Genesis and Geometry of the Meiklejohn Peak Lime Mud-Mound
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Bioinspired Intrinsic Control of Freeze Cast Composites: Harnessing Hydrophobic Hydration and Clathrate Hydrates
Acta Materialia 114 (2016) 67e79 Contents lists available at ScienceDirect Acta Materialia journal homepage: www.elsevier.com/locate/actamat Full length article Bioinspired intrinsic control of freeze cast composites: Harnessing hydrophobic hydration and clathrate hydrates * Steven E. Naleway a, , Christopher F. Yu b, Rachel L. Hsiong b, Arijit Sengupta e, Peter M. Iovine e, John A. Hildebrand c, Marc A. Meyers a, b, d, Joanna McKittrick a, b a Materials Science and Engineering Program, University of California, San Diego, 9500 Gilman Drive, La Jolla, CA 92093, USA b Department of Mechanical and Aerospace Engineering, University of California, San Diego, 9500 Gilman Drive, La Jolla, CA 92093, USA c Scripps Institution of Oceanography, University of California, San Diego, 9500 Gilman Drive, La Jolla, CA 92093, USA d Department of NanoEngineering, University of California, San Diego, 9500 Gilman Drive, La Jolla, CA 92093, USA e Department of Chemistry and Biochemistry, University of San Diego, San Diego, CA 92110, USA article info abstract Article history: Bioinspired ZrO2-epoxy, two-phase composite materials were fabricated by the freeze casting fabrication Received 7 January 2016 technique followed by polymer infiltration. These materials were intrinsically controlled by adding Received in revised form varying concentrations of the monofunctional alcohols ethanol (EtOH), n-propanol (n-PrOH) and n- 9 May 2016 butanol (n-BuOH). The microstructures of freeze cast scaffolds created with these alcohol additives Accepted 10 May 2016 demonstrated maximum pore areas (peak Ap) at concentrations of 10, 5e7 and 3 vol% for EtOH, n-PrOH and n-BuOH respectively. Differential scanning calorimetry analyses of binary mixtures of these additives and water suggested only n-PrOH was capable of developing clathrate hydrates. -
Sensors and Measurements Discussion
“Measurements for Assessment of Hydrate Related Geohazards” Report Type: Topical No: 41330R07 Starting March 2002 Ending September 2004 Edited by: R.L. Kleinberg and Emrys Jones September 2004 DOE Award Number: DE-FC26-01NT41330 Submitting Organization: ChevronTexaco Energy Technology Company 2811 Hayes Road Houston, TX 77082 DISCLAIMER “This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor any of their employees, makes any warranty, expressed or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference herein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise does not necessarily constitute or imply its endorsement, recommendation, or favoring by the United States Government or any agency thereof. The views and opinions of the authors expressed herein do not necessarily state or reflect those of the United States Government or any agency thereof.” ii Abstract Natural gas hydrate deposits are found in deep offshore environments. In some cases these deposits overlay conventional oil and gas reservoirs. There are concerns that the presence of hydrates can compromise the safety of exploration and production operations [Hovland and Gudmestad, 2001]. Serious problems related to the instability of wellbores drilled through hydrate formations have been document by Collett and Dallimore, 2002]. A hydrate-related incident in the deep Gulf of Mexico could potentially damage the environment and have significant economic impacts. -
Managing Winter Injury to Trees and Shrubs
Publication 426-500 Managing Winter Injury to Trees and Shrubs Diane Relf Extension Specialist, Horticulture, and Bonnie Appleton, Extension Specialist, Horticulture; Virginia Tech Reviewed by David Close, Consumer Horticulture and Master Gardener Specialist, Horticulture, Virginia Tech Introduction evergreen needles or leaves. It is worst on the side facing the wind. This can be particularly serious if plants are It is often necessary to provide extra attention to plants near a white house where the sun’s rays reflect off the in the fall to help them over-winter and start spring in side, causing extra damage. peak condition. Understanding certain principles and cultural practices will significantly reduce winter damage Management: Proper watering can is a critical factor in that can be divided into three categories: desiccation, winterizing. If autumn rains have been insufficient, give freezing, and breakage. plants a deep soaking that will supply water to the entire root system before the ground freezes. This practice is Desiccation especially important for evergreens. Watering when there Desiccation, or drying out, is a significant cause of dam- are warm days during January, February, and March is age, particularly on evergreens. Desiccation occurs when also important. water leaves the plant faster than it is taken up. Several environmental factors can influence desiccation. Needles Also, mulching is an important control for erosion and and leaves of evergreens transpire some moisture even loss of water. A 2-inch layer of mulch will reduce water during the winter months. During severely cold weather, loss and help maintain uniform soil moisture around the ground may freeze to a depth beyond the extent of roots. -
Journées “Hydrates”
Journées Hydrates, Brest, 09‐13 septembre 2019 Journées “Hydrates” 09‐13 septembre 2019 IFREMER Pôle Numérique 305 Avenue Alexis de Rochon 29280 PLOUZANE 1 Journées Hydrates, Brest, 09‐13 septembre 2019 2 Journées Hydrates, Brest, 09‐13 septembre 2019 WELCOME We are pleased to welcome you for the 2nd meeting of the French research consortium GdR2026 Hydrates at the University of Bordeaux. This event brings together leading experimental, theoretical, and computational scientists from among the unusually broad community of researchers interested in the various research areas of gas hydrates going from chemical and energy engineering to geosciences and astrophysics through physical‐ chemistry and thermodynamics. The issues addressed during this meeting concern major aspects of “hydrate sciences” such as hydrate/substrates interactions, thermodynamics, formation kinetics, cage occupancy and as well as formation at extreme conditions. The workshop is divided into two parts. The first part is dedicated to meetings of french research consortiums working on a common project (ANR, EU, etc.) in closed session. The second part is the general meeting, gathering about 60 participants. Its scientific program contains about 31 presentations, including invited talks, oral contributions and poster presentations. Organizing committee Livio Ruffine ‐ IFREMER, Brest Hélène Ondréas ‐ IFREMER, Brest Marie‐Odile Lamirault‐Gall ‐ IFREMER, Brest Alison Chalm‐ IFREMER, Brest Elisabeth Savoye ‐ IFREMER, Brest Olivia Fandino‐Torres – IFREMER, Brest Arnaud Desmedt, ISM CNRS ‐ Univ. Bordeaux Karine Ndiaye, ISM CNRS ‐ Univ. Bordeaux Audrey Bourgeois, ISM CNRS ‐ Univ. Bordeaux Daniel Broseta – LFC‐R UMR 5150 CNRS, Total, Univ. Pau Scientific Committee Baptiste Bouillot ‐ LGF, UMR 5703 CNRS, Mines Saint‐Etienne Daniel Broseta – LFC‐R UMR 5150 CNRS, Total, Univ. -
Final Investigation Report: E.I
Toxic Chemical Release at the U.S. Chemical Safety and DuPont La Porte Chemical Facility Hazard Investigation Board La Porte, Texas | Incident Date: November 15, 2014 | No. 2015-01-I-TX Investigation Report Published: June 2019 Investigation Report EY SSUES K I : • Emergency Planning and Response (Preparedness) • Implementation of Process Safety Management Systems • Assessment of Process Safety Culture FINAL COPY Toxic Chemical Release at the DuPont La Porte Chemical Facility U.S. Chemical Safety and Hazard Investigation Board La Porte, Texas | Incident Date: November 15, 2014 | No. 2015-01-I-TX The U.S. Chemical Safety and Hazard Investigation Board (CSB) is an independent federal agency whose mission is to drive chemical safety change through independent investigations to protect people and the environment. The CSB is a scientific investigative organization, not an enforcement or regulatory body. Established by the Clean Air Act Amendments of 1990, the CSB is responsible for determining accident causes, issuing safety recommendations, studying chemical safety issues, and evaluating the effectiveness of other government agencies involved in chemical safety. More information about the CSB is available at www.csb.gov. The CSB makes public its actions and decisions through investigative publications, all of which may include safety recommendations when appropriate. Types of publications include: Investigation Reports: Formal, detailed reports on significant chemical incidents that include key findings, root causes, and safety recommendations Investigation Digests: Plain-language summaries of Investigation Reports Case Studies: Reports that examine fewer issues than Investigation Reports Safety Bulletins: Short publications typically focused on a single safety topic Hazard Investigations: Broader studies of significant chemical hazards Safety Videos: Videos that animate aspects of an incident or amplify CSB safety messages CSB products can be freely accessed at www.csb.gov or obtained by contacting: U.S. -
Mechanical Characterization Via Full Atomistic Simulation: Applications to Nanocrystallized Ice
Mechanical Characterization via Full Atomistic Simulation: Applications to Nanocrystallized Ice A thesis presented By Arvand M.H. Navabi to The Department of Civil and Environmental Engineering in partial fulfillment of the requirements for the degree of Master of Science in the field of Civil Engineering Northeastern University Boston, Massachusetts August, 2016 Submitted to Prof. Steven W. Cranford Acknowledgements I acknowledge generous support from my thesis advisor Dr. Steven W. Cranford whose encouragement and availability was crucial to this thesis and also my parents for allowing me to realize my own potential. The simulations were made possible by LAMMPS open source program. Visualization has been carried out using the VMD visualization package. 3 Abstract This work employs molecular dynamic (MD) approaches to characterize the mechanical properties of nanocrystalline materials via a full atomistic simulation using the ab initio derived ReaxFF potential. Herein, we demonstrate methods to efficiently simulate key mechanical properties (ultimate strength, stiffness, etc.) in a timely and computationally inexpensive manner. As an illustrative example, the work implements the described methodology to perform full atomistic simulation on ice as a material platform, which — due to its complex behavior and phase transitions upon pressure, heat exchange, energy transfer etc. — has long been avoided or it has been unsuccessful to ascertain its mechanical properties from a molecular perspective. This study will in detail explain full atomistic MD methods and the particulars required to correctly simulate crystalline material systems. Tools such as the ReaxFF potential and open-source software package LAMMPS will be described alongside their fundamental theories and suggested input methods to simulate further materials, encompassing both periodic and finite crystalline models. -
Permafrost Soils and Carbon Cycling
SOIL, 1, 147–171, 2015 www.soil-journal.net/1/147/2015/ doi:10.5194/soil-1-147-2015 SOIL © Author(s) 2015. CC Attribution 3.0 License. Permafrost soils and carbon cycling C. L. Ping1, J. D. Jastrow2, M. T. Jorgenson3, G. J. Michaelson1, and Y. L. Shur4 1Agricultural and Forestry Experiment Station, Palmer Research Center, University of Alaska Fairbanks, 1509 South Georgeson Road, Palmer, AK 99645, USA 2Biosciences Division, Argonne National Laboratory, Argonne, IL 60439, USA 3Alaska Ecoscience, Fairbanks, AK 99775, USA 4Department of Civil and Environmental Engineering, University of Alaska Fairbanks, Fairbanks, AK 99775, USA Correspondence to: C. L. Ping ([email protected]) Received: 4 October 2014 – Published in SOIL Discuss.: 30 October 2014 Revised: – – Accepted: 24 December 2014 – Published: 5 February 2015 Abstract. Knowledge of soils in the permafrost region has advanced immensely in recent decades, despite the remoteness and inaccessibility of most of the region and the sampling limitations posed by the severe environ- ment. These efforts significantly increased estimates of the amount of organic carbon stored in permafrost-region soils and improved understanding of how pedogenic processes unique to permafrost environments built enor- mous organic carbon stocks during the Quaternary. This knowledge has also called attention to the importance of permafrost-affected soils to the global carbon cycle and the potential vulnerability of the region’s soil or- ganic carbon (SOC) stocks to changing climatic conditions. In this review, we briefly introduce the permafrost characteristics, ice structures, and cryopedogenic processes that shape the development of permafrost-affected soils, and discuss their effects on soil structures and on organic matter distributions within the soil profile. -
Ground Freezing and Frost Heaving Penner, E
NRC Publications Archive Archives des publications du CNRC Ground freezing and frost heaving Penner, E. For the publisher’s version, please access the DOI link below./ Pour consulter la version de l’éditeur, utilisez le lien DOI ci-dessous. Publisher’s version / Version de l'éditeur: https://doi.org/10.4224/40000788 Canadian Building Digest, 1962-02 NRC Publications Archive Record / Notice des Archives des publications du CNRC : https://nrc-publications.canada.ca/eng/view/object/?id=15f6f5eb-a070-4327-aec4-71472a903119 https://publications-cnrc.canada.ca/fra/voir/objet/?id=15f6f5eb-a070-4327-aec4-71472a903119 Access and use of this website and the material on it are subject to the Terms and Conditions set forth at https://nrc-publications.canada.ca/eng/copyright READ THESE TERMS AND CONDITIONS CAREFULLY BEFORE USING THIS WEBSITE. L’accès à ce site Web et l’utilisation de son contenu sont assujettis aux conditions présentées dans le site https://publications-cnrc.canada.ca/fra/droits LISEZ CES CONDITIONS ATTENTIVEMENT AVANT D’UTILISER CE SITE WEB. Questions? Contact the NRC Publications Archive team at [email protected]. If you wish to email the authors directly, please see the first page of the publication for their contact information. Vous avez des questions? Nous pouvons vous aider. Pour communiquer directement avec un auteur, consultez la première page de la revue dans laquelle son article a été publié afin de trouver ses coordonnées. Si vous n’arrivez pas à les repérer, communiquez avec nous à [email protected]. Canadian Building Digest Division of Building Research, National Research Council Canada CBD 26 Ground Freezing and Frost Heaving Originally published February 1962 E. -
Report No. REC-ERC-82-17, “Frost Action in Soil Foundations And
REC-ERC-82-17 June 1982 Engineering and Research Center U.S. Department of the Interior Bureau of Reclamation 7-2090 (4-81) . .- water ana Power ~ TECHNICAL RE lPORT STANDARD TITLE PAGE 3. RECIPIENT’S CATALOG NO. 5. REPORT DATE Frost Action in Soil Foundations and June 1982 Control of Surface Structure Heaving 6. PERFORMING ORGANIZATION CODE 7. AUTHORIS) 8. PERFORMING ORGANIZATION C. W. Jones, D. G. Miedema and J. S. Watkins REPORT NO. REC-ERC-B2- 17 9. PERFORMING ORGANIZATION NAME AN0 ADDRESS 10. WORK UNIT NO. Bureau of Reclamation Engineering and Research Center 11. CONTRACT OR GRANT NO. Denver, Colorado 80225 13. TYPE OF REPORT AND PERIOD COVERED 12. SPONSORING AGENCY NAME AND ADDRESS Same 14. SPONSORING AGENCY CODE DIBR IS. SUPPLEMENTARY NOTES Microfiche and/or hard copy available at the Engineering and Research Center, Denver, CO I Ed: ROM 1I6 ABSTRACT This is a report on frost action in soil foundations that may influence the performance of irriga- tion structures. The report provides background information and serves as a general guide for design, construction, and operation and maintenance. It also includes information on the mechanics of frost action, field and laboratory investigations of potential frost problems, case histories of frost damage to hydraulic structures, and measures to control detrimental freezing to avoid damage. The structures mentioned include earth embankment dams with appurte- nant structures, canals with linings, and various other concrete canal structures. 7. KEY WORDS ANO OOCU~~ENT *NALY~IS 3. DESCRIPTORS-- / frost action/ frost heaving/ ice lenses/ frost protection/ foundation dis- placements/ behavior (structural) 5. -
The Rheology of Frozen Soils
The Rheology of Frozen Soils Lukas U. Arenson*1, Sarah M. Springman2, Dave C. Sego1 1 Department of Civil & Environmental Engineering, UofA Geotechnical Centre, 3-065 Markin/CNRL Natural Resources Engineering Facility, University of Alberta, Edmonton, Alberta T6G 2W2, Canada 2 Institute for Geotechnical Engineering, ETH Zurich, Wolfgang-Pauli-Str. 15, 8093 Zurich, Switzerland *E-mail: [email protected] Fax: x1.780.492.8198 Received: 2.6.2006, Final version: 2.8.2006 Abstract: The rheological behaviour of frozen soils depends on a number of factors and is complex. Stress and tempera- ture histories as well as the actual composition of the frozen soil are only some aspects that have to be consid- ered when analysing the mechanical response. Recent improvements in measuring methods for laboratory inves- tigations as well as new theoretical models have assisted in developing an improved understanding of the thermo-mechanical processes at play within frozen soils and representation of their response to a range of per- turbations. This review summarises earlier work and the current state of knowledge in the field of frozen soil research. Further, it presents basic concepts as well as current research gaps. Suggestions for future research in the field of frozen soil mechanics are also made. The goal of the review is to heighten awareness of the com- plexity of processes interacting within frozen soils and the need to understand this complexity when develop- ing models for representing this behaviour. Zusammenfassung: Das rheologische Verhalten von gefrorenen Böden hängt von einer grossen Anzahl verschiedener Faktoren ab und ist äusserst komplex. Druck- und Temperaturgeschichte, sowie die Zusammensetzung des gefrorenen Bodens sind nur einige Aspekte, welche betrachtet und berücksichtigt werden müssen, wenn man die mecha- nischen Eigenschaften analysiert. -
Methane Clathrate Behavior in Martian Surface Ice, and Supporting Morphological Observations
Lunar and Planetary Science XXXIX (2008) 1163.pdf Methane Clathrate Behavior in Martian Surface Ice, and Supporting Morphological Observations. D.S. McMenamin and George E. McGill, Department of Geosciences, University of Massachusetts, Amherst, MA. Email: [email protected]. Introduction: Earlier, we reported on the likeli- If clathrate dissociates due to deformation in the hood that methane clathrate hydrate in martian glaciers HSZ, some methane may escape to the atmosphere. and other surface ice is the source of ancient glacial Trapped methane can re-combine with water to make meltwater features and modern atmospheric methane clathrate again, but if methane does escape and the [1, 2, 3]. In the current work, we consider the behavior temperature is high enough, films and small pockets of of methane clathrate in surface ice, and describe geo- water or brine can form [6]. In a glacier or debris flow morphic features that we interpret as being related to with an ice matrix, this increases pore pressure and clathrate dissociation. Methane clathrate may also be allows slippage of the surrounding layers of ice. When present in permafrost ice [4 5], but because sublima- the ice regelates or the clathrate re-associates, slippage tion of ice at the surface is inevitable, downward mi- stops. If ruptures are on a large enough scale, the ice gration of the HSZ (Hydrate Stability Zone) must re- will move episodically, with most of the movement sult in the gradual destabilization of any clathrate pre- probably near the toe of the glacier or debris flow, sent in surface ice, without the need to hypothesize any where strain rates are highest. -
The Origin of Titan's Atmosphere: Some Recent Advances
The origin of Titan’s atmosphere: some recent advances By Tobias Owen1 & H. B. Niemann2 1University of Hawaii, Institute for Astronomy, 2680 Woodlawn Drive, Honolulu, HI 96822, USA 2Laboratory for Atmospheres, Goddard Space Fight Center, Greenbelt, MD 20771, USA It is possible to make a consistent story for the origin of Titan’s atmosphere starting with the birth of Titan in the Saturn subnebula. If we use comet nuclei as a model, Titan’s nitrogen and methane could easily have been delivered by the ice that makes up ∼50% of its mass. If Titan’s atmospheric hydrogen is derived from that ice, it is possible that Titan and comet nuclei are in fact made of the same protosolar ice. The noble gas abundances are consistent with relative abundances found in the atmospheres of Mars and Earth, the sun, and the meteorites. Keywords: Origin, atmosphere, composition, noble gases, deuterium 1. Introduction In this note, we will assume that Titan originated in Saturn’s subnebula as a result of the accretion of icy planetesimals: particles and larger lumps made of ice and rock. Alibert & Mousis (2007) reached this same point of view using an evolutionary, turbulent model of Saturn’s subnebula. They found that planetesimals made in the solar nebula according to their model led to a huge overabundance of CO on Titan. We obviously have no direct measurements of the composition of these planetes- imals. We can use comets as a guide, always remembering that comets formed in the solar nebula where conditions must have been different from those in Saturn’s subnebula, e.g., much colder.