Organic Chemistry Section: Summary of Activities
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Novel Non-Aqueous Symmetric Redox Materials for Redox Flow Battery Energy Storage
Novel Non-Aqueous Symmetric Redox Materials for Redox Flow Battery Energy Storage Craig G. Armstrong This dissertation is submitted for the degree of Doctor of Philosophy January 2020 Department of Chemistry The search for ‘electrochemically promiscuous’ redox materials… - Craig Armstrong, 2017 ii Declaration This thesis has not been submitted in support of an application for another degree at this or any other university. It is the result of my own work and includes nothing that is the outcome of work done in collaboration except where specifically indicated. Many of the ideas in this thesis were the product of discussion with my supervisor Dr Kathryn E. Toghill. Dr Ross W. Hogue assisted in the acquisition of experimental results in chapters 4, 6 and 7. He is also credited for co-writing [3], of which Chapter 6 is based, and is a second author on [4]. Excerpts of this thesis have been published in the following academic publications [1–4]. [1] C.G. Armstrong, K.E. Toghill, Cobalt(II) complexes with azole-pyridine type ligands for non-aqueous redox-flow batteries: Tunable electrochemistry via structural modification, J. Power Sources. 349 (2017) 121–129. doi:10.1016/j.jpowsour.2017.03.034. [2] C.G. Armstrong, K.E. Toghill, Stability of molecular radicals in organic non- aqueous redox flow batteries: A mini review, Electrochem. Commun. 91 (2018) 19–24. doi:10.1016/j.elecom.2018.04.017. [3] R. Hogue, C. Armstrong, K. Toghill, Dithiolene Complexes of First Row Transition Metals for Symmetric Non-Aqueous Redox Flow Batteries, ChemSusChem. (2019) 1–11. doi:10.1002/cssc.201901702. -
Rhodizonic Acid on Noble Metals: Surface Reactivity and Coordination Chemistry
University of Nebraska - Lincoln DigitalCommons@University of Nebraska - Lincoln Stephen Ducharme Publications Research Papers in Physics and Astronomy 2013 Rhodizonic Acid on Noble Metals: Surface Reactivity and Coordination Chemistry Donna A. Kunkel University of Nebraska-Lincoln, [email protected] James Hooper State University of New York at Buffalo Scott Simpson State University of New York at Buffalo Sumit Beniwal University of Nebraska–Lincoln, [email protected] Katie L. Morrow California State University, San Bernardino See next page for additional authors Follow this and additional works at: https://digitalcommons.unl.edu/physicsducharme Part of the Atomic, Molecular and Optical Physics Commons, and the Condensed Matter Physics Commons Kunkel, Donna A.; Hooper, James; Simpson, Scott; Beniwal, Sumit; Morrow, Katie L.; Smith, Douglas C.; Cousins, Kimberly; Ducharme, Stephen; Zurek, Eva; and Enders, Axel, "Rhodizonic Acid on Noble Metals: Surface Reactivity and Coordination Chemistry" (2013). Stephen Ducharme Publications. 92. https://digitalcommons.unl.edu/physicsducharme/92 This Article is brought to you for free and open access by the Research Papers in Physics and Astronomy at DigitalCommons@University of Nebraska - Lincoln. It has been accepted for inclusion in Stephen Ducharme Publications by an authorized administrator of DigitalCommons@University of Nebraska - Lincoln. Authors Donna A. Kunkel, James Hooper, Scott Simpson, Sumit Beniwal, Katie L. Morrow, Douglas C. Smith, Kimberly Cousins, Stephen Ducharme, Eva Zurek, and Axel Enders This article is available at DigitalCommons@University of Nebraska - Lincoln: https://digitalcommons.unl.edu/ physicsducharme/92 Published in Journal of Physical Chemistry Letters, 4:20 (2013), pp. 3413–3419; doi: 10.1021/jz4016124 Copyright © 2013 American Chemical Society. -
Organic Chemistry: Radioactive Carbohydrates, Sugars
.ary, N.W. Bldg taken from the library. IDEEC 2 1965 274 ORRGANIC CHEMISTRY: RADIOACTIVE CARBOHYDRATES, SUGARS IN SOLUTION, ALDOL CONDENSATIONS, MOLECULAR STRUCTURE, SYNTHESIS OF SELECTED COMPOUNDS, AIR POLLUTION STUDIES, REFERENCE MATERIALS (ORGANIC) JULY 1964 TO JUNE 1965 THE NATIONAL BUR] The National Bureau of Standards is a principal focal point in the Federal Government for assui maximum application of the physical and engineering sciences to the advancement of te« industry and commerce. Its responsibilities include development and maintenance of the nai - ards of measurement, and the provisions of means for making measurements consistent with standards; determination of physical constants and properties of materials; development of for testing materials, mechanisms, and structures, and making such tests as may be ne> - lady for government agencies; cooperation in the establishment of standard practices for in< tion in codes and specifications; advisory service to government agencies on scientific and t- problems; invention and development of devices to serve special needs of the Government; a«-: e to industry, business, and consumers in the development and acceptance of commercial standi I* and simplified trade practice recommendations; administration of programs in cooperation wit! ted States business groups and standards organizations for the development of intec of practice; and maintenance of a clearinghouse for the collection and di>- m of scii h nical, and engineering information. The scope of the Bureau's activities i? - in the f nfj listing of its four Institutes and their organizational units. Institute for Basic Standards. Applied Mathematics. Electricity. M- ^| * Atomic Physics. Physical Chemistry. Laboratory Astrophysics Radiation Ph\sics I Laboratory:* Radio Standards Physics; Radio Standards Engineering. -
Chapter 1, September, 2004
Preferred IUPAC Names 1 Chapter 1, September, 2004 CHAPTER P-1 NOMENCLATURE OF ORGANIC COMPOUNDS P-10 Introduction P-11 Scope of nomenclature of organic compounds P-12 Preferred, preselected and retained names P-13 Operations in nomenclature P-14 General rules P-15 Types of nomenclature P-16 Name writing P-10 Introduction For nomenclature purposes, a structure containing at least one carbon atom is considered to be an organic compound. The formation of a systematic name for an organic compound requires selection and then naming of a parent structure. This basic name may then be modified by prefixes, infixes, and, in the case of a parent hydride, suffixes, which convey precisely the structural changes required to generate the compound in question from the parent structure. In contrast to such systematic names, there are traditional names which are widely used in industry and academic circles. Examples are acetic acid, benzene and pyridine. Therefore, when they meet the requirements of utility and when they fit into the general pattern of systematic nomenclature, these traditional names are retained. A major new principle is elaborated in these Recommendations. The concept of ‘preferred IUPAC names’ is developed and systematically applied. Up to now, the nomenclature developed and recommended by IUPAC has emphasized the generation of unambiguous names in accord with the historical development of the subject. In 1993, due to the explosion in the circulation of information and the globalization of human activities, it was deemed necessary to have a common language that will prove important in legal situations, with manifestations in patents, export-import regulations, environmental and health and safety information, etc. -
The Synthesis and Characterization of a Novel Single Source Beta-Barium Borate Precursor Barium (18-Crown-6) Dimesitylborinate Travis M
Rochester Institute of Technology RIT Scholar Works Theses Thesis/Dissertation Collections 2007 The synthesis and characterization of a novel single source beta-barium borate precursor barium (18-crown-6) dimesitylborinate Travis M. Scott Follow this and additional works at: http://scholarworks.rit.edu/theses Recommended Citation Scott, Travis M., "The synthesis and characterization of a novel single source beta-barium borate precursor barium (18-crown-6) dimesitylborinate" (2007). Thesis. Rochester Institute of Technology. Accessed from This Thesis is brought to you for free and open access by the Thesis/Dissertation Collections at RIT Scholar Works. It has been accepted for inclusion in Theses by an authorized administrator of RIT Scholar Works. For more information, please contact [email protected]. The Synthesis and Characterization of a Novel Single Source Beta-Barium Borate Precursor Barium (l8-crown-6) Dimesitylborinate Travis M. Scott Thesis Submitted for Partial Fulfillment of the Requirements for the Degree in Master of Science Approved: M. L. IIlingsworth Thesis Advisor T. C. Morrill Department Head Department of Chemistry Rochester Institute of Technology Rochester, New York February 13 , 2007 Thesis/Dissertation Author Permission Statement Title of thesis or dissertation: ike s'jl)tkes I ~ (tAd C~cJe f' r2(A hOI\ 4- C\. N()ve-l&tGt- B ">I'-I \...lJV\ J3(;1."G1.k- ~ C'e..0- v,.I'5<:"":';----- 1)o.!'I v-MC t~ -tNk".J) .... tD) D 1 Me-s, I-~I bc?('-.I t\o.te .-;. .... <./ . Name of author: 11\\ VI ~ 1'1 . _J( crit Degree: ·scMI McI5/-es'C) eIw'.'16tt\j I §5 H/c)Clv:"-'11lst (\~ Program: LhQ/b Istt-u College: _s_""' -"'c_,e..='1-'-'cc,"-"-_J________________________ _ I understand that I must submit a print copy of my thesis or dissertation to the RIT Archives, per current RIT guidelines for the completion of my degree. -
Nomenclature of Organic Chemistry. IUPAC Recommendations and Preferred Names 2013
International Union of Pure and Applied Chemistry Division VIII Chemical Nomenclature and Structure Representation Division Nomenclature of Organic Chemistry. IUPAC Recommendations and Preferred Names 2013. Prepared for publication by Henri A. Favre and Warren H. Powell, Royal Society of Chemistry, ISBN 978-0-85404-182-4 Chapter P-1 GENERAL PRINCIPLES, RULES, AND CONVENTIONS. P-10 Introduction P-11 Scope of nomenclature for organic compounds P-12 Preferred, Preselected, and Retained IUPAC Names P-13 Operations in Nomenclature of Organic Compounds P-14 General Rules P-15 Types of Nomenclature P-16 Name Writing P-10 INTRODUCTION For nomenclature purposes, a structure containing at least one carbon atom is considered to be an organic compound and can be named using the principles of organic nomenclature, such as substitutive or replacement nomenclature, as described in this book. The formation of a systematic name for an organic compound requires first selection and then naming of a parent structure. This basic name may then be modified by prefixes, infixes, and, in the case of a parent hydride, suffixes, which convey precisely the structural changes required to generate the compound in question from the parent structure. In contrast to such systematic names, there are traditional names which are widely used both in industry and academic circles. Examples are acetic acid, benzene, and pyridine. Therefore, when they meet the requirements of utility and when they fit into the general pattern of systematic nomenclature, these traditional names are retained. A major new principle is elaborated in these Recommendations; the concept of ‘preferred IUPAC names’ (PINs) is developed and systematically applied. -
First Draft of the National Chemicals Inventory (Rev. As of March 15 2017) No
First draft of the National Chemicals Inventory (rev. as of March 15 2017) No. CAS Chemical Name (proposal) 1 50-00-0 Formaldehyde 2 50-01-1 Guanidine hydrochloride 3 50-02-2 9-Fluoro-11beta,17,21-trihydroxy-16alpha-methylpregna-1,4-diene-3,20-dione 4 50-03-3 Hydrocortisone acetate 5 50-14-6 Ergocalciferol 6 50-21-5 2-Hydroxypropanoic acid 7 50-23-7 Cortisol 8 50-24-8 Prednisolone 9 50-27-1 Estriol 10 50-32-8 Benzo[a]pyrene 11 50-37-3 Lysergide 12 50-70-4 D-Glucitol 13 50-78-2 Aspirin 14 50-81-7 L-ascorbic acid 15 50-99-7 D-Glucose 16 51-03-6 5-Propan-1-yl-6-(2,5,8-trioxadodecan-1-yl)-1,3-benzodioxole 17 51-21-8 Fluorouracil 18 51-45-6 2-imidazol-4-ylethylamine 19 52-01-7 7alpha-(Acetylsulfanyl)-3-oxo-17alpha-pregn-4-ene-21,17-carbolactone 20 52-28-8 Codeine phosphate 21 52-49-3 Trihexyphenidyl hydrochloride 22 52-51-7 2-Bromo-2-nitropropane-1,3-diol 23 52-76-6 Lynestrenol 24 52-89-1 Cysteine hydrochloride 25 52-90-4 L-cysteine 26 53-36-1 Methylprednisolone 21-acetate 27 53-86-1 Indometacin 28 54-05-7 Chloroquine 29 54-21-7 Sodium salicylate 30 54-31-9 Furosemide 31 54-64-8 Sodium ethanide[2-(sulfide-kappaS)benzoato-kappaO]mercurate(1-) 32 54-86-4 Sodium nicotinate 33 55-63-0 Nitroglycerin 34 55-86-7 Bis(2-chloroethyl)(methyl)ammonium chloride 35 56-04-2 Methylthiouracil 36 56-12-2 4-aminobutyric acid 37 56-17-7 2,2'-dithiodi(ethylammonium) dichloride 38 56-23-5 Tetrachloromethane 39 56-40-6 Glycine 40 56-41-7 L-alanine 41 56-45-1 L-Serine 42 56-53-1 (E)-4,4'-Hex-3-ene-3,4-diyldiphenol 43 56-72-4 Coumaphos 44 56-75-7 Chloramphenicol 45 -
Draft National Chemicals Inventory As of Sep
Draft National Chemicals Inventory as of Sep. 15 No. CAS Chemical Name (proposal) 1 50-00-0 Formaldehyde 2 50-03-3 Hydrocortisone acetate 3 50-14-6 Ergocalciferol 4 50-21-5 2-Hydroxypropanoic acid 5 50-24-8 Prednisolone 6 50-37-3 Lysergide 7 50-70-4 D-Glucitol 8 50-78-2 Aspirin 9 50-81-7 L-ascorbic acid 10 50-99-7 D-Glucose 11 51-03-6 5-Propan-1-yl-6-(2,5,8-trioxadodecan-1-yl)-1,3-benzodioxole 12 51-21-8 Fluorouracil 13 52-01-7 7alpha-(Acetylsulfanyl)-3-oxo-17alpha-pregn-4-ene-21,17-carbolactone 14 52-28-8 Codeine phosphate 15 52-49-3 Trihexyphenidyl hydrochloride 16 52-76-6 Lynestrenol 17 52-89-1 Cysteine hydrochloride 18 52-90-4 L-cysteine 19 53-36-1 Methylprednisolone 21-acetate 20 53-86-1 Indometacin 21 54-05-7 Chloroquine 22 54-21-7 Sodium salicylate 23 54-31-9 Furosemide 24 54-64-8 Sodium ethanide[2-(sulfide-kappaS)benzoato-kappaO]mercurate(1-) 25 55-63-0 Nitroglycerin 26 56-04-2 Methylthiouracil 27 56-23-5 Tetrachloromethane 28 56-40-6 Glycine 29 56-41-7 L-alanine 30 56-45-1 L-Serine 31 56-75-7 Chloramphenicol 32 56-81-5 Glycerol 33 56-84-8 L-Aspartic acid 34 56-86-0 Glutamic acid 35 56-89-3 Cystine 36 57-03-4 1,2,3-Propanetriol, 1-(dihydrogen phosphate) 37 57-09-0 Cetrimonium bromide 38 57-10-3 Palmitic acid 39 57-11-4 Stearic acid 40 57-13-6 Urea 41 57-15-8 Chlorbutanol 42 57-24-9 Strychnine 43 57-48-7 D-Fructose 44 57-50-1 Sucrose 45 57-55-6 Propane-1,2-diol 46 58-08-2 1,3,7-Trimethyl-1H-purine-2,6(3H,7H)-dione 47 58-22-0 Testosterone 48 58-27-5 Menadione 49 58-56-0 3-Hydroxy-4,5-bis(hydroxymethyl)-2-methylpyridin-1-ium chloride 50 58-61-7 Adenosine 1/67 Draft National Chemicals Inventory as of Sep. -
Cyclic Polyhydroxy Ketones. I. Oxidation Products of Hexahydroxybenzene (Benzenehexol) Alexander J
JOURNAL OF RESEARCH of the National Bureau of Standards—A. Physics and Chemistry Vol. 67A, No. 2, March-April 1963 Cyclic Polyhydroxy Ketones. I. Oxidation Products of Hexahydroxybenzene (Benzenehexol) Alexander J. Fatiadi, Horace S. Isbell, and William F. Sager* (December 11, 1962) Reliable procedures are given for the preparation and purification of hexahydroxy benzene (benzenehexol), tetrahydroxy-p-benzoquinone, rhodizonic acid, triquinoyl (cyclo- hexanehexone), croconic acid, and leuconic acid (cyclopentanepentone). Certain derivatives and color tests, as well as infrared and ultraviolet spectra, are reported for their identification. 1. Introduction Hexahydroxybenzene (benzenehexol, I) can be prepared from inositols (cyclohexanehexols) and from On oxidation, cyclohexanehexols (inositols) yield tetrahydroxy-p-benzoquinone (II, obtained by self- keto derivatives which, by successive enolization and condensation of glyoxal in alkaline solution). Oxi elimination reactions, can be transformed to poly- dation of I yields II, which is further oxidized to hydroxybenzenes [1-5].l In progressing from cyclo- rhodizonic acid (III), and this is oxidized to tri hexane derivatives through cyclic olefinic intermedi quinoyl (cyclohexanehexone, IV). Tetrahydroxy- ates to aromatic compounds, reactions and materials ^-benzoquinone and rhodizonic acid are not only are encountered which are eminently suited for the interesting in their own right, but also serve as study of reaction mechanisms and basic concepts of intermediates in the preparation of croconic acid theoretical organic chemistry [6]. (V), a dihydroxy triketone having a five-carbon ring. Oxidation of croconic acid yields leuconic acid (VI). Because these compounds, needed as model substrates in a study of antioxidant and oxygen-carrier properties, were not available in a HO- ,-OH suitable state of purity, the methods reported in the experimental part were developed for their synthesis IIO- Y OH and purification. -
Radioactive Carbohydrates, Sugars in Solution, Aldol Condensations
.ary, N.W. Bldg taken from the library. IDEEC 2 1965 274 ORRGANIC CHEMISTRY: RADIOACTIVE CARBOHYDRATES, SUGARS IN SOLUTION, ALDOL CONDENSATIONS, MOLECULAR STRUCTURE, SYNTHESIS OF SELECTED COMPOUNDS, AIR POLLUTION STUDIES, REFERENCE MATERIALS (ORGANIC) JULY 1964 TO JUNE 1965 THE NATIONAL BUR] The National Bureau of Standards is a principal focal point in the Federal Government for assui maximum application of the physical and engineering sciences to the advancement of te« industry and commerce. Its responsibilities include development and maintenance of the nai - ards of measurement, and the provisions of means for making measurements consistent with standards; determination of physical constants and properties of materials; development of for testing materials, mechanisms, and structures, and making such tests as may be ne> - lady for government agencies; cooperation in the establishment of standard practices for in< tion in codes and specifications; advisory service to government agencies on scientific and t- problems; invention and development of devices to serve special needs of the Government; a«-: e to industry, business, and consumers in the development and acceptance of commercial standi I* and simplified trade practice recommendations; administration of programs in cooperation wit! ted States business groups and standards organizations for the development of intec of practice; and maintenance of a clearinghouse for the collection and di>- m of scii h nical, and engineering information. The scope of the Bureau's activities i? - in the f nfj listing of its four Institutes and their organizational units. Institute for Basic Standards. Applied Mathematics. Electricity. M- ^| * Atomic Physics. Physical Chemistry. Laboratory Astrophysics Radiation Ph\sics I Laboratory:* Radio Standards Physics; Radio Standards Engineering. -
Mechanisms of Heterogeneous Oxidations at Model Aerosol Interfaces by Ozone and Hydroxyl Radicals
University of Kentucky UKnowledge Theses and Dissertations--Chemistry Chemistry 2017 MECHANISMS OF HETEROGENEOUS OXIDATIONS AT MODEL AEROSOL INTERFACES BY OZONE AND HYDROXYL RADICALS Elizabeth A. Pillar-Little University of Kentucky, [email protected] Author ORCID Identifier: https://orcid.org/0000-0003-0444-2300 Digital Object Identifier: https://doi.org/10.13023/ETD.2017.269 Right click to open a feedback form in a new tab to let us know how this document benefits ou.y Recommended Citation Pillar-Little, Elizabeth A., "MECHANISMS OF HETEROGENEOUS OXIDATIONS AT MODEL AEROSOL INTERFACES BY OZONE AND HYDROXYL RADICALS" (2017). Theses and Dissertations--Chemistry. 80. https://uknowledge.uky.edu/chemistry_etds/80 This Doctoral Dissertation is brought to you for free and open access by the Chemistry at UKnowledge. It has been accepted for inclusion in Theses and Dissertations--Chemistry by an authorized administrator of UKnowledge. For more information, please contact [email protected]. STUDENT AGREEMENT: I represent that my thesis or dissertation and abstract are my original work. Proper attribution has been given to all outside sources. I understand that I am solely responsible for obtaining any needed copyright permissions. I have obtained needed written permission statement(s) from the owner(s) of each third-party copyrighted matter to be included in my work, allowing electronic distribution (if such use is not permitted by the fair use doctrine) which will be submitted to UKnowledge as Additional File. I hereby grant to The University of Kentucky and its agents the irrevocable, non-exclusive, and royalty-free license to archive and make accessible my work in whole or in part in all forms of media, now or hereafter known. -
Problems and Solutions in Organic Chemistry Is Primar- of Problems Included in Each Chapter Is Given Here
Problems and Solutions in Organic ChemistryPress Subrata Sen Gupta Formerly, Reader in Chemistry R.P.M.University College, West Bengal Oxford © Oxford University Press. All rights reserved. PSOC_FM.indd 1 12/30/2015 5:30:48 PM 3 Oxford University Press is a department of the University of Oxford. It furthers the University’s objective of excellence in research, scholarship, and education by publishing worldwide. Oxford is a registered trade mark of Oxford University Press in the UK and in certain other countries. Published in India by Oxford University Press YMCA Library Building, 1 Jai Singh Road, New Delhi 110001, India © Oxford University Press 2014 The moral rights of the author/s have been asserted. First published in 2014 All rights reserved. No part of this publication may be reproduced, stored in a retrieval system, or transmitted, in any form or by any means, without the prior permission in writing of Oxford University Press, or as expressly permitted by law, by licence, or under terms agreed with the appropriate reprographics rights organization. Enquiries concerning reproduction outside the scope of the above should be sent to the Rights Department, Oxford University Press, at the address above. You must not circulate this work in any other form and you must impose this same condition on any Pressacquirer. ISBN-13: 978-0-19-945546-1 ISBN-10: 0-19-945546-5 Typeset in Times New RoamnPSMT by Welkyn Software Solutions Pvt Ltd Printed in India by Rajkamal Electric Press, Kundli, Haryana Third-party website addresses mentioned in this book are provided by Oxford University Press in good faith and for information only.