt dqi. − ∂t − ∂qi − ∂qi − ∂t − ∂qi Equating the latter two expressions, we deduce that ∂H ∂L ∂H ∂H ∂L d ∂L = , = qi, = = = pi. ∂t − ∂t ∂pi ∂qi −∂qi −dt ∂qi − from which Hamilton’s equations (2.1) follow immediately. Example 2.1. In particle dynamics, the Lagrangian is the difference of kinetic and potential energy: n 1 L = m q2 U(t, q). 2 i i − i=1 X The Euler-Lagrange equations are just Newton’s laws F = ma: ∂U mi qi + =0, i =1,...,n. (2.8) ∂qi To place this system of second order ordinary differential equations in Hamiltonian form, in view of (2.4), set ∂L pi = = mi qi, ∂qi 9/9/21 5 c 2021 Peter J. Olver which is exactly the ith physical momentum. Thus, the Hamiltonian function (2.7) takes the form n n 1 p2 H(p, q) = m q2 + U(t, q) = i + U(t, q), 2 i i 2m i=1 i=1 i X X and is the total energy. As we have seen, Hamilton’s equations (2.1) are equivalent to Newton’s equations (2.8). Example 2.2. Geometric Optics: According to Fermat’s Principle, the light rays traveling between two points follows the path requiring the least time. If the light is traveling in a medium with index of refraction n(q), which is the ratio of the speed of light in the medium to the speed of light in vacuo, c, then its velocity is ds/dt = c/n. Therefore, taking units in which c = 1, the time to transit between two points A and B is B B t = dt = n(q) ds, ZA ZA where ds denotes the element of arc length on the path travelled by the light. Fermat says that we need to minimize (or at least find stationary values for) this functional. Now ds is not a very convenient parametrization, as the endpoints of the functional are no longer fixed. However, the integral does not depend on the particular parametrization of the path followed by the light ray, so that we can restrict attention to parametrized curves q(t) where the parameter t varies over a fixed interval [a,b].