Using Cold Energy of the LNG in the Integrated Process of Gasification and Electric Energy Production
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Process Technologies and Projects for Biolpg
energies Review Process Technologies and Projects for BioLPG Eric Johnson Atlantic Consulting, 8136 Gattikon, Switzerland; [email protected]; Tel.: +41-44-772-1079 Received: 8 December 2018; Accepted: 9 January 2019; Published: 15 January 2019 Abstract: Liquified petroleum gas (LPG)—currently consumed at some 300 million tonnes per year—consists of propane, butane, or a mixture of the two. Most of the world’s LPG is fossil, but recently, BioLPG has been commercialized as well. This paper reviews all possible synthesis routes to BioLPG: conventional chemical processes, biological processes, advanced chemical processes, and other. Processes are described, and projects are documented as of early 2018. The paper was compiled through an extensive literature review and a series of interviews with participants and stakeholders. Only one process is already commercial: hydrotreatment of bio-oils. Another, fermentation of sugars, has reached demonstration scale. The process with the largest potential for volume is gaseous conversion and synthesis of two feedstocks, cellulosics or organic wastes. In most cases, BioLPG is produced as a byproduct, i.e., a minor output of a multi-product process. BioLPG’s proportion of output varies according to detailed process design: for example, the advanced chemical processes can produce BioLPG at anywhere from 0–10% of output. All these processes and projects will be of interest to researchers, developers and LPG producers/marketers. Keywords: Liquified petroleum gas (LPG); BioLPG; biofuels; process technologies; alternative fuels 1. Introduction Liquified petroleum gas (LPG) is a major fuel for heating and transport, with a current global market of around 300 million tonnes per year. -
Gasification of Woody Biomasses and Forestry Residues
fermentation Article Gasification of Woody Biomasses and Forestry Residues: Simulation, Performance Analysis, and Environmental Impact Sahar Safarian 1,*, Seyed Mohammad Ebrahimi Saryazdi 2, Runar Unnthorsson 1 and Christiaan Richter 1 1 Mechanical Engineering and Computer Science, Faculty of Industrial Engineering, University of Iceland, Hjardarhagi 6, 107 Reykjavik, Iceland; [email protected] (R.U.); [email protected] (C.R.) 2 Department of Energy Systems Engineering, Sharif University of Technologies, Tehran P.O. Box 14597-77611, Iran; [email protected] * Correspondence: [email protected] Abstract: Wood and forestry residues are usually processed as wastes, but they can be recovered to produce electrical and thermal energy through processes of thermochemical conversion of gasification. This study proposes an equilibrium simulation model developed by ASPEN Plus to investigate the performance of 28 woody biomass and forestry residues’ (WB&FR) gasification in a downdraft gasifier linked with a power generation unit. The case study assesses power generation in Iceland from one ton of each feedstock. The results for the WB&FR alternatives show that the net power generated from one ton of input feedstock to the system is in intervals of 0 to 400 kW/ton, that more that 50% of the systems are located in the range of 100 to 200 kW/ton, and that, among them, the gasification system derived by tamarack bark significantly outranks all other systems by producing 363 kW/ton. Moreover, the environmental impact of these systems is assessed based on the impact categories of global warming (GWP), acidification (AP), and eutrophication (EP) potentials and Citation: Safarian, S.; Ebrahimi normalizes the environmental impact. -
Review of Technologies for Gasification of Biomass and Wastes
Review of Technologies for Gasification of Biomass and Wastes Final report NNFCC project 09/008 A project funded by DECC, project managed by NNFCC and conducted by E4Tech June 2009 Review of technology for the gasification of biomass and wastes E4tech, June 2009 Contents 1 Introduction ................................................................................................................... 1 1.1 Background ............................................................................................................................... 1 1.2 Approach ................................................................................................................................... 1 1.3 Introduction to gasification and fuel production ...................................................................... 1 1.4 Introduction to gasifier types .................................................................................................... 3 2 Syngas conversion to liquid fuels .................................................................................... 6 2.1 Introduction .............................................................................................................................. 6 2.2 Fischer-Tropsch synthesis ......................................................................................................... 6 2.3 Methanol synthesis ................................................................................................................... 7 2.4 Mixed alcohols synthesis ......................................................................................................... -
Proposal for Development of Dry Coking/Coal
Development of Coking/Coal Gasification Concept to Use Indiana Coal for the Production of Metallurgical Coke, Liquid Transportation Fuels, Fertilizer, and Bulk Electric Power Phase II Final Report September 30, 2007 Submitted by Robert Kramer, Ph.D. Director, Energy Efficiency and Reliability Center Purdue University Calumet Table of Contents Page Executive Summary ………………………………………………..…………… 3 List of Figures …………………………………………………………………… 5 List of Tables ……………………………………………………………………. 6 Introduction ……………………………………………………………………… 7 Process Description ……………………………………………………………. 11 Importance to Indiana Coal Use ……………………………………………… 36 Relevance to Previous Studies ………………………………………………. 40 Policy, Scientific and Technical Barriers …………………………………….. 49 Conclusion ………………………………………………………………………. 50 Appendix ………………………………………………………………………… 52 2 Executive Summary Coke is a solid carbon fuel and carbon source produced from coal that is used to melt and reduce iron ore. Although coke is an absolutely essential part of iron making and foundry processes, currently there is a shortfall of 5.5 million tons of coke per year in the United States. The shortfall has resulted in increased imports and drastic increases in coke prices and market volatility. For example, coke delivered FOB to a Chinese port in January 2004 was priced at $60/ton, but rose to $420/ton in March 2004 and in September 2004 was $220/ton. This makes clear the likelihood that prices will remain high. This effort that is the subject of this report has considered the suitability of and potential processes for using Indiana coal for the production of coke in a mine mouth or local coking/gasification-liquefaction process. Such processes involve multiple value streams that reduce technical and economic risk. Initial results indicate that it is possible to use blended coal with up to 40% Indiana coal in a non recovery coke oven to produce pyrolysis gas that can be selectively extracted and used for various purposes including the production of electricity and liquid transportation fuels and possibly fertilizer and hydrogen. -
Renewable Propane
Renewable propane Pathways to the prize Eric Johnson Western Propane Gas Association 4 November 2020 A bit of background Headed to Carbon Neutral: 2/3rds of World Economy By 2050 By 2045+ By 2060 By 2050 Facing decarbonisation: you’re not alone! Refiners Gas suppliers Oil majors A new supply chain for refiners Some go completely bio, others partially Today’s r-propane: from vegetable/animal oils/fats Neste’s HVO plant in Rotterdam HVO biopropane (r-propane) capacity in the USA PROJECT OPERATOR kilotonnes Million gal /year /year EXISTING BP Cherry Point BP ? Diamond Green Louisiana Valero: Diamond Green Diesel 10 5.2 Kern Bakersfield Kern ? Marathon N Dakota Tesoro, Marathon (was Andeavor) 2 1 REG Geismar Renewable Energy 1.3 0.7 World Energy California AltAir Fuels, World Energy 7 3.6 PLANNED Diamond Green Texas Valero: Diamond Green Diesel, Darling 90 46.9 HollyFrontier Artesia/Navajo HollyFrontier, Haldor-Topsoe 25 13 Marathon ? Next Renewables Oregon Next Renewable Fuels 80 41.7 Phillips 66 ? Biggest trend: co-processing • Conventional refinery • Modified hydrotreater • Infrastructure exists already Fossil petroleum BP, Kern, Marathon, PREEM, ENI and others…… But there is not enough HVO to meet longer-term demand. LPG production Bio-oil potential What about the NGL industry? Many pathways to renewables…. The seven candidate pathways Gasification-syngas, from biomass Gasification-syngas, from waste Plus ammonia, Pyrolysis from DME, biomass hydrogen etc Glycerine-to-propane Biogas oligomerisation Power-to-X Alcohol to jet/LPG Gasification to syngas, from biomass Cellulose Criterium Finding Process Blast biomass (cellulose/lignin) into CO and H2 (syngas). -
Process Intensification with Integrated Water-Gas-Shift Membrane Reactor Reactor Concept (Left)
INDUSTRIAL TECHNOLOGIES PROGRAM Process Intensification with Integrated Water-Gas-Shift Membrane Reactor Reactor concept (left). Flow diagram (middle): Hydrogen (H2) permeates the membrane where nitrogen (N2) sweeps the gas to Hydrogen-Selective Membranes for High- produce a high-pressure H2/N2 gas stream. Membrane diagram Pressure Hydrogen Separation (right): The H2-selective membrane allows the continuous removal of the H2 produced in the water-gas-shift (WGS) reaction. This allows for the near-complete conversion of carbon monoxide (CO) This project will develop hydrogen-selective membranes for an innovative water-gas-shift reactor that improves gas separation to carbon dioxide (CO2) and for the separation of H2 from CO2. efficiency, enabling reduced energy use and greenhouse gas Image Courtesy of General Electric Company, Western Research Institute, emissions. and Idaho National Laboratory. Benefits for Our Industry and Our Nation Introduction The development of an integrated WGS-MR for hydrogen The goal of process intensification is to reduce the equipment purification and carbon capture will result in fuel flexibility footprint, energy consumption, and environmental impact of as well as environmental, energy, and economic benefits. manufacturing processes. Commercialization of this technology has the potential to achieve the following: One candidate for process intensification is gasification, a common method by which hydrocarbon feedstocks such as coal, • A reduction in energy use during the separation process by biomass, and organic waste are reacted with a controlled amount replacing a conventional WGS reactor and CO2 removal system of oxygen and steam to produce synthesis gas (syngas), which with a WGS-MR and downsized CO2 removal unit is composed primarily of hydrogen (H2) and carbon monoxide (CO). -
A Comparative Exergoeconomic Evaluation of the Synthesis Routes for Methanol Production from Natural Gas
applied sciences Article A Comparative Exergoeconomic Evaluation of the Synthesis Routes for Methanol Production from Natural Gas Timo Blumberg 1,*, Tatiana Morosuk 2 and George Tsatsaronis 2 ID 1 Department of Energy Engineering, Zentralinstitut El Gouna, Technische Universität Berlin, 13355 Berlin, Germany 2 Institute for Energy Engineering, Technische Universität Berlin, 10587 Berlin, Germany; [email protected] (T.M.); [email protected] (G.T.) * Correspondence: [email protected]; Tel.: +49-30-314-23343 Received: 30 October 2017; Accepted: 20 November 2017; Published: 24 November 2017 Abstract: Methanol is one of the most important feedstocks for the chemical, petrochemical, and energy industries. Abundant and widely distributed resources as well as a relative low price level make natural gas the predominant feedstock for methanol production. Indirect synthesis routes via reforming of methane suppress production from bio resources and other renewable alternatives. However, the conventional technology for the conversion of natural gas to methanol is energy intensive and costly in investment and operation. Three design cases with different reforming technologies in conjunction with an isothermal methanol reactor are investigated. Case I is equipped with steam methane reforming for a capacity of 2200 metric tons per day (MTPD). For a higher production capacity, a serial combination of steam reforming and autothermal reforming is used in Case II, while Case III deals with a parallel configuration of CO2 and steam reforming. A sensitivity analysis shows that the syngas composition significantly affects the thermodynamic performance of the plant. The design cases have exergetic efficiencies of 28.2%, 55.6% and 41.0%, respectively. -
The Future of Gasification
STRATEGIC ANALYSIS The Future of Gasification By DeLome Fair coal gasification projects in the U.S. then slowed significantly, President and Chief Executive Officer, with the exception of a few that were far enough along in Synthesis Energy Systems, Inc. development to avoid being cancelled. However, during this time period and on into the early 2010s, China continued to build a large number of coal-to-chemicals projects, beginning first with ammonia, and then moving on to methanol, olefins, asification technology has experienced periods of both and a variety of other products. China’s use of coal gasification high and low growth, driven by energy and chemical technology today is by far the largest of any country. China markets and geopolitical forces, since introduced into G rapidly grew its use of coal gasification technology to feed its commercial-scale operation several decades ago. The first industrialization-driven demand for chemicals. However, as large-scale commercial application of coal gasification was China’s GDP growth has slowed, the world’s largest and most in South Africa in 1955 for the production of coal-to-liquids. consistent market for coal gasification technology has begun During the 1970s development of coal gasification was pro- to slow new builds. pelled in the U.S. by the energy crisis, which created a political climate for the country to be less reliant on foreign oil by converting domestic coal into alternative energy options. Further growth of commercial-scale coal gasification began in “Market forces in high-growth the early 1980s in the U.S., Europe, Japan, and China in the coal-to-chemicals market. -
Hydrogen-Rich Syngas Production Through Synergistic Methane
Research Article Cite This: ACS Sustainable Chem. Eng. XXXX, XXX, XXX−XXX pubs.acs.org/journal/ascecg Hydrogen-Rich Syngas Production through Synergistic Methane- Activated Catalytic Biomass Gasification † † † ‡ † Amoolya Lalsare, Yuxin Wang, Qingyuan Li, Ali Sivri, Roman J. Vukmanovich, ‡ † Cosmin E. Dumitrescu, and Jianli Hu*, † ‡ Department of Chemical and Biomedical Engineering and Department of Mechanical and Aerospace Engineering, West Virginia University, 395 Evansdale Drive, Morgantown, West Virginia 26505, United States *S Supporting Information ABSTRACT: The abundance of natural gas and biomass in the U.S. was the motivation to investigate the effect of adding methane to catalytic nonoxidative high-temperature biomass gasification. The catalyst used in this study was Fe− Mo/ZSM-5. Methane concentration was varied from 5 to 15 vol %, and the reaction was performed at 850 and 950 °C. While biomass gasification without methane on the same catalysts produced ∼60 mol % methane in the total gas yield, methane addition had a strong effect on the biomass gasification, with more than 80 mol % hydrogen in the product gas. This indicates that the reverse steam methane reformation (SMR) reaction is favored in the absence of additional methane in the gas feed as the formation of H2 and CO shifts the equilibrium to the left. Results showed that 5 mol % additional methane in the feed gas allowed for SMR due to formation of steam adsorbates from oxygen in the functional groups of aromatic lignin being liberated on the oxophilic transition metals like Mo and Fe. This oxygen was then available for the SMR reaction with methane to form H2, CO, and CO2. -
Exergy Recovery During Liquefied Natural Gas Regasification
View metadata, citation and similar papers at core.ac.uk brought to you by CORE provided by Infoscience - École polytechnique fédérale de Lausanne 535 A publication of CHEMICAL ENGINEERING TRANSACTIONS VOL. 70, 2018 The Italian Association of Chemical Engineering Online at www.aidic.it/cet Guest Editors: Timothy G. Walmsley, Petar S. Varbanov, Rongxin Su, Jiří J. Klemeš Copyright © 2018, AIDIC Servizi S.r.l. ISBN 978-88-95608-67-9; ISSN 2283-9216 DOI: 10.3303/CET1870090 Exergy Recovery During Liquefied Natural Gas Regasification Using Methane as Working Fluid Francesca Belfiore*, Francesco Baldi, François Maréchal École Polytechnique Fédérale de Lausanne (EPFL Valis Wallis), SCI-STI-FM, Industrial Process and Energy Systems Engineering (IPESE), Rue de l’Industrie 17, Case postale 440, CH-1951 Sion, Switzerland [email protected] The increased concerns about the effect of human activities on the climate have pushed natural gas among the most obvious solutions for the transition to a low-carbon economy. The growing importance and volumes of liquefied natural gas for transportation over long distances come as a consequence of this tendency. The liquefaction of natural gas requires a high amount of energy that can be recovered during the re-gasification phase. In this paper, a novel approach for this purpose is presented, where the main feature is the use of a combination of Rankine and Brayton cycles while retaining natural gas as the only working fluid of the system. The proposed system is optimized for cost and exergy efficiency using a bi-level multi-objective optimization procedur e, where the master level is setup as a nonlinear optimization problem and solved using an evolutionary algorithm , while the slave level as a mixed integer-linear programming problem. -
Natural Gas Annual Questionnaire 2017-2021
NATURAL GAS ANNUAL QUESTIONNAIRE 2017-2021 AND HISTORICAL REVISIONS August 2018 Attached is the annual questionnaire for natural gas which provides for the submission of 2017-2021 data and historical revisions where applicable. Countries reporting to the IEA are requested to complete the questionnaire at the latest by 30 September. Earlier submissions are welcome. Countries reporting to Eurostat are requested to complete the questionnaire by 30 November (Regulation (EC) No 1099/2008 on energy statistics). Earlier submissions are welcome. Please send your questionnaire to: International Energy Agency (IEA/OECD), Energy Data Centre (the IEA will forward the data to the United Nations Economic Commission for Europe in Geneva). European Commission, Eurostat, Energy Statistics (for EU Member States, European Economic Area countries, EU Candidate Countries and Potential Candidates, Energy Community Contracting Parties) United Nations Statistics Division, Energy Statistics Section Transmission details are provided in the “Data communication procedures” section. ANNUAL GAS QUESTIONNAIRE Data communication procedures IEA 31-35, rue de la Fédération, 75739, Paris, Cedex 15, France Please complete data for your country on the Energy Validation Outlet: https://evo.iea.org Alternatively send the completed questionnaire in a CSV or Excel file as an e-mail attachment. to [email protected] For questions regarding the questionnaire, contact [email protected] * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * Eurostat European Commission – Eurostat, Unit E.5: Energy, L-2920 Luxembourg (for EU Member States, European Economic Area countries, EU Candidate Countries and Potential Candidates, Energy Community Contracting Parties) The completed MS Excel questionnaire should be transmitted via the Single Entry Point following the implementing procedures of EDAMIS (Electronic Data Files Administration And Management Information System): https://webgate.ec.europa.eu/edamis/ selecting the electronic data collection ENERGY_NTGAS_A. -
Techno-Economic Analysis of Biofuels Production Based on Gasification Ryan M
Techno-Economic Analysis of Biofuels Production Based on Gasification Ryan M. Swanson, Justinus A. Satrio, and Robert C. Brown Iowa State University Alexandru Platon ConocoPhillips Company David D. Hsu National Renewable Energy Laboratory NREL is a national laboratory of the U.S. Department of Energy, Office of Energy Efficiency & Renewable Energy, operated by the Alliance for Sustainable Energy, LLC. Technical Report NREL/TP-6A20-46587 November 2010 Contract No. DE-AC36-08GO28308 Techno-Economic Analysis of Biofuels Production Based on Gasification Ryan M. Swanson, Justinus A. Satrio, and Robert C. Brown Iowa State University Alexandru Platon ConocoPhillips Company David D. Hsu National Renewable Energy Laboratory Prepared under Task No. BB07.7510 NREL is a national laboratory of the U.S. Department of Energy, Office of Energy Efficiency & Renewable Energy, operated by the Alliance for Sustainable Energy, LLC. National Renewable Energy Laboratory Technical Report 1617 Cole Boulevard NREL/TP-6A20-46587 Golden, Colorado 80401 November 2010 303-275-3000 • www.nrel.gov Contract No. DE-AC36-08GO28308 NOTICE This report was prepared as an account of work sponsored by an agency of the United States government. Neither the United States government nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference herein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise does not necessarily constitute or imply its endorsement, recommendation, or favoring by the United States government or any agency thereof.