Paleomagnetism, Magnetic Anisotropy and U-Pb Baddeleyite
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Baddeleyite Microstructures in Variably Shocked Martian Meteorites: an Opportunity to Link Shock Barometry and Robust Geochronology
51st Lunar and Planetary Science Conference (2020) 2302.pdf BADDELEYITE MICROSTRUCTURES IN VARIABLY SHOCKED MARTIAN METEORITES: AN OPPORTUNITY TO LINK SHOCK BAROMETRY AND ROBUST GEOCHRONOLOGY. L. G. Staddon1*, J. R. Darling1, N. R. Stephen2, J. Dunlop1, and K. T. Tait3,4. 1School of Environment, Geography and Geoscience, University of Portsmouth, UK; *[email protected], 2Plymouth Electron Microscopy Centre, Plymouth University, UK, 3Department of Earth Sciences, University of Toronto, Canada, 4Royal Ontario Museum, Toronto, Canada. Introduction: Baddeleyite (monoclinic ZrO2; m- [6]. Shergottites in which plagioclase has undergone ZrO2) has recently been shown to be capable of provid- complete transformation to maskelynite (S4), suggest- ing robust crystallisation ages for shergottites via in- ing shock pressures of at least ~29 GPa [6], are repre- situ U-Pb isotopic analyses [1,2]. However, in contrast sented by enriched shergottites NWA 8679 and NWA to experimental work [3], these studies also highlight 7257. Both samples are similarly evolved lithologies, that U-Pb isotope systematics of baddeleyite can be abundant in late stage phases such as Fe-Ti oxides, Cl- strongly modified by shock metamorphism. Up to apatite and Si- and K- rich mesostasis, though NWA ~80% radiogenic Pb loss was recorded within North- 7257 is doleritic [9,10]. Enriched basaltic shergottite west Africa (NWA) 5298 [1], with close correspond- NWA 5298 represents the most heavily shocked mar- ence of U-Pb isotopic ratios and baddeleyite micro- tian meteorite studied here (S6), containing both structures [4]. Combined microstructural analysis and maskelynite and vesicular plagioclase melt [4]. U-Pb geochronology of baddeleyite therefore offers Baddeleyite grains >2 µm in length were located tremendous potential to provide robust constraints on via a combination of automated backscattered electron crystallisation and impact ages for martian meteorites. -
An Introduction to Isotopic Calculations John M
An Introduction to Isotopic Calculations John M. Hayes ([email protected]) Woods Hole Oceanographic Institution, Woods Hole, MA 02543, USA, 30 September 2004 Abstract. These notes provide an introduction to: termed isotope effects. As a result of such effects, the • Methods for the expression of isotopic abundances, natural abundances of the stable isotopes of practically • Isotopic mass balances, and all elements involved in low-temperature geochemical • Isotope effects and their consequences in open and (< 200°C) and biological processes are not precisely con- closed systems. stant. Taking carbon as an example, the range of interest is roughly 0.00998 ≤ 13F ≤ 0.01121. Within that range, Notation. Absolute abundances of isotopes are com- differences as small as 0.00001 can provide information monly reported in terms of atom percent. For example, about the source of the carbon and about processes in 13 13 12 13 atom percent C = [ C/( C + C)]100 (1) which the carbon has participated. A closely related term is the fractional abundance The delta notation. Because the interesting isotopic 13 13 fractional abundance of C ≡ F differences between natural samples usually occur at and 13F = 13C/(12C + 13C) (2) beyond the third significant figure of the isotope ratio, it has become conventional to express isotopic abundances These variables deserve attention because they provide using a differential notation. To provide a concrete the only basis for perfectly accurate mass balances. example, it is far easier to say – and to remember – that Isotope ratios are also measures of the absolute abun- the isotope ratios of samples A and B differ by one part dance of isotopes; they are usually arranged so that the per thousand than to say that sample A has 0.3663 %15N more abundant isotope appears in the denominator and sample B has 0.3659 %15N. -
Is Earth's Magnetic Field Reversing? ⁎ Catherine Constable A, , Monika Korte B
Earth and Planetary Science Letters 246 (2006) 1–16 www.elsevier.com/locate/epsl Frontiers Is Earth's magnetic field reversing? ⁎ Catherine Constable a, , Monika Korte b a Institute of Geophysics and Planetary Physics, Scripps Institution of Oceanography, University of California at San Diego, La Jolla, CA 92093-0225, USA b GeoForschungsZentrum Potsdam, Telegrafenberg, 14473 Potsdam, Germany Received 7 October 2005; received in revised form 21 March 2006; accepted 23 March 2006 Editor: A.N. Halliday Abstract Earth's dipole field has been diminishing in strength since the first systematic observations of field intensity were made in the mid nineteenth century. This has led to speculation that the geomagnetic field might now be in the early stages of a reversal. In the longer term context of paleomagnetic observations it is found that for the current reversal rate and expected statistical variability in polarity interval length an interval as long as the ongoing 0.78 Myr Brunhes polarity interval is to be expected with a probability of less than 0.15, and the preferred probability estimates range from 0.06 to 0.08. These rather low odds might be used to infer that the next reversal is overdue, but the assessment is limited by the statistical treatment of reversals as point processes. Recent paleofield observations combined with insights derived from field modeling and numerical geodynamo simulations suggest that a reversal is not imminent. The current value of the dipole moment remains high compared with the average throughout the ongoing 0.78 Myr Brunhes polarity interval; the present rate of change in Earth's dipole strength is not anomalous compared with rates of change for the past 7 kyr; furthermore there is evidence that the field has been stronger on average during the Brunhes than for the past 160 Ma, and that high average field values are associated with longer polarity chrons. -
Isotopegeochemistry Chapter4
Isotope Geochemistry W. M. White Chapter 4 GEOCHRONOLOGY III: OTHER DATING METHODS 4.1 COSMOGENIC NUCLIDES 4.1.1 Cosmic Rays in the Atmosphere As the name implies, cosmogenic nuclides are produced by cosmic rays colliding with atoms in the atmosphere and the surface of the solid Earth. Nuclides so created may be stable or radioactive. Radio- active cosmogenic nuclides, like the U decay series nuclides, have half-lives sufficiently short that they would not exist in the Earth if they were not continually produced. Assuming that the production rate is constant through time, then the abundance of a cosmogenic nuclide in a reservoir isolated from cos- mic ray production is simply given by: −λt N = N0e 4.1 Hence if we know N0 and measure N, we can calculate t. Table 4.1 lists the radioactive cosmogenic nu- clides of principal interest. As we shall, cosmic ray interactions can also produce rare stable nuclides, and their abundance can also be used to measure geologic time. A number of different nuclear reactions create cosmogenic nuclides. “Cosmic rays” are high-energy (several GeV up to 1019 eV!) atomic nuclei, mainly of H and He (because these constitute most of the matter in the universe), but nuclei of all the elements have been recognized. To put these kinds of ener- gies in perspective, the previous gen- eration of accelerators for physics ex- Table 4.1. Data on Cosmogenic Nuclides periments, such as the Cornell Elec- -1 tron Storage Ring produce energies in Nuclide Half-life, years Decay constant, yr the 10’s of GeV (1010 eV); while 14C 5730 1.209x 10-4 CERN’s Large Hadron Collider, 3H 12.33 5.62 x 10-2 mankind’s most powerful accelerator, 10Be 1.500 × 106 4.62 x 10-7 located on the Franco-Swiss border 26Al 7.16 × 105 9.68x 10-5 near Geneva produces energies of 36Cl 3.08 × 105 2.25x 10-6 ~10 TeV range (1013 eV). -
Arizona Radiocarbon Dates X
[RADIOCARBON, VOL 23, No. 2, 1981, P 191-217] ARIZONA RADIOCARBON DATES X AUSTIN LONG and A B MULLER* Laboratory of Isotope Geochemistry, Department of Geosciences University of Arizona, Tucson, Arizona 85721 INTRODUCTION Routine radiocarbon analyses were last reported for the Laboratory of Isotope Geochemistry at the University of Arizona in 1971 (Haynes, Grey, and Long, 1971), and a special date list on packrat middens appeared in 1978 (Mead, Thompson, and Long, 1978). This list presents results obtained from our gas proportional counting facility before its major renovation and before the addition of a liquid scintillation counting system. The characteristics of these new systems will be de- scribed in the next date list. The majority of the results presented here are for extramural samples (submitted by researchers not associated with this laboratory) and were analyzed in conjunction with the service aspects of our facility. Results obtained from the radiocarbon analysis of bristlecone pine tree rings, which is the main thrust of our intramural research' on radio- carbon fluctuations in atmospheric CO2 and their relationship to climate, will be presented elsewhere. '4C All the ages reported here are based on the half-life of 5568 years, using 95% of the activity of NBS Oxalic Acid I as the modern value. The activities of samples of terrestrial organic material have been. normalized to account for the difference between the measured 613C and -25% PDB, as recommended by Stuiver and Polach (1977). Errors, based on counting statistics, are expressed as ± lo-; samples counting within'C 20- of background are reported as non-finite. -
The Stability, Electronic Structure, and Optical Property of Tio2 Polymorphs
The stability, electronic structure, and optical property of TiO2 polymorphs Tong Zhu and Shang-Peng Gaoa) Department of Materials Science, Fudan University, Shanghai 200433, P. R. China Phonon density of states calculation shows that a new TiO2 polymorph with tridymite structure is mechanically stable. Enthalpies of 9 TiO2 polymorphs under different pressure are presented to study the relative stability of the TiO2 polymorphs. Band structures for the TiO2 polymorphs are calculated by density functional theory with generalized gradient approximation and the band energies at high symmetry k-points are corrected using the GW method to accurately determine the band gap. The differences between direct band gap energies and indirect band gap energies are very small for rutile, columbite and baddeleyite TiO2, indicating a quasi-direct band gap character. The band gap energies of baddeleyite (quasi-direct) and brookite (direct) TiO2 are close to that of anatase (indirect) TiO2. The band gap of the newly predicted tridymite-structured TiO2 is wider than the other 8 polymorphs. For optical response calculations, two-particle effects have been included by solving the Bethe-Salpeter equation for Coulomb correlated electron-hole pairs. TiO2 with cotunnite, pyrite, and fluorite structures have optical transitions in the visible light region. I. INTRODUCTION 1,2 Even after half a century of research, investigation of the fundamental properties of TiO2 crystal phases remains very important properly due to their important role to effectively utilize solar energy. For instance, 3 4 photocatalytic splitting of water into H2 and O2, photovoltaic generation of electricity, degradation of 5,6 7 environmentally hazard materials, and reduction of CO2 into hydrocarbon fuels. -
Paleomagnetism and U-Pb Geochronology of the Late Cretaceous Chisulryoung Volcanic Formation, Korea
Jeong et al. Earth, Planets and Space (2015) 67:66 DOI 10.1186/s40623-015-0242-y FULL PAPER Open Access Paleomagnetism and U-Pb geochronology of the late Cretaceous Chisulryoung Volcanic Formation, Korea: tectonic evolution of the Korean Peninsula Doohee Jeong1, Yongjae Yu1*, Seong-Jae Doh2, Dongwoo Suk3 and Jeongmin Kim4 Abstract Late Cretaceous Chisulryoung Volcanic Formation (CVF) in southeastern Korea contains four ash-flow ignimbrite units (A1, A2, A3, and A4) and three intervening volcano-sedimentary layers (S1, S2, and S3). Reliable U-Pb ages obtained for zircons from the base and top of the CVF were 72.8 ± 1.7 Ma and 67.7 ± 2.1 Ma, respectively. Paleomagnetic analysis on pyroclastic units yielded mean magnetic directions and virtual geomagnetic poles (VGPs) as D/I = 19.1°/49.2° (α95 =4.2°,k = 76.5) and VGP = 73.1°N/232.1°E (A95 =3.7°,N =3)forA1,D/I = 24.9°/52.9° (α95 =5.9°,k =61.7)and VGP = 69.4°N/217.3°E (A95 =5.6°,N=11) for A3, and D/I = 10.9°/50.1° (α95 =5.6°,k = 38.6) and VGP = 79.8°N/ 242.4°E (A95 =5.0°,N = 18) for A4. Our best estimates of the paleopoles for A1, A3, and A4 are in remarkable agreement with the reference apparent polar wander path of China in late Cretaceous to early Paleogene, confirming that Korea has been rigidly attached to China (by implication to Eurasia) at least since the Cretaceous. The compiled paleomagnetic data of the Korean Peninsula suggest that the mode of clockwise rotations weakened since the mid-Jurassic. -
U-Pb (And U-Th) Dating of Micro-Baddeleyite
UU--PbPb (and(and UU--ThTh)) datingdating ofof micromicro--baddeleyitebaddeleyite 30 μm Axel K. Schmitt UCLA SIMS, NSF National Ion Microprobe Facility Collaborators:Collaborators: T.T. MaMarkrk HarrisonHarrison (UCLA)(UCLA) KevinKevin ChamberlainChamberlain (University(University ofof Wyoming)Wyoming) BaddeleyiteBaddeleyite (BAD(BAD--üü--LLĒĒ--iteite)*)* basicsbasics • chemical formula: ZrO2 • monoclinic (commonly twinned) • minor HfO2, TiO2, FeO, SiO2 • U between ~200 – 1000 ppm • low common Pb, Th/U <<0.2 • wide range of occurrences (terrestrial and extraterrestrial) • mafic and ultramafic rocks (basalt, gabbro, diabase) • alkali rocks (carbonatite, syenite) • mantle xenoliths (from kimberlites) • metacarbonates • impact-related rocks (tektites) Wingate and Compston, 2000 *National*National LibraryLibrary ServiceService forfor thethe BlindBlind andand PhysicallyPhysically HandicappeHandicappedd (NLS),(NLS), LibraryLibrary ofof CongressCongress BaddeleyiteBaddeleyite dating:dating: applicationsapplications andand examplesexamples BulkBulk analysisanalysis (TIMS)(TIMS) • Mafic dikes and layered intrusions (e.g., Heaman et al., 1992) • Detrital baddeleyite (e.g., Bodet and Schärer, 2000) InIn--situsitu methodsmethods (SIMS,(SIMS, LALA ICPICP MS,MS, EPMA)EPMA) • Mafic dikes and gabbros (e.g., Wingate et al., 1998; French et al., 2000) • SNC meteorites (Herd et al., 2007: 70±35 Ma and 171±35 Ma) MicroMicro--baddeleyitebaddeleyite analysis:analysis: inin--situsitu advantagesadvantages • Bulk analysis difficulties: • time-intensive, highly -
Constraints on the Formation of the Archean Siilinjärvi Carbonatite-Glimmerite Complex, Fennoscandian Shield
Constraints on the formation of the Archean Siilinjärvi carbonatite-glimmerite complex, Fennoscandian shield E. Heilimo1*, H. O’Brien2 and P. Heino3 1 Geological Survey of Finland, P.O. Box 1237, FI-70211, Kuopio, Finland (*correspondance: [email protected]) 2 Geological Survey of Finland, P.O. Box 96, FI-02151, Espoo, Finland. 3 Yara Suomi Oy, Siilinjärvi mine, P.O. Box FI-71801 Siilinjärvi, Finland. Abstract The Siilinjärvi carbonatite-glimmerite complex is the The main glimmerite-carbonatite intrusion within the Table 1 Siilinjärvi ore zone rocks, modal mineralogy, Genesis oldest carbonatite deposit currently mined for phos- Siilinjärvi complex occurs as a central tabular, up to 900 and calculated major element chemistry. The Siilinjärvi glimmerite-carbonatite complex prob- Ore1 Glimmerite Carbonatite apatite Carbonatite Lamprophyre phorous, and one of the oldest known on Earth at 2610 m wide, body of glimmerite and carbonatite running the containing apatite poor dike3 ably represents a plutonic complex formed as the result ± 4 Ma. The carbonatite-glimmerite is a 900 m wide length of the complex, surrounded by a fenite margin. Micas2 65 81.5 1.2 of passage of highly potassic magmas into and through Amphibole 5 4.5 0.6 0.2 and 14.5 km long tabular body of glimmerite with sub- Unlike many other carbonatite-bearing complexes that Calcite 15 1.6 61.2 86.8 a magma chamber, and the consequent accumulation ordinate carbonatite, surroundeed by fenites. The rocks contain a sequence of phlogopite-rich rocks intruded by Dolomite 4 0.9 13.4 10.6 of crystallizing minerals, a process that was active over Apatite 10 10.4 9.9 0.8 range from nearly pure glimmerite (tetraferriphlogo- a core of carbonatite (c.f., Kovdor, Phalaborwa), at Siil- Accessorices 1 0.7 0.1 0.4 the lifetime of the magma chamber. -
Oxygen Isotope Geochemistry of Laurentide Ice-Sheet Meltwater Across Termination I
Quaternary Science Reviews 178 (2017) 102e117 Contents lists available at ScienceDirect Quaternary Science Reviews journal homepage: www.elsevier.com/locate/quascirev Oxygen isotope geochemistry of Laurentide ice-sheet meltwater across Termination I * Lael Vetter a, , Howard J. Spero a, Stephen M. Eggins b, Carlie Williams c, Benjamin P. Flower c a Department of Earth and Planetary Sciences, University of California Davis, Davis, CA 95616, USA b Research School of Earth Sciences, The Australian National University, Canberra 0200, ACT, Australia c College of Marine Sciences, University of South Florida, St. Petersburg, FL 33701, USA article info abstract Article history: We present a new method that quantifies the oxygen isotope geochemistry of Laurentide ice-sheet (LIS) Received 3 April 2017 meltwater across the last deglaciation, and reconstruct decadal-scale variations in the d18O of LIS Received in revised form meltwater entering the Gulf of Mexico between ~18 and 11 ka. We employ a technique that combines 1 October 2017 laser ablation ICP-MS (LA-ICP-MS) and oxygen isotope analyses on individual shells of the planktic Accepted 4 October 2017 18 foraminifer Orbulina universa to quantify the instantaneous d Owater value of Mississippi River outflow, which was dominated by meltwater from the LIS. For each individual O. universa shell, we measure Mg/ Ca (a proxy for temperature) and Ba/Ca (a proxy for salinity) with LA-ICP-MS, and then analyze the same 18 18 O. universa for d O using the remaining material from the shell. From these proxies, we obtain d Owater and salinity estimates for each individual foraminifer. Regressions through data obtained from discrete 18 18 core intervals yield d Ow vs. -
Radiogenic Isotope Geochemistry
W. M. White Geochemistry Chapter 8: Radiogenic Isotope Geochemistry CHAPTER 8: RADIOGENIC ISOTOPE GEOCHEMISTRY 8.1 INTRODUCTION adiogenic isotope geochemistry had an enormous influence on geologic thinking in the twentieth century. The story begins, however, in the late nineteenth century. At that time Lord Kelvin (born William Thomson, and who profoundly influenced the development of physics and ther- R th modynamics in the 19 century), estimated the age of the solar system to be about 100 million years, based on the assumption that the Sun’s energy was derived from gravitational collapse. In 1897 he re- vised this estimate downward to the range of 20 to 40 million years. A year earlier, another Eng- lishman, John Jolly, estimated the age of the Earth to be about 100 million years based on the assump- tion that salts in the ocean had built up through geologic time at a rate proportional their delivery by rivers. Geologists were particularly skeptical of Kelvin’s revised estimate, feeling the Earth must be older than this, but had no quantitative means of supporting their arguments. They did not realize it, but the key to the ultimate solution of the dilemma, radioactivity, had been discovered about the same time (1896) by Frenchman Henri Becquerel. Only eleven years elapsed before Bertram Boltwood, an American chemist, published the first ‘radiometric age’. He determined the lead concentrations in three samples of pitchblende, a uranium ore, and concluded they ranged in age from 410 to 535 million years. In the meantime, Jolly also had been busy exploring the uses of radioactivity in geology and published what we might call the first book on isotope geochemistry in 1908. -
Equivalence of Current–Carrying Coils and Magnets; Magnetic Dipoles; - Law of Attraction and Repulsion, Definition of the Ampere
GEOPHYSICS (08/430/0012) THE EARTH'S MAGNETIC FIELD OUTLINE Magnetism Magnetic forces: - equivalence of current–carrying coils and magnets; magnetic dipoles; - law of attraction and repulsion, definition of the ampere. Magnetic fields: - magnetic fields from electrical currents and magnets; magnetic induction B and lines of magnetic induction. The geomagnetic field The magnetic elements: (N, E, V) vector components; declination (azimuth) and inclination (dip). The external field: diurnal variations, ionospheric currents, magnetic storms, sunspot activity. The internal field: the dipole and non–dipole fields, secular variations, the geocentric axial dipole hypothesis, geomagnetic reversals, seabed magnetic anomalies, The dynamo model Reasons against an origin in the crust or mantle and reasons suggesting an origin in the fluid outer core. Magnetohydrodynamic dynamo models: motion and eddy currents in the fluid core, mechanical analogues. Background reading: Fowler §3.1 & 7.9.2, Lowrie §5.2 & 5.4 GEOPHYSICS (08/430/0012) MAGNETIC FORCES Magnetic forces are forces associated with the motion of electric charges, either as electric currents in conductors or, in the case of magnetic materials, as the orbital and spin motions of electrons in atoms. Although the concept of a magnetic pole is sometimes useful, it is diácult to relate precisely to observation; for example, all attempts to find a magnetic monopole have failed, and the model of permanent magnets as magnetic dipoles with north and south poles is not particularly accurate. Consequently moving charges are normally regarded as fundamental in magnetism. Basic observations 1. Permanent magnets A magnet attracts iron and steel, the attraction being most marked close to its ends.