Minutes of the 613th meeting of the State Level Expert Appraisal Committee (SEAC) held on 19/03/2020 at Committee Room, Gujarat Pollution Control Board, Sector 10A, Gandhinagar.
The 613th meeting of the State Level Expert Appraisal Committee (SEAC) was held on 19th March 2020 at Committee Room, Gujarat Pollution Control Board, Sector 10A, Gandhinagar. Following members attended the meeting:
1. Dr. Dinesh Misra, Chairman, SEAC 2. Shri S. C. Srivastav, Vice Chairman, SEAC 3. Shri V. N. Patel, Member, SEAC 4. Shri. R. J. Shah, Member, SEAC 5. Shri A. K. Muley, Member, SEAC
The regular agenda of Appraisal, Screening & Scoping/ ToR / EC – Reconsideration cases were taken up. This meeting is conducted with reference to MoEF&CC’s OM vide F. No. 19-21/2020- IA.III (Part) dated 11/03/2020 regarding consideration of proects or activities in respect of Bulk drugs (Active Pharmaceutical Ingredients and Bulk Drug intermediates), out of turn, as a preparedness to the outbreak of Novel Coronavirus (COVID-19).
The Committee considered the applications made by project proponents, additional details submitted as required by the SEAC/SEIAA and details furnished in the Form-1, PFR, EIA-EMP reports.
Proposal No. Name and Address of the Unit Remarks
1 SIA/GJ/IND2/28859/2019 M/s. Phorvik Pharma Intermediate Appraisal Block Number 452, Village indrad, Tehsil, Kadi, District- Mehsana. Category of the unit: 5(f) Project status: New
• Project proponent (PP) has submitted online application vide no. SIA/GJ/IND2/28859/2019 on dated 16/03/2020 for obtaining Environmental Clearance. • The SEAC had recommended TOR to SEIAA and SEIAA issued TOR to PP vide their letter dated 31/12/2018. • Project proponent has submitted EIA Report prepared by M/s. Green Circle Inc, Vadodara based on the TOR issued by SEIAA. • Public Hearing of the Project was conducted by Gujarat Pollution Control Board at Project Site of
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M/s. Phorvik Pharma Intermediate, Block Number 452, Village indrad, Tehsil, Kadi, District- Mehsana dated 13/12/2019. • This is new unit proposes for manufacturing of synthetic organic chemical as tabulated below: Sr. Proposed Product Name Cas No. End Use No (MT/Month) 1 Fast Boudreaux G. P. Base 96-96-8 2 Fast Red B Base 97-52-9 45 3 Meta Nitro Para Toluidine 119-32-4 Pharmaceutical 4 2 Nitro 4 Thiocyno Aniline (TCN) 54029-45-7 30 Industries Biss 2 Chloro Ethyl Amine Hydro 5 821-48-7 60 Chloride Dyes and Dyes 6 Fast Scarlet R Base (By Product ) 99-59-2 6.5 Intermediates Total 141.5 • The project falls under Category B of project activity 5(f) as per the schedule of EIA Notification 2006. • The presentation was considred in the meeting dated 18/03/2020 as per the submission by PP via E- mail dated 17/03/2020. • Salient features of the project are as under: Sr. Particulars Details no. Total cost of Proposed Project A Proposed: 3.5 Cr. (Rs. in Crores): ii EMP details (Capital cost & Recurring cost)
Capital Total Installed Operating Maintenance Sr. Cost Recurring Unit Capacity Cost Cost No (Rs.in Cost (KLD) (Lacs/Month) (Lacs/Month) Lacs ) (Lacs/Month) Effluent 1 Treatment 14.7 12.0 1.45 0.10 1.55 Plant 2. APCM --- 6.0 0.40 0.10 0.50 TSDF 3 -- 0.50 0.15 - 0.15 Membership Health & 4 -- 0.60 - - - Safety
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AWH 5 -- - 0.50 - 0.5 Monitoring Green belt 6 Developmen - 2.9 0.50 - 0.5 t Total 22.0 3.0 0.20 3.2
iii CER details (As per MoEF&CC OM dated 01/05/2018) Year wise Budget (Lakhs) No CER-Proposed Planned Identified 2nd 3rd Area 1st Year . Activities Villages Year Year C R C R C R Promoting education through training and 1. 0. 0. awareness Programme in - - - 0 3 3 consultation with regulatory authority Dhanot, Distribution of notebooks Indrad, 0. 0. 0. 1 Education and school bags and Rajpur, - - - 2 3 3 other required item Chandard Scholarship to bright a students 0. 0. 0. (1th & 2th ) and - - - 5 3 3 appreciation pries to primary teacher Conduct medical camp 0. 0. 0. and distributing first aid Indrad - - - 2 3 3 2 Health boxes in schools Ambavpur General awareness a, Rajpur, 0. 0. 0. - - - health program 3 2 2 Distribution of tree guard Indrad, 0. 0. 0. 0. 0. 0. and pots Bileshvarp 2 5 2 2 2 3 Environmen Training and awareness ura, 3 t Programme in school on Rajpur, 0. 0. 0. - - - Environment day and Indrad, 3 2 2 Safety Day in Ambavpur
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consultation with a regulatory authority Indrad Agricultural tour & guide 0. 0. 0. 4 Agriculture Abavpura, - - - to farmers 3 2 2 Dhanot, 3. 0. 2. 0. 2. 0. Total (Year Wise) 0 5 0 2 0 3 7.00 (Capital – 6.0 and Grand Total Recurring – 1.0)
Total Plot area B Proposed: 4199 Sq. m. ( sq. meter) Green belt area Proposed: 1385 Sq. m (33%) ( sq. meter) C Employment generation 10 D Water Source of Water Supply Bore well Water Supply (GIDC Bore well, Surface water, Tanker supply etc...) i CGWA Application has been
Status of permission from the concern authority. submitted and and requisite processing fees has been paid ii Water consumption (KLD)
Sr. Water No Category consumption Remark . in KLD 1 Domestic 1.0 2 Gardening Industrial 4.7 KLD Reuse + 10 Manufacturing process 14.7 3 KLD Fresh Boiler 6.0 Fresh Water Cooling 1.0 Fresh Water Total domestic and gardening 1.0 Total industrial water consumption 21.7 Total Water Requirement 22.7
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Reuse Water 4.7 Total Water Requirement after Reuse 18.0
1) Total water requirement for the project: 22.7 KLD 2) Quantity to be recycle: 4.7 KLD 3) Total fresh water requirement: 18.0 KLD iii Waste water generation (KLD)
Sr No Category Waste water generation KLD
1 Domestic 0.5 2 Industrial
Mfg. Process 14.5 Boiler 0.2 Cooling NIL Total Domestic sewage 0.5 Total Industrial waste water 14.7
Treatment facility within premises with capacity iv [In-house ETP (Primary, Secondary, Tertiary), MEE, Stripper, Spray Dryer, STP etc. Sr No. Description Unit Capacity Collection cum Equalization 1 18 KL 1 Tank 2 Primary Settling 1 5 KL 3 Filter press 1 450 X 450 X 12 Plate 4 Holding tank 1 20 KL
Treatment scheme including segregation at source.
Collection Send to cum primary Filtter press Holding tank Common Equilization settling Facility tank
Note: (In case of CETP discharge) : Management of waste water keeping in view direction under section 18 (1) (b) of the Water (Prevention and Control of Pollution) act, 1974 issued by CPCB regarding compliance of CETP. ➢ Total Waste Water generation 14.7 KLD will be from manufacturing activity and other ancillary operation. These Waste Water will be collected in a tank out of which 4.7 KLD will be reused in the Process. After that the remaining 10 KLD will be sent to Common
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Spray Dryer of Chhatral environmental management system for the Evaporation. Brief note on adequacy of ZLD (In case of Zero Liquid Discharge): ➢ Total Waste Water generation 14.7 KLD will be from manufacturing activity and other ancillary operation. These Waste Water will be collected in a tank out of which 4.7 KLD will be reused in the Process. After that the remaining 10 KLD will be sent to Common Spray Dryer of Chhatral environmental management system for the Evaporation. The generated sewage @ 0.5 KLD will be disposed through soak v Domestic: pit/septic tank. Total Waste Water generation 14.7 KLD will be from manufacturing activity and other ancillary operation. These Waste Water will be Industrial: collected in a tank out of which 4.7 KLD will be reused in the Process. After that the remaining 10 KLD will be sent to Common Spray Dryer of Chhatral environmental management system for the Evaporation. In case of Common facility (CF) like CETP, Common Spray dryer, Common MEE, CHWIF etc. Name of Common facility (CF) (For waste water treatment) • Not Applicable vi Membership of Common facility (CF) (For waste water treatment) ➢ Not Applicable. vii Simplified water balance diagram with reuse / recycle of waste water
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viii Reuse/Recycle details (4.7 KLD) Total reuse 4.7 KLD Source of waste Application area Remarks water for reuse Characteristics of waste with quantity in regarding with quantity in water to be reused (COD, KLD (Where it is feasibility to KLD (From where it BOD, TDS etc.) used) reuse i.e. is coming) The water will pH – 7 -8 reuse with Manufacturing Manufacturing COD – 90 - 95 fresh water to Process 4.7 KLD Process 4.7 KLD TDS – 1500-1700 dilute the impurities.
E Air i Flue gas emission details No. of Boilers/TFH/Furnaces/DG sets etc. with capacities viz. TPH, Kcal/hr, MT/hr, KVA etc. Sr. Stack Stack Consumptio Type of no height in Fuel APCM attached to n Emission . meter
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Dust Natural Gas 140 SCM/hr. Boiler Collector and 1 21 OR OR (2 TPH) Multi cyclone Agro Waste 200 Kg/hr PM Separator SOx Thermic Fluid Dust Natural Gas 35 SCM/hr NOx Heater Collector and 2 21 OR OR (3 Lac. Multi cyclone Agro Waste 100 kg/Hr Kcal/hr) Separator
ii Process gas i.e. Type of pollutant gases (SO2, HCl, NH3, Cl2, NOx etc.) ➢ There will be no any Type of Process gas Emission from the proposed new unit. iii Fugitive emission details with its mitigation measures. ➢ The entire manufacturing activities will be carried out in the closed reactors and regular checking and maintenance of reactors will be carried out to avoid any leakages. ➢ The tank vents will be equipped with either a carbon filter or an oil trap to prevent water vapour from entering the tank as it breathes. ➢ Control of all parameters on a continuous basis will be done by adequate control valves, pressure release valves and safety valves etc. ➢ All the flange joints of the pipe lines will be covered with flange guards. ➢ All the raw materials will be stored in isolated storage area and containers tightly closed. ➢ There will also be provision of adequate ventilation system in process plant and hazardous chemical storage area ➢ A regular preventive maintenance will be planned to replace or rectify all gaskets, joints etc. ➢ The unit will also develop green belt within the factory premises to control the fugitive emission from spreading into surrounding environment. Hazardous wastes F (As per the Hazardous and Other Wastes (Management and Transboundary Movement) Rules 2016. Sr Types of . Categor Proposed Hazardou Sources Disposal N y (MT/Year) s Waste i o Collection, Storage, ETP 1 ETP Plant 35.3 12 Transportation and Waste disposal by sending to
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Active TSDF Site.
Collection, storage, 2 Used Oil Plant Machinery 5.1 0.72 Reused within premises. Collection, storage, Discarded Material Storage Transportation and 3 Container/ 33.1 44 and Handling Dispose to Registered Bags Recycler Collection, storage, Transportation and Dispose to Actual Sodium Fast Boudreaux Users mainly 4 acetate tri G.P. Base, Meta -- 575 manufacture of Sodium hydrate Nitro Pera Toluene Acetate and Sodium Anhydride having permission under rule- 9. Collection, storage, Transportation and Dispose to Actual Fast Boudreaux Users involve in Acetic Acid G.P. Base, Fast manufacturing of 5 (35 % to 26.3 260 Red B Base, Meta Acetanilide or reduction 55 %)) Nitro Pera Toluene process which required acetic acid having permission under rule- 9. 2 Nitro 4 Thiocyno Collection, storage, Spent HCl Aniline (TCN) and Transportation and sell 6 Acid (12% Biss 2 Chloro 26.3 325 out to unit having to 20 %) Ethyl Amine Hydro permission under rule-9 Chloride Collection, storage, Ammoniu 2 Nitro 4 Thiocyno 7 -- 220 Transportation and m Chloride Aniline (TCN) Dispose to Actual
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Users
Fast Boudreaux G.P. Base, Fast Red B Base, Meta Collection, Storage and Nitro Pera reuse within plant after Spent 8 Toluene, 2 Nitro 4 26.1 5650 in house distillation Solvent Thiocyno Aniline, process in same Biss 2 Chloro product. Ethyl Amine Hydro Chloride Collection, storage and Solvent 9 Distillation Unit 26.1 120 disposal by sending to Residue Co processing
We will obtained after Membership details of TSDF, CHWIF etc. ii getting NOC from (For HW management) GPCB. iii Details of Non-Hazardous waste & its disposal(MSW and others) Not Applicable. G Solvent management, VOC emissions etc. Types of solvents, Details of Solvent recovery, % recovery, reuse of recovered Solvents etc. i (Details in Table Format). Recover % Solvent B.P °C V.P Input kg y kg Recovery MDC 39.0 350 mbar @ 20 4166 4160
°C 99.86 Methanol 64.7 128 hPa (20 °C) 3430 3425 99.85 EDC 81.0 65mmHg @29 °C 2976 2970 99.80
ii VOC emission sources and its mitigation measures ➢ Sources of fugitive emissions include storage of chemicals, solvents storage, loading and unloading section, raw material handling and, hazardous waste storage area Measures: ➢ The fugitive emissions in terms of handling losses will get reduced by proper storage
and handling. ➢ Hazardous chemicals will be stored as per standard criteria. ➢ Periodically monitoring will be carried out as per the post project monitoring plan. ➢ Proper ventilation in storage & production area shall be ensured
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➢ All materials must be stored in suitable packing to prevent contamination of air ➢ Enclosed system & efficient procedures for materials charging shall be ensured. ➢ Procedures for start-up shut down, operation & maintenance procedures shall be established & maintained. ➢ The coverage of greenbelt around the plant also acts as natural barrier to stop carrying of dust along with the wind current. ➢ Details regarding storage of Hazardous chemicals Name of major Hazardous Storage details Remarks chemicals Acetic Anhydride Ammonium Thio Cyanate Caustic Flakes Di Ethanol Amine Drum/Barrel storage HNO3 (98 %) Ortho Anisidine Para Toluidine H Para Anisidine Sr. Storage Capacity Name of Chemical No. in MT Methylene dichloride 1 5 KL Storage tanks (MDC) 2 Methanol 5 KL 3 Ethylene Dichloride (EDC) 5 KL 4 Thionyle Chloride 05 MT
Tonner Chlorine Gas 2 Cylinder
➢ Applicability of PESO : Not Applicable • During the meeting dated 19/03/2020, the project was appraised based on the information furnished in the EIA Report, various issues raised during public hearing and details submitted by PP. • The baseline environmental quality has been assessed for various components of the environment viz. air, noise, water, biological and socioeconomic aspect. The baseline environmental study has been conducted for the study area of 10 km radial distance from project site for the January 2019 to March 2019. Ambient Air Quality monitoring was carried out for PM2.5, PM10, SO2, NOx, & VOC at eight locations, including the project site. Values conform to the prescribed standards for Ambient Air Quality. The incremental Ground Level Concentration (GLC) has been computed using AERMOD. The resultant concentrations are within the NAAQS. 613th meeting of SEAC-Gujarat, dated 19.03.2020 Page 11 of 217
• Risk assessment including prediction of the worst-case scenario and maximum credible accident scenarios has been carried out. The detail proposed safeguard measures including On-Site / Off-Site Emergency Plan has been covered in the RA report. • Committee deliberated on the Minutes of the Public Hearing dated 13/12/2019 along with the representation made by the Public and observed that Project Proponent has not submitted Point wise Compliance of the Public Hearing and asked them to address the same along with its status as on date. • Committee noted that proposal is new in Village: Indrad. Source of water is Bore well. Committee deliberated on product profile submitted by PP and asked to readdress the same in-line with Hazardous Waste Rules – 2016. PP submitted that effluent generated from process and boiler blow down will be treated in in-house primary ETP and after treatment partly effluent will be reused/recycle while partly it will be sent to Common Spray Dryer of Chhatral environmental management system for the Evaporation for final treatment and disposal. Committee noted that PP has not submitted membership certificate as per direction given by GPCB to common facility dated 8th January, 2020. Committee noted that PP has not submitted the characteristic of effluent that is going to be treated and disposed into common facility. PP submitted that they have proposed one steam boiler and one TFH. Fuel used will be Natural Gas/ Agro Waste. Committee noted that PP has not submitted LDAR along with its mitigation measures properly. Committee noted PP has not submitted Hazardous Waste as per HWR – 2016. • After detailed discussion, Committee unanimously decided to call the project proponent for presentation only after satisfactory submission of the following details. 1. Revised Product Profile in-line with consideration of Hazardous Waste Rules – 2016. 2. Manufacturing Process of Fast Scarlet R Base (By Product) along with Material & Mass Balance with Justification as to why it should be considered as By-Product instead of Hazardous Waste as per HWR – 2016. 3. Compliance of issues raised during Public Hearing in Tabular Form and current status of compliance. 4. Characteristic of effluent generated from Manufacturing Process and its fesibility for reuse/recycle after Primary treatment along with Justification as to why only part of the effluent is getting resued/recycle and rest is sent to Common Facility. 5. Membership Certificate from Common Facility (mentioning total capacity, consented quantity, occupied capacity and spare capacity and norms of acceptance of effluent from member units) in-line with the direction given by GPCB vide Letter No. GPCB/P-1/8-G (5)/550706 dated 08/01/2020. 6. Leak Detection and Repairing Programme (LDAR) for all the volatile organic solvent proposed for use in-house with detailed chemical properties including vapor pressure.
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LDAR shall endeavor prevention of losses of solvents to the best minimum extent. 7. Revised Need based CER as per Compliance of MoEF&CC OM dated 01/05/2018 and EMP with Fixed Capital Cost and Recurring Cost. 8. Adendum to EIA Report incorporating all the above mentioned changes. 2 SIA/GJ/IND2/52055/2019 M/s. Oliver Pharmaceuticals Appraisal Plot No. D-2/CH/143, Dahej II, Dahej Industrial Estate, Taluka: Vagra, Dist: Bharuch, Gujarat. Category of the unit: 5(f) Project status: New
• Project proponent (PP) has submitted online application vide no. SIA/GJ/IND2/52055/2019 on dated 16/03/2020 for obtaining Environmental Clearance. • The SEAC had recommended TOR to SEIAA and SEIAA issued TOR to PP vide their letter dated 23/08/2019. • Project proponent has submitted EIA Report prepared by M/s. Aqua-Air Environmental Engineers Pvt. Ltd, Surat based on the TOR issued by SEIAA. • This is new unit proposes for manufacturing of synthetic organic chemical as tabulated below: SR. PRODUCTS CAS NO. PROPOSE End Use of the product NO D QUANTITY (MT/MONT H) (I) ACTIVE PHARMACEUTICAL INGREDIENT (API) Cyclo-oxygenase inhibitor;
1 Ibuprofen 15687-27-1 analgesic; anti-inflammatory. Cyclo-oxygenase inhibitor;
2 Aspirin 50-78-2 50 analgesic; anti-inflammatory. Cyclo-oxygenase inhibitor;
3 Diclofenac Sodium 15307-86-5 analgesic; anti-inflammatory. 1051375-16-
4 Dolutegravir 6 to treat HIV/AIDS (Antivirus) Purine nucleoside analogue;
5 Acyclovir 59277-89-3 50 antiviral (herpesviruses). Purine nucleoside analogue;
6 Valacyclovir 124832-27-5 antiviral (herpesviruses).
7 Tenofovir 147127-20-6 to treat HIV/AIDS (Antivirus)
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8 Efavirenz 154598-52-4 to treat HIV/AIDS (Antivirus)
9 Levetiracetam 102767-28-2 Antiepileptic
10 Lamivudine 134678-17-4 to treat HIV/AIDS (Antivirus)
11 Guifenesin 93-14-1 Expectorant
12 Gabapentin 60142-96-3 Antiepileptic Anti histamine (anti allergic)
13 Chlorpheniramine Maleate 113-92-8 drug an antibiotic and antiprotozoal
14 Metronidazole 443-48-1 medication Cyclo-oxygenase inhibitor;
15 Naproxen sodium 26159-34-2 analgesic; anti-inflammatory. as antibiotic primarily used to
16 4-Aminosalicylic acid 65-49-6 treat tuberculosis Cyclo-oxygenase inhibitor;
17 Ibuprofen Sodium 31121-93-4 analgesic; anti-inflammatory. Local anaesthetic; Class I
18 Lidocaine hydrochloride 6108-05-0 antiarrhythmic
19 Tranexamic Acid 1197-18-8 Antifibrinolytic agent
20 Phenyramidol hydrochloride 326-43-2 Muscle relaxant 30 Cyclo-oxygenase inhibitor;
21 Ibuprofen Lysinate 57469-77-9 analgesic; anti-inflammatory. To treat inflammatory bowel
22 Mesalmine/Mesalazine 89-57-6 disease, anti-inflammatory. Cyclo-oxygenase inhibitor;
23 Aceclofenac 89796-99-6 analgesic; anti-inflammatory. used for the treatment of
24 Albendazole 54965-21-8 parasitic worm infestations
25 Ambroxol hydrochloride 23828-92-4 Mucolytic expectorant Monoamine reuptake inhibitor;
26 Trazodone 19794-93-5 antidepressant.
27 Pregabalin 148553-50-8 Antiepileptic Proton pump inhibitor; treatment
28 Omeprazole 73590-58-6 of peptic ulcer disease. Proton pump inhibitor; treatment
29 Esomeprazole 119141-88-7 of peptic ulcer disease.
30 Pantoprazole sodium 138786-67-1 Proton pump inhibitor; treatment
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of peptic ulcer disease. Proton pump inhibitor; treatment
31 Rabeprazole 117976-90-6 of peptic ulcer disease. Proton pump inhibitor; treatment
32 Lansoprazole 103577-45-3 of peptic ulcer disease.
33 Fluconazole 86386-73-4 Antifungal 20 Cyclo-oxygenase inhibitor;
34 Dexibuprofen 51146-56-6 analgesic; anti-inflammatory. Angiotensin II (AT1) receptor
35 Telmisartan 144701-48-4 antagonist; treatment of Hypertension Angiotensin II (AT1) receptor
36 Losartan 114798-26-4 antagonist; treatment of Hypertension Angiotensin II (AT1) receptor
37 Valsartan 137862-53-4 antagonist; treatment of Hypertension Angiotensin II (AT1) receptor
38 Olmisartan 144689-63-4 antagonist; treatment of Hypertension Angiotensin II (AT1) receptor
39 Candesartan cilexetil 145040-37-5 antagonist; treatment of Hypertension Angiotensin II (AT1) receptor
40 Irbesartan 138402-11-6 antagonist; treatment of Hypertension Smooth muscle relaxant;
41 Mebeverin hydrochloride 2753-45-9 antispasmodic Calcium channel blocker;
42 Verapamil hydrochloride 152-11-4 treatment of Hypertension Antispasmodic drug; used to
43 Drotaverinhydroch;loride 985-12-6 enhance cervical dilation during birth Angiotensin converting enzyme
44 Lisinopril 83915-83-7 inhibitor; treatment of Hypertension
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Angiotensin converting enzyme
45 Ramipril 87333-19-5 inhibitor; treatment of Hypertension HMG Co-A reductase inhibitor;
46 Atorvastatin calcium 134523-03-8 lipid-regulating drug HMG Co-A reductase inhibitor;
47 Rosuvastatin calcium 147098-20-2 lipid-regulating drug Inhibition of 5HT and
48 Venlafaxin hydrochloride 99300-78-4 noradrenaline reuptake; antidepressant Alpha-adrenoceptor agonist;
49 Phenylephrin hydrochloride 61-76-7 nasal decongestant
50 Lamotrigine 84057-84-1 Antiepileptic Alpha-and beta-adrenoceptor
51 Labetalol hydrochloride 32780-64-6 antagonist; treatment of Hypertension Histamine H1 receptor
52 Cetrizine hydrochloride 83881-52-1 antagonist; antihistamine. Histamine H1 receptor
53 Levocetrizine hydrochloride 130018-77-8 antagonist; antihistamine.
54 Vitamin D3 67-97-0 Vitamin D3 analogue
55 Terbinafine hydrochloride 78628-80-5 Antifungal Vasodilator; treatment of
56 Minoxidil 38304-91-5 hypertension; male pattern baldness. Selective serotonin reuptake
57 Sertaline hydrochloride 79559-97-0 inhibitor; antidepressant. Reversal of neuromuscular
58 Sugammadex sodium 343306-79-6 blockade
59 Apixaban 503612-47-3 Anticoagula t Treatment of rheumatoid arthritis
60 Tofacitinib 477600-75-2 and ulcerative colitis. dipeptidyl peptidase-4 inhibitors; 1572583-29-
61 Teneligliptin HBr treatment of type 2 diabetes 9 mellitus
62 Lidocaine base 137-58-6 Local anaesthetic; Class I
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antiarrhythmic
63 Benzocaine 94-09-7 Local anaesthetic
64 Procaine 59-46-1 Local anaesthetic
65 Articaine 23964-57-0 Local anaesthetic
66 Prilocaine hydrochloride 1786-81-8 Local anaesthetic
67 Prilocaine base 721-50-6 Local anaesthetic
68 Bupivacaine hydrochloride 18010-40-7 Local anaesthetic
69 Ropivacaine hydrochloride 132112-35-7 Local anaesthetic
70 Tetracaine hydrochloride 136-47-0 Local anaesthetic
71 Cinchocaine hydrochloride 61-12-1 Local anaesthetic Cyclo-oxygenase inhibitor;
72 Meloxicam 71125-38-7 analgesic; anti-inflammatory. Cyclo-oxygenase inhibitor;
73 Piroxicam 36322-90-4 analgesic; anti-inflammatory. Cyclo-oxygenase inhibitor;
74 Lornoxicam 70374-39-9 analgesic; anti-inflammatory. Cyclo-oxygenase inhibitor;
75 Piroxicam Betacyclodextrin 96684-39-8 analgesic; anti-inflammatory. 1307301-38-
76 Sodium Picosulphate 7 Stimulant laxative
77 Bisacodyl 603-50-9 Stimulant laxative
78 Alendronate Sodium 121268-17-5 Treatmet of osteoporosis Leukotriene CysLT1 receptor
79 Montelukast Sodium 151767-02-1 antagonist; treatment of asthma. TOTAL OF API 150 (II) ACTIVE PHARMACEUTICAL INGREDIENT (API) INTERMEDIATES
80 Isobutyl acetophenone 38861-78-8 Ibuprofen 81 1-(2,6-Dichlorophenyl)-2- 15307-86-05 Diclofenac
indolinone 82 Try amino pyrimidine 35011-47-3 Guanine
83 Guanine 73-40-5 Valacyclovir sulphate
84 Adenine 73-24-5 Tenofovir 50 85 (2S)-2-aminobutanamide 7682-20-4 Levetiracetam
Hydrochloride 86 1,1-Cyclohexane diacetic 4355-11-7 Gabapentin
acid 87 3,4-Dimethoxybenzoic 93-07-2 Mebeverin
acid(Veratric Acid)
88 Para Amino Benzoic Acid 150-13-0 Benzocaine
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1-(2,2-Dimethoxyethyl)-1,4- 1335210-23- 89 dihydro-3-methoxy-4-oxo- Dolutegravir 5 2,5-pyridinedicarboxylic acid
(S)2-methyl-1-(2-Amino ester -5- 90 209414-27-7 Efavirenz chlorophenyl)-1-
(S)(trifluoromethyl)-5-Chloro-alpha-3--
(cyclopropylacetenyl)cyclopropyl-2-propyn--12--ol[((4 - 91 173676-60-3 Efavirenz methoxyphenyl)methyl)amin 25 o]-alpha-(trifluoro
(1R,2S,5R)methyl)benzenemethanol-Menthyl- 92 (2R,5S)-5-(4-amino-2-oxo- 147027-10-9 Lamivudine 2H-pyrimidin-1-yl)- 2-Amino-3,5- 93 [1,3]oxathiolane-2- 50910-55-9 Ambroxol
dibromobenzaldehyde
carboxylic acid 94 Trans-4-Aminocyclohexanol 27489-62-9 Ambroxol 95 (3,4- 93-17-4 Verapamil
96 Dimethoxyphenyl)acetonitrilDenatonium Benzoate 3734-33-6 Bitterant 97 4-(Aminomethyl) Benzoic 56-91-7 Tranexamic Acid 1e- (3-Chlorophenyl)-4-(3- Acid 98 52605-52-4 Trazadone chloropropyl)piperazine
hydrochloride 99 (R)-(-)-3-(2-Amino-2-oxo 181289-33-8 Pregabaline ethyl)-5-methyl hexanoic 10 2-Chloromethyl-4-methoxy- 86604-75-3 Omeprazole acid 0 3,5-dimethylpyridine 10 5-Methoxy-2-Mercapto 37052-78-1 Omeprazole hydrochloride
1 Benzimidazole 10 5-Difluromethoxy-2- 97963-62-7 Pantoprazole
2 Mercapto Benzimidazole 5-Difluoromethoxy-2-{[(3,4- 10 10 dimethoxy-2- 102625-64-9 Pantoprazole 3 pyridinyl)methyl]thio}-1H-
10 2benzimidazole-Chloromethyl 3,4- 72830-09-2 Pantoprazole
4 Dimethoxy Pyridine HCl
10 2-Mercapto Benzimidazole 583-39-1 Rabeprazole 10 2-Chloromethoxy-4-(3- 5 153259-31-5 Rabeprazole 6 Methoxy Propoxy)-3- 2-[[[4-(3-Methoxy Propoxy)- 10 Methyl Pyridine 117977-21-6 Rabeprazole 7 3-Methyl Pyridine-2-yl] Methyl] Thio]-1H-
Benzimidazole
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[1,1’-Biphenyl]-2- 10 carbonitrile,4’-[(1,4’-dimethyl 144702-27-2 Telmisartan 8 -2’-propyl [2,6”-bi-1H- 10 Methylbenzimidazole 4'-bromomethyl ] -1’-yl) 114772-38-2 Telmisartan
9 biphenylmethyl ] -–2 -(1,1carboxylate-biphenyl) -2-
11 carbonitrile2-n-propyl-4 -methyl-6-(1- 152628-02-9 Telmisartan 0 methylbenzimidazole-2-
2nyl)benzimidazole-Butyl-4-chloro -[1-(2'- 11 cyanobiphenyl-4-yl) methyl]- 114772-55-3 Losartan 1
5-(hydroxymethyl)-imidazole 11 5-(4'-Bromomethyl-1, 1'- 124750-51-2 Losartan 2 biphenyl-2-yl)-1- 11 2triphenylmethyl-Butyl 4-Chloro-1H 5--Formyltetrazole 83857-96-9 Losartan
(TTBB) 3 Imidazole(BCFI) 4-(1-Hydroxy-1- 11 methylethyl)-2-propyl-1-[[2'- 144690-33-5 Olmesartan 4 [(triphenylmethyl)-1H- tetrazol-5-yl][1,1'-biphenyl]- 45-yl]methyl]Methoxy –-1H 2-oxo-imidazole-1,3- -5- dioxol - 4 - yl ) methyl - 4 - 11 carboxylic acid ethyl ester) (1-hydroxy -1 - methylethyl - 144690-92-6 Olmesartan 5 2 propyl-1- (2 –(2- triphenylmethyl ) -2H – 11 tetrazoleMethyl 1- [(2'-5 –-cyanobiphenyl yl ) biphenyl - - 139481-44-0 Candesartan 6 4-ylyl)methyl] ) methyl- 2) --ethoxy1H-imidazole-1H-
benzimidazole-7- 11 Ethyl– 5 – 2carboxylate-ethoxy-1-[(2'- 139481-41-7 Candesartan carboxylate 7 cyanobiphenyl-4-yl)methyl]- 1H-benzimidazole-7- 11 N-[(2'-Cyanobiphenyl-4- 482577-59-3 Valsartan carboxylate 8 methyl)-(L)-Valine methyl
ester Hydrochloride 11 4'-[(2-Butyl-4-oxo-1,3-
138401-24-8 Irbesartan 9 diazaspiro[4.4]non-1-en-3- tertyl)methyl]biphenyl-Butyl (4R,6R)--22--[[[6-(2-
carbonitrile 12 4-fluorophenyl)-5-isopropyl- 125971-95-1 Atorvastatin 0 3-phenyl-4- (phenylcarbamoyl)pyrrol-1- yl]ethyl]-2,2-dimethyl-1,3-
th
dioxan-4-yl]acetate 613 meeting of SEAC-Gujarat, dated 19.03.2020 Page 19 of 217
(4R,6R)-tert-Butyl-6-(2- 12 aminoethyl)-2,2-dimethyl- 125995-13-3 Atorvastatin 1
1,3-dioxane-4-acetate Methyl 4-(4-fluorophenyl)-6- 12 isopropyl-2-[(N-methyl-N- 289042-11-1 Rosuvastatine 2 methylsulfonyl)amino]pyrimi
tertdine-Butyl-5-carboxylate 6-[(1E)-2- [4-(4-
12 fluorophenyl)-6-(1- 289042-12-2 Rosuvastatine 3 methylethyl)-2- [methyl(methylsulfonyl)amin o]-5-pyrimidinyl]ethenyl]-2,2- 12 1-[Cyano-(p-methoxy dimethyl-1,3-dioxane-4- 93413-76-4 Venlafaxine
4 phenyl)methyl]cyclohexanol 12 1acetate-[2-Amino -1-(4- 149289-31-6 Venlafaxine 5 methoxyphenyl)
12 2,3-Dichlorobenzoylcyanide 77668-42-9 Lamotrigine
ethyl]cyclohexanol 126 5-Chloroacetylsalicylamide 33254-88-5 Labetalol 127 1-(4-Chloro benzhydryl) 303-26-4 Cetrizine
8 piperazine
12 2-Amino, 5-methyl thiazole 7305-71-7 Meloxicam 139 4-Hydroxy, 2-methyl, 2h,1,2- 118854-48-1 Meloxicam 0 benzothiazine carboxylic acid isopropyl ester-1,1- 13 4-Hydroxy, 2-methyl, 2h,1,2- 35511-15-0 Meloxicam dioxide 1 benzothiazine carboxylic acid methyl ester-1,1- 13 Chloro acetyl Xylidine 1131-01-7 Lidocaine
2dioxide-(2-(3- (S)-(3-(2-(7-Chloro- 132 2-quinolinyl)-ethenyl)phenyl- 142569-70-8 Montelukast 3 3-
13 1methanesulphonyloxypropyl-(Mercaptomethyl)- 162515-68-6 Montelukast
4 cyclopropane)pehenyl)-2-propanol acetic acid
13 Denatonium Saccharate 90823-38-4 Bitterant 135 3-Morpholino-1-(4-(2- 545445-44-1 Apixaban 6 oxopiperidin-1-yl)5,6-
13 zdihydropyridin-Ethyl-2-chloro-2(1h)-2-(2--one(4- 27143-07-3 Apixaban 7 methoxyphenyl)hydrazono)ace 5
13 tate4-Chloro -7-tosyl-7h- 479633-63-1 Tofacitanib
8 pyrrolo[2,3-d]pyrimidine Bis (3R, 4R) - (1- benzyl - 4 13 methyl - pipeidine - 3yl) 477600-70-7 Tofacitanib 9 methylamine di - toluoyl - L - tartaric acid 613th meeting of SEAC-Gujarat, dated 19.03.2020 Page 20 of 217
14 [(2S)-1-tert-butoxycarbonyl- 401564-36-1 Teneligliptin 0 4- oxo-2- 14 1pyrrolidinylcarbonyl]-(3-methyl-1-phenyl-1,3-5-- 401566-79-8 Teneligliptin
thiazolidine 1 pyrazolyl)- piperazine) 14 6-Chloro 4-Hydroxy 2- 70415-50-8 Lornoxicam 2 Methyl 2H- thieno[2,3,e][1,2]thiazine-3- 14 4,4’-(2- 603-41-8 Bisacodyl 3 Pyridinylmethylene)bisphenCarboxylate 1,1-dioxide 14 3-Amino-4-methyl-2- ol 85006-31-1 Articaine 4 thiophenecarboxylic acid me
thyl ester
14 Basic cromium sulphate 15244-38-9 15 Tanning of leather 5 TOTAL OF API INTERMEDIATES 105 (III) SPECIALITY CHEMICALS
14 Fusidic Acid 6990.06-3 2 Antibacterial
146 Vancomycine 1404-90-6 5 Antibacterial 147 Mupirocine 12650-69-0 3 Antibacterial 148 For fibrinolytic, anti-edemic, and
Seratiopaptidase 70851-98-8 5 9 anti-inflammatory activity.
15 Inhibitor of nucleic acid
Mycophenolate 24280-93-1 10 0 synthesis; immunomodulator.
TOTAL OF SPECIALITY CHEMICALS 25
TOTAL OF API, API INTERMEDIATES & 280 SPECIALITY CHEMICALS • The project falls under Category B of project activity 5(f) as per the schedule of EIA Notification 2006. • The presentation was considred in the meeting dated 19/03/2020 as per the submission by PP via E- mail dated 18/03/2020. • Salient features of the project are as under: S. Particulars Details n o A Total cost of Proposed 9.0 Crore Project (Rs. in Crores): Ii EMP details (Capital cost & Recurring cost) Brief details of EMP
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COMPONE CAPITAL COST OF RECURRING COST OF EMP (per NT EMP Month)
Cost Rs. 0.63 Crore Rs. 0.33 Crore
Bifurcation of EMP Cost Sr Unit Installe Capital Operating Maintena Total . d Cost (Rs. Cost nce Cost Recurring N Capacit in Lakhs (Lacs/Mo (Lacs/Mo Cost o y (KLD) ) nth) nth) (Lacs/Month) 1 Effluent ETP= 25.00 25.67 0.75 26.42 Treatment 111 Plant & KLD MEE Cost ETP =20 KLD 2. APCM -- 14.50 -- 0.04 0.04 3. Hazardous -- 3.90 6.36 -- 6.36 Waste 4. AWH -- -- 0.08 -- 0.08 Monitoring Cost 5. Greenbelt -- 19.45 -- 0.11 0.11 Total 131 62.85 32.11 0.90 33.01
Ii CER details (As per MoEF&CC OM dated 01/05/2018) i As per OM no. 22-65/2017 on dated 01/05/2018 regarding “Corporate Environment Responsibility” (CER), greenfield projects have to contribute 2% of the Capital Investment, the company will contribute Rs. 18.0 Lakhs as funds for CER activities. Component As per Norms Allocation CER Rs. 18.0 Lakhs (2%) Rs. 18.0 Lakhs (2%)
Activities to be carried out under CER: CER Activities Year Fund (Rs.) To provide computers, Projector screens & equipments required for extracurricular 2020- 6,00,000 activities in the primary schools of Galenda 2021 village.
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To provide training and Guidance camp for skill development of Vadadla, Galenda & 2020- 3,00,000 Vengni villagers for employment 2021 opportunities for groups or individuals. Awareness to local farmers to increase yield 2021- of crop. Distribution of Fertilizers in Vadadla, 3,00,000 2022 Galenda & Vengni villages. To provide computers, Projector screens & equipments required for extracurricular 2021- 6,00,000 activities in the primary schools of Vengni 2022 village.
Total Rs. 18,00,000/-
B Total Plot area ( sq. meter) 9862.84 Sq. m. Green belt area ( sq. meter) 3063.45 Sq. m. C Employment generation 30 persons D Water i Source of Water Supply GIDC Water Supply Authority (GIDC Bore well, Surface water, Tanker supply etc...) Status of permission from the Membership of GIDC Water Supply, letter no. concern authority. GIDC/DEE(WS)/BRH/457, dated: 17/06/2019. ii Water consumption (KLD) Category Quantity (KLD) Remarks (A) Domestic 7.00 (B) Gardenin 3.00 g (C) Industrial Process 82.0 Washing 5.0 Boiler 60.0 Cooling 30.0 Scrubbing 18.0 Industrial Total 195 Total (A + B + 205.0
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C) 1) Total water requirement for the project: 205 KLD 2) Quantity to be recycled: 30.0 KLD 3) Total fresh water requirement: 175 KLD ii Waste water generation (KLD) i Category Waste water Remarks (KLD) (A) Domestic 4.0 (B) Industrial Process 147.0 Washing 5.0 Boiler 6.0 Cooling 3.0 Scrubbing 24.0 Total Industrial waste 185.0 water Total [A + B ] 189.0
I Treatment facility within premises with capacity v [In-house ETP (Primary, Secondary, Tertiary), MEE, Stripper, Spray Dryer, STP etc. ➢ ETP (Primary treatment)- 20 KL/day ➢ ETP (Primary & secondary treatment)- 111KL/day Treatment scheme including segregation at source. → Total 189 KL/day (185 KL/day Industrial + 4.0 KL/day domestic) of effluent shall be generated. → Stream-I: 111 KL/day low COD & TDS stream will be treated in ETP giving primary & secondary treatment then sent to CETP, Dahej for further treatment & disposal. → Stream-II: 20 KL/day high COD & TDS stream will be given primary treatment than sent to Common MEE of M/s BEIL, Dahej. → Stream-III: 30 KL/day distilled water stream will be recovered & reuse by process distillation in process water. → 24 KL/day scrubbing media will be sold to authorized end user registered under Rule-9 and reuse in manufacturing of products within the premises. → Domestic waste water (4.0 KL/day) will be disposed by septic tank or soak pit system.
Note: (In case of CETP discharge) :
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Management of waste water keeping in view direction under section 18 (1) (b) of the Water (Prevention and Control of Pollution) act, 1974 issued by CPCB regarding compliance of CETP. → Stream-I: 111 KL/day low COD & TDS stream will be treated in ETP giving primary & secondary treatment then sent to CETP, Dahej for further treatment & disposal. Brief note on adequacy of ZLD (In case of Zero Liquid Discharge): → Total 189 KL/day (185 KL/day Industrial + 4.0 KL/day domestic) of effluent shall be generated. → Stream-I: 111 KL/day low COD & TDS stream will be treated in ETP giving primary & secondary treatment then sent to CETP, Dahej for further treatment & disposal. → Stream-II: 20 KL/day high COD & TDS stream will be given primary treatment than sent to Common MEE of M/s BEIL, Dahej. → Stream-III: 30 KL/day distilled water stream will be recovered & reuse by process distillation in process water. → 24 KL/day scrubbing media will be sold to authorized end user registered under Rule-9 and reuse in manufacturing of products within the premises.
→ Domestic waste water (4.0 KL/day) will be disposed by septic tank or soak pit system. v Mode of Disposal & Final meeting point Domest • Domestic waste water (4.0 KL/day) will be disposed by septic tank or soak pit ic: system. Industri → Total 189 KL/day (185 KL/day Industrial + 4.0 KL/day domestic) of effluent shall be al: generated. v In case of →Common Stream facility-I: 111 (CF) KL/day like CETP, low COD Common & TDS Spray stream dryer, will Common be treated MEE, in CHWIF ETP givingetc. i Name of Commonprimary & faci secondarylity (CF)(For treatme wastent thenwater sent treatment) to CETP, Dahej for further treatment & disposal. ➢ Common MEE of M/s BEIL, Dahej & CETP,Dahej. → Stream-II: 20 KL/day high COD & TDS stream will be given primary treatment Membership of Common facility (CF) than sent to Common MEE of M/s BEIL, Dahej. (For waste water treatment) → Stream-III: 30 KL/day distilled water stream will be recovered & reuse by ➢ Membership of common MEE Facility, M/s. BEIL, Dahej vide letter no. BEIL/ANK/8, dated: process distillation in process water. 15/06/2019 → 24 KL/day scrubbing media will be sold to authorized end user registered under Rule-9 ➢ Membership of CETP, Dahej, vide letter no. GIDC/BRH/DEE(DRG)/347, dated: 20/06/2019. and reuse in manufacturing of products within the premises vi Simplified water balance diagram with reuse / recycle of waste water i
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Total Water: 205 KLD (175 KLD fresh water + 30 KLD Distilled water)
Domesti c: 7.0 Industrial: Gardenin 195 g: 3.0
4.0: Septic tank or soak pit
Proces Boiler: Cooling Washi Scrubbi s: 82 60 : 30 ng: 5 ng: 18
Stream -III: 30 KLD Distilled Proces Cooling Washi water Boiler: s: 147 : 3 ng: 5 stream 6 (reuse) by 9 2 process 3 0 7. 4 0 Stream -II: Stream -I: 111 Scrubbing 20.0 KLD KLD media will High COD & Low COD & be sold to TDS stream TDS stream authorized end user registered ETP ETP under Rule- (Primary & (Primary 9 & reuse in secondary treatment) manufacturi treatment) ng of
Common MEE of M/s CETP, Dahej for BEIL, Dahej further treatment & v Reuse/Recycle details (KLD) ii [Source of reuse & application area] Total reuse 30 KLD
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Source of waste Application Characteristics of Remarks water for reuse area with waste water to be regarding with quantity in quantity in reused (COD, BOD, feasibility to KLD (From where KLD (Where it TDS etc.) reuse i.e. it is coming) is used) Distilled water Process: 30 COD: 20 mg/l - Stream: 30 KLD KLD BOD: 5 mg/l - E Air i Flue gas emission details No. of Boilers/TFH/Furnaces/DG sets etc. with capacities viz. TPH, Kcal/hr, MT/hr, KVA etc.
Sta Air Quanti Sr Source of ck Type of Pollution Type ty of . emission Hei emissions Control of Fuel no With ght i.e. Air Measure Fuel MT/Da . Capacity (me Pollutants s y ter) (APCM) Multi SPM < 150 Briquette 14 Cyclone mg/Nm3 Steam Boiler s MT/day Separator 13 SO2 < 100 1 (Capacity: or or with Bag m ppm 2000 kg/hr) Natural 4600 Filter & NOx < 50 Gas SCM/day Water ppm Scrubber SPM < 150 Thermic fluid 5000 mg/Nm3 Adequate heater 13 Natural SCM/Da SO2 < 100 2 stack (Capacity: 6 m Gas y ppm Height lakh kcal/hr. NOx < 50 ppm
DG Sets SPM < 150 (Capacity: 150 mg/Nm3 Adequate 10 400 3 KVA*1 No.) in Diesel SO2 < 100 stack m Liters/day emergency ppm Height case only NOx < 50
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ppm - ii Process gas emission details i.e. Type of pollutant gases (SO2, HCl, NH3, Cl2, NOx etc.) - Specific Source of Stack/Ve Air Pollution Sr. emission Type of nt Control Measures no. (Name of the emission Height (APCM) Product & Process) (meter) PROPOSED Process Stack 1
(Product No. Two Stage Water 1 HCl 15 meters 15,78,87,97,127 & Scrubber
144) Chlorination Process Stack 2 (Product No. 10, 31, SO2 Two Stage Water 2 71, 92 & 100) 15 meters HCl + Alkali scrubber Sulphonation & Chlorination Process Stack 3 Two Stage Water 3 (Product No. 58 & HBr 15 meters Scrubber 134) Bromination Process Stack 4 Two Stage Water 4 (Product No. 15) NH3 15 meters Scrubber Ammonification Process Stack 5 Two Stage Water 5 (Product No. 1, 80) HCl 15 meters Scrubber Chlorination
ii Fugitive emission details with its mitigation measures. i ➢ Airborne dust at all transfers operations/ points will be controlled either by spraying water or providing enclosures. ➢ Adequate ventilation will be provided. ➢ Care will be taken to store construction material properly to prevent fugitive emissions, if any ➢ Regular maintenance of valves, pumps, flanges, joints and other equipment will be done to prevent leakages and thus minimizing the fugitive emissions of VOCs. ➢ Entire process will be carried out in the closed reactors with proper maintenance of pressure and temperature.
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➢ Periodic monitoring of work area will be carried out to check the fugitive emission. ➢ Stand by pumps will be provided on all scrubbers. Besides, scrubbers will be equipped with on-line pH meter with hooter system for better operational control. ➢ To eliminate chances of leakages from glands of pumps, mechanical seal will be provided at all solvent pumps. ➢ Close feeding system will be provided for centrifuges. Centrifuge and filtrate tank vents will be connected to vent chillers. ➢ Fugitive emission over reactors, formulation areas, centrifuges, chemical loading, transfer area will be collected through hoods and ducts by induced draft and controlled by scrubber/ dust collector. ➢ Dedicated scrubber will be provided are used for fugitive emissions to control. ➢ For dust emissions bag filter will be provided. ➢ Minimum number of flanges, joints and valves in pipelines. ➢ Enclosures to chemical storage area, collection of emission from loading of raw materials in particular solvents through hoods and ducts by induced draft, and control by scrubber / dust collector to be ensured. ➢ Nitrogen blanketing will be provided, besides special care needs to be taken for control in respect of odorous chemicals. F Hazardous waste (As per the Hazardous and Other Wastes (Management and Transboundary Movement) Rules 2016. i Sr. Type/Nam Specific Categor Quantity Management of HW no e of Source of y and (MT/Ann . Hazardous generation Schedul um) waste (Name of the e as per Activity, HW Product etc.) Rules. Collection, Storage, ETP Sch -I transportation and disposal 1 ETP 999.6 Sludge (35.3) to co-processing or nearer common TSDF site. Collection, decontamination, Discarded Storage & Sch -I Storage, transportation, & 2 Drums/Bag Handling of 42 (33.1) Sale to GPCB approved s/ Liners Raw Materials recyclers/ vendors.
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Collection, Storage, transportation & Sale to Equipment & Sch -I 3 Used oil 2.4 GPCB approved recyclers or Machineries (5.1) use as lubricant within unit’s premises. Collection, Storage, Mfg. Process transportation and sent for Spent (Product No. Sch -I co-processing in cement 4 167.2 carbon 3,6,33, 48, (28.3) industries or incineration at 87,90,108) nearer common incinerator Site. Mfg. Process Collection, Storage, Of (Product Spent Sch -I Transportation & return back 5 No. 16, 175.8 Catalyst (28.2) to supplier for regeneration 27,51,88,94, registered under Rule-9. 125 & 136) Collection, Storage, transportation and disposal Distillation Distillation Sch -I by co processing in cement 6 576 Residue Process (36.1) industry or incineration at nearer common incinerator site. Collection, Storage, Mfg. Process Transportation and sent for Organic (Product No. Sch -I co-processing in cement 7 384 Residue 8,33, 60, (28.1) industries or incineration at 93,123 & 141) nearer common incinerator site. Mfg. Process Collection, Storage, Dilute (Ibuprofen Transportation, disposal by Caustic Lye Sch -I 8 &Isobutyl 6012 selling to authorized end Sol. (20- (28.1) Acetophenone user registered under Rule- 25%) ) 9. Liquor Scrubber Collection, Storage & reuse Sch -I 9 ammonia (Product No. 1044 entire qty. in plant premise (28.1) (22-25%) 15) for manufacturing of
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Metronidazole (Req. Qty.: 1320 MT/yr). Collection, Storage & reuse Scrubber entire qty. in plant premise HBr sol. Sch -I 10 (Product No. 288 for manufacturing of (45-47%) (28.1) 58 & 134) Tenofovir (Req. Qty.: 371.1 MT/yr). Collection, Storage & reuse in plant premise for manufacturing of (3,4- Dimethoxyphenyl) acetonitrile (Req. Qty.: 720 MT/yr), 5- Chloroacetylsalicylamide (Req. Qty.: 528 MT/yr), 6- Chloro 4-Hydroxy 2-Methyl Scrubber 2H-thieno[2,3,e][1,2]thiazine- (Product No. Sch-II- 3-Carboxylate 1,1-dioxide HCl sol. 15, 78, 87, 97, (60 MT/yr), Gabapentin 11 4968 (28-30%) 127, 144,10, Class- B (Req. Qty.: 582 MT/yr) and 31, 71, 92, (15) Mesalmine/Mesalazine (Req. 100,1 & 80) Qty.: 346.8 MT/yr), Venlafaxin hydrochloride (Req. Qty.: 240 MT/yr), (2S)- 2-aminobutanamide Hydrochloride (Req. Qty.: 1142.4 MT/yr) & excess quantity (1348.8 MT/yr) will be sell to authorized end user registered under Rule- 9. Collection, Storage, Scrubber Sodium Transportation, disposal by (Product No. Sch -I 12 bisulfite 2340 selling to authorized end 10, 31, 71, 92 (28.1) (30%) user registered under Rule- & 100) 9.
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Collection, Storage, 13 Spent Sch -I management, recovery by Mfg. Process 88672 Solvent (28.6) inhouse distillation & reuse within the premises. Mfg. Process Sch -I Collection, Storage, Aluminium (Ibuprofen (28.1) Transportation, disposal by Chloride 14 &Isobutyl 5388 selling to authorized end Sol. (8- acetophenone user registered under Rule- 10%) ) 9. Collection, Storage & reuse in plant premise for manufacturing of Basic cromium sulphate (Req. Qty: 28.2 MT/yr) and excess Chromium quantity (2191.8 MT/yr) will Mfg. Process Sch -I 15 Sulfate Sol. 2220 be sell to authorized end (Ibuprofen) (28.1) (8-10%) user registered under Rule-9 or sell entire quantity (2220 MT/yr) to authorized end user registered under Rule- 9. Collection, Storage & reuse Mfg. Process Sch -I entire qty. in plant premise 16 Acetic acid 864 (Acyclovir) (28.1) for manufacturing of Aspirin (Req. Qty.: 1132.8 MT/yr). Collection, Storage, Transportation, disposal by Sodium Mfg. Process Sch -I 17 154.8 selling to authorized end Phosphate (Lamotrigine) (28.1) user registered under Rule- 9. Collection, Storage, Mfg. Process transportation and send for Spent (Product No. Sch -I 18 5.75 co processing or incineration Hyflow 3,5,26, (28.1) at nearer common 46,83,121) incinerator site.
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Collection, Storage, Off Process Sch -I Transportation & send for 19 specificatio 21.6 (Batch failure) (28.4) incineration at nearer n product common incinerator Site.
ii Membership details of ➢ Membership of Hazardous Landfill (M/s. BEIL, Dahej) & TSDF, CHWIF etc. Hazardous Incineration (M/s BEIL, Ankleshwar), Ref no. (For HW management) BEIL/ANK/8, Dated: 15/06/2019 ➢ Membership of Waste Co-Processing (RSPL, Panoli) dated: 03/03/2020. ii Details of Non-Hazardous Non Hazardous Waste will not be generated. i waste & its disposal(MSW and others) G Solvent management, VOC emissions etc. i Types of solvents, Details of Solvent recovery, % recovery, reuse of recovered Solvents etc. (Details in Table Format) • All the solvents shall be directly distilled from product mixes and; if required shall be purified in packed column with the help of reflux. • The solvent distillation system shall be designed so as to achieve minimum 95.0 % recovery of solvent. • All the pumps shall be mechanical seal type to avoid any leakage of solvent. • All necessary fire fighting systems shall be provided with alarm system. Flame proof wiring and flame proof electrical accessories shall be provided to avoid any mishap. • All the distillation column vents are also connected to cooling water/ chilled brine condensers for maximum possible recovery of the solvents. • All the vents will be connected to a common carbon Adsorber for removing traces of solvent from vent gases. • Residue generated from the distillation will be sent to nearer common incinerator site. • Two condensers will install with cooling water and chilled brine to recover the solvent. • Primary Condenser HE-01: Cooling water or Chilled water (at 100C) will be used to condense the solvents depend on the vapor pressure at its operating conditions and the non condensed vapors will be condensed in a Secondary Condenser • VOC Trap Condenser HE-02: Chilled Brine at -05 0C will be used to trap any traces of Solvent which is slipped from Secondary condenser ii VOC emission sources and its mitigation measures During operation stage, leakage through valves/pumps, leakage and emission from open drum
613th meeting of SEAC-Gujarat, dated 19.03.2020 Page 33 of 217 containing chemicals, open feeding, storage tanks, etc. will be major sources of fugitive emissions and VOCs. Excess use of solvent/s may also results fugitive emission from the process vessels. • Solid raw material charging will be done through closed system. • Entire process will be carried out in the closed reactors with proper maintenance of pressure and temperature. • Close feeding system will be provided for centrifuges. Centrifuge and filtrate tank vents will be connected to vent chillers. • Fugitive emission over reactors, formulation areas, centrifuges, chemical loading, transfer area, will be collected through hoods and ducts by induced draft and controlled by scrubber/dust collector. • Emphasis will be given to solvent management/solvent loss prevention. • Control by having proper scrubbing system. • Condenser to trap VOC. • Enclosures to chemical storage area, collection of emission from loading of raw materials in particular solvents through hoods and ducts by induced draft, and control by scrubber/dust collector to be ensured. • Proper maintenance schedule will be adhered to avoid emissions through flange joints, pump seals etc. • Minimum number of flanges, joints and valves in pipelines. • Proper gland packing will be maintained for pumps and valves and to the extent possible pumps with mechanical seal. • All the raw materials will be pneumatically transfer to the reactor. • All rotating equipments like pumps will be installed with mechanical seals to arrest any sort of emissions. • A regular preventive maintenance schedule will be in place to replace or rectify all gaskets and joints etc. as a part of ISO systems to ensure no fugitive emissions take place. • Periodic monitoring of work area will be carried out to check the fugitive emission. • Solvent tank vents will be connected to vent chillers. • Adequate ventilation will be provided. • Airborne dust at all transfers operations/ points will be controlled either by spraying water or providing enclosures. • Breather valves will be provided on solvent tanks.
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H ➢ Details regarding storage of Hazardous chemicals Storage details Name of major Hazardous chemicals Storage tanks Isopropyl Alcohol, Methylene Chloride/Methylene Dichloride (MDC),Toluene ,Ethyl Acetate, Methanol & Acetone Drum/Barrel storage Ethanol, Ethylene Dichloride, Sulphuric Acid , Acetic Acid, Liquor Ammonia, Acetonitrile, Hydrochloric acid, Xylene, Hexane, Tetrahydrofuran, Cyclohexane, Dimethyl formamide, Aniline, Acetic Anhydride, Thionyl chloride, Chloroform & n-heptane Bank, Cylinder, Bottle or Tonner Hydrogen gas, Ammonia gas, Bromine gas & Chlorine gas
➢ Applicability of PESO : ➢ Permission will be taken after getting EC and all the standards of PESO for storage of solvents will be followed. • During the meeting dated 19/03/2020, the project was appraised based on the information furnished in the EIA Report and details submitted by PP. • The baseline environmental quality has been assessed for various components of the environment viz. air, noise, water, biological and socioeconomic aspect. The baseline environmental study has been conducted for the study area of 10 km radial distance from project site for the October 2018 to December 2018. Ambient Air Quality monitoring was carried out for SPM, PM2.5, PM10, SO2, NOx, O3, Pb, As, Ni, Benzene, CO, HC NH3, HCl, HBr & VOC at eight locations, including the project site. Values conform to the prescribed standards for Ambient Air Quality. The incremental Ground Level Concentration (GLC) has been computed using ISCST – 3. The resultant concentrations are within the NAAQS. • Risk assessment including prediction of the worst-case scenario and maximum credible accident scenarios has been carried out. The detail proposed safeguard measures including On-Site / Off-Site Emergency Plan has been covered in the RA report. • Committee noted that proposal is new in GIDC Dahej. Source of water is GIDC. PP submitted that high COD/TDS effluent generated from process will be segregated and treated in in-house primary ETP – 1 and treated effluent will be sent to Common MEE of BEIL, Dahej for final treatment and disposal. Committee noted that PP has not submitted membership certificate in-line with the direction given by GPCB dated 8th January, 2020. PP submitted that low COD/TDS effluent generated from process, boiler blow down, cooling tower blow down and washing will be treated in in-house ETP – 2 consisting of primary and secondary treatment and treated effluent will be discharged into CETP,
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Dahej for final treatment and disposal. Committee noted that PP has submitted total water requirnment, recycle quantity and fresh water requirnment which is in devation from ToR. PP submitted that they have proposed one steam boiler and one TFH. Fuel used will be Natural Gas/ Agro Briquettes. PP has not submitted Hazardous Waste details as per HWR – 2016. • After detailed discussion, Committee unanimously decided to consider the project only after submission of the following documents. 1. Membership Certificate from Common Facility (mentioning total capacity, consented quantity, occupied capacity and spare capacity and norms of acceptance of effluent from member units) in-line with the direction given by GPCB vide Letter No. GPCB/P-1/8-G (5)/550706 dated 08/01/2020. 2. Clarification regarding devation from ToR for Total Water Requirnment, Recycle Quantity and Fresh Water Requirnment. 3. Characteristic of Process Effluent generated from each Product as per Compliance of Specific ToR. 4. Saftey Precautions for Sodium Metal, Hydrogen gas, Ammonia gas, Bromine gas, Chlorine gas including transportation, storage, handling and process safety as per Compliance of Specific ToR. 5. Addendum to EIA Report incorporating all this changes. 3 SIA/GJ/IND2/40533/2019 M/s. Anupam Rasayan India Ltd. (Unit-4) Appraisal Plot No. 907/3 & 907/4, Jhagadia Industrial Estate, Jhagadia, Dist: Bharuch – 393 110, Gujarat. Category of the unit: 5(f) Project status: Expansion
• Project proponent (PP) submitted online application vide no. SIA/GJ/IND2/40533/2019 dated 16/03/2020 for obtaining Environmental Clearance. • SEIAA issued TOR to PP vide their letter dated 05/12/2019. • Project proponent has submitted EIA Report prepared by Aqua – Air Environmental Engineers Pvt. Ltd, Surat based on the TOR issued by SEIAA. • This is an expansion project for manufacturing of synthetic organic chemical as tabulated below. CAS End use Existing Total Additional Sr. No. Capacity capacity Name of Products Capacity No. (MT/Month (MT/Month (MT/Month) ) ) 123-91- 1.1 1,4 Dioxane Dyes 1 1000 0 1000 1.2 2- Methyl 1,3 Dioxolane 497-26- Pharma
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7 2.0 CHLORO / FLUORO / AMINO BENZENE COMPOUNDS 108-90- 2.1 Chloro Benzene (MCB) 7 Para Di Chloro Benzene 106-46- Dyes/Pigm 2.2 (PDCB) 7 ent Ortho Di Chloro Benzene 2.3 95-50-1 (ODCB) 1- Amino 2,4,6 Trichloro 634-93- 2.4 Benzene / 2,4,6 Tri Chloro Pharma 5 Aniline 2500 3621- 2.5 2,6 Di Chloro Benzoxazole Pharma 82-7 2,3,4,5,6 Penta Chloro 2176- 2.6 Pharma Pyridine 62-7
3,7 Di Chloro 8- Methyl 84086- 2.7 Pharma Quinoline 96-4
Proposed
Ortho Phenylene Diamine 2.8 95-54-5 Pharma (Proposed)
Meta Phenylene Diamine 108-45- 2.9 Pharma (Proposed) 2
2.1 Para Phenylene Diamine 106-50- Pharma 0 (Proposed) 3 2500 2500 2.1 2,4-Difluoro Aniline 367-25- Pharma 1 (Proposed) 9 2.1 2,6- Difluoro Aniline 5509- Pharma 2 (Proposed) 65-9 2.1 1,2-Di Fluoro Benzene 367-11- Pharma 3 (Proposed) 3 2.1 2-Amino Benzotrifluoride 88-17-5 Pharma 4 (Proposed) 00 2.1 3 – Amino Benzotrifluoride 98-16-8 Pharma 5 (Proposed) 2.1 455-14- 4 – Amino Benzotrifluoride Pharma 6 1
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2.1 3,4-Difluoro Benzonitrile 64248- Pharma 7 (Proposed) 62-0 2.1 1,3,5-Trimethoxybenzene 621-23- Pharma 8 (Proposed) 8 2.1 2-Amino-2-Phenyl Propane 585-32- Pharma 9 (Proposed) 0 2,4-Dichloro 2.2 13014- Benzotrichloride Pharma 0 18-1 (Proposed0 2.2 2-Chloro-4-Fluorophenol 1996- Pharma 1 (Proposed) 41-4 2.2 3,4-Dichloro 328-84- Pharma 2 Benzotrifluoride(Proposed) 7 2.2 3-Chloro Propiophenone 936-59- Pharma 3 (Proposed) 4 3-chloro-4-(2,6- 2.2 difluorophenyl)-6-methyl-5- 135806 Pharma 4 phenylpyridazine 1-55-8 (Proposed) 2.2 4-Bromo-6-methylpyridazin- 117888 Pharma 5 3(2H)-one (Proposed) 4-53-1 2.2 4-Chloro Benzotrichloride 5216- Pharma 6 (Proposed) 25-1 2.2 57946- 4-Chloro OFA (Proposed) Pharma 7 56-2 2.2 5-Chloro-2-Amino 445-03- Pharma 8 Benzotrifluoride(Proposed) 4 2.2 Benzotrichloride(Proposed) 98-07-7 Pharma 9 IsoPropyl-3-Chloro-4- 2.3 141855 Methyl Benzoate Pharma 0 4-01-4 (Proposed) 2.3 1,3-Difluorobenzene 372-18- Pharma 1 (Proposed) 9 2.3 2,4,5-Trifluoro Phenyl 209995- Pharma 2 Acetic Acid (Proposed) 38-0 Pharma
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2.3 2,4,6-Trimethyl Aniline 88-05-1 3 (Proposed) 3.0 SPECIALTY PHENOL COMPOUNDS 106-48- 3.1 Para Chloro Phenol (PCP) Pharma 9
3.2 Ortho Chloro Phenol (OCP) 95-57-8 Pharma
120-83- 3.3 2,4 Di Chloro Phenol Pharma 500 2 200
3.4 2,6 Di Chloro Phenol 87-65-0 Pharma Proposed 4- Bromo 2,5 Di Chloro 1940- 3.5 Pharma Phenol (Proposed) 42-7 Resorcinol / 1,3 700
Benzenediol / Meta Di 108-46- 3.6 Pharma Hydroxy Benzene 3 (Proposed) 00 700 Meta Amino Phenol 591-27- 3.7 Pharma (Proposed) 5 6-Chloro-Mercapto 22876- 3.8 Pharma Benzoxazole (Proposed) 20-6 3,4,5- 99627- 3.9 Pharma Trifluorophenol(Proposed) 05-1 Meta Dichloro Benzene 541-73- 4.0 Dyes 400 100 500 (MDCB) 1 5.0 NITRO COMPOUNDS 5.1 Nitro Benzene 98-95-3 Dyes 99-65-0 Meta Di Nitro Benzene ( 800 5.2 Dyes MDNB)
Proposed 800 800 2,4 Di Chloro 3,5 Dinitro 29091- 5.3 Pharma Benzotrifluoride 09-6 2,3,4 Tri Chloro Nitro 17700- 00 5.4 Pharma Benzene 09-3 5.5 4- Nitro Ortho Xylene 99-51-4 Pharma
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2,4- Difluoro Nitrobenzene 446-35- 5.6 Pharma (Proposed) 5 2-Cyano-4-Nitro Aniline 17420- 5.7 Pharma (Proposed) 30-3 10043- 6.0 Calcium Chloride Pharma 1800 0 1800 52-4 7.0 AMINO BENZOIC ACID / ESTERS 3-Amino-4-Methyl Benzoic 18595- 7.1 Pharma Acid Methyl Ester 18-1 3-Amino 4-Methyl Benzoic 21447- 7.2 Pharma Acid Isopropyl Ester (AMBI) 47-2 3-Amino 4-Methyl Benzoic 2458- 7.3 Acid (2' -Chloro Ethyl Ester) 12-0 Pharma
(AMBC)
5-Amino-2-Methyl Benzene 108933
7.4 Sulphonic Acid Phenyl 9-15-0 Pharma
Ester
Benzene Sulphonic Acid 3- 13653- 7.5 Pharma Amino Phenyl Ester 12-4
2-Cyano-3,4,5,6- 10276- 500 100 7.6 Tetrachloro Benzoic Acid 78-2 Pharma
Methyl Ester
Benzene Sulphonic Acid 2- 85896- 7.7 Pharma Methyl-5-Nitrophenyl Ester 03-5
4- Amino Benzoic Acid 619-45- 7.8 Pharma Methyl Ester 4
3,5 Di Amino 4- Chloro 32961- 7.9 Pharma Benzoic Acid Iso Butyl Ester 44-7
Proposed
7.1 3,4,5 Tri Methoxy Benzoic Acid118 -41- Pharma 600 0 (Proposed) 2 1- Methyl 3,4,5 Tri Methoxy 6443- 7.1 Benzene / 3,4,5 Tri 69-2 Pharma 1 Methoxy Toluene (Proposed) 7.1 5- Methyl 2,3 Pyridine Di 53636- Pharma
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2 Carboxyllic Acid (Proposed) 65-0 7.1 3,4,5 Tri Methoxy 86-81-7 Pharma 3 Benzaldehyde (Proposed) 00 600 2 – Amino 3-Chloro Benzoic 7.1 77820- Acid Methyl Ester Pharma 4 58-7 (Proposed) 2- Nitro-5-Chloro-4-Methyl 7.1 120451 Benzoic Acid Iso Propyl Pharma 5 8-43-3 Ester (Proposed) 7.1 N-(2-Hydroxypropyl)-2- 68892- Pharma 6 Picolylamine (Proposed) 16-0 7.1 Bromo Tri Chloro Methane 75-62-7 Pharma 7 (Proposed) Total 7500 400 7900 • The project falls under Category B of project activity 5(f) as per the schedule of EIA Notification 2006. • The presentation was considred in the meeting dated 19/03/2020 as per the submission by PP via E- mail dated 18/03/2020. • Salient features of the project are as under: Sr. Particulars Details no. A Total cost of Proposed Project Existing: 83 Crore (Rs. in Crores): Proposed: 10 Crore Total: 93 Crore i EMP details (Capital cost & Recurring cost)
Brief details of EMP
COMPON CAPITAL COST RECURRING COST OF EMP ENT OF EMP (per Month)
Cost Rs. 539.5 Lakhs Rs.911.448 Lakhs
Bifurcation of EMP Cost Sr. Unit Installed Capital Cost Operati Maintenanc Total No Capacity (Rs. in ng Cost e Cost Recurring (KLD) Lakhs ) (Lacs/M (Lacs/Mont Cost
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onth) h) (Lacs/Mo nth) 1 Effluent 77 KLD 305.5 57.00 0.75 57.75 treatment plant (ETP) consists of primary, secondary & Tertiary treatment units, MEE, SBT 2. APCM -- 125 -- 0.8 0.8 3. Hazardous -- 23 16.60 -- 16.60 Waste (Expense) 4. AWH -- 55 0.5 -- 0.5 Monitoring Cost 5. Greenbelt -- 31 -- 0.3 0.3 Total 539.5 75.95
ii CER details (As per MoEF&CC OM dated 01/05/2018) As per OM no. 22-65/2017 on dated 01/05/2018 regarding “Corporate Environment Responsibility” (CER), Brownfield projects have to contribute 1% of the Additional Capital Investment, the company will contribute Rs. 15.0 Lakhs as funds for CER activities Component As per Norms Allocation CER Rs. 10.0 Lakhs (1 %) Rs. 15 Lakhs (1.5 %)
Activities to be carried out under CER: CER Activities Fund (Rs.) Infrastructure development [ i.e 2 nos. of 10,00,000/- Classroom in Jhagadia Higher Secondary school] Organize Medical Camp in Dadheda Village (Once 2,00,000/- in year)
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To supply the fodder to gaushala at Jhagadia. 3,00,000/- Total 10,00,000/-
B Total Plot area Existing: 53997 Sq. m. ( sq. meter) Proposed: 00 Sq. m. Total: 53997 Sq. m. Green belt area Existing: 16467 Sq. m. ( sq. meter) Proposed: 1624 Sq. m. Total: 17819 Sq. m. C Employment generation Existing: 200 Proposed: 25 Total: 225 D Water i Source of Water Supply GIDC Water Supply (GIDC Bore well, Surface water, Tanker supply etc...) Status of permission from the GIDC Water Supply letter No. concern authority. GIDC/RM/ANK/3620 dated: 04/09/2014 ii Water consumption (KLD) Existing Proposed Total after Remarks KLD (Additional) Expansion KLD KLD (D) Domestic 5.0 2.0 7.0 (E) Gardening 5.0 0.0 5.0 (F) Industrial Process 63.0 4.0 67.0 Washing 4.0 0.0 4.0 Boiler 63.0 0.0 63.0 Cooling 98.0 0.0 98.0 Scrubber 72.0 10.0 82.0 Industrial Total 300.0 14.0 314.0 Grand Total (A+B+C) 310.0 16.0 326.0
1) Total water requirement for the project: 326 KLD 2) Quantity to be recycled:00 KLD 3) Total fresh water requirement: 326 KLD
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Note: Worst case scenario for water consumption is given below: Group-1 : No change in this group Group-2 : Product No. 2.1 Group-3 : Product No. 3.1 & 3.2 Group-4 : No water consumption in this group Group-5 : Product No. 5.2 Group-6 : No water consumption in this group Group-7 : Product No. 7.3 iii Waste water generation (KLD) Proposed Total after Existing Category (Additional) Expansion Remarks KLD KLD KLD (C) Domestic 4.0 1.6 5.6 (D) Industrial
Process 60.0 3.0 63.0 Washing 4.0 0.0 4.0 Boiler 5.0 0.0 5.0 Cooling 5.0 0.0 5.0 Others (Scrubber) 112.5 15.0 127.50 Scrubbing Media -Reuse & Sell to end user Total Industrial 74.0 3.0 77.0 waste water
iv Treatment facility within premises with capacity [In-house ETP (Primary, Secondary, Tertiary), MEE, Stripper, Spray Dryer, STP etc.. ➢ In-house ETP (Primary Treatment– 63 & 14 KL/Day) ➢ Note: Industry has installed Multi Effect Evaporator for the treatment of industrial effluent having capacity of 110 KL/Day and Capacity of SBT-75 KL/Day. So, Existing treatment system is adequate to treat additional load of effluent and there will no required additional infrastructure for treatment of additional effluent.
Treatment scheme including segregation at source. 77.0 KL/Day Industrial Waste Water will be treated in MEE & Condensate of MEE 74 KLD is treated finally at SBT based Bio Reactor System and Out of 74.0 KL/Day. Total
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74 KL/Day SBT Treated Industrial Waste Water which confirming NCT-Discharge Norms will be discharged to NCT-Jhagadia new pipeline leads to Marine Discharge in Deep Sea at Kantiyajal. Scrubbing media (127.5 KL/Day) will be reused in plant premises and sell to end user under Rule-9 permission. 5.6 KL/Day domestic waste water will be treated and disposed in septic Tank & Soak Pit. Note: (In case of CETP discharge) : Management of waste water keeping in view direction under section 18 (1) (b) of the Water (Prevention and Control of Pollution) act, 1974 issued by CPCB regarding compliance of CETP. ➢ Not Applicable as treated effluent will be discharged into deep sea through NCT, Pipeline. Brief note on adequacy of ZLD (In case of Zero Liquid Discharge): ➢ Not Applicable, Company will be disposed the treated effluent to deep sea through NCT Pipeline. v Mode of Disposal & Final meeting point Domestic: 5.6 KLD - Septic Tank/ Soak Pit System Industrial: 77.0 KL/Day Industrial Waste Water will be treated in MEE & Condensate of MEE 74 KLD is treated finally at SBT based Bio Reactor System and Out of 74.0 KL/Day. Total 74 KL/Day SBT Treated Industrial Waste Water which confirming NCT-Discharge Norms will be discharged to NCT-Jhagadia new pipeline leads to Marine Discharge in Deep Sea at Kantiyajal. Scrubbing Scrubbing media (127.5 KL/Day) will be reused in plant premises and sell to end user under Rule-9 permission. vi In case of Common facility (CF) like CETP, Common Spray dryer, Common MEE, CHWIF etc. Name of Common facility (CF)(For waste water treatment) ➢ Common facility (CF) like pipeline project of M/s. NCT, Jhagadia. Membership of Common facility (CF) – NCT letter – NCTL/JPP/SEPT-76 dated: 12/09/2014 (For waste water treatment) -vii Simplified water balance diagram with reuse / recycle of waste water
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Water Balance (Total after Proposed Expansion) (OPTION-1): (All dimensions are in KL/day)
vii Reuse/Recycle details (KLD) [Source of reuse & application area] Total reuse 00 KLD Source of waste Application Characteristics of Remarks water for reuse area with waste water to be regarding with quantity in quantity in reused (COD, BOD, feasibility KLD (From KLD (Where TDS etc.) to reuse where it is it is used) i.e. coming)
E Air i Flue gas emission details No. of Boilers/TFH/Furnaces/DG sets etc. with capacities viz. TPH, Kcal/hr, MT/hr, KVA etc. Existing & Proposed - Source of Stack Type of Quantit Type Air Sr. no. emission Height Fuel y of of Pollution
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With Capacity (meter) Fuel emis Control MT/Day sions Measures i.e. (APCM) Air Pollut ants Existing Steam Boiler Height-38 Coal Multi Capacity: 2.5 Meters Cyclone PM MT/Hr Dia:- 1.5 MT/ Separator, 1 SO2 1000mm Day Bag filter & NOX Water Scrubber Steam Boiler Coal OR 2 Capacity: 12 Briquettes ESP, Water 130 MT/ MT/Hr of Bio PM Scrubber Day OR Hot Air Generator Coal SO2 and On line 145 MT/ – 2 Nos. NOX monitoring 3 Day Capacity: 10 system. MT/Hr each Thermopack unit Height-25 Natural PM 4 Capacity:600 U Meters Gas SO2 Multi Dia:- NOX Cyclone Thermopack unit 400mm 2000 PM Separator, 5 Capacity:600 U SCM/Da SO2 Bag filter & y NOX Water Thermopack unit PM Scrubber 6 Capacity:800 U SO2 NOX D.G. Set 11 HSD 2400 PM Adequate 7 (800 KVA) Liter/Da SO2 Height y NOX D.G. Set 11 HSD 1800 PM Adequate 8 (600 KVA) Liter/Da SO2 Height y NOX
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No additional Flue Gas emissions. Note: Existing Steam boiler -12 MT/Hr is running at 10 MT/Hr capacity and 2 MT/Hr capacity is spare in existing boiler as well as spare capacity (200 U) available in existing Thermo pack unit -800 U, so additional flue gas emission will not require.
ii Process gas i.e. Type of pollutant gases (SO2, HCl, NH3, Cl2, NOx etc.) Existing & Proposed SR. TYPE OF AIR POLLUTION HEIGHT AIR EMISSION NO STACK CONTROL (M) POLLUTANT CONC. . SYSTEM EXISTING 1. Reaction Two Water 11 HCL 20 MG/NM3 Vessel Scrubber
(Group-1 – Product No. 2.18 & Group-2 – Product No. 3.1 & Group-7 – Product No. 7.16)
3 2. Reaction Two Alkali 11 SO2 40 MG/NM Vessel Scrubber
(Group-1 – Product No. 2.33 & Group-5 – Product No. 5.3)
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3 3 Reaction Two Alkali 11 Cl2 9 MG/NM Vessel Scrubber
(Group-1 – Product No. 2.18 & Group-2 – Product No. 3.1)
PROPOSED 4. Reaction Two Water 11 NH3 175 MG/NM3 Vessel Scrubber
(Group-7 – Product No. 7.14)
3 5. Reaction Two Water + 11 HBr 30 MG/NM Vessel Alkali Scrubber
(Group-7 – Product No. 7.17)
- iii Fugitive emission details with its mitigation measures. • Enclosed Processed • Minimum joints/flanges • Auto handling for charging Raw Materials • Pumps with double mechanical seals • Proper Ventilation ➢ PPEs F Hazardous waste (As per the Hazardous and Other Wastes (Management and Transboundary Movement) Rules 2016. Existing & Proposed i Sr. Waste Source Waste Quantity (MT/Month) Mode of Disposal
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No. Details Categor ExistiAddition Total y ng al
ETP Collection, 15 Storage, ETP SCH- 1.1 17.0 1. .8 Transportation Sludge I/35.3 7 0 3 and Disposal at Nearest TSDF
Collection, Process Process Storage, waste Transportation Sludge SCH- 50 2. 0 5000 and sell to (Inorgani I/28.1 00 Cement Industry c) or Disposal at
Nearest TSDF
Utilities Collection, 50 Storage, 50 SCH- Liter Transportation 3. Used Oil 0 Liter/M I/5.1 /Mo and Selling to onth nth authorized recyclers.
Discard RM & FG 1003 200 1203 ed Nos/ Nos/M Collection, liners/B Mont Nos/Mo onth Storage, ags h (1.8 nth Transportation Carboy SCH- 4. (9 MT/M (10.8 and Selling to I/33.1 Drums MT/ onth) MT/Mo authorized Mont nth) recyclers after Unit in h) decontamination. No./Mo
nth
MEE Collection, Salt from SCH- Storage, 5. 60 15 75 MEE I/35.3 Transportation and Disposal at
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Nearest TSDF
Collection, Storage,
Transportation Distillatio Distillatio 85 and sell to SCH- 85.6 6. n n .6 0 Cement Industry I/20.3 6 Residue 6 for Co-processing or Disposal at Common Incineration Site
Boiler Collection, Storage, 7. Fly Ash -- 80 0 80 Transportation and sell to brick manufacturers
Process
(Product Collection, No. Storage, 2.33, Dilute Transportation & 3.1,3.2, SCH- 753. 3789. 8. Sulphur 4543.0 Sell to end user 3.8, 3.9, I/28.1 3 7 ic Acid which have rule-9 5.3, 5.4, permission with 5.5, 5.7, MOU. 7.1, 7.2,7.3)
Proces Collection, s Storage and reuse in CaCl2 (Produc 30 % Plant or in case of t No. SCH- 3375 9. HCl 180.0 3555.0 non-operation of 2.4,2.5, I/28.1 .0 Solution CaCl2 Plant, 2.6, Transportation & 2.18,2. Sell to end user 19,2.21 under rule-9
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, permission with 2.22,2. MOU. 23,2.24 , 2.26, 2.27, 2.28, 2.29, 2.30, 3.1, 3.2,3.3, 3.4, 7.15, 7.16) & Scrubb er
35 -40 Process Collection, % Storage, Nitrosyl Transportation & Sulphur SCH- 986. 10. 0 986.0 Sell to end user ic Acid / I/28.1 0 which have rule-9 Sodium permission with Nitrite MOU. Solution Process Collection, Storage, Caustic (Product Soda Transportation & No.1) SCH- 470. 11. Solution 0 470.0 Sell to end user I/28.1 0 (30% to which have rule-9 40%) permission with MOU.
Process Collection, Ammoni Storage, um (Product SCH- 12. 55.0 0 55.0 Transportation & Chlorid No.7.6) I/28.1 Sell to end user e which have rule-9
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permission with MOU.
Process Collection, Storage, (Product Ammoni Transportation & um No.7.6) SCH- 150. 13. 0 150.0 Sell to end user Sulphat I/28.1 0 which have rule-9 e Salt permission with MOU.
Process Collection, (Product Storage, No.2.25, 20-28 Transportation & 3.5, 7.10, SCH- 14. % HBr 0 3625 3625 Sell to end user 7.11, I/28.1 Solution which have rule-9 7.13, permission with 7.17) & MOU. Scrubber
Process Collection, (Product Storage,
Sodium No., Transportation & SCH- 15. Bromid 7.10, 0 490 490 Sell to end user I/28.1 e Salt 7.11, which have rule-9 7.13, permission with 7.17) MOU.
Process Collection,
(Product Storage, Sodium No., Transportation SCH- 16. Sulphat 7.10, 0 1093 1093 and Sell to end I/28.1 e 7.11, user which have 7.12, rule-9 permission 7.13) with MOU.
8-10 % Process SCH- Collection, 17. 0 600 600 Sodium (Product I/28.1 Storage,
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Hypochl No., 2.4, Transportation & orite 2.7) Sell to end user Soln. which have rule-9 permission with MOU.
Process Collection,
30 -40 (Product Storage, % No., Transportation & SCH- 18. Dilute 2.29, 0 492 492 Sell to end user I/28.1 Nitric 3.9) which have rule-9 Acid permission with MOU.
Process Collection, Storage, (Product Sulphur Transportation & No 2.5) SCH- 19. Dichlori 0 1090 1090 Sell to end user I/28.1 de which have rule-9 permission with MOU.
Process Collection, Storage, (Product Potassi Transportation & um No 5.6) SCH- 20. 0 900 900 Sell to end user Chlorid I/28.1 which have rule-9 e salt permission with MOU.
Proces Collection, s Storage, Ammoni (Produc Transportation & um Bi SCH- 21. t No 0 945 945 Sell to end user Sulphat I/28.1 3.6, which have rule-9 e Salt 3.7) permission with MOU.
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Proces Collection, s Storage,
Liq. (Produc Transportation & SCH- 22. Ammoni t No 0 190 190 Sell to end user I/28.1 a 7.14) & which have rule-9 Scrubb permission with er MOU.
Scrubb Collection, er Storage, Transportation & Sodium SCH- 23. 0 155 155 Sell to end user Sulfite I/28.1 which have rule-9 permission with MOU.
Proces Collection, s Storage,
Copper (Produc Transportation & SCH- 24. Sulphat t No 0 425 425 Sell to end user I/28.1 e Salt 2.17) which have rule-9 permission with MOU.
Proces Collection,
Sodium s Storage, Acetate (Produc Transportation & SCH- 25. (20% t No 0 1750 1750 Sell to end user I/28.1 Solution 2.27) which have rule-9 ) permission with MOU.
Proces Collection, s Storage, distill Spent SCH- 26. 3000 0 3000 inhouse and Solvent I/28.6 reuse in plant premises.
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Proces Collection, s Storage, Transportation & Spent SCH- 27. 0 10 10 Sell to end user Catalyst I/28.0 which have rule-9 permission with MOU.
Proces s Collection, (Produc Storage, Iron SCH- 28. t No. 00 1158 1158 Transportation & Sludge I/28.1 7.1,7.2, Sell to cement 7.3,7.4, industries. 7.5)
ii Membership details of TSDF, Membership of TSDF, CHWIF –M/s.Ecocare CHWIF etc. Infrastructure Private Limited and SEPPL (For HW management) Letter No. ECIPL-1576 dated: 03/12/2019 iii Details of Non-Hazardous No non-Hazardous waste will be generated. waste & its disposal(MSW and others) G Solvent management, VOC emissions etc. Primary Condenser HE-01: Cooling Tower water or Chilled water will be used to condense the solvents depend on the vapor pressure at its operating conditions and the non-condensed vapors will be condensed in a Secondary Condenser Secondary Condenser HE-02: Chilled Brine at - 5 0C will be used to condense the non-condensed vapors in the Secondary Condenser Final venting will be done after passing through carbon column. i Types of solvents, Details of Solvent recovery, % recovery, reuse of recovered Solvents etc. (Details in Table Format)
Sr Name of the Name of Solvent Solvent Percent Loss No. Product Solvent Quantity Recovere age Percenta used in d quantity Recove ge (MT/Month (MT/Month ry
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) ) Group-2 2,4,6-Tri 2.50 1 Chloro EDC 10000 9750 97.50 Aniline 2-Mercapto- 2.00 6- 2 EDC 3750 3625 98.00 Chlorobenzo xazole Ortho / Meta 4.00 / Para 3 Toluene 2000 1920 96.00 Phenylene Diamine 2,6-Di Fluoro Tri Ethyl 2.65 4 1438 1400 97.35 Aniline Amine 1,3,5- Methanol 3950 3780 95.70 4.30 5 Trimethoxyb 4.00 Toluene 2750 2640 96.00 enzene 2-Amino-2- 3.30 6 Phenyl Xylene 2430 2350 96.70 Propane Group-3 4-Bromo 2, 3.00 7 5-Dichloro EDC 840 815 97.00 Phenol 8 Resorcinol MIBK 350 336 96.00 4.00 3,4,5- Toluene 950 910 95.80 4.20 9 Trifluorophe 2.00 IPA 630 617 98.00 nol Group-5 Nitro 2.00 10 EDC 1200 1176 98.00 Benzene 2-Cyano-4- EDC 1000 975 97.50 2.50 11 Nitroaniline MCB 1600 1520 95.0 5.0 Group-7 12 3-Amino 4- ODCB 840 816 97.14 2.86
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Methyl Benzoic Acid Methyl Ester 3,4,5-Tri Methanol 720 690 95.83 4.17 13 Methoxy EDC 660 636 96.36 3.64 14 Benzoic Acid Toluene 1800 1770 98.33 1.67
ii VOC emission sources and its mitigation measures ➢ VOC Control Measures • Vacuum Distillation • Enclosed Processed • Minimum joints/flanges • Adequate Condenser • Brine will be utilized as chilling agent • Pumps with double mechanical seals • Proper Ventilation • PPEs H ➢ Details regarding storage of Hazardous chemicals Storage details Name of major Hazardous chemicals Remarks Storage tanks Benzene, Methanol, Nitric Acid, Sulphuric acid, Acetic Acid, Toluene, MIBK, Thionyl Chloride, EDC, o-Xylene, Carbon Disulphide, DMF (Dimethyl Formamide), Bromine Drum/Barrel storage 3- Nitro -4- Methyl Benzoic Acid, 2- Methyl -5- Nitro Phenol, 4-Chloro Benzoic Acid, m-Dichlorobenzene, 2,5 – Dimethyl Aniline, 2,4 – Dichloro Phenol, Dichloro Nitro Benzene, Phenol Cylinder Chlorine, Hydrogen, Ammonia
➢ Applicability of PESO : Applicable ➢ • During the meeting dated 19/03/2020, the project was appraised based on the information furnished in the EIA Report, CCR obtained from RO – Bhopal and details submitted by PP. • The baseline environmental quality has been assessed for various components of the environment viz. air, noise, water, biological and socioeconomic aspect. The baseline environmental study has
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been conducted for the study area of 10 km radial distance from project site for the October 2018 to December 2018. Ambient Air Quality monitoring was carried out for SPM, PM2.5, PM10, SO2, NOx, O3, Pb, As, Ni, Benzene, CO, HC NH3, HCl, HBr & VOC at eight locations, including the project site. Values conform to the prescribed standards for Ambient Air Quality. The incremental Ground Level Concentration (GLC) has been computed using ISCST – 3. The resultant concentrations are within the NAAQS. • Risk assessment including prediction of the worst-case scenario and maximum credible accident scenarios has been carried out. The detail proposed safeguard measures including On-Site / Off-Site Emergency Plan has been covered in the RA report. • Committee noted that the proposal is for expansion. Unit has valid EC & CC&A for existing plant. Copy of EC and CC&A, its compliance report is submitted. PP ensured that there are no court cases pending and no public complaints against the project. PP submitted details regarding area adequacy. Source of water is GIDC. Committee deliberated on Certified Compliance Report (CCR) of RO – Bhopal for EC granted vide Letter No. SEIAA/GUJ/EC/5(f)/186/2013 dated 18th July, 2013 and noted that out of 62 condition three conditions are complied subject to acceptance by SEIAA, Gujarat and for EC granted vide Letter No. SEIAA/GUJ/EC/5(f)/318/2016 dated 10th May, 2016 out of total 107 condition one condition is complied subject to acceptance by issuing authority, one is complied subject to needful amedmnet in EC by the EC issuing authority and two condition are partly complied. Committee also noted that PP has not submitted any details of Ministry’s Letter No. J- 11011/202/2017-IA.II (I) dated 10/07/2017. Committee noted that PP has submitted fenton treatment for high concentrated stream generated from process followed by in-house MEE, Condensate of MEE will be treated by Soil Biotechnology (SBT) and treated effluent will be discharged into new pipeline of NCT, Jhagadia while concentrate will be treated in ATFD and salt/residue generated will be disposed at approved TSDF while low concentrated stream generated from washing, boiler blow down and cooling tower blow down will be treated in in-house ETP consisting of primary treatment and treated effluent will be subjected to MEE along with concentrated stream and further to SBT and treated effluent will be discharged into new pipeline of NCT, Jhagadia which leads to Marine Discharge in Deep Sea at Kantiyajal. Committee noted PP has not proposed to use any new additional utilities as existing steam boiler and THF has spare steam. Committee noted that PP has not submitted Hazardous Waste details as per HWR – 2016. • After detailed discussion, Committee unanimously decided to call the project proponent for presentation only after satisfactory submission of the following documents. 1. Compliance of Certified Compliance Report obtained from RO – Bhopal for EC vide Letter No. SEIAA/GUJ/EC/5(f)/186/2013 dated 18th July, 2013 for all the conditions which are complied subject to acceptance by SEIAA, Gujarat as on date in tabular form. 2. Compliance of Certified Compliance Report obtained from RO – Bhopal for EC granted vide Letter
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No. SEIAA/GUJ/EC/5(f)/318/2016 dated 10th May, 2016 for all the conditions which are complied subject to acceptance by EC by the EC issuing authority/Compliance of Partly Complied condition/Condition in which compliance is accepted subject to needful amedmnet in EC as on date in tabular form. 3. Clarification on Ministry’s Letter No. J-11011/202/2017-IA.II (I) dated 10/07/2017. 4. Characteristic of Effluent to be treated in Soil Biotechnology (SBT) and with stage wise reduction and Clarification of disposal into new pipeline of NCT, Jhagadia which leads to Marine Discharge in Deep Sea at Kantiyajal mentioning status as on date that is the pipeline operative or not. 5. Justification regarding no additional fuel requirnment along with steam balance mentioning that existing utilities is capable to cater the steam requirnment for the production to be taken in expansion stage. 6. Hazardous Waste Matrix in-line with HWR – 2016 properly addressing its final disposal mode. 7. Addendum to EIA Report incorporating all the above mentioned changes. 4 SIA/GJ/IND2/37268/2019 M/s. Macleods Pharmaceutical Ltd Appraisal Plot No: D-3/27, Dahej-III Notified Industrial area, GIDC Dahej, Tal. Vagra, Dist.: Bharuch, 392140, Gujarat. Category of the unit: 5(f) Project status: New
• Project proponent (PP) submitted online application vide no. SIA/GJ/IND2/37268/2019 dated 16/03/2020 for obtaining Environmental Clearance. • SEIAA issued TOR – Amendment to PP vide their letter dated 04/11/2019. • Project proponent has submitted EIA Report prepared by Eco Chem Sales and Services, Surat based on the TOR issued by SEIAA. • This is a new project for manufacturing of synthetic organic chemical as tabulated below.
S. No. Product CAS Number Qty (TPM) End Use A. API Bulk Drugs -- 60 (Either of the products) Used in 1. Valaciclovir 124832-27-5 pharmaceutical formulation like anti- 2. Famciclovir 104227-87-4 Tuberculosis, anti-bacterial, anti- 3. Levofloxacin 138199-71-0 hypertensive, anti-inflammatory, anti- 4. Quetiapine 111974-72-2 psychotic, anti-thyroid and antibiotic etc. 5. Irbesartan 138402-11-6 as per requirement. 6. Valsartan 2462–34-2 7. Valganciclovir 175865-59-5
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Fosfomycin 8. 78964-85-9 Trometamole 9. Indomethacin 53-86-1 10. Doxofylline 69975-86-6 11. Eperisone HCl 56839-43-1 Olmesartan 12. 144689-63-4 Medoximil 13. Ranolazine HCl 95635-56-6 14. Efavirenz 154598-52-4 15. Oxaprozin 21256-18-8 16. Actarit 18699-02-0 17. Granisetron 107007-99-8 18. Ethionamide 536-33-4 19. Prothionamide 14222-60-7 20. Rebamipide 90098-04-7 21. Levodropropazine 99291-25-5 22. Erdosteine 84611-23-4 23. Tiropramide 53567-47-8 24. Epalrestat 82159-09-9 25. Pyrazinamide 98-96-4 26. Rifampicin 13292-46-1 27. Rifapentine 61379-65-5 28. Ethambutol 74-55-5 29. Repaglinide 135062-02-1 30. Atorvastatin 134523-03-8 31. Donepezil 134523-03-8 32. Pantoprazole 138786-67-1 33. Olanzapine 132539-06-1 34. Pioglitazone 112529-15-4 35. Pramipexole 104632-25-9 36. Escitalopram 219861-08-2 37. Sildenafil 171599-83-0 38. Clopidogrel 120202-66-6 39. Risedronate 105462-24-6 40. Esomeprazole 217087-09-7
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41. Moxifloxacin 120202-66-6 42. Telmisartan 144701-48-4 43. Linezolid 165800-03-3 44. Rosuvastatin 147098-20-2 45. Pazufloxacin 163680-77-1 46. Voriconazole 137234-62-9 Tenofovir Disoproxil 47. 147127-20-6 Fumarate 48. D-cycloserine 68-41-7 49. Etizolam 40054-69-1 50. Gemifloxacin 175463-14-6 51. Amlexanox 68302-57-8 52. Eplerenone 107724-20-9 53. Amtolmetin 87344-06-7 54. Ozagrel 82571-53-7 55. Sitafloxacin 127254-12-0 56. Pimobendent 74150-27-9 57. Trimabutine maleate 34140-59-5 58. Levothyroxin 51-48-9 59. Torasemide 56211-40-6 60. Tolterodine 124937-52-6 61. Rabeprazole 117976-90-6 62. Eszopiclone 138729-47-2 63. Emtricitabine 143491-57-0 64. Lopinavir 192725-17-0 65. Ritonavir 155213-67-5 66. Aripiprazole 129722-12-9 67. Duloxetine HCl 136434-34-9 68. Zolmetriptan 139264-17-8 69. Sevelamer HCl 152751-57-0 70. Entacapone 130929-57-6 71. Deflazacort 14484-47-0 72. Pregabaline 148553-50-8 73. Tenatoprazole 113712-98-4 74. Tadalafil 171596-29-5
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75. Cinacalcet 226256-56-0 76. Roflumilast 162401-32-3 77. Efonidipine 111011-76-8 78. Alvimopan 1217616-62-0 79. Montelukast 158966-92-8 80. Eberconazole 128326-82-9 81. Conivaptan 168626-94-6 82. Candesartan 139481-59-7 83. Dolasetron 115956-12-2 84. Rizatriptan 145202-66-0 85. Rivastigmine 123441-03-2 86. Milanosepran 101152-94-7 87. Tranexanic Acid 1197-18-8 88. Propyl Thio uracyl 51-52-5 89. Fobuxostat 144060-53-7 90. Moxonidine 75438-57-2 91. Ziprasidone 146939-27-7 92. Memantine 19982-08-2 93. Oseltamivir 196618-13-0 94. Prasugrel 150322-43-3 95. Sitagliptin 486460-32-6 96. Ramelteon 196597-26-9 97. Ruboxi Staurine 246852-12-0 98. Sertaconazole 99592-39-9 99. Levosimendan 141505-33-1 100. Posaconazole 171228-49-2 101. Vardenafil 224785-90-4 102. Solifinacin succinate 242478-38-2 103. Mesalamine 89-57-6 104. Lansoprazole 103577-45-3 105. Ezetimibe 163222-33-1 106. Eslicarbazepine 236395-14-5 107. Frovatriptan 158930-17-7 108. Rasagiline Mesylate 161735-79-1 109. Rifabutin 72559-06-9
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110. Vildagliptin 274901-16-5 Propafenone 111. 34183-22-7 Hydrochloride 112. Eletriptan 143322-58-1 113. Zolpidem Tartrate 99294-93-6 Levocetrizine 114. 130018-77-8 Hydrochloride 115. Paliparidone 144598-75-4 Darifenacin 116. 133099-07-7 Hydrobromide Darunavir 117. 635728-49-3 Ethanolate 118. Desvenlafaxine 386750-22-7 119. Dexlansoprazole 138530-94-6 120. Dronedarone 141626-36-0 121. Dydrogesterone 152-62-5 122. Riluzole 1744-22-5 123. Atazamavir 229975-97-7 124. Adefovir 142340-99-6 125. Rilpivirine 500287-72-9 126. Trospilem 10405-02-4 127. Ibandrosate 114084-78-5 128. Dutasteride 164656-23-9 129. Diacerein 13739-02-1 Carvedil Oil 130. 610309-89-2 phosphate 131. Di Pyridamole 58-32-2 132. Cilnidipine 132203-70-4 133. Ilaprazole 172152-36-2 134. Lacosamide 175481-36-4 135. Levetiracetam 102767-28-2 136. Azelnidipine 123524-52-7 137. Terizidone 25683-71-0 138. Entecavir 142217-69-4 139. Celecoxib 169590-42-5
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140. Nebivolol 99200-09-6 141. Methimazole 60-56-6 142. Carbimazole 22232-54-8 143. Nitrofurantoin 67-20-9 144. Hydralazine 304-20-1 145. Atomoxetine 82248-59-7 Amino Salicylate 146. 6018-19-5 Sodium Dihydrate 147. Raloxafine 82640-04-8 148. Sofosbuvir 1190307-88-0 149. Ledipasvir 1256388-51-8 150. Dolutegravir 1051375-19-9 151. Dimethyl Fumarate 624-49-7 152. Bedaquillin 843663-66-1 153. Pretomanid 187235-37-6 154. Delamanid 681492-22-8 155. Artimether 71963-77-4 156. Deferaserox 201530-41-8 157. Vilazadone 163521-08-2 158. Perphenazine 58-39-9 159. Dabigatran 872728-81-9 Tenofovir 160. Alafenamide 1392275-56-7 Fumarate 161. Silodosin 160970-54-7 162. Dapagliflozin 461432-26-8 163. Canagliflozin 842133-18-0 164. Empagliflozin 864070-44-0 165. Lurasidone 367514-88-3 166. Gaunfacine 29110-48-3 167. Felbamate 25451-15-4 168. Fingolimod 162359-56-0 169. Simeprevir 1241946-89-3 170. Labetalol 32780-64-6 171. Liothyronine 6893-02-3
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172. Ursodiol 128-13-2 173. Dapsone 80-08-0 174. Chlorthalidone 77-36-1 175. Saxagliptin 361442-04-8 176. Eptifibatide 188627-80-7 177. Exenatide 141732-76-5 178. Glatiramer Acetate 147245-92-9 179. Bivalrudin 128270-60-0 180. Efonidipine 111011-63-3 181. Linagliptin 668270-12-0 182. Rivaroxaban 366789-02-8 183. Dexlansoprazole 313640-86-7 184. Edoxaban 480449-70-5 185. Brexpiprazole 913611-97-9 186. Lesinurad 1533519-93-5 Daclatasvir 187. 1009119-65-6 dihydrochloride 188. Vorapaxar Sulfate 705260-08-8 189. Teneligliptinl 760937-92-6 190. Praziquantel 55268-74-1 191. Albendazole 54965-21-8 192. Vortioretine 508233-74-7 193. Luliconazole 187164-19-8 194. Efinaconazole 164650-44-6 Sucroferricoxy 195. 8047-67-4 hydroxide 196. Lumefantrine 82186-77-4 197. Sulfadoxine 2447-57-6 198. Velpatasavir 1377049-84-7 Prasugre 199. 389574-19-0 Hydrobromide 200. Apremilast 608141-41-9 201. Pyrimethamine 58-14-0 Formulation of API 30 Crore B. --- Bulk Drugs (Tablets Nos./M
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& Capsules ) • The project falls under Category B of project activity 5(f) as per the schedule of EIA Notification 2006. • The presentation was considred in the meeting dated 19/03/2020 as per the submission by PP via E- mail dated 18/03/2020. • Salient features of the project are as under: Sr. Particulars Details no. A A Total cost of Proposed Project Rs. 89.25 Crores (Rs. in Crores):
B Total Plot area ( sq. meter) 169858.53 sq. meter Green belt area ( sq. meter) 56053 Sq. m. C Employment generation 270 Nos. D Water i Source of Water Supply 840 KLD (GIDC Bore well, Surface water, Tanker supply etc...) Source: GIDC Water Supply Department Status of permission from the concern authority. Permission Letter received with Letter No. GIDC/DEE(WS)/BRH/907 ii Water consumption (KLD) Quantity Category Remarks KLD (G) Domestic 50.0 (H) Gardening 40.0 (I) Industrial Process 300.0 Product Washing 135.0 Boiler 185.0 Cooling 100.0 Container / Floor Washing 5.0 Scrubber 5.0 Others 20.0 RO Plant (For formulation plant)
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for equipment of formulation plant Industrial Total 750.0 Total (A + B + C) 840
1) Total water requirement for the project: 840 KLD 2) Quantity to be recycled: 104.0 KLD 3) Total Fresh Water requirement: 736 KLD (Total water requirement = Fresh water + Recycled water) iii Waste water generation (KLD) Quantity Category Remarks KLD (A) Domestic 40.0 Utilise for gardening/sanitation (B) Industrial Process 264.0 59: Solvent stripper/MEE , 205 : ETP Product washing 120.0 ETP Cooling Water Blowdown 15.0 RO/Recycle Boiler Blowdown 60.0 RO/Recycle Container / Floor Washing / ETP 10.0 Scrubber RO Rejection 5.0 MEE/ETP Washing of equipment of ETP 15.0 Formulation plant Industrial Total 489.0 Total (A + B ) 529.0
iv Treatment facility within premises with capacity [In-house ETP (Primary, Secondary, Tertiary), MEE, Stripper, Spray Dryer, STP etc. ➢ In-house waste water treatment facilities consisting of primary, secondary and tertiary ETP, solvent stripper, MEE, ATFD and RO plant ➢ ETP: 500 m3/day ➢ Solvent stripper: 100 m3/day ➢ MEE: 150 m3/day ➢ ATFD: 10 m3/hr. ➢ RO plant: 75 m3/day ❖ 403.4 KLD of Effluent from Scrubber (5.0 KLD), Processing (205.0 KLD), Product Washing (120.0 KLD), Floor Container Washing (5.0 KLD), Equipment Washing (15.0
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KLD) , RO Reject (5.0 KLD) ,MEE Condensate (48.4 KLD) will be treated in Primary, Secondary and Tertiary ETP and treated effluent will be discharged to CETP through closed underground pipeline and disposed into Arabian sea. ❖ 59.0 KLD of Effluent from Processing will be treated in Solvent Stripper follower by MEE for High TDS Stream (45.3 KLD) and rest 13.7 KLD of High COD will be sent to RSPL for Co-processing. Note: (In case of CETP discharge) : Management of waste water keeping in view direction under section 18 (1) (b) of the Water (Prevention and Control of Pollution) act, 1974 issued by CPCB regarding compliance of CETP.
➢ 403.4 KLD of Effluent from Scrubber (5.0 KLD), Processing (205.0 KLD), Product Washing (120.0 KLD), Floor Container Washing (5.0 KLD), Equipment Washing (15.0 KLD) , RO Reject (5.0 KLD) ,MEE Condensate (48.4 KLD) will be treated in Primary, Secondary and Tertiary ETP and treated effluent will be discharged to CETP through closed underground pipeline and disposed into Arabian sea. Brief note on adequacy of ZLD (In case of Zero Liquid Discharge):
➢ Not applicable. v Mode of Disposal & Final meeting point: Zero liquid discharge Domestic: Sewage treatment plant (treated domestic waste water will used for gardening/toilet flushing. Industrial: ➢ Total 403.4 KLD of Effluent from Scrubber (5.0 KLD), Processing (205.0 KLD), Product Washing (120.0 KLD), Floor Container Washing (5.0 KLD), Equipment Washing (15.0 KLD) , RO Reject (5.0 KLD) ,MEE Condensate (48.4 KLD) will be treated in Primary, Secondary and Tertiary ETP and treated effluent will be discharged to CETP through closed underground pipeline and disposed into Arabian sea. ➢ 59.0 KLD of Effluent from Processing will be treated in Solvent Stripper follower by MEE for High TDS Stream (45.3 KLD) and rest 13.7 KLD of High COD will be sent to RSPL for Co-processing. Thus there will be no additional discharge into CETP and will comply the 18(1) b Condition issued by CPCB. vi In case of Common facility (CF) like CETP, Common Spray dryer, Common MEE etc. Name of CF ➢ CETP will be used as an common facility. Membership of Common facility (CF)
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(For waste water treatment) CETP Discharge Membership vide GIDC/BRH/DEE/(ORG)/54 dated 28/01/2019 vii Simplified water balance diagram with reuse / recycle of waste water
viii Reuse/Recycle details (KLD) Total reuse 104 KLD Remarks regarding feasibility Source of waste water for Application area with quantity to reuse i.e. w/w reuse with quantity in in KLD characteristics (COD, BOD, KLD TDS etc.) COD: 100-150 mg/l RO Permeate Processing: 64 BOD: 40-50 mg/l 64 KLD KLD TDS: 80-100 mg/l BOD: <20 mg/l Gardening - 40 STP- 40 KLD TSS:<30 mg/l KLD Residual Chorine:>0.5 mg/l
E Air i Flue gas emission details No. of Boilers/TFH/Furnaces/DG sets etc. with capacities viz. TPH, Kcal/hr, MT/hr, KVA etc. Source of Stack Quantity Type of Air Pollution Sr. emission Height Type of Fuel of Fuel emissions Control no. With Capacity (meter) MT/Day i.e. Air Measures
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Pollutants (APCM)
Boiler (1 No) Imported ESP followed 1. (Capacity: 6 30 coal/Briquette 15 by Wet TPH) s scrubber Boiler (1 No) Imported ESP followed 2. (Capacity: 8 30 coal/Briquette 25 by Wet TPH) s scrubber Boiler (1 No) Imported ESP followed 3. (Capacity: 10 30 coal/Briquette 35 by Wet TPH) s scrubber Boiler:I 4. (Capacity 850 kg/hr), 30 Adequate Boiler:II meters Stack Height 5. (Capacity 850 commo as per kg/hr), n Furnace Oil formula Boiler:III chimney PM 6. (Capacity 850 *All FO fired SOx kg/hr), 6 Numbers 4.8 NOx Boiler:IV steam 7. (Capacity 850 boilers will kg/hr), 30 be kept as a Adequate Boiler:V meters standby Stack Height 8. (Capacity 1250 commo as per kg/hr), n formula Boiler: VI chimney 9. (Capacity: 2 TPH) D G
10. set (1010 KVA 11 HSD Adequate x 1 ) Stack Height D G Set (1250 *will be kept 3.9 as per 11. 11 KVA x 2) as a Stand formula D G set (320 by. - 12. 11 KVA x 1)
613th meeting of SEAC-Gujarat, dated 19.03.2020 Page 71 of 217 ii Process gas emission details i.e. Type of pollutant gases (SO2, HCl, NH3, Cl2, NOx etc.) Specific Source of emission Stack/Vent Air Pollution Control Sr. Type of (Name of the Height Measures no. emission Product & (meter) (APCM) Process) Vent attached to 26 Two stage water Reactors at HCl 1. 11 followed by alkali Scrubber Block A- SO2 scrubber 01 Vent attached to 09 Two stage water Reactors at HCl 2. 11 followed by alkali Scrubber Block B- Br2 scrubber 01 Vent attached to 18 Two stage water Reactors at HCl 3. 11 followed by alkali Scrubber Block C- Br2 scrubber 01 Vent attached to 16 HCl Two stage water Reactors at 4. SO2 11 followed by alkali Scrubber Block D- H2S scrubber 01 Vent attached to 9 SO2 Two stage water Centrifuge at 5. H2S 11 followed by alkali Scrubber Block E- Br2 scrubber 01 Vent attached to 14 HCL Two stage water Reactors at 6. H2S 11 followed by alkali Scrubber Block E- Br2 scrubber 02 Vent attached to 14 HCl Two stage water Receiver (tanks) at SO2 7. 11 followed by alkali Scrubber Block E- H2S scrubber 03 Br2 Vent attached to 15 HCl Two stage water 8. 11 Reactors at SO2 followed by alkali
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Scrubber Block G- Br2 scrubber 01
Vent attached to 10 HCl Two stage water Reactors at 9. SO2 11 followed by alkali Scrubber Block G- Br2 scrubber 02 Vent attached to 14 HCl Two stage water Reactors at 10. SO2 11 followed by alkali Scrubber Block G- Br2 scrubber 03 Vent attached to Two stage water Vibro shifter & Multi 11. PM 11 followed by alkali mill at formulation scrubber block-01
iii Fugitive emission details with its mitigation measures: As below: • Concrete road will be developed within plot premises to avoid fugitive dust due to vehicle movement. • Manufacturing activity will be carried out in closed reactors/vessels and regular checking and maintenance of the same will be carried out to avoid any leakages. • All the raw materials will be stored in closed containers and in sealed bags and will be handled through closed system to avoid the handling losses. • Water Sprinkling will be done to avoid dust emission.
F Hazardous wastes (as per the Hazardous and Other Wastes (Management and Transboundary Movement) Rules 2016. i Sr. Type/Name of Specific Category Quantity Management of HW no. Hazardous Source of and TPM waste generation Schedule (Name of the as per HW Activity, Rules. Product etc.) (Sch: Collection, Storage, 1 ETP waste ETP 750.0 I/35.3) transportation and
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dispose off into TSDF of BEIL, Dahej Collection, Storage, Machineries & 2 Used Oil (Sch: I/5.1) 5.0 transportation and sell to DG Set registered recycler Raw Material Collection, Storage, Discarded (Sch: 3 Storage & 50.0 transportation and Sell Containers I/33.1) Utility Area to authorized recycler Collection, Storage, transportation and sell to authorized recycler Manufacturing (Sch: 4 Spent Solvent 9612.0 having permission under Process I/28.6) Rule 9 for distillation or distillate in our own solvent distillation plant. Will be Sent to M/S Manufacturing (Sch: 5 Spent catalyst 137.5 RSPL, Panoli for co- Process I/28.2) processing Will be Sent to M/S Manufacturing (Sch: 6 Spent Carbon 250.0 RSPL, Panoli for co- Process I/28.3) processing Process Will be Sent to M/S Manufacturing (Sch: 7 Residue & 1002.0 RSPL, Panoli for co- Process I/28.1) Waste processing Will be Sent to M/S Off specification Manufacturing (Sch: 8 10.0 RSPL, Panoli for co- products Process I/28.4) processing Will be Sent to M/S Date expired (Sch: 9 Products 10.0 RSPL, Panoli for co- products I/28.5) processing Spent mother Will be Sent to M/S liquor (High Manufacturing (Sch: RSPL, Panoli for co- 10 4932.0 COD) from Process I/28.1) processing process Sludge from wet (Sch: Will be disposed off into 11 Scrubber 1560.0 scrubber (bleed I/37.1) ETP & RO plant
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liquor) Collection, Storage, Waste (salt) (Sch: transportation and 12 MEE 2465.0 from MEE I/37.3) dispose off into TSDF of BEIL, Dahej Will be Sent to M/S Distilation Solvent 13 (Sch:I/36.1) 668 RSPL, Panoli for co- residue distillation processing
ii Membership details of TSDF, CHWIF etc. TSDF of BEIL Ankleshwar. (For HW management) iii Details of Non-Hazardous waste & its disposal ➢ Fly Ash: 2246 TPA Disposal: (MSW and others) Sell to brick manufacturer/cement industries. ➢ 700 TPA of STP Sludge will be used as a manure in own premises. G Solvent management, VOC emissions etc. i Types of solvents, Details of Solvent recovery, % recovery, reuse of recovered Solvents etc. (Details in Table Format) Solvent, MT/Month of product S. Product Consumptio % No. Solvent Recovery Loss n Recovery Chloroform 171.00 162.45 8.55 95.00 Iso-propyl ether 240.00 235.20 4.8 98.00 Di isopropyl amine 147.60 143.17 4.43 97.00 Aceto nitrile 180.00 172.80 7.2 96.00 Tolterodin 1. Acetone 30.00 29.40 0.6 98.00 e Methylene 42.00 40.72 1.28 96.95 dichloride Ethanol 18.00 17.40 0.6 96.67 Total 828.60 801.14 27.46 -- Note: Overall recovery of solvent will be 96.6% The solvents will be recovered by solvent extraction in-house and reused in the manufacturing process.
613th meeting of SEAC-Gujarat, dated 19.03.2020 Page 75 of 217 ii VOC emission sources and its mitigation measures Source: • Process Reactor. • Raw Material Handling & Storage. Mitigation Measures: • The raw materials will be stored in closed containers and will be handled through closed system to avoid the handling losses • Reactor and solvent handling pumps will have mechanical seals to prevent leakages. Reactors shall also be provided with breather valve to prevent losses. H Details regarding storage of Hazardous chemicals
Storage details Name of major Hazardous chemicals Remarks • Under Ground • Toluene --- storage tank • HDPE Carboys • N- Hexane • Benzene --- • Hydrogen gas • HDPE Drums • Xylene --- • Cylinder • Ammonia --- • Glass bottle • Bromine ---
• Applicability of PESO : NA • During the meeting dated 19/03/2020, the project was appraised based on the information furnished in the EIA Report and details submitted by PP. • The baseline environmental quality has been assessed for various components of the environment viz. air, noise, water, biological and socioeconomic aspect for the study area of 10 km radial distance from project site for the period December 2018 to Febuary 2019. Ambient Air Quality monitoring was carried out for PM10, PM2.5, SOx, NOx, CO, H2S, HCl & Br2 at eight locations, including the project site. Values conform to the prescribed standards for Ambient Air Quality. The incremental Ground Level Concentration (GLC) has been computed using ISCST – 3. The resultant concentrations are within the NAAQS. The modeling study proved that the air emissions from the proposed plant would not affect the ambient air quality of the region in any significant manner. The ambient air quality around the proposed project site will remain within the National Ambient Air Quality Standards (NAAQS). • Risk assessment including prediction of the worst-case scenario and maximum credible accident scenarios has been carried out. The detail proposed safeguard measures including On-Site / Off-Site 613th meeting of SEAC-Gujarat, dated 19.03.2020 Page 76 of 217
Emergency Plan has been covered in the RA report. • Committee noted that proposal is new in GIDC Dahej. Source of water is GIDC. PP submitted that high COD/TDS effluent generated from process will be segregated and treated in solvent stripper and stripped effluent having high COD will be sent to RSPL for co-processing while stripped effluent having high TDS will be subjected to in-house MEE, Condensate of MEE will be treated in in-house ETP while concentrate will be treated in ATFD and generated salt/residue will be disposed at approved TSDF, while low CODTDS effluent generated from process washing, product washing, equipnment washing, container washing, scrubber and RO – Reject from RO plant will be treated in in-house ETP consisting of primary, secondary & tertiary treatment and treated effluent will be sent to CETP of Dahej via underground pipeline for disposal into deep sea. PP submitted that they have proposed nine steam boiler and one TFH. Fuel used in three steam boiler will be Briquettes/Imported Coal while in rest of the boiler it will be FO. Committee noted that PP has not submitted Hazardous Matrix as per HWR – 2016. Committee noted that PP has not submitted LDAR and its mitigation measures as per compliance of ToR. • After detailed discussion, Committee unanimously decided to consider the project only after submission of the following documents. 1. Characteristic of effluent to be treated in solvent stripper, segregation method to separate high COD & high TDS effluent after passing through solvent stripper and characteristic of effluent to be sent to RSPL for co-processing and effluent to be treated in in-house MEE along with effluent to be treated in in-house ETP along with stage wise reduction of pollutants. 2. Compliance of GPCB Notification dated 12th December, 2019 regarding deletation of FO as Fuel from the approved Fuel List. 3. Leak Detection and Repairing Programme (LDAR) for all the volatile organic solvent proposed for use in-house with detailed chemical properties including vapor pressure. LDAR shall endeavor prevention of losses of solvents to the best minimum extent. 4. Saftey Precautions for all the hazardous chemicals to be used covering loading, unloading, transportation, storage, handling and process safety. 5. Hazardous Waste Matrix in-line with HWR – 2016 properly addressing source of generation and mode of disposal. 6. Quantity wise bifurcation of Spent Solvent to be done distillation in-house to be sold under Rule – 9 as per HWR – 2016. 7. Revised EMP with Fixed Capital Cost and Recurring Cost. 8. Adendum to EIA Report incorporating all the above mentioned changes. 5 SIA/GJ/IND2/51928/2019 M/s. Medikament Pharma Appraisal Plot No – C/368, GIDC – Sayakha, Dist: Bharuch, Gujarat, India.
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Category of the unit: 5(f) Project status: New
• Project proponent (PP) submitted online application vide no. SIA/GJ/IND2/36037/2019 dated 16/03/2020 for obtaining Environmental Clearance. • SEIAA issued TOR to PP vide their letter dated 05/12/2020. • Project proponent has submitted EIA Report prepared by Environ, Ahmedabad based on the TOR issued by SEIAA. • This is new project for manufacturing of synthetic organic chemical as tabulated below. Quantity CAS no. /CI Sr. No Name of the Products (MT/Mont End-use of the products no. h)
Group 1
2 Bromo 4-5- Dimethoxy Pharma Intermediates 1. 53207-00-4 Benzyl Bromide AND/OR
2-(Diethylamino)ethyl Amiodarone, Bietaserpine, Chloride Hydrochloride Butetamate, Camylofin, AND/OR Ciclonium bromide, Clomifene, Cloricromen, DEA Dextran, Dimazole, Etafenone, Etamiphylline, Fenoxedil, Flurazepam, Gallamine triethiodine, Imolamine, Isothipendyl, 2. 869-24-9 40.00 Methadone, Myrtecaine, Naftidrofuryl, Oxitefonium bromide, Penthienate methobromide, Phenglutarimide, Promethazine, Propoxycaine, Proxymetacaine, Tiamulin, Tibezonium iodide, Tiropramide
2,3,4 Bis -o-(1 methyl)-B-D- Topiramate 3. N/A Fructopyranose AND/OR
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2-Methyl-4,5- Fragrance Intermediate 4. Dimethoxybenzoic Acid N/A AND/OR
5. 3-Methoxy Phenol AND/OR 150-19-6 Aroma chemical
4-Iso Propyl Catechol Perfumery agent 6. 2138-43-4 AND/OR
4-Methyl Cathechol Diacetic Fragrance Intermediate 7. Acid Dimethyl Ester 52589-39-6 AND/OR
8. 6 chloro hexanol AND/OR 2009-83-8 Aroma Chemical
6-Chloro-5(2-Chlor Ethyl) Ziprasidone 9. 118289-55-7 Oxindole AND/OR
Benzaldehyde Dimethyl Flavor and Compounds 10. 1125-88-8 Acetal AND/OR
Bis(2-chloroethyl)amine Aripiprazole, Batoprazine, hydrochloride AND/OR Cyclophosphamide, Eltoprazine hydrochloride, 11. 821-48-7 Estramustine phosphate, Ifosfamide, Itraconazole, Ketoconazole, Lensiprazine, Naluzotan, Trazodone
Cetyl Pyridinium Chloride This is mainly used in AND/OR mouthwashes, toothpastes, lozenges, throat 12. 123-03-5 sprays, Breathe sprays, antiseptic towels, and nasal sprays.
13. Lasamide AND/OR 2736-23-4 Furosemide
N,N Dimethyl Form amide Imatinib,itraconazole 14. 4637-24-5 Diemthyl Acetal AND/OR
15. Sesamol AND/OR 533-31-3 Paroxetine
2-Diethylaminoethanethiol Desvenlafaxine 16. 1942-52-5 AND/OR
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Guanidine AND/OR sulfamethyldiazine, 17. 50-01-1 sulfamethazine and folic acid intermediates
Analgesic
Dimethyl fumarate And/Or Analgesic 18. 624-49-7 its intermediates AND/OR
Etodolac And/Or its 41340-36-7 Analgesic 19. intermediates AND/OR /12188-02-7
Iguratimod And/Or its Analgesic 20. 149436-41-9 intermediates AND/OR
Naproxen And/Or its Analgesic 21. 3900-45-6 intermediates AND/OR
Pregabalin And/Or its 75143-89-4 Analgesic 22. intermediates AND/OR /181289-15-6
Anti Prostatic
Naftopidil And/Or its AntiProstatic 23. 5464-78-8 intermediates AND/OR
AntiArrhythmias
Ivabradine Hcl And/Or its AntiArrhythmias 24. 148870-57-9 intermediates AND/OR
AntiAsthmatic
Doxofylline And/Or its AntiAsthmatic 25. 7252-83-7 intermediates AND/OR
AntiBiotic
Amoxicillin And/Or its Antibiotic 26. 551-16-6 intermediates AND/OR
Chloramphenicol And/Or its Antibiotic 27. 56-75-7 intermediates AND/OR
Doxycycline And/Or its Antibiotic 28. 24390-14-5 intermediates AND/OR
Erythromycin And/Or its Antibiotic 29. 114-07-8 intermediates AND/OR
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Metronidazole And/Or its Antibiotic 30. 443-48-1 intermediates AND/OR
Trimethoprim And/Or its Antibiotic 31. 738-70-5 intermediates AND/OR
AntiCoagulant
Dabigatran And/Or its AntiCoagulant 32. 212322-56-0 intermediates AND/OR
Rivaroxaban And/Or its 898543-06-1 / AntiCoagulant 33. intermediates AND/OR 446292-08-6
Warfarin And/Or its AntiCoagulant 34. 81-81-2 intermediates AND/OR
AntiConvulsants
Carbamazepine And/Or its AntiConvulsants 35. 298-46-4 intermediates AND/OR
Levetiracetam And/Or its AntiConvulsants 36. 7682-20-4 intermediates AND/OR
Topiramate And/Or its AntiConvulsants 37. 106881-35-0 intermediates AND/OR
AntiDepressant
Desvenlafexine And/Or its AntiDepressant 38. 93413-61-7 intermediates AND/OR
Venlafaxine hydrochloride AntiDepressant 39. And/Or its intermediates 93413-76-4 AND/OR
AntiDiabetic
Gliclazide And/Or its AntiDiabetic 40. 58108-05-7 intermediates AND/OR
Glipizide And/Or its AntiDiabetic 41. 5521-55-1 intermediates AND/OR
Metformin Hydrochloride AntiDiabetic 42. And/Or its intermediates 1115-70-4 AND/OR
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Saxagliptin And/Or its AntiDiabetic 43. 361440-67-7 intermediates AND/OR
Sitagliptin And/Or its AntiDiabetic 44. 762240-14-6 intermediates AND/OR
Voglibose And/Or its AntiDiabetic 45. 83480-29-9 intermediates AND/OR
AntiHypertensive AntiDiabetic
Diltiazem hydrochloride AntiDiabetic 46. And/Or its intermediates 42399-49-5 AND/OR
Irbesartan And/Or its AntiDiabetic 47. 138401-24-8 intermediates AND/OR
Metoprolol Succinate AntiDiabetic 48. And/Or its intermediates 56718-70-8 AND/OR
Perindopril And/Or its AntiDiabetic 49. 82834-12-6 intermediates AND/OR
Valsartan And/Or its AntiDiabetic 50. 482577-59-3 intermediates AND/OR
AntiLipemic
Fenofibrate And/Or its AntiLipemic 51. 42017-89-0 intermediates AND/OR
AntiPsychotic AntiLipemic
Aripiprazole And/Or its AntiLipemic 52. 119532-26-2 intermediates AND/OR
Clozapine And/Or its AntiLipemic 53. 5786-21-0 intermediates AND/OR
Escitalopram oxalate And/Or AntiLipemic 54. 717133-25-0 its intermediates AND/OR
Olanzapine And/Or its AntiLipemic 55. 138564-60-0 intermediates AND/OR
Erectile Dysfunction
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Sildenafil Citrate And/Or its Erectile Dysfunction 56. 139756-21-1 intermediates AND/OR
Proton Pump Inhibitors
Esomeprazole magnesium Proton Pump Inhibitors 57. And/Or its intermediates 73590-85-9 AND/OR
Lansoprazole And/Or its Proton Pump Inhibitors 58. 127337-60-4 intermediates AND/OR
SSRIs
Citalopram And/Or its SSRIs 59. 103146-26-5 intermediates AND/OR
Paroxetine HCl Hemihydrate SSRIs 60. And/Or its intermediates 105812-81-5 AND/OR
Sertraline And/Or its SSRIs 61. 79617-89-3 intermediates
Group 2
AntiMuscarinics
62. Tiotropium Bromide And/Or AntiMuscarinics 85700-55-6 its intermediates AND/OR
AntiOsteoporotic
63. Alendronate sodium And/Or AntiOsteoporotic 121268-17-5 its intermediates AND/OR
AntiRetroviral
64. Darunavir And/Or its AntiRetroviral 169280-56-2 10.00 intermediates AND/OR
65. Zidovudine And/Or its AntiRetroviral 25442-42-6 intermediates AND/OR
AntiVirals
66. Valacyclovir hydrochloride AntiVirals And/Or its intermediates 124832-31-1 AND/OR
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Benzodiazepines
67. Diazepam And/Or its Benzodiazepines 439-14-5 intermediates AND/OR
Chelating Agent
68. Deferasirox And/Or its Chelating Agent 1218-69-5 intermediates AND/OR
Corticosteroids
69. Prednisolone sodium Corticosteroids phosphate And/Or its 50-24-8 intermediates AND/OR
Hyperuricemia
70. Febuxostat And/Or its Hyperuricemia 160844-75-7 intermediates AND/OR
Immunosuppressant
71. Mycophenolate Mofetill Immunosuppressant And/Or its intermediates 128794-94-5 AND/OR
Iron Deficiency
72. Iron Sucrose Complex Iron Deficiency And/Or its intermediates 8047-67-4 AND/OR
Leukotriene Receptor
Antagonist
73. Montelukast Sodium And/Or Leukotriene Receptor 142569-70-8 its intermediates AND/OR Antagonist
Overactive Bladder
74. Solifenacin And/Or its Overactive Bladder 118864-75-8 intermediates AND/OR
Rheumatoid Arthritis
75. Baricitinib And/Or its Rheumatoid Arthritis 1187595-85-2 intermediates AND/OR
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Vasoconstrictor
76. Phenylephrine And/Or its Vasoconstrictor 61-76-7 intermediates AND/OR
Vitamins
77. Folic acid And/Or its Vitamins 35011-47-3 intermediates AND/OR
78. Methylcobalamin And/Or its Vitamins 13422-55-4 intermediates AND/OR
79. (+_)3-(Carbamoyl methyl)-5- Pregabaline Intermediate 181289-33-8 methyl hexanoic acid
Group 3
Alzheimer's Disease
80. Memantine HCL And/Or its Alzheimer's Disease 941-37-7 intermediates AND/OR
Analgesic
81. Etoricoxib And/Or its Analgesic 221615-75-4 intermediates AND/OR
82. Flurbiprofen And/Or its Analgesic 5104-49-4 intermediates AND/OR
83. Gabapentin And/Or its Analgesic 64744-50-9 intermediates AND/OR
84. Lidocaine HCL And/Or its 5.00 Analgesic 1131-01-7 intermediates AND/OR
AntiArrhythmias
85. Amiodarone And/Or its AntiArrhythmias 19774-82-4 intermediates AND/OR
AntiArthritis
86. Apremilast And/Or its AntiArthritis 608141-41-9 intermediates AND/OR
AntiAsthmatic
87. Salbutamol And/Or its 16475-90-4 AntiAsthmatic
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intermediates AND/OR
AntiBiotic
88. Ciprofloxacin HCL And/Or AntiBiotic 85721-33-1 its intermediates AND/OR
AntiDiabetic
89. Teneligliptin And/Or its AntiDiabetic 401566-79-8 intermediates AND/OR
AntiFungals
90. Fluconazole And/Or its AntiFungals 86404-63-9 intermediates AND/OR
91. ketoconazole And/Or its AntiFungals 67914-60-7 intermediates AND/OR
AntiHistaminic
92. Desloratidine And/Or its AntiHistaminic 31255-55-7 intermediates AND/OR
93. Levocetirizine AntiHistaminic dihydrochloride And/Or its 42137-88-2 intermediates AND/OR
AntiHypertensive
94. Bisoprolol And/Or its AntiHypertensive 177034-57-0 intermediates AND/OR
95. Ramipril And/Or its AntiHypertensive 93779-29-4 intermediates AND/OR
96. Rosuvastatin Calcium AntiHypertensive And/Or its intermediates 147118-37-4 AND/OR
AntiLipemic
97. Niacin And/Or its AntiLipemic 59-67-6 intermediates AND/OR
98. Simvastatin And/Or its AntiLipemic 5856-77-9 intermediates AND/OR
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AntiPsychotic
99. Quetiapine And/Or its AntiPsychotic 07-07-3159 intermediates AND/OR
Erectile Dysfunction
100. Tadalafil And/Or its Erectile Dysfunction 14907-27-8 intermediates AND/OR
Receptor Antagonist
101. Varenicline tartrate And/Or Receptor Antagonist 230615-51-7 its intermediates AND/OR
Vertigo
102. Betahistine Dihydrochloride Vertigo 5579-84-0 And/Or its intermediates
Group 4
AntiHypertensive
103. Telmisartan And/Or its AntiHypertensive 144702-27-2 intermediates AND/OR
Proton Pump Inhibitors
104. Omeprazole And/Or its 2.50 Proton Pump Inhibitors intermediates AND/OR 86604-75-3
105. Pantoprazole sodium Proton Pump Inhibitors 97963-62-7 And/Or its intermediates
Group 5
AntiGlaucoma
106. Travoprost And/Or its AntiGlaucoma1.00 1204185-88-5 intermediates AND/OR
Alzheimer's Disease 1.00 107. Donepezil hydrochloride Alzheimer's Disease And/Or its intermediates 22065-85-6 AND/OR
Analgesic
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108. Celecoxib And/Or its Analgesic 720-94-5 intermediates AND/OR
AntiBiotic
109. Azithromycin monohydrate AntiBiotic And/Or its intermediates 83905-01-5 AND/OR
110. Cefixime And/Or its AntiBiotic 79349-82-9 intermediates AND/OR
AntiCancer
111. Capecitabine And/Or its 161599-46-8 AntiCancer intermediates AND/OR
112. Imatinib Mesylate And/Or its AntiCancer 106261-64-7 intermediates AND/OR
AntiCoagulant
113. Apixaban And/Or its AntiCoagulant 503614-91-3 intermediates AND/OR
AntiConvulsants
114. Lacosamide And/Or its AntiConvulsants 880468-89-3 intermediates AND/OR
115. Oxcarbamazepine And/Or AntiConvulsants 28721-09-7 its intermediates AND/OR
AntiDepressant
116. Mirtazapine Hemihydrate AntiDepressant And/Or its intermediates 61337-89-1 AND/OR
AntiDiabetic
117. Vildagliptin And/Or its AntiDiabetic 207557-35-5 intermediates AND/OR
AntiHistaminic
118. Loratidine And/Or its AntiHistaminic 31251-41-9 intermediates AND/OR
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AntiHypertensive
119. Amlodipine And/Or its AntiHypertensive 88150-62-3 intermediates AND/OR
120. Carvedilol And/Or its AntiHypertensive 1836-62-0 intermediates AND/OR
121. Clopidogrel Bisulphate AntiHypertensive And/Or its intermediates 141109-19-5 AND/OR
122. Lisinopril And/Or its AntiHypertensive 16652-71-4 intermediates AND/OR
123. Losartan potassium And/Or AntiHypertensive 114798-26-4 its intermediates AND/OR
124. Olmesartan medoxomil AntiHypertensive And/Or its intermediates 80841-78-7 AND/OR
AntiLipemic
125. Atorvastatin And/Or its AntiLipemic 125971-95-1 intermediates
Group 6
Benign Prostatic
Hyperplasia
126. Silodosin And/Or its Benign Prostatic Hyperplasia 1375180-30-5 0.15 intermediates
Hormonal Therapy
127. Tamoxifen And/Or its Hormonal Therapy 4584-46-7 0.08 intermediates
Insomia
128. Zopiclone And/Or its Insomia 43200-81-3 11.00 intermediates
Analgesic
129. Cyclosporine And/Or its 59865-13-3 Analgesic 0.35 intermediates
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AntiArrhythmias
130. Digoxin And/Or its 20830-75-5 AntiArrhythmias 0.02 intermediates
Group 7
131. R & D development 0.50 ---
Total (Group 1 to 7) 70.60
• The project falls under Category B of project activity 5(f) as per the schedule of EIA Notification 2006. • The presentation was considred in the meeting dated 19/03/2020 as per the submission by PP via E- mail dated 18/03/2020. • Salient features of the project are as under: Sr. Particulars Details no. A A Total cost of Proposed Project (Rs. in Crores): Rs. 3.65 Crore Details of EMP Capital Cost (Lakhs) : 45.00 Recurring Cost : 80.60 (Lakhs/Annum) Recurring Cost Sr. No. Description Capital Cost (Lakhs) (Lakhs/Annum) 1. Air Pollution Control 12.00 2.50 2. Water Pollution Control 20.00 40.00 Hazardous / Solid Waste 3. 2.50 35.00 Management 4. Noise Pollution 1.00 0.10 Occupational Health and 5. 8.00 2.50 Safety 6. Green Belt Development 1.50 0.50 Total 45.00 80.60
Details of CER as per OM dated 01/05/2018 7.30 Lakhs A budget of Rs. 7,30,000.00/- which is 2 % of proposed project cost will be allocated for CER activities and it will be implemented in next 5 years after implementation of the project at nearby villages i.e.
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Vorasamni, Vagara, Kasad. Year wise Budget (Lakhs) Sr. Total CER Activities No. 2020- 2021- 2022- 2023- 2024- (Lakhs) 2021 2022 2023 2024 2025 Rain water harvesting ponds, ground water 1. recharge Pits and Water 0.30 0.30 0.50 0.50 0.50 2.10 conservation awareness programs. Provide drinking water 2. facilities i.e. UV + R.O 0.30 0.30 0.30 0.40 0.40 1.70 Plant 3. Tree will be planted 0.30 0.30 0.30 0.40 0.40 1.70 Provision of scholarship to needy students and Distribution of 4. 0.15 0.15 0.20 0.20 0.20 0.90 educational books, stationary, uniforms and aids etc. Organize Medical 5. checkup and health 0.15 0.15 0.20 0.20 0.20 0.90 awareness camps Total 1.20 1.20 1.50 1.70 1.70 7.30
B Total Plot area ( sq. meter) 5,000.00 Sq. m Green belt area 1,655.00 Sq. m. ( sq. meter) C Employment generation 26 Nos. D Water i Source of Water Supply GIDC (GIDC Bore well, Surface water, Tanker supply etc...) Status of permission from the concern authority. Yes ii Water consumption (KLD)
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Water Consumption Category Quantity Remarks (KLD) (J) Domestic 1.50 (K) Gardening 6.50 (L) Industrial Process 43.00 Including APCM Washing 5.00 Boiler 5.00 Cooling 5.00 Others 0.00 Industrial Total 58.00 Total (A + B + C) 66.00
1) Total water requirement for the project: 66.00 KLD 2) Quantity to be recycled: 0.00 KLD 3) Total fresh water requirement: 66.00 KLD iii Waste water generation (KLD)
Category Waste water generation KLD (E) Domestic 1.00 (F) Industrial Process 54.00 Washing 4.00 Boiler 0.50 Cooling 0.50 Others 0.00 Total Industrial waste water 59.00
Total [A + B] 60.00 iv Treatment facility within premises with capacity [In-house ETP (Primary, Secondary, Tertiary), MEE, Stripper, Spray Dryer, STP etc. ➢ ETP – 55 KLD ➢ MEE – 100 KLD
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Sr. No. Name of the units Size (m) Nos. 1. Collection Tank -1 60 KL 1.0 2. Collection Tank - 2 100 KL 1.0 3. Neutralization tank 5 KL 2.0 4. Flocculation tank 5 KL 2.0 5. Tube Settler 25 KL 3.0 6. Aeration tank 150 KL 2.0 7. Pressure sand Filter 4 KL/Hr 1.0 8. Activated carbon Filter 4 KL/Hr 1.0 MEE Plant With Stripper + 1.0 9. 55 KL ATFD 10. Final Holding tank 100 KL 1.0
Treatment scheme including segregation at source. ➢ Wastewater directly send to ETP = 60.00 KLD & ➢ Wastewater directly send to MEE = 54.00 KLD. The industrial effluent generation from the proposed project will be 59 KLD. The effluent will be segregated as follow: ➢ High Concentrated Effluent: High concentrated effluent from manufacturing process of 54 KLD will be sent to Neutralization tank, Tube Settler, Aeration Tank and Collection Tank and after that it will be sent to Stripper followed by MEE with ATFD having capacity of 55 KLD. The concentrate from MEE shall be further evaporated in ATFD. The condensate of MEE will be sent to ETP. ➢ High COD and High TDS water may be in acidic/ basic or neutral in characteristics. Industry will be proposed the stripper SS 316 (Contact part). In such scenario and looking the MOC, Industry can`t feed acidic water in stripper. So Industry first do pH correction and sludge sedimentation and then feed into the Stripper. ➢ Low Concentrated Effluent: Low concentrated effluent from cooling tower, boiler, washing and MEE Condensate around 59 KLD which will be treated in ETP consisting of Neutralization tank, Tube Settler, Aeration Tank, Pressure Sand Filter, Activated Carbon Filter and Final Holding Tank. Then final treated effluent will be sent to the CETP, Saykha for further treatment. Note: (In case of CETP discharge) : Management of waste water keeping in view direction under section 18 (1) (b) of the Water (Prevention and Control of Pollution) act, 1974 issued by CPCB regarding compliance of CETP. ➢ Not Applicable Brief note on adequacy of ZLD (In case of Zero Liquid Discharge):
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➢ Not Applicable v Mode of Disposal & Final meeting point Domestic: Sewage generated during operation phase shall be treated in proposed soak pit/septic system. Industrial: The industrial effluent generation from the proposed project will be 59 KLD. The effluent will be segregated as follow: ➢ High Concentrated Effluent: High concentrated effluent from manufacturing process of 54 KLD will be sent to Neutralization tank, Tube Settler, Aeration Tank and Collection Tank and after that it will be sent to Stripper followed by MEE with ATFD having capacity of 55 KLD. The concentrate from MEE shall be further evaporated in ATFD. The condensate of MEE will be sent to ETP. ➢ High COD and High TDS water may be in acidic/ basic or neutral in characteristics. Industry will be proposed the stripper SS 316 (Contact part). In such scenario and looking the MOC, Industry can`t feed acidic water in stripper. So Industry first do pH correction and sludge sedimentation and then feed into the Stripper. ➢ Low Concentrated Effluent: Low concentrated effluent from cooling tower, boiler, washing and MEE Condensate around 59 KLD which will be treated in ETP consisting of Neutralization tank, Tube Settler, Aeration Tank, Pressure Sand Filter, Activated Carbon Filter and Final Holding Tank. Then final treated effluent will be sent to the CETP, Saykha for further treatment. vi In case of Common facility (CF) like CETP, Common Spray dryer, Common MEE etc. Name of CF ➢ Saykha CETP Membership of Common facility (CF) (For waste water treatment) ➢ Wastewater generation from the proposed production activity will be treated in MEE with stripper and ETP having capacity of 55 KLD and 100 KLD respectively. Then send to the CETP, Saykha for further treatment. vii Simplified water balance diagram with reuse / recycle of waste water Water Balance Diagram (Proposed, Kl/day)
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viii Reuse/Recycle details (KLD) Total reuse: 0.00 KLD Source of waste Characteristics Remarks Application area water for reuse of waste water regarding with quantity in with quantity in to be reused feasibility KLD (Where it is KLD (From where (COD, BOD, TDS to reuse used) it is coming) etc.) i.e. ------
E Air i Flue gas emission details No. of Boilers/TFH/Furnaces/DG sets etc. with capacities viz. TPH, Kcal/hr, MT/hr, KVA etc. - Type of Air Sr Stack Quantity emission Pollution . Source of emission Type of Height of Fuel s i.e. Air Control N With Capacity Fuel (meter) MT/Day Pollutant Measures o. s (APCM)
Boiler – 600 kg/Hr – Coal 3.0 PM < 150 Multi 1. 30 1 No. OR MT/Day mg/Nm3 Cyclone
2. Thermic Fluid 30 Agro OR SO2< 100 Separator,
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Heater – 2 lacs Briquettes 3.4 ppm Bag Filter
Kcal/Hr. OR MT/day NOx< 50 & Scrubber Natural OR ppm Gas 400 m3/day
Stack Height & 3. D.G. Set – 200 KVA 5 HSD 32 Lit/hr. Acoustic Enclosure
ii Process gas emission details i.e. Type of pollutant gases (SO2, HCl, NH3, Cl2, NOx etc.) -
Stack/Ve Air Pollution Sr. Specific Source of Type of Permissi nt Control no emission (Name of the emissi ble Height Measures . Product & Process) on Limit (meter) (APCM)
2-(Diethylamino)ethyl 1. Chloride Hydrochloride
2. Lasamide 40 Sildenafil Citrate And/Or its SO2 3. mg/Nm3 intermediates
Tadalafil And/Or its 4. intermediates Water Scrubber 5. Lasamide followed by Alkali Clozapine And/Or its 20 m 6. Scrubber intermediates
Sildenafil Citrate And/Or its 7. 20 intermediates HCl mg/Nm3 Bisoprolol And/Or its 8. intermediates
Tadalafil And/Or its 9. intermediates
10 Naproxen And/Or its NH3 175 Water Scrubber
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. intermediates mg/Nm3 followed by Acid
11 Pregabalin And/Or its Scrubber . intermediates
12 Zidovudine and/or Its . Intermediates
13 Atorvastatin And/Or its . intermediates
14 Niacin And/Or its . intermediates
15 Simvastatin And/Or its . intermediates
16 Omeprazole And/Or its . intermediates
17 2-Diethylaminoethanethiol . hydrochloride
iii Fugitive emission details with its mitigation measures: As below:
Sr. Source Control measures No
Area of acid storage tank • Close handling system will be provided 1. • Carry out work place monitoring to find out concentration level in ambient air.
During reactions & Solvent • All reactors will be closed and provided with main recovery systems condenser with cooling water circulation & vent condenser with chilled water circulation for maximum vapour recovery. 2. • Minimum 98 % of solvent recovery will be achieved. • Temperature and pressure conditions shall be stringently controlled as per the process requirement and optimized with low temperature and vacuum conditions wherever feasible.
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Handling of raw material • Provision of exhaust ventilation 3. bags in storage area • Provision of PPE • Provision of Job rotation to reduce exposure
Flange joints of pipeline, • Routine & periodic inspection to check leakage pump & motors • Preventive maintenance, follow SOP for maintenance 4. • mechanical seal type Pumps & motors will be used • LDAR program will be followed.
Solid raw material • Hopper with magnet will be provided with powder 5. transferring to reactor transfer system.
Liquid raw material • Feeding of liquid raw material will be carried out by 6. transferring to reactor closed pipeline and mechanical seal pump.
Loading /unloading of • Unloading through pipeline to tank in a close system 7. liquid raw material at storage area
Valves, Flanges, plugs • Seamless pipes to be used wherever feasible and instrument • Suitable gasket material to be used 8. connections • Suitable gland packing to be used in valves • Periodic inspection and maintenance of pipes and pipe fittings.
Chemical vapors during • Closed systems to be adopted, workers shall be 9. filtration and drying provided PPE, dust extraction systems, local exhausts process and roof top ventilators, wherever required
F Hazardous wastes (as per the Hazardous and Other Wastes (Management and Transboundary Movement) Rules 2016. i Categor Sr Type/Name Specific Source of y and Quantity . of generation Schedul Management (MT/Ann N Hazardous (Name of the Activity, e as per of HW um) o. waste Product etc.) HW Rules.
1. Process Process (Maximum 28.1 1,389.71 Collection,
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residue from Group no. 1 – (Sch. I) Storage and Product - Sitagliptin send to CHWIF And/Or its for further intermediates, treatment & Maximum from Group disposal. no. 2 – Product - Valacyclovir hydrochloride And/Or its intermediates , Maximum from Group no. 3 – Product - Varenicline tartrate And/Or its intermediates, Maximum from Group no. 4 – Product - Omeprazole And/Or its intermediates, Maximum from Group no. 5 – Product - Amlodipine And/Or its intermediates, From Group no. 6 – Product - Tamoxifen And/Or its intermediates , Zopiclone And/Or its intermediates, Cyclosporine And/Or its intermediates)
Process (Maximum Collection, from Group no. 1 – Storage, Product - Aripiprazole Distillation 20.3 Transportation 2. And/Or its 1,747.34 residue (Sch. I) & send to intermediates, CHWIF or co- Maximum from Group processing. no. 2 - Product -
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Valacyclovir hydrochloride And/Or its intermediates, Maximum from Group no. 3 – Product - Simvastatin And/Or its intermediates, Maximum from Group no. 4 – Only from product - Telmisartan And/Or its intermediates, Maximum from Group no. 5 – Product - Mirtazapine Hemihydrate And/Or its intermediates, From Group no. 6 – Product - Cyclosporine And/Or its intermediates, Digoxin And/Or its intermediates)
Process (Maximum from Group no. 1 – Product – Levetiracetam And/Or Collection, its intermediates, Storage, Maximum from Group Transportation no. 2 – Product - 28.3 3. Spent carbon 516.20 & send to Solifenacin And/Or its (Sch. I) CHWIF or co- intermediates, processing. Maximum from Group
no. 3 – Product - Tadalafil And/Or its intermediates , Maximum from Group
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no. 5 – Product - Vildagliptin And/Or its intermediates, From Group no. 6 – Product - Tamoxifen And/Or its intermediates , Zopiclone And/Or its intermediates , Digoxin And/Or its intermediates)
Collection, storage, transport (Through GPS 35.3 4. ETP Sludge ETP 300.00 mounted (Sch. I) vehicle) and Disposal to authorized TSDF.
Collection, Storage, Transportation, Disposal by selling to 5.1 (Sch. 3000.00 5. Used Oil Machinery GPCB/ MoEF I) kl/Annum approved recycler/ reuse as lubricant within premises.
Collection, Raw Material Storage Discarded 9,000.00 Storage, area and Finished 33.1 6. Container/ Nos./Ann Transportation, product packing (Sch. I) barrels/ liners um Decontaminati Material on, Disposal by
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send to the GPCB authorized dealer.
Collection, storage, transport (Through GPS 35.3 7. MEE Salt ATFD 1,460.00 mounted (Sch. I) vehicle) and Disposal to authorized TSDF.
Collection, storage, transport Process (Group no. 6 - (Through GPS Allumina only from product - 28.1 8. 1.08 mounted Powder Digoxin And/Or its (Sch. I) vehicle) and intermediates) Disposal to authorized TSDF.
Collection, Process (Group no. 6 - Storage and Lanata only from product - 28.1 send to CHWIF 9. 175.70 leaves Digoxin And/Or its (Sch. I) for further intermediates) treatment & disposal.
Process (Group no. 1 – Collection, Only from Product - Storage and N,N Dimethyl Form Sold to actual 10 Spent 20.2 amide Diemthyl Acetal, 1,704.00 users having . Solvent (Sch. I) Maximum from Group permission of no. 3 – Product - Rule – 9 from Ramipril And/Or its SPCB/CPCB.
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intermediates , Group no. 5 – Only from Product - Azithromycin monohydrate And/Or its intermediates , Group no. 6 – Only from Product - Digoxin And/Or its intermediates)
250.00 Stripper KL/Annu m
Collection, Storage and Sold to actual 11 Ammonium 35.1 Scrubbing Media 180.00 users having . Sulphate (Sch. I) permission of Rule – 9 from SPCB/CPCB.
Collection, Storage and Sold to actual 12 Ammonium 35.1 Scrubbing Media 14.93 users having . Chloride (Sch. I) permission of Rule – 9 from SPCB/CPCB.
Collection, Storage and Sold to actual 35.1 Scrubbing Media 30.00 users having 13 Sodium (Sch. I) permission of . sulphate Rule – 9 from SPCB/CPCB.
Process (Maximum 28.1 Collection, 1,202.00 from Group no. 1 – (Sch. I) Storage,
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Product - reused as raw Levetiracetam And/Or material its intermediates, (Product - Group no. 3 - only from Levetiracetam product - Quetiapine And/Or its And/Or its intermediates, intermediates) Escitalopram oxalate And/Or its intermediates, Darunavir And/Or its intermediates, Solifenacin And/Or its intermediates, Apremilast And/Or its intermediates, Desloratidine And/Or its intermediates, Quetiapine And/Or its intermediates, Capecitabine And/Or its intermediates, Tamoxifen And/Or its intermediates)
Collection, Hydrogen Storage and 14 35.1 Chloride Scrubbing Media 38.40 Sold to actual . (Sch. I) (30%) users having permission of
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Rule – 9 from SPCB/CPCB.
Collection, Storage, reused as raw Process (Maximum material from Group no. 1 – 28.1 (Product - 4- Product - Bis(2- 327.60 (Sch. I) Methyl chloroethyl)amine Cathechol hydrochloride) Diacetic Acid Dimethyl Ester).
Collection, Storage and Process (Only from Sold to actual 15 Aluminium 28.1 Group no. 1 – Product - 645.80 users having . hydroxide (Sch. I) Guanidine) permission of Rule – 9 from SPCB/CPCB.
Collection, Storage and Process (Group no. 1 - Sold to actual 16 Potassium only from product - 28.1 38.96 users having . sulphate Trimethoprim And/Or (Sch. I) permission of its intermediates) Rule – 9 from SPCB/CPCB.
Collection, Storage and Process (Group no. 2 - Sold to actual 17 only from product - 28.1 Boric acid 16.74 users having . Phenylephrine And/Or (Sch. I) permission of its intermediates) Rule – 9 from SPCB/CPCB.
18 Triphenyl Process (Group no. 1 - 28.1 Collection, 180.00 . Carbinal only from product - (Sch. I) Storage and
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Zidovudine And/Or its Sold to actual intermediates) users having permission of Rule – 9 from SPCB/CPCB.
Collection, Process (Group no. 3 - Storage and Piperazine only from product - Sold to actual 19 28.1 Hydrochlorid Ciprofloxacin HCL 24.80 users having . (Sch. I) e And/Or its permission of intermediates) Rule – 9 from SPCB/CPCB.
Collection, Storage and Process (Group no. 1 - Sold to actual 20 Tert. Butyl only from product 28.1 90.72 users having . alcohol Saxagliptin And/Or its (Sch. I) permission of intermediates) Rule – 9 from SPCB/CPCB.
Collection, Process (Group no. 5 - Storage and only from product - Sold to actual 21 P - Toluene 28.1 Clopidogrel Bisulphate 5.11 users having . Sulfonic acid (Sch. I) And/Or its permission of intermediates) Rule – 9 from SPCB/CPCB.
Collection, Storage, Process (Maximum reused as raw from Group no. 1 – material 22 Sulphuric 28.1 Product - Trimethoprim 90.72 (Product 2 . acid (Sch. I) And/Or its Bromo 4-5- intermediates) Dimethoxy Benzyl Bromide, 2,3,4
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Bis -o-(1 methyl)-B-D- Fructopyranos e).
Collection, Storage, reused as raw Process (Group no. 1 - material 23 Sodium only from product - 28.1 (Product - 4-Iso 115.90 . Nitrate Trimethoprim And/Or (Sch. I) Propyl its intermediates) Catechol, Apixaban And/Or its intermediates).
Collection, Storage, reused as raw material Process (Group no. 1 - (Product - 6- 24 Potassium only from product - 28.1 343.80 Chloro-5(2- . Carbonate Lansoprazole And/Or (Sch. I) Chlor Ethyl) its intermediates) Oxindole, Doxofylline And/Or its intermediates)
Process (Maximum Collection, from Group no. 1 – Storage, Product - 2- reused as raw Diethylaminoethanethio material 25 Sodium l , Group no. 2 - Only 28.1 (Product -. 427.00 . Chloride from product - (Sch. I) Topiramate Phenylephrine And/Or And/Or its its intermediates, intermediates, Maximum from Group Sitagliptin no. 3 – Product - And/Or its
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Fluconazole And/Or its intermediates, intermediates) Paroxetine HCl Hemihydrate And/Or its intermediates, Darunavir And/Or its intermediates, Zidovudine And/Or its intermediates, Fluconazole And/Or its intermediates, Capecitabine And/Or its intermediates, Vildagliptin And/Or its intermediates, Carvedilol And/Or its intermediates, Lisinopril And/Or its intermediates).
Collection, Storage, reused as raw Process (Maximum material 26 28.1 Zinc Chloride from Group no. 1 - 594.00 (Product - 6- . (Sch. I) Product - Sesamol) Chloro-5(2- Chlor Ethyl) Oxindole, Sesamol)
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Collection, Storage, Process (Only from reused as raw Group no. 1 - Product - material 27 Aluminium 28.1 2-Methyl-4,5- 475.00 (Product - 2- . Chloride (Sch. I) Dimethoxybenzoic Methyl-4,5- Acid) Dimethoxybenz oic Acid , Guanidine)
Collection, Storage, reused as raw material (Product 4-Iso Propyl Catechol, 2- Diethylaminoet Process (Maximum hanethiol, from Group no. 1 – Etodolac 28 Sodium 28.1 product - Trimethoprim 60.00 And/Or its . Hydroxide (Sch. I) And/Or its intermediates, intermediates) Naproxen And/Or its intermediates, Pregabalin And/Or its intermediates, Trimethoprim And/Or its intermediates).
Collection, Process (Group no. 1 - Storage, 29 Sodium only from product - 28.1 9.26 reused as raw . Acetate Naproxen And/Or its (Sch. I) material intermediates) (Product -
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Apixaban And/Or its intermediates).
Collection, Storage and Sold to actual 330.50 users having permission of Rule – 9 from SPCB/CPCB.
Collection, Storage, reused as raw material (Product - 187.85 Lansoprazole And/Or its Process (Group no. 1 - intermediates, 30 Ammonium only from product - 28.1 Omeprazole . acetate Trimethoprim And/Or (Sch. I) And/Or its its intermediates) intermediates). Collection, Storage and Sold to actual 74.23 users having permission of Rule – 9 from SPCB/CPCB
Collection, Process (Only from Storage, Group no. 1 – Product - reused as raw 31 Sodium 28.1 2-Methyl-4,5- 24.90 material . Bisulfate (Sch. I) Dimethoxybenzoic (Product - Acid) Bisoprolol And/Or its
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intermediates, Digoxin And/Or its intermediates)
Collection, Storage and Sold to actual 510.10 users having permission of Rule – 9 from SPCB/CPCB.
Collection, Storage, reused as raw material 1.20 Process (Maximum (Product - from Group no. 1 – Silodosin Product - 4-Iso Propyl And/Or its 32 Sodium 28.1 Catechol , Group no. 2 intermediates) . Bromide (Sch. I) - Only from Product - Collection, Phenylephrine And/Or Storage and its intermediates) Sold to actual 701.80 users having permission of Rule – 9 from SPCB/CPCB.
ii Membership details of TSDF, CHWIF etc. For Incineration Certificate No. – (For HW management) 37292/171416 dated 07/11/2019. For TSDF Site Certificate No. – BEIL/ANK/2019 dated 30/12/2019. iii Details of Non-Hazardous waste & its disposal Not applicable (MSW and others) G Solvent management, VOC emissions etc. i Types of solvents, Details of Solvent recovery, % recovery, reuse of recovered Solvents etc. (Details in Table Format)
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Sr Quantity (kg/Batch) Reco . In Out Name of Product Name of Solvent very N (%) o.
2 Bromo 4-5- Dimethoxy Methanol 0.20 0.198 99.00
Benzyl Bromide MDC 1.06 1.044 98.86 1. HBr 0.45 0.441 98.00
Cyclohexane 0.45 0.445 98.89
2,3,4 Bis -o-(1 methyl)-B- Acetone 1,000.00 981.00 98.10 2. D-Fructopyranose Toluene 300.00 295.00 98.33
2-Methyl-4,5- Toluene 1,500.00 1,472.00 98.13 3. Dimethoxybenzoic Acid MDC 1,500.00 1,473.00 98.20
4. 3-Methoxy Phenol Toluene 1,000.00 981.00 98.10
4-Iso Propyl Catechol MDC 1,000.00 983.00 98.30
5. CuSO4 1,000.00 982.00 98.20
N-Butanol 1,400.00 1,375.00 98.21
4-Methyl Cathechol Methanol 2,500.00 2,455.00 98.20 6. Diacetic Acid Dimethyl Toluene 1,000.00 981.00 98.10 Ester
6 chloro hexanol 14,400.0 7. Toluene 14,681.50 98.08 0
6-Chloro-5(2-Chlor Ethyl) DMSO 1,000.00 981.00 98.10
Oxindole MDC 700.00 687.00 98.14 8. Methanol 1,000.00 982.00 98.20
Acetic acid 600.00 589.00 98.17
Benzaldehyde Dimethyl 9. Methanol 700.00 687.00 98.14 Acetal
10 Bis (2- chloroethyl) amine EDC 0.00188 0.00185 98.40 . hydrochloride
11 CetylPyridinium Chloride Pyridine 0.000464 0.000455 98.06 . Methyl Ethyl 0.0040 0.0039 98.00
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Ketone
Acetone 0.0040 0.0039 98.00
Sesamol MDC 800.00 785.00 98.13
12 Toluene 1,650.00 1,620.00 98.18 . Methanol 300.00 295.00 98.33
Formic acid 620.00 610.00 98.38
13 Dimethyl fumarate And/Or Methanol 7.00 6.87 98.14 . its intermediates
14 Etodolac And/Or its Methanol 2,000.00 1,963.00 98.15 . intermediates
Pregabalin And/Or its n-Hexane 450.00 441.10 98.02 15 intermediates Chloroform 5,100.00 5,005.00 98.14 . Diethylmalonate 50.00 49.00 98.00
16 Ivabradine Hcl And/Or its Methanol 0.21 0.21 98.10 . intermediates DMSO 0.533 0.531 99.62
17 Chloramphenicol And/Or Methanol 1,300.00 1,276.00 98.15 . its intermediates
18 Erythromycin And/Or its MDC 9.02 8.85 98.07 . intermediates
19 Trimethoprim And/Or its Methanol 700.00 687.50 98.21 . intermediates Dimethyl Sulfoxide 150.00 147.00 98.00
20 Rivaroxaban And/Or its THF 9.07 8.89 98.02 . intermediates Ethanol 9.67 9.48 98.04
21 Warfarin And/Or its Toluene 20.00 19.61 98.05 . intermediates
22 Carbamazepine And/Or its Methanol 150.00 147.50 98.33 . intermediates
23 Levetiracetam And/Or its Ethyl acetate 16.16 15.87 98.21 . intermediates Dichloromethane 38.75 38.10 98.32
24 Topiramate And/Or its Acetone 2,100.00 2,060.00 98.10 . intermediates n-Hexane 1,370.00 1,344.10 98.11
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Toluene 1,600.00 1,570.00 98.13
Ethyl acetate 1,610.00 1,580.00 98.14
Isopropyl alcohol 1,415.00 1,389.00 98.16
Desvenlafexine And/Or its DCM 8.50 8.34 98.11
intermediates DMF 5.00 4.91 98.2 25 Methanol 2.05 2.01 98.04 . Acetone 5.652 5.54 98.01
Ethanol 7.81 7.67 98.20
26 Venlafaxine hydrochloride Ethyl acetate 328.00 328.00 100.00 . And/Or its intermediates
27 Glipizide And/Or its Methanol 246.00 242.10 98.41 . intermediates Acetone 100.00 98.00 98.00
Saxagliptin And/Or its DMF 625.00 613.00 98.08
intermediates Isopropyl alcohol 350.00 343.00 98.00 28 (IPA) . Methylene 470.00 461.00 98.09 dichloride (MDC)
Ethyl acetate 620.00 607.90 98.05
Sitagliptin And/Or its MDC 250.00 245.10 98.04 29 intermediates Iso-propyl alcohol 200.00 196.10 98.05 . Methanol 350.00 343.10 98.03
30 Voglibose And/Or its DMSO 0.0050 0.0049 98.00 . intermediates
Diltiazem hydrochloride Methanol 400.00 392.000 98.00
31 And/Or its intermediates Toluene 750.00 737.400 98.32 . Ethyl acetate 500.00 490.000 98.00
Iso-propyl alcohol 93.00 92.60 99.57
Irbesartan And/Or its 2,450.00 o-Xylene 2,500.000 98.00 32 intermediates 0 . 3,729.00 Toluene 3,800.000 98.13 0
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1,570.00 Isopropyl Alcohol 1,600.000 98.13 0
Ethyl acetate 450.000 442.000 98.22
Tributyltin Chloride 220.000 216.000 98.18
Valsartan And/Or its Methanol 17.03 16.70 98.06
intermediates Toluene 2.48 2.44 98.39
MDC 67.11 65.90 98.20
33 Acetonitrile 9.45 9.28 98.20 . O-Xylene 25.74 25.30 98.29
Hexane 16.70 16.40 98.20
Acetone 12.91 12.69 98.30
Ethyl acetate 21.06 20.70 98.29
Olanzapine And/Or its 1,470.00 Dimethysulphoxide 1,500.00 98.00 34 intermediates 0 . 1,570.00 Ethyl acetate 1,600.00 98.13 0
Tiotropium Bromide and/or Toluene 105.00 103.00 98.10 35 Its intermediates Acetonitrile 260.00 255.00 98.08 . Ethanol 280.00 275.00 98.21
Zidovudine and/or Its 4,752.00 36 Toluene 4,800.00 99.00 Intermediates 0 . Ethyl acetate 500.00 490.000 98.00
37 Diazepam and/or Its Methanol 629.20 620.00 98.54 . Intermediates Toluene 520.20 510.00 98.04
Deferasirox And/Or its Toluene 3.18 3.13 98.43 38 intermediates Methanol 0.80 0.79 98.75 . Ethanol 18.08 17.80 98.45
Prednisolone Sodium Tetra Hydro Furan 435.00 427.00 98.16 39 Phosphate And/Or its . Acetone 175.00 172.00 98.29 intermediates
40 Febuxostat And/Or its IPA 3.95 3.88 98.23 . intermediates
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41 Mycophenolate Mofetill Xylene 1,400.00 1,375.00 98.21 . And/Or its intermediates Isobutyl Acetate 600.00 589.00 98.17
42 Montelukast Sodium Toluene 300.00 295.00 98.33 . And/Or its intermediates Methanol 400.00 393.00 98.25
43 Folic acid And/Or its Acetonitrile 1,400.00 1,372.00 98.00 . intermediates Ethyl acetate 1,750.00 1,718.00 98.17
Donepezil hydrochloride Methanol 438.00 430.10 98.20
44 And/Or its intermediates Toluene 133.00 130.50 98.12 . DMF 46.00 45.10 98.04
Iso-propyl alcohol 165.00 163.00 98.79
45 Celecoxib And/Or its Toluene 24.00 23.60 98.33 . intermediates Iso-propyl alcohol 2.59 2.54 98.03
Cyclosporine And/Or its Toluene 4,666.67 4,578.33 98.11
46 intermediates Acetone 33.33 32.70 98.10 . Methanol 33.33 32.73 98.20
Cyclohexane 33.33 32.70 98.10
47 Lidocaine HCL And/Or its Acetone 129.88 128.73 99.11 . intermediates Toluene 77.30 75.86 98.14
48 Digoxin And/Or its Chloroform 10,057.50 9,857.50 98.01 . intermediates Isopropylether 39.09 38.35 98.11
Salbutamol And/Or its Iso-propyl alcohol 180.00 178.00 98.89
intermediates Ethy Acetate 105.00 103.00 98.10
49 Retarder 105.00 103.00 98.10 . Toluene 12.00 11.80 98.33
Methanol 696.00 683.00 98.13
Acetone 300.00 294.50 98.17
Cefixime And/Or its MDC 133.82 131.18 98.02
intermediates MeOH 373.16 367.78 98.56 50 TPPO 20.12 19.74 98.10 . DMF 36.09 35.38 98.03
NBA 388.24 384.12 98.94
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Phenol 92.65 90.88 98.10
Acetone 47.06 46.18 98.13
NaBr 8.64 8.47 98.06
51 Ciprofloxacin HCL And/Or N-Butanol 333.33 327.50 98.25 . its intermediates
Apixaban And/Or its Ethyl acetate 157.14 154.21 98.14
intermediates Tetrahydrofuran 75.00 73.61 98.14 52 Dichloroethane 71.43 70.07 98.10 . Morophine 57.14 56.07 98.13
Toluene 85.71 84.07 98.08
Lacosamide And/Or its Tetrahydrofuran 1,411.90 1,385.00 98.09
intermediates Methyl Tertiary 1028.64 1020.00 99.16 Butyl Ether
53 Methanol 1,550.00 1,520.00 98.06 . Toluene 1,159.28 1,152.00 99.37
Methylene chloride 3,608.60 3,550.00 98.38
Acetone 1,147.00 1,125.00 98.08
Ethyl acetate 220.50 216.50 98.19
Oxcarbamazepine And/Or Toluene 21.19 20.80 98.16 54 its intermediates N-Propanol 13.17 12.95 98.33 . Acetone 2.23 2.19 98.21
55 Mirtazapine And/Or its Ethyl acetate 1,162.70 1,142.86 98.29 . intermediates
56 Teneligliptin And/Or its EDC 862.07 845.98 98.13 . intermediates MIBK 275.86 271.26 98.33
Vildagliptin And/Or its Methanol 35.48 34.8 98.083
intermediates Methylene 57 267.37 262.5 98.17 diChloride (MDC) . Ethyl acetate 24.3 23.85 98.14
Iso-propyl alcohol 2.8 2.75 98.21
58 Fluconazole And/Or its Toluene 10.52 10.32 98.10
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. intermediates Hexane 1.40 1.38 98.36
Iso-propyl alcohol 10.52 10.32 98.10
MDC 14.73 14.45 98.11
59 Desloratidine And/Or its Ethyl acetate 450.00 441.00 98.00 . intermediates Di Isopropyl ether 610.80 598.90 98.05
Levocetirizine Toluene 555.56 546.30 98.33
dihydrochloride And/Or its Cyclohexane 601.85 592.59 98.46 60 intermediates MDC 1,481.48 1,452.31 98.03 . Ethyl acetate 1,851.85 1,818.52 98.20
Acetone 1,250.00 1,226.85 98.15
Carvedilol And/Or its EDC 6.37 6.24 98.02
intermediates MeOH 19.01 18.70 98.35
Chloroform 37.76 37.10 98.25
61 Acetone 22.68 22.25 98.11 . Acetic acid 12.27 12.05 98.18
DNS 7.00 6.88 98.29
IPA 7.46 7.32 98.12
Ethyl acetate 13.26 13.00 98.07
Lisinopril And/Or its MDC 335.00 329.00 98.21
62 intermediates MTBE 35.00 34.40 98.29 . Ethyl alcohol 180.00 178.00 98.89
Ethanol 443.70 438.50 98.83
63 Losartan potassium Methanol 34.13 33.50 98.15 . And/Or its intermediates Acetonitrile 2.40 2.36 98.33
64 Olmesartan medoxomil Acetone 276.22 272.73 98.73 . And/Or its intermediates
Ramipril And/Or its Methyldichloride 239.50 235.00 98.12 65 intermediates DIPE 45.00 44.10 98.00 . Diethyl ether 100.70 98.90 98.21
66 Rosuvastatin Calcium Acetone 556.52 549.28 98.70 . And/Or its intermediates Toluene 1,375.65 1,356.52 98.61
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Methanol 847.25 840.58 99.21
MIBK 333.62 331.88 99.48
Ethyl acetate 264.06 262.32 99.34
Iso-propyl alcohol 262.03 260.87 99.56
BHT 65.22 65.22 100.00
67 Niacin And/Or its Toluene 30.95 30.36 98.08 . intermediates
Quetiapine And/Or its Toluene 1,251.09 1,227.91 98.15 68 intermediates DCM 2,739.30 2,692.33 98.29 . Ethanol 1,850.12 1,813.97 98.05
Tadalafil And/Or its Methanol 533.20 526.60 98.76 69 intermediates IPA 266.60 263.30 98.76 . Acetic Acid 333.30 330.00 99.01
70 Pantoprazole sodium Acetone 444.44 435.56 98.00 . And/Or its intermediates Iso-propyl alcohol 833.33 816.67 98.00
Zopiclone And/Or its Iso-propyl alcohol 444.60 435.91 98.05 71 intermediates MDC 2,292.25 2,248.64 98.10 . Ethyl acetate 2,281.50 2,238.25 98.10
Varenicline And/Or its Methanol 80.00 78.55 98.19 72 intermediates n-Hexane 25.60 25.15 98.24 . MDC 28.00 27.50 98.21
Betahistine Toluene 2,307.69 2,294.87 99.44 73 Dihydrochloride And/Or its . Iso-propyl alcohol 1,666.67 1,639.74 98.38 intermediates
Capecitabine And/Or its Dichloromethane 347.60 341.00 98.10
intermediates Pyridine 1,966.00 1,930.00 98.17 74 n-pentyl . 1,914.00 1,880.00 98.22 chloroformate
Methanol 16.72 16.45 98.39
75 Imatinib Mesylate And/Or Pyridine 160.00 156.90 98.06 . its intermediates DiChloro Methane 38.00 37.27 98.08
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Methanol 2.00 1.96 98.00
Ethanol 3.60 3.53 98.06
76 Iguratimod And/Or its Dimethyl 2.22 2.20 99.09 . intermediates formamide
77 Amoxicillin And/Or its Enzyme 10.00 9.85 98.50 . intermediates
Sr. Quantity (kg/day) Recove Name of Product Name of Solvent No. In Out ry (%)
Naproxen And/Or its 1. Toluene 0.0032 0.0031 98.025 intermediates
Naftopidil And/Or its Methanol 1.52 1.50 98.14 2. intermediates Ethyl acetate 1.83 1.80 98.15
Doxofylline And/Or its 8,586.0 Methanol 8,750.00 98.13 intermediates 0
3,628.8 3. DMF 4,141.80 87.61 0
3,210.2 Toluene 3,270.00 98.17 0
Dabigatran And/Or its Ethanol 80.00 78.40 98.00 4. intermediates Acetone 40.00 39.21 98.03
Gliclazide And/Or its DMF 0.00074 0.00073 98.65
5. intermediates 0.00028 Toluene 0.000294 98.30 9
Metformin 2,352.0 Isopropyl alcohol 2,400.00 98.00 Hydrochloride And/Or 0
its intermediates 1,618.0 6. Methanol 1,650.00 98.06 0
Dimethylformamid 1,764.0 1,800.00 98.00 e (DMF) 0
Metoprolol Succinate Toluene 400.00 392.00 98.00 7. And/Or its Acetone 1,500.00 1,477.5 98.50
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intermediates 0
Perindopril And/Or its Toluene 665.00 652.00 98.05
intermediates 13,530. EA 13,795.00 98.08 8. 00
2,870.0 Ethanol 2,925.00 98.12 0
Fenofibrate And/Or its Acetone 77.34 75.95 98.20
intermediates Chloroform 27.77 27.25 98.15 9. Iso-propyl alcohol 101.39 99.50 98.14
Toluene 450.00 441.50 98.11
Aripiprazole And/Or its Toluene 1,162.50 1140.00 98.06
intermediates Methanol 135.00 132.75 98.33
10. Iso-propyl alcohol 687.50 675.20 98.21
Chloroform 400.00 392.00 98.00
MDC 612.50 600.45 98.03
Clozapine And/Or its DMF 120.00 117.80 98.17
intermediates 1,017.8 Ethanol 1,032.00 98.62 0 11. Toluene 628.00 616.10 98.11
Anisole 55.00 54.00 98.18
Iso-propyl alcohol 165.00 162.40 98.42
Escitalopram oxalate Acetonitrile 220.00 215.80 98.09
12. And/Or its Toluene 80.00 78.50 98.13 intermediates EA 50.00 49.00 98.00
Sildenafil Citrate Toluene 800.00 785.000 98.13
And/Or its 1,520.0 MDC 1,550.00 98.06 intermediates 00 13. 1,029.0 Methanol 1,050.00 98.00 00
Acetone 500.00 490.000 98.00
14. Esomeprazole Acetone 100.00 98.10 98.10
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magnesium And/Or its Methanol 62.50 61.25 98.00
intermediates MDC 120.00 118.05 98.38
Toluene 90.00 88.20 98.00
Lansoprazole And/Or 1,325.0 Methanol 1,351.60 98.03 its intermediates 0
Diisopropyl ether 371.65 365.00 98.21
3,000.0 Ethyl acetate 3,051.75 98.30 15. 0
7,780.4 Acetone 7,820.60 99.49 5
1,252.8 Ethanol 1,252.80 100.00 0
Citalopram HBr Acetic Acid 500.00 490.00 98.00
And/Or its Acetonitrile 1,000.00 982.60 98.26 intermediates 1,079.9 Diisopropylether 1,100.00 98.17 0 16. Iso-propyl alcohol 550.00 540.00 98.18
THF 750.00 735.00 98.00
1,969.8 Toluene 2,000.00 98.49 0
Paroxetine HCl 2,210.2 Ethyl acetate 2,254.30 98.04 Hemihydrate And/Or 0
its intermediates 1,148.2 Propan-2-ol 1,170.00 98.14 0
1,824.6 Heptane 1,860.00 98.10 0 17. 8,768.3 Toluene 8,935.00 98.13 0
THF 145.00 142.50 98.28
4,780.4 Acetone 4,865.00 98.26 0
MDC 3,255.00 3,194.8 98.15
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0
3,103.2 Iso-propyl alcohol 3,160.00 98.20 0
Sertraline And/Or its MDC 500.00 493.70 98.74
18. intermediates Methanol 85.00 83.60 98.35
Iso-propyl alcohol 900.00 888.90 98.76
Alendronate Sodium 19. and/or Its Methanol 375.00 368.000 98.13 Intermediates
Darunavir Ethanolate Ethyl Acetate 560.00 550.00 98.21
and/or Its Tetrahydofuran 150.00 147.00 98.00 20. Intermediates MDC 640.00 630.00 98.44
Cyclohexane 450.00 443.30 98.51
Valacyclovir HCl Dimethyl 600.00 589.00 98.17 and/or Its formamide
Intermediates 1,878.0 21. Methanol 1,915.00 98.07 0
1,304.0 Acetone 1,330.00 98.05 0
Solifenacin Succinate Methanol 6.00 5.890 98.17
And/Or its Toluene 15.40 15.120 98.18 intermediates 22. Pyridine 0.05 0.053 98.15
THF 3.00 2.940 98.00
Iso-propyl alcohol 8.40 8.240 98.10
(+_)3-(Carbamoyl 23. methyl)-5-methyl Toluene 800.00 785.00 98.13 hexanoic acid
Memantine HCL Formic acid 150.00 147.20 98.13 24. And/Or its Methanol 150.00 147.10 98.07 intermediates
Etoricoxib And/Or its 25. Methanol 25.00 24.55 98.20 intermediates
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Gabapentin And/Or Methylene 5,713.5 5,825.00 98.09 its intermediates Dichloride 0
1,750.0 26. Acetone 1,785.00 98.04 0
1,775.0 Methanol 1,810.00 98.07 0
Amiodarone And/Or Toluene 600.00 589.00 98.17 27. its intermediates Iso-propyl alcohol 859.20 842.30 98.03
Apremilast And/Or its Acetic acid 875.00 859.00 98.17
intermediates Ethyl acetate 1,000.00 981.00 98.10 28. n- Hexane 250.00 245.50 98.20
Ethanol 350.00 343.50 98.14
Azithromycin 5,275.0 MDC 5,373.50 98.17 monohydrate And/Or 0
its intermediates 1,567.5 Acetone 1,597.00 98.15 0 29. 2,100.0 DCM 2,139.00 98.18 0
8,175.0 Methanol 8,315.50 98.31 0
ketoconazole And/Or Methanol 550.00 540.00 98.18
its intermediates 4,260.0 Ethyl acetate 4,345.00 98.04 0 30. 1,933.0 Acetone 1,970.00 98.12 0
Dimethyl Sulfoxide 815.00 800.00 98.16
Loratidine And/Or its Xylene 50.00 49.10 98.20
intermediates Tetrahydrofuran(T 31. 35.00 34.40 98.29 HF)
Acetonitrile 50.00 49.10 98.20
Amlodipine And/Or its 8,250.0 32. Toluene 8,401.30 98.20 intermediates 0
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Methanol 345.90 340.00 98.29
9,890.0 Cyclohexane 10,088.10 98.04 0
2,890.0 Ethyl acetate 2,920.20 98.97 0
13,400. Acetic acid 13,630.90 98.31 00
Bisoprolol And/Or its 1,471.0 Toluene 1,500.00 98.07 intermediates 0
1,962.0 33. Methanol 2,000.00 98.10 0
2,945.0 Acetone 3,000.00 98.17 0
Clopidogrel Bisulphate MDC 310.00 303.80 98.00
34. And/Or its Ethyl acetate 165.00 161.80 98.06 intermediates Methanol 60.00 58.80 98.00
Telmisartan And/Or its 3,272.5 Methanol 3,337.70 98.05 intermediates 0
Dimethyl 35. 969.60 952.00 98.18 formamide
Acetone 295.10 290.00 98.27
Acetic acid 470.60 462.00 98.17
Atorvastatin And/Or its 14,686. Methanol 14,953.00 98.22 intermediates 50
9,096.6 Cyclohexane 9,261.90 98.22 0 36. 20,739. Iso-propyl alcohol 21,112.50 98.23 70
Methyl ethyl 2,258.0 2,300.00 98.17 ketone 0
Simvastatin And/Or its 10,835. 37. Methanol 11,023.00 98.30 intermediates 90
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11,111. Toluene 11,311.30 98.23 30
14,509. Ethyl acetate 14,709.90 98.64 90
11,688. MDC 11,862.60 98.53 10
11,994. Cyclohexane 12,180.20 98.47 40
Omeprazole And/Or 23,632. Methanol 24,106.92 98.03 its intermediates 21
38. 13,490. Dichloro Methane 13,765.58 10 98.00
Acetone 667.69 654.52 98.03
Phenylephrine And/Or Iso-propyl alcohol 856.00 839.00 98.01 39. its intermediates Ethyl Acetate 500.00 491.00 98.20
ii VOC emission sources and its mitigation measures ➢ Equipment/machineries engaged in handling and storage operations will be checked prior to loading/unloading and they will be kept in proper working conditions through regular inspection and maintenance. ➢ The VOC emission in terms of handling losses will be reduced by storing solvents in a tank and handling solvent/raw material feeding will be carried out by pumps in a close loop. ➢ Proper maintenance schedule will be adhered to avoid emissions through flange joints, pump seals etc. ➢ Regular inspection of floating roof seals and proper preventive maintenance of roofs and seals for tanks. ➢ Enclosures to chemical storage area, collection of emission from loading of raw materials in particular solvents throughhoods and ducts by induced draft, and control by scrubber/dust collector to be ensured ➢ Adequate ventilation will be provided. ➢ All rotating equipments like pump will be installed with mechanical seals to arrest any sort of emissions.
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➢ Airborne dust at all transfers operations will be controlled either by spraying water or providing enclosures. H ➢ Details regarding storage of Hazardous chemicals Storage details Name of major Hazardous Remarks chemicals Storage tanks Toluene --- Methanol Drum/Barrel storage N-propanol --- Tri ethyl Amine Fresh IPA Ethanol Acetonitrile Thionyl chloride HCl Glass Bottle Liquid Bromine Liquid Bromine should be stored in a cool, dry, well-ventilated area away from sources of moisture. Keep glass container tightly closed and in a well- ventilated place. Store at +5°C to +30°C.
➢ Applicability of PESO: PESO will be obtained after getting EC. • During the meeting dated 19/03/2020, the project was appraised based on the information furnished in the EIA Report and details submitted by PP. • The baseline environmental quality has been assessed for various components of the environment viz. air, noise, water, biological and socioeconomic aspect for the study area of 10 km radial distance from project site for the period October 2019 to December 2019. Ambient Air Quality monitoring was carried out for PM10, PM2.5, SO2, NOX, NH3, CO, HCL & VOC at eight locations, including the project site. Values conform to the prescribed standards for Ambient Air Quality. The incremental Ground Level Concentration (GLC) has been computed using ISCST – 3. The resultant concentrations are within the NAAQS. The modeling study proved that the air emissions from the proposed plant would not affect the ambient air quality of the region in any significant manner. The ambient air quality around the proposed project site will remain within the National Ambient Air Quality Standards (NAAQS). • Risk assessment including prediction of the worst-case scenario and maximum credible accident
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scenarios has been carried out. The detail proposed safeguard measures including On-Site / Off-Site Emergency Plan has been covered in the RA report. • Committee noted that proposal is new in GIDC Sayakha. Source of water is GIDC. PP submitted that high COD/TDS effluent generated from process will be segregated and treated in in-house primary ETP – 1 followed by stripper and treated effluent will be subjected to MEE, Condensate of MEE will be send to ETP – 2 while concentrated will be treated in ATFD and generated salt/residue will be disposed in approved TSDF while Low COD/TDS effluent generated from washing, boiler blow down & cooling tower blow down will be treated in ETP – 2 compromising of primary, secondary and tertiary treatment along with MEE Condensate and treated effluent will be discharged into CETP of Sayakha GIDC via Underground pipeline for final treatment and disposal. PP submitted that they have proposed one steam boiler and one TFH. Fuel used will be Natural Gas/ Agro Briquettes /Coal. PP has submitted Hazardous Waste as per HWR – 2016. Committee noted that PP has submitted EMP & CER satisfactorily. • Compliance of ToR found satisfactory. • After detailed discussion, Committee unanimously decided to recommend the project to SEIAA, Gujarat for grant of Environment Clearance. 1 SIA/GJ/IND2/28859/2019 M/s. Phorvik Pharma Intermediate Appraisal Block Number 452, Village indrad, Tehsil, Kadi, District- Mehsana. =
6. SIA/GJ/IND2/50056/2020 M/s.Nectarine Biopharma & chemicals Screening and acoping Plot No. T-5, GIDC-Saykha,Ta-Vagra, Dist.: Bharuch, Gujarat
Category of the unit: 5(f)
Project status: New • This office has received an application vide their online proposal no. SIA/GJ/IND2/50056/2020 dated 04/03/2020 made by project proponent (PP) regarding grant of Terms of Reference [ToR] for preparation of EIA/EMP report. • Project proponent (PP) has submitted Form-1, PFR and relevant details/information. • This is a new unit proposes for manufacturing of synthetic organic chemicals as tabulated below: SR QUANTITY NO. PRODUCT NAME MT/M CAS NO END USE
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88150-42- 1 AMLODIPINE 9 ANTIHYPERTENSI VE
134523- 2 ATORVASTATIN CALCIUM 00-5 ANTICHOLESTROL TRIHYDRATE
120202- 3 CLOPIDOGREL BISULPHATE 66-6 PLATELET 75.00 INHIBITOR MT/M 69655-05- 4 DIDANOSINE 6 ANTI RETROVIRAL
217087- PROTON PUMP 5 ESOMEPRAZOLE MAGNESIUM 09-7 INHIBITOR TRIHYDRATE
84625-61- 6 ITRACONAZOLE 6 ANTIFUNGAL
103577- 7 LANSOPRAZOLE 45-3 ANTIULCERATIVE
165800- 8 LINEZOLID 03-3 ANTIBIOTIC
73590-58- PROTON PUMP 9 OMEPRAZOLE 6 INHIBITOR
164579- PROTON PUMP 10 PANTOPRAZOLE SODIUM 32-2 INHIBITOR SESQUIHYDRATE
148553- 11 PREGABALIN 50-8 ANTIEPILEPSY
12 SITAGLIPTIN PHOSPHATE 654671-78-0 ANTIDIABETIC
139481- 13 CANDESARTAN 59-7 CARDIOVASCULAR
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129938- 14 DAPOXETINE HYDROCHLORIDE ANTI 20-1 DEPRESSANT
141625‐ 15 DRONEDARONE HYDROCHLORIDE ANTI ARRHYTHMIC 93-6
143491- 16 EMTRICITABINE 57-0 ANTIRETROVIRAL
202409- 17 ETORICOXIB ANTI RHEUMATIC 33-4
150812- 18 EZOGABINE ANTICONVULSANT 12-7
153439- 19 FEXOFENADINE HYDROCHLORIDE ANTIHISTAMINE 40-8
172152- 20 ILAPRAZOLE PROTON PUMP 36-2
102767- 21 LEVETIRACETAM ANTI 28-2 CONVULSANT
70374-39- 22 LORNOXICAM ANTI 9 INFLAMMATORY
192927- 23 MOXIFLOXACIN HYDROCHLORIDE ANTI INFECTIVE 63-2
132539- 24 OLANZAPINE ANTI PSYCHOTIC 06-1
144689- 25 OLMESARTAN MEDOXIMIL ANTI 63-4 HYPERTENSIVE
389574- 26 PRASUGREL HYDROCHLORIDE PLATELET 19-0 INHIBITOR
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123447- 27 PRULIFLOXACIN ANTI BIOTIC 62-1
111974- 28 QUETIAPINE FUMARATE ANTI PSYCHOTIC 72-2
117976- 29 RABEPRAZOLE SODIUM ANTI ULCERATIVE 90-6
518048- 30 RALTEGRAVIR ANTIRETROVIRAL 05-0
147098- 31 ROSUVASTATIN CALCIUM ANTI LIPEMIC 20-2
79559-97- 32 SERTRALINE HYDROCHLORIDE ANTI 0 DEPRESSANT
175591- 33 TAPENTADOL HYDROCHLORIDE ANALGESIC 09-0
144701- 34 TELMISARTAN ANTI 48-4 HYPERTENSIVE
202138- 35 TENOFOVIR DISOPROXIL FUMARATE ANTI RETROVIRAL 50-9
36 TIOCONAZOLE 65899-73-2 ANTI FUNGAL
137862- 37 VALSARTAN CARDIOVASCULAR 53-4
99300-78- 38 VENLAFAXINE HYDROCHLORIDE ANTI 4 DEPRESSANT
137234- 39 VORICONAZOLE ANTI FUNGAL 62-9
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142340- 40 ADEFOVIR ANTI HAPATITIS B 99-6
129722- 41 ARIPIPRAZOLE ANTIPSYCHOTIC 12-9
85650-56- 42 ASENAPINE MALEATE 2 ANTISCHIZOPHRE NIA
127294- 43 BALOFLOXACIN DIHYDRATE 70-6 ANTIHYPERTENSI VE
132203- 44 CILNIDIPINE 70-4 ANTIBIOTIC
211915- CALCIUM 45 DABIGATRAN ETEXILATE MESYLATE 06-9 CHANNEL BLOCKER
143322- 46 ELETRIPTAN 58-1 ANTIMIGRAINE
274901- ANTI- 47 VILDAGLIPTIN 16-5 HYPERGLYCEMIC
286930- 48 FESOTERODINE FUMARATE 03-8 ANTIMUSCARINIC
114084- 49 IBANDRONATE SODIUM 78-5 ANTIHYPERCALCE MIA
175481- 50 LACOSAMIDE 36-4 ANTIEPILEPTIC
130018- 51 LEVOCETIRIZINE DI 77-8 ANTIHISTAMINE HYDROCHLORIDE
668270- 52 LINAGLIPTIN 12-0 ANTODIABETIC
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367514- 53 LURASIDONE HYDROCHLORIDE 88-3 ANTIPSYCHOTIC
158966- 54 MONTELUKAST SODIUM 92-8 ANTIASTHAMA
55985-32- CALCIUM 55 NICARDIPINE HYDROCHLORIDE 5 CHANNEL BLOCKER
147511- 56 PITAVASTATIN CALCIUM 69-1 ANTICHOLESTROL
105462- 57 RISEDRONATE SODIUM 24-6 ANTIOSTEOPORO SIS
709031- 58 SAXAGLIPTIN HYDROCHLORIDE 78-7 ANTIDIABETIC
160970- 59 SILDOSIN 54-7 ALPHA- ADRENERGIC
60 TAMSULOSIN HYDROCHLORIDE 106463-17-6 ALPHA- ADRENERGIC 10405-02- MUSCARINIC 61 TROSPIUM CHLORIDE 4 ANTAGONIST
249296- 62 VARENICLINE TARTRATE 44-4 ANTINICOTINE
31431-39- ANTIPARASITIC 63 MEBENDAZOLE 7 WORM INFESTATIONS
54182-58- 64 SUCROSE OCTASULFATE 0 ANTIULCERATIVE AMMONIUM SALT
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PENTASODIUM_[2-[17-(1- 65 HYDROXYETHYL)-22- [[2-[[3- 8068-28-8 HYDROXY-2-[[2-(6- ANTIBIOTIC METHYLOCTANOYLAMINO)-4- (SULFONATOMETHYLAMINO)BUTANO YL]AMINO]
66 DIMETHYL (E) – BUT – 2 - ENEDIOATE 624-49-7 ANTIPSORIASIS
6 – 4 – METHOXY – 3 – TRICYLO - 3. 106685- 67 3. 1. 1 – DEC – 40-9 1–YLPHENYLNAPTHALENE–2- ANTIACNE CARBOXYLIC ACID
114798- 68 LOSARTAN ACE INHIBITOR 26-4
187164- 69 LULICONAZOLE ANTIFUNGAL 19-8
PHARMA 70 2, 4 DI CHLORO PYRIMIDINE 3934-20-1 INTERMEDIATE
10538-55- PHARMA 71 URSODEOXYCHOLIC PYRIMIDINE 3 INTERMEDIATE
906093- 72 TENALIGLIPTIN ANTIDIABETIC 29-6 9.00 MT/M
2CHLOROBENZLDEHYDE5- 33513-44- PHARMA 73 SULFONICACID SODIUMSALT 9 INTERMEDIATE
54029-45- PHARMA 74 2 - NITRO 4 – THIOCYNO ANILINE 7 INTERMEDIATE
PHARMA 75 META BROMO NITRO BENZENE 585-79-5 INTERMEDIATE
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PHARMA 76 META BROMO ANISOLE 2398-37-0 INTERMEDIATE
R-1-2-7-CHLOROBENZO- 147403- PHARMA 77 THIOPHENE-3-YL- METHOXY-2- 03-0 INTERMEDIATE 2-4-DICHLOROPHENYL-1H- IMIDAZOLE
2 –CYCLOHEXYLIDENE –HYDRAZINE 934371- PHARMA 78 O –2 -(3, 4 - 48-9 INTERMEDIATE DIHYDROXYBENZYL)- PROPIONICACIDMETHYL ESTER
116313- PHARMA 79 3,4-DIHYDROXY 5- 85-0 INTERMEDIATE NITROBENZALDEHYDE
[N-[(4-methylphenyl)Sulfonyl]- 21187-98- PHARMA 80 hydrazidecarboxamide] 4 INTERMEDIATE
23088-28- PHARMA 81 CPDCA 0 INTERMEDIATE
2-BENZYL AMINO-1-6-FLUORO-3-4- 12900050- PHARMA 82 DIHYDRO-2- H-CHROMEN-2-YL- 27-7 INTERMEDIATE ETHANOL
ISOPROPYL -2S-2-S-PENTA FLUORO 1334513- PHARMA 83 PHENOXY 02-8 INTERMEDIATE PHOSPHORYL AMINO PROPANOATE
3,4 – DIHYDRO -7- HYDROXY 37074-40- PHARMA 84 NAPHTHALEIN – 1- 1 INTERMEDIATE 2H-ONE
5-{4-[(4-(5-CYANO-1H-INDOL-3- 1451194- PHARMA 85 YL)-BUTYL]- PIPERAZIN-1-YL}- 35-6 INTERMEDIATE BENZOFURAN-2- CARBOXYLATE METHYL
136434- 86 DULOXETINE HYDROCHLORIDE ANTI DEPRESSANT 34-9
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219861- 87 ESCITALOPRAM OXALATE ANTI DEPRESSANT 08-2
0.95 MT/M 173334- RENIN INHIBITORS 88 ALISKIREN HEMIFUMARATE 58-2
863031- 89 AZILSARTAN MEDOXOMIL ANTIHYPERTENSIV 21-4 E
224785- 90 VARDENAFIL PDE INHIBITOR 90-4
91 R& D products 0.05 MT/M - R& D PRODUCTS
85.00 MT/M
• The project falls under 5(f) as per the schedule of EIA Notification 2006. • This project was considered in SEAC meeting dated 19/03/2020. • Salient features of project are as follows.
Sr. Particulars Details no.
A Total cost of Proposed Project (Rs. in 4.8 Crores Crores): B Total Plot area ( sq. meter) 5000 Sq. m. Green belt area ( sq. meter) 1650 Sq. m. C Employment generation 25 D Water i Source of Water Supply GIDC water supply letter issued GIDC/DEE(WS)/BRH/782 (GIDC Bore well, Surface water, Tanker supply etc...)Status of permission from the concern authority. ii Water consumption (KLD)
Category Quantity Remarks
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KLD
(M) Domestic 4.00 (N) Gardening 7.50 (O) Industrial Process 32.50 Washing 6.00 scrubber Boiler 5.00 Cooling 5.00 Hot Water Generator -- Industrial Total 48.50 Total (A + B + C) 60.00
4) Total water requirement for the project: 60 KLD 5) Quantity to be recycled: 0.0 KLD 6) Total fresh water requirement: 60 KLD (Total water requirement = Fresh water + Recycled water)
Iii Waste water generation (KLD) Category Waste water Remarks KLD (G) Domestic 2.50 (H) Industrial Process 39.50 Washing 4.50 Scrubber Boiler 2.50 Cooling 3.50 Total Industrial 50.00 waste water Total [A + B] 52.50
Iv Treatment facility within premises with capacity [In-house ETP (Primary, Secondary), MEE, Stripper, Spray Dryer, STP etc. LOW COD ➢ Primary, SecondaryTreatment ETP with capacity of 60 KLD
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The industry has less space in site premises. For low COD waste water will be treated in our ETP & High COD water (Filter mother liquor (ML)/ Solvent reduce / High COD contain will not be treated in our ETP so that we will sent it to Co-process/ Incineration. so we have not establish ETP for High COD
Treatment scheme including segregation at source.
Note: (In case of CETP discharge) : Management of waste water keeping in view direction under section 18 (1) (b) of the Water (Prevention and Control of Pollution) act, 1974 issued by CPCB regarding compliance of CETP. Brief note on adequacy of ZLD (In case of Zero Liquid Discharge): Not Applicable V Mode of Disposal & Final meeting point Domestic: Disposed through septic tank/ soak pit Industrial: Total Waste Water generation 39.5 KLD will be from Process and total 50 KLD waste water to be sent to CEPT Saykha.135 MT/month High COD water cum residue generated from process in terms of ML, Distilled residue etc. This will be sent to co-process /CHWIF of BEIL Ankleshwar / SEPPL. The industry has less space in site premises. For low COD waste water will be treated in our ETP & High COD water (Filter mother liquor (ML)/ Solvent reduce / High COD contain will not be treated in our ETP so that we will sent it to Co-process/ Incineration. so we have not establish ETP for High COD
Low COD
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Vi In case of Common facility (CF) like CETP, Common Spray dryer, Common MEE etc. Name of CF Membership of Common facility (CF) (For waste water treatment) GIDC- GIDC/BRH/DEE(DRG)/584, DATE 16/10/2019 vii Simplified water balance diagram with reuse / recycle of waste water
Water Balance for Low COD
For High COD The industry has less space in site premises. For low COD waste water will be treated in our ETP & High COD water (Filter mother liquor (ML)/ Solvent reduce / High COD contain will not be treated in our ETP so that we will sent it to Co-process/ Incineration. so we have not establish ETP for High COD viii Reuse/Recycle details (KLD)
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Total reuse 0.KLD NIL E Air I Flue gas emission details No. of Boilers/TFH/Furnaces/DG sets etc. with capacities viz. TPH, Kcal/hr, MT/hr, KVA etc.
Fuel Requirement Bio coal – 2.5 MT/Day, LDO / Diesel – 20 LT/Hr
Air Type of Source Stack Pollution Sr. Type of emissions Permissib of Height Control no. Fuel i.e. Air emission (meter) Measures le Limit Pollutants WithCap (APCM) acity Mechanical 1. Steam 22 m Bio coal/ dust Boiler Briquettes collector (Capacity /Coal & Water -2 MT) PM Scrubber Thermic SOX Mechanical 150 Bio coal/ NOX 2. fluid 22 m dust mg/Nm3 Briquettes heater collector Capacity - /Coal 100 ppm & Water 4 lakh k Scrubber 50 ppm cal D.G. Set Adequate 3. (Capacit 11 m Diesel Stack y -250 Height KVA)
Ii Process gas emission details i.e.Type of pollutant gases (SO2, HCl, H2S, NH3, Cl2, NOxetc.)
AirPollution Sr. Type of Stack/Ven Source of emission Control no. emission Permist Height Measures (APCM) sible (meter) limit Process Vent-I Multi cyclone 1. (attached to Drier & PM 150 11 Separator/ Cooler) BagFilter Cl2, 9 Process Vent-II HCl, 20 Alkali Scrubber 2. 11 (attached to HBr 5 Reaction Vessel)
Iii Fugitive emission details with its mitigation measures: As below:
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• All the raw materials will be stored in isolated storage area and containers tightly closed. • The unit will also develop green belt within the factory premises to control the fugitive emission from spreading into surrounding environment. • A regular preventive maintenance will be planned to replace or rectify all gaskets, joints etc. F Hazardous wastes (As per the Hazardous and Other Wastes (Management and Transboundary Movement) Rules 2016.
I Sr Cat Total Hazardous waste Quantity Method of disposal . . (MT/Annum) No No . Collection, Storage, Sch-I/ 0.16 1 Used Oil Reuse or sell to 5.1 MT/Month RegisteredRefiners. Collection, Storage, Discarded/Containers/ Sch-I/ 25 2 ReuseorselltoGPCB Barrels/ liners 33.1 MT/Month authorizedvendor. Collection, Storage 3 ETP sludge Sch-I/ 11.00 &sendtocommon TSDF site 35.3 MT/Month BEIL Dahej.
Collection, Storage &sendtocommon TSDF site BEIL Dahej. To be Consider 4 Organic Process Sch-I/ 15.50 Group - 1(Product No: 29) Waste 28.1 MT/Month &Group -3(Product No: 89)
Collection, Storage &send to Inorganic Process Sch-I/ 23.50 common TSDF site BEIL 5 Waste 28.1 MT/Month Dahej. To be Group- 1(Product No: 3,38) & Group - 3(Product No: 86,87)
Collection, Storage & sent toCo-process/Incineration BEIL / SEPPL To be Sch-I/ Consider Group -1(Product 6 Distillation Residue 36.1 135.00 No: 54), Group -2(Product MT/Month No: 73) & Group -3(Product No: 89)
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Collection, Storage&sendtoCo- process/ Incineration BEIL/ (SEPPL, To be Group -1(Product No: 7 54), Group - 2(Product No: 30.80 Spent Carbon 72) & Group -3(Product MT/Month No:88)
7.50 Collection, Storage&sendto 8 Spent Catalyst MT/Month Co process/Incineration BEIL- /(SEPPL. To be Group - 1(Product No:53)
Collection, Storage &CaptiveConsumption or sell SCH- to enduser/s having Rule 48.5 9 H2SO4 Solution II/ B- 9Permission. To be 15 MT/Month Consider Group - 2(Product No:75)
Collection, Storage &Captive Consumption or sell to enduser/s. having Rule9 10 Sodium Sulphate 7.50 Permission. To be Consider MT/Month Group - 1(Product No: 29
Collection, Storage & Captive consumption or sell to enduser/s. having Rule 9 Permission. To be Consider Phosphoric Acid 141.00 Group - 1(Product No: 11 MT/Month 34(2))& Group - 2(Product No: 70)
Collection, Storage & Captive Consumption or sell to enduser/s. having Rule 9 Sodium Nitrite 22.50 Permission. To be Consider 12 Group - 1(Product No: 29(2)) MT/Month
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Collection, Storage & Captive Consumption or sell HBR 35.00 to enduser/s. having Rule 9 13 Permission. KL/Month
Collection, Storage & Captive Consumption or sell HNO3 55.00 to enduser/s. having Rule 9 14 Permission. KL/Month Collection, Storage & Captive Consumption or sell Dilute HCl 23.00 to enduser/s. having Rule 9 15 Permission. KL/Month
Sodium Bi-Sulphite Collection, Storage & Solution 37 Captive Consumption or sell 16 KL/Month to end user/s. having Rule 9 Permission.
Collection, Storage & Captive Consumption or sell Mix Solvent 200.00 to enduser/s. having Rule 9 Permission. 17 KL/Month
Ii Membership details of TSDF, CHWIF etc. M/s. BEIL Infrastructure Limited (formally (For HW management) known as Bharuch Enviro Infrastructure Limited) & SEPPL
Iii Details of Non-Hazardous waste & its disposal Dust collected from dust collector will be sent to brick manufacturer or TSDF. (MSW and others) G Solvent management, VOC emissions etc.-- I Types of solvents, Details of Solvent recovery, % recovery, reuse of recovered Solvents etc. (Details in Table Format) : It will be given in EIA report. Ii VOC emission sources and its mitigation measures : It will be given in EIA report H Details regarding storage of Hazardous chemicals submitted.
• Committee noted that this proposal is new unit at GIDC, Saykha. Looking to proposed product profile, Committee insisted for technical justification regarding proposed production plant size.PP has shown 50 KLD waste water generation and it will be segregated in High COD and Low COD stream alongwith Low COD characteristic.Low COD will be treated in primary and secondary ETP and then treated effluent will be
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sent to CETP of Saykha for further treatment and disposal.High COD stream will be sent to Co-processing and Incineration but its characteristic and treatment is not mentioned. • Biocoal and coal will be used as fuel in proposed boiler and thermopack. Multi dust collector and water scrubber will be provided as APCM with boiler and thermo pack. • Single stage alkali scrubber will be provided as APCM with process gas emission reactor and MCS and bag filter as APCM with drier and cooler . • Considering the above project details, after detailed discussion, the terms of reference (ToR) were prescribed as below and as per the standard TOR for the Synthetic Organic Chemical projects recommended by SEAC vide letter no. EIA-10-GEN-21/1480 dated 14/09/2017 and approved by SEIAA in its 12th meeting dated 16/09/2017 for the EIA study to be done covering 10 Km radial distance from the project boundary. 1. Technical justification regarding proposed production size and 69 bulk drug products mentioned in one group. 2. Adequacy of High COD effluent disposal for co-processing and Incineration without any sort of inhouse treatment. Also submit high COD effluent quantity and quality considering worst case scenario with mentioning BOD,COD,TDS and Ammonical nitrogen characteristics. 3. Leak Detection and Repairing Programme (LDAR) for all the volatile organic solvent proposed for use in-house with detailed chemical properties including vapor pressure. LDAR shall endeavor prevention of losses of solvents to the best minimum extent. 4. Membership Certificate from Common Facility (mentioning total capacity, consented quantity, occupied capacity and spare capacity and norms of acceptance of effluent from member units) in-line with the direction given by GPCB vide Letter No. GPCB/P-1/8-G (5)/550706 dated 08/01/2020. 5. Segregation of waste water streams based on characteristics and its proper management keeping in view direction under section 18 (1) (b) of the Water (Prevention and Control of Pollution) act, 1974 issued by CPCB regarding compliance of CETP(COD, BOD, TDS etc. of each stream shall be given) . 6. Submit justification regarding common APCM with process reactors and revised hazardous waste matrix considering adequate disposal of Hazardous waste with justification regarding adequacy of reuse in which process with its quantity and mass balance. 7. Compliance of MoEFCC’s OM dated 01/05/2018 regarding “Corporate Environment Responsibility” (CER). Fund allocation for Corporate Environment Responsibility (CER) shall be made as per MoEFCC’s O.M. No. 22-65/2017-IA.III dated 01/05/2018 for various activities therein. The details of fund allocation and activities for CER shall be incorporated in EIA/EMP report. 8. Explore the use of renewable energy to the maximum extent possible. Details of provisions
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to make the project energy-efficient through of energy efficient devices and adoption of modes of alternative eco-friendly sources of energy like solar water heater, solar lighting etc. Measures proposed for energy conservation. 9. PP shall furnish status of all the applicable rules, acts, regulation, clearances in a tabular form. 10. Safety precautions including flame proof electric fittings to be taken to avoid fire hazard during unloading, storage, transportation, handling and processing of Solvents.
• The TOR prescribed as above and as per the standard TOR approved by SEIAA and the model ToRs available in the MoEFCC’s sector specific EIA Manual for ‘Synthetic Organic Chemical Industry’ shall be considered as generic TORs for preparation of the EIA report in addition to all the relevant information as per the generic structure of EIA given in Appendix III in the EIA Notification, 2006.
• Further Project Proponent may be advised to submit final EIA Report with EC application within 100 days from the date of issuance of this ToR to expedite processing of Environment Clearance application.
• The project proponent shall have to apply for Environmental clearance through online portal http://environmentclearance.nic.in/ along with final EIA report.
7. SIA/GJ/IND2/51021/2020 M/s.Darshan Industries Screening and scoping Plot No. D-2-CH-95, GIDC-Dahej-II,Ta- Vagra, Dist.: Bharuch, Gujarat
Category of the unit: 5(f) Project status: New • This office has received an application vide their online proposal no. SIA/GJ/IND2/47571/2019 dated 11/03/2020 made by project proponent (PP) regarding grant of Terms of Reference [ToR] for preparation of EIA/EMP report. • Project proponent (PP) has submitted Form-1, PFR and relevant details/information. • This is new unit proposes for manufacturing of synthetic organic product as tabulated below: Sr. CAS no. /CI Quantity End-use of the No Name of the Products no. MT/Month products . 1. Di Methyl Amino Ethyl Chloride 4584-46-7 Antibacterial Hydrochloride 2. Di Ethyl Amino Ethyl Chloride 869-24-9 Antibacterial hydrochloride 100 3. cis-2-(2,4-Dichlorophenyl)-2-(1H-1,2,4- 67914-86-7 ltraconazole Triazol-1-yl methyl)-1,3-Dioxolan-4- ylmethyl] methane sulfonate 4. 2-[3-[4-(m-chlorophenyl)-1- 25332-39-2 Trazodone HCl
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piperazinyl]propyl]s-triazolo[4,3-a]- pyridin-3(2H)-one monohydrochloride 5. 7-(4-Bromo-butoxy)-3,4-dihydro-1H- 129722-34-5 Aripiprazole quinolin-2-one 6. Meloxicam 71125-38-7 Painkiller 7. (4aS, 7aS)-2,3,4,4a,5,6,7,7a-octahydro- 151096-09-2 Moxifloxacin Nonane 1H-pyrrolo[3,4-b]pyridine-6-yl]-1- cyclopropyl-6-fluoro-8-methoxy-4- oxoquinoline-3-carboxylic acid none 8. Tetra-butyl 2-((4R,6R)-6-(2-aminoethyl)- 125995-13-3 Atorvastatin 2,2-dimethyl-1,3-dioxan-4-yl)acetate 9. 2-Chloro Ethyl Amine Hydrochloride 870-24-6 Ifasamine 10. N,N, Bis (2-Chloro Ethyl) Amine 821-48-7 Piperazine Hydrochloride derivatives 11. 4-(2-Chloroethyl)morpholine 3647-69-6 Floredil hydrochloride 12. 3-(cyclopropylmethoxy)-4- 672883-68-0 Anti-inflammatory (difluoromethoxy) benzoylchloride 13. 2-((4-(2-methoxyethyl)phenoxy)methyl) 56718-70-8 Metropolol 14. 1-(4-Aminophenyl)-4-(4-Methoxyphenyl) 74852-62-3 ltraconazole Piperazine 15. cis-(2,4-Dichlorophenyl)-2-(1H-1,2,4- 67914-86-7 ltraconazole Triazol-1-yl)Methyl-1,3-Dioxolan-4-yl methanol 16. Carbazepamine 298-46-4 Anticonvulsant 17. 1-(3-Methyl-1-phenyl-5- 401566-79-8 Teneligliptin pyrazolyl)Piperazine 18. 1-[2-(2-Hydroxyethoxy)ethyl]piperazine 13349-82-1 Quetiapine 19. 2-(4-(4-chlorobenzoyl)phenoxy-2- 42017-89-0 Fenofibric Acid methylpropanoic acid 20. 1-(2,4-difluorophenyl)-2-(1,2,4-triazol-1- 86404-63-9 Fluconazole yl)ethanone 21. Tert-butyl 4-oxo-2-(1,3-thiazolidin- 3-yl 401564-36-1 Teneligliptin carbonyl) pyrrolidine-1-carboxylate 22. N-(trans)-4-hydroxycyloohexyl)acetamide 27489-60-7 Pramipexole 23. (S)-2-((2- 446292-08-6 Rivarxoban oxomorpholino)phenyl)oxazolidin-5- yl)isoindoline-1,3-dione 24. sodium 3-oxo-3H-[1,2,4]triazolo[4,3- 6969-71-7 Trazodone HCl a]pyridin-2-ide 25. Tert-butyl 2-((4R,6R)-6-(2-(2-(4- 125971-95-1 Atorvastatin fluorophenyl)-5-isopropyl-3-phenyl-4- (phenylcarbamoyl)-1H-pyrrol-1-yl)ethyl)- 2,2-dimethyl-1,3-dioxan-4-yl)acetate 26. 2-Chloro-1-(2,4-difluorophenyl)ethanone 51336-94-8 Fluconazole 27. (R)-5-(2-aminopropyl)-2-methoxy 112101-81-2 Tamsulosine benzene sulfonamide 28. 2-[3-Cyano-4-(2-methylpropoxy) phenyl]- 160844-75-7 Febuxostat 4-methyl-5-thiazole carboxylic Acid 29. 1-[2-(2,4-di fluorophenyl)-2,3- 86386-76-7 Fluconazole epoxypropyl]-1H-1,2,4-Triazole 30. 4-Sulphanamido Phenyl Hydrazine 17852-52-7 Anti-inflammatory Hydrochloride
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31. (E)-7-((1R,2R,3R,5S)-3,5-dihydroxy-2- 38344-08-0 Bimatoprost Acid ((E)-3-hydroxy-5-phenylpent-1-en-1- yl)cyclopentl)hept-5-enoic acid 32. [5-(2-Benzyloxy-5-bromo-phenyl)-1- - Fesoterodine fumrate methyl-5-phenyl-pentyl]-isopropyl-amine 33. N-(4-oxocyclohexyl)acetamide 27514-08-5 Pramipexole 34. (3R)-3-(tert.butoxy carbonylamino-1-[3- 486480-00-8 Sitagliptin (trifluoromethyl)-5-6- dihydro[1,2,4]triazolo[4,3-a] pyrazin- 7(8H)-yl]-4-(2,4,5-triflurophenyl)butan-1- one 35. ethyl 3-(cyclopropylamino)-2-(2,4,5- 112811-70-8 Moxifloxacin trifluoro-3-methoxy-benzoyl)prop-2- enoate 36. 4-[4-[(4-Methoxyphenyl)-1-Piperazinyl] 252964-68-4 ltraconazole Phenyl] 2 4-Dihydro-3H-1,2,4-Triazol-3- On 37. 4-[4-[(4-Methoxyphenyl)-1-Piperazinyl] 106461-41-0 ltraconazole Phenyl] 2,4-Dihydro-2-(1-Methyl propyl)- 3H-1,2,4-Triazol-3-One 38. 3-(2-Benzyloxy-5-bromo-phenyl) -3- 950773-38-3 Fesoterodine fumrate phenyl-propan-1-ol 39. 2-((4-(2- 56718-70-8 Metropolol methoxyethyl)phenoxy)methyl)oxirane 40. Moxifloxacin base 354812-41-2 Moxifloxacin HCl 41. 4-Benzyloxy-3-(5-isopropylamino-1- - Fesoterodine fumrate phenyl-hexyl)-benzoic acid methyl ester 42. 2-(2-(tert-butyldimethylsilyloxy0-2-(6- - Intermediate flurochroman-2-yl)ethylamino)-1-(6- fluorchroman-2-yl)ethanol 43. Desvenlafexine 93413-62-8 Desvenlafexine HCl 44. 1-[4-[4-(4-Methoxyphenyl)Piperazinyl] 74852-89-4 ltraconazole Phenyl] Hydrazine Carboxamide 45. 2-Amino-2-[2-(4-octylphenyl)ethyl]-1,3- 162359-55-9 Fingolimod propanediol 46. (3R,5R)-Tert-Butyl 7-(2-(4-Fluoro 134523-00-5 Atorvastatin Phenyl)-5-Isopropyl-3-Phenyl- 4-(Phenyl Carbonyl) 4-Pyrol-1-Yl)-3,5-Dihydroxy Heptanoate 47. (-/+)2,6-Diamino-4,5,6,7-tetrahydro 106092-09-5 Pramipexole benzothiazole 48. Cis –Bromo benzoate 61397-56-6 Ketaconazole 49. Cis-Imidazole alcohol 61397-58-8 Ketaconazole 50. Cis –Tosylate 154003-23-3 Ketaconazole 51. Ethyl 2-[3-Cyano-4-(2-methylpropoxy) 160844-75-7 Febuxostat phenyl]-4-methyl-5-thiazole carboxylate 52. 7-{4-[4-(2,3-Dichloro-phenyl)-piperazin-1- 1424857-68- Aripiprazole yl]- butoxy}-3,4-dihydro-quinolin-2-ol 0 53. (4aS,7aS)-6-benzyl-1,2,3,4,4a,5,7,7a- 151096-09-2 Moxifloxacin octaydropyrrolo[3,4-b]pyridine-6-yl]-1- cyclopropyl-6-fluoro-8-methoxy-4- oxoquinoline-3-carboxylic acid 54. Triphenylphosphine oxide 791-28-6 Bimatoprost
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55. Levocitrizine 2HCl 130018-77-8 Antihistamine 56. 1-Acetyl-4-(4-hydroxy phenyl)piperazine 67914-60-7 Ketaconazole 57. 3-(4-(3-chlorophenyl)piperazin-1- 32229-98-4 Trazodone HCl yl)propen-1-ol 58. (R)-2-(2-(4-((4-chlorophenyl)oxirane 83881-56-5 Cetirizine (phenyl)methyl)piperazin- 1- Dihydrochloride yl)ethoxy)acetamide 59. Ethyl 2-[3-Formyl-4-(2-methylpropoxy) 161798-03-4 Febuxostat phenyl]-4-methyl-5-thiazole carboxylate 60. 2-(3-(4-(3-chlorophenyl)piperazin-1- 19794-93-5 Trazodone HCl yl)propyl)-[1,2,4]triazolo[4,3-a]pyridin- 3(2H)-one 61. 1-cyclopropyl-6,7-difluoro-8-methoxy-4- 112811-71-9 Moxifloxacin oxo-quinoline-3-carboxylic acid 62. Tamsulosin Base 106138-88-9 benign prostatic hyperplasia 63. 7-(4-Bromo-butoxy)-3,4-dihydro-1H- 22246-18-0 Aripiprazole quinolinone 64. Levatiracetam 102767-28-2 Epilepsy 65. 1 – Methyl– 3–Phenyl Piperazine 5271-27-2 Mirtazapine 66. Rivaroxaban 366789-02-8 Anticoagulant 67. Finofibrate 49562-28-9 hypercholesterolemia 68. 4-[4-[(4-Hydroxyphenyl)-1-Piperazinyl] 106461-41-0 ltraconazole Phenyl] 2,4-Dihydro-2-(1-Methyl propyl)- 3H-1,2,4-Triazol-3-One 69. 5-(4-(4-(5-Cyano1H-indol-3-yl)- butyl)- 163521-19-5 Vilazodone HCl piperazin-1- yl)benzofuran-2- carboxamide 70. Acetamide,N-[1,1-bis(acetyloxy)methyl]- 162358-09-0 Fingolimod 3-(4-octylphenyl)propyl R&D 10 KG/Month TOTAL 100 MT/Month • The project falls under Category B of project activity 5(f) as per the schedule of EIA Notification 2006. • This case was considered in the SEAC meeting dated 19/03/2020. • Salient features of the project including Water, Air and Hazardous waste management : Sr. Particulars Details no. A A Total cost of Proposed Project 4.88 Crores (Rs. in Crores): B Total Plot area ( sq. meter) 5000.0 Green belt area 1371.2 Sq m. in plant premises ( sq. meter) + 280 Sq. m. in font side of plant along road side = 1651.2 Sq m. (33% of plant area) C Employment generation Direct = 20 Employees Indirect = 10 Employees D Water i Source of Water Supply GIDC Water Supply Letter 613th meeting of SEAC-Gujarat, dated 19.03.2020 Page 148 of 217
(GIDC Bore well, Surface water, Tanker supply etc...) Status of permission from the concern authority. Letter No.: GIDC/DEE(WS)/BRH/895 ii Water consumption (KLD)
Category Proposed Remark (KL/Day) (P) Domestic 7.0 Source: GIDC Water Supply (Q) Gardening 7.0 (R) Industrial Process Worst Case: 5-(4-(4-(5-Cyano1H- 100 indol-3-yl)- butyl)-piperazin-1- yl)benzofuran-2- carboxamide Washing 8.5 Boiler 10.0 Cooling 3.0 Others (Scrubber) 8 Total Ind. 129.5 Total (A+B+C) 143.5
1) Total water requirement for the project: 143.5KLD 2) Quantity to be recycled:NilKLD 3) Total fresh water requirement: 143.5KLD (Total water requirement = Fresh water + Recycled water) iii Waste water generation (KLD) - Category Proposed Mode of disposal (KL/Day) (I) Domestic 6.0 Septic tank & Soak pit (B) Industrial Process 100 Worst Case: 5-(4-(4-(5- Cyano1H-indol-3-yl)- butyl)- piperazin-1- yl)benzofuran- 2- carboxamide Washing 8.5 Boiler 2.5 Cooling 1.0 Scrubbing Solution 2.5 Treated with effluent in ETP (10 % NaCl) Scrubbing Solution 2.5 To End User (20-22% Na2SO3) Scrubbing Solution 2.0 To End User (30-35 % NaBr/HBr) Scrubbing Solution 1.0 Reused within premises. (30 % Liq. Ammonia) Total Ind. 120.0 Total (A+B) 126.0 iv Treatment facility within premises with capacity [In-house ETP (Primary, Secondary, Tertiary), MEE, Stripper, Spray Dryer, STP etc. ➢ Hydraulic Load: • *Dilute Stream: ETP 1:14.5 KLD • ** Concentrate Stream: ETP 2: 100.0 KLD, Solvent Stripper: 100 KLD & MEE: 98.5 KLD
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• Combine Effluent (*Dilute Stream+** Concentrate stream): Secondary&Tertiary ETP: 111 KLD
➢ In-houseCapacity: • *Dilute Stream: ETP 1: 20.0 KLD • ** Concentrate stream: ETP 2: 130.0 KLD, Solvent Stripper: 110 KLD & MEE: 128 KLD • Combine Effluent (*Dilute Stream+** Concentrate stream): Secondary&Tertiary ETP: 150 KLD
Treatment scheme including segregation at source. ➢ *Dilute Stream 14.5 KLD (2.5 KLD from Boiler, 1.0 KLD from cooling, 8.5 KLD from washing & 8.0 KLD from Scrubber (2.50 KLD NaCl sent to wastewater, 1 KLD Liq. Ammonia reuse within premises & other 4.50 KLD sell to End user)) Wastewater will be treated in house primary ETP. ➢ **Concentrate Stream 100 KLD from Process effluent will be subjected to stripper + primary ETP. 98.5 KLD)Solvent stripper outlet will be allowed to in house MEE (MEE Condensate 96.5 KLD will be subjected to secondary treatment. MEE bottom will subjected to centrifuge and salt will be sent to TSDF site.)) ➢ Combine Effluent 111 KLD (*Dilute Stream 14.5 KLD + ** MEE Condensate 96.5 KLD) will be treated in house Secondary & tertiary ETP and will be sent to Common CETP, Dahej after achieving CETP Norms.
➢ High COD range from 52574mg/L (Tert-butyl 4-oxo-2-(1,3-thiazolidin- 3-yl carbonyl) pyrrolidine-1-carboxylate)to 66453 mg/l (5-(4-(4-(5-Cyano1H-Indol-3-Yl)- Butyl)-Piperazin-1- Yl) Benzo furan-2- Carboxamide) ➢ Low COD range from Boiler Blowdown 100mg/L to Washing Section 2500mg/L. Note: (In case of CETP discharge) : Management of wastewater keeping in view direction under section 18 (1) (b) of the Water (Prevention and Control of Pollution) act, 1974 issued by CPCB regarding compliance of CETP. ➢ Treated Effluent 111.0 KLD will be sent to Common CETP, Dahej. Brief note on adequacy of ZLD (In case of Zero Liquid Discharge): ➢ Not Applicable, Treated Effluent 111.0 KLD will be sent to Common CETP, Dahej. v Mode of Disposal & Final meeting point Domestic: Septic Tank & Soak Pit Industrial: • *Dilute Stream 14.5 KLD Wastewater will be treated in house primary ETP. • **Concentrate Stream 100 KLD will be treated in house Stripper + primary ETP + MEE. MEE Condensate will be subjected to in-house ETP (Secondary + Tertiary) • Combine Effluent 111 KLD (*Dilute Stream 14.5 KLD + ** MEE Condensate 96.5 KLD) will be treated in house Secondary&tertiary ETP and sent to Common ETP, Dahej. vi In case of Common facility (CF) like CETP, Common Spray dryer, Common MEE etc. Name of CF ➢ Common CETP, Dahej Membership of Common facility (CF) (For waste water treatment) ➢ Common CETP, Dahej ( Assurance Letter No. – GIDC/DEE/DRG/BRH/680) vii Simplified water balance diagram with reuse / recycle of waste water
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viii Reuse/Recycle details (KLD)
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Total reuse:- KLD
SR Para Unit Concentrate After After MEE MEE Bottom . Stream Primary Solvent Condens subjected to No (Worst Treatment Stripper ate Centrifuge . Case) Quantity (KLD) 100 100 98.5 96.5 2 1 pH pH 7-7.5 7-7.5 7-9 8-10 6-8 Unit 2 TSS mg/L 234 150 150 <30 >100 3 TDS mg/L 17420 19162 19162 <1000 >45500 4 BOD mg/L 19935 15948 11163 5581 >13000 5 COD mg/L 66453 56485 39593 19769 >45000 6 Ammo. mg/L Nitroge 30 <20 Nil Nil Nil n
SR. Para Unit Combined Effluent Dilute stream after No. (Boiler: 2.5 + Primary Treatment Cooling: 1 + washing: 8.5 + scrubber: 2.5) Quantity (KLD) 14.5 14.5 1 pH pH Unit 6-8 6-8 2 TSS mg/L 126 70 3 TDS mg/L 1062 1168 4 BOD mg/L 520 443 5 COD mg/L 1748 1486 6 Ammo. mg/L Nil Nil Nitrogen
SR. Para Unit Combine effluent (MEE After Secondary Treatment No. Condensate: 96.5 + Dilute Stage I Stage II Stream After Primary Treatment: 14.5) Quantity (KLD) 111 88.4 88.4 1 pH pH Unit 6-8 7.5 7.5 2 TSS mg/L 34 <30 <30 3 TDS mg/L 877 850 <1000 4 BOD mg/L 4911 982 <90 5 COD mg/L 17381 3476 <250 6 Ammo. mg/L Nil Nil Nil Nitrogen
E Air i Flue gas emission details No. of Boilers/TFH/Furnaces/DG sets etc. with capacities viz. TPH, Kcal/hr, MT/hr, KVA etc.
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Stack Stack Sr. Permissible attached Height/Dia. Fuel Fuel Qty. APCM No. limit to (Meter) 13.5 MCS + Bio Coal/ MT/Day Water Steam Briquette PM < 150 OR Scrubber Boiler OR mg/Nm3 1. 30/0.5 with Each (2.0 TPH) SO < 100 ppm Adequate 2 (2 nos.) Natural 7200SCM NOX< 50 ppm Stack Height Gas /Day with each 6.0 Bio Coal/ MCS + Thermic MT/Day Briquette Water PM < 150 Fluid OR OR Scrubber mg/Nm3 2. Heater 30/0.5 SO < 100 ppm (10 Lac 2 Natural 3050SCM Adequate NOX< 50 ppm KCal/Hr.) Gas /Day Stack Height
Bio Coal/ 5 MT/Day MCS + Hot Air Briquette OR Water PM < 150 Generator OR Scrubber mg/Nm3 3. 30/0.5 (9 Lac SO2< 100 ppm Kcal/Hr.) Natural 2500 Adequate NOX< 50 ppm Gas SCM/Day Stack Height
PM < 150 D.G. Set Adequate mg/Nm3 3 11/0.25 Diesel 15 lit/Hr. (125 KVA) Stack Height SO2< 100 ppm NOX< 50 ppm ii Process gas emission details i.e. Type of pollutant gases (SO2, PM,NOx etc.)
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- Sr. Height Permissib Vent attached to APCM No. (Meter) le limit
Reaction Vessel Height: 11 (Sulphonation) Meters Two Stage SO < 40 1. 3-(cyclopropylmethoxy)-4- 2 Dia: 0.2 Alkali Scrubber mg/Nm3 (difluoromethoxy) Meters benzoylchloride
Reaction Vessel Height: 11 (Chlorination) Meters Two Stage HCl < 20 2. 4-Benzyloxy-3-(5- Dia: 0.2 Alkali Scrubber mg/Nm3 isopropylamino-1-phenyl-hexyl)- Meters benzoic acid methyl ester Height: 11 Reaction Vessel Meters Two Stage HBr < 20 3. (Bromination) Dia: 0.2 Alkali Scrubber mg/Nm3 Cis –Bromo benzoate Meters Reaction Vessel Height: 11 5-(4-(4-(5-Cyano1H-indol-3-yl)- Meters Two Stage NH < 175 4. 3 butyl)-piperazin-1- Dia: 0.2 Water Scrubber mg/Nm3 yl)benzofuran-2- carboxamide Meters -
Iii Fugitive emission details with its mitigation measures: As below: • Whole process will be carried out in close loop. • Pipe line will be having minimum flange. • Pump with double mechanical seals • Proper ventilation. F Hazardous wastes (As per the Hazardous and Other Wastes (Management and Transboundary Movement) Rules 2016. I S Type of Hazardo Source Qty. Management of HW r. Hazard us (MT/ N ous Waste Year) o Waste Categor . y & Schedul e 1. ETP 35.3/SC ETP 670 Collection, Storage, Sludge H-I Transportation, disposal 2. MEE - From MEE 720 at nearest TSDF site. Salt (M/s. BEIL, Dahej) 3. Used Oil 5.1/SCH- Maintenance 2.0 Collection, Storage, I activity Transportation & Disposal by selling to Authorised re-refiners or reused as lubricant within premises.
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4. Discard 33.1/SCH- Raw Material 23.5 MT Collection, Storage, ed I Supplier (Discard Transportation & Contain ed Reuse/ Sale to ers/ Contain Authorized Vendor. Bags/Lin ers ers 1500 Nos. & Bags/Li ners 10500 Nos.) 5. Distillati 20.3/SC Mfg. Process 1130 on H-I Acetamide,N- Residue [1,1- bis(acetyloxy)met hyl]-3-(4- Collection, Storage, octylphenyl)propy Transportation & send l to pre/co-processing 6. Process 28.1/SC Mfg. Process 1970 units (cement Waste H-I Desvenlafexine industries) OR disposal (Organic at nearest CHWIF site ) 7. Spent 28.3/SC Purification 2.0 Carbon H-I Process 8. Spent 28.2/SC Mfg. Process 2.0 Catalyst H-I 9. Process 28.1/SC Mfg. Process 1705 Collection, Storage, Inorgani H-I 7-(4-Bromo- Transportation, disposal c Waste butoxy)-3,4- at nearest TSDF site. dihydro-1H- (M/s. BEIL, Dahej) quinolin-2-one 10. Spent 28.6/SC Mfg. Process *9362 Collection, Storage, Solvent H-I 5-(4-(4-(5- 4 Transportation Cyano1H-indol-3- recovered & recycled by yl)- butyl)- Solvent Distillation Plant piperazin-1- within premises. yl)benzofuran-2- carboxamide Solvent Stripper 540 Collection, Storage, & recover by distillation & Reuse in process within the premises OR send to pre/co processing unit OR send to CHWIF. 11. Scrubbi 28.1/SC From Scrubber 900 Treated with effluent & ng H-I (4-Benzyloxy-3- KL Send to CETP Dahej. Solution (5- 10% isopropylamino- NaCl 1-phenyl-hexyl)- benzoic acid methyl ester)
12. Scrubbi 28.1/SC From Scrubber 900 Collection, Storage, ng H-I Mfg. Process KL Transportation Sell to
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Solution (3-(cyclopropyl End Users having (20- methoxy)-4- permission under Rule- 22% (difluoro 9. Na2SO3) methoxy) benzoyl chloride)
13. Scrubbi 28.1/SCH-I From Scrubber 720 Collection, Storage, ng Mfg. Process KL Transportation Sell to Solution Cis –Bromo End Users having (30-35 benzoate permission under Rule- % 9. NaBr/H Br) 14. Scrubbing 28.1/SCH-I From Scrubber 360 Collection, Storage & Solution Mfg. Process KL Reuse in Mfg. Process 30% ([(3R,5R)-tert- of 1 – Methyl– 3– (Liq. butyl 7-(2-(4- Phenyl Ammonia) fluoro phenyl)-5- Piperazine(11280 isopropyl-3- KL/Annum) phenyl- 4-(phenyl carbonyl)4-pyrol- 1-yl)-3,5- dihydroxy heptanoate]) 15. Spent 28.1/SC Mfg. Process 1440 Collection, Storage, Sulphuri H-I Finofibrate KL Transportation Sell to c Acid End Users having 70% permission under Rule- 9.
Product Name Spent Solvent Quantity (MT/Annum) *5-(4-(4-(5-Cyano1H- indol-3-yl)- butyl)- piperazin-1- Dimethylformamide 93624 yl)benzofuran-2- carboxamide TOTAL 93624 ii Membership details of TSDF, CHWIF etc. Membership of TSDF site vide (For HW management) letter No. BEIL/ANK/2020 dated: 07-02-2020. Unit will be obtain membership of CHWIF site. iii Details of Non-Hazardous waste & its disposal Nil (MSW and others) G Solvent management, VOC emissions etc. i Types of solvents, Details of Solvent recovery, % recovery, reuse of recovered Solvents etc. (Details in Table Format) S Qty. Qty. r. Use Reco Solvent B.P. Total n Product Name Solvent d vered Recovery °C Loss o MT/ MT/M (%) . MT T
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Di Methyl Amino Ethyl EDC 83.5 2 1.92 0.08 96.00 1. Chloride Hydrochloride IPA 82.5 0.5 0.48 0.02 96.00 Di Ethyl Amino Ethyl Toluene 111 1.5 1.43 0.075 95.00 2. Chloride hydrochloride Acetone 56.2 1 0.97 0.03 97.00 Methylene cis-2-(2,4- 39 4.78 4.64 0.1434 97.00 Dichloride Dichlorophenyl)-2-(1H- Triethylami 3. 1,2,4-Triazol-1-yl methyl)- 90 0.53 0.5 0.03 95.00 ne 1,3-Dioxolan-4-ylmethyl] 118. methane sulfonate Acetic acid 5.71 5.42 0.2855 95.00 1 2-[3-[4-(m-chlorophenyl)- 1-piperazinyl]propyl]s- 4. triazolo[4,3-a]-pyridin- Methanol 64.5 6.03 5.85 0.1809 97.00 3(2H)-one monohydrochloride 7-(4-Bromo-butoxy)-3,4- DMF 153 3.47 3.28 0.1908 95.00 5. dihydro-1H-quinolin-2- Cyclohexa 81 4.71 4.52 0.1884 96.00 one ne IPA 82.5 0.19 0.18 0.0076 96.00 6. Meloxicam o-Xylene 145 7.4 6.99 0.407 95.00 (4aS, 7aS)- 19.2 Methanol 64.5 18.65 0.5769 97.00 2,3,4,4a,5,6,7,7a- 3 7. octahydro-1H-pyrrolo[3,4- IPE 69 9.62 9.24 0.3848 96.00 b]pyridine ( (Tetra-butyl 2-((4R,6R)-6- (2-aminoethyl)-2,2- 8. Methanol 64.5 3.2 3.10 0.096 97.00 dimethyl-1,3-dioxan-4- yl)acetate) 2-Chloro Ethyl Amine 9. EDC 83.5 1.88 1.80 0.0752 96.00 Hydrochloride N,N, Bis (2-Chloro Ethyl) 10. EDC 83.5 1.88 1.80 0.0752 96.00 Amine Hydrochloride 4-(2- 11. Chloroethyl)morpholine EDC 83.5 2.94 2.82 0.1176 96.00 hydrochloride 1-(4-Aminophenyl)-4-(4- 12. Methoxyphenyl) DMF 153 7.36 6.96 0.4048 95.00 Piperazine cis-(2,4-Dichlorophenyl)- 0.2392 DMF 153 4.35 4.11 95.00 2-(1H-1,2,4-Triazol-1- 5 13. yl)Methyl-1,3-Dioxolan-4- Toluene 111 6.17 5.86 0.3085 95.00 yl methanol 10.8 14. Carbazepamine Ethanol 78 10.50 0.3246 97.00 2 1-(3-Methyl-1-phenyl-5- MDC 39 2.5 2.43 0.075 97.00 15. pyrazolyl)Piperazine IPA 82.5 1.65 1.58 0.066 96.00 1-[2-(2- 16. Hydroxyethoxy)ethyl]pipe Methanol 64.5 0.39 0.38 0.0117 97.00 razine 2-(4-(4- Chlorofor 17. chlorobenzoyl)phenoxy-2- 61.5 0.75 0.73 0.0225 97.00 m methylpropanoic acid
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1-(2,4-difluorophenyl)-2- Ethyl 18. (1,2,4-triazol-1- 77 4.38 4.20 0.1752 96.00 Acetate yl)ethanone Tert-butyl 4-oxo-2-(1,3- Ethyl 19. thiazolidin- 3-yl carbonyl) 77 0.25 0.24 0.01 96.00 Acetate pyrrolidine-1-carboxylate N-(trans)-4- 20. hydroxycyloohexyl)aceta Acetone 56.2 1.15 1.12 0.0345 97.00 mide (S)-2-((2- oxomorpholino)phenyl)ox 21. THF 66 9.34 8.95 0.39 95.82 azolidin-5-yl)isoindoline- 1,3-dione sodium 3-oxo-3H- 22. [1,2,4]triazolo[4,3- IPA 82.5 13.5 12.96 0.54 96.00 a]pyridin-2-ide (Tert-butyl 2-((4R,6R)-6- (2-(2-(4-fluorophenyl)-5- Cyclohexa isopropyl-3-phenyl-4- 81 3.5 3.36 0.14 96.00 23. (phenylcarbamoyl)-1H- ne pyrrol-1-yl)ethyl)-2,2- dimethyl-1,3-dioxan-4- yl)acetate) IPA 82.5 3.2 3.07 0.128 96.00 2-Chloro-1-(2,4- 24. MDC 39 5.71 5.54 0.1713 97.00 difluorophenyl)ethanone (R)-5-(2-aminopropyl)-2- 16.0 25. methoxy benzene Methanol 64.5 15.54 0.4806 97.00 2 sulfonamide 2-[3-Cyano-4-(2- methylpropoxy) phenyl]- 26. THF 66 7.41 7.16 0.25 96.63 4-methyl-5-thiazole carboxylic Acid 1-[2-(2,4-di fluorophenyl)- 27. 2,3-epoxypropyl]-1H- Toluene 111 5 4.75 0.25 95.00 1,2,4-Triazole (E)-7-((1R,2R,3R,5S)-3,5- THF 66 7.81 7.5 0.31 96.03 dihydroxy-2-((E)-3- 28. hydroxy-5-phenylpent-1- 0.4295 DMSO 189 7.81 7.38 95.00 en-1-yl)cyclopentl)hept-5- 5 enoic acid [5-(2-Benzyloxy-5-bromo- IPA 82.5 2.63 2.52 0.1052 96.00 phenyl)-1-methyl-5- TEA 90 2.63 2.53 0.1 96.20 29. phenyl-pentyl]-isopropyl- Acetonitril 82 2.63 2.52 0.1052 96.00 amine e n-Hexane 69 1.5 1.44 0.06 96.00 N-(4- Ethyl 30. 77 1.11 1.07 0.0444 96.00 oxocyclohexyl)acetamide Acetate Chloroben 132 1.33 1.26 0.0665 95.00 zene (3R)-3-(tert.butoxy MDC 39 4.72 4.58 0.1416 97.00 carbonylamino-1-[3- 31. (trifluoromethyl)-5-6- IPA 82.5 3.77 3.62 0.1508 96.00 dihydro[1,2,4]triazolo[4,3-
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a] pyrazin-7(8H)-yl]-4- (2,4,5- triflurophenyl)butan-1-one
ethyl 3- (cyclopropylamino)-2- 32. (2,4,5-trifluoro-3- methoxy-benzoyl)prop-2- DMF 153 4.78 4.52 0.2629 95.00 enoate Toluene 111 6.57 6.24 0.3285 95.00 IPA 82.5 4.18 4.01 0.1672 96.00
4-[4-[(4-Methoxyphenyl)- Dimethylfo 1-Piperazinyl] Phenyl] 2 153 2.75 2.67 0.0825 97.00 33. rmamide 4-Dihydro-3H-1,2,4- Triazol-3-On Methanol 64.5 1.01 0.98 0.0303 97.00
4-[4-[(4-Methoxyphenyl)- DMS 189 5.26 4.97 0.2893 95.00 1-Piperazinyl] Phenyl] 34. 2,4-Dihydro-2-(1-Methyl propyl)-3H-1,2,4-Triazol- 2- 3-One Bromobuta 91 1.12 0.63 0.49 96.00 ne Acetone 56.2 5 4.85 0.15 97.00 3-(2-Benzyloxy-5-bromo- methanol 64.5 5 4.85 0.15 97.00 35. phenyl) -3-phenyl-propan- 1-ol IPA 82.5 6 5.76 0.24 96.00 Toluene 111 5 4.75 0.25 95.00 Toluene 111 5.71 5.42 0.2855 95.00 36. Moxifloxacin base THF 66 2.86 2.75 0.11 96.15 MDC 39 3.49 3.39 0.1047 97.00 4-Benzyloxy-3-(5- Methanol 64.5 3.49 3.39 0.1047 97.00 isopropylamino-1-phenyl- n-Hexane 69 2.33 2.24 0.0932 96.00 hexyl)-benzoic acid methyl ester THF 66 3.49 3.34 0.15 95.00 IPA 82.5 2.33 2.24 0.0932 96.00 10.8 2-(2-(tert- THF 66 9.88 0.95 95.00 butyldimethylsilyloxy0-2- 3 37. (6-flurochroman-2- Methanol 64.5 5 4.85 0.15 97.00 yl)ethylamino)-1-(6- Ethyl 77 5.42 5.20 0.2168 96.00 fluorchroman-2-yl)ethanol Acetate DCM 39 8.8 8.54 0.264 97.00 38. Desvenlafexine DMF 153 5 4.73 0.275 95.00 Methanol 64.5 2.05 1.99 0.0615 97.00 1-[4-[4-(4- Toluene 111 2.72 2.58 0.136 95.00 Methoxyphenyl)Piperazin 39. yl] Phenyl] Hydrazine Methanol 64.5 0.75 0.73 0.0225 97.00 Carboxamide 2-Amino-2-[2-(4- 40. octylphenyl)ethyl]-1,3- Methanol 64.5 15 14.55 0.45 97.00 propanediol (3R,5R)-Tert-Butyl 7-(2- Methanol 64.5 1.49 1.45 0.0447 97.00 41. (4-Fluoro Phenyl)-5- Cyclohexa 11.2 81 10.84 0.4516 96.00 Isopropyl-3-Phenyl- 4- ne 9
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(Phenyl Carbonyl) 4- Toluene 111 2.13 2.02 0.1065 95.00 Pyrol-1-Yl)-3,5-Dihydroxy Heptanoate IPA 82.5 7.43 7.13 0.2972 96.00 Chloroben (-/+)2,6-Diamino-4,5,6,7- 132 1.24 1.18 0.062 95.00 42. zene tetrahydro benzothiazole Methanol 64.5 1.48 1.44 0.0444 97.00 Methanol 64.5 8.6 8.34 0.258 97.00 43. (Cis –Bromo benzoate) Toluene 111 6.45 6.13 0.3225 95.00 117. n-Butanol 1.08 1.03 0.054 95.00 6 44. (Cis-Imidazole alcohol) Methanol 64.5 7.58 7.35 0.2274 97.00 Methanol 64.5 7.45 7.23 0.2235 97.00 MDC 39 7.45 7.23 0.2235 97.00 45. (Cis –Tosylate) Ethyl 77 5.32 5.11 0.2128 96.00 Acetate n-Hexane 69 5.32 5.11 0.2128 96.00 Ethyl 2-[3-Cyano-4-(2- methylpropoxy) phenyl]- 46. DMF 153 7.86 7.43 0.4323 95.00 4-methyl-5-thiazole carboxylate 7-{4-[4-(2,3-Dichloro- phenyl)-piperazin-1-yl]- 47. Methanol 64.5 5.31 5.15 0.1593 97.00 butoxy}-3,4-dihydro- quinolin-2-ol 10.8 (4aS,7aS)-6-benzyl- DMF 153 10.29 0.5989 95.00 9 1,2,3,4,4a,5,7,7a- 48. 13.0 octaydropyrrolo[3,4- Toluene 111 12.42 0.6535 95.00 7 b]pyridine Acetone 56.2 4.36 4.23 0.1308 97.00 THF 66 10 9.6 0.4 96.00 Ethyl 16.6 77 16.00 0.6668 96.00 Acetate 7 49. Triphenylphosphine oxide Acetone 56.2 8.33 8.08 0.2499 97.00 tert- 83 0.65 0.62 0.03 95.38 Butanol Toluene 111 4.8 4.56 0.24 95.00 50. Levocitrizine 2HCl Cyclohexa 81 5.2 4.99 0.208 96.00 ne 1-Acetyl-4-(4-hydroxy 117. 11.6 51. n-Butanol 11.05 0.5815 95.00 phenyl)piperazine 6 3 3-(4-(3- 52. chlorophenyl)piperazin-1- Toluene 111 2.3 2.19 0.115 95.00 yl)propen-1-ol
(R)-2-(2-(4-((4- Toluene 111 4.73 4.49 0.2365 95.00 chlorophenyl)oxirane(phe 53. nyl)methyl)piperazin- 1- Cyclohexa yl)ethoxy)acetamide 81 4.27 4.10 0.1708 96.00 ne
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2-(3-(4-(3- chlorophenyl)piperazin-1- 0.1985 54. yl)propyl)- DMF 153 3.61 3.41 95.00 5 [1,2,4]triazolo[4,3- a]pyridin-3(2H)-one 1-cyclopropyl-6,7- 13.1 Toluene 111 12.48 0.657 95.00 difluoro-8-methoxy-4-oxo- 4 55. quinoline-3-carboxylic Cyclohexa 81 4.93 4.73 0.1972 96.00 acid ne 10.9 Methanol 64.5 10.66 0.3297 97.00 9 n-Hexane 69 3.3 3.17 0.132 96.00 56. Tamsulosin Base Ethyl 12.6 77 12.13 0.5056 96.00 Acetate 4 Ethanol 78 6.59 6.39 0.1977 97.00 7-(4-Bromo-butoxy)-3,4- DMF 153 3.47 3.28 0.1908 95.00 57. dihydro-1H-quinolin-2- Cyclohexa 81 4.71 4.52 0.1884 96.00 one ne MDC 39 9.7 9.41 0.291 97.00 58. Levatiracetam Ethyl 77 6.07 5.83 0.2428 96.00 Acetate Toluene 111 6.92 6.57 0.346 95.00 1 – Methyl– 3–Phenyl 59. Ethyl Piperazine 77 1.8 1.73 0.072 96.00 Acetate 16.4 IPA 82.5 15.77 0.6572 96.00 3 20.9 Toluene 111 19.93 1.049 95.00 60. Rivaroxaban 8 Methanol 64.5 8.17 7.92 0.2451 97.00 11.4 DCM 39 11.11 0.3435 97.00 5 Acetone 56.2 9.26 8.98 0.2778 97.00 Chlorofor 61.5 3.33 3.23 0.0999 97.00 m 12.1 IPA 82.5 11.68 0.4868 96.00 61. Finofibrate 7 53.8 Toluene 111 51.20 2.6945 95.00 9 118. Acetic acid 0.12 0.11 0.006 95.00 1 118. 4-[4-[(4-Hydroxyphenyl)- Acetic acid 4.79 4.55 0.2395 95.00 1 1-Piperazinyl] Phenyl] Chlorofor 17.0 62. 2,4-Dihydro-2-(1-Methyl 61.5 16.51 0.5106 97.00 m 2 propyl)-3H-1,2,4-Triazol- 12.0 3-One Methanol 64.5 11.66 0.3606 97.00 2 5-(4-(4-(5-Cyano1H-indol- 3-yl)- butyl)-piperazin-1- 81.2 4.4698 63. DMF 153 76.80 95.00 yl)benzofuran-2- 7 5 carboxamide Acetamide,N-[1,1- Cyclohexa 64. 81 28 26.88 1.12 96.00 bis(acetyloxy)methyl]-3- ne
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(4-octylphenyl)propyl IPA 82.5 17 16.32 0.68 96.00 Ethyl 77 16.5 15.84 0.66 96.00 Acetate Methylene 39 10 9.70 0.3 97.00 Dichloride ii VOC emission sources and its mitigation measures ➢ Sources - Charging Materials ➢ Measures - Enclose Process - Minimum flanges & joints - Handled by pump with double mechanical seals - Proper Ventilation - Adequate PPEs H ➢ Details regarding storage of Hazardous chemicals Storage Name of major Hazardous chemicals Remarks details Storage Liquor Ammonia, Toluene, Hydrochloric Acid, Storage tanks Methanol, MDC,Sulphuric acid condition as ATP
Drum& Ethyl Acetate, Iso Propanol, Acetone, DMF, Storage Carboy Acetonitrile, Chloroform, Cyclohexane, THF, Acetic condition as ATP storage Acid, Formic Acid, Sodium hydroxide. Cylinder Storage Storage Ammonia Gas. condition as Under Pressure Glass Bottle Bromine Storage condition as ATP Hydrogen Hydrogen Gas. Storage Bank condition as Under Pressure ➢ Applicability of PESO : Not Applicable
• This proposal is for new synthetic organic manufacturing plant at GIDC - Dahej Industrial Estate. During meeting, Committee insisted for proposed production plant size. PP submitted that industrial effluent will be segregated in high COD and Low COD stream.High COD industrial effluent will be treated in stripper and ETP-1 (Having Primary Treatment Unit) followed by MEE & Centrifuge. MEE condensate from MEE will be treated in Low COD stream ETP- 2 for further treatment. • Low COD stream will be treated In house ETP-2-consisting of primary, secondary and tertiary units and Treated low concentration effluent will be sent to CETP- Dahej for further treatment and disposal. Committee insisted for segregation of effluent and adequacy of ETP to achieve CETP inlet norms along with stage wise reduction of pollutants like BOD, COD, Ammonical nitrogen & TDS and membership certificate of CETP as per GPCB letter dated 08/01/2020. • Two Stage scrubber will be provided for each process stack as APCM. Multi Cyclone Dust collector followed by water scrubber will be provided as APCM with steam boiler , thermopack & HAG separately. • Considering the above project details, after detailed discussion, the terms of reference (ToR) were prescribed as below and as per the standard TOR for the Synthetic Organic Chemical projects
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recommended by SEAC vide letter no. EIA-10-GEN-21/1480 dated 14/09/2017 and approved by SEIAA in its 12th meeting dated 16/09/2017 for the EIA study to be done covering 10 Km radial distance from the project boundary. 1. Technical justification of quantity of ETP sludge and MEE salt against treatment of industrial effluent. 2. Adequacy assessment report of ETP to treat industrial effluent to achieve inlet norms of CETP (with ETP stage wise reduction in pollutants like BOD, COD, Amonical nitrogen and TDS) considering worst case scenario for proposed products. 3. Membership Certificate from Common Facility (mentioning total capacity, consented quantity, occupied capacity and spare capacity and norms of acceptance of effluent from member units) in-line with the direction given by GPCB vide Letter No. GPCB/P-1/8-G (5)/550706 dated 08/01/2020. 4. Technical justification regarding proposed production size and 70 bulk drug products mentioned in one group. 5. Compliance of MoEFCC’s OM dated 01/05/2018 regarding “Corporate Environment Responsibility” (CER). Fund allocation for Corporate Environment Responsibility (CER) shall be made as per MoEFCC’s O.M. No. 22-65/2017-IA.III dated 01/05/2018 for various activities therein. The details of fund allocation and activities for CER shall be incorporated in EIA/EMP report. 6. Explore the use of renewable energy to the maximum extent possible. Details of provisions to make the project energy-efficient through of energy efficient devices and adoption of modes of alternative eco-friendly sources of energy like solar water heater, solar lighting etc. Measures proposed for energy conservation. 7. Qualitative and quantitative analysis of hazardous waste streams generation from the manufacturing process (Product wise) and scrubber. Explore the possibility to reuse such waste streams within premises as raw materials for other products. Sound management of such waste streams as per the HW Rules 2016 as amended time to time. Feasibility study report for utilization shall be incorporated in EIA report. 8. Safety precautions for Chlorine, hydrogen transportation, storage, handling and in-case of emergency/accident as per prevailing guidelines. 9. Safety precaution measures for chlorine handling and storage in plant. 10. PP shall furnish status of all the applicable rules, acts, regulation, clearances in a tabular form. 11. Leak Detection and Repairing Programme (LDAR) for all the volatile organic solvent proposed for use in- house with detailed chemical properties including vapor pressure. LDAR shall endeavor prevention of losses of solvents to the best minimum extent. 12. Safety precautions including flame proof electric fittings to be taken to avoid fire hazard during unloading, storage, transportation, handling and processing of Solvents. 13. MoU for selling of Hazardous waste to endusers having Rule-9 permission under HWRules’2016. • The TOR prescribed as above and as per the standard TOR approved by SEIAA and the model ToRs available in the MoEFCC’s sector specific EIA Manual for ‘Synthetic Organic Chemical Industry’ shall be considered as generic TORs for preparation of the EIA report in addition to all the relevant information as
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per the generic structure of EIA given in Appendix III in the EIA Notification, 2006.
• Further Project Proponent may be advised to submit final EIA Report with EC application within 100 days from the date of issuance of this ToR to expedite processing of Environment Clearance application.
• The project proponent shall have to apply for Environmental clearance through online portal http://environmentclearance.nic.in/ along with final EIA report.
8. SIA/GJ/IND2/49618/2020 M/s.Biosynth Industries Screening and scoping Plot No. 1713,1715, GIDC-Sarigam ,Ta- Umbergaon, Dist.: Valsad, Gujarat
Category of the unit: 5(f) Project status: Expansion • This office has received an application vide their online proposal no. SIA/GJ/IND2/49618/2020 dated 04/03/2020 made by project proponent (PP) regarding grant of Terms of Reference [ToR] for preparation of EIA/EMP report. • Project proponent (PP) has submitted Form-1, PFR and relevant details/information. • This is an existing inorganic unit and proposes for manufacturing of synthetic organic product as tabulated below:
Quantity MT/Month Group Sr. CAS No. / End-use of Name of the Products No. No. CI No. the products Existing Proposed Total
Inorganic Products (Existing Product) A Copper Sulphate 1 7782-63-0 25.00 AND/OR Ferrous Sulphate InorganicProd 2 10034-96-5 250.00 AND/OR ucts Manganese Sulphate 400 -Used as raw 3 7786-81-4 50.00 0 AND/OR AND/ OR materials in Nickel Sulphate chemical 4 7733-02-0 25.00 AND/OR industries 5 Zinc Sulphate 7758-99-8 50.00 Pharma Intermediate (Proposed Product) B Phenyl Hydrazine 6 100-63-0 AND/OR Used as Ferrous Ascorbate 7 14356-17-5 Pharma AND/OR Intermediate Ferrous Fumarate 25.00 25.00 8 141-01-5 0.00 in AND/OR Pharmaceuti Chlorotrityl Chloride(2- 9 42074-68-0 cal industries CTC) AND/OR Ethyl Ethoxy Methylene 10 87-13-8 Malonate
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C Resin (Proposed Product) 11 Alkyd Resin 9003-35-4 0.00 AND/OR 12 Polyamide Resin 63428-84-2 0.00 AND/OR 13 Polyester Resin 113669-95-7 0.00 AND/OR Used to Ink 200.00 200.00 14 Acrylic Resin Manufacturing 25034-86-0 0.00 AND/OR units 15 Rosin Ester 68475-37-6 0.00 AND/OR 16 Epoxy Resin 24969-06-0 0.00 17 Alkyl Resin 9003-35-4 0.00 TOTAL PRODUCTION 400.0 225.0 625.0
• The project falls under Category B of project activity 5(f) as per the schedule of EIA Notification 2006. • This case was considered in the SEAC meeting dated 19/03/2020. • Salient features of the project including Water, Air and Hazardous waste management : Sr. no Particulars Details . A Total cost of Proposed Project Existing:0.7226Cr. (Rs. in Crores): Proposed:0.7613Cr. Total: 1.4839Cr. B Total Plot area Existing: 1351.99 ( sq. meter) Proposed: 1477.08 Total: 2829.07 Green belt area Outside area ( sq. meter) (160 Nos. of Plants in Approx. 1000 Sq. Mtr.) C Employment generation Existing: 10 Proposed:30 Total:40 D Water i Source of Water Supply GIDC (GIDC Bore well, Surface water, Tanker supply etc...) Status of permission from the concern authority. Letter submitted ii Water consumption (KLD)
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Water Sr. Type of Activity Existing Proposed Requirement No. in KLD 1. Domestic 1.5 0.5 2 2. Gardening 0 0 0 3. Industrial a. Process 2 0 2 b. Cooling-make up 0 2 2 c. Boiler 0 3 3 d. Scrubber 0 3 3
Industrial Total 2 8 10
Total ( a+b+c) 3.5 8.5 12
1) Total water requirement for the project: 12 KLD 2) Quantity to be recycled: 0.0KLD 3) Total fresh water requirement: 12KLD (Total water requirement = Fresh water + Recycled water) iii Waste water generation (KLD)
Waste Water Sr. Type of Activity Existing Proposed Generation No. in KLD 1. Domestic 1 0.5 1.5 2. Gardening 0 0 0 3. Industrial e. Process 0 15 15 f. Cooling- blow down 0 1 1 g. Boiler- blow down 0 1 1 h. Scrubber 0 3 3 Industrial Total 0 20 20
Total ( a+b+c) 1 20.5 21.5
iv Treatment facility within premises with capacity [In-house ETP (Primary, Secondary, Tertiary), MEE, Stripper, Spray Dryer, STP etc. ➢ Industrial waste water is treated in Effluent Treatment Plant (ETP) andtreated effluent will be sent to CETP–Sarigam through GIDC Underground Drainage system. Treatment scheme including segregation at source. ➢ Industrial effluent treated in ETP having Primary & Secondary treatment units. Note: (In case of CETP discharge) :
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Management of waste water keeping in view direction under section 18 (1) (b) of the Water (Prevention and Control of Pollution) act, 1974 issued by CPCB regarding compliance of CETP. ➢ Generated industrial effluent will be treated in ETP & then after it will be discharged to CETP–Sarigam through GIDC Underground Drainage system. Brief note on adequacy of ZLD (In case of Zero Liquid Discharge): ➢ Not Applicable v Mode of Disposal & Final meeting point Domestic: Disposed through septic tank/ Soak pit Industrial: Disposed through CETP of Sarigam vi In case of Common facility (CF) like CETP, Common Spray dryer, Common MEE, CHWIF etc. Name of Common facility (CF) (For waste water treatment) CETP of Sarigam – SARIGAM CLEAN INITIATIVE Membership of Common facility (CF): M/s. SARIGAM CLEAN INITIATIVE – CETP Sarigam (For waste water treatment) vii Simplified water balance diagram with reuse / recycle of waste water
vii Reuse/Recycle details (KLD) - 6.6 KLD [Source of reuse & application area]
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Total reuse 0.0 KLD Source of waste Application area Characteristics of waste Remarks water for reuse with with quantity in water to be reused (COD, regarding quantity in KLD KLD (Where it is BOD, TDS etc.) feasibility to (From where it is used) reuse i.e. coming) ------
E Air i Flue gas emission details No. of Boilers/TFH/Furnaces/DG sets etc. with capacities viz. TPH, Kcal/hr, MT/hr, KVA etc. Existing & Proposed Permis- Air Stack Fuel sible Sr. Fuel Pollution Para- Stack Attached to Height Consum- Limit No. Used Control meter (meter) ptionQty (mg/Nm Measure 3) Thermic fluidheater Adequate 0.03 1 -I 11 LPG Stack MT/day (Existing) Height SteamBoiler Dust Coal/ Bio 0.8 Capacity - 850 kg) 22 Collector/ 2 coal MT/day Proposed) BagFilter PM 150 Thermic Fluid (4.0 Dust Coal/ Bio 1.5 SOX 100 3 Lakh kcal/hr) 11 Collector/ coal MT/day NOX 50 Proposed) Bag Filter D.G. Set Adequate (Stand By) 18 4 11 Diesel Stack (Capacity -100KVA) Lit/hr Height (Proposed)
ii Process gas i.e. Type of pollutant gases (SO2, HCl, NH3, Cl2, NOxetc.) Existing & Proposed Sr Stack Attached To Stack Parameter Permissible APCM NO. Height Limit (meter) (mg/Nm3) 1 Process Vent-I (attached Multicyclone
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to Drier & Cooler) 11 PM 150 Separator/Bag Filter 2 Process Vent-II (attached SOx 100 Two Stage to Reaction Vessel) 11 NOxNH3 50 Alkali 400 Scrubber 3 FBD (Fluidise Bed 11 PM 150 Bag Filter Reactor) iii Fugitive emission details with its mitigation measures. ➢ NA F Hazardous waste (As per the Hazardous and Other Wastes (Management and Trans boundary Movement) Rules 2016. Existing & Proposed i Sr. Source of Cat. Total Hazardous waste Method of disposal No Generation No. Quantity Plant Machinery Collection, Storage, Sch- 0.016 Reuse or sell to 1 Used Oil I/ MT/Month GPCB Registered 5.1 Refiners. ETP plant Collection, Storage & Sch- 200 send to 2 ETP sludge I/ MT/Year common TSDF site 35.3 BEIL Dahej. From Raw material Collection, Storage, Sch- Discarded/Container Storage Section 1.66 Reuse or sell to 3 I/ s/ Barrels/ liners MT/Month GPCB authorized 33.1 recycler /vendor. From product of Collection, Storage Sch- Ethylethoxymethyle 71.25 &sell to end 4 Zinc Chloride Wet I/ ne Malonate MT/Month user/s having rule 9 6.1 permission From product of Collection, Storage Sch- Ferrous Ascorbate 15.00 &sell to end 5 Sodium Sulphate I/ MT/Month user/s having rule 9 26.1 permission From Collection, Storage Sch- Ammonium Ferrous Fumarate 68.50 &sell to end 6 I/ Sulphate MT/Month user/s having rule 9 26.1 permission. From ETP Collection, Storage & Inorganic Process Sludge Sch-I 15 send to 7 Waste 37.3 MT/Year common TSDF site BEIL Dahej. ii Membership details of TSDF, CHWIF etc. TSDF Site (For HW management) iii Details of Non-Hazardous waste & its NA disposal(MSW and others)
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G Solvent management, VOC emissions etc. NA i Types of solvents, Details of Solvent recovery, % recovery, reuse of recovered Solvents etc. (Details in Table Format) ➢ NA ii VOC emission sources and its mitigation measures ➢ NA H ➢ Details regarding storage of Hazardous chemicals ➢ Applicability of PESO : NA
• This proposal is for expansion of manufacturing plant at GIDC - Sarigam Industrial Estate.PP submitted valid CCA of the Board for existing inorganic products and there is no legal action taken by the Board against unit. PP submitted that total industrial effluent will be treated in ETP and treated effluent will be sent to CETP of Sarigam. Committee insisted for revised water balance diagram mentioning high COD and Low COD stream quantity and quality with stage wise reduction of pollutant and technical justification regarding process waste water generation shown 15 KLD from proposed product and water consumption for proposed product is nil. • Two stage alkali scrubber will be provided as APCM with each reactor stack.Multi cyclone and bag filter will be provided as APCM with drier and cooler and bag filter as APCM with FBD. Dust collector and Bag Filter will be provided as APCM with steam boiler and thermopack. • PP addressed hazardous waste management for proposed production in place of expansion. • Considering the above project details, after detailed discussion, the terms of reference (ToR) were prescribed as below and as per the standard TOR for the Synthetic Organic Chemical projects recommended by SEAC vide letter no. EIA-10-GEN-21/1480 dated 14/09/2017 and approved by SEIAA in its 12th meeting dated 16/09/2017 for the EIA study to be done covering 10 Km radial distance from the project boundary. 1. Revised water balance diagram with mentioning quantity and quality of High COD and Low COD stream and technical justification regarding process waste water generation shown 15 KLD from proposed product and water consumption for proposed product is nil 2. Adequacy assessment report of ETP to treat industrial effluent to achieve CETP inlet norms (with stage wise reduction in pollutants like BOD, COD,TDS). 3. Details with respect to justification for proposed expansion: (1) To address proportionate availability of space for production plant. (2) To address proportionate availability of storage area for raw materials finished goods, utilities and goods carrier movement within premises. (3) To address proportionate
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captive/common infrastructure available to accommodate additional load due to proposed expansion. (4) Environment impact and its mitigation measures for common/ captive infrastructure due to proposed production. 4. Membership Certificate from Common Facility (mentioning total capacity, consented quantity, occupied capacity and spare capacity and norms of acceptance of effluent from member units) in-line with the direction given by GPCB vide Letter No. GPCB/P-1/8-G (5)/550706 dated 08/01/2020. 5. Explore possibility of reuse of treated effluent within premises. Feasibility study report to reuse treated industrial effluent within premises for bulk drug products. 6. Compliance of MoEFCC’s OM dated 01/05/2018 regarding “Corporate Environment Responsibility” (CER). Fund allocation for Corporate Environment Responsibility (CER) shall be made as per MoEFCC’s O.M. No. 22-65/2017-IA.III dated 01/05/2018 for various activities therein. The details of fund allocation and activities for CER shall be incorporated in EIA/EMP report. 7. Explore the use of renewable energy to the maximum extent possible. Details of provisions to make the project energy-efficient through of energy efficient devices and adoption of modes of alternative eco- friendly sources of energy like solar water heater, solar lighting etc. Measures proposed for energy conservation. 8. Adequacy of common APCM for process pollutants like NH3 , NOx and SO2 parameters 9. Submit revised Hazardous waste matrix considering expansion project in place of new project. 10. Qualitative and quantitative analysis of hazardous waste streams generation from the manufacturing process (Product wise) and scrubber. Explore the possibility to reuse such waste streams within premises as raw materials for other products. Sound management of such waste streams as per the HW Rules 2016 as amended time to time. Feasibility study report for utilization shall be incorporated in EIA report. 11. PP shall furnish status of all the applicable Rules, Acts, Regulation, Clearances in a tabular form.
• The TOR prescribed as above and as per the standard TOR approved by SEIAA and the model ToRs available in the MoEF&CC’s sector specific EIA Manual for ‘Synthetic Organic Chemical Industry’ shall be considered as generic TORs for preparation of the EIA report in addition to all the relevant information as per the generic structure of EIA given in Appendix III in the EIA Notification, 2006.
• Further Project Proponent may be advised to submit final EIA Report with EC application within 100 days from the date of issuance of this ToR to expedite processing of Environment Clearance application.
• The project proponent shall have to apply for Environmental clearance through online portal http://environmentclearance.nic.in/along with final EIA report.
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9. SIA/GJ/IND2/45606/2019 M/s.Kaival Impex Screening and scoping Plot No. T-105/2, GIDC-Saykha,Ta-Vagra, Dist.: Bharuch, Gujarat
Category of the unit: 5(f) Project status: New • This office has received an application vide their online proposal no. SIA/GJ/IND2/45606/2019 dated 04/03/2020 made by project proponent (PP) regarding grant of Terms of Reference [ToR] for preparation of EIA/EMP report. • Project proponent (PP) has submitted Form-1, PFR and relevant details/information. • This is new unit proposes for manufacturing of synthetic organic product as tabulated below: SR NO. PRODUCT NAME Quantity CAS NO. END USE DIABITIC 148553-50-8 1 PREGABALIN NEUROPATHY PAIN 2 4:7-DICHLOROQUINOLIN 86-98-6 ANTIMALARIAL
3 ALBENDAZOLE 54965-21-8 ANTHELMINTIC 4 ACYCLOVIR 59277-89-3 ANTIVIRAL 5 AMBROXOL HCL 23828-92-4 EXPECTORANT AMODIAQUINE 6 DIHYDROCHLORIDE 69-44-3 ANTIMALARIAL
7 CHLOROQUINE 54-05-7 ANTIMALARIAL
PHOSPHATE
8 LUMEFANTRINE 82186-77-4 ANTIMALARIAL 9 ARTEMETHER 69.95 71963-77-4 ANTIMALARIAL MT/M 10 MOXIFLOXACIN 354812-41-2 ANTIBACTARIAL 11 FLUCONAZOLE 86386-73-4 ANTIFUNGAL DIABITIC 12 METHYLCOBALAMINE 13422-55-4 NEUROPATHY PAIN
938-73-8 ANTI 13 ETHENZAMIDE INFLAMMATORY 14 MEFENAMIC ACID 61-68-7 ANTIINFLAMMATORY 15 3-NITROPHTHALIC ACID 603-11-2 CANDE SARTAN 16 3-NITROPHTHALONITRILE 51762-67-5 CANDE SARTAN 17 4-NITROPHTHALIMIDE 89-40-7 CITALOPRAM 18 4-NITROPHTHALONITRILE 31643-49-9 CITALOPRAM 3-ACETYL AMINO DICARBOXYLIC ACID 19 METHYL ESTER - ANTI PSORIASIS (HYDROGENATION) 3-METHOXY-4- 20 METHYLBENZOIC ACID 3556-83-0 ZAFIRLUKAST METHYL ESTER
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21 8-HYDROXY QUINOLINE 148-24-3 ANTI CANCER
4-NITRO 2-AMINOPHENOL 6- DRUG 22 96-67-3 SULFONIC ACID(4-NAPSA) INTERMEDIATES
CHLOROTRITYL CHLORIDE(2- CONVERGENT 23 42074-68-0 CTC) PEPTIDE AGENT
HERBICIDES 24 2:4-DICHLOROAMINO 527-62-8 PRESERVATIVES PHENOL
5872-08-2 PROTECTING 25 CAMPHOR SULPHONIC CATALYST ACID
DRUG 26 5-NITRO-2-AMINOPHENOL 121-88-0 INTERMEDIATES
DRUG 27 4-CHLORO-2-AMINOPHENOL - INTERMEDIATES META NITRO PARA DRUG 28 TOLUIDINE 119-32-4 INTERMEDIATES ETHOXY METHYLENE DRUG 29 87-13-8 MALONATE INTERMEDIATES
618-88-2 DRUG 30 5-NITROISOPHTHALIC ACID INTERMEDIATES 5-AMINOISOPHTHALIC DRUG 31 99-31-0 ACID(HYDROGENATION) INTERMEDIATES 8-HYDROXYQUINOLINE 5- 283158-18-9 ANTI FUNGAL 32 SULFONIC ACID MONO/DIHYDRATE 33 CHLORZOXAZONE USP 95-25-0 ANTI FUNGAL 3:5-DIHYDROXY BENZOIC DRUG 34 ACID 99-10-5 INTERMEDIATES
2-METHYL-3- DRUG 35 1975-50-4 NITROBENZOICA INTERMEDIATES CID 3:5-DICHLOROBENZOIC DRUG ACID 51-36-5 INTERMEDIATES 5-CHLORO-8- 37 130-16-5 HYDROXYQUINOLINE ANTI FUNGAL 5:7-DICHLORO-8- 38 212-258-3 ANTI FUNGAL HYDROXYQUINOLINE 39 4-ISOPROPYL ANILINE 99-88-7 HERBICIDE INT.
575-75-7 DRUG 40 TOLDIMFOS SODIUM INTERMEDIATES 41 TRAMADOL HCL 27203-92-5 ANALGESIC
2-METHYL-6- DRUG 42 13506-76-8 NITROBENZOICA INTERMEDIATES CID
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3-HYDROXY DRUG 43 ACETOPHENONE 121-71-1 INTERMEDIATES 44 5-CYANO PHTHALIDE 82104-74-3 CITALOPRAM 2-AMINO-4-tert- DRUG 45 BUTYLPHENOL 1199-46-8 INTERMEDIATES 5-CYANO INDOLE ENZYME 46 15861-24-2 INHIBITOR
MISCARRIAGE 47 ALLYLESTRENOL AND PRETERM 432-60-0 LABOR FOR WOMAN 48 R& D Product 0.05 -- R&D Product Total 70.00 MT/Month • The project falls under Category B of project activity 5(f) as per the schedule of EIA Notification 2006. • This case was considered in the SEAC meeting dated 19/03/2020. • Salient features of the project including Water, Air and Hazardous waste management : Sr. Particulars Details no.
A Total cost of Proposed Project (Rs. in Crores): 2.25 Cr. B Total Plot area ( sq. meter) 2539.67 Sq. m. Green belt area ( sq. meter) 838.00 Sq. m. C Employment generation 25 D Water i Source of Water Supply GIDC, Saykha (GIDC Bore well, Surface water, Tanker supply EE/WD/GIDC/BRH/1284, DATE 4/10/2019 etc...) Status of permission from the concern authority. ii Water consumption (KLD)
Category Quantity Remarks KLD (S) Domestic 3.00 (T) Gardening 2.00 (U) Industrial Process 36.00 Washing 10.00 Scrubber Boiler 4.00 Cooling 5.00
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Hot Water Generator -- Industrial Total 55.00 Total (A + B + C) 60.00
1) Total water requirement for the project: 60KLD 2) Quantity to be recycled: 0.0 KLD 3) Total fresh water requirement:60KLD
(Total water requirement = Fresh water + Recycled water) iii Waste water generation (KLD)
Category Waste water Remarks KLD (J) Domestic 2.50 (K) Industrial Process 40.00 Washing 8.00 Scrubber Boiler 1.00 Cooling 2.00 Total Industrial waste 51.00 water Total [A + B] 53.50
iv Treatment facility within premises with capacity [In-house ETP (Primary, Secondary), MEE, Stripper, Spray Dryer, STP etc. For LOW COD ➢ Primary, SecondaryTreatment ETP with capacity of 55 KLD
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For High COD The industry has less space in premises. For low COD waste water will be treated in our ETP & High COD water (Filter mother liquor (ML)/ Solvent reduce / High COD contain will not be treated in our ETP so that we will sent it to Co-process/ Incineration. so we have not establish ETP for High COD Treatment scheme including segregation at source.
Note: (In case of CETP discharge) : Management of waste water keeping in view direction under section 18 (1) (b) of the Water (Prevention and Control of Pollution) act, 1974 issued by CPCB regarding compliance of CETP. Brief note on adequacy of ZLD (In case of Zero Liquid Discharge):Not Applicable v Mode of Disposal & Final meeting point Domestic: Disposed through septic tank/ soak pit Industrial: Disposed through CETP, Saykha or external incineration/Co- process facility (BEIL)/SEPPL
Low COD
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vi In case of Common facility (CF) like CETP, Common Spray dryer, Common MEE etc. Name of CF Membership of Common facility (CF) (For waste water treatment) GIDC-GIDC/BRH/DEE(DRG)/567, DATE11/102019 vii Simplified water balance diagram with reuse / recycle of waste water For LOW COD
For High COD The industry has less space in premises. For low COD waste water will be treated in our ETP & High COD water (Filter mother liquor (ML)/ Solvent reduce / High COD contain will not be treated in our ETP so that we will sent it to Co-process/ Incineration. so we have not establish ETP for High COD. viii Reuse/Recycle details (KLD) Total reuse 0.KLD NIL
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E Air i Flue gas emission details No. of Boilers/TFH/Furnaces/DG sets etc. with capacities viz. TPH, Kcal/hr, MT/hr, KVA etc.
Source of Stack Quantit Type of Air Pollution Sr. emission Height y of emission Control no Type of Fuel With (meter Fuel s i.e. Air Measures . Capacity ) MT/Day Pollutants (APCM) Bio coal/ Dust Boiler 1. 22 Briquettes/co 850Kg Collector/B (01) al (850 ag Kg/day.) Filter Thermic Bio coal/ Dust 2. Fluid (4.0 11 Briquettes/co 850Kg Collector/Bag Lakh al PM,SO2, Filter kcal/hr) NOx D.G Adequate 3. Set 11 Diesel 100 Stack Height (Stan KVA d By) (100 KVA)
Fuel Requirement: Bio coal/ Briquettes/coal: 0.85 MT/day & Diesel: 18 Liter/ Hr. ii Process gas emission details i.e.Type of pollutant gases (SO2, HCl, H2S, NH3, Cl2, NOxetc.)
AirPollution Control Sr. Type of Stack/Ven Source of emission Measures (APCM) no. emission Permis t Height sible (meter) limit Process Vent-I Multi cyclone Separator/ 1. (attached to Drier & PM 11 BagFilter Cooler) 150 Cl2, 9 Process Vent-II HCl, 20 Two Stage Alkali 2. 11 (attached to HBr 5 Scrubber Reaction Vessel) iii Fugitive emission details with its mitigation measures: As below:
• All the raw materials will be stored in isolated storage area and containers tightly closed. • The unit will also develop green belt within the factory premises to control the fugitive emission from spreading into surrounding environment. 613th meeting of SEAC-Gujarat, dated 19.03.2020 Page 178 of 217
• A regular preventive maintenance will be planned to replace or rectify all gaskets, joints etc. F Hazardous wastes (As per the Hazardous and Other Wastes (Management and Transboundary Movement) Rules 2016. i Sr. Source of Cat. Total No Hazardous waste Generation No. Quantity Method of disposal From Plant Collection,Storage, Sch-I/ 0.016 1 Used Oil machineries during Reuse or sell to 5.1 MT/Month lubrication authorized vendor. Collection,Storage, Discarded/Container From Raw material Sch-I/ 1.66 2 Reuse or sell to s/ Barrels/ liners section 33.1 MT/Month GPCBauthorized vendor. Collection, Storage & During treatment of 264.00 send to common TSDF 3 ETP sludge Industrial effluent Sch-I/ site BEIL Dahej. generated from 35.3 MT/Year ancillary operation During the Collection Storage & manufacturing send to common TSDF 4 Process Waste process of products Sch-I/ 336.00 site BEIL Dahej. like Mefenamic 28.1 MT/Year Acid, 2:4- Dichloroaminophen ol etc. During distillation of Collection Storage, various solvents to Sch-I/ 29.20 Transportation & 5 Distillation Residue be used in 36.1 MT/Month disposal and sent manufacturing tocommon incineration facility site or SEPPL (CHWIF) From scrubber of Collection, Storage & stack attached to Captive Consumption Process vessel of or sell to end user/s 6 HCl Solution products like Sch- 69.30 having Rule 9 Albendazole, II/ B- MT/Month Permission. Chloroquine, 15 Phosphate, 4 Isopropyl Anil ine etc. From scrubber of Collection, Storage & Sodium Bromide stack attached to Sch- 44.70 Captive Consumption 7 (NaBr) Process vessel of II/ B- MT/Month or sell to end user/s product like 15 having Rule 9 Albendazole Permission. During filtration stage from the Collection, Storage & process of product Captive Consumption like 4-Nitro Sch- 784.00 or sell to end user/s H2SO4 Solution Phthalimide,5- II/ B- MT/Month having Rule 9 613th meeting of SEAC-Gujarat, dated 19.03.2020 Page 179 of 217
8 Nitroisophthalic 15 Permission. Acid,5- Aminoisophthalic Acid(Hydrogenation ) etc During the process of products like Collection, Storage, Pregabalin, Sch - 18.20 Transportation & Acyclovir, I 36.2 MT/Month disposal and send for 9 Spent Carbon Artemether, co-processing/ Ethenzamide, 8- common Hydroxyuinoline, incineration 3:5- facility. Dihydroxybenzoic Acid, 5-Chloro-8 Hydroxyquinoline, Tramadol HCl, etc. Duringesterification stage fromprocessof productslikeAcyclovi Collection, Storage & r, Sch - Captive Consumption or AmodiaquineDihydr I 28.6 100.75 10 Spent Acetic Acid ochloride, Meta MT/Month sell to end user/s. having Rule 9 NitroParaTolu Permission. idine, 5-Cyano Indole, Duringdistillation Sch - I Collection, Storage & 7.7 11 Spent Methanol process invarious 28.6 reused back in to MT/Month products theProcess. From scrubber of Collection, Storage & stack attached to Captive Consumption NH Cl (Ammonium Sch - I 44.70 12 4 Process vessel of or sell to end user/s. Chloride Solution) 28.6 product like MT/Month having Rule9 Albendazole Permission. Recovered during Collection, Storage & the process of Captive Consumption Sch - I 41.90 13 Acetic Anhydride products like or sell to end user/s. 28.1 MT/Month Acyclovir. having Rule9 Permission.
During Collection, Storage & Manufacturing Of Captive Consumption Sch - I 70.00 14 Sodium Acetate Products like or sell to end user/s. 28.1 MT/Month Acyclovir, Meta having Rule9 Nitro Para Permission. ToluidineEtc. During Collection, Storage & Manufacturing Of Captive Consumption Sch - I 25.50 15 Sodium Sulphate Productlike Acyclovir or sell to end user/s. 28.1 MT/Month having Rule9 Permission.
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During Collection, Storage & Manufacturing Of Captive Consumption Sch - I 7.50 16 Sodium Fluoride Productlike or sell to end user/s. 28.1 MT/Month Moxifloxacin having Rule9 Permission. During Collection, Storage & Ethyl Manufacturing Sch - I 16.10 sell to end user/s. 17 Diethoxymethylene Of Product 28.1 MT/Month having Rule9 Malonate like Permission. Ethylethoxymethyle neMalonate 18 Zinc Chloride During Sch - I 199.50 Collection, Storage& Manufacturing Of 28.1 MT/Month Captive Consumption Product like or sell to end user/s. Ethylethoxymethyle havingRule9Permissio neMalonate n. During Collection, Storage & DPA ManufacturingOf Sch - I 92.00 sell to end user/s. 19 (2,6- Productlike 4- 28.1 MT/Month having Rule9 diisopropylaniline) IsopropylAniline Permission. During Collection, Storage & ManufacturingOf Sch - I 5.00 sell to end user/s. 20 Al2O Productlike4- 28.1 MT/Month having Rule9 3 Isopropyl Aniline Permission. During Collection, Storage & ManufacturingOf Sch - I 175 sell to end user/s. 21 Zinc Dust Productlike5- 28.1 MT/Month having Rule9 CyanoPhthalide Permission. Collection, Storage & During Captive Consumption ManufacturingOf Sch - I 19.25 22 Sodium Nitrate or sell to end user/s. Product like 28.1 MT/Month having Rule9 TramadolHCl Permission.
ii Membership details of TSDF, CHWIF etc. M/s. BEIL Infrastructure Limited (For HW management) (BEL/ANK/2019, DATE 1/10/2019) SEPPL(SEPPL/1200004016/2019-20/164 DATE 28/01/2020) iii Details of Non-Hazardous waste & its disposal Dust collected from dust collector will be sent to brick manufacturer or TSDF. (MSW and others) G Solvent management, VOC emissions etc.-- i Types of solvents, Details of Solvent recovery, % recovery, reuse of recovered Solvents etc. (Details in Table Format) : It will be given in EIA report. ii VOC emission sources and its mitigation measures : It will be given in EIA report H Details regarding storage of Hazardous chemicals is submitted.
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• Committee noted that this proposal is new unit at GIDC, Saykha. Looking to proposed product profile, Committee insisted for technical justification regarding proposed production plant size.PP has shown 40 KLD waste water generation and it will be segregated in High COD and Low COD stream alongwith Low COD characteristic.Low COD will be treated in primary and secondary ETP and then treated effluent will be sent to CETP of Saykha for further treatment and disposal.High COD stream will be sent to Co-processing and Incineration but its characteristic and treatment is not mentioned. • Biocoal and coal will be used as fuel in proposed boiler and thermopack. Multi dust collector and water scrubber will be provided as APCM with boiler and thermo pack. • Single stage alkali scrubber will be provided as APCM with process gas emission reactor and MCS and bag filter as APCM with drier and cooler. • Considering the above project details, after detailed discussion, the terms of reference (ToR) were prescribed as below and as per the standard TOR for the Synthetic Organic Chemical projects recommended by SEAC vide letter no. EIA-10-GEN-21/1480 dated 14/09/2017 and approved by SEIAA in its 12th meeting dated 16/09/2017 for the EIA study to be done covering 10 Km radial distance from the project boundary. 1. Technical justification regarding proposed production size and 47 bulk drug products mentioned in one group. 2. Adequacy of High COD effluent disposal for co-processing and Incineration without any sort of inhouse treatment. Also submit high COD effluent quantity and quality considering worst case scenario with mentioning BOD,COD,TDS and Ammonical nitrogen characteristics. 3. Leak Detection and Repairing Programme (LDAR) for all the volatile organic solvent proposed for use in-house with detailed chemical properties including vapor pressure. LDAR shall endeavor prevention of losses of solvents to the best minimum extent. 4. Membership Certificate from Common Facility (mentioning total capacity, consented quantity, occupied capacity and spare capacity and norms of acceptance of effluent from member units) in-line with the direction given by GPCB vide Letter No. GPCB/P-1/8-G (5)/550706 dated 08/01/2020. 5. Segregation of waste water streams based on characteristics and its proper management keeping in view direction under section 18 (1) (b) of the Water (Prevention and Control of Pollution) act, 1974 issued by CPCB regarding compliance of CETP(COD, BOD, TDS etc. of each stream shall be given) . 6. Submit justification regarding common APCM with process reactors and revised hazardous waste matrix considering adequate disposal of Hazardous waste with justification regarding adequacy of reuse in which process with its quantity and mass balance. 7. Compliance of MoEFCC’s OM dated 01/05/2018 regarding “Corporate Environment Responsibility” (CER). Fund allocation for Corporate Environment Responsibility (CER) shall
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be made as per MoEFCC’s O.M. No. 22-65/2017-IA.III dated 01/05/2018 for various activities therein. The details of fund allocation and activities for CER shall be incorporated in EIA/EMP report. 8. Explore the use of renewable energy to the maximum extent possible. Details of provisions to make the project energy-efficient through of energy efficient devices and adoption of modes of alternative eco-friendly sources of energy like solar water heater, solar lighting etc. Measures proposed for energy conservation. 9. PP shall furnish status of all the applicable rules, acts, regulation, clearances in a tabular form. 10. Safety precautions including flame proof electric fittings to be taken to avoid fire hazard during unloading, storage, transportation, handling and processing of Solvents.
• The TOR prescribed as above and as per the standard TOR approved by SEIAA and the model ToRs available in the MoEFCC’s sector specific EIA Manual for ‘Synthetic Organic Chemical Industry’ shall be considered as generic TORs for preparation of the EIA report in addition to all the relevant information as per the generic structure of EIA given in Appendix III in the EIA Notification, 2006.
• Further Project Proponent may be advised to submit final EIA Report with EC application within 100 days from the date of issuance of this ToR to expedite processing of Environment Clearance application.
• The project proponent shall have to apply for Environmental clearance through online portal http://environmentclearance.nic.in/ along with final EIA report.
10. SIA/GJ/IND2/49419/2020 M/s.Pharma chem. Industries(Gujarat) Screening and scoping Private Ltd. Plot No. 1020, GIDC-Sarigam ,Ta- Umbergaon, Dist.: Valsad, Gujarat
Category of the unit: 5(f) Project status: New • This office has received an application vide their online proposal no. SIA/GJ/IND2/49419/2020 dated 24/02/2020 made by project proponent (PP) regarding grant of Terms of Reference [ToR] for preparation of EIA/EMP report. • Project proponent (PP) has submitted Form-1, PFR and relevant details/information. • This is new unit proposes for manufacturing of synthetic organic product as tabulated below: S. No. Product CAS Number Capacity, End use TPM Rubber accelerators & Antioxidants Used in tyre like industries
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latex and surgical 1 2-Mercapto 149-30-4 industries Benzothiozole or 500 2 Zinc 2-Mercapto 155-04-4 Benzothiozole Or
3 4,5 Methyl-2- 53988-10-6 MercaptoBenzimida zole Or
4 Zinc salt of 4,5 61617-00-3 Methyl-2- MercaptoBenzimida zole
• The project falls under Category B of project activity 5(f) as per the schedule of EIA Notification 2006. • This case was considered in the SEAC meeting dated 19/03/2020. • Salient features of the project including Water, Air and Hazardous waste management : Sr. no. Particulars Details A Total cost of Proposed Project Rs. 4.5Crores (Rs. in Crores):
B Total Plot area 1800Sq. m. ( sq. meter) Green belt area 594 Sq. m. C Employment generation 30 D Water i Source of Water Supply GIDC Sarigam water supply (GIDC Bore well, Surface water, Tanker supply etc...) Status of permission from the concern authority. Permission issued by GIDC Sarigam vide letter No.NAO/SRG/494dated 18th Sep 2019
Water consumption (KLD) ii Category Quantity Remarks KLD (V) Domestic 5.0 (W) Gardening 1.0 613th meeting of SEAC-Gujarat, dated 19.03.2020 Page 184 of 217
(X) Industrial Process 77.0 Processing and washing Washing 2.0 Floor/equipment washing Boiler -- Cooling 25.0 Others 1.0 Hot water generator Industrial Total 105.0 Total (A + B + C) 111.0
1) Total water requirement for the project: 111KLD 2) Quantity to be recycled:0 KLD 3) Total fresh water requirement: 111KLD (Total water requirement = Fresh water + Recycled water) iii Waste water generation (KLD)
Category Waste water Remarks KLD (L) Domestic 4.0 (M) Industrial Process 92.0 Processing and washing Washing 2.0 Floor/equipment washing Boiler -- Cooling 2.0 Others 0 Hot water generator Total Industrial waste 96.0 water Total [A + B] 100.0 iv Treatment facility within premises with capacity [In-house ETP (Primary, Secondary, Tertiary), MEE, Stripper, Spray Dryer, STP etc. ➢ Primary and tertiary effluent treatment plant Treatment scheme including segregation at source. ➢ Total Industrial Waste water generation will be 96 m3/day mainly from process, washing, and cooling tower blowdown etc. Entire industrial effluent will be treated in primary and tertiary ETP and finally discharge into CETP Sarigam through underground effluent drainage pipe line for further treatment and disposal into Arabian Sea through closed pipe line. Note: (In case of CETP discharge) : Management of waste water keeping in view direction under section 18 (1) (b) of the Water (Prevention and Control of Pollution) act, 1974 issued by CPCB regarding
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compliance of CETP.: Not applicable, there is no 18(1) b condition imposed by CPCB to Sarigam CETP. Total Industrial Waste water generation will be 96 m3/day mainly from process, washing, and cooling tower blowdown etc. Entire industrial effluent will be treated in primary and tertiary ETP and finally discharge into CETP Sarigam through underground effluent drainage pipe line for further treatment and disposal into Arabian Sea through closed pipe line. Brief note on adequacy of ZLD (In case of Zero Liquid Discharge): ➢ Not Applicable ➢ Total Industrial Waste water generation will be 96 m3/day mainly from process, washing, and cooling tower blowdown etc. Entire industrial effluent will be treated in primary and tertiary ETP and finally discharge into CETP Sarigam through underground effluent drainage pipe line for further treatment and disposal into Arabian Sea through closed pipe line. v Mode of Disposal & Final meeting point Domestic: Domestic waste water (4 m3/day) will be disposed off through septic tank/soak pit. Industrial: Total Industrial Waste water generation will be 96 m3/day mainly from process, washing, and cooling tower blowdown etc. Entire industrial effluent will be treated in primary and tertiary ETP and finally discharge into CETP Sarigam through underground effluent drainage pipe line for further treatment and disposal into Arabian Sea through closed pipe line. vi In case of Common facility (CF) like CETP, Common Spray dryer, Common MEE, CHWIF etc. Name of Common facility (CF)(For waste water treatment) ➢ Treated Waste water will be sent to CETP for further treatment and disposal into Arabian Sea. Membership of Common facility (CF) (For waste water treatment) Applied for Membership of CETP Sarigam. vii Simplified water balance diagram with reuse / recycle of waste water
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Water Balance
Total Water consumption, 111 KLD source from GIDC Sarigam
Domestic: 5.0 Process & product washing: 77.0 Hot water generator: 1.0 Cooling: 25.0 Floor/container washing: 2.0 Gardening: 1.0
Septic tank/soak pit: 4.0 92.0 0 2.0 2.0
96.0 KLD
Primary & tertiary ETP
CETP Sarigam Characteristics of treated effluent: S. Effluent Combined normal Treated effluent CETP inlet norms No Parameter effluent 1. pH 7.0-8.0 6.5-7.5 6.5-8.5 2. Color pt. Co 200-300 80-100 <100 3. Suspended 150-200 60-80 <300 solids , mg/L 4. Total 1800-2000 1800-1900 <2100 dissolved solids, mg/L 5. Oil and 1-2 0.05- 0.07 <10 grease, mg/L
6. NH3-N, mg/L ND ND <50 7. BOD , mg/L 300-350 150-200 <400 8. COD , mg/L 1000-1200 600-800 <1000 9. Heavy metal, ND ND <1 mg/L 10. Phenolic ND ND <1 Compounds, mg/L
vii Reuse/Recycle details (KLD) [Source of reuse & application area] Total reuse: Nil -
E Air i Flue gas emission details No. of Boilers/TFH/Furnaces/DG sets etc. with capacities viz. TPH, Kcal/hr, MT/hr, KVA etc. -
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Air Source of Type of Stack Quantity Pollution Sr. emission Type emissions Height of Fuel Control no. With of Fuel i.e. Air (meter) Measures Capacity Pollutants (APCM) Hot Water Briquet 150 kg/h Multi Generator tes or 1. 15 or 55 Cyclone (4 Lakhs k Natural SCM/h PM separator Cal/h) gas SOX NOX D G set (125 2. 11 HSD 35 kg/h Chimney KVA)
ii Process gas i.e. Type of pollutant gases (SO2, HCl, NH3, Cl2, NOxetc.) Specific Source of Air Pollution Control Sr. emission Type of Stack/Vent Measures No. (Name of the Product & emission Height (meter) (APCM) Process) Cyclone separator 1. Spin Flash Dryer PM 11 & pulse jet bag filter
Cyclone separator 2. Pulveriser PM 11 & pulse jet bag filter
iii Fugitive emission details with its mitigation measures. ➢ Concrete road will be developed within plot premises to avoid fugitive dust due to vehicle movement. ➢ Manufacturing activity will be carried out in closed reactors/vessels and ➢ Regular checking and maintenance of the same will be carried out to avoid any leakages. ➢ All the raw materials will be stored in closed containers and in sealed bags and will be handled through closed system to avoid the handling losses. F Hazardous waste (As per the Hazardous and Other Wastes (Management and TransboundaryMovement) Rules 2016. i Sr. Type/Name Specific Category Quantity Management of no. of Source of and (MT/Annum) HW Hazardous generation Schedule waste (Name of the as per HW Activity, Rules. Product etc.) 1. Used oil D G set and Sch: I/5.1 0.1 Collection, gearbox of storage, reactors transportation and selling to authorized recycler 2. Discarded Empty Sch: I/33.1 20.0 selling to container containers of authorized recycler
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raw materials after de- contamination 3. ETP waste Neutralization Sch: I/35.3 25.0 Collection, and Filtration storage, process of transportation and effluent Dispose off into TSDF of BEIL Dahej. - ii Membership details of TSDF, CHWIF etc. • Applied for Membership of TSDF–BEIL, (For HW management) Dahej. iii Details of Non-Hazardous waste & its Fly ash-90 TPA will be disposed to brick disposal(MSW and others) manufacturer. G Solvent management, VOC emissions etc. i Types of solvents, Details of Solvent recovery, % recovery, reuse of recovered Solvents etc. (Details in Table Format) No Solvent will be used. ii VOC emission sources and its mitigation measures NIL H ➢ Details regarding storage of Hazardous chemicals Storage details Name of major Hazardous Remarks chemicals Storage tanks • Sodium MercptoBenzoThiozole • Sodium MercptoBenzimidazole • Sulphuric acid (98%) Drum/Barrel storage • Caustic lye
➢ Applicability of PESO:Not Applicable
• This proposal is for new synthetic organic manufacturing plant at GIDC - Sarigam Industrial Estate.Upon looking about wastewater management, PP submitted water balance diagram showing total industrial effluent will be treated in primary and tertiary ETP units.Treated effluent will be discharged into GIDC u/g drainage leading to CETP of Sarigam. Committee insisted for revised water balance diagram with exploring reuse of treated waste water in plant in place of disposal to CETP. • Cyclone and pulse jet bag filter will be provided as APCM with each spin flash dryer and pulveriser. Multi Cyclone will be provided as APCM with Hot water generator. • Considering the above project details, after detailed discussion, the terms of reference (ToR) were 613th meeting of SEAC-Gujarat, dated 19.03.2020 Page 189 of 217
prescribed as below and as per the standard TOR for the Synthetic Organic Chemical projects recommended by SEAC vide letter no. EIA-10-GEN-21/1480 dated 14/09/2017 and approved by SEIAA in its 12th meeting dated 16/09/2017 for the EIA study to be done covering 10 Km radial distance from the project boundary. 1. Revised water balance diagram with exploring reuse of treated waste water in plant in place of disposal to CETP. 2. Adequacy assessment report of ETP to treat industrial effluent to achieve CETP inlet norms (with stage wise reduction in pollutants like BOD, COD,TDS) 3. Compliance of MoEFCC’s OM dated 01/05/2018 regarding “Corporate Environment Responsibility” (CER). Fund allocation for Corporate Environment Responsibility (CER) shall be made as per MoEFCC’s O.M. No. 22-65/2017-IA.III dated 01/05/2018 for various activities therein. The details of fund allocation and activities for CER shall be incorporated in EIA/EMP report. 4. Membership Certificate from Common Facility (mentioning total capacity, consented quantity, occupied capacity and spare capacity and norms of acceptance of effluent from member units) in-line with the direction given by GPCB vide Letter No. GPCB/P-1/8-G (5)/550706 dated 08/01/2020. 5. Explore the use of renewable energy to the maximum extent possible. Details of provisions to make the project energy-efficient through of energy efficient devices and adoption of modes of alternative eco- friendly sources of energy like solar water heater, solar lighting etc. Measures proposed for energy conservation. 6. PP shall furnish status of all the applicable Rules, Acts, Regulation, Clearances in a tabular form.
• The TOR prescribed as above and as per the standard TOR approved by SEIAA and the model ToRs available in the MoEF&CC’s sector specific EIA Manual for ‘Synthetic Organic Chemical Industry’ shall be considered as generic TORs for preparation of the EIA report in addition to all the relevant information as per the generic structure of EIA given in Appendix III in the EIA Notification, 2006.
• Further Project Proponent may be advised to submit final EIA Report with EC application within 100 days from the date of issuance of this ToR to expedite processing of Environment Clearance application.
• The project proponent shall have to apply for Environmental clearance through online portal http://environmentclearance.nic.in/along with final EIA report.
11. SIA/GJ/IND2/48270/2019 M/s.Ree Atharva Life Science Private Ltd Screening and scoping Plot No. D-2/CH/34 GIDC-Dahej,Ta-Vagra, Dist.: Bharuch, Gujarat
Category of the unit: 5(f)
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Project status: New
• This office has received an application vide their online proposal no. SIA/GJ/IND2/48270/2019 dated 24/02/2020 made by project proponent (PP) regarding grant of Terms of Reference [ToR] for preparation of EIA/EMP report. • Project proponent (PP) has submitted Form-1, PFR and relevant details/information. • This is new unit proposes for manufacturing of synthetic organic product as tabulated below: Sr. Name of the Products CAS Quantity End Use of the No. product No. MT/Month
GROUP A :- API (SYNTHETIC APIs) : 30 MT/Month
1 Venlafaxine Either / or 93413-69-5 30 Depression & Anxiety disorder
2 Amlodipine Either / or 88150-42-9 Antihypertensive
3 Atorvastatin Either / or 134523-00-5 Cardiovascular Disease
4 Citalopram hydrobromide Either 59729-32-7 Depression, Anxiety / or disorder, Phobia
5 Quetiapin Fumarate Either / or 111974-72-2 Atypical anti-psychotic
6 Escitalopram Oxalate Either / or 219861-08-2 Treatment of Depression
7 Dothiepine Hydrochloride Either 897-15-4 Major Depressive / or Disorder
8 Rosiglitazone Maleate Either / or 155141-29-0 Diabetes
9 Clomipramine Hydrochloride 17321-77-6 Depression and Either / or obsessive-compulsive disorder
10 Carbamazepine Either / or 298-46-4 Antiepilepsy
11 MetoprololTartarate Either / or 37350-58-6 Chest Pain, Heart failure & High Blood Pressure
12 Mebendazole Either / or 31431-39-7 Antifungal
13 Phenylephrine HCL Either / or 61-76-7 Allergic
14 Sucralfate USP Either / or 54182-58-0 Intestinal Ulcers & Stomach ulcers
15 Theobromine Either / or 83-67-0 lung diseases
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16 Metoprolol Succinate Either / or 98418-47-4 Antihypertensive
17 Fluconazole Either / or 86386-73-4 Antifungal
18 AtenololEither / or 29122-68-7 Cardiovascular Agent
19 Tramadol HCLEither / or 27203-92-5 Analgesic
20 Letrozole 112809-51-5 Antitumor
GROUP A TOTAL QUANTITY 30
GROUP B :- INTERMEDIATES :- 80 MT/Month
21 2, 5 Dichloro Para 20103-09-7 80 Pharma Intermediates PhenyleneDiamine Either / or
22 2,5 Dimethyl Para 86386-73-4 PhenyleneDiamine Either / or
23 2-{2[2-[ 2,6 1216495-92-9 Dichlorophenyl)Amino]
Phenyl]Acetyl]Oxyacetic Acid] Either / or
24 2-Mercapto 5-Methoxy 37052-78-1 Benzimidazole Either / or
25 2 Nitro 4 Methoxy Aniline Either 96-96-8 / or
26 3-[4-Chloro-5-(Cyclopentyloxy)- 2886-65-9 2-Fluorophenyl]-5-(Propan-2- Ylidene)-1,3-Oxazolidin-4-One. (PIK) Either / or
27 Sodium/Potassium { 2-[ (2,6 15307-77-4 Dichloro Phenyl)Amino] Phenyl} Acetate Either / or
28 2 Chloro Para 615-66-7 PhenyleneDiamine Either / or
29 2-Chloro 1-Phenoxy Benzene 10304-81-1 Either / or
30 2,3 XylylAnthranilic Acid Either / 28022-11-9 or
31 2 Chloro 5 Methyl PPD Either / 5307-03-9 or
32 5 Amino Ortho Toluedene Either 99-55-8 / or
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33 4-Bromo Anisole Either / or 104-92-7
34 3 Amino 4 Methoxy Acetanilide 6375-47-9 Either / or
35 Para Anisidine Either / or 104-94-9
36 2 Chlor 4 Fluoro 5NBC Either / 86393-34-2 or
37 Para Amino Salicylic Acid 65-49-6
GROUP B TOTAL QUANTITY 80
GROUP C-1 :- DERIVATIVES TO CHLORINATION USING THIONYL CHLORIDE :- 30 MT/Month
38 Bis-(2 Chloro Ethyl) Amine Hcl 821-48-7 30 Aripriprazole,Trazodon Either / or e
39 4(2-Chlore Ethyl) Morpholine 3647-69-6 Floredil,Morclofone HCL (CEM HCL) Either / or
40 2 Chloro Ethyl Amine Hcl Either 821-48-7 Ifosfamide / or
41 Di Methyl Amino Isopropyl 4584-49-0 Methadone,Isothipendy Chloride (DMIPC)-HCL Either / l or
42 4CBC (4 Chloro – Butyryl 4635-59-0 Mitomycin Chloride ) Either / or
43 M4CB(4-Methoxy Butyryl 824-94-2 Pharma Intermediates Chloride) Either / or
44 Cyclo Propyl Carbonyl Chloride 4023-34-1 Prazepam Either / or
45 Cyclohexane Carbonyl Chloride 2719-27-9 Praziquantel Either / or
46 2-Furoyl Chloride Either / or 527-69-5 Diloxanide
47 Acetyl Salicyl Chloride Either / or 5538-51-2 Pharma Intermediates
GROUP C-2 :- OXIDATION PRODUCT :- 30 MT/Month
48 O P Dichloro Benzoic Acid 50-84-0 Lamotrigine Either / or
49 Para Nitro Benzoic Acid 62-23-7 Pharma Intermediates
GROUP C – TOTAL QUANTITY 30
GROUP – D :- NITRO TO AMINO CONVERSION BY CATALYTIC HYDROGENATION :- 120 MT/Month
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50 Nitro to Amino Conversion by catalytic 120 Pharma Industries Hydrogenation
P-(Nitro methyl)Benzoate Either 619-50-1 / or
5-Amino Salicylic Acid Either / or 89-57-6
4-Amino 2-Chloro Aniline Either 3964-52-1 / or
2,5 Di Amino Toluene 95-70-5
GROUP D – TOTAL QUANTITY 120
GROUP – E :- ALDEHYDE TO ALCOHOL CONVERSION BY CATALYTIC HYDROGENATION :- 120 MT/Month
51 Aldehyde to Alcohol Conversion by catalytic 120 Hydrogenation
Benzyl Alcohol Either / or 100-51-6
P-Hydroxy Benzyl Alcohol Either 623-05-2 / or Pharma Industries P-Chloro Benzyl Alcohol Either / 873-76-7 or
P-Nitro Benzyl Alcohol Either / 619-73-8 or
2,4-Di Nitro Benzyl Alcohol 4836-66-2
GROUP E – TOTAL QUANTITY 120
52 R & D Product 1
Grand Total 381 ---
• The project falls under Category B of project activity 5(f) as per the schedule of EIA Notification 2006. • This case was considered in the SEAC meeting dated 19/03/2020. • Salient features of the project including Water, Air and Hazardous waste management : Sr Particulars Details . no . A A Total cost of Proposed Project 21.7 Crores (Rs. in Crores):
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B Total Plot area ( sq. meter) 8000Sq. m.
Green belt area 2640Sq. m. ( sq. meter) C Employment generation 74
D Water i Source of Water Supply GIDC Bharuch.
(GIDC Bore well, Surface water, Tanker supply etc...)
Status of permission from the concern authority. Unit have Obtained Assurance letter of 411 KLD water consumption from GIDC. ii Water consumption (KLD) Category Quantity Remarks KLD (A)Domestic 7.0 Fresh water (B) Gardening 5.0 Fresh water (C )Industrial Process 98 Fresh water washing 20 Fresh water Boiler 20 Fresh water Cooling 30 Fresh water Others (Scrubber) 17.5 2.5 KLD Fresh water in Process Scrubber. 15 KLD used in Boiler Scrubber. (From Boiler Blow Down) Total Industrial 185.5 Fresh 170.5 KLD + 15 KLD Boiler Blow Down. TOTAL (1+2+3) 197.5 Total Fresh water consumption 182.5 KLD &15 KLD Internal Recycle.
1) Total water requirement for the project: 197.5 KLD 2) Quantity to be recycled: 15 KLD 3) Total fresh water requirement: 182.5KLD
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Category Waste water Remarks KLD (N) Domestic 6.0 Disposed through Soak pit (O) Industrial Process 152 Total 152 KLD generated from which 145.5 KLD will be subjected to ETP. Washing 20 Subjected to ETP Boiler 15 Boiler blow down will be used in Boiler Scrubber. Cooling 5.0 Subjected to ETP Scrubber 5.5 2.5 KLD Scrubber Solution to ETP and 3 KLD Sodium Bisulphite sol. To sell. Total Industrial 197.5 Total 173 KLD Industrial effluents Subjected to ETP. 145.5 KLD from Process+ 20 KLD from Washing + 5 KLD Cooling water + 2.5 KLD Scrubber solution. TOTAL (Domestic + 203.5 Total 203.5 KLD Effluent Generated from Industrial) Domestic and Industrial Activity. From Which, Domestic:-6 KLD to sock pit. Industrial:-197.5 KLD from which 173 KLD effluent subjected to ETP. iv Treatment facility within premises with capacity [In-house ETP (Primary, Secondary, Tertiary), MEE, Stripper, Spray Dryer, STP etc. ➢ ETP Capacity 200 KLD,MEE Capacity 150 KLD, Primary Treatment, Secondary Treatment and Tertiary Treatment. Treatment scheme including segregation at source. ➢ ETP Flow diagram is given below.
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Strip solvent
High COD Collectio Neutralization Stripper MEE MEE Salt To TSDF Plant Effluent from n tank process Sludge
Sludge MEE Condensate
Low COD Collection O & G Neutralization Settling tank Aeration Primary Stream tank Chamber Tank-1 Clarifie r Decanter/ Centrifuge
Aeration Secondary
Tank-2 Clarifier
Activated Pressure Carbon Filter Sand Filter
Final Collection tank Note: (In case of CETP discharge) : Management of waste water keeping in view direction under section 18 (1) (b) of the Water (Prevention and Control of Pollution) act, 1974 issued by CPCB regarding compliance of CETP. ➢ It is new project, then 18 (1) (b) is not applicable. Brief note on adequacy of ZLD (In case of Zero Liquid Discharge): ➢ Not Applicable. v Mode of Disposal & Final meeting point
Domestic: Disposed in soak pit.
Industrial: MEE WITH STRIPPER High Concentrated effluent will be fed to Solvent Stripper for Recovery of solvents. This stream afterwards shall be subjected to Multiple Effect Evaporator (MEE) (Under Vacuum Evaporation). Condensate shall be transferred in O & G Chamber for further treatment at ETP.
PRIMARY TREATMENT 1. Screen, Oil and solvent trap: - This will ensure removal of free and floating
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material, oily material and solvents. These are to be removed manually. The oil and solvent trap unit operation shall work on gravity separation principle. 2. Equalization cum Neutralization tank: - The effluent after removal of screenings, oily matter / solvents shall be collected in equalization cum neutralization tank. Suitable mixing device (flash mixer) shall be used to mix the contents of the tank. Acid and alkali shall be used as per the incoming effluent pH. pH of 7 to 8 shall be maintained here. 3. Settler: - This will be used to remove the Settleable solids from the effluent by sedimentation process and the effluent will be further transferred to Anoxic tank.
SECONDARY TREATMENT Biological Treatment: The biological treatment consist of an Anoxic tank to remove excess Ammonical nitrogen from effluents. It will be followed by Aerobic process. There are two aeration tanks with diffused aeration system. The oxygen supply shall be done by use of air blower and air bubble diffusers. Suitable levels of mixed liquor suspended solids (MLSS) shall be maintained in the aeration system as per detailed biological process design. The excess biological sludge shall be discharged over to the sludge handling system via two clarifiers connected with each aeration tank.
TERTIARY TREATMENT Rest of the treated effluent shall pass through Activated carbon filter, Multi Grade Sand filter. After that it will be send to Finall collection tank for final disposal at CETP Pipeline dahej. vi In case of Common facility (CF) like CETP, Common Spray dryer, Common MEE etc. Name of CF ➢ CETP Pipeline, Dahej. Membership of Common facility (CF) (For waste water treatment)
vii Simplified water balance diagram with reuse / recycle of waste water
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Total Water Requirement 197.5 KLD (Fresh:-182.5 KLD + Recycle:-15 KLD)
Process Scrubber Boiler Cooling Washing Domestic Gardening 7 KLD 10 KLD 98 KLD 2.5 KLD 20 KLD Tower 20 KLD 5 KLD Loss fresh fresh Fresh 30 KLD Fresh Fresh Fresh Fresh
64 KLD 5 KLD Due to 5.5 KLD Loss Chemical 25 KLD Reaction Waste Water Scrubber Solution 15 KLD Blow Loss Generation Down 6 KLD to 152 KLD 20 KLD 5 KLD 5 KLD Sock Pit 2.5 Loss Blow Boiler 3 KLD KLD Down Sodium Scrubb er 2 KLD Strip Bisulphite Solvent Stripper sol. To sell 10 KLD to ash (Mix 152 KLD quenching Solvent)
150 KLD EFFLUENT TREATMENT PLANT (173 KLD)
MEE & ATFD 0.5 145.5 KLD 150 KLD KLD Loss 1 KLD 172 KLD to Sludge CETP Pipeline 4 KLD Dahej MEE Salt viii Reuse/Recycle details (KLD) Total recycle 15KLD Source of waste Application Characteristics of waste Remarks water for reuse area with water to be reused regarding with quantity in quantity in KLD (COD, BOD, TDS etc.) feasibility to KLD (From where (Where it is reuse i.e. it is coming) used) Boiler Blow down 15 KLD Boiler Waste water Reusable in 15 KLD blow down will characteristics Boiler be reused in COD:-50-70 mg/l, Scrubber boiler scrubber. BOD:-15-25 mg/l and TDS:- 1500-2000 mg/l.
E Air i Flue gas emission details No. of Boilers/TFH/Furnaces/DG sets etc. with capacities viz. TPH, Kcal/hr, MT/hr, KVA etc. - Source of Stack Quantity Type of Air Pollution Control Sr. Type of emission Height of Fuel emissions Measures no. Fuel With (meter) MT/Day i.e. Air (APCM)
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Capacity Pollutants
Boiler-1 Agro Agro (5 MT/Hr.) waste :- waste / 0.8 MT/Hr PM Cyclone Separator 01 Coal 30 OR SO2 + Bag filter + water
Boiler-1 Coal:- 0.7 NOX scrubber (3 MT/Hr.) MT/Hr (Stand By) Thermic Fluid Agro Heater Agro waste :- (12 Lacs waste / 0.30 Kcal/Hr.) MT/Hr OR PM Cyclone Separator Coal 02 Thermic Fluid 30 Coal:- SO2 + Bag filter + water
Heater 0.25 NOX scrubber (6 Lacs MT/Hr Kcal/Hr.) (Stand By) D.G. Set 15 Lit/ Hr. PM Adequate Stack (250 KVA) Diesel Or 360 SO2 Height 03 & 11 NOX (250 KVA) Lit/Day
ii Process gas emission details i.e. Type of pollutant gases (SO2, HCl, NH3, Cl2, NOx etc.) - Specific Source of Stack/Vent Air Pollution Control emission Type of Sr. no. Height Measures (Name of the Product emission (meter) (APCM) & Process)
1. Reaction vessel -1 NH3 11 Two Stage WaterScrubber
2. Reaction vessel -2 H2S 11 Two Stage Alkali Scrubber
3. Reaction vessel -3 HCl 11 Water Scrubber SO 2 followed by Alkali scrubber 4. Reaction vessel -4 NOx 11 Two Stage Alkali Scrubber 5. Spin Flash Dryer PM 30 Bag Filter + Water Scrubber
- iii Fugitive emission details with its mitigation measures:
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As below: Sr. Source Probable Control Measures/ APCM No. Pollutant Emission 1. Solvent Air pollutant • i) Carry out work place area monitoring storage tank (VOC) to find out concentration level in ambient air. • ii) Provision of breather valve cum flame arrester. 2. Solvent Air pollutant • i) Solvent recovery system with steam recovery (VOC) condensation system. system • ii) Pumps & motors are mechanical seal type. 3 Handling of Air pollutant • i) Provision of exhaust ventilation raw material (PM) • ii) Provision of PPE. bags in • iii) Provision of Job rotation to reduce storage area exposure. 4 Flange joints Air pollutant • i) Routine &periodic inspection to of pipeline, (VOC) check leakage. pump & • ii) Preventive maintenance, Follow motors SOP for maintenance. • iii) Pumps & motors will be mechanical seal type. • iv) LDAR program will be followed. • Provision of Flange guard. 5 Solid raw Air pollutant Hopper will be provided with powder material (PM) transfer system. transferring to reactor 6 Liquid raw Air pollutant • Feeding of liquid raw material will be material (VOC) carried out by closed pipeline and transferring to mechanical seal pump. reactor 7 Loading Air pollutant • Unloading through pipeline to tank in a /unloading at (VOC) close system. storage area
F Hazardous wastes (as per the Hazardous and Other Wastes (Management and Transboundary Movement) Rules 2016. i -
Sr. Type/Name of Specific Categor Quantity Management of HW no Hazardous waste Source of y and (MT/Annu . generation Schedul m) (Name of e as per
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the Activity, HW Product Rules. etc.) 1. ETP Sludge From ETP & 35.3 653 Collection, Storage, Production Transportation, Disposal Process at TSDF site authorized by the GPCB. 2. MEE salt From 35.3 1460 Collection, Storage, Evaporator Transportation, Disposal at TSDF site authorized by the GPCB. 3. Iron Sludge Production 35.3 840 Collection, Storage, process of Transportation, and send 2,5 Dimethyl to Cement Industries for PPD Co-Processing. 4. Recoverable Spent From SRP 20.2 31,860 Collection, Storage, Solvents Unit Transportation & recover and reuse internally. 5. Strip solvent From 20.2 730 Collection, Storage, Send (Mix Solvent) Solvent for Co-Processing. Stripper 6. Distillation Residue Production 20.3 1059 Collection, Storage, Send process of for Co-Processing. TRAMADOL
HCL 7. Empty From 33.1 30 Collection, storage, barrels/containers/lin Packing transportation & disposal ers contaminate with Material by selling to GPCB hazardous authorized recycler chemicals/wastes 8. Used or Spent oil From 5.1 7 Collection, storage, Lubrication transportation & disposal by selling to GPCB authorized recycler/refiner. 9. Spent Production 28.3 300 Collection, Storage & Carbon/Charcoal process of Disposal by sent it to Co- Rosiglitazon Processing. e Maleate, and from ETP & solvent recovery system 10 Spent Catalyst Production 28.2 169 Collection, Storage, . process of Transportation & sell to Venlafaxine supplier for reactivation & reuse. 11 Hyflo Production 28.3 10 Collection, Storage & . process of Disposal by sent it to Co- Fluconazole Processing. 12 Process solid waste Production 28.1 912 Collection,
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. process of Decontamination, Sucralfate Disposal by sent it to USP & From Co-Processing. R& D Product
13 Sodium Bromide Generated B15 972 Collection, Storage and . Solution from disposal by sell out to manufacturi authorize vendor under ng of PIK Rule 9 permission. 14 Sodium Bisulphite Scrubber B2 1059 . Solution (30-35 %) Solution Collection, Storage and Generated disposal by sell out to authorized vendor under from 2 Rule 9 permission or in Chloro Ethyl house disposal Amine HCl 15 Liquor Ammonia Generated B2 127.5 Collection, Storage and . solution from treated in its own Effluent manufacturi Treatment Plant. ng process of Atenolol. 16 Sodium Bisulfide Generated B2 217.5 Collection, Storage and . Solution from treated in its own Effluent manufacturi Treatment Plant. ng process of Atenolol. 17 Date expired Product From 28.4 12 Collection, storage, . premises transportation and send for Co-Processing. 18 Off-specification Production 28.5 12 Collection, storage, . Product process transportation and send for Co-Processing.
ii Membership details of TSDF, CHWIF etc. Unit have obtain membership (For HW management) certificate of TSDF and Co- processing. iii Details of Non-Hazardous waste & its disposal MSW waste will be collected by (MSW and others) notified authority of GIDC.
Sr. Waste Quantity Mode Of Disposal No. 1. Glass Waste ( Z13) 0.01 To TSDF. MT/month 2. Paper waste (Z44) 0.1 MT/month At notified area facility. 3. Fly Ash 1.5 MT/ Send to authorize Brick Month manufactures
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G Solvent management, VOC emissions etc.
i Types of solvents, Details of Solvent recovery, % recovery, reuse of recovered Solvents etc. (Details in Table Format) Sr Name of Name of Produ Solvent Solvent Solvent Percentag . Representati Solvent used ct Quantity recover Recovere e ve Product Quant used in Quantity d Quantity Recovery N ity in ton per in Ton in o. MT/M ton of per ton MT/Month onth product of product
Methanol 2.25 2.16 64.8 96 %
1. Venlafaxine Cyclohexane 30 1.75 1.68 50.4 96 %
Acetic Acid 5.63 5.40 162 96 %
Iso Propyl 2. Escitalopram Alcohol 30 14.21 13.49 142.5 95 % Oxalate
Carbamazep Methanol 3. 30 1.02 0.95 238.10 93 % ine
THEOBROM DIMETHYL 4. 30 0.28 0.27 8.05 96 % INE SULPHATE
METOPROL 5. OL Acetone 30 5.48 5.37 161.04 98 % SUCCINATE
6. ATENOLOL Toluene 30 0.83 0.79 23.75 95 %
7. Bis 2 CEA EDC 30 2.6 2.5 74.4 96 %
ii VOC emission sources and its mitigation measures ➢ Provision of mechanical seal in pump. ➢ Regular inspection of tank roof seals. ➢ Adequate measures for the minimization/prevention of the fugitive emission. ➢ Regular maintenance of valves, pumps and other equipment to prevent leakage. ➢ Entire process to be carried out in the closed reactor with proper maintenance of temperature. ➢ Regular periodic monitoring of work area to check the fugitive emission.
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➢ Adequate stack heights as per the GPCB estimation will be provides at all locations to reduce GLCs of pollutants. ➢ Air Pollution Control System will be installed in the plant.
H ➢ Details regarding storage of Hazardous chemicals Storage details Name of major Remarks Hazardous chemicals Drums Acetic Acid -- Drums Acetic anhydride -- Drums Acetone -- Bags Ammonium Sulphate -- Glass Container Bromine -- Drums Hydrochloric acid -- Bags Sodium chloride -- Storage Tank Ethyl acetate -- Bags Sodium bisulphite -- Storage Tank Hexane -- Storage Tank Isopropyl alcohol -- Storage Tank Methyl alcohol -- Drums Nitric acid -- Storage Tank Toluene -- Storage Tank Tetra Hydro Furan --
➢ Applicability of PESO:Unit will apply for PESO Certificate after getting CCA.
• This proposal is for new synthetic organic manufacturing plant at GIDC – Dahej-II Industrial Estate.Upon looking about product profile, Committee insisted for technical justification regarding each group proposed production size with details regarding separate production plant for API drugs and other groups and R and D products in kg/Month in place of Mt/Month. PP submitted industrial effluent segregated in High COD and Low COD stream. • High Concentrated Effluent from the process will be treated in primary ETP and treated effluent passed through solvent stripper followed by MEE & ATFD. MEE condensate will be further treated in Low COD stream ETP. • Low Concentrated Effluent along with MEE condensate will be treated in primary, secondary and Tertiary ETP and treated effluent will be discharged into CETP Dahej pipeline.Boiler blow down will be directly
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reused back in process. • Two stage scrubber will be provided as APCM with each reactor stack. Cyclone followed by Bag Filter & Wet Scrubber will be provided as APCM with steam boiler and thermopack. • Considering the above project details, after detailed discussion, the terms of reference (ToR) were prescribed as below and as per the standard TOR for the Synthetic Organic Chemical projects recommended by SEAC vide letter no. EIA-10-GEN-21/1480 dated 14/09/2017 and approved by SEIAA in its 12th meeting dated 16/09/2017 for the EIA study to be done covering 10 Km radial distance from the project boundary. 1. Technical justification of quantity of ETP sludge and MEE salt against treatment of industrial effluent. 2. Technical justification regarding each group proposed production size with details regarding separate production plant for API drugs and other groups and R and D products in kg/Month in place of Mt/Month. 3. Adequacy assessment report of ETP, MEE and solvent stripper to treat industrial effluent and complete to achiev CETP inlet norms (with stage wise reduction in pollutants like BOD, COD,TDS) 4. Compliance of MoEFCC’s OM dated 01/05/2018 regarding “Corporate Environment Responsibility” (CER). Fund allocation for Corporate Environment Responsibility (CER) shall be made as per MoEFCC’s O.M. No. 22-65/2017-IA.III dated 01/05/2018 for various activities therein. The details of fund allocation and activities for CER shall be incorporated in EIA/EMP report. 5. Explore the use of renewable energy to the maximum extent possible. Details of provisions to make the project energy-efficient through of energy efficient devices and adoption of modes of alternative eco- friendly sources of energy like solar water heater, solar lighting etc. Measures proposed for energy conservation. 6. Qualitative and quantitative analysis of hazardous waste streams generation from the manufacturing process (Product wise) and scrubber. Explore the possibility to reuse such waste streams within premises as raw materials for other products. Sound management of such waste streams as per the HW Rules 2016 as amended time to time. Feasibility study report for utilization shall be incorporated in EIA report. 7. Leak Detection and Repairing Programme (LDAR) for all the volatile organic solvent proposed for use in-house with detailed chemical properties including vapor pressure. LDAR shall endeavor prevention of losses of solvents to the best minimum extent. 8. Safety precautions including flame proof electric fittings to be taken to avoid fire hazard during unloading, storage, transportation, handling and processing of Solvents etc. 9. PP shall furnish status of all the applicable Rules, Acts, Regulation, Clearances in a tabular form. 10. Membership Certificate from Common Facility (mentioning total capacity, consented quantity, occupied capacity and spare capacity and norms of acceptance of effluent from member units) in-line with the direction given by GPCB vide Letter No. GPCB/P-1/8-G (5)/550706 dated 08/01/2020.
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11. Safety precaution measures for hydrogenation and nitration process and mitigation steps for leakage of carcinogenic chemicals from proposed products as per prevailing guidelines. 12. Notarized undertaking for assurance of regular medical checkup of workers for detect carcinogenic compound. 13. MoU for selling of various Hazardous waste to end users having Rule-9 permission under HWRules’2016. 14. Technical justification regarding liquer ammonia and scrubber bleed liquer disposal to ETP alongwith adequacy of ETP to treat such Hazardous waste in ETP. • The TOR prescribed as above and as per the standard TOR approved by SEIAA and the model ToRs available in the MoEF&CC’s sector specific EIA Manual for ‘Synthetic Organic Chemical Industry’ shall be considered as generic TORs for preparation of the EIA report in addition to all the relevant information as per the generic structure of EIA given in Appendix III in the EIA Notification, 2006.
• Further Project Proponent may be advised to submit final EIA Report with EC application within 100 days from the date of issuance of this ToR to expedite processing of Environment Clearance application.
• The project proponent shall have to apply for Environmental clearance through online portal http://environmentclearance.nic.in/along with final EIA report.
12. SIA/GJ/IND2/139973/2020 M/s.Luna chemical Ind. Pvt. Ltd ToR- Amendment Plot No. T-7,T-8,T-9, GIDC-Saykha,Ta- Vagra, Dist.: Bharuch, Gujarat
Category of the unit – 5(f) Project status – ToR Amendment • SEIAA, Gujarat has accorded ToR [Terms of Reference] to M/s: Luna chemical Ind. Pvt. Ltd, vide letter no. SEIAA/GUJ/TOR/5(f)/1062/2019 dated 17/07/ 2019.
• Project proponent has submitted revised Form-1 and PFR with their application for the amendment sought vide online application no. SIA/GJ/IND2/139973/2020 .
• Project proponent requested for amendment in the ToR as under:
Condition As per ToR As per proposed amendment Justification Sr no. in . which no changes . proposed . 1 Point No. Total Water Consumption - 1051 Total Water Consumption - Revision in Mass VI KLD 1051 KLD Balance of Sub: D (Including Domestic) (Including Domestic) Ibuprofen. Detailed (ii) Comparison of Process – 180 KLD Process – 161 KLD Mass Balance of 613th meeting of SEAC-Gujarat, dated 19.03.2020 Page 207 of 217
Washing – 5 KLD Washing – 5 KLD TOR Granted and Boiler – 58 KLD Boiler – 58 KLD TOR Amendment Cooling – 800 KLD Cooling – 819 KLD is given as Gardening – 3 KLD Gardening – 3 KLD Annexure - 1 Domestic – 5 KLD Domestic – 5 KLD 2 Point No. Total Industrial Waste Water - Total Industrial waste water - Revision in Mass VI 161 KLD 227 KLD Balance of Sub: D Ibuprofen. Detailed (iii) Total – 166 KLD (Including Total – 232 KLD (Including Comparison of Domestic) Domestic) Mass Balance of TOR Granted and TOR Amendment is given as Annexure - 1 3 Point No. Treatment Scheme including Treatment Scheme including Revision in Mass VI segregation at source segregation at source Balance of Sub: D & & Ibuprofen. Detailed (iv) Brief note on adequacy of ZLD (In Brief note on adequacy of Comparison of case of Zero Liquid Discharge) ZLD (In case of Zero Liquid Mass Balance of Discharge) TOR Granted and 166 KL/day (Industrial: 161 TOR Amendment KL/day + Domestic: 5 KL/day) 232 KL/day (Industrial: 227 is given as effluents will be generated. Low KL/day + Domestic: 5 KL/day) Annexure - 1 COD effluent stream (158 effluents will be generated. KL/day) will be treated in ETP Low COD effluent stream followed by RO and will be (227 KL/day) will be treated in reused in utilities (135 KL/day i.e. ETP followed by RO and will RO Permeate). Domestic Effluent be reused in utilities (186 (5 KL/day) will be sent to septic KL/day i.e. RO Permeate). tank & soak pit. RO Reject (23 Domestic Effluent (5 KL/day) KL/day) will be treated in Multiple will be sent to septic tank & Effect Evaporator, MEE soak pit. RO Reject (33 Condensate (20 KL/day) will be KL/day) will be treated in reused & its salt after treatment Multiple Effect Evaporator, will be sent to TSDF. 8 KL/Day MEE Condensate (29 effluent from industrial stream will KL/day) will be reused & its be incinerated after neutralize in salt after treatment will be ETP, incinerator ash will be sent sent to TSDF. 8 KL/Day to TSDF. effluent from industrial stream will be incinerated after neutralize in ETP, incinerator ash will be sent to TSDF. 4 Point No. Mode of Disposal and Final Mode of Disposal and Final Revision in Mass VI Meeting Point Meeting Point Balance of Sub: D Ibuprofen. Detailed (v) Domestic: Domestic Effluent (5 Domestic: Domestic Effluent Comparison of KL/day) will be sent to septic tank (5 KL/day) will be sent to Mass Balance of & soak pit. septic tank & soak pit. TOR Granted and TOR Amendment Industrial: 166 KL/day (Industrial: Industrial: 232 KL/day is given as 161 KL/day + Domestic: 5 (Industrial: 227 KL/day + Annexure - 1 KL/day) effluents will be Domestic: 5 KL/day) effluents generated. Low COD effluent will be generated. Low COD stream (158 KL/day) will be effluent stream (227 KL/day)
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treated in ETP followed by RO will be treated in ETP and will be reused in utilities (135 followed by RO and will be KL/day i.e. RO Permeate). reused in utilities (186 KL/day Domestic Effluent (5 KL/day) will i.e. RO Permeate). Domestic be sent to septic tank & soak pit. Effluent (5 KL/day) will be RO Reject (23 KL/day) will be sent to septic tank & soak pit. treated in Multiple Effect RO Reject (33 KL/day) will be Evaporator, MEE Condensate (20 treated in Multiple Effect KL/day) will be reused & its salt Evaporator, MEE after treatment will be sent to Condensate (29 KL/day) will TSDF. 8 KL/Day effluent from be reused & its salt after industrial stream will be treatment will be sent to incinerated after neutralize in TSDF. 8 KL/Day effluent from ETP, incinerator ash will be sent industrial stream will be to TSDF. incinerated after neutralize in ETP, incinerator ash will be sent to TSDF. 5 Point No. Simplified Water Balance Revised Simplified Water Revision in Mass VI Diagram with reuse/recycle of Balance Diagram with Balance of Sub: D wastewater reuse/recycle of wastewater Ibuprofen. Detailed (vii) Comparison of Mass Balance of TOR Granted and TOR Amendment is given as Annexure - 1 6 Point No. Recycle/Reuse details (KLD) Recycle/Reuse details (KLD) Revision in Mass VI Balance of Sub: D RO Permeate – 135 KLD RO Permeate – 186 KLD Ibuprofen. Detailed (viii) MEE Condensate – 20 KLD MEE Condensate – 29 KLD Comparison of Mass Balance of TOR Granted and TOR Amendment is given as Annexure - 1 7 Point No. Incinerator- Incinerator- As per Guidelines VI Type of pollutants: PM, SO2, Type of pollutants: Sub: E (i) NOx, HCl, TOC, CO PM, SO2, NOx, HCl, TOC, CO, HF, Dioxin + Furans,Cd APCM- Ventury scrubber + + Th + theirCompounds, Hg Packed bed scrubber+ Drop back and itsCompounds,Sb + As + scrubber Pb +Cr + Co + Cu +Mn + Ni + V +theircompounds
APCM- Ventury scrubber + Packed bed scrubber+ Drop back scrubber 8 Point No. Spent Solvent - 408 MT/Annum Spent Solvent - 408 Revision in Mass VI Poly Aluminium Chloride - 39600 MT/Annum Balance of Sub: F (i) MT/Annum Poly Aluminium Chloride Ibuprofen. Detailed Green Acid- 4320 MT/Annum (Spent) containing HCl Comparison of Distillation Residue -60 Solution - 17000 MT/Annum Mass Balance of MT/Annum Green Acid-14400 TOR Granted and MT/Annum TOR Amendment
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Distillation Residue -60 is given as MT/Annum Annexure - 1 9. Point No. Solvent Management Solvent Management Revision in Mass VI Balance of Sub: G N In R Lo R Lo Na In R L R L Ibuprofen. Detailed (i) a pu ec ss ec ss me pu ec o ec o Comparison of m t (k (k (% (% of t (k s (% s Mass Balance of e (k g) g) ) ) Sol (k g) s ) s TOR Granted and of g) ve g) (k ( TOR Amendment S nt g) % is given as ol ) Annexure - 1 ve ED 20 19 5 97 2. nt C 47 97 0 .5 4 E 13 12 20 98 1. 5 5 D 00 80 .4 54 IP 37 34 2 92 7. C 6 A 14 36 7 .5 4 IP 91 66 25 72 27 8 1 9 A 0 0 0 .5 .4 N- 29 29 9 97 3 3 7 He 98 08 0 N- 12 12 60 95 4. xa H 60 00 .2 76 ne ex 4 Ac 24 24 5 97 2. a eto 74 24 0 .9 0 n ne 8 2
e A 14 13 15 89 10 ce 80 30 0 .8 .1 to 7 3 n e
• PP has submitted amendment in water balance diagram, air matrix and subsequent changes in hazardous waste generation only. There is no change in product profile due to proposed amendment.
• This proposal was considered in the SEAC meeting dated 19.03.2020. Committee deliberated on need for the proposed change in ToR, water balanc, diagramHW management, area adequacy etc.
• Committee noted that they have proposed to change water balance diagram due to change in mass balance of Ibuprofen product. Detailed Comparison of Mass Balance of TOR Granted and TOR Amendment is. Submitted by PP. Committee noted that PP has revised water consumption for process and cooling and industrial waste water increase from 161 KLD to 227 KLD.PP has shown treatment of 227 KLD (industrial effluent) in ETP and RO plant and RO reject will be evaporated in in-house MEE.RO permeate(186 KLD)h and MEE condensate(29 KLD) will be reused back in process and subsequent change in Hazardous waste matrix. PP has also submitted change in Hazardous waste like Poly Aluminium Chloride (Spent) containing HCl Solution - 17000 MT/Annum in place of Poly Aluminium Chloride - 39600 MT/Annum and Green Acid-14400 MT/Annum in place of Green Acid- 4320 MT/Annum.PP has also revised pollutants
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from incinerator and solvent management.
• After deliberation, it was decided to recommend for amendment in TOR as requested.
• Based on the information furnished by the project proponent in revised Form-1, PFR and relevant documents, Committee decided for the amendment sought and now project activity/ details mentioned in the TOR letter no. SEIAA/GUJ/TOR/5(f)/1062/2019 dated July 17, 2019 is amended as below and ToR mentioned in ToR letter no- SEIAA/GUJ/TOR/5(f)/1350/2019 dated 3/10/2019 shall remain unchanged:
1. Salient features of the project including Water, Air and Hazardous waste management now read as under in place of previously mentioned in ToR letter no- SEIAA/GUJ/TOR/5(f)/1062/2019 dated July 17, 2019
Sr. Particulars Details no. A A Total cost of Proposed Project Rs. 20 Crores (Rs. in Crores): B Total Plot area (sq. meter) 44791.8 Sq. m. Green belt area 14781 Sq. m. (sq. meter) C Employment generation 50 Nos. D Water i Source of Water Supply GIDC Water Supply (GIDC Bore well, Surface water, Tanker supply etc...) Status of permission from the concern authority. Obtained vide letter no. GIDC/DEE (WS)/BRH/139 dated 14/02/2019 ii Water consumption (KLD) Category QuantityKLD (Y) Domestic 5 (Z) Gardening 3 (AA) Industrial Process 161 Washing 5 Boiler 58 Cooling 819 Others 0 Industrial Total 1043 Total (A + B + C) 1051 1) Total water requirement for the project: 1051 KLD 2) Quantity to be recycled: 215KLD 3) Total fresh water requirement: 836 KLD iii Waste water generation (KLD) Category Waste waterKLD
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(P) Domestic 5 (Q) Industrial Process 128 Washing 5 Boiler 24 Cooling 70 Others 0 Total Industrial 227 waste water Total [A + B] 232
iv Treatment facility within premises with capacity [In-house ETP (Primary, Secondary, Tertiary), MEE, Stripper, Spray Dryer, STP etc. ➢ ETP followed by RO & MEE Treatment scheme including segregation at source. ➢ 232 KL/day (Industrial: 227 KL/day + Domestic: 5 KL/day) effluents will be generated. Low COD effluent stream (219 KL/day) will be treated in ETP followed by RO and will be reused in utilities (186 KL/day i.e. RO Permeate). Domestic Effluent (5 KL/day) will be sent to septic tank & soak pit. RO Reject (33 KL/day) will be treated in Multiple Effect Evaporator, MEE Condensate (29 KL/day) will be reused & its salt after treatment will be sent to TSDF. 8 KL/Day effluent from industrial stream will be incinerated after neutralize in ETP, incinerator ash will be sent to TSDF. Note: (In case of CETP discharge) : Management of waste water keeping in view direction under section 18 (1) (b) of the Water (Prevention and Control of Pollution) act, 1974 issued by CPCB regarding compliance of CETP. ➢ Not Applicable Brief note on adequacy of ZLD (In case of Zero Liquid Discharge): ➢ 232 KL/day (Industrial: 227 KL/day + Domestic: 5 KL/day) effluents will be generated. Low COD effluent stream (219 KL/day) will be treated in ETP followed by RO and will be reused in utilities (186 KL/day i.e. RO Permeate). Domestic Effluent (5 KL/day) will be sent to septic tank & soak pit. RO Reject (33 KL/day) will be treated in Multiple Effect Evaporator, MEE Condensate (29 KL/day) will be reused & its salt after treatment will be sent to TSDF. 8 KL/Day effluent from industrial stream will be incinerated after neutralize in ETP, incinerator ash will be sent to TSDF. v Mode of Disposal & Final meeting point Domestic: Domestic Effluent (5 KL/day) will be sent to septic tank & soak pit. Industrial: Low COD effluent stream (219 KL/day) will be treated in ETP followed by RO and will be reused in utilities (186 KL/day i.e. RO Permeate). Domestic Effluent (5 KL/day) will be sent to septic tank & soak pit. RO Reject (33 KL/day) will be treated in Multiple Effect Evaporator, MEE Condensate (29 KL/day) will be reused & its salt after treatment will be sent to TSDF. 8 KL/Day effluent from industrial stream will be incinerated after neutralize in ETP, incinerator ash will be sent to TSDF. vi In case of Common facility (CF) like CETP, Common Spray dryer, Common MEE etc. Name of CF ➢ Not Applicable Membership of Common facility (CF) (For waste water treatment) Not Applicable vii Simplified water balance diagram with reuse / recycle of waste water
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viii Reuse/Recycle details (KLD) Total reuse155 KLD Source of waste water Application Characteristics of Remarks for reuse with quantity area with waste water to be regarding in KLD (From where it quantity in reused (COD, BOD, feasibility to is coming) KLD (Where it TDS etc.) reuse i.e. is used) RO Permeate 186 KLD COD - <50 mg/L - (Reused in TDS – <100 mg/L Cooling) MEE Condensate 29 KLD COD – <50mg/L - (Reused in TDS – <100 mg/L Boiler)
E Air
613th meeting of SEAC-Gujarat, dated 19.03.2020 Page 213 of 217 i Flue gas emission details No. of Boilers/TFH/Furnaces/DG sets etc. with capacities viz. TPH, Kcal/hr, MT/hr, KVA etc. - Source of Stack Quantit Type Type of Air Pollution Sr. emission Height y of of emissions i.e. Air Control Measures no. With (meter Fuel Fuel Pollutants (APCM) Capacity ) MT/Day Thermic 30 Coal 30 PM Air Pre heater + Multi
Fluid SO2 cyclone + Bag filter + Heater NOx Water Scrubber 1 (15 Lakh Kcal/Hrs) (3 Nos.) Steam 30 Coal 10 PM Air Pre heater + Multi
2 Boiler SO2 cyclone + Bag filter + (7 Ton/Hr) NOx Water Scrubber Furnace (2 30 FO 10 PM Air Pre heater +
3 Nos.) SO2 Heat recovery unit + NOx Caustic Scrubber DG Set 11 HSD 425 PM Adequate Stack 1250 X 2= Lit./Hr SO Height 4 2 2500 KVA NOx (Stand By) PM, SO2, NOx, HCl, TOC, CO, HF, Dioxin + Furans
Cd + Th + their compounds Ventury scrubber + Packed bed scrubber 5 Incinerator 30 FO 2 Hg and its + Compounds Drop back scrubber
Sb + As + Pb + Cr + Co + Cu + Mn + Ni + V + their compound - ii Process gas emission details i.e. Type of pollutant gases (SO2, HCl, NH3, Cl2, NOx etc.)
No Process Gas Emissions iii Fugitive emission details with its mitigation measures: Fugitive emissions are expected to be generated during Operational stage and vehicular movement of the proposed project.
Source: The movement of vehicles carrying chemicals and other materials and vehicles used for
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transport.
Operational Phase: Leakage through valves, pumps, emission from open drum containing chemicals, open feeding; storage tanks, etc.
Following measures is taken and will be adopted to prevent and control fugitive emissions if required:
(1) Airborne dust at all transfers operations/ points will be controlled either by spraying water or providing enclosures. (2) Raw materials loading and unloading will be done in close loop. (3) All the raw materials will be transfer to the reactor in closed loop. (4) Plantation will be done around the project area and along the roads. (5) Adequate ventilation will be provided. (6) Regular maintenance of valves, pumps and other equipment will be done to prevent leakages and thus minimizing the fugitive emissions of VOCs. (7) Entire process will be carried out in the closed reactors with proper maintenance of pressure and temperature. (8) To eliminate chances of leakages from glands of pumps, mechanical seal will be provided at all solvent pumps. (9) Periodic monitoring of work area will be carried out to check the fugitive emission as per the norms of Gujarat Factory Rule.
F Hazardous wastes (as per the Hazardous and Other Wastes (Management and Transboundary Movement) Rules 2016. i Sr. Type/Nam Specific Category Quantity Management of HW no. e of Source of and (MT/Annu Hazardous generation Schedule m) waste (Name of as per HW the Activity, Rules Product etc.) 1 Used Oil Equipment Sch-I/ 480 Collection, Storage, and 5.1 Litres Transportation and selling to Machinery authorized recyclers. 2 Discarded Process Sch-I/ 1200 Collection, Storage, Plastic Bag 33.1 Nos. Transportation and selling to / Liners authorized recyclers. 3 ETP ETP Sch-I/ 2570 Collection, storage, Sludge 35.3 transportation and final disposal at common TSDF 4 MEE Salt MEE Sch-I/ 2190 Collection, storage, 35.3 transportation and final disposal at common TSDF 5 Fly Ash Process -- 1920 Collection, storage, transportation and sell to Fly Ash Brick manufacturer
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6 Spent Process Sch-I/ 408 Collection, Storage, Solvent 26.4 Transportation & Sell to end user under Rule-9 Permission. 7 Distillation Distillation Sch-I/ 60 Collection, Storage, Residue 20.3 Transportation & Sent toCo- Processing in Cement Industries or CHWIF 8 Recovered Process – Sch-I/ 7512 Collection, Storage & re-used Acetic Acid Acetic 26.1 in process for mfg. of Acetic Anhydride Anhydride (Reqd Qty:- 10080 TPA). 9 Ash from Incinerator Sch-I/ 15 Collection, storage, incinerator 37.2 transportation and final and flue disposal at common TSDF gas cleaning residue 10 Poly Process – Sch-I/ 28.1 17000 Collection, Storage & Sold end Aluminium Ibuprofen users under Rule – 9 Chloride Permission 11 Green Acid Process – Sch-I/ 28.1 14400 Ibuprofen - ii Membership details of TSDF, CHWIF etc. BEIL, Ankleshwar TSDF Membership (For HW management) vide letter no. BEIL/ANK/2019 dated 18/02/2019 iii Details of Non-Hazardous waste & its disposal Not Applicable (MSW and others) G Solvent management, VOC emissions etc. i Types of solvents, Details of Solvent recovery, % recovery, reuse of recovered Solvents etc. Name of Boilin Vapour Inpu Recovere Loss Recover Loss Solvent g Pressure t Qty d Qty Qty y % % Point (kPa@20 (kg) (kg) (kg) (°C) °C) Acetone 56.5 53.32 2474 2424 50 97.98 2.02 IPA 82.5 4.4 3714 3436 278 92.51 7.49 EDC 83.5 11.99 2047 1997 50 97.55 2.45 N- 69 19.99 2998 2908 90 97.00 3.00 Hexane A highly efficient and full fledge solvent recovery system from spent solvent is installed to recover maximum possible solvent and will be reused back in process. For the efficient solvent recovery system, cooling water followed by chilled water circulation along with high efficiency plate and frame type heat exchangers are installed along with vent traps for arresting any escape of vapours from the reaction and distillation unit. The reactors will be connected to water condenser and secondary condenser connected with chilled water system and vents are having flame arrestors and breather valves. The receiver will also be jacketed with circulation of water. The recovered solvents will then be reused in the same product/ same stage. Solvent which cannot be used at site will be sold to end users having permission under rule 9. Distillation residue shall be disposed through Co-processing with cement industry. The
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recovery efficiency of every solvent used is approximately 95%.
ii VOC emission sources and its mitigation measures Source: VOC emissions mainly from material handling, loading / unloading and process vessels. Mitigation Measure: Material handling in closed loop system. Loading / Unloading will be also connected with the Central Absorption Systems. Regular maintenance of valves, pumps and other equipment will be done to prevent leakages and thus minimizing emissions of VOCs. Breather valves will be provided on solvent tanks. To eliminate chances of leakages from glands of pumps, mechanical seal will be provided at all solvent transferring pumps. Entire process will be carried out in the closed reactors with proper maintenance of pressure and temperature.
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Meeting ended with thanks to the Chair. Minutes approved by:
1. Dr. Dinesh Misra, Chairman, SEAC
2. Shri S. C. Srivastav, Vice Chairman, SEAC
3. Shri V. N. Patel, Member, SEAC
4. Shri R. J. Shah, Member, SEAC
5. Shri Shri A. K. Muley, Member, SEAC
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