The Dirac Equation
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1 Notation for States
The S-Matrix1 D. E. Soper2 University of Oregon Physics 634, Advanced Quantum Mechanics November 2000 1 Notation for states In these notes we discuss scattering nonrelativistic quantum mechanics. We will use states with the nonrelativistic normalization h~p |~ki = (2π)3δ(~p − ~k). (1) Recall that in a relativistic theory there is an extra factor of 2E on the right hand side of this relation, where E = [~k2 + m2]1/2. We will use states in the “Heisenberg picture,” in which states |ψ(t)i do not depend on time. Often in quantum mechanics one uses the Schr¨odinger picture, with time dependent states |ψ(t)iS. The relation between these is −iHt |ψ(t)iS = e |ψi. (2) Thus these are the same at time zero, and the Schrdinger states obey d i |ψ(t)i = H |ψ(t)i (3) dt S S In the Heisenberg picture, the states do not depend on time but the op- erators do depend on time. A Heisenberg operator O(t) is related to the corresponding Schr¨odinger operator OS by iHt −iHt O(t) = e OS e (4) Thus hψ|O(t)|ψi = Shψ(t)|OS|ψ(t)iS. (5) The Heisenberg picture is favored over the Schr¨odinger picture in the case of relativistic quantum mechanics: we don’t have to say which reference 1Copyright, 2000, D. E. Soper [email protected] 1 frame we use to define t in |ψ(t)iS. For operators, we can deal with local operators like, for instance, the electric field F µν(~x, t). -
Path Integrals in Quantum Mechanics
Path Integrals in Quantum Mechanics Dennis V. Perepelitsa MIT Department of Physics 70 Amherst Ave. Cambridge, MA 02142 Abstract We present the path integral formulation of quantum mechanics and demon- strate its equivalence to the Schr¨odinger picture. We apply the method to the free particle and quantum harmonic oscillator, investigate the Euclidean path integral, and discuss other applications. 1 Introduction A fundamental question in quantum mechanics is how does the state of a particle evolve with time? That is, the determination the time-evolution ψ(t) of some initial | i state ψ(t ) . Quantum mechanics is fully predictive [3] in the sense that initial | 0 i conditions and knowledge of the potential occupied by the particle is enough to fully specify the state of the particle for all future times.1 In the early twentieth century, Erwin Schr¨odinger derived an equation specifies how the instantaneous change in the wavefunction d ψ(t) depends on the system dt | i inhabited by the state in the form of the Hamiltonian. In this formulation, the eigenstates of the Hamiltonian play an important role, since their time-evolution is easy to calculate (i.e. they are stationary). A well-established method of solution, after the entire eigenspectrum of Hˆ is known, is to decompose the initial state into this eigenbasis, apply time evolution to each and then reassemble the eigenstates. That is, 1In the analysis below, we consider only the position of a particle, and not any other quantum property such as spin. 2 D.V. Perepelitsa n=∞ ψ(t) = exp [ iE t/~] n ψ(t ) n (1) | i − n h | 0 i| i n=0 X This (Hamiltonian) formulation works in many cases. -
Symmetry Conditions on Dirac Observables
Proceedings of Institute of Mathematics of NAS of Ukraine 2004, Vol. 50, Part 2, 671–676 Symmetry Conditions on Dirac Observables Heinz Otto CORDES Department of Mathematics, University of California, Berkeley, CA 94720 USA E-mail: [email protected] Using our Dirac invariant algebra we attempt a mathematically and philosophically clean theory of Dirac observables, within the environment of the 4 books [10,9,11,4]. All classical objections to one-particle Dirac theory seem removed, while also some principal objections to von Neumann’s observable theory may be cured. Heisenberg’s uncertainty principle appears improved. There is a clean and mathematically precise pseudodifferential Foldy–Wouthuysen transform, not only for the supersymmeytric case, but also for general (C∞-) potentials. 1 Introduction The free Dirac Hamiltonian H0 = αD+β is a self-adjoint square root of 1−∆ , with the Laplace HS − 1 operator ∆. The free Schr¨odinger√ Hamiltonian 0 =1 2 ∆ (where “1” is the “rest energy” 2 1 mc ) seems related to H0 like 1+x its approximation 1+ 2 x – second partial sum of its Taylor expansion. From that aspect the early discoverers of Quantum Mechanics were lucky that the energies of the bound states of hydrogen (a few eV) are small, compared to the mass energy of an electron (approx. 500 000 eV), because this should make “Schr¨odinger” a good approximation of “Dirac”. But what about the continuous spectrum of both operators – governing scattering theory. Note that today big machines scatter with energies of about 10,000 – compared to the above 1 = mc2. So, from that aspect the precise scattering theory of both Hamiltonians (with potentials added) should give completely different results, and one may have to put ones trust into one of them, because at most one of them can be applicable. -
Unit 1 Old Quantum Theory
UNIT 1 OLD QUANTUM THEORY Structure Introduction Objectives li;,:overy of Sub-atomic Particles Earlier Atom Models Light as clectromagnetic Wave Failures of Classical Physics Black Body Radiation '1 Heat Capacity Variation Photoelectric Effect Atomic Spectra Planck's Quantum Theory, Black Body ~diation. and Heat Capacity Variation Einstein's Theory of Photoelectric Effect Bohr Atom Model Calculation of Radius of Orbits Energy of an Electron in an Orbit Atomic Spectra and Bohr's Theory Critical Analysis of Bohr's Theory Refinements in the Atomic Spectra The61-y Summary Terminal Questions Answers 1.1 INTRODUCTION The ideas of classical mechanics developed by Galileo, Kepler and Newton, when applied to atomic and molecular systems were found to be inadequate. Need was felt for a theory to describe, correlate and predict the behaviour of the sub-atomic particles. The quantum theory, proposed by Max Planck and applied by Einstein and Bohr to explain different aspects of behaviour of matter, is an important milestone in the formulation of the modern concept of atom. In this unit, we will study how black body radiation, heat capacity variation, photoelectric effect and atomic spectra of hydrogen can be explained on the basis of theories proposed by Max Planck, Einstein and Bohr. They based their theories on the postulate that all interactions between matter and radiation occur in terms of definite packets of energy, known as quanta. Their ideas, when extended further, led to the evolution of wave mechanics, which shows the dual nature of matter -
Relational Quantum Mechanics and Probability M
Relational Quantum Mechanics and Probability M. Trassinelli To cite this version: M. Trassinelli. Relational Quantum Mechanics and Probability. Foundations of Physics, Springer Verlag, 2018, 10.1007/s10701-018-0207-7. hal-01723999v3 HAL Id: hal-01723999 https://hal.archives-ouvertes.fr/hal-01723999v3 Submitted on 29 Aug 2018 HAL is a multi-disciplinary open access L’archive ouverte pluridisciplinaire HAL, est archive for the deposit and dissemination of sci- destinée au dépôt et à la diffusion de documents entific research documents, whether they are pub- scientifiques de niveau recherche, publiés ou non, lished or not. The documents may come from émanant des établissements d’enseignement et de teaching and research institutions in France or recherche français ou étrangers, des laboratoires abroad, or from public or private research centers. publics ou privés. Noname manuscript No. (will be inserted by the editor) Relational Quantum Mechanics and Probability M. Trassinelli the date of receipt and acceptance should be inserted later Abstract We present a derivation of the third postulate of Relational Quan- tum Mechanics (RQM) from the properties of conditional probabilities. The first two RQM postulates are based on the information that can be extracted from interaction of different systems, and the third postulate defines the prop- erties of the probability function. Here we demonstrate that from a rigorous definition of the conditional probability for the possible outcomes of different measurements, the third postulate is unnecessary and the Born's rule naturally emerges from the first two postulates by applying the Gleason's theorem. We demonstrate in addition that the probability function is uniquely defined for classical and quantum phenomena. -
Motion of the Reduced Density Operator
Motion of the Reduced Density Operator Nicholas Wheeler, Reed College Physics Department Spring 2009 Introduction. Quantum mechanical decoherence, dissipation and measurements all involve the interaction of the system of interest with an environmental system (reservoir, measurement device) that is typically assumed to possess a great many degrees of freedom (while the system of interest is typically assumed to possess relatively few degrees of freedom). The state of the composite system is described by a density operator ρ which in the absence of system-bath interaction we would denote ρs ρe, though in the cases of primary interest that notation becomes unavailable,⊗ since in those cases the states of the system and its environment are entangled. The observable properties of the system are latent then in the reduced density operator ρs = tre ρ (1) which is produced by “tracing out” the environmental component of ρ. Concerning the specific meaning of (1). Let n) be an orthonormal basis | in the state space H of the (open) system, and N) be an orthonormal basis s !| " in the state space H of the (also open) environment. Then n) N) comprise e ! " an orthonormal basis in the state space H = H H of the |(closed)⊗| composite s e ! " system. We are in position now to write ⊗ tr ρ I (N ρ I N) e ≡ s ⊗ | s ⊗ | # ! " ! " ↓ = ρ tr ρ in separable cases s · e The dynamics of the composite system is generated by Hamiltonian of the form H = H s + H e + H i 2 Motion of the reduced density operator where H = h I s s ⊗ e = m h n m N n N $ | s| % | % ⊗ | % · $ | ⊗ $ | m,n N # # $% & % &' H = I h e s ⊗ e = n M n N M h N | % ⊗ | % · $ | ⊗ $ | $ | e| % n M,N # # $% & % &' H = m M m M H n N n N i | % ⊗ | % $ | ⊗ $ | i | % ⊗ | % $ | ⊗ $ | m,n M,N # # % &$% & % &'% & —all components of which we will assume to be time-independent. -
Quantum Theory of the Hydrogen Atom
Quantum Theory of the Hydrogen Atom Chemistry 35 Fall 2000 Balmer and the Hydrogen Spectrum n 1885: Johann Balmer, a Swiss schoolteacher, empirically deduced a formula which predicted the wavelengths of emission for Hydrogen: l (in Å) = 3645.6 x n2 for n = 3, 4, 5, 6 n2 -4 •Predicts the wavelengths of the 4 visible emission lines from Hydrogen (which are called the Balmer Series) •Implies that there is some underlying order in the atom that results in this deceptively simple equation. 2 1 The Bohr Atom n 1913: Niels Bohr uses quantum theory to explain the origin of the line spectrum of hydrogen 1. The electron in a hydrogen atom can exist only in discrete orbits 2. The orbits are circular paths about the nucleus at varying radii 3. Each orbit corresponds to a particular energy 4. Orbit energies increase with increasing radii 5. The lowest energy orbit is called the ground state 6. After absorbing energy, the e- jumps to a higher energy orbit (an excited state) 7. When the e- drops down to a lower energy orbit, the energy lost can be given off as a quantum of light 8. The energy of the photon emitted is equal to the difference in energies of the two orbits involved 3 Mohr Bohr n Mathematically, Bohr equated the two forces acting on the orbiting electron: coulombic attraction = centrifugal accelleration 2 2 2 -(Z/4peo)(e /r ) = m(v /r) n Rearranging and making the wild assumption: mvr = n(h/2p) n e- angular momentum can only have certain quantified values in whole multiples of h/2p 4 2 Hydrogen Energy Levels n Based on this model, Bohr arrived at a simple equation to calculate the electron energy levels in hydrogen: 2 En = -RH(1/n ) for n = 1, 2, 3, 4, . -
Quantum Field Theory*
Quantum Field Theory y Frank Wilczek Institute for Advanced Study, School of Natural Science, Olden Lane, Princeton, NJ 08540 I discuss the general principles underlying quantum eld theory, and attempt to identify its most profound consequences. The deep est of these consequences result from the in nite number of degrees of freedom invoked to implement lo cality.Imention a few of its most striking successes, b oth achieved and prosp ective. Possible limitation s of quantum eld theory are viewed in the light of its history. I. SURVEY Quantum eld theory is the framework in which the regnant theories of the electroweak and strong interactions, which together form the Standard Mo del, are formulated. Quantum electro dynamics (QED), b esides providing a com- plete foundation for atomic physics and chemistry, has supp orted calculations of physical quantities with unparalleled precision. The exp erimentally measured value of the magnetic dip ole moment of the muon, 11 (g 2) = 233 184 600 (1680) 10 ; (1) exp: for example, should b e compared with the theoretical prediction 11 (g 2) = 233 183 478 (308) 10 : (2) theor: In quantum chromo dynamics (QCD) we cannot, for the forseeable future, aspire to to comparable accuracy.Yet QCD provides di erent, and at least equally impressive, evidence for the validity of the basic principles of quantum eld theory. Indeed, b ecause in QCD the interactions are stronger, QCD manifests a wider variety of phenomena characteristic of quantum eld theory. These include esp ecially running of the e ective coupling with distance or energy scale and the phenomenon of con nement. -
Introductory Lectures on Quantum Field Theory
Introductory Lectures on Quantum Field Theory a b L. Álvarez-Gaumé ∗ and M.A. Vázquez-Mozo † a CERN, Geneva, Switzerland b Universidad de Salamanca, Salamanca, Spain Abstract In these lectures we present a few topics in quantum field theory in detail. Some of them are conceptual and some more practical. They have been se- lected because they appear frequently in current applications to particle physics and string theory. 1 Introduction These notes are based on lectures delivered by L.A.-G. at the 3rd CERN–Latin-American School of High- Energy Physics, Malargüe, Argentina, 27 February–12 March 2005, at the 5th CERN–Latin-American School of High-Energy Physics, Medellín, Colombia, 15–28 March 2009, and at the 6th CERN–Latin- American School of High-Energy Physics, Natal, Brazil, 23 March–5 April 2011. The audience on all three occasions was composed to a large extent of students in experimental high-energy physics with an important minority of theorists. In nearly ten hours it is quite difficult to give a reasonable introduction to a subject as vast as quantum field theory. For this reason the lectures were intended to provide a review of those parts of the subject to be used later by other lecturers. Although a cursory acquaintance with the subject of quantum field theory is helpful, the only requirement to follow the lectures is a working knowledge of quantum mechanics and special relativity. The guiding principle in choosing the topics presented (apart from serving as introductions to later courses) was to present some basic aspects of the theory that present conceptual subtleties. -
An S-Matrix for Massless Particles Arxiv:1911.06821V2 [Hep-Th]
An S-Matrix for Massless Particles Holmfridur Hannesdottir and Matthew D. Schwartz Department of Physics, Harvard University, Cambridge, MA 02138, USA Abstract The traditional S-matrix does not exist for theories with massless particles, such as quantum electrodynamics. The difficulty in isolating asymptotic states manifests itself as infrared divergences at each order in perturbation theory. Building on insights from the literature on coherent states and factorization, we construct an S-matrix that is free of singularities order-by-order in perturbation theory. Factorization guarantees that the asymptotic evolution in gauge theories is universal, i.e. independent of the hard process. Although the hard S-matrix element is computed between well-defined few particle Fock states, dressed/coherent states can be seen to form as intermediate states in the calculation of hard S-matrix elements. We present a framework for the perturbative calculation of hard S-matrix elements combining Lorentz-covariant Feyn- man rules for the dressed-state scattering with time-ordered perturbation theory for the asymptotic evolution. With hard cutoffs on the asymptotic Hamiltonian, the cancella- tion of divergences can be seen explicitly. In dimensional regularization, where the hard cutoffs are replaced by a renormalization scale, the contribution from the asymptotic evolution produces scaleless integrals that vanish. A number of illustrative examples are given in QED, QCD, and N = 4 super Yang-Mills theory. arXiv:1911.06821v2 [hep-th] 24 Aug 2020 Contents 1 Introduction1 2 The hard S-matrix6 2.1 SH and dressed states . .9 2.2 Computing observables using SH ........................... 11 2.3 Soft Wilson lines . 14 3 Computing the hard S-matrix 17 3.1 Asymptotic region Feynman rules . -
Identical Particles
8.06 Spring 2016 Lecture Notes 4. Identical particles Aram Harrow Last updated: May 19, 2016 Contents 1 Fermions and Bosons 1 1.1 Introduction and two-particle systems .......................... 1 1.2 N particles ......................................... 3 1.3 Non-interacting particles .................................. 5 1.4 Non-zero temperature ................................... 7 1.5 Composite particles .................................... 7 1.6 Emergence of distinguishability .............................. 9 2 Degenerate Fermi gas 10 2.1 Electrons in a box ..................................... 10 2.2 White dwarves ....................................... 12 2.3 Electrons in a periodic potential ............................. 16 3 Charged particles in a magnetic field 21 3.1 The Pauli Hamiltonian ................................... 21 3.2 Landau levels ........................................ 23 3.3 The de Haas-van Alphen effect .............................. 24 3.4 Integer Quantum Hall Effect ............................... 27 3.5 Aharonov-Bohm Effect ................................... 33 1 Fermions and Bosons 1.1 Introduction and two-particle systems Previously we have discussed multiple-particle systems using the tensor-product formalism (cf. Section 1.2 of Chapter 3 of these notes). But this applies only to distinguishable particles. In reality, all known particles are indistinguishable. In the coming lectures, we will explore the mathematical and physical consequences of this. First, consider classical many-particle systems. If a single particle has state described by position and momentum (~r; p~), then the state of N distinguishable particles can be written as (~r1; p~1; ~r2; p~2;:::; ~rN ; p~N ). The notation (·; ·;:::; ·) denotes an ordered list, in which different posi tions have different meanings; e.g. in general (~r1; p~1; ~r2; p~2)6 = (~r2; p~2; ~r1; p~1). 1 To describe indistinguishable particles, we can use set notation. -
Vibrational Quantum Number
Fundamentals in Biophotonics Quantum nature of atoms, molecules – matter Aleksandra Radenovic [email protected] EPFL – Ecole Polytechnique Federale de Lausanne Bioengineering Institute IBI 26. 03. 2018. Quantum numbers •The four quantum numbers-are discrete sets of integers or half- integers. –n: Principal quantum number-The first describes the electron shell, or energy level, of an atom –ℓ : Orbital angular momentum quantum number-as the angular quantum number or orbital quantum number) describes the subshell, and gives the magnitude of the orbital angular momentum through the relation Ll2 ( 1) –mℓ:Magnetic (azimuthal) quantum number (refers, to the direction of the angular momentum vector. The magnetic quantum number m does not affect the electron's energy, but it does affect the probability cloud)- magnetic quantum number determines the energy shift of an atomic orbital due to an external magnetic field-Zeeman effect -s spin- intrinsic angular momentum Spin "up" and "down" allows two electrons for each set of spatial quantum numbers. The restrictions for the quantum numbers: – n = 1, 2, 3, 4, . – ℓ = 0, 1, 2, 3, . , n − 1 – mℓ = − ℓ, − ℓ + 1, . , 0, 1, . , ℓ − 1, ℓ – –Equivalently: n > 0 The energy levels are: ℓ < n |m | ≤ ℓ ℓ E E 0 n n2 Stern-Gerlach experiment If the particles were classical spinning objects, one would expect the distribution of their spin angular momentum vectors to be random and continuous. Each particle would be deflected by a different amount, producing some density distribution on the detector screen. Instead, the particles passing through the Stern–Gerlach apparatus are deflected either up or down by a specific amount.