DOCSLIB.ORG

N-Butanol 2-Ethylhexanol

Total Page：16

File Type：pdf, Size：1020Kb

Download full-text PDF Read full-text
N-Butanol 2-Ethylhexanol years years Oxoviflex® Oxoplast Medica® Trade name: Oxoplast Medica® Trade name: Chemical name: Oxoviflex® bis(2-ethylhexyl) phthalate Chemical name: Bis(2-ethylhexyl) terephthalate CAS: 117-81-7 Status REACH: DPHP CAS: 6422-86-2 registered 20/09/2010 Status REACH: DEHT registered 06/09/2012 Oxoplast Medica® is our response to medical grade PVC processing where highest quality and extra safety is required especially for blood bags manufacturing. Oxoplast Medica® fulfils PLASTICIZERS strict safety standards of European pharmacopeia and is certifi ed for its quality.Oxoplast PLASTICIZERS Medica® do not apply to registration according to EC regulation No. 1907/2006 because of its special application fi eld. Oxoviflex® is our response to growing interest in Specification Value Test method non-phthalate plasticizers. Oxoviflex® formulation is based on our 2-EH OXO alcohol and PTA which is also used Oxoplast Medica® It has been positively tested in PET bottles manufacturing. Colour, Pt-Co scale max. 20 [°Hz] DIN ISO 6271 is our response to for usage in food packaging medical grade PVC and child toys according to Oxoviflex® is completely safe in terms of CLP classifi cation and in most cases it can Flash point min. 206 [°C] ISO 2592 processing European regulation. substitute phthalate plasticizers. Oxoviflex® is REACH registered according to EC regulation Internal method No. 1907/2006. Volatile matter content (150°C/2 h) max. 0.4 [wt %] of Grupa Azoty ZAK S.A. Di(2-ethylhexyl) phthalate content min. 99.5 [wt %] GC min. 0.983 [g/cm3] IDENTIFIED USE: Specification Value Test method Density at 20°C ISO 12185 IDENTIFIED USE: max. 0.986 [g/cm3] Colour, Pt-Co scale <20max. [°Hz] 20 [°Hz]ISO DIN 6271ISO 6271 Paints & Lacquers Free acids as phthalic acid max. 0.010 [wt %] ISO 1385/IV Paints & Lacquers Wires & Cables Flash point ≥230min. 230[°C] [°C]ISO 2592 Water content max. 0.10 [wt %] ISO 760 Wires & Cables ZAK’sInternal internal method of Plastic (PVC) additives Volatile matter content (150∞C/2 h) <0.20 [% m/m] Metals content Plastic (PVC) additives Volatile matter content (150°C/2 h) max. 0.20 [wt %] methodGrupa Azoty ZAK Cd max. 0.1 [ppm] S.A. (GC) Sn max. 1.0 [ppm] No equivalent Chemical Synthesis Bis(2-ethylhexyl) terephthalate ≥98.0 [% m/m] GC Chemical Synthesis Zn max. 10 [ppm] ICP-OES Bis(2-ethylhexyl) terephthalate min. 98.0 [wt %] GC Automotive ≥0.980 [g/cm3] Areometric Ba max. 1.0 [ppm] Automotive Density at 20°C <0.985min. 0.980 [g/cm [g/cm3] 3] method Ca max. 10 [ppm] Density at 20°C ISO 12185 Pharmaceutics max. 0.985 [g/cm3] Pharmaceutics & Cosmetics Free acids as phthalic acid <0.01 [% m/m] ISO 1385/IV Absorbance (260 nm; water extract) max. 0.3 No equivalent & Cosmetics Free acids as phthalic acid max. 0.01 [wt %] ISO 1385/IV According to Technical Gases Water content <0.1 [% m/m] ISO 760 Reducing substances (water extract; Technical Gases max. 20 [ml] Ph. Eur. 8th Water content max. 0.1 [wt %] ISO 760 KMnO4) Textiles Edition Te x ti les Other Other www.oxoplast.com/en/plasticizers/oxovifl ex/ www.oxoplast.com/en/plasticizers/oxoplast-medica/ Oxoplast® O Oxoplast® PH Trade name: Trade name: Oxoplast®O Oxoplast® PH Chemical name: Chemical name: Bis(2-ethylhexyl) phthalate bis(2-propylheptyl) phthalate CAS: 117-81-7 CAS: 53306-54-0 REACH Status: DEHP REACH Status: DEHP registered 20/09/2010 registered 23/11/2010 PLASTICIZERS PLASTICIZERS Oxoplast® O has the longest For our European customers we have initiated REACH authorisation process due to safety Oxoplast® PH unique feature is low volatility thus it is highly recommended for high Oxoplast® PH is a high production history within concerns risen by European regulation authorities. We aim at providing our customers with temperature applications such as automotive (cables, car interior trims). molecular weight plasticizer our plasticizers portfolio. full legal safety towards employing Oxoplast® O in their PVC processing and fi nal products. (C10) used in PVC processing. Oxoplast® PH is also resistant to ambient conditions and suitable for roofi ng and exterior coatings. Oxoplast® PH is REACH registered according to EC regulation No. 1907/2006. IDENTIFIED USE: Specification Value Test method Specification Value Test method IDENTIFIED USE: Paints & Lacquers Colour, Pt-Co scale max. 30 [°Hz] DIN ISO 6271 Colour, Pt-Co scale max. 30 [°Hz] DIN ISO 6271 Paints & Lacquers Wires & Cables Flash point min. 206 [°C] ISO 2592 Flash point min. 220 [°C] ISO 2592 Wires & Cables Internal method Internal method Plastic (PVC) additives Plastic (PVC) additives Volatile matter content (150°C/2 h) max. 0.4 [wt %] of Grupa Azoty Volatile matter content (150°C/2 h) max. 0.4 [wt %] of Grupa Azoty ZAK S.A. ZAK S.A. Chemical Synthesis Chemical Synthesis Esters as di(2-ethylhexyl) phthalate min. 99.5 [wt %] ISO 1385/V Esters as bis(2-propylheptyl) phthalate min. 99.5 [wt %] ISO 1385/V Automotive Automotive Di(2-ethylhexyl) phthalate content min. 99.5 [wt %] GC min. 0.960 [g/cm3] Density at 20°C ISO 12185 Pharmaceutics max. 0.965 [g/cm3] Pharmaceutics & Cosmetics min. 0.983 [g/cm3] & Cosmetics Density at 20°C ISO 12185 max. 0.986 [g/cm3] Free acids as phthalic acid max. 0.01 [wt %] ISO 1385/IV Technical Gases Te chnic al G ases Free acids as phthalic acid max. 0.010 [wt %] ISO 1385/IV Water content max. 0.1 [wt %] ISO 760 Textiles Text i les Water content max. 0.10 [wt %] ISO 760 Other Other www.oxoplast.com/en/plasticizers/oxoplast-o/ www.oxoplast.com/en/plasticizers/oxoplast-ph/ 2-Ethylhexanol n-Butanol Trade name: Trade name: 2-Ethylhexanol n-Butanol Chemical name: Chemical name: 2-Ethylhexan-1-ol Butan-1-ol, n-Butanol CAS: 104-76-7 CAS: 71-36-3 REACH Status: 2-Ethylhexanol REACH Status: n-Butanol registered 28/09/2010 registered 02/11/2010 OXO ALCOHOLS OXO ALCOHOLS 2-Ethylhexanol (2-EH) It is produced according to strict process regime derived from our experience. We put an It is manufactured according to highest quality standards which guarantees our customers n-Butanol is our second is our main OXO alcohol. extra emphasis on its quality which is transferred to further processed products: plasticizers, that all requirements concerning its further processing to acrylates, acetates and solvents and most important OXO acrylates, fuel additives (2-EHN) and other chemical products. other chemical substances are met. alcohol. 2-EH is REACH registered according to EC regulation No. 1907/2006 N-butanol is REACH registered according to EC regulation No. 1907/2006 IDENTIFIED USE: Specification Value Test method Specification Value Test method IDENTIFIED USE: Paints & Lacquers 2-Ethylhexanol min. 99.7 [wt %] GC n-Butanol min. 99.8 [wt %] GC Paints & Lacquers Wires & Cables Colour, Pt-Co scale max. 5 [APHA] ISO 6271 Colour, Pt-Co scale max. 5 [APHA] ISO 6271 Wires & Cables min. 0.832 [g/cm3] min. 0.810 [g/cm3] Plastic (PVC) additives Density at 20°C ISO 12185 Density at 20°C1 ISO 12185 Plastic (PVC) additives max. 0.834 [g/cm3] max. 0.812 [g/cm3] Chemical Synthesis Acids as acetic acid max. 0.01 [wt %] ASTM D 1613 Acids as acetic acid1 max. 0.005[wt %] ASTM D 1613 Chemical Synthesis Automotive Aldehydes as 2-ethylhexanal max. 0.05 [wt %] BS 4583 Aldehydes as butanal1 max. 0.05 [wt %] BS 4583 Automotive Pharmaceutics Water content max. 0.05 [wt %] ISO 12937:2000 Water content max. 0.05 [wt %] ISO 12937:2000 Pharmaceutics & Cosmetics & Cosmetics 1These parameters are covered by the producer’s guarantee, to be analysed in case of a claim only. Technical Gases Te chnic al G ases Textiles Text i les Other Other www.oxoplast.com/en/oxo-alcohols/2-ethylhexanol/ www.oxoplast.com/en/oxo-alcohols/n-butanol/ Isobutanol Octyl alcohol F Trade name: Trade name: Isobutanol Octyl alcohol F Chemical name: Chemical name: 2-Metylopropan-1-ol, isobutanol 1-Hexanol, 2-ethyl-, manuf. of, by-products from, distn. residues CAS: 78-83-1 REACH Status: Isobutanol CAS: 68609-68-7 registered 04/11/2010 REACH Status: Octyl alcohol F registered 12/01/2012 OXO ALCOHOLS OXO ALCOHOLS Isobutanol is produced Our product is mailny used as solvent in many appreciated brands of paints, Octyl alcohol F is a liquid with various colourations: from yellow through yellow-brown to from our Isobutyraldehyde. varnishes and resins. greenish and with the specific odour. Isobutanol is REACH registered according to EC regulation No. 1907/2006 Octyl alcohol F is REACH registered according to EC regulation No. 1907/2006 IDENTIFIED USE: Specification Value Test method Specification Value Test method IDENTIFIED USE: Paints & Lacquers Isobutanol min. 99.8 [wt %] GC 2-Ethylhexanol max. 30 [wt %] GC Paints & Lacquers Colour, Pt-Co scale max. 5 [APHA] ISO 6271 High molecular weight compounds (>C ) min. 70 [wt %] GC Wires & Cables 8 Wires & Cables min. 0.802 [g/cm3] Plastic (PVC) additives Density at 20°C ISO 12185 Plastic (PVC) additives max. 0.804 [g/cm3] Chemical Synthesis Acids as acetic acid max. 0.003 [wt %] ASTM D 1613 Chemical Synthesis Automotive Aldehydes as butyraldehyde max. 0.05 [wt %] BS 4583 Automotive Pharmaceutics Water content max. 0.10 [wt %] ISO 12937:2000 Pharmaceutics & Cosmetics & Cosmetics Technical Gases Te chnic al G ases Textiles Text i les Other Other www.oxoplast.com/en/oxo-alcohols/isobutanol/ www.oxoplast.com/en/oxo-alcoholst/oktanol-f/ Aldehydes Aldehydes n-Butyraldehyde Isobutyraldehyde Trade name: Trade name: n-Butyraldehyde Isobutyraldehyde Chemical name: Chemical name: n-Butyraldehyde; Butanal Isobutyraldehyde; 2-methylpropanal CAS: 123-72-8 CAS: 78-84-2 REACH Status: n-Butyraldehyde REACH Status: Isobutyraldehyde registered 07/10/2010 registered 11/08/2010 ALDEHYDES ALDEHYDES n-Butyraldehyde is a main Owing to its high quality our alcohols are recognised as leading products on the market.
Load more

Recommended publications
  • Octyl Alcohol F Oxo Alcohols
    Octyl alcohol F Oxo alcohols Trade name: Octyl alcohol F Chemical name: Distillation residue, by-products from the production of 2-ethylhexan-1-ol. CN: 3824 90 97 CAS: 68609-68-7 Properties Use Octyl alcohol F is a liquid whose colour varies from yellow, Octyl alcohol F is used as a flotation agent. through brown-yellow to greenish, with a characteristic odour. Product classification Octyl alcohol F is not classified as a hazardous material according to RID/ADR. Physical and chemical properties Parameter Business unit Value Test methods 2-ethylhexanol, not more than % m/m 30 ZAK’s internal rmethod High-molecular compounds >C8, not less than % m/m 70 ZAK’s internal rmethod oxoplast.pl Manufacturer: Grupa Azoty Zakłady Azotowe Kędzierzyn S.A. Isobutyraldehyde Trade name: Isobutyraldehyde Chemical name: 2-methylpropanal, isobutyraldehyde, isobutanal CN: 2912 19 00 CAS: 78-84-2 Chemical formula: (CH3)2CHCHO Properties Use Isobutyraldehyde is a transparent, colourless liquid with a char- Isobutyraldehyde is used as a raw material for producing acteristic odour. alcohols, acids, amines, and esters. It is used in processes of manufacturing plasticizers, pharmaceutical products, plant Product classification protection agents, synthetic resins, fragrances, solvents and all sorts of additives used in many branches of industry Isobutyraldehyde is classified as a hazardous material (antioxidants, wetting agents, perfume ingredients, improvers). according to RID/ADR. - RID KI. 3, packing group II - ADR KI. 3, packing group II Physical and chemical properties Parameter Business unit Value Test methods Colour, not more than Pt-Co 15 ISO 6271 Acid number, not more than mg KOH/g 2 ZAK’s internal rmethod N-butyraldehyde, not more than % m/m 0,2* ZAK’s internal rmethod Water, not more than % m/m 1,5 ISO 760 Isobutyraldehyde, not less than % m/m 99,5* ZAK’s internal rmethod * the values do not take into account water content in the product oxoplast.pl Manufacturer: Grupa Azoty Zakłady Azotowe Kędzierzyn S.A.
    [Show full text]
  • Review Article Di-2-Ethylhexylphthalate May Be a Natural Product, Rather Than a Pollutant
    Hindawi Journal of Chemistry Volume 2018, Article ID 6040814, 7 pages https://doi.org/10.1155/2018/6040814 Review Article Di-2-ethylhexylphthalate May Be a Natural Product, Rather than a Pollutant Aurelio Ortiz and Estibaliz Sansinenea Facultad de Ciencias Qu´ımicas, Beneme´rita Universidad Auto´noma de Puebla, C.P. 72570, Puebla, PUE, Mexico Correspondence should be addressed to Estibaliz Sansinenea; [email protected] Received 28 June 2018; Revised 22 August 2018; Accepted 3 September 2018; Published 26 September 2018 Academic Editor: Qizhen Du Copyright © 2018 Aurelio Ortiz and Estibaliz Sansinenea. )is is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. Di-2-ethylhexylphtalate is an ester of phthalic acid that has been used as plasticizer in many materials. Due to the extended use, it has been persistently found in different environments being classified as a pollutant with some risks for human health. However, in the last years, it has been found that this compound is produced by plants or microorganisms like bacteria or fungi. )is finding opened a serious debate about the origin of this compound and questioned if it is a real pollutant or a natural metabolite with some biological activities that could help us in several ways. )is review tries to give some data of the different points of view about this question. 1. Introduction presence of these compounds in the environment, many reactions have been reported to degrade and transform these Phthalate compounds are colorless liquid chemicals that compounds.
    [Show full text]
  • Purification and Properties of the Inducible Coenzyme A-Linked Butyraldehyde Dehydrogenase from Clostridium Acetobutylicum NEIL R
    JOURNAL OF BACTERIOLOGY, JUlY 1988, p. 2971-2976 Vol. 170, No. 7 0021-9193/88/072971-06$02.00/0 Copyright © 1988, American Society for Microbiology Purification and Properties of the Inducible Coenzyme A-Linked Butyraldehyde Dehydrogenase from Clostridium acetobutylicum NEIL R. PALOSAARI* AND PALMER ROGERS Department of Microbiology, University of Minnesota, Minneapolis, Minnesota 55455 Received 13 November 1987/Accepted 25 March 1988 The coenzyme A (CoA)-linked butyraldehyde dehydrogenase (BAD) from Clostridium acetobutylicum was characterized and purified to homogeneity. The enzyme was induced over 200-fold, coincident with a shift from an acidogenic to a solventogenic fermentation, during batch culture growth. The increase in enzyme activity was found to require new protein synthesis since induction was blocked by the addition of rifampin and antibody against the purified enzyme showed the appearance of enzyme antigen beginning at the shift of the fermentation and increasing coordinately with the increase in enzyme specific activity. The CoA-linked acetaldehyde dehydrogenase was copurified with BAD during an 89-fold purification, indicating that one enzyme accounts for the synthesis of the two aldehyde intermediates for both butanol and ethanol production. Butanol dehydrogenase activity was clearly separate from the BAD enzyme activity on TEAE cellulose. A molecular weight of 115,000 was determined for the native enzyme, and the enzyme subunit had a molecular weight of 56,000 indicating that the active form is a homodimer. Kinetic constants were determined in both the forward and reverse directions. In the reverse direction both the V,ax and the apparent affinity for butyraldehyde and caproaldehyde were significantly greater than they were for acetaldehyde, while in the forward direction, the Vmax for butyryl-CoA was fivefold that for acetyl-CoA.
    [Show full text]
  • Sids Initial Assessment Profile
    SIAM 31, 20-22 October 2010 BIAC/ICCA SIDS INITIAL ASSESSMENT PROFILE CAS No. 123-05-7 Chemical Name 2-Ethylhexaldehyde Structural Formula O=CH-CH(CH2-CH3)-CH2-CH2-CH2-CH3 SUMMARY CONCLUSIONS OF THE SIAR Analogue Rationale Several of the health endpoints for 2-ethylhexaldehyde make use of data from 2-ethylhexanol and 2-ethylhexanoic acid experiments. The logic for this “metabolic series” approach includes the metabolism of alcohols (2-ethylhexanol) proceeding via a readily reversible reaction with alcohol dehydrogenase(s) to rapidly form the respective aldehydes (2-ethylhexaldehyde). The aldehydes are short-lived due to the enzymatic activity of aldehyde dehydrogenase that forms the respective organic acids (2-ethylhexanoic acid). Assuming 2-ethylhexaldehyde behaves as other aldehydes, direct exposure to 2-ethylhexaldehyde will result in the rapid formation of both 2 -ethylhexanol and 2-ethylhexanoic acid. The metabolic processes of these two chemicals are well characterized. Toxicity data from studies conducted with 2-ethylhexanol and 2-ethylhexanoic acid have been used to identify the hazards associated with systemic exposure to 2 -ethylhexaldehyde and therefore are useful in identifying hazards associated with 2-ethylhexaldehyde systemic exposures. Structural analogues are used to address several Environmental Hazard endpoints: 2-methyl propionaldehyde (CAS No.78-84-2), 2-ethyl butyraldehyde (CAS No.97-96-1), 2-methyl valeraldehyde (CAS No. 123-15-9), valeraldehyde (CAS No. 110-62-3), hexaldehyde (CAS No.66-25-1), and octylaldehyde (CAS No. 124-13-0). Physical-Chemical Properties 2-Ethylhexaldehyde is a liquid at standard temperature and pressure, with a boiling point of 163 ºC and a melting (freezing) point of <–100 ºC.
    [Show full text]
  • Kinetics of Oxidation of Formaldehyde, Acetaldehyde, Propionaldehyde & Butyraldehyde by Ditelluratocuprate(III) in Alkaline Medium
    r Jndlan Journal of Chemistry Vol. 17A, January 1979,pp. 48·51 Kinetics of Oxidation of Formaldehyde, Acetaldehyde, Propionaldehyde & Butyraldehyde by Ditelluratocuprate(III) in Alkaline Medium C. P. MURTHY, B. SETHURAM & T. NAVANEETH RAO· Department of Chemistry, Osmania University, Hyderabad 500007 Received 8 June 1978; accepted 25 July 1978 Kinetics of oxidation oJ formaldehyde, acetaldehyde, proplonaldehyde and n-butyraldehyde by potasstum ditelluratocuprate(III) has been studied in alkaline medium spectrophoto- :metrically. The order in [aldeh;de] and [Cu(III)) are found to be one each and rates decreased with increase in [tellurate] and increase in [OH-]. There is no effect of addition of salts like Na, SO. and KNOa• The products of oxidation are identified as corresponding carboxylic acids. Under the experimental conditions the :monotelluratocuprate(III) species is assu:med as the active species. The ther:modynamic para:meters are also reported and a plausible mechanism has been suggested. SE of Cu(III) as an oxidizing agent is well corrections made for any self-decomposition of known in analytical chemistry in the estimation Cu (III) during the reaction. U of sugars-, glycerols-, amino acids", proteinss, carboxylic acids", carbonyl compounds" and alcohols? Results The presence of Cu(III) as intermediate was also Under the conditions [Cu(III)] ~ [aldehyde] the reported in some Cu(II)-catalysed oxidation reactions plots of log (absorbance) versus time were linear by peroxydisulphate" and vanadium (V)9. The kine- (Fig. lA), indicating the order in [Cu(III)J to be tics of decomposition and formation of Cu(III) unity. From the slopes of the above plots the diperiodate and ditellurate complexes were also pseudo-first order rate constants (k') were evaluated.
    [Show full text]
  • Food and Drugs
    21 Part 170 to 199 Revised as of April 1, 2001 Food and Drugs Containing a codification of documents of general applicability and future effect As of April 1, 2001 With Ancillaries Published by Office of the Federal Register National Archives and Records Administration A Special Edition of the Federal Register VerDate 11<MAY>2000 11:38 Apr 16, 2001 Jkt 194064 PO 00000 Frm 00001 Fmt 8091 Sfmt 8091 Y:\SGML\194064F.XXX pfrm02 PsN: 194064F U.S. GOVERNMENT PRINTING OFFICE WASHINGTON : 2001 For sale by the Superintendent of Documents, U.S. Government Printing Office Internet: bookstore.gpo.gov Phone: (202) 512-1800 Tax: (202) 512-2250 Mail Stop: SSOP, Washington, DC 20402–0001 VerDate 11<MAY>2000 11:38 Apr 16, 2001 Jkt 194064 PO 00000 Frm 00002 Fmt 8092 Sfmt 8092 Y:\SGML\194064F.XXX pfrm02 PsN: 194064F Table of Contents Page Explanation ................................................................................................ v Title 21: Chapter I—Food and Drug Administration, Department of Health and Human Services (Continued) ................................................. 3 Finding Aids: Material Approved for Incorporation by Reference ............................ 573 Table of CFR Titles and Chapters ....................................................... 587 Alphabetical List of Agencies Appearing in the CFR ......................... 605 Redesignation Table ............................................................................ 615 List of CFR Sections Affected ............................................................. 617
    [Show full text]
  • Butyraldehyde Casrn: 123-72-8 Unii: H21352682a
    BUTYRALDEHYDE CASRN: 123-72-8 UNII: H21352682A FULL RECORD DISPLAY Displays all fields in the record. For other data, click on the Table of Contents Human Health Effects: Human Toxicity Excerpts: /HUMAN EXPOSURE STUDIES/ Three Asian subjects who reported experiencing severe facial flushing in response to ethanol ingestion were subjects of patch testing to aliphatic alcohols and aldehydes. An aqueous suspension of 75% (v/v) of each alcohol and aldehyde was prepared and 25 uL was used to saturate ashless grade filter paper squares which were then placed on the forearm of each subject. Patches were covered with Parafilm and left in place for 5 minutes when the patches were removed and the area gently blotted. Sites showing erythema during the next 60 minutes were considered positive. All three subjects displayed positive responses to ethyl, propyl, butyl, and pentyl alcohols. Intense positive reactions, with variable amounts of edema, were observed for all the aldehydes tested (valeraldehyde as well as acetaldehyde, propionaldehyde, and butyraldehyde). [United Nations Environment Programme: Screening Information Data Sheets on n-Valeraldehyde (110-62-3) (October 2005) Available from, as of January 15, 2009: http://www.chem.unep.ch/irptc/sids/OECDSIDS/sidspub.html] **PEER REVIEWED** [United Nations Environment Programme: Screening Information Data Sheets on n­Valeraldehyde (110­62­3) (October 2005) Available from, as of January 15, 2009: http://www.chem.unep.ch/irptc/sids/OECDSIDS/sidspub.html] **PEER REVIEWED** /SIGNS AND SYMPTOMS/ May act as irritant, /SRP: CNS depressant/ ...[Budavari, S. (ed.). The Merck Index - Encyclopedia of Chemicals, Drugs and Biologicals. Rahway, NJ: Merck and Co., Inc., 1989., p.
    [Show full text]
  • The Impact of Ethanol and Iso-Butanol Blends on Gaseous and Particulate
    Energy 82 (2015) 168e179 Contents lists available at ScienceDirect Energy journal homepage: www.elsevier.com/locate/energy The impact of ethanol and iso-butanol blends on gaseous and particulate emissions from two passenger cars equipped with spray-guided and wall-guided direct injection SI (spark ignition) engines * Georgios Karavalakis a, b, , Daniel Short a, b, Diep Vu a, b, Robert L. Russell a, Akua Asa-Awuku a, b, Heejung Jung a, c, Kent C. Johnson a, b, Thomas D. Durbin a, b a University of California, Bourns College of Engineering, Center for Environmental Research and Technology (CE-CERT), 1084 Columbia Avenue, Riverside, CA 92507, USA b Department of Chemical and Environmental Engineering, Bourns College of Engineering, University of California, Riverside, CA 92521, USA c Department of Mechanical Engineering, Bourns College of Engineering, University of California, Riverside, CA 92521, USA article info abstract Article history: We examined the effects of different ethanol and iso-butanol blends on the gaseous and particulate Received 2 August 2014 emissions from two passenger cars equipped with spark ignition direct injection engines and with one Received in revised form spray-guided and one wall-guided configuration. Both vehicles were tested over triplicate FTP (Federal 3 December 2014 Test Procedure) and UC (Unified Cycles) using a chassis dynamometer. Emissions of THC (total hydro- Accepted 8 January 2015 carbons), NMHC (non-methane hydrocarbons), and CO (carbon monoxide) reduced with increasing Available online 7 February 2015 oxygen content in the blend for some of the vehicle/fuel combinations, whereas NOx (nitrogen oxide) emissions did not show strong fuel effects.
    [Show full text]
  • Method TO-11A
    EPA/625/R-96/010b Compendium of Methods for the Determination of Toxic Organic Compounds in Ambient Air Second Edition Compendium Method TO-11A Determination of Formaldehyde in Ambient Air Using Adsorbent Cartridge Followed by High Performance Liquid Chromatography (HPLC) [Active Sampling Methodology] Center for Environmental Research Information Office of Research and Development U.S. Environmental Protection Agency Cincinnati, OH 45268 January 1999 Method TO-11A Acknowledgements This Method was prepared for publication in the Compendium of Methods for the Determination of Toxic Organic Compounds in Ambient Air, Second Edition (EPA/625/R-96/010b), which was prepared under Contract No. 68-C3-0315, WA No. 3-10, by Midwest Research Institute (MRI), as a subcontractor to Eastern Research Group, Inc. (ERG), and under the sponsorship of the U.S. Environmental Protection Agency (EPA). Justice A. Manning, John O. Burckle, and Scott Hedges, Center for Environmental Research Information (CERI), and Frank F. McElroy, National Exposure Research Laboratory (NERL), all in the EPA Office of Research and Development, were responsible for overseeing the preparation of this method. Additional support was provided by other members of the Compendia Workgroup, which include: • John O. Burckle, U.S. EPA, ORD, Cincinnati, OH • James L. Cheney, Corps of Engineers, Omaha, NB • Michael Davis, U.S. EPA, Region 7, KC, KS • Joseph B. Elkins Jr., U.S. EPA, OAQPS, RTP, NC • Robert G. Lewis, U.S. EPA, NERL, RTP, NC • Justice A. Manning, U.S. EPA, ORD, Cincinnati, OH • William A. McClenny, U.S. EPA, NERL, RTP, NC • Frank F. McElroy, U.S. EPA, NERL, RTP, NC • Heidi Schultz, ERG, Lexington, MA • William T.
    [Show full text]
  • Assessing the Impacts of Ethanol and Isobutanol on Gaseous and Particulate Emissions from Flexible Fuel Vehicles
    Article pubs.acs.org/est Assessing the Impacts of Ethanol and Isobutanol on Gaseous and Particulate Emissions from Flexible Fuel Vehicles † ‡ † ‡ † † § † ‡ Georgios Karavalakis,*, , Daniel Short, , Robert L. Russell, Heejung Jung, , Kent C. Johnson, , † ‡ † ‡ Akua Asa-Awuku, , and Thomas D. Durbin , † Bourns College of Engineering, Center for Environmental Research and Technology (CE-CERT), University of California, 1084 Columbia Avenue, Riverside, California 92507, United States ‡ § Department of Chemical and Environmental Engineering and Department of Mechanical Engineering, Bourns College of Engineering, University of California, Riverside, California 92521, United States *S Supporting Information ABSTRACT: This study investigated the effects of higher ethanol blends and an isobutanol blend on the criteria emissions, fuel economy, gaseous toxic pollutants, and particulate emissions from two flexible-fuel vehicles equipped with spark ignition engines, with one wall-guided direct injection and one port fuel injection configuration. Both vehicles were tested over triplicate Federal Test Procedure (FTP) and Unified Cycles (UC) using a chassis dynamometer. Emissions of nonmethane hydrocarbons (NMHC) and carbon monoxide (CO) showed some statistically significant reduc- tions with higher alcohol fuels, while total hydrocarbons (THC) and nitrogen oxides (NOx) did not show strong fuel effects. Acetaldehyde emissions exhibited sharp increases with higher ethanol blends for both vehicles, whereas butyraldehyde emissions showed higher emissions for
    [Show full text]
  • Product Range
    PRODUCT RANGE www.oxea-chemicals.com WE ARE THE OXO PEOPLE Oxo chemicals are OXEA’s core competency. We produce end-market applications. With a total production capacity Oxo intermediates and Oxo derivatives in our plants in of over 1.2 million tons, we are the largest Oxo chemicals Germany, the Netherlands, and the USA and started up in producer for the Oxo merchant market overall. 2014 our first manufacturing facility in China. Our global customer base is served from sales offices in numerous Being a market leader requires constant innovation and locations, including Europe, North America, Asia and Latin a stringent process of business optimization. At OXEA, America. we continuously analyze the geographies and industrial sectors we serve – always eager to learn more about the As “The Oxo People”, OXEA has more than 75 years of dynamics and perspectives in our clients’ industries. experience in the production of Oxo chemicals. We are the inventor of the Oxo synthesis process (or “hydro- OXEA is recognized by our customers as a knowledgeable formylation”) as well as several other proprietary techno- partner and a reliable supplier. Our long-standing and logies for the manufacture of Oxo chemicals. The produc- trusted customer relationships, some spanning more than tion process for Oxo intermediates and Oxo derivatives 50 years of productive cooperation, provides our global is complex, requiring efficient integration and an under- commercial teams with a deep understanding of our custo- stand ing of the underlying processes and end-markets. mers’ needs and allow us to align closely with our custo- We benefit from highly integrated production facilities and mers’ strategies and growth activities.
    [Show full text]
  • Cross-Aldol Condensation of Acetone and N-Butanol Into Aliphatic Ketones Over Supported Cu Catalysts on Ceria-Zirconia
    catalysts Article Cross-Aldol Condensation of Acetone and n-Butanol into Aliphatic Ketones over Supported Cu Catalysts on Ceria-Zirconia Minseok Kim 1, Jongha Park 1, Hari Prasad Reddy Kannapu 1,2 and Young-Woong Suh 1,2,* ID 1 Department of Chemical Engineering, Hanyang University, Seoul 04763, Korea; [email protected] (M.K.); [email protected] (J.P.); [email protected] (H.P.R.K.) 2 Research Institute of Industrial Science, Hanyang University, Seoul 04763, Korea * Correspondence: [email protected]; Tel.: +82-2-2220-2329 Academic Editor: Christophe Len Received: 7 August 2017; Accepted: 23 August 2017; Published: 24 August 2017 Abstract: A long-chain hydrocarbon biofuel of jet fuel range can be produced via aldol condensation of fermented products such as acetone and alcohols over the catalysts containing both metallic sites for the dehydrogenation of alcohols and basic sites for the condensation reaction. However, an efficient catalyst system has not been studied widely yet the route is promising for biofuel production. In this work, Cu catalysts supported on ceria-zirconia (Cu/xCeZr) were prepared using coprecipitated CexZr1-xO2 supports with different Ce/Zr ratios for the cross-aldol condensation of acetone and n-butanol into mono- and di-alkylated aliphatic ketones, 2-heptanone and 6-undecanone. The acetone conversion and 6-undecanone selectivity increased with specific Cu surface area due to formation of the dehydrogenation product butyraldehyde at a higher concentration. The total yield of cross-aldol condensation products was strongly dependent on a combination of Cu sites and basic sites. This was confirmed by the results in the reaction between acetone and butyraldehyde over supported Cu catalysts that additionally examined the adsorbed acyl species on Cu surface taking part in the aldol condensation reaction.
    [Show full text]