1 On-Surface Hydrogen-Induced Covalent Coupling of Polycyclic
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SCIENCE ADVANCES | RESEARCH ARTICLE CHEMISTRY Copyright © 2019 The Authors, some rights reserved; Atomically precise bottom-up synthesis exclusive licensee p American Association of -extended [5]triangulene for the Advancement Jie Su1,2*, Mykola Telychko1,2*, Pan Hu1*, Gennevieve Macam3*, Pingo Mutombo4, of Science. No claim to 1 1,2 1,2 3 1,5 original U.S. Government Hejian Zhang , Yang Bao , Fang Cheng , Zhi-Quan Huang , Zhizhan Qiu , Works. Distributed 1,5 6 4,7† 3† 1† 1,2† Sherman J. R. Tan , Hsin Lin , Pavel Jelínek , Feng-Chuan Chuang , Jishan Wu , Jiong Lu under a Creative Commons Attribution The zigzag-edged triangular graphene molecules (ZTGMs) have been predicted to host ferromagnetically coupled NonCommercial edge states with the net spin scaling with the molecular size, which affords large spin tunability crucial for License 4.0 (CC BY-NC). next-generation molecular spintronics. However, the scalable synthesis of large ZTGMs and the direct observation of their edge states have been long-standing challenges because of the molecules’ high chemical instability. Here, we report the bottom-up synthesis of p-extended [5]triangulene with atomic precision via surface-assisted cyclo- dehydrogenation of a rationally designed molecular precursor on metallic surfaces. Atomic force microscopy measurements unambiguously resolve its ZTGM-like skeleton consisting of 15 fused benzene rings, while scanning tunneling spectroscopy measurements reveal edge-localized electronic states. Bolstered by density functional theory calculations, our results -
LD5655.V856 1966.G733.Pdf (6.196Mb)
A STUDYOF THE SYNTHESISAND REACTIONS OF NKW POLYNUCLEARAROMATIC ACIDS ANDRELATED COMPOUNDS by . Edward James Greenwood, B.S., M.S. Thesis submitted to the Graduate Faculty of the Virginia Polytechnic Institute in candidacy for the degree of DOCTOROF PHILOSOPHY in Chemistry APPROVED: Chainnan, Dr. F. A. Vingiello Dr. L. K. Brice, Jr. Dr. P. E. Field Dr. J. G. Mason Dr. J. F. Wolfe February, 1966 Blacksburg, Virginia -2- TO PATAND DEBBIE -3- ACKNOWLEDGEMENTS The author wishes to express his sincere and earnest appreciation to Dr. Frank A. Vingiello for his guidance and encouragement throughout the course of this work. Thanks are also extended to the other faculty members and to fellow graduate students for their valuable assistance. Particular appreciation is due to Mr. Thomas Greenwood who performed elemental analyses on six compounds prepared in this work. Financial assistance received in the form of a part-time instructorship from Virginia Polytechnic Institute and a research fellowship from the National Institutes of Health is gratefully acknowledged. Finally, the author wishes to express his appreciation of the help and encouragement provided by his wife which was essential to the successful completion of this work. -4- TABLEOF CONTENTS Page I. INTRODUCTION• • • • • • • • • • • • • • • • • 8 II. NOiwlliNCLATURE• • • • • . 12 III. HISTORICAL . • • • • • 14 IV. DISCUSSIONOF RESULTS. • • • • • • . • • 29 A. Preparation of Starting Materials • • • JO 1. l-Bromo-3-chloronaphthalene • • • • JO 2. 2-(J-Chloro-l-naphthyl- methyl)bromobenzene •••••••• 32 B. The Unequivocal Synthesis of Dibenzo[hi,l]chrysen-9-one •••• • • • 47 1. 2-(J-Chloro-l-naphthylmethyl)- 2'-carboxybenzophenone and 6-chloro-7-(2-carboxyphenyl)- benz[a)anthracene ••. • • • • • • . 47 2. -
Messengers from Outer Space
The complete absence of national laboratories for standardizing radiation measurements and the lack of physics departments in most radiotherapy centres in Latin America warrant the setting up of one or more regional dosimetry facilities, the functions of which would be primarily to calibrate dosimeters; to provide local technical assistance by means of trained staff; to check radiation equipment and dosimeters; to arrange a dose-intercomparison service; and to co-operate with local personnel dosimetry services. To be most effective, this activity should be in the charge of local personnel, with some initial assistance in the form of equipment and experts provided by the Agency. Although the recommendations were presented to the IAEA as the or ganization responsible for the setting up of the panel, the participants re commended that the co-operation of the World Health Organization and the Pan-American Health Organization should be invited. It was also suggested that the panel report be circulated to public health authorities in the countries represented. MESSENGERS FROM OUTER SPACE Although no evidence has yet been confirmed of living beings reaching the earth from space, it has been estimated that hundreds of tons of solid matter arrive every day in the form of meteorites or cosmic dust particles. Much is destroyed by heat in the atmosphere but fragments recovered can give valuable information about what has been happening in the universe for billions of years. Some of the results of worldwide research on meteorites were given at a symposium in Vienna during August. During six days of discussions a total of 73 scientific papers was present ed and a special meeting was held for the purpose of improving international co-operation in the research. -
The Water on Mars Vanished. This Might Be Where It Went
The water on Mars vanished. This might be where it went. timesofindia.indiatimes.com/home/science/the-water-on-mars-vanished-this-might-be-where- it-went-/articleshow/81599751.cms NYT News Service | Mar 20, 2021, 10:32 IST Mars was once wet, with an ocean’s worth of water on its surface. Today, most of Mars is as dry as a desert except for ice deposits in its polar regions. Where did the rest of the water go? Some of it disappeared into space. Water molecules, pummeled by particles of solar wind, broke apart into hydrogen and oxygen atoms, and those, especially the lighter hydrogen atoms, sped out of the atmosphere, lost to outer space. A tall outcropping of rock, with layered deposits of sediments in the distance, marking a remnant of an ancient, long-vanished river delta in Jezero Crater, are pictured in this undated image taken by NASA's Mars rover Perseverance. (Reuters) But most of the water, a new study concludes, went down, sucked into the red planet’s rocks. And there it remains, trapped within minerals and salts. Indeed, as much as 99% of the water that once flowed on Mars could still be there, the researchers estimated in a paper published this week in the journal Science. Data from the past two decades of robotic missions to Mars, including NASA ’s Curiosity rover and the Mars Reconnaissance Orbiter, showed a wide distribution of what geologists call hydrated minerals. “It became very, very clear that it was common and not rare to find evidence of water alteration,” said Bethany Ehlmann, a professor of planetary science at the California Institute of Technology and one of the authors of the paper. -
Closed Network Growth of Fullerenes
ARTICLE Received 9 Jan 2012 | Accepted 18 Apr 2012 | Published 22 May 2012 DOI: 10.1038/ncomms1853 Closed network growth of fullerenes Paul W. Dunk1, Nathan K. Kaiser2, Christopher L. Hendrickson1,2, John P. Quinn2, Christopher P. Ewels3, Yusuke Nakanishi4, Yuki Sasaki4, Hisanori Shinohara4, Alan G. Marshall1,2 & Harold W. Kroto1 Tremendous advances in nanoscience have been made since the discovery of the fullerenes; however, the formation of these carbon-caged nanomaterials still remains a mystery. Here we reveal that fullerenes self-assemble through a closed network growth mechanism by incorporation of atomic carbon and C2. The growth processes have been elucidated through experiments that probe direct growth of fullerenes upon exposure to carbon vapour, analysed by state-of-the-art Fourier transform ion cyclotron resonance mass spectrometry. Our results shed new light on the fundamental processes that govern self-assembly of carbon networks, and the processes that we reveal in this study of fullerene growth are likely be involved in the formation of other carbon nanostructures from carbon vapour, such as nanotubes and graphene. Further, the results should be of importance for illuminating astrophysical processes near carbon stars or supernovae that result in C60 formation throughout the Universe. 1 Department of Chemistry and Biochemistry, Florida State University, 95 Chieftan Way, Tallahassee, Florida 32306, USA. 2 Ion Cyclotron Resonance Program, National High Magnetic Field Laboratory, Florida State University, 1800 East Paul Dirac Drive, Tallahassee, Florida 32310, USA. 3 Institut des Matériaux Jean Rouxel, CNRS UMR 6502, Université de Nantes, BP32229 Nantes, France. 4 Department of Chemistry and Institute for Advanced Research, Nagoya University, Nagoya 464-8602, Japan. -
Geometric and Electronic Properties of Graphene-Related Systems: Chemical Bondings Arxiv:1702.02031V2 [Physics.Chem-Ph] 13
Geometric and electronic properties of graphene-related systems: Chemical bondings Ngoc Thanh Thuy Trana, Shih-Yang Lina;∗, Chiun-Yan Lina, Ming-Fa Lina;∗ aDepartment of Physics, National Cheng Kung University, Tainan 701, Taiwan February 14, 2017 Abstract This work presents a systematic review of the feature-rich essential properties in graphene-related systems using the first-principles method. The geometric and electronic properties are greatly diversified by the number of layers, the stacking con- figurations, the sliding-created configuration transformation, the rippled structures, and the distinct adatom adsorptions. The top-site adsorptions can induce the signif- icantly buckled structures, especially for hydrogen and fluorine adatoms. The elec- tronic structures consist of the carbon-, adatom- and (carbon, adatom)-dominated energy bands. There exist the linear, parabolic, partially flat, sombrero-shaped and oscillatory band, accompanied with various kinds of critical points. The semi-metallic or semiconducting behaviors of graphene systems are dramatically changed by the multi- or single-orbital chemical bondings between carbons and adatoms. Graphene oxides and hydrogenated graphenes possess the tunable energy gaps. Fluorinated graphenes might be semiconductors or hole-doped metals, while other halogenated systems belong to the latter. Alkali- and Al-doped graphenes exhibit the high-density free electrons in the preserved Dirac cones. The ferromagnetic spin configuration is revealed in hydrogenated and halogenated graphenes under certain distributions. Specifically, Bi nano-structures are formed by the interactions between monolayer arXiv:1702.02031v2 [physics.chem-ph] 13 Feb 2017 graphene and buffer layer. Structure- and adatom-enriched essential properties are compared with the measured results, and potential applications are also discussed. -
The Protection of Frequencies for Radio Astronomy 1
JOURNAL OF RESEARCH of the National Bureau of Standards-D. Radio Propagation Vol. 67D, No. 2, March- April 1963 b The Protection of Frequencies for Radio Astronomy 1 R. 1. Smith-Rose President, International Scientific Radio Union (R eceived November 5, 1962) The International T elecommunications Union in its Geneva, 1959 R adio R egulations r recognises the Radio Astronomy Service in t he two following definitions: N o. 74 Radio A st1" onomy: Astronomy based on t he reception of waves of cos mi c origin. No. 75 R adio A st1"onomy Se1"vice: A service involving the use of radio astronomy. This service differs, however, from other r adio services in two important respects. 1. It does not itself originate any radio waves, and therefore causes no interference to any other service. L 2. A large proportion of its activity is conducted by the use of reception techniques which are several orders of magnit ude )]).ore sensitive than those used in other ra dio services. In order to pursue his scientific r esearch successfully, t he radio astronomer seeks pro tection from interference first, in a number of bands of frequencies distributed t hroughout I t he s p ~ct run:; and secondly:. 1~10r e complete and s p ec i~c prote.ction fOl: t he exact frequency bands III whIch natural radIatIOn from, or absorptIOn lD, cosmIc gases IS known or expected to occur. The International R egulations referred to above give an exclusive all ocation to one freq uency band only- the emission line of h ydrogen at 1400 to 1427 Mc/s. -
Issue 47 | Apr 2018
Issue 47 j Apr 2018 . Dear Colleagues, Our April cover is illustrated with a collage of different hydrocarbon structures, in light of the diverse species presented in this issue. The In Focus section, presented by Xiao- Ye Wang, Akimitsu Narita and Klaus Mullen,¨ introduces us to multiple new synthetic pathways for the production of large PAHs. This month’s collection of abstracts presents both PAH research and a broader look into the periphery of PAH research with theory on the treatment of out-of-plane motions, experiments on unimolecular reaction energies, predictions of adsorption and ionization energies of PAHs on water ice, ion implementation in nanodiamonds, study of photon flux in photochemical aerosol experiments, dust in supernovae and their remnants, and PAHs with straight edges and their band intensity ratios in reflection nebulae. We would like to take this opportunity to repeat the news that the JWST cycle 1 proposal deadline has been postponed to early 2019. For those who ran out of time, you have another chance! Other news is the kick-off of the Dutch Astrochemistry Net- work II on Monday 23 April. We are happy with this follow-up of the successful DAN-I programme and look forward to new exciting studies. Do you want to highlight your research, a facility or another topic, please contact us for a possible In Focus. Of course, do not forget to send us your abstracts! We also encourage you to send in your vacancies, conference announcements and more. For publication in the next AstroPAH, see the deadlines below. The Editorial Team Next issue: 17 May 2018. -
Graphene Molecule Compared with Fullerene C60 As Circumstellar
arXiv.org 1904.xxxxx (arXiv: 1904.xxxxx by Norio Ota) page 1 of 9 Graphene Molecule Compared With Fullerene C60 As Circumstellar Carbon Dust Of Planetary Nebula Norio Ota Graduate School of Pure and Applied Sciences, University of Tsukuba, 1-1-1 Tenoudai Tsukuba-city 305-8571, Japan, E-mail: [email protected] It had been understood that astronomically observed infrared spectrum of carbon rich planetary nebula as like Tc 1 and Lin 49 comes from fullerene (C60). Also, it is well known that graphene is a raw material for synthesizing fullerene. This study seeks some capability of graphene based on the quantum-chemical DFT calculation. It was demonstrated that graphene plays major role rather than fullerene. We applied two astrophysical conditions, which are void creation by high speed proton and photo-ionization by the central star. Model molecule was ionized void-graphene (C23) having one carbon pentagon combined with hexagons. By molecular vibrational analysis, we could reproduce six major bands from 6 to 9 micrometer, large peak at 12.8, and largest peak at 19.0. Also, many minor bands could be reproduced from 6 to 38 micrometer. Also, deeply void induced molecules (C22) and (C21) could support observed bands. Key words: graphene, fullerene, C60, infrared spectrum, planetary nebula, DFT 1. Introduction Soccer ball like carbon molecule fullerene-C60 was discovered in 1985 and synthesized in 1988 by H. Kroto and their colleagues1-2). In these famous papers, they also pointed out another important message “Fullerene may be widely distributed in the Universe”. After such prediction, many efforts were done for seeking C60 in interstellar space3-4). -
Constructing Covalent Organic Nanoarchitectures Molecule by Molecule Via Scanning Probe Manipulation
ARTICLES https://doi.org/10.1038/s41557-021-00773-4 Constructing covalent organic nanoarchitectures molecule by molecule via scanning probe manipulation Qigang Zhong 1,2 ✉ , Alexander Ihle 1,2, Sebastian Ahles2,3, Hermann A. Wegner 2,3, Andre Schirmeisen 1,2 ✉ and Daniel Ebeling 1,2 ✉ Constructing low-dimensional covalent assemblies with tailored size and connectivity is challenging yet often key for applica- tions in molecular electronics where optical and electronic properties of the quantum materials are highly structure depen- dent. We present a versatile approach for building such structures block by block on bilayer sodium chloride (NaCl) films on Cu(111) with the tip of an atomic force microscope, while tracking the structural changes with single-bond resolution. Covalent homo-dimers in cis and trans configurations and homo-/hetero-trimers were selectively synthesized by a sequence of deha- logenation, translational manipulation and intermolecular coupling of halogenated precursors. Further demonstrations of structural build-up include complex bonding motifs, like carbon–iodine–carbon bonds and fused carbon pentagons. This work paves the way for synthesizing elusive covalent nanoarchitectures, studying structural modifications and revealing pathways of intermolecular reactions. he vision of assembling nanoarchitectures by con- the tip of a scanning tunnelling microscopy (STM) or atomic force trolled mechanical manipulation on an atom-by-atom or microscopy (AFM) instrument18–21. However, tip-induced intermo- Tmolecule-by-molecule basis has been a dream since its cre- lecular coupling is still very challenging due to the poorly controlled ation by R. Feynman and eventually led to the field of nanotechnol- alignment of the molecules and the strong chemical interactions ogy. -
On the Possibility of the Dyson Spheres Observable Beyond The
On the possibility of the Dyson spheres observable beyond the infrared spectrum Osmanov Z. & Berezhiani V. I. School of Physics, Free University of Tbilisi, 0183, Tbilisi, Georgia ABSTRACT In this paper we revisit the Dysonian approach and assume that a superadvanced civilisation is capable of building a cosmic megastructure located closer than the habitable zone (HZ). Then such a Dyson Sphere (DS) might be visible in the optical spectrum. We have shown that for typical high melting point meta material - Graphene, the radius of the DS should be of the order of 1011cm, or even less. It has been estimated that energy required to maintain the cooling system inside the DS is much less than the luminosity of a star. By considering the stability problem, we have found that the radiation pressure might stabilise dynamics of the megastructure and as a result it will oscillate, leading to interesting observational features - anomalous variability. The similar variability will occur by means of the transverse waves propagating along the surface of the cosmic megastructure. In the summary we also discuss the possible generalisation of definition of HZs that might lead to very interesting observational features. Subject headings: Dyson sphere; SETI; Extraterrestrial; life-detection 1. Introduction which are capable of utilising the total energy of their host star (Level-II civilisation in the Kar- A recent revival of interest to the search for ad- dashev scale (Kardashev 1964)), then they could vanced extraterrestrial civilisations has been pro- have built a relatively thin spherical shell (Dyson voked by the discovery of the object KIC8462852 sphere (DS) with radius ∼ 1AU surrounding the observed by the Keppler mission (Boyajian et al. -
Synthesis of Graphene Through Direct Decomposition of CO2 with the Aid of Ni–Ce–Fe Trimetallic Catalyst
Bull. Mater. Sci., Vol. 39, No. 1, February 2016, pp. 235–240. c Indian Academy of Sciences. Synthesis of graphene through direct decomposition of CO2 with the aid of Ni–Ce–Fe trimetallic catalyst GHAZALEH ALLAEDINI1,∗, SITI MASRINDA TASIRIN1 and PAYAM AMINAYI2 1Department of Chemical and Process Engineering, Universiti Kebangsaan Malaysia, 43600 Bangi, Malaysia 2Department of Chemical and Paper Engineering, College of Engineering and Applied Sciences, Parkview Campus, Western Michigan University, 4601 Campus Drive, Kalamazoo, MI 49008, USA MS received 29 June 2015; accepted 9 September 2015 Abstract. In this study, few-layered graphene (FLG) has been synthesized using the chemical vapour deposition (CVD) method with the aid of a novel Ni–Ce–Fe trimetallic catalyst. Carbon dioxide was used as the carbon source in the present work. The obtained graphene was characterized by Raman spectroscopy, and the results proved that high-quality graphene sheets were obtained. Scanning electron microscopy, atomic force microscopy and trans- mission electron microscopy pictures were used to investigate the morphology of the prepared FLG. The energy- dispersive X-ray spectroscopy results confirmed a high yield (∼48%) of the obtained graphene through this method. Ni–Ce–Fe has been shown to be an active catalyst in the production of high-quality graphene via carbon diox- ide decomposition. The X-ray photoelectron spectroscopy spectrum was also obtained to confirm the formation of graphene. Keywords. Chemical vapour deposition; carbon dioxide; Ni–Ce–Fe trimetallic catalyst; graphene. 1. Introduction methanol storage materials [5], graphene with a large, high- quality surface area, and few structural defects is needed. The allotropes of carbon differ in the way the atoms bond Graphene, which has a hexagonal arrangement of carbon with each other and arrange themselves into a structure.