The Multiplicity of Industrial R&D That Produced High-Strength Aramid Fibers
Total Page:16
File Type:pdf, Size:1020Kb
Load more
Recommended publications
-
BLUE HEN CHEMIST University of Delaware, Department of Chemistry and Biochemistry Annual Alumni Newsletter Number 41 August 2014 John L
BLUE HEN CHEMIST University of Delaware, Department of Chemistry and Biochemistry Annual Alumni Newsletter NUMBER 41 AUGUST 2014 JOHN L. BURMEISTER, EDITOR ON THE COVER THREE Newly Renovated Organic Laboratories! # 3 8 - P AGE I BLU E H E N C H E MIST ON THE COVER One of the three newly-renovated Organic Chemistry teaching laboratories (QDH 302) is shown. Work on the labs (QDH 112, 318, 320) started on May, 2013 and was completed in February of this year. The refurbishment of the labs was a crucial step in the ongoing revision of the Organic Chemistry laboratory curricula. The additional fume hoods allow each student to conduct experiments individually while minimizing their exposure to chemical reagents. The transparent glass construction helps teaching assistants observe students while they work. The hoods are equipped with inert-gas lines, which can allow the students to work with air-sensitive compounds and learn advanced laboratory techniques. The hoods are also equipped with vacuum lines, which obviate the need for water aspirators and dramatically reduce the labs' water usage. The lab design also allows for instrumentation modules to be swapped in and out according to the needs of the experiment. Carts are designed to house instruments such as gas chromatographs and infrared spectrometers as well as any necessary computer equipment. These carts can then be wheeled into docking areas that have been fitted with the necessary inert gas and electrical lines. The design expands the range of possible instrumentation the students can use while occupying a small footprint of lab space. The labs also feature large flat screen monitors, wireless internet, and computer connectivitiy that will enable the use of multimedia demonstrations and tablet computing. -
Eugene Du Pont Jr. Papers 2656
Eugene du Pont Jr. papers 2656 This finding aid was produced using ArchivesSpace on September 14, 2021. Description is written in: English. Describing Archives: A Content Standard Manuscripts and Archives PO Box 3630 Wilmington, Delaware 19807 [email protected] URL: http://www.hagley.org/library Eugene du Pont Jr. papers 2656 Table of Contents Summary Information .................................................................................................................................... 3 Biographical .................................................................................................................................................... 3 Scope and Content ......................................................................................................................................... 4 Arrangement ................................................................................................................................................... 4 Administrative Information ............................................................................................................................ 4 Related Materials ........................................................................................................................................... 5 Controlled Access Headings .......................................................................................................................... 5 Collection Inventory ...................................................................................................................................... -
Exploring the Influence of Entropy on Dynamic Macromolecular Ligation
Exploring the Influence of Entropy on Dynamic Macromolecular Ligation Zur Erlangung des akademischen Grades eines DOKTORS DER NATURWISSENSCHAFTEN (Dr. rer. nat.) der KIT-Fakultät für Chemie und Biowissenschaften des Karlsruher Instituts für Technologie (KIT) genehmigte DISSERTATION von Dipl.-Chem. Kai Pahnke aus Nagold, Deutschland KIT-Dekan: Prof. Dr. Willem M. Klopper Referent: Prof. Dr. Christopher Barner-Kowollik Korreferent: Prof. Dr. Manfred Wilhelm Tag der mündlichen Prüfung: 22.07.2016 Die vorliegende Arbeite wurde im Zeitraum von Februar 2013 bis Juni 2016 im Rahmen einer Kollaboration zwischen dem KIT und der Evonik Industries AG unter der Betreuung von Prof. Dr. Christopher Barner-Kowollik durchgeführt Only entropy comes easy. Anton Chekhov ABSTRACT The present thesis reports a novel, expedient linker species as well as previously unforeseen effects of physical molecular parameters on reaction entropy and thus equilibria with extensive implications on diverse fields of research via the study of dynamic ligation chemistries, especially in the realm of macromolecular chemistry. A set of experiments investigating the influence of different physical molecular parameters on reaction or association equilibria is designed. Initially, previous findings of a mass dependant effect on the reaction entropy – resulting in a more pronounced debonding of heavier or longer species – are reproduced and expanded to other dynamic ligation techniques as well as further characterization methods, now including a rapid and catalyst- free Diels–Alder reaction. The effects are evidenced via high temperature nuclear magnetic resonance spectroscopy (HT NMR) as well as temperature dependent size exclusion chromatography (TD SEC) and verified via quantum chemical ab initio calculations. Next, the impact of chain mobility on entropic reaction parameters and thus the overall bonding behavior is explored via the thermoreversible ligation of chains of similar mass and length, comprising isomeric butyl side-chain substituents with differing steric demands. -
Pierre Samuel Du Pont De Nemours from the Executive Director
Summer 2017 - Vol. 46 No. 2 SAVE THE DATE Fireworks at Hagley June 16 & 23 Bike & Hike Wednesday Evenings June 7 through September 13 HagleyMAGAZINE Summer Camps 2016 ANNUAL REPORT July 10-14, July 31-August 4 Pierre Samuel du Pont de Nemours From The Executive Director Several months ago, I received a phone education system in Virginia. And speaking Executive Director David Cole call from a professor on the Faculty of Law of Jefferson, let’s not forget the crucial role at the University of Paris. He was calling to that du Pont de Nemours played as a behind- inform me that his university is planning a the-scenes broker of the Louisiana Purchase. Cover: Portrait of Pierre Samuel 2017 academic conference in commemoration Across oceans, political divides, and academic du Pont de Nemours on display in of the 200th anniversary of the death of disciplines, this gifted thinker was a true the Morning Room of Eleutherian duPont family patriarch, Pierre Samuel innovator—always eager to experiment in the Mills. The portrait was painted by du Pont de Nemours. This conference, he service of better living. Joseph Ducreux, court painter for Marie Antoinette, in Paris circa 1876. explained, will draw scholars from across the globe Back: Visitors enjoy biking on the and will invite a critical property during Bike & Hike on Across oceans, political summer Wednesday evenings. reappraisal of the intellectual contributions and legacy of divides, and academic this extraordinary figure of the French enlightenment. disciplines, this gifted I was delighted to have thinker was a true innovator. this news, as I have felt for some time that du Pont de Nemours’s life and career as Board of Trustees a philosopher, educator, political figure, and In 2017, Hagley will join the University of Henry B. -
Polymers: a Historical Perspective
Journal & Proceedings of the Royal Society of New South Wales, vol. 152, part 2, 2019, pp. 242–250. ISSN 0035-9173/19/020242-09 Polymers: a historical perspective Robert Burford, FRSN Emeritus Professor, School of Chemical Engineering, UNSW Sydney Email: [email protected] Abstract This commissioned paper outlines the emergence of new forms of synthetics and plastics as our under- standing of polymer chemistry has advanced. Synopsis phenols and styrene are “polymerised” to olymers have been ubiquitous since form thermosets,1 including phenol for- simple gaseous molecules began to form maldehyde “Bakelite” thermosets, but are P 2 life-giving organic structures many millions also present in thermoplastics including of years ago. Today, we rely upon proteins polystyrene and related materials such as comprising twenty amino acids, as well as styrene acrylonitrile (SAN) and ABS.3 The DNA and RNA with many fewer nucleic manufacture of Bakelite is often viewed as acids. Similarly, many fibres and plants the birth of the synthetic polymer industry. comprise carbohydrate polymers: we and The enormous growth both in diversity and other animals use these and protein-based volume of thermoplastics is a feature of the polymers for our diet. Hence, organic earth’s 20th century, dismissively called the “plastics surface has an enormous diversity of natu- age.” Again, important but sometimes ser- rally occurring polymers, sometimes called endipitous discoveries are a feature of this macromolecules. period, but the associated large-scale produc- Today, these continue to feed and clothe tion introduced multinational corporations us, and much more, but the beginning of originating mainly in Europe, the US and man-made materials might be considered Japan. -
Syn Thetic Slings 87
87 Synthetic Slings Synthetic Synthetic Slings Synthetic lifting slings are slings made with materials—yarns, webbing, rope, etc.—that are woven from synthetic or man-made fibers. Background Carbon steel was the dominant raw material used in rigging slings throughout the 19th and most of the 20th centuries. However, slings fabricated from synthetic fibers steadily gained popularity through the later half of the 20th century. Since the turn of the century, many industries and applications—such as aircraft construction and maintenance, aerospace, power generation, etc.— have moved entirely to the use of lightweight, high- strength synthetic slings, fabricated with the latest generation of synthetic fibers. Modern synthetic lifting slings have their origins in the development of the first true synthetic fiber in 1935 by Wallace Carothers of DuPont. DuPont marketers christened this fiber nylon, a made-up name derived from the “on” suffix of cotton and the arbitrary letters “nyl” that simply “sounded good” together. Nylon is a thermoplastic polymer made of repeating molecular units linked by amide bonds, and is often referred to as polyamide. It was the first commercially successful synthetic polymer. In the rigging industry, nylon has found wide use as the fiber of choice for inexpensive, light weight lifting slings fabricated from flat nylon webbing. Numerous other synthetic fibers have been developed since nylon was introduced, and many of these fibers—most notably polyesters—are woven or spun into materials used to fabricate a wide range of synthetic rigging types. Experience with nylon and polyester processing and manufacturing led to the development of aromatic © 2015 Yarbrough Cable Service, LLC Pride. -
Foxcatcher Directed by Bennett Miller
Sony Pictures Classics Presents An Annapurna Pictures Production Foxcatcher Directed by Bennett Miller Cannes Film Festival 2014 Telluride Film Festival 2014 Toronto International Film Festival 2014 New York Film Festival 2014 Winner - Best Director, Cannes Film Festival 2014 134 mins | Rated R | Opens 11/14/14 (NY/LA) East Coast Publicity West Coast Publicity Distributor 42West Block Korenbrot Sony Pictures Classics Scott Feinstein Max Buschman Carmelo Pirrone 220 West 42nd Street Blair Bender Maya Anand 12th floor 6100 Wilshire Blvd., 550 Madison Ave New York, NY 10036 Ste. 170 New York, NY 10022 212-277-7555 Los Angeles, CA 90048 212-833-8833 tel 323-634-7001 tel 212-833-8844 fax 323-634-7030 fax FOXCATCHER The Cast John du Pont STEVE CARELL Mark Schultz CHANNING TATUM Dave Schultz MARK RUFFALO Jean du Pont VANESSA REDGRAVE Nancy Schultz SIENNA MILLER Jack ANTHONY MICHAEL HALL Henry Beck GUY BOYD Documentary Filmmaker DAVE “DOC” BENNETT The Filmmakers Director BENNETT MILLER Written by E. MAX FRYE DAN FUTTERMAN Producers MEGAN ELLISON BENNETT MILLER JON KILIK ANTHONY BREGMAN Executive Producers CHELSEA BARNARD RON SCHMIDT MARK BAKSHI MICHAEL COLEMAN TOM HELLER JOHN P. GUIRA Co-Producer SCOTT ROBERTSON Director of Photography GREIG FRASER Production Designer JESS GONCHOR Editor STUART LEVY CONOR O’NEILL JAY CASSIDY Costume Designer KASIA MAIMONE WALICKA Music ROB SIMONSEN Additional Music WEST DYLAN THORDSON Valley Forge Theme MYCHAEL DANNA Casting Director JEANNE McCARTHY Makeup Designer BILL CORSO Hair Department Head KATHRINE GORDON Wrestling Coordinator JOHN GUIRA Wrestling Choreographer JESSE JANTZEN 2 FOXCATCHER Synopsis Based on true events, FOXCATCHER tells the dark and fascinating story of the unlikely and ultimately tragic relationship between an eccentric multi-millionaire and two champion wrestlers. -
THE HISTORY of POLYMERS : the ORIGINS and the GROWTH of a SCIENCE Part II
THE HISTORY OF POLYMERS : THE ORIGINS AND THE GROWTH OF A SCIENCE Part II Dr. S. Sivaram, National Chemical Laboratory, Pune-411 008, INDIA National Chemical Laboratory Tel : 0091 20 2589 2614 Pune Fax : 0091 20 2589 2615 Email : [email protected] Visit us at : http://www.ncl-india.org February 18, 2012 WALLACE CAROTHERS AND THE BIRTH OF RATIONAL POLYMER SYNTHESIS With Julian Hill, extends the reaction to adipic acid and hexamethylene diamine, a polyamide forming reaction , leading to the first synthesis of Nylon-66 in 1934. Nylon-66 goes into production in 1939 Develops a theoretical understanding of the polycondensation reaction relating the average degree of polymerization to fractional conversions ( Carother`s Equation) Carothers had been troubled by periods of mental depression since his youth. Despite his success with nylon, he felt that he had not accomplished much and had run out of ideas ?? His unhappiness was compounded by the death of his sister, Isobel, and on the evening of April 28, 1937 he checked into a Philadelphia hotel room and committed suicide by drinking A young man joins a cocktail of lemon juice laced with potassium cyanide Carothers at DuPont in 1934 who will go on to make history His daughter, Jane, was born seven months later on November 27, 1937. SUMMARY OF LECTURE : PART I • The tale of two Hermanns : Staudinger and Mark • The link between Mark and Pauling: the “Nature of the Chemical Bond” and the origins of the structural chemistry • Wallace Carothers and the birth of rational polymer synthesis: realization that large macromolecules can be derived using the same laws of chemistry that define small molecules • Paul Flory and the dawn of the physical chemistry of polymers Polymers were considered largely an empirical, instinctive and intuitive discipline till the mid twenties. -
Wallace Hume Carothers Letters to Frances Gelvin Spencer 2435
Wallace Hume Carothers letters to Frances Gelvin Spencer 2435 This finding aid was produced using ArchivesSpace on September 26, 2021. Description is written in: English. Describing Archives: A Content Standard Manuscripts and Archives PO Box 3630 Wilmington, Delaware 19807 [email protected] URL: http://www.hagley.org/library Wallace Hume Carothers letters to Frances Gelvin Spencer 2435 Table of Contents Summary Information .................................................................................................................................... 3 Biographical Note .......................................................................................................................................... 3 Scope and Contents ........................................................................................................................................ 4 Administrative Information ............................................................................................................................ 4 Related Materials ........................................................................................................................................... 5 Controlled Access Headings .......................................................................................................................... 5 - Page 2 - Wallace Hume Carothers letters to Frances Gelvin Spencer 2435 Summary Information Repository: Manuscripts and Archives Creator - crp: Carothers, Wallace Hume, 1896-1937 Creator - rcp: Spencer, Frances -
D-49 Horn Point, (Dupont Dairy Barn)
D-49 Horn Point, (duPont Dairy Barn) Architectural Survey File This is the architectural survey file for this MIHP record. The survey file is organized reverse- chronological (that is, with the latest material on top). It contains all MIHP inventory forms, National Register nomination forms, determinations of eligibility (DOE) forms, and accompanying documentation such as photographs and maps. Users should be aware that additional undigitized material about this property may be found in on-site architectural reports, copies of HABS/HAER or other documentation, drawings, and the “vertical files” at the MHT Library in Crownsville. The vertical files may include newspaper clippings, field notes, draft versions of forms and architectural reports, photographs, maps, and drawings. Researchers who need a thorough understanding of this property should plan to visit the MHT Library as part of their research project; look at the MHT web site (mht.maryland.gov) for details about how to make an appointment. All material is property of the Maryland Historical Trust. Last Updated: 01-31-2013 MARYLAND HISTORICAL TRUST DETERMINATION OF ELIGIBILITY FORM D-49 operty Name: Horn Point Dairy Bam Complex Inventory Number: Horns Address: 2020 HemsPoint Road Historic district: yes no City: Cambridge Zip Code: County: Dorchester USGS Quadrangle(s): Church Creek Property Owner: State of Maryland Tax Account ID Number: 1007174969 Tax Map Parcel Number(s): 9 Tax Map Number: 29 Project: DOE Agency: UMD Agency Prepared By: Stephen G. Del Sordo, HRG, Inc. Preparer's -
Du Pont Family.Qxp
fWinterthur Library An Introduction to Resources ef The du Pont Family The Winterthur Archives Winterthur house and museum. Bills, correspon- The Archives hold the personal and business dence, and other documents from architects papers of Henry Francis du Pont and his immediate Thomas Waterman, Albert Ely Ives, and the firm family. The focus of the papers is the development of Perot and Bissell show the evolution from a of the Winterthur estate and the creation and family home to a museum. development of Winterthur Museum. The approx- imate date range of material in the Archives is Between 1928 and the late 1950s, H. F. du Pont 1860 to 1980. purchased entire rooms of woodwork from early American houses and had spaces at Winterthur Personal Papers redesigned to incorporate them. He then filled the The personal papers of H. F. du Pont; his wife, rooms with furnishings of a similar place and Ruth Wales du Pont; his father, Colonel Henry A. time, changing the furniture and arrangement as du Pont; and other members of the immediate more appropriate objects became available. A family detail their lives on the Winterthur estate. series of room designs and plans as well as the Included are social and business correspondence documents concerning the purchase and installation and financial material concerning the management of the interior architecture, are available in the of the estate. One group of letters between du Pont Archives. A group of stereographic views from the and Jacqueline Kennedy relates to his chairmanship 1930s display the rooms with changing seasonal of the White House Fine Arts Commission in the decoration. -
Interview with Harry B. Gray
HARRY B. GRAY (b. 1935) INTERVIEWED BY SHIRLEY K. COHEN SEPTEMBER 2000 – MARCH 2001 AND HEIDI ASPATURIAN JANUARY – MAY 2016 Photo taken in 1997 ARCHIVES CALIFORNIA INSTITUTE OF TECHNOLOGY Pasadena, California Subject area Chemistry Abstract Two interviews in seven and six sessions respectively, with Harry Gray, the Arnold O. Beckman Professor of Chemistry. The first series of interviews, conducted in 2000-01 with Shirley Cohen, deals with Gray’s life and career up to that time. The second series, conducted in 2016 with Heidi Aspaturian, covers the period 2001–2016, expands on a number of topics discussed in the first interview series, and adds to the account of Gray’s earlier decades. Discussion topics common to the two interviews are cross-referenced in both texts. 2000–01 Interview Gray opens this interview series with a description of his family roots and formative years in Kentucky’s tobacco-farming country, including his youthful career with the local newspaper and early interest in chemistry. He then provides an account of his undergraduate studies at Western Kentucky State College (BS 1957), graduate work with F. Basolo and R. Pearson at Northwestern University http://resolver.caltech.edu/CaltechOH:OH_Gray_H (PhD 1960), and postdoctoral work with C. Ballhausen at the University of Copenhagen, where he pioneered the development of ligand field theory. As a professor at Columbia University, he continued work at the frontiers of inorganic chemistry, published several books and, through an affiliation with Rockefeller University, was drawn to interdisciplinary research, which led him to accept a faculty position at Caltech in 1966. He talks about his approach to teaching and his research in inorganic chemistry and electron transfer at Caltech, his interactions with numerous Caltech personalities, including A.