Fabrication of Manila Hemp Fiber Reinforced Cross Ply Biodegradable Composites and Their Tensile Properties

Home , Manila hemp

Open Journal of Composite Materials, 2018, 8, 75-83 http://www.scirp.org/journal/ojcm ISSN Online: 2164-5655 ISSN Print: 2164-5612

Shinji Ochi

Department of Mechanical Engineering, National Institute of Technology, Niihama College, Ehime, Japan

How to cite this paper: Ochi, S. (2018) Abstract Fabrication of Manila Hemp Fiber Rein- forced Cross Ply Biodegradable Composites Natural plant fibers, including flax, kenaf, jute, bamboo, ramie and much and Their Tensile Properties. Open Journal more are renewable and sustainable resources and are considered good can- of Composite Materials, 8, 75-83. didates for cost-effective alternatives to glass and carbon fibers. In this re- https://doi.org/10.4236/ojcm.2018.83007 search, cross ply biodegradable composites were fabricated by press-forming

Received: April 8, 2018 method. The biodegradable composites consist of Manila hemp textile as a Accepted: June 30, 2018 reinforcement and starch-based biodegradable plastics as a matrix was fabri- Published: July 3, 2018 cated and investigated about mechanical properties. The tensile strength increased with the fiber content until fiber content of about 50% and leveled off Copyright © 2018 by author and thereafter. This dependence on the fiber content is due to the decrease in fiber Scientific Research Publishing Inc. This work is licensed under the Creative strength of loading direction caused by fiber damages introduced during Commons Attribution International hot-pressing. In order to decrease the damage of fibers aligned in loading di- License (CC BY 4.0). rection, Manila hemp textile was produced by using Manila hemp fibers for http://creativecommons.org/licenses/by/4.0/ warp and biodegradable resin thread for weft. As a result, the tensile strength Open Access of cross ply composites increased from 153 MPa to 202 MPa.

Keywords Natural Fiber, Biodegradable Plastics, Manila Hemp, Biocomposites and Mechanical Properties

1. Introduction

These past few years have witnessed the speedy development of scientific tech- niques and an addition in the standard of living of human. However, these devel- opments have their disadvantages. Fossil fuels were running out and there is insuf- ficient space for our garbage. In order to reduce the environmental load generated from the disposal of used plastic products, significant attention has been placed on biodegradable resin. This resin can be completely resolved into water and carbon

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dioxide by the action of the microorganism, when it is disposed of in the soil. Moreover, there are no emissions of toxic gases during incineration. The applica- tion of biodegradable resin has been restricted due to their relatively lower strength compared to conventional plastics such as POM (polyacetal) and nylon. Resent years, because of their extensive use in many diverse fields, plastics, including FRP (fiber reinforced plastics) products have become indispensable to our life. However, the primary raw material used in plastic production is petroleum and there are strong social and economic pressures to conserve petroleum resources. Furthermore, because FRP wastes are non-flammable, they must be disposed of in landfills after use, and this contributes to high environmental loads. The use of natural plant fibers as a reinforcement in FRP to replace synthetic fibers such as glass and carbon fibers is presently receiving attention because of advantages such as renewable resources, low density and high specific strength. Furthermore, in recent years, development of biodegradable composites using natural plant fibers such as flax [1] [2], bamboo [3] [4], pineapple [5], silk [6], jute [7], kenaf [8] and ramie [9] [10] as a reinforcement and biodegradable resin as a matrix is conducted actively. And researches on molding condition, mechanical properties and interfacial bonding have been carried out. In former paper [11], the research about development of high strength unidirectional Manila hemp fiber reinforced biodegradable composites was reported. The unidirectional biodegradable composites were made from Manila hemp fiber bundles and a starch-based emulsion-type biodegradable resin. The tensile and flexural strengths of the composites increased with increasing fiber content up to 70%. The composites possessed extremely high tensile strengths of 365 MPa. The aim of this study is to develop cross ply biodegradable composites to expand the range of applications of the biodegradable composites. Manila hemp textile was used as the reinforcement for cross ply biodegradable composites and investigated about their mechanical properties.

2. Experimental Procedures 2.1. Materials

As a matrix, emulsion-type biodegradable polymer (Miyoshi Oil & Fat Co., LTD.,CP-300) was used. Plastic particles of approximately 5 μm in diameter are suspended in water-based solution with a mass content of about 40%. The properties of this biodegradable plastics are shown in Table 1. And biodegradable resin thread (Miyoshi Oil & Fat Co., LTD., CPR-LF) as a weft for Manila hemp textile were used. This resin thread has same properties as matrix resin. Manila hemp fibers were provided by Fujiseishi Co., LTD in Japan. The dimensions of Manila hemp fibers are shown in Table 2. In this research, fiber bundles which have a diameter of about 200 μm were used. In addition, the surface treatment of fibers was not carried out.

2.2. Preliminary Molded Manila Hemp Textile

Firstly, Manila hemp textiles of 100mm square were produced using Manila

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hemp fibers with textile machine. Next, emulsion-type biodegradable polymer was put on the surface of Manila hemp fibers. The preliminary molded sheets were produced by drying at 105˚C for 120 min in an oven. The photograph of Manila hemp textile produced is shown in Figure 1.

2.3. Laminating Method

As shown in Figure 2, cross ply composites were produced by laminating 0˚ply sheets and 90˚ply sheets alternately. 0˚ply laminates and 90˚ply laminates composites were also produced in the same manner.

2.4. Molding Method

Specimens were produced by the hot-pressing with a metallic mold and a press machine. Firstly, laminated preliminary molded sheets were put into the metallic mold, and then they were heated to 130˚C with the flexible heater rolled around the metallic mold. Next it held at 130˚C for 5 min, and specimens were produced by pressing at 10 MPa for 10 min.

Table 1. Properties of biodegradable resin used as matrix.

Density (g/cm3) 1.18

Melting point (˚C) 58

Water absorption (%) 2

Tensile strength (MPa) 11.7

Young’s modulus (MPa) 415

Table 2. Dimensions of used manila hemp fibers.

Fiber bundle Single fiber

Length (m) Diameter (mm) Length (mm) Diameter (μm)

2 - 3 0.1 - 0.3 2 - 12 10 - 50

Figure 1. Aspect photograph of manila hemp textile.

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Figure 2. Schematic illustration of laminates.

2.5. Mechanical Testing

Tensile test was carried out by using 5567 type Instron testing machine. The width, thickness and length of the tensile specimen are 10 mm, 0.8 - 1.5 mm and 100 mm, respectively. Tensile test was performed at a strain rate of 0.03 per min and the gauge length of 30 mm. Figure 3 shows shape and dimensions of tensile specimen.

3. Results and Discussions 3.1. Microstructure of Cross Ply Biodegradable Composites

The top view and transverse section of fabricated cross ply biodegradable composites is shown in Figure 4 and Figure 5, respectively. From these figures, Ma- nila hemp fibers distributed straight in bi-directions. From these figures, it can be observed that the distribution of fibers is parallel, and that there are no voids or fiber contacts that would cause a decrease in strength. To use an emulsion-type biodegradable resin, provides a suitable internal environment for achieving high fiber volume such as 60%. And the density of the cross ply biodegradable composites indicates 1.09 g/cm3.

3.2. Tensile Properties of Cross Ply Biodegradable Composites

Figure 6 shows the relationship between tensile strength of cross ply composites and fiber content. Figure 6 shows relationship between tensile strength and fiber content. Symbols of △ , ○, ▽ and □ indicate tensile strength of 0˚ply laminates, cross ply laminates, 90˚ply laminates and biodegradable resin. From this figure, tensile strength reached 153 MPa at 50% of fibers, but remain constant thereafter. The model of cross ply laminates is shown in Figure 7. The stress of parallel to loading direction and stress of parallel to vertical direction are expressed as σp and σv, respectively. When applied stress is greater than σp, cross ply laminates will fracture. This fracture stress is given by Equation (1) [12]. Symbols of a and b indicate the thickness of 0˚ply and 90˚ply.

σσ=p ⋅ aab( + ) (1)

Since the cross ply was laminated as a = b in this research, fracture stress is given by Equation (2).

σσσ= ( pv+ ) 2 (2)

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Figure 3. Shape and dimensions of tensile specimen.

Figure 4. Top view of cross ply biodegradable composites.

Figure 5. Optical micrograph of transverse section of cross ply biodegradable composites with 60% of fibers.

500 0o ply C r oss pl y 400 o (MPa) 90 ply

σ R esi n 300

200

100 Tensile strength strength Tensile 0 0 20 40 60 80 10 Volume fraction of M anila hemp fiber (% ) Figure 6. Relationship between tensile strength and volume fraction of Manila hemp fiber of biodegradable composites.

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Loading direction

a b

Figure 7. Schematic illustration of model for cross ply composites.

The dotted line in Figure 6 represents the theoretical strength value calculated from Equation (2). It can be seen that tensile strength properties of cross ply laminates significantly depend on the strength of 0˚ply laminates. As can be seen from fracture behavior of tensile specimen (Figure 8), the fibers parallel to loading direction were subject to getting damage by the fibers that intersected perpendicularly with the fibers parallel to loading direction. It was found that such fiber damage controls the fracture behavior of whole composites. The experimental values of cross ply laminates are slightly higher than calculated values from Equation (2) in Figure 6, because of neglecting the strength of 90˚ply laminates. Taking into account the strength of 90˚ply laminates, the strength of cross ply laminates is given by Equation (3).

σσσ= ( pv+ ) 2 (3)

The solid line in Figure 6 is the theoretical strength calculated from Equation (3), and the strength obtained from Equation (3) shows a good agreement with experimental result.

3.3. Development of High Strength Cross Ply Biodegradable Composites

Figure 9 shows top view of Manila hemp textile made using Manila hemp fibers for warp and biodegradable resin thread for weft. And cross ply biodegradable composites were fabricated at same method as section 2.4. Top view of cross ply biodegradable composites was shown in Figure 10. From this figure, Manila hemp fibers were distributed parallel, furthermore biodegradable resin thread were mixed with biodegradable resin of matrix by heat during hot pressing. Figure 11 shows relationship between tensile strength and fiber content. Symbols of △, ○, ▽ and □ indicate tensile strength of 0˚ply laminates, cross ply laminates, 90˚ply laminates and biodegradable resin. From this figure, both tensile strength of 0˚ply laminates and cross ply laminates increase lineally with the fiber content until fiber content of 70%. And at fiber content of 70%, the cross-ply composites possessed extremely high tensile strength of 202 MPa, the tensile strength of cross ply composites using biodegradable resin thread for weft indicate high value than that of cross ply composites using Manila hemp fiber for weft.

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Figure 12 shows fracture behavior of cross ply composites after tensile test. In the case of specimen using Manila hemp fibers both warp and weft intersected perpendicularly with the fibers parallel to loading direction as shown Figure 7. However, in the case of specimen using biodegradable resin thread for weft cannot find influence of weft. Because the influence of the weft did not appear, tensile strength is guessed to be increase lineally with fiber content and indicate high strength than conventional composites.

Figure 8. Fracture behavior of cross ply biodegradable composites reinforced by Manila hemp fibers.

Figure 9. Aspect photograph of Manila hemp textile using biodegradable resin fiber for weft.

Figure 10. Top view of cross ply biodegradable composites using biodegradable resin thread for weft.

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500 ° 400 0 ply

(MPa) C r oss- ply 90°ply σ 300 R esin

200

100 Tensile strength strength Tensile 0 0 20 40 60 80 10 V olume fr action of M anila hemp fiber (% ) Figure 11. Relationship between tensile strength and volume fraction of Manila hemp fiber of biodegradable composites.

Figure 12. Fracture behavior of specimen after flexural test. Molding temperature of 160˚C. fiber content of 50%.

4. Conclusions

This research was performed to examine the tensile properties of cross ply biodegradable composites that were made using an emulsion-type biodegradable resin as the matrix and Manila hemp textile as the reinforcement. The results obtained are as follows: 1) Using an emulation type biodegradable polymer and Manila hemp textile, cross ply biodegradable composites that their fibers are arranged straightly and fiber content is high were fabricated. 2) Tensile strength increased with the fiber content until 50% and remained constant thereafter. This fiber content dependence is due to the decrease in fiber strength caused by fiber damage introduced during hot-pressing. 3) Tensile strength of cross ply composites using biodegradable resin thread for weft increased lineally with the fiber content until fiber content of 70%. And at fiber content of 70%, the composites possessed extremely high tensile strength of 202 MPa.

References [1] Perremans, D., Verpoest, I., Dupont-Gillain, C. and Van Vuure, A.W. (2018) Inves- tigation of the Tensile Behavior of Treated Flax Fibre Bio-Composites at Ambient humidity. Composites Science and Technology, 159, 119-126. https://doi.org/10.1016/j.compscitech.2018.02.038

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[2] Bulota, M. and Budtova, T. (2015) Highly Porous and Light-Weight Flax/PLA Composites. Industrial Crops and Products, 74, 132-138. https://doi.org/10.1016/j.indcrop.2015.04.045 [3] Huang, X.S. and Netravali, A. (2009) Biodegradable Green Composites Made Using Bamboo Micro/Nano-Fibrils and Chemically Modified Soy Protein Resin. Compo- sites Science and Technology, 69, 1009-1015. https://doi.org/10.1016/j.compscitech.2009.01.014 [4] Liu, W., Misra, M., Askeland, P., Drzal, L. and Mohanty, A.K. (2005) “Green” Composites from Soy Based Plastic and Pineapple Leaf Fiber: Fabrication and Properties Evaluation. Polymer, 46, 2710-2721. https://doi.org/10.1016/j.polymer.2005.01.027 [5] Luo, S. and Netravali, A.N. (1999) Interfacial and Mechanical Properties of Envi- ronment-Friendly “Green” Composites Made From Pineapple Fibers and Poly(hydroxybutyrate-co-valerate)Resin. Journal of Materials Science, 34, 3709-3719. https://doi.org/10.1023/A:1004659507231 [6] Gao, A.L., Yang, Q. and Xue, L.X. (2016) Poly (L-Lactic acid)/Silk Fibroin Compo- site Membranes with Improved Crystallinity and Thermal Stability from Non-Solvent Induced Phase Separation Processes Involving Hexafluoroisopropanol. Composites Science and Technology, 132, 38-46. https://doi.org/10.1016/j.compscitech.2016.06.011 [7] Plackett, D., Andersen, T.L., Pedersen, W.B. and Nielsen, L. (2003) Biodegradable Composites Based on Polylactide and Jute Fibres. Composites Science and Tech- nology, 63, 1287-1296. https://doi.org/10.1016/S0266-3538(03)00100-3 [8] Julkapli, N.M. and Akil, H.Md. (2008) Degradability of Kenaf Dust-Filled Chitosan Biocomposites. Materials Science and Engineering C, 28, 1100-1111. https://doi.org/10.1016/j.msec.2007.05.003 [9] Zhou, N.T., Yao, L., Liang, Y.Z., Yu, B., Yea, M.Q., Shanc, Z.D. and Qiu, Y.P. (2013) Improvement of Mechanical Properties of ramie/poly (lactic acid) (PLA) Laminated Composites Using a Cyclic Load Pre-Treatment Method. Industrial Crops and Products, 45, 94-99. https://doi.org/10.1016/j.indcrop.2012.12.014 [10] Lodha, P. and Netravali, A.N. (2005) Characterization of Stearic Acid Modified Soy Protein Isolate Resin and Ramie Fiber Reinforced “Green” Composites. Composites Science and Technology, 65, 1211-1225. https://doi.org/10.1016/j.compscitech.2004.12.036 [11] Ochi, S. (2006) Development of High Strength Biodegradable Composites Using Manila Hemp Fiber and Starch Based Biodegradable Resin. Composites: Part A, 37, 1879-1883. https://doi.org/10.1016/j.compositesa.2005.12.019 [12] Hull and Clyne (1996) An Introduction to Composite Materials. 2nd Edition, Cam- bridge University Press, Cambridge.

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