POLYHYDROXYALKANOATE BLENDS NONWOVEN AGRICULTURAL MULCHES in AMBIENT SOIL CONDITIONS Sathiskumar Dharmalingam University of Tennessee - Knoxville, [email protected]

Total Page:16

File Type:pdf, Size:1020Kb

POLYHYDROXYALKANOATE BLENDS NONWOVEN AGRICULTURAL MULCHES in AMBIENT SOIL CONDITIONS Sathiskumar Dharmalingam University of Tennessee - Knoxville, Sdharmal@Utk.Edu University of Tennessee, Knoxville Trace: Tennessee Research and Creative Exchange Doctoral Dissertations Graduate School 5-2014 BIODEGRADATION AND PHOTODEGRADATION OF POLYLACTIC ACID AND POLYLACTIC ACID/ POLYHYDROXYALKANOATE BLENDS NONWOVEN AGRICULTURAL MULCHES IN AMBIENT SOIL CONDITIONS Sathiskumar Dharmalingam University of Tennessee - Knoxville, [email protected] Recommended Citation Dharmalingam, Sathiskumar, "BIODEGRADATION AND PHOTODEGRADATION OF POLYLACTIC ACID AND POLYLACTIC ACID/ POLYHYDROXYALKANOATE BLENDS NONWOVEN AGRICULTURAL MULCHES IN AMBIENT SOIL CONDITIONS. " PhD diss., University of Tennessee, 2014. https://trace.tennessee.edu/utk_graddiss/2760 This Dissertation is brought to you for free and open access by the Graduate School at Trace: Tennessee Research and Creative Exchange. It has been accepted for inclusion in Doctoral Dissertations by an authorized administrator of Trace: Tennessee Research and Creative Exchange. For more information, please contact [email protected]. To the Graduate Council: I am submitting herewith a dissertation written by Sathiskumar Dharmalingam entitled "BIODEGRADATION AND PHOTODEGRADATION OF POLYLACTIC ACID AND POLYLACTIC ACID/ POLYHYDROXYALKANOATE BLENDS NONWOVEN AGRICULTURAL MULCHES IN AMBIENT SOIL CONDITIONS." I have examined the final electronic copy of this dissertation for form and content and recommend that it be accepted in partial fulfillment of the requirements for the degree of Doctor of Philosophy, with a major in Biosystems Engineering. Douglas G. Hayes, Major Professor We have read this dissertation and recommend its acceptance: Arnold M. Saxton, Jennifer M. DeBruyn, Larry C. Wadsworth Accepted for the Council: Dixie L. Thompson Vice Provost and Dean of the Graduate School (Original signatures are on file with official student records.) BIODEGRADATION AND PHOTODEGRADATION OF POLYLACTIC ACID AND POLYLACTIC ACID/ POLYHYDROXYALKANOATE BLENDS NONWOVEN AGRICULTURAL MULCHES IN AMBIENT SOIL CONDITIONS A Dissertation Presented for the Doctor of Philosophy Degree The University of Tennessee, Knoxville Sathiskumar Dharmalingam May 2014 DEDICATION I dedicate my work to my Parents. ii ACKNOWLEDGEMENTS It is a great pleasure to thank everyone who helped me write my dissertation successfully. This dissertation would not have been possible without the help, support, and patience of my principal supervisors, Drs. Douglas G. Hayes and Larry C. Wadsworth, not to mention their advices and unsurpassed knowledge on polymer chemistry and nonwoven materials. I am extremely grateful to one of my Committee members, Dr. Arnold M. Saxton, for offering invaluable suggestions in statistics and helped me in interpreting the data. I owe my sincere thankfulness to the last, but by no means least, of Committee member, Dr. Jennifer M. DeBruyn, for suggestions on statistics and microbiological aspects of this project, not to mention the thought-provoking suggestions on this dissertation. I am truly indebted and thankful to Postdoctoral Research Associate in Michigan State University, Dr. Elodie Hablot. It was particularly kind of her to offer a help in weatherometry and biodegradation experiment. I would also like to extend my thanks to Dr. Ramani Narayan, who let me use his lab for biodegradability apparatus ASTM D5338. Assistance provided by Ms. Rachel N. Dunlap was greatly appreciated. I am obliged to thank Dr. Ran Ye who supported me. Finally, my special thanks to my parents and younger brother for unequivocal moral support and encouragement throughout, as always, for which mere expression of thanks does not suffice. iii ABSTRACT Agricultural mulch films, typically made of polyethylene—derived from fossil fuels— improve crop productivity by controlling weeds and providing a microclimate. Extreme fragmentation of films imposes retrieval and disposal costs, and causes environmental problems during and after their service life. Although mulch films made of biodegradable polymers such as cellulose, (fossil fuel-based) poly (butylene adipate-co-terephthalate) and polybutylene succinate are employed in the field, the fate of biodegradation of “synthetic” additives and their impact on mechanical strength are concerns. Mulches, made of biobased polymers such as poly (lactic acid) (PLA) and PLA/ polyhydroxyalkanoate (PHA) blends, has been developed using nonwoven textile technology to address the poor mechanical properties and/or biodegradability of traditional mulch films. This dissertation focuses upon biodegradation of nonwoven mulches—spunbond (SB) and meltblown (MB)—buried in soil for 30 weeks and after exposure to simulated weathering. Soil moisture, temperature, amendments, the nonwoven processing type, color, and composition (fraction of PLA and PHA) of the mulches were evaluated in soil burial studies. The biodegradation of nonwoven mulches was characterized by the loss of tensile strength, depolymerization via hydrolysis of ester bonds and decrease of glass transition temperature, melting temperature and enthalpy of fusion. At high moisture conditions, SB mulches were recalcitrant to all the soil environmental conditions and amendments, evidenced by marginal depolymerization and insignificant loss of tensile strength. MB mulches, particularly when prepared from PLA/PHA blends, underwent the greatest (~90%) loss of tensile strength among other physico-chemical losses. Although weathered SB mulches did not undergo physico- chemical changes during simulated weathering, the rate and extent of biodegradation test under composting conditions, measured using ASTM D5338, met the compostability standard (ASTM D6400) criteria ( ≥ 60% biodegradation after 90 days). MB mulches experienced the greatest extent of biodegradation ( > 90% after 90 days via ASTM D5338) and therefore are recommended as a “Class II” material in ASTM WK 29802, the standard specification being developed for biodegradability of agricultural plastics in soil. iv TABLE OF CONTENTS CHAPTER 1 INTRODUCTION AND OBJECTIVES ............................................................................ 1 1.1 AGRICULTURAL PLASTIC MULCHES ........................................................ 2 1.2 BIODEGRADABLE MULCHES (BDMs) ........................................................ 3 1.2.1 CURRENT BDMs IN THE MARKET .......................................................... 3 1.2.2 CELLULOSE- BASED MULCHES .............................................................. 4 1.2.3 STARCH-BASED MULCHES ...................................................................... 5 1.2.4 POLY (BUTYLENE ADIPATE-CO-TEREPHTHALATE) or PBAT- BASED MULCHES ....................................................................................... 6 1.3 POLYLACTIC ACID, POLYHYDROXYALKANOATE, AND THEIR BLENDS AS POTENTIALLY VALUABLE FEEDSTOCK FOR BDMs ....... 7 1.3.1 POLYLACTIC ACID (PLA).......................................................................... 7 1.3.2 POLYHYDROXYALKANOATE (PHA) ...................................................... 8 1.3.3 PLA/PHA BLENDS AS BDMs ..................................................................... 10 1.4 OBJECTIVES ..................................................................................................... 10 1.5 ORGANIZATION OF THIS DISSERTATION .............................................. 11 CHAPTER 2 LITERATURE REVIEW ................................................................................................. 13 2.1 INTRODUCTION ............................................................................................ 14 2.2 PROCESSING OF PLA ................................................................................... 14 2.3 BLENDING AND PLASTICIZATION ........................................................... 15 2.4 NONWOVEN TECHNOLOGY....................................................................... 18 2.4.1 SPUNBONDING (SB) PROCESS ............................................................... 20 2.4.2 MELTBLOWING (MB) PROCESS ............................................................ 21 2.4.3 VARIABLES IN SPUNBOND AND MELTBLOWN, AND CHARACTERISTICS OF THE PROCESS ................................................. 23 2.4.4 COMPARISON OF PLA-BASED NONWOVENS TO CONVENTIONAL NONWOVENS ............................................................................................. 25 2.5 BIODEGRADABILITY OF PLASTICS IN SOIL .......................................... 26 2.5.1 INTRODUCTION ........................................................................................ 26 2.5.2 GENERAL MECHANISM OF PLASTIC BIODEGRADATION .............. 27 2.5.3 HYPOTHESIS: DEGRADATION OF PLA MULCHES VIA A THREE STAGE PROCESS ....................................................................................... 29 2.5.4 FORMAL DEFINITIONS OF BIODEGRADABILITY ............................. 31 2.5.5 GENERAL PRINCIPLES OF TESTING THE BIODEGRADABLE PLASTICS .................................................................................................... 32 2.6 COMPOSTABILITY AND COMPOSTING CONDITIONS OF PLASTICS 36 2.7 AMERICAN SOCIETY FOR TESTING AND MATERIALS (ASTM) INTERNATIONAL STANDARDS FOR BIODEGRADABILITY AND COMPOSTABILITY........................................................................................ 37 2.7.1 ASTM STANDARDS FOR BIODEGRADABILITY OF PLASTICS........ 38 v 2.7.2 ASTM TESTING METHODS USED WITHIN THE STANDARD TO DETERMINE THE BIODEGRADABILITY OF PLASTICS IN SOIL ..... 43 2.8 SOIL BURIAL STUDY 1 ...............................................................................
Recommended publications
  • Development of Polylactic Acid-Polyhydroxybutyrate Blends for Packaging Applications
    Development of Polylactic Acid-Polyhydroxybutyrate Blends for Packaging Applications A thesis submitted in fulfilment of the requirements for the degree of Master of Engineering DEHAO KONG B. Eng. School of Engineering College of Science, Engineering and Health RMIT University December 2017 1 DECLARATION I certify that except where due acknowledgement has been made, the work is that of the author alone; the work has not been submitted previously, in whole or in part, to qualify for any other academic award; the content of the thesis is the result of work which has been carried out since the official commencement date of the approved research program; any editorial work, paid or unpaid, carried out by a third party is acknowledged; and, ethics procedures and guidelines have been followed. DEHAO KONG December 21, 2017 2 ACKNOWLEDGEMENTS I sincerely thank my supervisors, Associate Prof. Nhol Kao and Prof. Sati N. Bhattacharya for their supervision and for the opportunity to start and achieve my goal of obtaining a Master. It would not have been possible without your guidance, patience, understanding, and hard work throughout the process. I appreciate their immense knowledge and expertise and their assistance at all levels of the research project. I would also like to thank the staff members of Rheology and Materials Processing Group, especially Mike Allan, Dr. Muthu Pannirselvam and Cameron Crombie for their help in operational training initially and continuous support during the use of instruments throughout the course of the project. I would also like to acknowledge the support and encouragement of my colleagues in the Chemical and Environmental Engineering, School of Engineering as well.
    [Show full text]
  • Aerobic Biodegradation of Polyhydroxybutyrate in Compost
    ENVIRONMENTAL ENGINEERING SCIENCE Volume 28, Number 7, 2011 ª Mary Ann Liebert, Inc. DOI: 10.1089/ees.2010.0208 Aerobic Biodegradation of Polyhydroxybutyrate in Compost Maria T. Gutierrez-Wing,1,2,* Benjamin E. Stevens,3 Chandra S. Theegala,4 Ioan I. Negulescu,5,6 and Kelly A. Rusch1 Departments of 1Civil and Environmental Engineering, 4Biological and Agricultural Engineering, and 5Chemistry; 2Louisiana Sea Grant College Program 116 Elab; 6School of Human Ecology; Louisiana State University, Baton Rouge, Louisiana. 3Sage Environmental Consulting, Baton Rouge, Louisiana. Received: July 6, 2010 Accepted in revised form: February 3, 2011 Abstract Aerobic biodegradation of polyhydroxybutyrate (PHB) was investigated. Mass loss experiments were performed to determine degradation kinetics. Tributyl citrate was blended with some test samples to determine the impact of a natural plasticizer on biodegradation. Effects of biodegradation in the physical, chemical, thermal, and mechanical properties of the materials tested were determined. Plates of different thicknesses (0.24, 1.2, 3.5, and 5.0 mm) were degraded to determine the effect of initial mass:initial surface area ratio on degradation rates. The mass:initial surface area is proportional to the plate thickness. PHB biodegradation rates obtained are dependent on the mass:surface area ratio. Temperature affects the relation of degradation rate to initial mass:initial surface area. PHB in plates up to a thickness of 3.5 mm can degrade completely in compost. Plates with an initial mass:initial surface area ratio of < 67 will degrade in < 4 months. Maximum degradation rates were obtained in plates 3.5 mm thick (1.57 mg cm - 2 d - 1) and the minimum in plates 0.24 mm thick (0.16 mg cm - 2 d - 1).
    [Show full text]
  • (Phb) Production Across Scale: Life Cycle Assessment, Pure Culture Experimentation, and Pathway/Genome Database Development
    UNDERSTANDING METHANOTROPHIC POLYHYDROXYBUTYRATE (PHB) PRODUCTION ACROSS SCALE: LIFE CYCLE ASSESSMENT, PURE CULTURE EXPERIMENTATION, AND PATHWAY/GENOME DATABASE DEVELOPMENT A DISSERTATION SUBMITTED TO THE DEPARTMENT OF CIVIL AND ENVIRONMENTAL ENGINEERING AND THE COMMITTEE ON GRADUATE STUDIES OF STANFORD UNIVERSITY IN PARTIAL FULFILLMENT OF THE REQUIREMENTS FOR THE DEGREE OF DOCTOR OF PHILOSOPHY Katherine Helen Rostkowski June 2012 © 2012 by Katherine Helen Rostkowski. All Rights Reserved. Re-distributed by Stanford University under license with the author. This work is licensed under a Creative Commons Attribution- Noncommercial 3.0 United States License. http://creativecommons.org/licenses/by-nc/3.0/us/ This dissertation is online at: http://purl.stanford.edu/mc120yq3299 ii I certify that I have read this dissertation and that, in my opinion, it is fully adequate in scope and quality as a dissertation for the degree of Doctor of Philosophy. Craig Criddle, Primary Adviser I certify that I have read this dissertation and that, in my opinion, it is fully adequate in scope and quality as a dissertation for the degree of Doctor of Philosophy. Michael Lepech I certify that I have read this dissertation and that, in my opinion, it is fully adequate in scope and quality as a dissertation for the degree of Doctor of Philosophy. Perry McCarty I certify that I have read this dissertation and that, in my opinion, it is fully adequate in scope and quality as a dissertation for the degree of Doctor of Philosophy. Peter Karp Approved for the Stanford University Committee on Graduate Studies. Patricia J. Gumport, Vice Provost Graduate Education This signature page was generated electronically upon submission of this dissertation in electronic format.
    [Show full text]
  • Photodegradation of Photodynamic Therapy Agents in Aqueous Tio2 Suspensions
    Sustainable Development and Planning VI 719 Photodegradation of photodynamic therapy agents in aqueous TiO2 suspensions A. S. Oliveira1,2, C. G. Maia1, P. Brito1, R. Boscencu3, R. Socoteanu4, M. Ilie3 & L. F. V. Ferreira2 1 Centro Interdisciplinar de Investigação e Inovação, C3I, Escola Superior de Tecnologia e Gestão, Instituto Politécnico de Portalegre, Portugal 2Centro de Química-Física Molecular e Instituto de Nanociencias e Nanotecnologia, Instituto Superior Técnico, Universidade Técnica de Lisboa, Portugal 3Faculty of Pharmacy, “Carol Davila” University of Medicine and Pharmacy, Romania 4 “Ilie Murgulescu” Institute, Romanian Academy, Romania Abstract The presence of emergent pollutants in waters and wastewaters are an issue of increasing concern due to the risk they pose to human and environmental health. Cancer Photodynamic Therapy photosensitizers and their metabolites and photodegradation products are pharmaceutical substances that after treatment will be eliminated from the human body and will eventually reach water bodies. Porphyrins are well established PDT sensitizers and cyanine dyes are promising candidates for the same use. In that way it is important to know how those compounds degrade once they reach water bodies and to find efficient treatment methodologies in case they are persistent. In this paper the simulated solar light photodegradation of a porphyrin (Zinctetraphenylporphyrin) and of a cyanine dye (3,3´-diethylindocarbocyanine iodide) in water was investigated, in the absence and in the presence of the most used photocatalyst for semiconductor photocatalysis: Titanium dioxide (TiO2). We observed that the porphyrin (1x10-3M) did not undergo photodegradation in the absence of photocatalyst and that in its presence the photodegradation process was strongly promoted (60% photodegradation reached after 1 hour of irradiation with 0,01g of TiO2).
    [Show full text]
  • Biodegradation of Different Formulations of Polyhydroxybutyrate Films in Soil
    Altaee et al. SpringerPlus (2016) 5:762 DOI 10.1186/s40064-016-2480-2 RESEARCH Open Access Biodegradation of different formulations of polyhydroxybutyrate films in soil Nadia Altaee1,2, Gamal A. El‑Hiti3* , Ayad Fahdil1, Kumar Sudesh4 and Emad Yousif5* *Correspondence: gelhiti@ ksu.edu.sa; emadayousif@ Abstract gmail.com Background: Petroleum polymers contribute to non-degradable waste materials and 3 Cornea Research Chair, Department of Optometry, it would therefore be desirable to produce ecofriendly degradable materials. Biodeg‑ College of Applied Medical radation of polyhydroxybutyrate (PHB) in the presence of oligomer hydrolase and PHB Sciences, King Saud depolymerase gave 3-hydroxybutyric acid which could be oxidized to acetyl acetate. University, P.O. Box 10219, Riyadh 11433, Saudi Arabia Several bacteria and fungi can degrade PHB in the soil. 5 Department of Chemistry, Results: Biodegradation of PHB showed a significant decrease in the molecular College of Science, Al-Nahrain University, weight (Mw), number-average molecular weight (Mn) and the dispersity (Mw/Mn) for Baghdad 64021, Iraq all the film formulations. Nanofibers of PHB and its composites showed faster degrada‑ Full list of author information tion compared to other films and displayed complete degradation after 3 weeks. The is available at the end of the article SEM micrographs showed various surface morphology changes including alterations in appearance of pores, cavity, grooves, incisions, slots and pointers. Such changes were due to the growth of microorganisms that secreted PHB depolymerase enzyme which lead to the biopolymer films degradation. However, PHB nanofibers and its composites films in the presence of TiO2 demonstrated more surface changes with rupture of most nanofibers in which there was a drop in fibres diameter.
    [Show full text]
  • Polyhydroxyalkanoate Biosynthesis by Oxalotrophic Bacteria from High Andean Soil
    Univ. Sci. 23 (1): 35-59, 2018. doi: 10.11144/Javeriana.SC23-1.pbb0 Bogotá ORIGINAL ARTICLE Polyhydroxyalkanoate biosynthesis by oxalotrophic bacteria from high Andean soil Roger David Castillo Arteaga1, *, Edith Mariela Burbano Rosero2, Iván Darío Otero Ramírez3, Juan Camilo Roncallo1, Sandra Patricia Hidalgo Bonilla4 and Pablo Fernández Izquierdo2 Edited by Juan Carlos Salcedo-Reyes Abstract ([email protected]) 1. Universidade de São Paulo, Oxalate is a highly oxidized organic acid anion used as a carbon and energy Instituto de Ciências Biomédicas, Laboratório de Bioprodutos, source by oxalotrophic bacteria. Oxalogenic plants convert atmospheric CO2 Av. Prof. Lineu Prestes, 1374, São Paulo, into oxalic acid and oxalic salts. Oxalate-salt formation acts as a carbon sink in SP, Brasil, CEP 05508-900. terrestrial ecosystems via the oxalate-carbonate pathway (OCP). Oxalotrophic 2. Universidad de Nariño, bacteria might be implicated in other carbon-storage processes, including Departamento de Biología. the synthesis of polyhydroxyalkanoates (PHAs). More recently, a variety Grupo de Investigación de Biotecnología of bacteria from the Andean region of Colombia in Nariño have been Microbiana. Torobajo, Cl 18 - Cra 50. reported for their PHA-producing abilities. These species can degrade oxalate San Juan de Pasto, Colombia. and participate in the oxalate-carbonate pathway. The aim of this study 3. Universidad del Cauca, was to isolate and characterize oxalotrophic bacteria with the capacity to Facultad de Ciencias Agrarias, Grupo de Investigación en accumulate PHA biopolymers. Plants of the genus Oxalis were collected Aprovechamiento de Subproductos and bacteria were isolated from the soil adhering to the roots. The isolated Agroindustriales, Cl 5 No.
    [Show full text]
  • Integrated Photo-Catalytic and Anaerobic Treatment of Industrial Wastewater for Biogas Production
    INTEGRATED PHOTO-CATALYTIC AND ANAEROBIC TREATMENT OF INDUSTRIAL WASTEWATER FOR BIOGAS PRODUCTION Report to the WATER RESEARCH COMMISSION by OCHIENG AOYI, SETH O. APOLLO, JOHN AKACH, KWENA Y. PETE Centre for Renewable Energy and Water, Vaal University of Technology WRC Report No 2105/1/14 ISBN 978-1-4312-0648-3 March 2015 Obtainable from Water Research Commission Private Bag X03 GEZINA, 0031 [email protected] or download from www.wrc.org.za DISCLAIMER This report has been reviewed by the Water Research Commission (WRC) and approved for publication. Approval does not signify that the contents necessarily reflect the views and policies of the WRC, nor does mention of trade names or commercial products constitute endorsement or recommendation for use. © Water Research Commission ii EXECUTIVE SUMMARY _________________________________________________________________________________ Introduction: Anaerobic treatment of high strength wastewater is a widely accepted practice in the industry due to the fact that it converts the organic pollutants into biogas, which is a mixture of methane and carbon dioxide. As a result, this process leads to the reduction in chemical oxygen demand (COD) of industrial wastewater. Moreover, the biogas produced is a source of energy which can be used in industry or for domestic purposes to offset the ever increasing energy demand. Waste removal and methane yield are the key parameters used in the evaluation of an anaerobic digester (AD) performance in the anaerobic digestion process. The performance of ADs is inadequate in removing some biorecalcitrant wastes effectively. For this reason, advanced oxidation processed (AOPs) such photocatalytic degradation as well as integrated techniques have attracted a lot of interest in the recent years.
    [Show full text]
  • Trash Trunk Educator's Guide
    EDUCATOR’S GUIDE A Collection of Lessons, Activities and Supporting Materials A KIT FOR LEARNING ABOUT MARINE DEBRIS TRASH TRUNK A KIT FOR LEARNING ABOUT MARINE DEBRIS EDUCATOR’S GUIDE A collection of lessons, activities and supporting materials Written and assembled by Jill Bartolotta, extension educator, Ohio Sea Grant Ginny Carlton, education outreach specialist, Wisconsin Sea Grant Meaghan Gass, extension educator, Michigan Sea Grant Lyndsey Manzo, education specialist, Ohio Sea Grant Elizabeth White, editor, Wisconsin Sea Grant Reviewed by Sue Bixler, educator, Stone Lab and Ohio Sea Grant Laura Killingsworth, student assistant, Wisconsin Sea Grant Sarah Lowe, Great Lakes regional coordinator, NOAA Marine Debris Program and Freestone Environmental Services, Inc. Anne Moser, senior special librarian and education coordinator, Wisconsin Water Library and Wisconsin Sea Grant ATMOSP ND HE A RI IC C N A A D E M I C N O I S L T A R N A O T I I O T A N N U .S E . C D R E E P M A M RT O MENT OF C September 2020 WISCU-E-20-008 2 TRASH TRUNK EDUCATOR’S GUIDE CONTENTS INTRODUCTION ....................................................................................................... 5 What Is Marine Debris? Where Does it Come From? ........... 30 ABOUT THE LESSONS, ACTIVITIES AND SUMMARIES .......... 6 Top 15 Marine Debris Items ................................................................. 31 TRASH TRUNK LIST OF MATERIALS ....................................................... 7 Talking Trash Grey Debris Deck .................................................
    [Show full text]
  • The Importance of Degradation in the Fate of Selected Organic Compounds in the Environment
    Polish Journal of Environmental Studies Vol. 13, No. 6 (2004), 617-626 Review The Importance of Degradation in the Fate of Selected Organic Compounds in the Environment. Part II. Photodegradation and Biodegradation D. Dąbrowska, A. Kot-Wasik, J. Namieśnik* Department of Analytical Chemistry, Chemical Faculty, Gdańsk University of Technology, 11/12 Narutowicz Str., 80-952 Gdańsk, Poland Received: 12 December 2003 Accepted: 3 June 2004 Abstract Compounds characterized by a slow degradation rate in the environment, i.e. resistant to biodegrada- tion, and photolysis processes, are classified as persistent and have often been considered as potential environmental problems. A more exacting approach recognizes that a compound released to the environ- ment has a tendency to accumulate in one medium more than in others. Hence, partitioning, transport, and transformation rates of any particular compound will differ in each medium. Degradation processes in the dominant medium (where the compound is preferentially accumulated) are expected to have more effect on overall persistence of the measured compound than degradation processes in the other media. Photo- degradation and biodegradation are the degradation processes which can naturaly clean up the environ- ment. Biodegradation is expected to be the major mechanism of loss for most chemicals released into the environment. In this study, photodegradation and biodegradation processes of selected organic pollutants in different media have been reviewed. Keywords: organic pollutants, photodegradation, biodegradation, products of degradation Introduction layers of soil. The intensity of UV radiation depends on many factors, among others, a time of the year, a time of the Persistent organic pollutants (POPs) can cause serious day, latitude, height above the sea level, air density, cloud problems in various environmental compartments due to cover or the size of the ozone hole [1].
    [Show full text]
  • Dell: Upcycling Ocean Plastics Through Supply Chain Innovation
    For the exclusive use of E. Atolagbe, 2019. case Ravi Anupindi June 18, 2018 Andrew Hoffman W91C21 Dell: Upcycling Ocean Plastics Through Supply Chain Innovation Piyush Bhargava, vice president of global operations at Dell, glanced out his office window. It was a sunny and hot late-August day in Round Rock, Texas in 2017. The sunshine reminded him of the beaches in Indonesia and he could not help but wish he were back there where his goals seemed much more straightforward. It was not long ago that he and his team had been in South Asia surveying the availability of ocean plastics waste, meeting with processors, and enjoying more than their fair share of bakso.i Indeed, the trip to Asia had been a huge success. The team, supported by two University of Michigan Tauber Institute for Global Operations1 interns, had not only proven that incorporating ocean plastics into Dell’s packaging for products was feasible, but that doing so could deliver both meaningful cost savings over conventional sources of plastic and a substantial diversion of waste from the oceans. Bhargava had been happy to see the results but he also knew now that the real work was only just beginning: developing and certifying the supply chain that the team recommended and finding ways to utilize meaningful volumes of ocean plastics, through both Dell products and packaging and creative partnerships with other companies. Even by the most conservative estimates, millions of tons of plastic enter the ocean every year. The scope of the environmental crisis was staggering and it would take a concerted effort well beyond Dell’s scale to fully address the problem.
    [Show full text]
  • Photodegradation and Biodegradation of Poly (Lactic) Acid Containing
    materials Article Photodegradation and Biodegradation of Poly(Lactic) Acid Containing Orotic Acid as a Nucleation Agent Jan Salaˇc 1 , Jana Šerá 1, Martin Jurˇca 1, Vincent Verney 2 , Adam A. Marek 3 and Marek Koutný 1,* 1 Department of Environmental Protection Engineering, Faculty of Technology, Tomas Bata University, Vavreˇckova275, 760 01 Zlín, Czech Republic; [email protected] (J.S.); [email protected] (J.Š.); [email protected] (M.J.) 2 Institut de Chimie de Clermont-Ferrand, Université Clermont Auvergne, CNRS, F-63000 Clermont–Ferrand, France; [email protected] 3 Department of Organic Chemical Technology and Petrochemistry, Silesian University of Technology, 44100 Gliwice, Poland; [email protected] * Correspondence: Correspondence: [email protected]; Tel.: +420-576-031-208 Received: 11 January 2019; Accepted: 2 February 2019; Published: 4 February 2019 Abstract: Orotic acid is a natural heterocyclic compound that acts as a nucleation agent in poly(lactic acid) (PLA). PLA materials with increasing orotic acid content were prepared and characterized. It was found that crystallinity of about 28% was reached with 0.3% content of the agent. Further enhancement in the content of the agent did not provoke any additional significant increase of crystallinity. Subsequently, it was investigated whether the orotic acid content affected photodegradation of PLA and, in the next phase, its biodegradation. The results of rheological measurements showed that the compound slightly accelerates photodegradation of the material, which was accompanied by the cleavage of PLA chains. Previous photodegradation was shown to accelerate the subsequent biodegradation by shortening the lag phase of the process, where the explanation is probably in the reduction of the polymer molecular weight during the photodegradation.
    [Show full text]
  • SOURCES, FATE and EFFECTS of MICROPLASTICS in the MARINE ENVIRONMENT: PART 2 of a GLOBAL ASSESSMENT Science for Sustainable Oceans
    93 SOURCES, FATE AND EFFECTS OF MICROPLASTICS IN THE MARINE ENVIRONMENT: PART 2 OF A GLOBAL ASSESSMENT Science for Sustainable Oceans ISSN 1020–4873 REPORTS AND STUDIES AND STUDIES REPORTS AND REPORTS 93 SOURCES, FATE AND EFFECTS OF MICROPLASTICS IN THE MARINE ENVIRONMENT: PART TWO OF A GLOBAL ASSESSMENT A report to inform the Second United Nations Environment Assembly GESAMP Working Group 40 2nd phase REPORTS AND STUDIES REPORTS Published by the INTERNATIONAL MARITIME ORGANIZATION 4 Albert Embankment, London SE1 7SR www.imo.org Printed by Micropress Printers Ltd. ISSN: 1020-4873 Cover photo: Peter Kershaw Notes: GESAMP is an advisory body consisting of specialized experts nominated by the Sponsoring Agencies (IMO, FAO, UNESCO-IOC, UNIDO, WMO, IAEA, UN, UNEP, UNDP). Its principal task is to provide scientific advice concerning the prevention, reduction and control of the degradation of the marine environment to the Sponsoring Agencies. The report contains views expressed or endorsed by members of GESAMP who act in their individual capacities; their views may not necessarily correspond with those of the Sponsoring Agencies. Permission may be granted by any of the Sponsoring Agencies for the report to be wholly or partially reproduced in publication by any individual who is not a staff member of a Sponsoring Agency of GESAMP, provided that the source of the extract and the condition mentioned above are indicated. Information about GESAMP and its reports and studies can be found at: http://gesamp.org ISSN 1020-4873 (GESAMP Reports & Studies Series) Copyright © IMO, FAO, UNESCO-IOC, UNIDO, WMO, IAEA, UN, UNEP, UNDP 2015 For bibliographic purposes this document should be cited as: GESAMP (2016).
    [Show full text]