International Paint Ltd is part of AkzoNobel, the Netherlands based Blue Grey M400 Dove Grey M319 Westmorland Grey J300 Silver Grey H001 Flotilla H000 Hemp J071 company serving customers throughout the world with coatings and chemicals. Colour Card Our most popular colours Pearl Grey H017 Pebble Grey J019 Mist Grey F000 Dawn Grey E000 Blued White C000 Gardenia B052
International Paint Ltd, Stoneygate Lane, Felling Oyster White E019 Vanilla B088 Stone D053 Cream S089 Yellow S041 Cream B108 Gateshead, NE10 0JY United Kingdom
Call: +44 (0)191 469 6111 Fax: +44 (0)191 495 2003
Golden Yellow B169 Yellow B134 Canary C065 Golden Yellow B183 Buff E143 Primrose G164 Send an email: [email protected]
Visit our website: www.international-marine.com
Sign up to keep up to date with our latest news visit www.international-marine.com/signup Sand B125 Beige H108 Orange E229 Light Orange D243 Pure Orange D259 Funnel Orange Y74R Follow us 10 0 Mink D104 Red Buff G194 International Orange D260 Signal Red C287 Ensign Red B295 Teak M231 The contents of this card are for information purposes only and no representation or warranty of any kind is given in relation to any of the information or opinions expressed in it. Whilst we have made all reasonable efforts to ensure that statements appearing in this leaflet are accurate, we disclaim all liability and responsibility arising from any reliance placed on the information, advice and opinions contained in this leaflet.
and International and all products mentioned in this publication are trademarks Brown T229 Brown R244 Red Brown P275 Copper Beech M254 Red L274 Red M273 ® of, or are licensed to, AkzoNobel. © AkzoNobel, 2012
All products supplied and technical advice or recommendations given are subject to our standard Conditions of Sale. Colours shown for illustrative purposes only. All of the colours illustrated on this card are available worldwide from our core range of cosmetic finishes, which Ultramarine Blue C922 Aircraft Blue B941 Azure Blue E938 Blue B969 Ocean Blue E992 Caribbean Blue C935 French Blue C921 Blue B921 features acrylic polysiloxane, acrylic polyurethane, epoxy, modified acrylic and traditional alkyd gloss technologies. Blue S651 Blue C967 Blue F967 Blue E967 Blue C919 Signal Blue B953 Signal Blue D913 Cornflower B571
Sky Blue B915 Light French Blue C901 Lagoon D531 Seaspray D320 Arctic Blue S419 Light Blue B419 Light Blue S439 Arctic Blue E480
Notes: • When placing orders, please quote the product name, number, colour and shade reference, Turquoise Blue E533 Blue Green K534 Opal Green B601 Green B558 Tropical Blue D441 Serpentine G301 Green N404 Signal Green L549 e.g. Interthane®990, Ocean Blue E992.
• Whilst great care is taken to match the colours on this card exactly, there may be slight variations in the colour of product supplied.
Colours black and white, not illustrated on this card, Green G609 Yew Q879 Green P467 Spray Green E323 Light Green F321 Reseda Green M404 Light Olive Green L389 Grass Green K528 are also available.
To view our colour cards online please visit www.international-marine.com/colour
Estuary Green F445 Eau-de-Nil F384 Pastel Green E322 Light Green E302 Silver Sage E020 Light Grey H725 Dark Admiralty Grey R764 Mid Graphite T806
Light Admiralty Grey F379 Cloud Blue O835 Surf Grey F684 Silver Grey K766 French Grey J724 Haze Grey K705 Storm Grey K724 Thundercloud M000 Dark Grey L764 Grey M745
All products supplied and technical advice or recommendations given are subject to our standard Conditions of Sale.
Marine Paint Guide
Updated: 16/12/14
1. Definitions and abbreviations
TOLERANCES
The numerical information quoted on marine product datasheets has been derived from laboratory test data obtained under controlled conditions for the products described. Whilst every effort has been made to ensure accuracy, this information will be subject to minor variations obtained in normal manufacturing tolerances, and any fluctuations in ambient conditions during the application and curing periods.
GLOSS LEVEL
Typical gloss values have been determined in accordance with ISO 2813:1994/ Corr 1:1997 using a 60° gloss head or, for North America, ASTM-D-523. The categories used in the data sheet are:
Finish (sheen) Gloss (60°) head Matt 0-15 Eggshell 16-30 Semi-gloss 31-60 Gloss 61-85 High gloss >85
In practice, the level of sheen and surface finish will be dependent upon a number of factors, including application and the condition of the surface to be overcoated.
International Paint T +44 (0)191 469 6111 Stoneygate Lane F +44 (0)191 438 3711 Felling www.international-marine.com 1 Tyne and Wear NE10 0JY
Registered office 26th Floor, Portland House, Bressenden Place, London, SW1E 5BG, England. Registered number 00063604 DRY FILM THICKNESS (DFT)
The measured thickness of the final dried film applied to the substrate.
WET FILM THICKNESS (WFT)
The initial thickness of the wet coating applied to the substrate.
VOLUME SOLIDS
The volume solids figure given on the product data sheet is the percentage of the wet film, which remains as the dry film, and is obtained from a given wet film thickness under specified application method and conditions. These figures have been determined under laboratory conditions using a modification of the test method described in ISO 3233:1998/Corr 1:1999 – Determination of Volume Solids by Measurement of Dry Film Density. The modification is technically equivalent involving the use of slightly smaller glass slides. For North America, volume solids are measured by ASTM-D-2697 (1986) which determines the volume solids of a coating using the recommended dry film thickness of the coating quoted on the product data sheet, and a specified drying schedule at ambient temperature, i.e. 7 days at 25°C + 1°C.
DRYING TIME
The drying times quoted in the product data sheet have been determined in the laboratory using a typical dry film thickness, the ambient temperature quoted in the relevant product data sheet, and the appropriate test method, i.e.
Touch Dry (ISO 1517 - 1973) - The surface drying state of a coating when Ballotini (small glass spheres) can be lightly brushed away without damaging the surface of the coating.
International Paint T +44 (0)191 469 6111 Stoneygate Lane F +44 (0)191 438 3711 Felling www.international-marine.com 2 Tyne and Wear NE10 0JY
Registered office 26th Floor, Portland House, Bressenden Place, London, SW1E 5BG, England. Registered number 00063604 Hard Dry (ISO 9117-1990) - The condition of the film in which it is dry throughout its thickness, as opposed to that condition in which the surface of the film is dry but the bulk of the coating is still mobile.
This through drying state is determined by the use of a “mechanical thumb” device “in situ” at the temperature quoted.
In North America the Touch Dry, Hard Dry and Re-coat times are determined in accordance with ASTM-D-1680 (1995) using sections 7.5, 7.7 and 7.8 respectively.
The drying times achieved in practice may show some slight fluctuation, particularly in climatic conditions where the substrate temperature differs significantly from the ambient air temperature and because of variations in practical dry film thickness.
OVERCOATING INTERVAL
The product data sheet gives both a “minimum” and a “maximum” overcoating interval and the figures quoted at the various temperatures are intended as guidelines, consistent with good painting practices. Certain terms require elaboration as follows:
Minimum
The “minimum overcoating time” quoted is an indication of the time required for the coating to attain the necessary state of dryness and hardness to allow the application of a further coat of paint without the development of any film irregularities such as lifting or loss of adhesion of the first coat (ASTM-D-1640). It assumes:
(i) the coating has been applied at the normal recommended thickness.
(ii) environmental conditions both during and after application were as recommended for
International Paint T +44 (0)191 469 6111 Stoneygate Lane F +44 (0)191 438 3711 Felling www.international-marine.com 3 Tyne and Wear NE10 0JY
Registered office 26th Floor, Portland House, Bressenden Place, London, SW1E 5BG, England. Registered number 00063604 that particular coating, especially in respect of temperature, relative humidity and ventilation.
(iii) the paint used for overcoating is suitable for that purpose.
(iv) an understanding of the “method of application”. For example, if a coating can be applied by both brush and spray it is expected that overcoating may be carried out more rapidly if sprayed and it is the “lowest” figure that is quoted.
If the above conditions are not met, the quoted minimum overcoating times are liable to variation and will invariably have to be extended.
Maximum
The “maximum overcoating time” indicates the allowable time period within which overcoating should take place in order to ensure acceptable intercoat adhesion is achieved.
Extended
Where an “extended” overcoating time is stated, the anticipated level of intercoat adhesion can only be achieved if:
(i) the coating has been applied in accordance with good painting practices and at the specified film thickness.
(ii) the aged coating has the “intended” surface characteristics required for long term overcoatability. For example, an over- applied epoxy MIO may not have its usual “textured” surface and will no longer be overcoatable after ageing unless it is abraded.
International Paint T +44 (0)191 469 6111 Stoneygate Lane F +44 (0)191 438 3711 Felling www.international-marine.com 4 Tyne and Wear NE10 0JY
Registered office 26th Floor, Portland House, Bressenden Place, London, SW1E 5BG, England. Registered number 00063604 (iii) the coating to be overcoated must be intact, tightly adherent, clean, dry and free from all contaminants. For example, the leached layer on an antifouling coating is usually porous and friable and must be removed to provide the necessary surface for overcoating.
(iv) coatings having a glossy surface which could have a detrimental effect on the adhesion of subsequent coats should be treated by light surface abrasion, sweep blasting, or other suitable processes which will not cut through or detract from the performance of the underlying coating.
(v) in some situations, and with specific products, it may be necessary to high pressure fresh water wash prior to overcoating.
It should be recognised that the level of intercoat adhesion obtained is also dependent upon the chemistry of the “topcoat”. By their nature, primers or undercoats will have inherently better adhesion than finish coats.
The measurement of ultimate “adhesion strength” can often be a difficult process, and interpretation of results can be subjective. Excellent adhesion does not necessarily mean good performance, nor does relatively poor adhesion necessarily mean poor performance.
Although the adhesion of coatings applied to aged / cured coatings may be deemed satisfactory for the specified end use, actual numerical values obtained for adhesion may be less than with coatings applied within “minimum / short” overcoating intervals.
FLASH POINT
The minimum temperature at which a product, when confined in a Setaflash closed cup, must be heated for the vapours emitted to ignite momentarily in the presence of a
International Paint T +44 (0)191 469 6111 Stoneygate Lane F +44 (0)191 438 3711 Felling www.international-marine.com 5 Tyne and Wear NE10 0JY
Registered office 26th Floor, Portland House, Bressenden Place, London, SW1E 5BG, England. Registered number 00063604 flame (ISO 3679:1983). In North America Flash Point is determined in accordance with ASTM-D-3278 (1996).
VOLATILE ORGANIC COMPOUND (VOC)
VOC content is the weight of volatile organic compounds which participate in atmospheric photochemical reactions for litre of paint. Legislative requirements differ from country to country, and from region to region, and are constantly being reviewed. Values quoted for VOC on the product data sheet are calculated from the product formulation or have been determined practically in the laboratory using one of the following published test methods:-
UK-PG6/23(92), Appendix 3
This test method was published in February 1992, by the UK Department of the Environment as part of the Secretary of State’s Guidance Note (PG6/23(92)), issued as a guide to local authorities on the appropriate techniques to control air pollution, in order to achieve the objectives laid down in the Environmental Protection Act 1990. The method described in Appendix 3 includes guidance on the method of meeting VOC of coatings, as applied to demonstrate compliance with Clause 19 of the Guidance Note.
USA - EPA Federal Reference Method 24
The Environmental Protection Agency (EPA), published procedures for demonstration of compliance with VOC limits under Federal Reference Method 24 “The Determination of Volatile Matter Content, Density, Volume Solids and Weight Solids of Surface Coatings”. This method was originally published in the Federal Register in October 1980, and coded 40 CFR, Part 60, Appendix A, and amended in 1992 to incorporate instructions for dealing with multi-component systems, and a procedure for the quantitative determination of VOC exempt solvent.
International Paint T +44 (0)191 469 6111 Stoneygate Lane F +44 (0)191 438 3711 Felling www.international-marine.com 6 Tyne and Wear NE10 0JY
Registered office 26th Floor, Portland House, Bressenden Place, London, SW1E 5BG, England. Registered number 00063604 It is recommended that users check with local agencies for details of current VOC regulations, to ensure compliance with any local legislative requirements when proposing the use of any coating.
EU Council Directive 1999/13/EC
The purpose of this directive is to prevent or reduce the direct and indirect effects of the emission of volatile organic compounds into the environment, mainly into air, and the potential risks to human health. In essence the directive sets emission limits for coatings users (installations), these differ by application and for old/new installations. For the purpose of the Directive a Volatile Organic Compound (VOC) is defined as:
“Any organic compound having at 293.15 K a vapour pressure of 0.01 kPa or more, or having a corresponding volatility under the particular conditions of use.”
International Paint T +44 (0)191 469 6111 Stoneygate Lane F +44 (0)191 438 3711 Felling www.international-marine.com 7 Tyne and Wear NE10 0JY
Registered office 26th Floor, Portland House, Bressenden Place, London, SW1E 5BG, England. Registered number 00063604 WORKING POT LIFE
The maximum time during which the product supplied as separate components should be used after they have been mixed together at the specified temperature.
The values quoted have been obtained from a combination of laboratory tests, and application trials, and refer to the time periods under which satisfactory coating performance will be achieved.
Application of any product after the working pot life has been exceeded will lead to inferior product performance, and must NOT be attempted, even if the material in question appears liquid in the can.
SHIPPING WEIGHT
The shipping weights quoted are typical values and refer to the total weight of the product supplied plus the weight of the can and are for guidance only. They will vary according to the specific colour. These weights are quoted for individual components and do not take into account any additional packaging weight attributable to cartons, etc. Factory supplied material will show differences to the figures quoted on the product Technical Data Sheet.
SHELF LIFE
The shelf life quoted on the product datasheets is generally a conservative value, and it is probable that the coating can be applied without any deterioration in performance after this period has elapsed. Exceeding the shelf life of a product does not necessarily render it unusable. However, if the specified shelf life has been exceeded, it is recommended that the condition of the material is checked before any large scale application is undertaken using materials beyond the quoted shelf life. If this occurs, contact International for advice on how to progress.
International Paint T +44 (0)191 469 6111 Stoneygate Lane F +44 (0)191 438 3711 Felling www.international-marine.com 8 Tyne and Wear NE10 0JY
Registered office 26th Floor, Portland House, Bressenden Place, London, SW1E 5BG, England. Registered number 00063604
Marine Paint Guide Updated : 12/10/04 2. Surface Preparation
INTRODUCTION Proper surface preparation is essential for the success of any marine coating scheme. The importance of removing oil, grease, old coatings and surface contaminants (such as millscale and rust on steel, and zinc salts on zinc containing primers or galvanised surfaces) cannot be over emphasised.
The performance of any paint coating is directly dependent upon the correct and thorough preparation of the surface prior to coating. The most expensive and technologically advanced coating system will fail if the surface preparation is incorrect or incomplete.
STEEL Some of the various methods of surface preparation of steel are briefly described below. For more explicit details and recommendations please refer to full specifications, such as:
1. International Standard ISO 8504-1:2000, which is in three parts: • ISO 8504-1:2000 Preparation of steel substrates before application of paints and related products – Surface preparation methods – Part 1: General principles. • ISO 8504-2:2000 Preparation of steel substrates before application of paints and related products – Surface preparation methods – Part 2: Abrasive blast-cleaning. • ISO 8504-3:1993 Preparation of steel substrates before application of paints and related products – Surface preparation methods – Part 3: Hand- and power-tool cleaning.
2. The Society for Protective Coatings (SSPC), Pittsburgh, PA, USA. Full range of surface preparation standards.
3. International Standards ISO 8501-1:1988 and ISO 8501-2:1994. Preparation of steel substrate before application of paints and related products – visual assessment of surface cleanliness.
4. Shipbuilding Research Association of Japan – Standard for the Preparation of Steel Surfaces prior to Painting (“JSRA Standard – 1984”).
5. International Marine Hydroblasting Standards.
6. International Marine Slurryblasting Standards.
7. International Marine Pictorial Abrasive Sweep Blasting Standards – for shop primed surfaces.
8. International Marine Pictorial Abrasive Sweep Blasting Standards – for previously coated surfaces.
REMOVAL OF The performance of marine coatings applied to steel is significantly CONTAMINANTS affected by the condition of the steel substrate immediately prior to painting. The principal factors affecting performance are:
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a) surface contamination including salts, oils, grease, drilling and cutting compounds,
b) Rust and millscale, c) Surface profile.
The main objective of surface preparation is to ensure that all such contamination is removed to reduce the possibility of initiating corrosion and to create a surface profile that allows satisfactory adhesion of the coating to be applied. Recommended procedures are outlined in International Standard ISO 8504:2000 and SSPC SP Specifications.
It is essential to remove all soluble salts, oil, grease, drilling and cutting compounds and other surface contaminants prior to further surface preparation or painting of the steel.
Oil and Grease
The presence of even a very thin layer of oil or grease can destroy or seriously impair adhesion of paint. Solvents (e.g. paraffin or white spirit) can be used to dissolve the grease, but the problem then becomes one of completely removing the solution of oil in the solvent. Drying with cloths is only effective if two or three treatments are carried out, each time drying with clean cloths. A single treatment is rarely satisfactory and can aggravate the situation by spreading the oil or grease over an area greater than that originally affected.
Commercial chemical cleaners such as water rinsable detergents are available but before they are used it must be determined that they will not adversely attack the painted surface. It is usual to apply sufficient cleaner to incorporate the contaminant, leave for a few minutes and then hose down thoroughly with fresh water. It is imperative that all traces of the cleaner should be removed before painting. When cleaning old tanks which have contained crude oil before overcoating, it is likely that a combination of steam cleaning and degreasing will be necessary.
Salts
Sea salts are fairly easily dissolved by fresh water. Surfaces should therefore be thoroughly hosed with fresh water.
The major difficulty however is not the solubility of the salt but surface irregularities and porosity. Fine hair cracks in a paint surface can hold salt quite tenaciously. Spent and spongy antifouling films also prevent easy salt removal.
For this reason high pressure fresh water washing should always be used to flush out all the salt from the surface cracks and crevices. If high pressure fresh water washing is not available then normal fresh water hosing with thorough scrubbing should be employed. This is time consuming, but necessary, as to paint over salt residues will certainly lead to detachment or blistering of the fresh paint.
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Weed Fouling
The term “weed fouling” is meant to encompass not only those organisms which are readily recognised as marine weeds, but also the algal slimes which are often only visible when wet.
They are most effectively removed by high pressure fan jet fresh water washing, the pressure being in the range 140-350 bar (2000-5000 p.s.i.).
If high pressure fresh water washing equipment is not available, scraping, hosing and scrubbing should be employed. Results are not as good as high pressure fresh water washing but with care and attention a satisfactory result can be achieved. It must be remembered that with manual methods the final phase of the operation should be to thoroughly hose the surface with fresh water.
Shell Fouling
Acorn barnacles, tubeworms, etc. are much more difficult to dislodge from a surface than weed. Quite often high pressure water washing will not remove acorn barnacles, although other species such as goose necked barnacles, tubeworms and hydrozoa may be removed. In all cases the first step should be to determine the effect of high pressure fresh water cleaning.
Those organisms which resist removal by high pressure fresh water washing should be removed by scraping, although in many cases it will be found that either shell bases remain or the underlying paint coatings are broken. After scraping, the surface should be re-washed to clear away all the shell splinters, barnacle bases, cement residues, tissue remnants and soluble material.
HIGH PRESSURE The operation consists of directing a high pressure fresh water jet at the FRESH WATER surface. As with sweep blasting the effect will depend on the nature and CLEANING condition of the surface and also on the pressure of water. Distance of the nozzle Fan Jet Lance or Rocky Washer from the surface will also have an effect. Usually for removing surface contamination or weed fouling, pressures in the range 140-350 bar (2000-5000 p.s.i.) are employed. Shell fouling and antifouling paint leached layers may resist the water jet. See the section “Shell Fouling”.
HAND TOOL Loosely adhering millscale, rust and old paint coatings may be removed CLEANING from steel by hand wire brushing, sanding, scraping and chipping. However, these methods are incomplete, and always leave a layer of tightly adhering rust on the steel surface. Methods for hand tool cleaning are described in SSPC-SP2 and should be to ISO 8501-1:1988 grade St2-B, C or D and also in the JSRA Standard – 1984, this standard is particularly useful for Newbuilding projects.
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POWER TOOL Generally more effective and less laborious than hand tool cleaning for CLEANING the removal of loosely adhering millscale, paint and rust. However, power tool cleaning will not remove tightly adhering rust and millscale. Power wire brushes, impact tools (such as needle guns), grinders and sanders are all commonly used, the cutting actions of grinding discs would be the preferred choice. Care should be taken, particularly with power wire brushes, not to polish the metal surface as this will reduce the key for the subsequent paint coating. Methods are described in SSPC-SP3 and SSPC-SP11 and should be to ISO 8501-1:1988 grade St3-B, C or D. SSPC-SP11 describes a degree of surface profile which can be achieved by power tool cleaning. JSRA standard – 1984 describes power tool cleaning methods of particular use in Newbuilding projects.
BLAST CLEANING By far the most effective method for removal of millscale, rust and old coatings, using abrasives such as garnet, grit or shot under high pressure.
The grade of blasting suitable for a particular coating specification depends on a number of factors, the most important of which is the type of coating system selected.
The primary standard used in marine product datasheets is ISO 8501- 1:1988, preparation of steel substrate before application of paints and related products – visual assessment of surface cleanliness. This standard represents a slight extension of the old Swedish Standard (SIS 05 59 00), which was developed by the Swedish Corrosion Institute, in co- operation with the American Society for Testing & Materials (ASTM), and the Society for Protective Coatings (SSPC), USA, and is already used on a worldwide scale. The JSRA Standard 1984 is the principal standard quoted for Japanese Newbuilding projects.
In North American marine product datasheets the nearest equivalent SSPC specification has been quoted. It is recognised that the SSPC and ISO standards are not identical, and as a consequence worldwide/North American product datasheets may show grade Sa2½ (ISO 8501-1:1988) as equivalent to SSPC-SP6, (commercial blast cleaning), whilst others will be equivalent to SSPC-SP10 (near white metal). The selection of these blast cleaning grades have been assessed using a number of factors including coating type, performance expectation, and in-service conditions.
As a general principle, where products are recommended for immersion or aggressive atmospheric conditions the blasting standard required will be to Sa2½ (ISO 8501-1:1988) or SSPC-SP10, however, when products are recommended for general atmospheric exposure the blasting standard required will be Sa2 (ISO 8501-1:1988) or SSPC-SP6.
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Prior to blasting, steelwork should be degreased and all weld spatter removed. If salts, grease or oil are present on the surface it will appear to be removed by the blasting process, but this is not the case. Although not visible, the contamination will still be present as a thin layer, and will affect the adhesion of subsequent coatings. Weld seams, metal slivers and sharp edges revealed by the blasting process should be ground down, as paint coatings tend to run away from sharp edges, resulting in thin coatings and reduced protection. Weld spatter is almost impossible to coat evenly, in addition to often being loosely adherent, and it is a common cause of premature coating failure.
The surface profile obtained during blasting is important, and will depend on the abrasive used, the air pressure and the technique of blasting. Too low a profile may not provide a sufficient key for coating, while too high a profile may result in uneven coverage of high, sharp peaks possibly leading to premature coating failure, particularly for thin film coatings such as blast primers. The following table gives a brief guide to typical roughness profiles obtained using various types of abrasive.
Type of Abrasive Mesh Size Max. Height of Profile
Very fine sand 80 37 microns (1.5 mils)
Coarse sand 12 70 microns (2.8 mils)
Iron shot 14 90 microns (3.6 mils)
Typical non metallic - 75-100 microns (3-4 mils) “copper slag” 1.5-2.0mm grain size
Iron grit No. G16 12 200 microns (8.0 mils)
Grit Blasting
When large areas of a vessel’s hull or tanks are cleaned by grit blasting a variety of steel surface conditions will be found. Previously coated or superficially corroded steel, can be readily cleaned to Sa2½. However, cleaning heavily corroded or pitted surfaces is more difficult and Sa2½ may not be practically achievable.
The effectiveness of various types and particle sizes of abrasives has been examined in carefully controlled practical trials and the most efficient grit particle size for corroded steel is found to be mineral slag with a range of 0.3-1.5mm (12-60 mils).
After grit blasting, surface dust must be removed. In open conditions, blowing with dry compressed air from the blasting kettle is satisfactory. Tanks however require careful cleaning normally using vacuum cleaners to remove all grit and dust particles.
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Spot Blasting
This localised abrasive cleaning is often carried out on the outside of the hull of a vessel where patchy corrosion has occurred. It will effectively remove corrosion and yield surfaces cleaned to Standards described in ISO 8501-1:1998. In practice there are some precautions which need to be taken in order to prevent subsequent breakdown:
The surrounding paint film (particularly epoxy coatings) can be undercut by the abrasive particles and the edges around the blasted patch loosened from the steel surface. If this occurs the loose edges must be removed by thorough scraping or feathering, using a rotary disc.
The surrounding paint will be peppered by stray abrasive particles and the protective value of the scheme in the vicinity may be destroyed. In making good the coating system it is necessary to treat the area of damage around the blasted area.
Damage can also occur in the areas between patches if the jet of abrasive particles is played across the surface. Blasting should be discontinued whilst moving from one patch to the next. Any damage which is sustained in this way should be made good as described above.
It is recommended that whenever possible the patches to be blasted should be defined by “marking in” the boundaries.
Sweep Blasting
Sweep blasting is the treatment of a surface by the sweeping of a jet of abrasive across the surface. Its effectiveness depends on the nature and condition of the surface, the type and particle size of the abrasive and above all the skill of the operator. a) Light Sweeping
Rapid sweep blasting will clean the surface of contamination or loose coatings. It may be used to etch the surface of an existing hard and tough coating to improve the adhesion of the following coat. Superficial corrosion such as that found on weathered shop primed steel also responds well to this type of treatment, but more deep seated corrosion is not removed. Where such removal is required, Sa2½ by ‘full blasting’ should be specified. Particle size of the abrasive is important, a fine abrasive is most suitable when the paint surface under treatment is not to be destroyed (grit or sand particle size 0.2mm-0.5mm, 8-20 mils). b) Hard/Heavy Sweeping
The old coatings are removed to shop primer or bare steel. The surface standard of steel exposed will vary but all standards, nevertheless, are satisfactory provided rust scale has been removed.
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Hard/heavy sweeping is used for example to upgrade otherwise unsuitable vessels to higher performance coating systems.
Particle size considerations are the same as those described in the sections dealing with blasting/grit blasting.
c) Sweeping of Shop Primers
At Newbuilding it is often necessary to remove the shop primer coat (fully or partially) prior to subsequent overcoating. The surface preparation standard to be achieved is agreed and is to one of : JSRA Standard 1984 or International Marine Pictorial Abrasive Sweep Blasting Standard
WET ABRASIVE Wet abrasive blasting uses a slurry of water and abrasive rather than dry BLASTING/SLURRY abrasive alone. This has the advantage that the hazards of dust and BLASTING associated health problems are largely overcome.
A further advantage is that when wet blasting old, well rusted surfaces, many of the soluble corrosion products in the pits of the steel will be washed out, which will greatly improve the performance of the applied coating system. However, a disadvantage of this technique is that the cleaned steel begins to rust rapidly after blasting.
The use of corrosion inhibitors is not recommended when wet blasting areas which will be exposed to marine environments.
Where wet blasted surfaces have been allowed to corrode, they should be mechanically cleaned or preferably sweep blasted, to remove the corrosion prior to painting.
HYDROBLASTING Hydroblasting is a technique for cleaning surfaces, which relies entirely on the energy of water striking a surface to achieve its cleaning effect. Abrasives are NOT used in hydroblasting systems. Consequently the problems caused by dust pollution and by the disposal of spent abrasives are eliminated. Two different hydroblasting operating pressures are commonly encountered.
• High pressure hydroblasting, operating at pressures between 680 bar (10,000 p.s.i.) and 1,700 bar (25,000 p.s.i.).
• Ultra high pressure hydroblasting, operating at pressures above 1700 bar (25,000 p.s.i.).
The terms hydroblasting, hydrojetting and water jetting essentially mean the same thing, with all being used to describe the same process. There can be confusion however over the difference between simple water washing and hydroblasting. To clarify the situation, International Paint have adopted the following commonly accepted definitions.
Low Pressure Water Washing: Operates at pressures less than 68 bar (1,000 p.s.i.).
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High Pressure Water Washing: Operates at pressures between 68-680 bar (1,000-10,000 p.s.i.).
High Pressure Hydroblasting: Operates at pressures between 680-1,700 bar (10,000-25,000 p.s.i.).
Ultra High Pressure Hydroblasting: Operates at pressures above 1,700 bar (25,000 p.s.i.) with most machines operating in the 2,000-2,500 bar range (30,000-36,000 p.s.i.).
The International Marine Hydroblasting Standards have been prepared using ultra high pressure hydroblasting equipment. This standard however is also applicable to surfaces produced by a whole range of hydroblasting pressures, providing the equipment used is capable of cleaning to the visual standard depicted.
The steel surfaces produced by hydroblasting do NOT look the same as those produced by dry abrasive blasting, or slurryblasting. This is because water on its own cannot cut, or deform steel in the same way as abrasives. Hydroblasted surfaces therefore tend to look dull, even before they “flash rust”. In addition steel, with active corrosion pitting, shows a mottled appearance after hydroblasting. Mottling occurs when the corrosion products are washed out of the pits, leaving a bright patch, and the surrounding areas are left a dull grey, brown to black colour. This pattern is the reverse of that left by abrasive blasting, where anodic pits are often dark, due to corrosion products not being entirely removed, and the surrounding areas are bright. “Flash rusting”, i.e. light oxidation of the steel, which occurs as hydroblasted steel dries off, will quickly change this initial appearance.
When flash rusting is too heavy for coating application, it may be removed or reduced by brushing with a hard bristle brush, or by washing down with high pressure fresh water. High pressure washing, at pressures above 68 bar (1,000 p.s.i.) using either the rotational nozzles, or fan jet lances of the hydroblasting equipment itself is the preferred method. It will cause the area to re-rust, but it is possible to reduce the degree of flash rusting from heavy to light using this method. Hand wire or bristle brushing to remove heavy flash rusting may be acceptable for small areas, but will generally produce an inadequate surface. Mechanical rotary wire brushing can however produce acceptable surfaces for large areas.
When large areas are hydroblasted, flash rusting which obscures the original blast standard may occur, before an inspection can be carried out. Establishing the required standard by blasting a small test area prior to the main blast may help, providing the rest of the job is blasted to the same standard. Methods of ensuring the rest of the job is blasted to the same standard will vary from project to project.
The use of corrosion inhibitors is not recommended when wet blasting areas which will be exposed to marine environments.
The temperature of steel substrates can rise during the hydroblasting process. There are two reasons for this:
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a) Compression of the water to reach hydroblasting pressure will create a temperature rise in the water itself,
b) the velocity of the water striking the steel will impart energy to it as heat. This temperature rise can be substantial and may help hydroblasted surfaces dry off more quickly, with a corresponding reduction in the severity of flash rusting.
An important property of the hydroblasting process is that it can emulsify and remove oil and grease from a surface as it is blasted. However, this does not preclude the need for proper degreasing procedures as specified in SSPC-SP1, prior to hydroblasting.
Hydroblasting will not produce a surface profile, although the process can eventually erode steel and result in metal loss. The surface profile exposed after hydroblasting will have been produced by earlier surface preparation work, or by corrosion. For most coating schemes, International Paint will accept a profile in the 50 to 100 microns range.
NON FERROUS Galvanised Steel METALS The surface should be clean, dry and grease free (see under Steel – Degreasing). Degreasing of most galvanised surfaces requires some effort to obtain a clean surface. Any white zinc corrosion products should be removed by high pressure fresh water washing, or fresh water washing with scrubbing. When using the preferred method of surface preparation, i.e. sweep blasting, it is still advisable to fresh water wash to remove soluble zinc salts. Many coatings based on non-saponifiable polymers can be applied directly to galvanised surfaces prepared in this way.
When sweep blasting is not possible, then an acid etch solution or etch primer should be used to passivate the surface and provide a key for further paint coatings. Details of coatings which can be applied to sweep blasted galvanised steel and of suitable etch solutions and primers can be obtained from International Paint.
When steel has been treated with a passivating treatment immediately after galvanising, then this must either be allowed to weather off over a period of several months exterior exposure or be abraded before application of a coating. In general etch treatments have no effect on fresh materials of this type.
Other Non Ferrous Metals/Aluminium (Abrading)
The surface should be clean, dry and grease free (see under Steel – Removal of Contaminants). Any corrosion salts should be removed by light abrasion and water washing. The cleaned surface should then be prepared by abrasive blasting at low pressure, using aluminium oxide or garnet abrasive. The specified surface profile should be achieved.
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Aluminium (Acid Etching)
International Paint do not normally recommend the use of acid etch primers, however in non-immersed areas they may be used.
Before painting, apply one thin coat of a proprietary etch primer to provide a key for further coats. A colour change from pale yellow to green/brown should occur. If this reaction does not take place, adhesion will be found to be poor. The surface should be scraped clean, and treated with a proprietary aluminium pre-treatment solution, and the acid etch primer then re-applied.
SAFETY Always carefully read and completely follow the safety procedures and CONSIDERATIONS instructions recommended by manufacturers of surface preparation devices, application equipment, media or products and the job site safety measures.
Prior to use, obtain and consult the Material Safety Data Sheet for this product concerning health and safety information. Read and follow all precautionary notices on the Material Safety Data Sheet and container label. If you do not fully understand these warnings and instructions or if you cannot strictly comply with them, do not use this product. Proper ventilation and protective measures must be provided during application and drying to keep solvent vapour concentrations within safe limits and to protect against toxic or oxygen deficient hazards. Actual safety measures are dependent on application methods and work environment.
These are general statements to alert you to the importance of specific warnings and instructions on individual products. These statements are not intended to be specific warnings or advice.
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Marine Paint Guide Updated : 12/10/04 3. Paint Application
INTRODUCTION The object in applying a coating is to provide a film which will give protection and/or decoration to the surface being painted. The success of any paint application will be governed by a number of parameters, including:
• Surface preparation
• Film thickness applied
• Methods of application
• Conditions during application
These are discussed below.
SURFACE The importance of surface preparation to the success of a coating PREPARATION system cannot be over emphasised. See Section 2 – Surface Preparation.
FILM THICKNESS An adequate film thickness is essential for the success of any coating system. Under-application will generally result in premature failure for obvious reasons. However, the old adage of “the more paint, the better” can be equally dangerous. The gross over-application of coatings can lead either to solvent entrapment and subsequent loss of adhesion, cracking or to splitting of primer coats. With the majority of coatings, the limits of acceptable dry film thickness allow for reasonable practical variation, but the specified film thickness should always be the target during application.
The actual dry film thickness recommended for a particular surface will depend on the type of coating system being used and the nature of the surface. Recommended dry film thicknesses for individual products are given on the product datasheets.
DRY FILM If a coating is applied to a steel substrate previously blast cleaned with THICKNESS abrasive grit or shot, the measurement of its dry film thickness is more MEASUREMENT complicated than that of a coating applied to a smooth steel substrate.
The measurement results are influenced by the profile of the abrasive blasted surfaces which change from point-to-point.
International Paint recommends that all measuring instruments are calibrated on smooth steel in accordance with ISO 2808 (1997), Method 6, or SSPC-PA2.
When thin films are being applied care should be taken to consider the surface profile whereby some of the coating is being used to fill in the profile. For shop primers and coatings of less than 25 microns, measurement over the blasted surfaces is not meaningful. For recommended measurement techniques, consult International Paint.
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METHOD OF The accepted methods of applying the coatings described in the APPLICATION datasheets are by brush, roller, conventional (air) spray, conventional (pressure pot) spray and airless spray. The advantages and dis- advantages of each method are briefly discussed below.
BRUSH APPLICATION Brush application should always be undertaken using good quality natural fibre or synthetic brushes of the appropriate size compatible with the product being applied. However, this application technique is relatively slow, but is generally used for coating small areas with decorative paints and for surface tolerant primers, where good penetration of rusty steel substrates is required. It is particularly suitable for the application of stripe coats and for coating complex areas where the use of spray methods would lead to considerable losses due to overspray and associated dry spray problems.
However, most high build coatings are designed for application by airless spray, and high film build will generally not be achieved by brush application. In general, twice as many coats will have to be applied by brush to achieve a similar build when compared to airless spray.
Brush application requires considerable care when applying non- convertible coatings over one another, e.g. chlorinated rubber over chlorinated rubber, or vinyl on top of vinyl. In these cases, the solvents in the wet coat readily redissolve the previously dry bottom coat. Even a mild degree of the “brushing-out” normally given to topcoats will cause pick-up of the previous coat and result in a very poor finish. Even, light strokes should be used in these circumstances, covering a particular area with one or two brush strokes, and on no account working the bristles into the previous coat.
ROLLER Roller application is faster than brush on large, even surfaces and can be APPLICATION used for the application of most decorative paints.
However, control of film thickness is not easily achieved. As with brush application, high film build will generally not be attained. Care must be taken to choose the correct roller pile length and material, depending on the type of paint and degree of roughness of the surface.
Typically, phenolic core rollers should be used, fitted with a smooth to medium pile roller cover. The roller cover should be pre-washed to remove any loose fibres prior to use.
AIR SPRAY This is a widely accepted, rapid method of coating application in which (CONVENTIONAL) paint is atomised by a low pressure air stream. “Conventional” air spray equipment is relatively simple and inexpensive, but it is essential to use the correct combination of air volume, air pressure and fluid flow to give good atomisation and a paint film free from defects. If conventional spray application is not controlled correctly, large losses of paint can result from overspray and rebound from the surface in addition to problems such as poor flow, sagging and pinholing. The major disadvantage of conventional air spray is that high build coatings can generally not be applied by this method as most paints have to be thinned to a suitable viscosity for satisfactory atomisation, and so lose their high build properties.
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AIR SPRAY Pressure feed tanks or “pressure pots” are commonly used in association (PRESSURE POT) with low pressure air stream (conventional) spray guns, to provide a means of delivering paint at a regulated pressure from a tank, through a fluid hose to a spray gun.
Several manufacturers produce suitable equipment (e.g. DeVilbiss, Binks) which operate in the following manner.
A length of air hose from the compressed air supply is connected to an air pressure regulator on the tank lid. Some air bleeds through the regulator at an adjusted pressure into the tank but most of the air passes the regulator and reaches the spray gun through a second length of air hose to atomise the paint as it is sprayed. The air which has entered the tank forces paint from it to the gun through a length of fluid hose. Paint in the tank can be prevented from settling by means of an agitator driven by hand or by a compressed air motor.
Air spray (pressure pot) is often used in the application of zinc silicate coatings and is recommended in cases where large quantities of paint are to be applied, and their use instead of a suction or gravity feed cup attached to the gun significantly reduces waste time in constant refilling and also enables the gun to be turned to any angle to coat objects effectively without spilling paint. Pressure feed tanks up to 20 litres (5 US gallon) capacity can be used and allow ease of movement around the workplace.
AIRLESS SPRAY Unlike air spray techniques, air is not mixed with the coating to form a spray, hence the name airless spray. Atomisation is achieved by forcing the paint through specially designed nozzles or tips, by hydraulic pressure. The required hydraulic pressure is usually generated by an air powered pump having a high ratio of fluid pressure to air input pressure. Pumps with ratios between 20:1 and 60:1 (or greater) are available, perhaps the most common being around 45:1.
The chief advantages of airless spray are:
1. High build coatings can be applied without thinning.
2. Very rapid application is possible, giving an economic advantage.
3. Compared to conventional spray, overspray and bounce-back are reduced, leading to reduced losses of material and less dust and fume hazards.
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The tips, through which the paint is forced to achieve atomisation, are precisely constructed from tungsten carbide. The atomised “fan” is produced by a slot ground on the face of the orifice. Various orifice sizes together with different slot angles are available. The choice of tip is governed by the fluid pressure required to give atomisation coupled with the orifice size needed to give the correct fluid delivery rate. The fluid delivery rate controls the film thickness applied per pass of the spray gun.
Different slot angles produce spray fans of different widths. The selection of a particular fan width depends on the shape and size of the structure to be painted. Choice of fan width is also related to orifice size – for the same orifice size, the paint applied per unit area will be less the wider the spray fan.
Airless spray equipment normally operates at fluid line pressures up to 352kg/cm2 (5,000 p.s.i.), and should always be used in accordance with the manufacturer’s operating instructions and safety precautions.
Generally, tips with an orifice size 0.23-0.33mm (9-12 thou) are suitable for coatings to be applied at approximately 50 microns (2 mils) wet film thickness. Tip sizes from 0.33-0.48mm (13-19 thou) for wet films of 100- 200 microns (4-8 mils) and 0.48-0.79mm (19-31 thou) for 200 microns (8 mils) and above. Heavy duty mastics which are applied at very high film thicknesses may need tips with orifices as large as 1.02-1.52mm (40-60 thou).
There are several designs of tips available, the choice of which depends upon the finish required, the ease of application and ease of clearing blockages from the tips. With some products, the decorative effect achieved with airless spray is not as good as can be achieved by conventional spray. However, airless spray application is now widely accepted as a convenient method of applying marine coatings.
Some paints are designed to be applied at high film thicknesses. Others, such as conventional finishing paints are not. The data sheet will show a typical film thickness. If over-application occurs sagging and running can result. To avoid over-application the recommendations for each product shown on the appropriate data sheet should be followed.
The area sprayed should be within a comfortable distance of the operator to avoid a long traverse of the jet or arcing of the gun.
It is essential that due regard be paid to safety because an airless spray gun ejects a paint stream under very high pressure, and injury can be caused if the jet is directed at someone close by. The skin can be easily penetrated.
For high solids, high viscosity paints, it may be necessary to apply using twin-feed equipment, where the two compounds are heated and circulated separately and only mixed near the spray tip. A typical example of such equipment is the Graco Hydra-Cat. Various models exist and the manufacturers instructions must be followed in conjunction with advise given by International Paint relating to the equipment set-up for specific products.
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CONDITIONS When applying marine coatings, the most important factors to consider DURING are the condition of the substrate, the surface temperature, and the APPLICATION atmospheric conditions at the time of painting.
Paint application should only be carried out when good atmospheric conditions and clement weather prevail.
Painting should not be undertaken;
• when the air temperature falls below the lower drying or curing limit of the coating,
• during fog or mist conditions or when rain or snow is imminent,
• when the surface to be painted is wet with condensation or when condensation can occur during the initial drying period of the paint.
During the night steel temperatures fall. They rise again during the day but there is always a lag in movement of steel temperature compared to the atmospheric condition, so condensation on the steel surface is possible. Condensation will occur if the steel temperature is below the dew point of the atmosphere.
Borderline Conditions
Bad weather is a familiar problem to those using marine coatings. Relative humidity itself rarely creates a problem. Most paints will tolerate high humidities, but humidity should not be permitted to lead to condensation on the surface being painted. In order to determine whether or not a surface is wet, the steel temperature should be measured using a surface temperature thermometer and the dew point calculated after measurement of humidity with a hygrometer. Paint application should not take place when steel temperature is less than 3°C (5°F) above the dew point.
Paint should not be applied when surfaces are affected by rain or ice. Some two component paints (for example certain epoxy coatings) should not be applied at low temperatures as curing may be retarded.
Extreme Conditions
Generally, extreme conditions refers to ambient temperatures below 5°C (41°F) or above 40°C (104°F).
Below 5°C (41°F) the curing of coatings, such as traditional two component epoxies, slows down dramatically and for some paints curing stops altogether. International Paint’s product range contains certain epoxy and polyurethane coatings specifically formulated for use at temperatures below 5°C. Consult International Paint. Other marine coatings are not so severely affected; chlorinated rubbers and vinyls are quite suitable for use at temperatures below 0°C (32°F) provided that the surface is clean and free from ice or frost.
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At the other extreme of 40°C (104°F) and above, the drying and curing of paints is rather rapid and care should be taken to avoid dry spray. This is caused by the too rapid loss of solvent from paint droplets between the spray nozzle and the surface. It can be avoided by:-
(i) Keeping the spray gun at the minimum suitable distance from the work piece, spraying consistently at 90° to the surface being painted.
(ii) Adding thinners, if necessary, up to a maximum of 5% by volume.
In conditions of high temperature, techniques must be adopted to prevent defects such as voids, pinholes, bubbles and poor coverage due to the over rapid evaporation of solvent. However, provided that good standards of workmanship are maintained, it is normally possible to satisfactorily apply most International Marine Coatings products on to steel substrates up to 65°C (149°F). Consult International Paint for specific product guidance.
SAFETY Always carefully read and completely follow the safety procedures and CONSIDERATIONS instructions recommended by manufacturers of surface preparation devices, application equipment, media or products and the job site safety measures.
Prior to use, obtain and consult the Material Safety Data Sheet for products being used concerning health and safety information. Read and follow all precautionary notices on the Material Safety Data Sheet and container label. If you do not fully understand these warnings and instructions or if you cannot strictly comply with them, do not use this product. Proper ventilation and protective measures must be provided during application and drying to keep solvent vapour concentrations within safe limits and to protect against toxic or oxygen deficient hazards. Actual safety measures are dependant on application methods and work environment.
These are general statements to alert you to the importance of specific warnings and instructions on individual products. These statements are not intended to be specific warnings or advice.
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Onboard Maintenance Painting Guide Contents
Introduction and planning: 3
Surface preparation: 4 - 5
Paint application: 6 - 8
Health and safety: 9 - 10
Marine Coatings 2 All products supplied and technical recommendations given are subject to our conditions of sale. OBM Painting Guide Introduction
Onboard maintenance (OBM) Once these steps have been taken, it is time to look at the critical vessel areas and the paint specification. of coating systems is important The coating specification to be applied will be dependent in maintaining the cosmetic upon the vessel area being treated and this will have an appearance of your vessel, impact on planning the work. It is recommended that the and planning Introduction vessel be sectioned off into small, manageable areas. minimising the onset of corrosion and ensuring that your vessel stays in good condition which reduces the costs and time of scheduled dry dockings.
This guide contains information on planning and carrying out OBM work efficiently and safely.
Planning Surface preparation
Maintenance painting onboard and alongside in port should be planned to maximise the efficient use of resources both An OBM planning meeting in terms of crew time and in the volume of paint used. Key factors to consider are: A well planned maintenance programme that involves evaluation of the entire process, good record-keeping, and s 4IME BETWEEN COATS IN A MULTI COAT SPECIlCATION use of high performance coating materials can mean less s 4IME BEFORE ACCESS TO PAINTED AREAS IS POSSIBLE time and money spent on OBM in the long run. The technical data sheets for the products to be The success of any coating system relates directly to the used provide the following information: level of care and attention paid to the fundamentals of good painting practice, particularly surface preparation, mixing s 4OUCH DRY TIME of coating materials, and, of course, their application. s (ARD DRY TIME s -INIMUM AND MAXIMUM OVERCOATING TIME
Furthermore, the paint locker should be well ordered, the s 7ORKING LIFE POT LIFE FOR TWO COMPONENT PRODUCTS n POT Paint application racks and shelves clearly labelled by product name, and life, in practical terms, is the time from combining the good stock rotation should be followed. Outdated, worn, components of a two component product to the point and poorly maintained equipment for preparation and at which the mixed paint is no longer usable) application can dramatically reduce the success of OBM s %QUIPMENT CLEANERS painting.
Here is a simple checklist of good practices for improving onboard maintenance. s 0ERFORM AN AUDIT OF EQUIPMENT AND INVEST IN NEW equipment as needed. s #ARRY OUT AN INVENTORY OF THE PAINT NOTING THE AGE coating type, and condition of the stock. s %NSURE THAT A COPY OF THE /"- PAINT SPECIlCATION IS KEPT onboard in an easily accessible and well-known place. Health and safety 3 Surface preparation
The single most important s Steel preparation n &OR /"- )NTERNATIONAL recommends that a standard of at least St2 thorough function which can influence hand and power tool cleaning is achieved for bare steel areas. The existing coating should be taken back to a paint performance is the quality sound edge and the edges should be “feathered” back
Introduction and planning Introduction of the surface preparation. The using a combination of manual methods:
importance of removing oil, s Hard scraping or slicing n THIS IS CARRIED OUT WITH various types of scraper. Scrapers are useful for grease, old coatings, rust and removing loose material. other surface contaminants s Chipping hammers or chisels n CHIPPING CAN cannot be over stressed. be carried out using a wide variety of hammers or chisels, best results are obtained if chipping is followed by secondary preparation such as wire The following process is recommended: brushing.
Freshwater wash s n TO REMOVE ALL SALT CONTAMINATION s Wire brushing can remove loose contamination, This is best achieved using something like a fan jet but it is ineffective at removing scale and deep lance or a power washer if available seated corrosion.
Surface preparation s Degrease n TO REMOVE ALL SURFACE GREASE AND OIL 4HIS is usually done using rags or brushes soaked in solvent. If a painted surface is to be degreased without being damaged, a solvent must be chosen which will not dissolve the paint film. Paint application Hard scraping
Freshwater washing Health and safety Marine Coatings 4 All products supplied and technical recommendations given are subject to our conditions of sale. OBM Painting Guide Power tool methods of surface preparation For both rotary wire brushing and rotary discing, the surface must not be polished and it is essential that a Power tools used for cleaning fall into two basic categories surface profile is created. n ROTARY CLEANING TOOLS AND IMPACT CLEANING TOOLS s Clean down n 4HE PREPARED AREA SHOULD HAVE ANY
residual dust, paint flakes and debris removed by and planning Introduction s Rotary wire brushing using “braided” wire wheels Radial brushes are used for preparing awkward areas brushing or vacuuming. Paint application should begin as soon as possible after cleaning to prevent SUCH AS CORNERS OR WELD SEAMS #UP BRUSHES ARE MORE often used for preparing large areas. deterioration of the prepared surface. s Rotary discing cleaning of a surface is achieved by coated abrasive discs attached to angle grinders or by using abrasive flap wheels attached to straight or in-line tools. Surface preparation
Rotary discing
Rotary wire brushes Paint application Health and safety 5 Paint application
Paint mixing Brush application
Before use, paints should be mixed well, following the s "RUSHES SHOULD NOT BE DIPPED INTO THE PAINT MORE THAN instructions on the technical data sheet. half the length of their bristles, the aim is to load the brush with enough paint to get some work done, but
Introduction and planning Introduction s 4HINNING n THINNING OF PAINT IS NOT RECOMMENDED &OLLOW not too much so the paint drips and splatters. the guidelines on the technical data sheet. s 4HE APPLIED PAINT SHOULD SPREAD EVENLY USING SMOOTH s &ILM THICKNESS n IT IS IMPORTANT TO APPLY THE SPECIlED steady strokes then be smoothed by light parallel wet film thickness. This should be measured using a strokes to eliminate irregularities. comb gauge. s /N mAT VERTICAL SURFACES IT IS BEST TO lNALLY LAY OFF THE paint in a vertical direction because this will reduce the tendency of the paint to run or sag.
s !PPLICATORS SHOULD EITHER BE ADVISED TO APPLY A SINGLE “thick” coat or multiple thin coats which can be applied when the paint is touch dry if the area is accessible.
s 0ARTICULAR ATTENTION SHOULD BE PAID IN ENSURING THAT THE
Surface preparation applied paint is brushed into the bottom of pitted areas of steel and that the edges of nuts, etc are well coated.
7ET lLM THICKNESS SHOULD BE MEASURED WITH A COMB GAUGE
Brush selection
Application by brush is recommended for patch priming and repair work to ensure good wetting of the substrate. This is essential when painting over manually prepared surfaces. Flat and round ended paint brushes Paint application s 4HE CHOICE OF BRUSH WILL DEPEND UPON THE APPLICATION required and the quality of finish to be achieved.
s &LAT SQUARE END BRUSHES OFTEN CALLED WALL BRUSHES ARE used on flat areas. Angular cut ‘sash’ brushes 2” - 3” (5cm - 8cm) wide are used on narrow surfaces, and round or elliptical section brushes are used on irregular shapes such as nuts and bolts.
s "RUSHES WITH ANGLED HEADS AND LONG HANDLES ARE USED for painting the backs of stiffening bars and other The brush should be held like a pencil inaccessible areas in tanks. Health and safety Marine Coatings 6 All products supplied and technical recommendations given are subject to our conditions of sale. OBM Painting Guide Roller selection s 2OLLERS ARE USEFUL FOR APPLYING PAINT TO LARGE mAT AREAS such as tank tops, vertical sides, walkways and deck areas. Introduction and planning Introduction s ! SHORT BRISTLED BRUSH IS MORE PRACTICAL FOR BADLY PITTED and rough steel, because paint can be worked into the profile of the steel. s 2OLLER APPLICATION REQUIRES LESS SKILL FROM PAINTERS THAN brush application. s 4HE MOST COMMON ROLLER FABRICS USED ARE LAMBS WOOL and mohair. Synthetic foam rollers have no role to play in the marine industry, they are prone to dissolve in the type of solvents used in heavy duty coatings and can swell and distort. s 2OLLER COVERS VARY IN DIAMETER LENGTH TYPE OF FABRIC AND fibre length. Small diameter rollers are used for areas Surface preparation of awkward or difficult access, but the most common sizes are 1½” - 2” (4 - 5cm). Length can be anything from 1” to 18” (2.5 - 46cm), but the 9” length (23cm) is most popular.
Roller application Roller application s 0ITTED AREAS SHOULD BE TOUCHED UP BY BRUSH BEFORE s 0AINT SHOULD THEN BE APPLIED TO THE SURFACE BY FORMING roller application. A @7 OR @- SHAPE IN THE AREA TO BE COATED 4HE @7 or ‘M’ shape area should then be filled by rolling back s )MMERSE THE ROLLER INTO THE PAINT TRAY ROLL IT IN THE PAINT and forth until it is covered, with finished rolling in one until fully saturated, and then roll it back and forth on the direction so that appearance is uniform. tray ramp to remove all excess material.
s )T IS DIFlCULT TO ACHIEVE HIGH THICKNESS IN SINGLE s 4HIS NOT ONLY AVOIDS THE PROBLEMS OF DRIPS AND SPLATTERS coats; multiple applications can be required to meet
but ensures that the roller is fully wetted and that air is Paint application specifications. removed from the fibre pile.
s /VER ROLLING CAN CAUSE PAINT PICK UP PARTICULARLY WITH fast drying coatings. This is often associated with serious entrapment of air.
s !N ALTERNATIVE TO USING PAINT TRAYS IS TO PUT A ROLLER GRID in the paint bucket or paint tin and work out excess material on this. This can allow the painter to work from ladders or scaffolds.
Roller sleeves Health and safety 7 Comparison table Weather conditions
The following table gives a simple comparison between s 5SUALLY IT IS NOT POSSIBLE TO PAINT WET SURFACES IF RAIN IS brush and roller paint application: forecast then exterior maintenance painting should be abandoned or suitable covering should be installed over
Introduction and planning Introduction the areas in question, condensation also needs to be avoided. Advantages Disadvantages
s #ONDENSATION IS FORMED WHEN THE STEEL TEMPERATURE IS Brush Good for small, They require lower than the atmospheric dew point; providing that complex areas more coats to THE STEEL TEMPERATURE IS AT LEAST ª# HIGHER THAN THE achieve film measured dew point then condensation is unlikely to thickness occur and painting can proceed.
Inexpensive s %XTREME WEATHER CONDITIONS CAN ALSO CAUSE PROBLEMS equipment during maintenance painting activities. Technical data sheets should be consulted during planning of any Minimal maintenance painting work: wastage s "ELOW ª# THE CURING OF TWO PACK PAINTS SUCH AS epoxies and polyurethanes can be slowed down. Surface preparation Roller Faster than They require brushing more coats to s 0AINTS WHICH DRY BY SOLVENT EVAPORATION SUCH AS ALKYDS achieve correct film thickness AND ACRYLICS CAN BE USED BELOW ª# PROVIDED THAT THE surface is free of frost and ice.
Good for large Possibility of s !BOVE ª# SOLVENT CAN EVAPORATE VERY QUICKLY WHICH flat areas uneven film can result in difficulties in brushing and rollering of paint. thickness Paint application Health and safety Marine Coatings 8 All products supplied and technical recommendations given are subject to our conditions of sale. OBM Painting Guide Health and safety
The primary source of health and The following notes give some very basic advice on health and safety when using International Marine paint: safety information is the product Material Safety Data Sheet; these Health hazards
are available for all International s /VER EXPOSURE CAN LEAD TO IRRITATION OF THE EYES AND and planning Introduction RESPIRATORY SYSTEM %XCESSIVE EXPOSURE CAN RESULT IN Marine products from: headache, nausea, dizziness and drowsiness and in extreme cases even loss of consciousness. Splashes http://www.international-marine.com/products/msds.aspx in the eye will cause discomfort and possible damage. Prolonged contact with skin can lead to skin irritation )NTERNATIONAL ALSO PUBLISHES A SECONDARY SOURCE OF HEALTH and in some cases dermatitis. and safety information in the form of simple one page safety advice sheets, which are designed to help paint Health precautions applicators, for example. s Inhalation n AVOID BREATHING VAPOURS WORK IN WELL ventilated areas and if necessary use local ventilation
methods such as respirator masks.
Marine & Protective Coatings safety advice sheet
This contains basic health, safety and environmental information that is important for the actual user of the product. It does not replace the Material Safety Data Sheet. s Eye contact n AVOID SPLASHES IN THE EYE BY WEARING Product Name: Interlac 665 Ref No: 0015
Revision Number 1 suitable safety goggles or glasses. Use/Application An alkyd cosmetic coating for use in non-immersed areas. May be applied by airless spray, conventional spray, Surface preparation brush or roller. Safety Dangers This paint contains solvents. When used or spilt it will release solvent vapours which may catch fire or explode. Skin contact Health Dangers If breathed in, solvents may cause headaches and dizziness and long term nervous system s n AVOID SKIN CONTACT BY WEARING damage. Paint in the eyes will cause irritation. Repeated splashes on the skin may cause irritation, loss of fat and skin damage (dermatitis). suitable clothing and gloves. Barrier creams are not an Control Measures Extraction/Local Extract Ventilation: When paint is used anywhere inside a confined space or area with limited ventilation on a ship or inside a building, forced extraction with fans must be used to stop solvent from creating an explosive mixture and to reduce the solvent concentration that people may breathe in. acceptable alternative to the proper choice of glove. Ignition: Cigarettes, lighters, matches, welding or cutting torches, grinding and all electrical equipment except approved spark proof lights must be kept well away from paint mixing and paint application. Personal Protective Equipment s Ingestion - whilst there is little hazard by this route Lungs (Inhalation) The sprayer and assistant should always wear a cartridge respirator. Other people who can smell paint should also wear a cartridge respirator or carbon mask unless they are sure the solvent concentration is below the national occupational exposure limit (OES). Cartridge during onboard maintenance painting, do not eat or respirators and carbon masks become less efficient with time and should be replaced periodically. (Follow respirator manufacturers recommendations). Eyes: Wear safety glasses or goggles or a face shield at all times when mixing, spraying, rolling or whilst handling paint. or brushing paint. Skin: Wear an overall with full length sleeves and legs. Wear solvent resistant ‘rubber’ gloves (long sleeve). Wear safety boots. Make sure there is no gap at wrist and ankles. Change and wash the overall as appropriate and at least twice a week. If paint is able to pass through the overall, replace + + + it. Wear a hard hat. Protect face skin with barrier cream (not petroleum jelly). Gloves should be replaced periodically. First aid Hygiene/Cleanliness: Always wash hands before eating, smoking or going to the toilet. Paint transferred from the hands to other parts of the body can cause damage. Have a shower at the end of the working day. First Aid Breathing/Dizziness: If inhaled, quickly take the person to a place with fresh air. Lie them down and keep them warm. If breathing has stopped, give them artificial respiration (the ‘kiss of life’). If s Inhalation n REMOVE THE SUFFERER TO FRESH AIR (In case of doubt seek breathing is difficult give oxygen. Seek medical attention. Medical Advice) Eyes: Give rapid assistance by holding the eyelids apart and washing with clean fresh water for at keep warm and rest. least 15 minutes. Afterwards seek medical attention (some paints stick to the eyes and need UV light to be seen and specialist cleaning to remove all traces of paint). Skin: Quickly remove clothing and wash skin with soap and water or a special skin cleaner. DO NOT use solvents (thinner/equipment cleaner). Mouth: If paint is accidentally swallowed quickly get a doctor or take the person to a hospital, DO s Eye contact n WASH WITH PLENTY OF CLEAN FRESH WATER NOT make the person vomit/be sick unless instructed to do so by medical personnel. If conscious they should drink as much water as possible. Never give anything by mouth to an unconscious person. for at least ten minutes holding the eyelids apart. Paint application Other Spillage: Put sand/earth around spills to stop them getting into drains or rivers or the sea. Absorb the paint with more sand/earth and send to a special waste dump/treatment works. Emergencies Fire: Fight fire with foam (large fires); Powder, CO2 foam (small fires). Waste Disposal Follow local regulatory requirements. s Skin contact n REMOVE ANY CONTAMINATED CLOTHING The Product Data Sheet, the Material Safety Data Sheet and the package labelling together form an integral information system about this product. Copies of the Product Important Note Data Sheet and the Material Safety Data Sheet are available from International Paint on request or from our Internet sites: http//www.international-marine.com & http//www.international-pc.com wash the skin thoroughly with a proprietary skin
CLEANSER $/ ./4 53% 3/,6%.43
Official Advisory Body Tel. No. For Advice to Doctors & Hospitals Only +44 (0)870 600 6266
Country 24 Hr. Emergency Tel. No. Country 24 Hr. Emergency Tel. No. Australia +61 (0) 1 800 807 001 Sweden 112 s Ingestion n DO NOT INDUCE VOMITING SEEK MEDICAL ADVICE WM/Interlac 665/DS Finland +358 (0) 9 471 977 Turkey +90 (0) 216 574 31 91 January 2004 Portugal +351 (0) 65 702 025 UK & Rest of World +44 (0) 191 469 6111
s General n IN ALL CASES OF DOUBT SEEK MEDICAL ATTENTION
Safety advice sheets for marine products are available from: http://www.international-marine.com/supportadvice/ safety-advice-sheets.aspx Health and safety 9 Fire and safety precautions Safety goggles Safety spectacles
s Storage n USUALLY PAINT SHOULD BE STORED IN DRY shaded conditions away from heat and ignition sources. Specific conditions can be found on individual
Introduction and planning Introduction product technical data sheets. s Ventilation n THE USE OF SUITABLE VENTILATION DURING painting operations should be promoted. s Ignition n PAINTING SHOULD ONLY BE UNDERTAKEN WHEN all naked lights and unprotected electrical equipment Fluorescent or high visibility Dust mask vest or jacket have been removed from the area. s Waste disposal n ANY WASTE SHOULD BE DEALT WITH IN accordance with prevalent local requirements.
Personal protective equipment
The following equipment should be used during onboard maintenance painting:
Surface preparation s /VERALLS s &LUORESCENT OR HIGH VISIBILITY VEST OR JACKET The following should also be available as s (EARING PROTECTION appropriate: s $UST MASK s ,IFE JACKET IF WORKING OVER WATER Safety helmet Safety boots and/or shoes s ! FALL ARREST SAFETY HARNESS AND LANYARD IF WORKING AT HEIGHT
Fall arrest safety harness Life jacket and lanyard
Gloves or gauntlets Face mask and cartridge filters Paint application
For further information:
#ALL +44 (0)191 469 6111 Fax: +44 (0)191 495 2003 Overalls Hearing protection Send an email: [email protected] Health and safety Marine Coatings 10 All products supplied and technical recommendations given are subject to our conditions of sale. OBM Painting Guide 11 International Paint Ltd is part of AkzoNobel, the Netherlands based company serving customers throughout the world with coatings and chemicals.
International Paint Ltd, Stoneygate Lane, Felling Gateshead, NE10 0JY United Kingdom
Call: +44 (0)191 469 6111 Fax: +44 (0)191 495 2003 Send an email: [email protected] Visit our website: www.international-marine.com
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Important Notes: All products supplied and technical advice or recommendations given are subject to our standard Conditions of Sale.
The contents of this leaflet are for information purposes only and no representation or warranty of any kind is given in relation to any of the information or opinions expressed in it. Whilst we have made all reasonable efforts to ensure that statements appearing in this leaflet are accurate, we disclaim all liability and responsibility arising from any reliance placed on the information, advice and opinions contained in this leaflet.
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AkzoNobel is a leading global paints and coatings company and a major producer of specialty chemicals. We supply industries and consumers worldwide with innovative products and are passionate about developing sustainable answers for our customers. Our portfolio includes well-known brands such as Dulux, Sikkens, International and Eka. Headquartered in Amsterdam, the Netherlands, we are consistently ranked as one of the leaders in the area of sustainability. With operations in more than 80 countries, our 50,000 people around the world are committed to delivering leading products and technologies to meet the growing demands of our fast-changing world.
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Marine Paint Guide Updated : 12/10/04 4. Theoretical & Practical Coverage
INTRODUCTION Estimating paint coverage is a key costing factor for both owners, vessel operators, shipyards and contractors.
On site, practical coverage is a function of many factors, with losses due to surface condition, paint distribution, application procedure, ambient weather conditions and wastage being the major factors in determining the volume of paint required for a given specification. At the initial costing stage, however, paint usage is calculated from the quoted “volume solids”.
The variety of methods used by different manufacturers to calculate, or determine “volume solids” can lead to confusion and misunderstanding, particularly when comparisons between paint systems are being made. These notes are intended to guide users and specifiers both in the practical assessment of paint losses, and in their theoretical calculations.
The technique and approach described have been adopted by International Marine Coatings throughout its worldwide organisation.
VOLUME SOLIDS The volume solids of a coating is the ratio of the volume of its non volatile components to its total wet volume.
Traditionally, this figure was calculated from the paint formulation but, since this took no account of factors such as pigment packing, solvent retention, or film contraction, the value bore little relation to that obtained in practice. Also, since these factors vary in importance between paint types, the calculated volume solids can result in an underestimation of coverage of some generic types of paint and an overestimation of others.
To overcome this problem, International Marine Coatings (and most other manufacturers) use a more practical method to establish a paint’s “volume solids”.
The method used measures the dry film thickness obtained from a measured wet film thickness, and volume solids is given by:
Volume solids = measured dft x 100 measured wft
MEASUREMENT OF The volume solids figure given in the product datasheets is the VOLUME SOLIDS IN percentage of the film obtained from a given wet film thickness under THE LABORATORY specified application method and conditions. These figures have been determined under laboratory conditions using the test method described in ISO 3233:1998/Corr 1:1999 “Determination of Volume Solids by Measurement of Dry Film Density”. For North America, volume solids are measured by ASTM D-2697 which determines the volume solids of a coating using the recommended dry film thickness of the coating quoted on the product data sheet, and a specified drying schedule at ambient temperature, i.e. 7 days at 25°C + 1°C.
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SPECIAL SITUATIONS The volume solids of such paints are determined by different means - ZINC PAINTS because they are so highly pigmented. The high pigment loading means that the dry film contains voids and the extent of the voids is dependent, to some extent, on the techniques of application. An alternative method of measuring volume solids has therefore been used to circumvent the variable void content of the dry film and thus provide a reliable figure. Details of the methods used will be given on request. In general a modification of ASTM D-2697 gives the most meaningful results and is used on International Marine Coatings Product Datasheets.
THEORETICAL The theoretical coverage can be determined from the two formulae below: COVERAGE DETERMINATION Formula 1 (Metric) FROM VOLUME SOLIDS volume solids (%) x 10 = Theoretical Coverage (m2/ltr) measured dft (in microns)
Formula 2 (US Measure)
volume solids (%) x 16.04 =Theoretical Coverage (sq.ft/US gallon) measured dft (in mils)
CONVERSION FROM THEORETICAL TO PRACTICAL COVERAGE
INTRODUCTION Estimating accurately the quantity of paint required for a particular job is complicated, since the theoretical coverage takes no account of the variable “losses” involved in converting paint in the can to a film on the chosen surfaces. Experienced contractors, with their knowledge of local conditions and their workforce etc., are best able to produce accurate estimates. These notes are intended to supplement this experience by highlighting the major areas of “losses”. Two types of loss are considered; “apparent losses” where the paint, though on the surface, does not contribute to the specified thickness, and “actual losses”, where the paint is lost or wasted.
By far the biggest discrepancy in practice results from an inability to distribute paint evenly. Measured dry film thickness at any one point is either well below or above the target thickness. It may be stipulated that the measured thickness should not fall below a minimum. Typically such guide lines take the form: “90% of readings will be at the specified thickness or better and no reading will be less than 80% of specified”. Attempts to ensure that the minimum thickness requirements are met everywhere, mean applying more paint than the calculated “theoretical”.
THE EFFECT OF When paint is applied to an abrasive blasted surface, the paint thickness BLAST PROFILE over the peaks on the surface is less than the thickness over the troughs.
However, in general, it is the thickness over the peaks which is most important in relation to performance. Therefore, it can be considered that the paint which does not contribute to this thickness is “lost in the steel profile”.
The surface profile produced by blasting and hence the extent of the paint “loss” is proportional to the dimensions of the abrasive used.
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Where steel has been blasted by small round steel shot and shop primed, the influence of the fine surface roughness on paint loss is low, but when in situ blasting is carried out, particularly with coarse grit, then the allowance necessary for paint “lost on profile” is considerable.
Typical “losses” in dry paint film thickness for given blast profiles are suggested below:
Surface Blast Profile DFT “Loss”
Steel preparation by wheelabrator 0-50 microns 10 microns using round steel shot and shop (0-2 mils) (0.4 mils) primed
Fine open blasting (80 mesh) 50-100 microns 35 microns (2-4 mils) (1.4 mils)
Coarse open blasting (12 mesh) 100-150 microns 60 microns (4.6 mils) (2.4 mils)
Old “honeycomb pitted” steel 150-300 microns 125 microns - reblasted (6-12 mils) (5 mils)
(Note: For the shop primers and holding primers which are applied at low film thickness, the concept of losses in the blast profile is not appropriate. These thin coatings are not normally considered to contribute to the total film thickness of the paint system.)
PAINT This is the loss of paint resulting from over-application when a competent DISTRIBUTION painter is attempting to achieve, with reasonable accuracy, the minimum thickness specified. The extra paint used over and above that calculated from the theoretical spreading rate is very dependent on the method of application, i.e. brush, roller or spray, and also on the type of structure being painted. A simple (uncomplicated) shape with a high proportion of flat surfaces should not incur heavy losses but if there are stiffeners or open lattice work involved then obviously losses will be high.
The following approximate over-applications are suggested as being appropriate:
Brush & Roller “Loss” Simple structures 5% Complex structures 10-15% (including stripe coat)
Spray “Loss” Simple structures 20% Complex structures 60% for single coat (including stripe coat) 40% for two coats 30% for three coats
Where open lattice work is sprayed, no realistic estimate can be made of paint distribution loss.
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In those special cases where the specification calls for a minimum thickness at all measured points, then the distribution losses would be greater than those indicated above.
ACTUAL LOSSES – There is a real loss of paint during the painting operation, i.e. paint which APPLICATION drips from a brush or roller during the transfer from the paint container to the surface to be painted. With care this can be disregarded as a significant contribution to the overall “loss”. The use of “man helps” to extend the painter’s reach however can increase this type of loss, and in an extreme case could result in a 5% loss.
When application is by spray, losses are inevitable and their magnitude is dependent on the shape of the structure being painted, together with weather conditions.
The following losses are common:
Well ventilated but confined - 5% space Outdoors in almost static air - 5–10% Outdoors in windy conditions - over 20% (obviously this figure can become exceptionally high if painting is attempted in unsuitable windy conditions)
PAINT WASTAGE Some paint wastage is inevitable; paint is spilt, a certain amount remains in discarded containers; and in the case of two component materials, mixed paint may be left beyond its pot life.
The following losses are common:
Single component paints - No more than 5% Two component paints - 5-10%
SUMMARY OF Paint losses are summarised in the table: LOSSES Loss Source of Loss Factor Apparent loss 1.1 Surface profile 1.2 Distribution Actual loss 2.1 Application losses 2.2 Wastage Factor 1.1 effectively applies to the first coat. Factors 1.1 and 1.2 should be added and 2.1 and 2.2 compounded.
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PRACTICAL Given the theoretical coverage and the preceding loss factors, it is COVERAGE possible to calculate a practical coverage. However, due to the extremely complex nature of the calculations, and variability of a number of external factors which include surface roughness, ambient climatic conditions, complexity of structure, access limitations and application methods, it is advised that these calculations are performed by professional estimators who have the appropriate knowledge and experience of the application of marine coatings under various site conditions.
The following example illustrates the calculation of practical coverage, using the loss factors described:
Example: Two coats of two pack paint are applied by spray in a confined space to a shot blasted and shop primed surface to yield a dft per coat of 125 microns/5 mils (i.e. 250 microns/10 mils total dft). Theoretical spreading rate for the paint at the recommended film thickness is 5.0m2/litre, 204 sqft/gal. What is the practical spreading rate?
Loss Consider 1st Coat: 125 microns 5 mils Factor
1.1 “Loss” due to 10 microns 0.4 surface roughness
1.2 “Loss” due to 50 microns 2.0 distribution – 40% i.e. dft x 0.4 dft 185 microns 7.4
2.1 Loss due to 9.25 microns 0.4 application – 5% i.e. dft x 0.05 dft 194.25 7.8 microns
2.2 Loss due to wastage 19.42 microns 0.8 – 10% . i.e. dft x 0.1 Total 213.67 8.6 dft microns
Extra paint used 213.67 - 125 = 8.6 – 5 = 3.6x100 88.67x100 125 5 = 71% = 71%
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Loss Consider 2nd 125 microns 5 mils Factor Coat:
1.1 “Loss” due to - - surface roughness
1.2 “Loss” due to 50 microns 2.0 distribution – 40% i.e. dft x 0.4 dft 175 microns 7.0
2.1 Loss due to 8.75 microns 0.4 application – 5% i.e. dft x 0.05 dft 183.75 7.4 microns
2.2 Loss due to 18.37 microns 0.7 wastage – 10% i.e. dft x 0.1 Total dft 202.12 8.1 microns
Extra paint used 202.12 – 125 = 8.1 – 5 = 3.1x100 77.12x100 125 5 = 62% = 62%
In other words for the two coat system (71 + 62)% = 66.5% ( 2 ) more paint has been needed than would have been calculated from the ideal spreading rate.
In the example the theoretical spreading rate is one litre of paint per 5 sq.metres or 1 US gallon of paint per 204 sq. feet. In practice 1.66 litres of paint can be expected to cover 5 sq.metres or 1.66 US gallons can be expected to cover 204 sq.feet. Practical spreading rate = 5 = 3m2/litre or 204 = 123 sq ft/US gallon 1.66 1.66
It has been customary in our industry to refer to “loss factors” i.e. the difference between theoretical spreading rate and practical spreading rate expressed as a percentage of the theoretical spreading rate. In the above example: Loss factor = 5 – 3 x 100 = 40% 5
Or = 204 – 123 x 100 = 40% 204
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Marine Paint Guide Updated : 12/10/04 5. Safety Precautions
INTRODUCTION These notes concern health and safety requirements, industrial hygiene and potential hazards involved in handling paint and thinners. They are not intended to be exhaustive and do not cover all eventualities during the application and storage of paint.
International Paint places considerable emphasis on the importance of the safe use of paint, and has developed products to cope with potential hazards.
Solvent free and WB products are available which minimise the hazards of fire and explosion and reduce the interference with people’s work in the vicinity of the painting operation.
Material Safety Datasheets on all products are available on request.
FIRE AND The majority of paints contain flammable organic solvents. As soon as a EXPLOSION paint container is opened, solvent vapours are released.
The lower explosive limit (LEL) is defined as the percentage of solvent vapour in the air which is the point where an explosion will occur if the air and solvent mixture is ignited with a spark. If the LEL is never reached, no explosion can occur. Information on LELs can be found on Product Health & Safety Datasheets.
The flash point is the lowest temperature at which a liquid gives off sufficient vapour to form an inflammable mixture in contact with air:-
- If the flash point of the paint is lower than or close to the temperature of the air there is a very considerable risk of explosion and fire. - If the flash point exceeds the air temperature then there is no risk of explosion but there is still a risk of fire.
As such, therefore, no naked flames, cigarettes, matches or other sources of ignition should be allowed near an area where paint is being applied or stored. Precautions should also be taken to avoid sparks from electrical appliances or caused by metal to metal contact. If a fire involving paint does occur:-
• Do not extinguish with water, as paint solvents float on water, and this helps to spread fire.
• Use a dry chemical, foam or CO2 extinguisher. • Protect yourself from the smoke and vapours with breathing apparatus/supplied air.
SKIN AND EYE If paint is spilled the following precautions should be taken: CONTACT • Eliminate all potential ignition sources. • Ventilate the area to remove the vapours. • Wear appropriate Personal Protective Equipment (PPE). • Do not walk into the spill.
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• Mop up all spilled paint with absorbent material, ensuring that all materials used to mop up the paint are disposed of in closed metal containers. • Arrange for proper disposal of all waste materials.
It is recommended that the following precautions should be taken to prevent paint coming into contact with the skin and eyes.
• Select sensible working clothes, that cover as much of the body as possible. • Always wear gloves and eye protection. See Material Safety Data Sheet for details on relevant PPE. • Do not touch your mouth or eyes with your gloves. • Read and observe precautionary notices on paint containers. • Eyes are particularly sensitive, so if you are splashed in the eyes, by paint or thinners, flood them immediately with fresh water for at least 15 minutes and seek medical advice immediately. • If paint should splash on your skin, remove it with soap and water. NEVER USE SOLVENT. • Remember to wash hands and rinse mouth after working with paint. • Despite these precautions paint can still come into contact with the skin or eyes (e.g. spray mist, excessive splashing), so a non-greasy barrier cream is recommended for all exposed skin.
Remember the objective is to avoid skin contact. If your clothes become soaked in paint, change them immediately and thoroughly wash the affected garments with suitable detergent and water.
INHALATION The inhalation of solvent vapours, paint vapours and dust must be avoided. Please follow the precautions listed.
• Ensure that ventilation is available to remove solvent vapours. • Check Material Safety Data Sheet for appropriate respiratory protection. • If spaces are difficult to ventilate efficiently wear an airfed hood / mask. • Spaces may require monitoring for LEL and exposure levels. • Think about where the vapours are being ventilated. They could affect other people in adjacent spaces.
Remember solvent vapours are heavier than air, they push breathable air upwards. They can flow down drains and ventilation ducts.
• If dizziness, drunkenness or headaches are experienced this could indicate you are being affected by solvent vapours. Move into fresh air and do not return until the ventilation has improved. • If breathing vapours results in the collapse of a painter medical attention should be sought immediately. Forced exercise is inadvisable. • Never enter a space where vapours have or could have accumulated without breathing apparatus.
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INHALATION OF • The mist of paint particles created when spraying should not be SPRAY MISTS inhaled. • In well ventilated spaces a dust cartridge respirator can filter out these particles of paint effectively. Cartridges can be product specific, careful selection is required. (Replace the cartridge regularly, following a regular schedule). • If ventilation is poor an airfed hood or mask is essential, if any doubt whatsoever exists wear an airfed hood/mask. • Never filter spray mists through rags wrapped over the mouth, as the rags can get soaked and allow paint to come into direct contact with the mouth. Rags are also rather inefficient filters.
INGESTION Food and drink should not be consumed, stored or prepared in areas where paint is stored or being applied.
In the case of accidental ingestion, medical attention should be obtained at once.
Safety can be assured by adopting a sensible working attitude and good housekeeping practice.
MATERIAL SAFETY Prior to use, obtain and consult the Material Safety Data Sheet for DATASHEETS products being used concerning health and safety information. Read and follow all precautionary notices on the Material Safety Data Sheet and container label. If you do not fully understand these warnings and instructions or if you can not strictly comply with them, do not use this product. Proper ventilation and protective measures must be provided during application and drying to keep solvent vapour concentrations within safe limits and to protect against toxic or oxygen deficient hazards. Take precautions to avoid skin and eye contact (i.e. gloves, goggles, face, mask, barrier creams etc.) Actual safety measures are dependent on application methods and work environment.
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Marine & Protective Coatings safety advice sheet
This contains basic health, safety and environmental information that is important for the actual user of the product. It does not replace the Material Safety Data Sheet.
Product Name: Interprime 198 Ref No: 0029
Revision Number 1 Use/Application An alkyd anticorrosive primer for use on above water areas. May be applied by airless spray, brush or roller. Safety Dangers This paint contains solvents. When used or spilt it will release solvent vapours which may catch fire or explode. Health Dangers If breathed in, solvents may cause headaches and dizziness and long term nervous system damage. Paint in the eyes will cause irritation. Repeated splashes on the skin may cause irritation, loss of fat and skin damage (dermatitis).
Control Measures Extraction/Local Extract Ventilation: When paint is used anywhere inside a confined space or area with limited ventilation on a ship or inside a building, forced extraction with fans must be used to stop solvent from creating an explosive mixture and to reduce the solvent concentration that people may breathe in. Ignition: Cigarettes, lighters, matches, welding or cutting torches, grinding and all electrical equipment except approved spark proof lights must be kept well away from paint mixing and paint spraying, rolling or brushing. Personal Protective Equipment Lungs (Inhalation) The sprayer and assistant should always wear a cartridge respirator. Other people who can smell paint should also wear a cartridge respirator or carbon mask unless they are sure the solvent concentration is below the national occupational exposure limit (OES). Cartridge or respirators and carbon masks become less efficient with time and should be replaced periodically. (Follow respirator manufacturers recommendations). Eyes: Wear safety glasses or goggles or a face shield at all times when mixing, spraying, rolling or or brushing paint. Skin: Wear an overall with full length sleeves and legs. Wear solvent resistant ‘rubber’ gloves (long sleeve). Wear safety boots. Make sure there is no gap at wrist and ankles. Change and wash the overall as appropriate and at least twice a week. If paint is able to pass through the overall, replace + + + it. Wear a hard hat. Protect face skin with barrier cream (not petroleum jelly). Gloves should be replaced periodically. Hygiene/Cleanliness: Always wash hands before eating, smoking or going to the toilet. Paint transferred from the hands to other parts of the body can cause damage. Have a shower at the end of the working day. First Aid Breathing/Dizziness: If inhaled, quickly take the person to a place with fresh air. Lie them down and keep them warm. If breathing has stopped, give them artificial respiration (the ‘kiss of life’). If (In case of doubt seek breathing is difficult give oxygen. Seek medical attention. Medical Advice) Eyes: Give rapid assistance by holding the eyelids apart and washing with clean fresh water for at least 15 minutes. Afterwards seek medical attention (some paints stick to the eyes and need UV light to be seen and specialist cleaning to remove all traces of paint). Skin: Quickly remove clothing and wash skin with soap and water or a special skin cleaner. DO NOT use solvents (thinner/equipment cleaner). Mouth: If paint is accidentally swallowed quickly get a doctor or take the person to a hospital, DO NOT make the person vomit/be sick unless instructed to do so by medical personnel. They should drink as much water as possible. Never give anything by mouth to an unconscious person. Other Spillage: Put sand/earth around spills to stop them getting into drains or rivers or the sea. Absorb the paint with more sand/earth and send to a special waste dump/treatment works. Emergencies Fire: Fight fire with foam (large fires); Powder, CO2 foam (small fires). Waste Disposal Follow local regulatory requirements.
The Product Data Sheet, the Material Safety Data Sheet and the package labelling together form an integral information system about this product. Copies of the Product Important Note Data Sheet and the Material Safety Data Sheet are available from International Coatings on request or from our Internet site: http//www.international-marine.com
Official Advisory Body Tel. No. For Advice to Doctors & Hospitals Only +44 (0)870 600 6266
Country 24 Hr. Emergency Tel. No. Country 24 Hr. Emergency Tel. No. Australia +61 (0) 1 800 807 001 Sweden 112 WM/Interprime 198/DS Finland +358 (0) 9 471 977 Turkey +90 (0) 216 574 31 91 January 2004 Portugal +351 (0) 65 702 025 UK & Rest of World +44 (0) 191 469 6111
International Paint Ltd Marine & Protective Coatings Technical Operations Safety Advice Sheet This contains basic health, safety and environmental information that is important for the actual user of the product for on board applications. It does not replace the Material Safety Data Sheet.
Product Name: Interfine 5703 Revision Number 1 NOTE: this sheet applies to the mixed paint Use/Application A high performance, single pack, low VOC acrylic modified polysiloxane finish. May be applied by airless spray, conventional spray, brush or roller Safety Dangers This paint contains solvents. When used or spilt it will release solvent vapours which may catch fire or explode. Health Dangers If breathed in, solvents may cause headaches and dizziness and long term nervous system damage. Paint in the eyes will cause severe irritation and possible damage. Repeated splashes on the skin may cause irritation, loss of fat and skin damage (dermatitis). Control Extraction/Local Extract Ventilation: When paint is used anywhere inside a confined space or area with limited ventilation on a ship or inside a building, forced Measures extraction with fans must be used to stop solvent from creating an explosive mixture and to reduce the solvent concentration that people may breathe in. Ignition: Cigarettes, lighters, matches, welding or cutting torches, grinding and all electrical equipment except approved spark proof lights must be kept well away from paint mixing and paint application. Personal Protective Equipment
Lungs (Inhalation) The sprayer and assistant should always wear a cartridge respirator. Other people who can smell paint should also wear a cartridge respirator or or carbon mask unless they are sure the solvent concentration is below the national occupational exposure limit (OES). Cartridge respirators and carbon masks become less efficient with time and should be replaced periodically. (Follow respirator manufacturers recommendations). Eyes: Wear safety glasses or goggles or a face shield at all times when mixing, spraying, rolling or brushing paint. or Skin: Wear an overall with full length sleeves and legs. Wear solvent resistant ‘rubber’ gloves (long sleeve). Wear safety boots. Make sure there is no gap at wrist and ankles. Change and wash the overall as appropriate and at least twice a week. If paint is able to pass through the overall, replace it. Wear a hard hat. Protect face skin + + + with barrier cream (not petroleum jelly). Gloves should be replaced periodically. Hygiene/Cleanliness: Always wash hands before eating, smoking or going to the toilet. Paint transferred from the hands to other parts of the body can cause damage. Have a shower at the end of the working day. First Aid Breathing/Dizziness: If inhaled, quickly take the person to a place with fresh air. Lie them down and keep them warm. If breathing has stopped, give them artificial (In case of doubt seek respiration (the ‘kiss of life’). If breathing is difficult give oxygen. Seek medical Medical Advice) attention. Eyes: Give rapid assistance by holding the eyelids apart and washing with clean fresh water for at least 15 minutes. Afterwards seek medical attention (some paints stick to the eyes and need UV light to be seen and specialist cleaning to remove all traces of paint). Skin: Quickly remove clothing and wash skin with soap and water or a special skin cleaner. DO NOT use solvents (thinner/equipment cleaner). Mouth: If paint is accidentally swallowed quickly get a doctor or take the person to a hospital, DO NOT make the person vomit/be sick unless instructed to do so by medical personnel. If conscious they should drink as much water as possible. Never give anything by mouth to an unconscious person. Other Spillage: Put sand/earth around spills to stop them getting into drains or rivers or the sea. Absorb the paint with more sand/earth and send to a special waste Emergencies dump/treatment works.
Fire: Fight fire with foam (large fires); Powder, CO2 foam (small fires). Waste Disposal Follow local regulatory requirements. The Product Data Sheet, the Material Safety Data Sheet and the package labelling together form an integral information system about this product. Copies of the Product Data Important Note Sheet and the Material Safety Data Sheet are available from International Paint on request or from our Internet sites: http//www.international-marine.com & http//www.international- pc.com
Official Advisory Body Tel. No. For Advice to Doctors & Hospitals Only +44 (0)870 600 6266 Country 24 Hr. Emergency Tel. No. Country 24 Hr. Emergency Tel. No. Country 24 Hr. Emergency Tel. No. Australia +61 (0) 1 800 680 071 Portugal +351 (0) 65 702 025 Turkey +90 (0) 216 574 31 91 Finland +358 (0) 9 471 977 Sweden 112 UK & Rest of World +44 (0) 191 469 6111
All products supplied and technical advice or recommendations given are subject to our standard Conditions of Sale.
Registered in England No. 63604 Registered Office 26th Floor, Portland House, Bressenden Place, London SW1E 5BG July 2015
Marine & Protective Coatings safety advice sheet
This contains basic health, safety and environmental information that is important for the actual user of the product. It does not replace the Material Safety Data Sheet.
Product Name: International Thinners/Cleaners Ref No: 0057
Revision Number 1 Use As a thinner or equipment cleaner. Safety Dangers These materials contain solvents. When used or spilt they will release solvent vapours which may catch fire or explode. Health Dangers If breathed in, solvents may cause headaches and dizziness and long term nervous system damage. Paint in the eyes will cause irritation. Repeated splashes on the skin may cause irritation, loss of fat and skin damage (dermatitis).
Control Measures Extraction/Local Extract Ventilation: When paint is used anywhere inside a confined space or area with limited ventilation on a ship or inside a building, forced extraction with fans must be used to stop solvent from creating an explosive mixture and to reduce the solvent concentration that people may breathe in. Ignition: Cigarettes, lighters, matches, welding or cutting torches, grinding and all electrical equipment except approved spark proof lights must be kept well away from paint mixing and paint spraying, rolling or brushing. Personal Protective Equipment Lungs (Inhalation) The sprayer and assistant should always wear a cartridge respirator. Other people who can smell paint should also wear a cartridge respirator or carbon mask unless they are sure the solvent concentration is below the national occupational exposure limit (OES). Cartridge or respirators and carbon masks become less efficient with time and should be replaced periodically. (Follow respirator manufacturers recommendations). Eyes: Wear safety glasses or goggles or a face shield at all times when mixing, spraying, rolling or or brushing paint. Skin: Wear an overall with full length sleeves and legs. Wear solvent resistant ‘rubber’ gloves (long sleeve). Wear safety boots. Make sure there is no gap at wrist and ankles. Change and wash the overall as appropriate and at least twice a week. If paint is able to pass through the overall, replace + + + it. Wear a hard hat. Protect face skin with barrier cream (not petroleum jelly). Gloves should be replaced periodically. Hygiene/Cleanliness: Always wash hands before eating, smoking or going to the toilet. Paint transferred from the hands to other parts of the body can cause damage. Have a shower at the end of the working day. First Aid Breathing/Dizziness: If inhaled, quickly take the person to a place with fresh air. Lie them down and keep them warm. If breathing has stopped, give them artificial respiration (the ‘kiss of life’). If (In case of doubt seek breathing is difficult give oxygen. Seek medical attention. Medical Advice) Eyes: Give rapid assistance by holding the eyelids apart and washing with clean fresh water for at least 15 minutes. Afterwards seek medical attention (some paints stick to the eyes and need UV light to be seen and specialist cleaning to remove all traces of paint). Skin: Quickly remove clothing and wash skin with soap and water or a special skin cleaner. DO NOT use solvents (thinner/equipment cleaner). Mouth: If paint is accidentally swallowed quickly get a doctor or take the person to a hospital, DO NOT make the person vomit/be sick unless instructed to do so by medical personnel. They should drink as much water as possible. Never give anything by mouth to an unconscious person. Other Spillage: Put sand/earth around spills to stop them getting into drains or rivers or the sea. Absorb the paint with more sand/earth and send to a special waste dump/treatment works. Emergencies Fire: Fight fire with foam (large fires); Powder, CO2 foam (small fires). Waste Disposal Follow local regulatory requirements.
The Product Data Sheet, the Material Safety Data Sheet and the package labelling together form an integral information system about this product. Copies of the Product Important Note Data Sheet and the Material Safety Data Sheet are available from International Coatings on request or from our Internet site: http//www.international-marine.com
Official Advisory Body Tel. No. For Advice to Doctors & Hospitals +44 (0)870 600 6266
Country 24 Hr. Emergency Tel. No. Country 24 Hr. Emergency Tel. No. Australia +61 (0) 1 800 807 001 Sweden 112 WM/International Thinners/Cleaners/DS Finland +358 (0) 9 471 977 Turkey +90 (0) 216 574 31 91 January 2004 Portugal +351 (0) 65 702 025 UK & Rest of World +44 (0) 191 469 6111
Marine & Protective Coatings safety advice sheet
This contains basic health, safety and environmental information that is important for the actual user of the product. It does not replace the Material Safety Data Sheet.
Product Name: Interzone 1000 Ref No: 0059 NOTE: this sheet applies to the mixed paint
Revision Number 1 Use/Application A low VOC glass flake epoxy for the protection of steelwork from corrosion and abrasion in severe environments. May be applied by airless spray, pressure pot air spray or brush. Safety Dangers This paint contains solvents. When used or spilt it will release solvent vapours which may catch fire or explode. If breathed in, solvents may cause headaches and dizziness and long term nervous system Health Dangers damage. Paint in the eyes will cause irritation. Repeated splashes on the skin may cause irritation, loss of fat and skin damage (dermatitis). Splashes on the skin may cause severe allergic rashes from minor exposure. Control Measures Extraction/Local Extract Ventilation: When paint is used anywhere inside a confined space or area with limited ventilation on a ship or inside a building, forced extraction with fans must be used to stop solvent from creating an explosive mixture and to reduce the solvent concentration that people may breathe in. Ignition: Cigarettes, lighters, matches, welding or cutting torches, grinding and all electrical equipment except approved spark proof lights must be kept well away from paint mixing and paint spraying, rolling or brushing. Personal Protective Equipment Lungs (Inhalation) The sprayer and assistant should always wear a cartridge respirator. Other people who can smell paint should also wear a cartridge respirator or carbon mask unless they are sure the solvent concentration is below the national occupational exposure limit (OES). Cartridge or respirators and carbon masks become less efficient with time and should be replaced periodically. (Follow respirator manufacturers recommendations). Eyes: Wear safety glasses or goggles or a face shield at all times when mixing, spraying, rolling or or brushing paint. Skin: Wear an overall with full length sleeves and legs. Wear solvent resistant ‘rubber’ gloves (long sleeve). Wear safety boots. Make sure there is no gap at wrist and ankles. Change and wash the overall as appropriate and at least twice a week. If paint is able to pass through the overall, replace + + + it. Wear a hard hat. Protect face skin with barrier cream (not petroleum jelly). Gloves should be replaced periodically. Hygiene/Cleanliness: Always wash hands before eating, smoking or going to the toilet. Paint transferred from the hands to other parts of the body can cause damage. Have a shower at the end of the working day. First Aid Breathing/Dizziness: If inhaled, quickly take the person to a place with fresh air. Lie them down and keep them warm. If breathing has stopped, give them artificial respiration (the ‘kiss of life’). If (In case of doubt seek breathing is difficult give oxygen. Seek medical attention. Medical Advice) Eyes: Give rapid assistance by holding the eyelids apart and washing with clean fresh water for at least 15 minutes. Afterwards seek medical attention (some paints stick to the eyes and need UV light to be seen and specialist cleaning to remove all traces of paint). Skin: Quickly remove clothing and wash skin with soap and water or a special skin cleaner. DO NOT use solvents (thinner/equipment cleaner). Mouth: If paint is accidentally swallowed quickly get a doctor or take the person to a hospital, DO NOT make the person vomit/be sick unless instructed to do so by medical personnel. They should drink as much water as possible. Never give anything by mouth to an unconscious person. Other Spillage: Put sand/earth around spills to stop them getting into drains or rivers or the sea. Absorb the paint with more sand/earth and send to a special waste dump/treatment works. Emergencies Fire: Fight fire with foam (large fires); Powder, CO2 foam (small fires). Waste Disposal Follow local regulatory requirements.
The Product Data Sheet, the Material Safety Data Sheet and the package labelling together form an integral information system about this product. Copies of the Product Important Note Data Sheet and the Material Safety Data Sheet are available from International Coatings on request or from our Internet site: http//www.international-marine.com
Official Advisory Body Tel. No. For Advice to Doctors & Hospitals Only +44 (0)870 600 6266
Country 24 Hr. Emergency Tel. No. Country 24 Hr. Emergency Tel. No. Australia +61 (0) 1 800 807 001 Sweden 112 WM/Interzone 1000/DS Finland +358 (0) 9 471 977 Turkey +90 (0) 216 574 31 91 January 2004 Portugal +351 (0) 65 702 025 UK & Rest of World +44 (0) 191 469 6111
Interprime 198 Alkyd Primer
PRODUCT DESCRIPTION A quick drying, one pack primer. Interprime 198 is surface tolerant, compatible with most substrates and can be overcoated with a wide range of finishes.
INTENDED USES For the maintenance of above water areas. Approved for the carriage of grain when used as part of an approved scheme. For use at Maintenance & Repair or On Board Maintenance.
PRODUCT INFORMATION Color CPA097-White, CPA098-Grey, CPA099-Red Finish/Sheen Matt Part B (Curing Agent) Not applicable Volume Solids 41% ±2% (ISO 3233:1998)
Mix Ratio Not applicable Typical Film Thickness 3 mils dry (7.3 mils wet) Theoretical Coverage 219 ft²/US gal at 3 mils dft, allow appropriate loss factors Method of Application Airless Spray, Brush, Roller Flash Point Single Pack 95°F
Drying Information 23°F 41°F 77°F 95°F
Touch Dry [ISO 9117/3:2010] 8 hrs 3 hrs 60 mins 30 mins Hard Dry [ISO 9117-1:2009] 48 hrs 24 hrs 4 hrs 2 hrs
Overcoating Data - see limitations Substrate Temperature 23°F 41°F 77°F 95°F
Overcoated By Min Max Min Max Min Max Min Max
Interfine 5703 - - - - 2 hrs 3 days 2 hrs 24 hrs Interfine 599 - - 9 hrs 3 days 3 hrs 2 days 60 mins 24 hrs Interlac 665 24 hrs 3 days 6 hrs 3 days 2 hrs 2 days 60 mins 24 hrs Interprime 198 8 hrs ext 3 hrs ext 60 mins ext 30 mins ext Intersheen 579 24 hrs 3 days 24 hrs 3 days 12 hrs 2 days 6 hrs 24 hrs Interstores Alkyd - - 6 hrs 3 days 2 hrs 2 days 60 mins 24 hrs Interstores Polyurethane - - 24 hrs 7 days 12 hrs 7 days 6 hrs 3 days Interthane 990 - - 24 hrs 7 days 12 hrs 7 days 6 hrs 3 days Intertherm 891 24 hrs 28 days 6 hrs 28 days 2 hrs 28 days 60 mins 28 days
REGULATORY DATA VOC 506 g/lt (4.22 lb/US gal) as supplied (EPA Method 24) 416 g/kg of liquid paint as supplied. EU Solvent Emissions Directive (Council Directive 1999/13/EC)
Note: VOC values are typical and are provided for guidance purposes only. These may be subject to variation depending on factors such as differences in color and normal manufacturing tolerances.
Marine Coatings
Page 1 of 4 Issue Date:2/4/2015 Ref:169 Interprime 198 Alkyd Primer CERTIFICATION When used as part of an approved scheme, this material has the following certification:
• Fire Resistance - Surface Spread of Flame (Exova Warringtonfire) • Fire Resistance - Surface Spread of Flame (Korean Register of Shipping) • Fire Resistance - Smoke & Toxicity (Exova Warringtonfire) • Food Contact - Carriage of Grain (NOHA) • Fire Resistance - Marine Equipment Directive compliant
Consult your International Paint representative for details.
SYSTEMS AND Consult your International Paint representative for the system best suited for the surfaces to be protected. COMPATIBILITY
SURFACE PREPARATIONS Use in accordance with the standard Worldwide Marine Specifications. All surfaces to be coated should be clean, dry and free from contamination. High pressure fresh water wash or fresh water wash, as appropriate, and remove all oil or grease, soluble contaminants and other foreign matter in accordance with SSPC-SP1 solvent cleaning. REPAIR/OBM Prepare area to be repaired to a minimum of St2 (ISO 8501-1:1998). Higher levels of surface preparation by abrasive blasting to Sa2 (ISO 8501-1:2001) or hydroblasting to HB2M (International Paint Hydroblasting Standards), will enhance product performance. Feather or chip back surrounding area to a sound edge. Ensure that the area is clean and dry prior to application of Interprime 198. Overlap the primer onto existing coatings by approximately 2-3cm.
Consult your International Paint representative for specific recommendations. NOTE For use in Marine situations in North America, the following surface preparation standards can be used: SSPC-SP6 in place of Sa2 (ISO 8501-1:2007) SSPC-SP2 in place of St2 (ISO 8501-1:2007)
Marine Coatings
Page 2 of 4 Issue Date:2/4/2015 Ref:169 Interprime 198 Alkyd Primer APPLICATION
Mixing This material is a one pack coating and should always be mixed thoroughly with a power agitator before application.
Thinner Not recommended. Use International GTA007 only in exceptional circumstances. DO NOT thin more than allowed by local environmental legislation. Airless Spray Recommended Tip Range 21-26 thou (0.53-0.66 mm) Total output fluid pressure at spray tip not less than 2500 psi (176 kg/cm²) Conventional Spray Application by conventional spray is not recommended. Brush Recommended. Multiple coats may be required to achieve specified dft. Roller Recommended. Multiple coats may be required to achieve specified dft. Cleaner International GTA007 Work Stoppages and Cleanup Thoroughly flush all equipment with International GTA007. All unused material should be stored in tightly closed containers. Partially filled containers may show surface skinning and/or a viscosity increase of the material after storage. Material should be filtered prior to use.
Welding In the event welding or flame cutting is performed on metal coated with this product, dust and fumes will be emitted which will require the use of appropriate personal protective equipment and adequate local exhaust ventilation. In North America do so in accordance with instruction in ANSI/ASC Z49.1 "Safety in Welding and Cutting."
SAFETY All work involving the application and use of this product should be performed in compliance with all relevant national Health, Safety & Environmental standards and regulations.
Prior to use, obtain, consult and follow the Material Safety Data Sheet for this product concerning health and safety information. Read and follow all precautionary notices on the Material Safety Data Sheet and container labels. If you do not fully understand these warnings and instructions or if you can not strictly comply with them, do not use this product. Proper ventilation and protective measures must be provided during application and drying to keep solvent vapor concentrations within safe limits and to protect against toxic or oxygen deficient hazards. Take precautions to avoid skin and eye contact (ie. gloves, goggles, face masks, barrier creams etc.) Actual safety measures are dependant on application methods and work environment. EMERGENCY CONTACT NUMBERS: USA/Canada - Medical Advisory Number 1-800-854-6813 Europe - Contact (44) 191 4696111. For advice to Doctors & Hospitals only contact (44) 207 6359191 China – Contact (86) 532 83889090 R.O.W. - Contact Regional Office
Marine Coatings
Page 3 of 4 Issue Date:2/4/2015 Ref:169 Interprime 198 Alkyd Primer LIMITATIONS It is recommended that Interprime 198 is not overcoated with epoxy coatings. In certain regions, for specific customer requests and where cosmetic properties are not of concern, Interprime 198 may be applied without a cosmetic finish. Consult your regional technical centre for guidelines and details of colors available.
Overcoating information is given for guidance only and is subject to regional variation depending upon local climate and environmental conditions. Consult your local International Paint representative for specific recommendations. Apply in good weather. Temperature of the surface to be coated must be at least 5°F above the dew point. For optimum application properties bring the material to 70°F-81°F, unless specifically instructed otherwise, prior to mixing and application. Unmixed material (in closed containers) should be maintained in protected storage in accordance with information given in the STORAGE Section of this data sheet. Technical and application data herein is for the purpose of establishing a general guideline of the coating application procedures. Test performance results were obtained in a controlled laboratory environment and International Paint makes no claim that the exhibited published test results, or any other tests, accurately represent results found in all field environments. As application, environmental and design factors can vary significantly, due care should be exercised in the selection, verification of performance and use of the coating.
UNIT SIZE Unit Size Vol Pack 1 US gal 1 US gal 1 US gal 5 US gal 5 US gal 5 US gal 5 lt 5 lt 5 lt 20 lt 20 lt 20 lt
For availability of other unit sizes consult International Paint UNIT SHIPPING WEIGHT Unit Size Unit Weight 1 US gal 12.2 lb 20 lt 26.7 Kg 5 lt 6.71 Kg 5 US gal 60.9 lb
STORAGE Shelf Life 24 months minimum at 77°F. Subject to reinspection thereafter. Store in dry, shaded conditions away from sources of heat and ignition
WORLDWIDE AVAILABILITY Consult International Paint.
IMPORTANT NOTE The information in this data sheet is not intended to be exhaustive; any person using the product for any purpose other than that specifically recommended in this data sheet without first obtaining written confirmation from us as to the suitability of the product for the intended purpose does so at their own risk. All advice given or statements made about the product (whether in this data sheet or otherwise) is correct to the best of our knowledge but we have no control over the quality or the condition of the substrate or the many factors affecting the use and application of the product. Therefore, unless we specifically agree in writing to do so, we do not accept any liability at all for the performance of the product or for (subject to the maximum extent permitted by law) any loss or damage arising out of the use of the product. We hereby disclaim any warranties or representations, express or implied, by operation of law or otherwise, including, without limitation, any implied warranty of merchantability or fitness for a particular purpose. All products supplied and technical advice given are subject to our Conditions of Sale. You should request a copy of this document and review it carefully. The information contained in this data sheet is liable to modification from time to time in the light of experience and our policy of continuous development. It is the user's responsibility to check with their local representative that this data sheet is current prior to using the product.
This Technical Data Sheet is available on our website at www.international-marine.com or www.international-pc.com, and should be the same as this document. Should there be any discrepancies between this document and the version of the Technical Data Sheet that appears on the website, then the version on the website will take precedence.
All trademarks mentioned in this publication are owned by, or licensed to, the AkzoNobel group of companies.
© AkzoNobel, 2015 www.international-marine.com
Marine Coatings
Page 4 of 4 Issue Date:2/4/2015 Ref:169 Interfine 5703 Acrylic Modified Polysiloxane Finish
PRODUCT DESCRIPTION A high performance, one pack, high gloss, low VOC acrylic modified polysiloxane finish providing excellent colour and gloss retention. Interfine 5703 significantly improves upon the gloss and color retention exhibited by typical one pack finishes.
INTENDED USES As an easily maintained cosmetic finish for above water areas. For use at Newbuilding, Maintenance & Repair or On Board Maintenance.
PRODUCT INFORMATION Color SUB000-White, Tinted to provide a range of colors. Finish/Sheen High Gloss Part B (Curing Agent) Not applicable Volume Solids 60% ±2% (ASTM D2697-86)
Mix Ratio Not applicable Typical Film Thickness 2 mils dry (3.3 mils wet) Theoretical Coverage 481 ft²/US gal at 2 mils dft, allow appropriate loss factors Method of Application Airless Spray, Brush, Conventional Spray, Roller Flash Point Single Pack 102°F
Drying Information 50°F 59°F 77°F 95°F
Touch Dry [ISO 9117/3:2010] 4 hrs 3 hrs 2.5 hrs 1.5 hrs Hard Dry [ISO 9117-1:2009] 72 hrs 35 hrs 29 hrs 10 hrs
Overcoating Data - see limitations Substrate Temperature 50°F 59°F 77°F 95°F Overcoated By Min Max Min Max Min Max Min Max
Interfine 5703 72 hrs ext 35 hrs ext 29 hrs ext 24 hrs ext
REGULATORY DATA VOC 334 g/lt (2.79 lb/US gal) as supplied (EPA Method 24)
Note: VOC values are typical and are provided for guidance purposes only. These may be subject to variation depending on factors such as differences in color and normal manufacturing tolerances.
Marine Coatings
Page 1 of 4 Issue Date:2/4/2015 Ref:10247 Interfine 5703 Acrylic Modified Polysiloxane Finish CERTIFICATION When used as part of an approved scheme, this material has the following certification:
• Fire Resistance - Marine Equipment Directive compliant • Fire Resistance - Surface Spread of Flame (WFR) - (BS476:Part 7)
Consult your local representative for details.
SYSTEMS AND Consult your International Paint representative for the system best suited for the surfaces to be protected. COMPATIBILITY
SURFACE PREPARATIONS Paint only clean, dry surfaces. Remove all grease, oil, soluble contaminants and other foreign matter by "solvent cleaning" (SSPC-SP1). Unpainted surfaces: Prepare surface and apply recommended primer. Apply one or more coats of Interfine 5703 as specified. (Consult the relevant primer data sheet for surface preparation and overcoating information.)
Previously Painted Surfaces: Remove all mill scale, loose rust, loose paint and other foreign matter by "Hand or Power Tool Cleaning" (SSPC-SP2 or SP3, respectively). Sand or "Brush Blast" (SSPC-SP7) any hard glossy areas until dull. Spot prime bare areas as recommended and apply one or more coats of Interfine 5703 as specified. Consult the relevant primer data sheet for specific surface preparation and overcoating information. Check integrity of existing coating system and apply a representative test patch to confirm compatibility. Consult your International Paint representative for procedures.
Marine Coatings
Page 2 of 4 Issue Date:2/4/2015 Ref:10247 Interfine 5703 Acrylic Modified Polysiloxane Finish APPLICATION Tinting Range of colors available from Chromascan. Most colors require that containers be slightly short filled to accommodate the addition of colorant. Actual coverage will depend upon amount of colorant added and should be taken into consideration when ordering. A limited number of Interfine 5703 tinted colors may require more than one coat for complete hiding. Mixing This material is a one pack coating. Always mix thoroughly before application.
Thinner DO NOT THIN BEYOND YOUR STATE'S COMPLIANCY. Maximum thinning for VOC compliance is color specific. Contact your International Paint representative for thinning and VOC information. Airless Spray Minimum 28:1 ratio pump; 0.015" - 0.019" (381-483 microns) orifice tip; 3/8" (9.5 mm) ID high pressure material hose, 60 mesh tip filter. Attention must be paid while applying with larger size of tip to control the thickness better. Conventional Spray DeVilbiss MBC-510 gun E tip and 704 air cap; 3/8" (9.5 mm) ID material hose; double regulated pressure tank with oil and moisture separator. Brush Use appropriate size China bristle brush. Roller Use All Purpose Roller cover with 3/8" (9.5mm) smooth to medium nap. Prewash roller cover to remove loose fibres prior to use. Cleaner International GTA007 Work Stoppages and Cleanup Clean all equipment immediately after use with International GTA007. It is good working practice to periodically flush out spray equipment during the course of the working day. Frequency of cleaning will depend upon amount sprayed, temperature and elapsed time, including any delays. Do not exceed pot life limitations. All surplus materials and empty containers should be disposed of in accordance with appropriate regional regulations/legislation.
Welding In the event welding or flame cutting is performed on metal coated with this product, dust and fumes will be emitted which will require the use of appropriate personal protective equipment and adequate local exhaust ventilation. In North America do so in accordance with instruction in ANSI/ASC Z49.1 "Safety in Welding and Cutting."
SAFETY All work involving the application and use of this product should be performed in compliance with all relevant national Health, Safety & Environmental standards and regulations.
Prior to use, obtain, consult and follow the Material Safety Data Sheet for this product concerning health and safety information. Read and follow all precautionary notices on the Material Safety Data Sheet and container labels. If you do not fully understand these warnings and instructions or if you can not strictly comply with them, do not use this product. Proper ventilation and protective measures must be provided during application and drying to keep solvent vapor concentrations within safe limits and to protect against toxic or oxygen deficient hazards. Take precautions to avoid skin and eye contact (ie. gloves, goggles, face masks, barrier creams etc.) Actual safety measures are dependant on application methods and work environment. EMERGENCY CONTACT NUMBERS: USA/Canada - Medical Advisory Number 1-800-854-6813 Europe - Contact (44) 191 4696111. For advice to Doctors & Hospitals only contact (44) 207 6359191 R.O.W. - Contact Regional Office
Marine Coatings
Page 3 of 4 Issue Date:2/4/2015 Ref:10247 Interfine 5703 Acrylic Modified Polysiloxane Finish LIMITATIONS Apply in good weather when air and surface temperatures are at and above 41°F. Surface temperature must be at least 5°F above dew point. For optimum application properties, bring material to 60-90°F prior to mixing and application. Unmixed material (in closed containers) should be maintained in protected storage between 40 and 100°F.
Overcoating information is given for guidance only and is subject to regional variation depending upon local climate and environmental conditions. Consult your local International Paint representative for specific recommendations. Technical and application data herein is for the purpose of establishing a general guideline of the coating and proper coating application procedures. Test performance results were obtained in a controlled laboratory environment and International Paint makes no claim that the exhibited published test results, or any other tests, accurately represent results actually found in all field environments. As application, environmental and design factors can vary significantly, due care should be exercised in the selection, verification of performance and use of the coating. In the overcoating data section 'ext' = extended overcoating period. Please refer to our Marine Painting Guide - Definitions and Abbreviations available from our website.
TINT BASE AVAILABILITY SUA011-Light Base, SUA044-Ultra Deep, SUA055-Yellow Base, SUA066-Red Base
UNIT SIZE Unit Size Vol Pack 1 US gal 1 US gal 1 US gal
UNIT SHIPPING WEIGHT Unit Size Unit Weight 1 US gal 11.4 lb
STORAGE Shelf Life 12 months minimum from date of manufacture when maintained in protected storage at 55- 100°F. Subject to reinspection thereafter. Store in dry, shaded conditions away from sources of heat and ignition.
WORLDWIDE AVAILABILITY Consult International Paint.
IMPORTANT NOTE The information in this data sheet is not intended to be exhaustive; any person using the product for any purpose other than that specifically recommended in this data sheet without first obtaining written confirmation from us as to the suitability of the product for the intended purpose does so at their own risk. All advice given or statements made about the product (whether in this data sheet or otherwise) is correct to the best of our knowledge but we have no control over the quality or the condition of the substrate or the many factors affecting the use and application of the product. Therefore, unless we specifically agree in writing to do so, we do not accept any liability at all for the performance of the product or for (subject to the maximum extent permitted by law) any loss or damage arising out of the use of the product. We hereby disclaim any warranties or representations, express or implied, by operation of law or otherwise, including, without limitation, any implied warranty of merchantability or fitness for a particular purpose. All products supplied and technical advice given are subject to our Conditions of Sale. You should request a copy of this document and review it carefully. The information contained in this data sheet is liable to modification from time to time in the light of experience and our policy of continuous development. It is the user's responsibility to check with their local representative that this data sheet is current prior to using the product.
This Technical Data Sheet is available on our website at www.international-marine.com or www.international-pc.com, and should be the same as this document. Should there be any discrepancies between this document and the version of the Technical Data Sheet that appears on the website, then the version on the website will take precedence.
All trademarks mentioned in this publication are owned by, or licensed to, the AkzoNobel group of companies.
© AkzoNobel, 2015 www.international-marine.com
Marine Coatings
Page 4 of 4 Issue Date:2/4/2015 Ref:10247 CPA098_D1
Material Safety Data Sheet INTERPRIME 198 GREY
Sales Order: {SalesOrd} Bulk Sales Reference No.: CPA098 MSDS Revision Date: 01/27/2015 MSDS Revision Number: D1-3
1. Identification of the preparation and company
1.1. Product identifier Product Identity INTERPRIME 198 GREY Bulk Sales Reference No. CPA098
1.2. Relevant identified uses of the substance or mixture and uses advised against Intended Use See Technical Data Sheet. Application Method See Technical Data Sheet.
1.3. Details of the supplier of the safety data sheet Company Name International Paint LLC 6001 Antoine Drive Houston, Texas 77091
Emergency CHEMTREC (USA) (800) 424-9300 International Paint (713) 682-1711 Poison Control Center (800) 854-6813 Customer Service International Paint (800) 589-1267 Fax No. (800) 631-7481
2. Hazard identification of the product
2.1. Classification of the substance or mixture Flam. Liq. 3;H226 Flammable liquid and vapor. Skin Irrit. 2;H315 Causes skin irritation. Eye Dam. 1;H318 Causes serious eye damage. Aquatic Chronic 2;H411 Toxic to aquatic life with long lasting effects.
2.2. Label elements Using the Toxicity Data listed in section 11 & 12 the product is labelled as follows.
Danger. H226 Flammable liquid and vapor. H315 Causes skin irritation. H318 Causes serious eye damage. H411 Toxic to aquatic life with long lasting effects.
P210 Keep away from heat / sparks / open flames / hot surfaces - No smoking. P260 Do not breathe mist / vapors / spray.
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P262 Do not get in eyes, on skin, or on clothing. P273 Avoid release to the environment. P280 Wear protective gloves / eye protection / face protection. P301+310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P302+352 IF ON SKIN: Wash with soap and water. P303+361+353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P305+351+338 IF IN EYES: Rinse continuously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing. P310 Immediately call a POISON CENTER or doctor / physician. P331 Do NOT induce vomiting. P362 Take off contaminated clothing and wash before reuse. P370 In case of fire: Use water spray, fog, or regular foam.. P391 Collect spillage. P403+233 Store in a well ventilated place. Keep container tightly closed. P501 Dispose of contents / container in accordance with local / national regulations.
HMIS Rating Health: 3* Flammability: 3 Reactivity: 0
3. Composition/information on ingredients
This product contains the following substances that present a hazard within the meaning of the relevant State and Federal Hazardous Substances regulations. Ingredient/Chemical Weight % GHS Classification Notes Designations Petroleum naphtha 10 - 25 Asp. Tox. 1;H304 [1] CAS Number: 0064742-95-6 Aquatic Chronic 2;H411 (Self Classification) Limestone 10 - 25 ---- [1] CAS Number: 0001317-65-3 1,2,4-Trimethyl benzene 10 - 25 Flam. Liq. 3;H226 [1] CAS Number: 0000095-63-6 Acute Tox. 4;H332 Eye Irrit. 2;H319 STOT SE 3;H335 Skin Irrit. 2;H315 Aquatic Chronic 2;H411 Barium sulfate 1.0 - 10 ---- [1][2] CAS Number: 0007727-43-7 Wollastonite (Ca(SiO3)) 1.0 - 10 ---- [1] CAS Number: 0013983-17-0 Xylenes (o-, m-, p- isomers) 1.0 - 10 Flam. Liq. 3;H226 [1][2] CAS Number: 0001330-20-7 Acute Tox. 4;H332 Acute Tox. 4;H312 Skin Irrit. 2;H315 Eye Irrit. 2;H319 STOT SE 3;H335 Asp. Tox. 1;H304 Butanol 1.0 - 10 Flam. Liq. 3;H226 [1][2] CAS Number: 0000071-36-3 Acute Tox. 4;H302 STOT SE 3;H335 Skin Irrit. 2;H315 Eye Dam. 1;H318 STOT SE 3;H336 Titanium dioxide 1.0 - 10 ---- [1][2] CAS Number: 0013463-67-7 1,3,5-Trimethylbenzene 1.0 - 10 Flam. Liq. 3;H226 [1] CAS Number: 0000108-67-8 STOT SE 3;H335 Aquatic Chronic 2;H411 Methyl ethyl ketoxime 0.10 - 1.0 Carc. 2;H351 [1] CAS Number: 0000096-29-7 Acute Tox. 4;H312
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Eye Dam. 1;H318 Skin Sens. 1;H317 [1] Substance classified with a health or environmental hazard. [2] Substance with a workplace exposure limit. [3] PBT-substance or vPvB-substance.
*The full texts of the phrases are shown in Section 16.
4. First aid measures
4.1. Description of first aid measures General Remove contaminated clothing and shoes. Get medical attention immediately. Wash clothing before reuse. Thoroughly clean or destroy contaminated shoes. Inhalation If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately. Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention immediately. Skin In case of contact, immediately flush skin with soap and plenty of water. Get medical attention immediately. Ingestion If swallowed, immediately contact Poison Control Center at 1-800-854-6813. DO NOT induce vomiting unless instructed to do so by medical personnel. Never give anything by mouth to an unconscious person. 4.2. Most important symptoms and effects, both acute and delayed Overview NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. Avoid contact with eyes, skin and clothing. Inhalation Harmful if inhaled. Causes lung irritation. Causes nose and throat irritation. Vapors may affect the brain or nervous system causing dizziness, headache or nausea. Eyes Causes severe eye irritation. Avoid contact with eyes. Skin Causes skin irritation. May be harmful if absorbed through the skin. Ingestion Harmful if swallowed. May cause abdominal pain, nausea, vomiting, diarrhea, or drowsiness. Chronic effects Possible cancer hazard. Contains an ingredient which may cause cancer based on animal data (See Section 2 and Section 15 for each ingredient). Risk of cancer depends on duration and level of exposure.
5. Fire-fighting measures
5.1. Extinguishing media CAUTION: This product has a very low flashpoint. Use of water spray when fighting fire may be inefficient. CAUTION: For mixtures containing alcohol or polar solvent, alcohol-resistant foam may be more effective. SMALL FIRES: Use dry chemical, CO2, water spray or regular foam. LARGE FIRES: Use water spray, fog, or regular foam. Do not use straight streams. Move containers from fire area if you can do so without risk. 5.2. Special hazards arising from the substance or mixture HIGHLY FLAMMABLE MATERIALS: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks) creating a vapor explosion hazard. Runoff to sewers may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water. 5.3. Advice for fire-fighters Cool closed containers exposed to fire by spraying them with water. Do not allow run off water and contaminants from fire fighting to enter drains or water courses. ERG Guide No. 128
6. Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures ELIMINATE ALL IGNITION SOURCES (no smoking, flares, sparks or flames in immediate area). Use only non-sparking equipment to handle spilled material and absorbent. Do not touch or walk through spilled material. Stop leak if you can do so without risk. Prevent entry into waterways, sewers, basements or confined areas. A vapor suppressing foam may be used to reduce vapors. Absorb or cover with dry earth, sand, or other non-combustible material and transfer to containers. Use non-sparking tools to collect absorbed material.
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6.2. Environmental precautions Do not allow spills to enter drains or watercourses. 6.3. Methods and material for containment and cleaning up CALL CHEMTREC at (800)-424-9300 for emergency response. Isolate spill or leak area immediately for at least 50 meters (150 feet) in all directions. Keep unauthorized personnel away. Stay upwind. Keep out of low areas. Ventilate closed spaces before entering. LARGE SPILLS: Consider initial downwind evacuation for at least 300 meters (1000 feet).
7. Handling and storage
7.1. Precautions for safe handling Handling Vapors may cause flash fire or ignite explosively.
In Storage Keep away from heat, sparks and flame.
7.2. Conditions for safe storage, including any incompatibilities Store between 40-100F (4-38C). Do not get in eyes, on skin or clothing. Strong oxidizing agents. Do not smoke. Extinguish all flames and pilot lights, and turn off stoves, heaters, electric motors and other sources of ignition during use and until all vapors are gone.
7.3. Specific end use(s) Close container after each use. Wash thoroughly after handling. Prevent build-up of vapors by opening all windows and doors to achieve cross-ventilation.
8. Exposure controls and personal protection
8.1. Control parameters Exposure CAS No. Ingredient Source Value 0000071-36-3 Butanol OSHA 100 ppm TWA; 300 mg/m3 TWA50 ppm Ceiling; 150 mg/m3 Ceiling ACGIH 20 ppm TWA NIOSH 50 ppm Ceiling; 150 mg/m3 Ceiling1400 ppm IDLH (10% LEL) Supplier No Established Limit OHSA, 20 ppm TWA CAN Mexico No Established Limit Brazil 40 ppm TWA LT; 115 mg/m3 TWA LT 0000095-63-6 1,2,4-Trimethyl benzene OSHA No Established Limit ACGIH No Established Limit NIOSH 25 ppm TWA; 125 mg/m3 TWA Supplier No Established Limit OHSA, No Established Limit CAN Mexico No Established Limit Brazil No Established Limit 0000096-29-7 Methyl ethyl ketoxime OSHA No Established Limit ACGIH No Established Limit NIOSH No Established Limit Supplier No Established Limit OHSA, No Established Limit CAN Mexico No Established Limit
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Brazil No Established Limit 0000108-67-8 1,3,5-Trimethylbenzene OSHA No Established Limit ACGIH No Established Limit NIOSH 25 ppm TWA; 125 mg/m3 TWA Supplier No Established Limit OHSA, No Established Limit CAN Mexico No Established Limit Brazil No Established Limit 0001317-65-3 Limestone OSHA 15 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction) ACGIH No Established Limit NIOSH 10 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable dust) Supplier No Established Limit OHSA, No Established Limit CAN Mexico 10 mg/m3 TWA LMPE-PPT20 mg/m3 STEL [LMPE-CT] Brazil No Established Limit 0001330-20-7 Xylenes (o-, m-, p- isomers) OSHA 100 ppm TWA; 435 mg/m3 TWA150 ppm STEL; 655 mg/m3 STEL ACGIH 100 ppm TWA150 ppm STEL NIOSH No Established Limit Supplier No Established Limit OHSA, 100 ppm TWA150 ppm STEL CAN Mexico 100 ppm TWA LMPE-PPT; 435 mg/m3 TWA LMPE-PPT150 ppm STEL [LMPE-CT]; 655 mg/m3 STEL [LMPE-CT] Brazil 78 ppm TWA LT; 340 mg/m3 TWA LT 0007727-43-7 Barium sulfate OSHA 15 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction) ACGIH 10 mg/m3 TWA NIOSH 10 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable dust) Supplier No Established Limit OHSA, 10 mg/m3 TWA CAN Mexico No Established Limit Brazil No Established Limit 0013463-67-7 Titanium dioxide OSHA 15 mg/m3 TWA (total dust) ACGIH 10 mg/m3 TWA NIOSH 5000 mg/m3 IDLH Supplier No Established Limit OHSA, 10 mg/m3 TWA CAN Mexico 10 mg/m3 TWA LMPE-PPT (as Ti)20 mg/m3 STEL [LMPE-CT] (as Ti) Brazil No Established Limit 0013983-17-0 Wollastonite (Ca(SiO3)) OSHA No Established Limit ACGIH No Established Limit NIOSH No Established Limit Supplier No Established Limit OHSA, No Established Limit CAN Mexico No Established Limit Brazil No Established Limit 0064742-95-6 Petroleum naphtha OSHA No Established Limit
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ACGIH No Established Limit NIOSH No Established Limit Supplier No Established Limit OHSA, No Established Limit CAN Mexico No Established Limit Brazil No Established Limit
Health Data CAS No. Ingredient Source Value 0000071-36-3 Butanol NIOSH Eye and mucous membrane irritation CNS depression 0000095-63-6 1,2,4-Trimethyl benzene NIOSH No Established Limit 0000096-29-7 Methyl ethyl ketoxime NIOSH No Established Limit 0000108-67-8 1,3,5-Trimethylbenzene NIOSH No Established Limit 0001317-65-3 Limestone NIOSH Eye and skin irritation Physical irritation 0001330-20-7 Xylenes (o-, m-, p- isomers) NIOSH Central nervous system depressant; respiratory and eye irritation 0007727-43-7 Barium sulfate NIOSH Eye nose 0013463-67-7 Titanium dioxide NIOSH Lung tumors in animals 0013983-17-0 Wollastonite (Ca(SiO3)) NIOSH No Established Limit 0064742-95-6 Petroleum naphtha NIOSH No Established Limit
Carcinogen Data CAS No. Ingredient Source Value 0000071-36-3 Butanol OSHA Select Carcinogen: No NTP Known: No; Suspected: No IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No; 0000095-63-6 1,2,4-Trimethyl benzene OSHA Select Carcinogen: No NTP Known: No; Suspected: No IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No; 0000096-29-7 Methyl ethyl ketoxime OSHA Select Carcinogen: No NTP Known: No; Suspected: No IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No; 0000108-67-8 1,3,5-Trimethylbenzene OSHA Select Carcinogen: No NTP Known: No; Suspected: No IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No; 0001317-65-3 Limestone OSHA Select Carcinogen: No NTP Known: No; Suspected: No IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No; 0001330-20-7 Xylenes (o-, m-, p- OSHA Select Carcinogen: No isomers) NTP Known: No; Suspected: No IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: Yes; Group 4: No; 0007727-43-7 Barium sulfate OSHA Select Carcinogen: No NTP Known: No; Suspected: No IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No; 0013463-67-7 Titanium dioxide OSHA Select Carcinogen: Yes NTP Known: No; Suspected: No IARC Group 1: No; Group 2a: No; Group 2b: Yes; Group 3: No; Group 4: No; 0013983-17-0 Wollastonite (Ca(SiO3)) OSHA Select Carcinogen: No NTP Known: No; Suspected: No
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IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: Yes; Group 4: No; 0064742-95-6 Petroleum naphtha OSHA Select Carcinogen: No NTP Known: No; Suspected: No IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No;
8.2. Exposure controls Respiratory Select equipment to provide protection from the ingredients listed in Section 3 of this document. Ensure fresh air entry during application and drying. If you experience eye watering, headache or dizziness or if air monitoring demonstrates dust, vapor, or mist levels are above applicable limits, wear an appropriate, properly fitted respirator (NIOSH approved) during and after application. Follow respirator manufacturer's directions for respirator use. FOR USERS OF 3M RESPIRATORY PROTECTION ONLY: For information and assistance on 3M occupational health and safety products, call OH&ESD Technical Service toll free in U.S.A. 1-800-243-4630, in Canada call 1-800-267-4414. Please do not contact these numbers regarding other manufacturer's respiratory protection products. 3M does not endorse the accuracy of the information contained in this Material Safety Data Sheet. Eyes Avoid contact with eyes. Protective equipment should be selected to provide protection from exposure to the chemicals listed in Section 3 of this document. Depending on the site-specific conditions of use, safety glasses, chemical goggles, and/or head and face protection may be required to prevent contact. The equipment must be thoroughly cleaned, or discarded after each use. Skin Protective equipment should be selected to provide protection from exposure to the chemicals listed in Section 3 of this document. Depending on the site-specific conditions of use, protective gloves, apron, boots, head and face protection may be required to prevent contact. The equipment must be thoroughly cleaned, or discarded after each use. Engineering Controls Depending on the site-specific conditions of use, provide adequate ventilation. Other Work Practices Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. Use good personal hygiene practices. Wash hands before eating, drinking, using toilet facilities, etc. Promptly remove soiled clothing and wash clothing thoroughly before reuse. Shower after work using plenty of soap and water.
9. Physical and chemical properties
Appearance Coloured Liquid Odour threshold Not Measured pH No Established Limit Melting point / freezing point Not Measured Initial boiling point and boiling range 76 (C) 169 (F) Flash Point 35 (C) 95 (F) Evaporation rate (Ether = 1) Not Measured Flammability (solid, gas) Not Applicable Upper/lower flammability or explosive Lower Explosive Limit: .9 limits Upper Explosive Limit: No Established Limit vapor pressure (Pa) Not Measured Vapor Density Heavier than air Specific Gravity 1.34 Partition coefficient n-octanol/water (Log Not Measured Kow) Auto-ignition temperature Not Measured Decomposition temperature Not Measured Viscosity (cSt) No Established Limit Not Measured Refer to the Technical Data Sheet or label where information is VOC % available.
9.2. Other information No further information
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10. Stability and reactivity
10.1. Reactivity No data available 10.2. Chemical stability This product is stable and hazardous polymerization will not occur. Not sensitive to mechanical impact. Excessive heat and fumes generation can occur if improperly handled. 10.3. Possibility of hazardous reactions No data available 10.4. Conditions to avoid No data available 10.5. Incompatible materials Strong oxidizing agents. 10.6. Hazardous decomposition products HIGHLY FLAMMABLE MATERIALS: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks) creating a vapor explosion hazard. Runoff to sewers may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.
11. Toxicological information
Acute toxicity
NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal.
Ingredient Oral LD50, Skin LD50, Inhalation Inhalation mg/kg mg/kg Vapor LD50, Dust/Mist LD50, mg/L/4hr mg/L/4hr Petroleum naphtha - (64742-95-6) 6,800.00, Rat - 3,400.00, No data No data available Category: NA Rabbit - available Category: 5 Limestone - (1317-65-3) No data No data No data No data available available available available 1,2,4-Trimethyl benzene - (95-63-6) 3,400.00, Rat - 3,160.00, 18.00, Rat - No data available Category: 5 Rabbit - Category: 4 Category: 5 Barium sulfate - (7727-43-7) 3,000.00, No data No data No data available Mouse - available available Category: 5 Wollastonite (Ca(SiO3)) - (13983-17-0) No data No data No data No data available available available available Xylenes (o-, m-, p- isomers) - 4,299.00, Rat - 1,548.00, 20.00, Rat - No data available (1330-20-7) Category: 5 Rabbit - Category: 4 Category: 4 Butanol - (71-36-3) 2,292.00, Rat - 3,430.00, No data No data available Category: 5 Rabbit - available Category: 5 Titanium dioxide - (13463-67-7) 10,000.00, Rat 10,000.00, No data 6.82, Rat - - Category: NA Rabbit - available Category: NA Category: NA 1,3,5-Trimethylbenzene - (108-67-8) No data No data 24.00, Rat - No data available available available Category: NA Methyl ethyl ketoxime - (96-29-7) 930.00, Rat - 2,000.00, 20.00, Rat - No data available Category: 4 Rabbit - Category: 4 Category: 4
Item Category Hazard Acute Toxicity (mouth) Not Classified Not Applicable Acute Toxicity (skin) Not Classified Not Applicable
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Acute Toxicity (inhalation) Not Classified Not Applicable Skin corrosion/irritation 2 Causes skin irritation. Eye damage/irritation 1 Causes serious eye damage. Sensitization (respiratory) Not Classified Not Applicable Sensitization (skin) Not Classified Not Applicable Germ toxicity Not Classified Not Applicable Carcinogenicity Not Classified Not Applicable Reproductive Toxicity Not Classified Not Applicable Specific target organ systemic toxicity Not Classified Not Applicable (single exposure) Specific target organ systemic Not Classified Not Applicable Toxicity (repeated exposure) Aspiration hazard Not Classified Not Applicable
12. Ecological information
12.1. Toxicity No additional information provided for this product. See Section 3 for chemical specific data.
Aquatic Ecotoxicity
96 hr LC50 fish, 48 hr EC50 crustacea, ErC50 algae, Ingredient mg/l mg/l mg/l Petroleum naphtha - 9.22, Oncorhynchus 6.14, Daphnia magna 19.00 (72 hr), Selenastrum (64742-95-6) mykiss capricornutum Limestone - (1317-65-3) Not Available Not Available Not Available 1,2,4-Trimethyl benzene - 7.72, Pimephales 3.60, Daphnia magna Not Available (95-63-6) promelas Barium sulfate - 59,000.00, Poecilia 32.00, Daphnia Not Available (7727-43-7) sphenops magna Wollastonite (Ca(SiO3)) - Not Available Not Available Not Available (13983-17-0) Xylenes (o-, m-, p- 3.30, Oncorhynchus 8.50, Palaemonetes 100.00 (72 hr), Chlorococcales isomers) - (1330-20-7) mykiss pugio Butanol - (71-36-3) 1,328.00, Daphnia 500.00 (96 hr), Scenedesmus 1,376.00, Pimephales magna subspicatus promelas Titanium dioxide - 1,000.00, Fundulus 5.50, Daphnia magna (13463-67-7) heteroclitus 5.83 (72 hr), Pseudokirchneriella subcapitata 1,3,5-Trimethylbenzene - 12.52, Carassius 6.00, Daphnia magna 25.00 (48 hr), Scenedesmus (108-67-8) auratus subspicatus Methyl ethyl ketoxime - 320.00, Leuciscus 500.00, Daphnia 83.00 (72 hr), Scenedesmus (96-29-7) idus magna subspicatus
12.2. Persistence and degradability No data available 12.3. Bioaccumulative potential Not Measured 12.4. Mobility in soil No data available 12.5. Results of PBT and vPvB assessment This product contains no PBT/vPvB chemicals. 12.6. Other adverse effects No data available
13. Disposal considerations
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13.1. Waste treatment methods Do not allow spills to enter drains or watercourses. Dispose of in accordance with local, state and federal regulations. (Also reference RCRA information in Section 15 if listed).
14. Transport information
14.1. UN number UN 1263 14.2. UN proper shipping name PAINT 14.3. Transport hazard class(es)
DOT (Domestic Surface Transportation) IMO / IMDG (Ocean Transportation) DOT Proper Shipping PAINT IMDG Proper PAINT Name Shipping Name DOT Hazard Class 3 IMDG Hazard Class 3 Sub Class 3 UN / NA Number UN 1263 DOT Packing Group III IMDG Packing Group III CERCLA/DOT RQ 256 gal. / 2857 lbs. System Reference 1 Code
14.4. Packing group III 14.5. Environmental hazards IMDG Marine Pollutant: Yes ( Petroleum naphtha )
14.6. Special precautions for user Not Applicable 14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not Applicable
15. Regulatory information
Regulatory Overview The regulatory data in Section 15 is not intended to be all-inclusive, only selected regulations are represented. All ingredients of this product are listed on the TSCA (Toxic Substance Control Act) Inventory or are not required to be listed on the TSCA Inventory. WHMIS Classification B2 D2B E
DOT Marine Pollutants (10%): (No Product Ingredients Listed) DOT Severe Marine Pollutants (1%): (No Product Ingredients Listed) EPCRA 311/312 Chemicals and RQs (>.1%) : Cumene (5000 lb final RQ; 2270 kg final RQ) Benzene, ethyl- (1000 lb final RQ; 454 kg final RQ) Butanol (5000 lb final RQ; 2270 kg final RQ) Xylenes (o-, m-, p- isomers) (100 lb final RQ; 45.4 kg final RQ) EPCRA 302 Extremely Hazardous (>.1%) : (No Product Ingredients Listed) EPCRA 313 Toxic Chemicals (>.1%) : 1,2,4-Trimethyl benzene Cumene Benzene, ethyl- Butanol Xylenes (o-, m-, p- isomers) Mass RTK Substances (>1%) : 1,2,4-Trimethyl benzene
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Barium sulfate Limestone Butanol Titanium dioxide 1,3,5-Trimethylbenzene Xylenes (o-, m-, p- isomers) Penn RTK Substances (>1%) : 1,2,4-Trimethyl benzene Barium sulfate Limestone Butanol Titanium dioxide Xylenes (o-, m-, p- isomers) Penn Special Hazardous Substances (>.01%) : (No Product Ingredients Listed) RCRA Status: (No Product Ingredients Listed) N.J. RTK Substances (>1%) : 1,2,4-Trimethyl benzene Barium sulfate Limestone Butanol Titanium dioxide Xylenes (o-, m-, p- isomers) N.J. Special Hazardous Substances (>.01%) : Carbon black Cumene Ethyl alcohol Benzene, ethyl- Isopropyl alcohol Methanol Butanol Quartz Xylenes (o-, m-, p- isomers) N.J. Env. Hazardous Substances (>.1%) : 1,2,4-Trimethyl benzene Cumene Benzene, ethyl- Butanol Xylenes (o-, m-, p- isomers) Proposition 65 - Carcinogens (>0%): Carbon black Cumene Ethyl alcohol Benzene, ethyl- Methylisobutyl ketone Naphthalene Quartz Titanium dioxide Proposition 65 - Female Repro Toxins (>0%): (No Product Ingredients Listed) Proposition 65 - Male Repro Toxins (>0%): (No Product Ingredients Listed) Proposition 65 - Developmental Toxins (>0%): Ethyl alcohol Methanol
16. Other information
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The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or warranty of any kind, expressed or implied, is made with respect to the information contained herein. We accept no responsibility and disclaim all liability for any harmful effects which may be caused by exposure to our products. Customers/users of this product must comply with all applicable health and safety laws, regulations, and orders.
The full text of the phrases appearing in section 3 is:
H226 Flammable liquid and vapor. H302 Harmful if swallowed. H304 May be fatal if swallowed and enters airways. H312 Harmful in contact with skin. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H319 Causes serious eye irritation. H332 Harmful if inhaled. H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness. H351 Suspected of causing cancer. H372 Causes damage to organs through prolonged or repeated exposure. H411 Toxic to aquatic life with long lasting effects.
The following sections have changed since the previous revision.
End of Document
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Safety Data Sheet INTERPRIME 198 RED
Sales Order: {SalesOrd} Bulk Sales Reference No.: CPA099 SDS Revision Date: 01/27/2015 SDS Revision Number: Q4-3
1. Identification of the preparation and company
1.1. Product identifier Product Identity INTERPRIME 198 RED Bulk Sales Reference No. CPA099
1.2. Relevant identified uses of the substance or mixture and uses advised against Intended Use See Technical Data Sheet. Application Method See Technical Data Sheet.
1.3. Details of the supplier of the safety data sheet Company Name International Paint LLC 6001 Antoine Drive Houston Texas 77091
Emergency CHEMTREC (USA) (800) 424-9300 International Paint (713) 682-1711 Poison Control Center (800) 854-6813 Customer Service International Paint (800) 589-1267 Fax No. (800) 631-7481
2. Hazard identification of the product
2.1. Classification of the substance or mixture Flam. Liq. 3;H226 Flammable liquid and vapor. Skin Irrit. 2;H315 Causes skin irritation. Eye Dam. 1;H318 Causes serious eye damage. Aquatic Chronic 2;H411 Toxic to aquatic life with long lasting effects.
2.2. Label elements Using the Toxicity Data listed in section 11 & 12 the product is labelled as follows.
Danger. H226 Flammable liquid and vapor. H315 Causes skin irritation. H318 Causes serious eye damage. H411 Toxic to aquatic life with long lasting effects.
P210 Keep away from heat / sparks / open flames / hot surfaces - No smoking. P260 Do not breathe mist / vapors / spray.
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P262 Do not get in eyes, on skin, or on clothing. P273 Avoid release to the environment. P280 Wear protective gloves / eye protection / face protection. P301+310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P302+352 IF ON SKIN: Wash with soap and water. P303+361+353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P305+351+338 IF IN EYES: Rinse continuously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing. P310 Immediately call a POISON CENTER or doctor / physician. P331 Do NOT induce vomiting. P362 Take off contaminated clothing and wash before reuse. P370 In case of fire: Use water spray, fog, or regular foam.. P391 Collect spillage. P403+233 Store in a well ventilated place. Keep container tightly closed. P501 Dispose of contents / container in accordance with local / national regulations.
HMIS Rating Health: 2* Flammability: 3 Reactivity: 0
3. Composition/information on ingredients
This product contains the following substances that present a hazard within the meaning of the relevant State and Federal Hazardous Substances regulations. Ingredient/Chemical Weight % GHS Classification Notes Designations Petroleum naphtha 10 - 25 Asp. Tox. 1;H304 [1] CAS Number: 0064742-95-6 Aquatic Chronic 2;H411 (Self Classification) Limestone 10 - 25 ---- [1] CAS Number: 0001317-65-3 1,2,4-Trimethyl benzene 10 - 25 Flam. Liq. 3;H226 [1] CAS Number: 0000095-63-6 Acute Tox. 4;H332 Eye Irrit. 2;H319 STOT SE 3;H335 Skin Irrit. 2;H315 Aquatic Chronic 2;H411 Wollastonite (Ca(SiO3)) 1.0 - 10 ---- [1] CAS Number: 0013983-17-0 Barium sulfate 1.0 - 10 ---- [1][2] CAS Number: 0007727-43-7 Xylenes (o-, m-, p- isomers) 1.0 - 10 Flam. Liq. 3;H226 [1][2] CAS Number: 0001330-20-7 Acute Tox. 4;H332 Acute Tox. 4;H312 Skin Irrit. 2;H315 Eye Irrit. 2;H319 STOT SE 3;H335 Asp. Tox. 1;H304 Butanol 1.0 - 10 Flam. Liq. 3;H226 [1][2] CAS Number: 0000071-36-3 Acute Tox. 4;H302 STOT SE 3;H335 Skin Irrit. 2;H315 Eye Dam. 1;H318 STOT SE 3;H336 Iron oxide 1.0 - 10 ---- [1][2] CAS Number: 0001309-37-1 1,3,5-Trimethylbenzene 1.0 - 10 Flam. Liq. 3;H226 [1] CAS Number: 0000108-67-8 STOT SE 3;H335 Aquatic Chronic 2;H411 Methyl ethyl ketoxime 0.10 - 1.0 Carc. 2;H351 [1] CAS Number: 0000096-29-7 Acute Tox. 4;H312
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Eye Dam. 1;H318 Skin Sens. 1;H317 [1] Substance classified with a health or environmental hazard. [2] Substance with a workplace exposure limit. [3] PBT-substance or vPvB-substance.
*The full texts of the phrases are shown in Section 16.
4. First aid measures
4.1. Description of first aid measures General Remove contaminated clothing and shoes. Get medical attention immediately. Wash clothing before reuse. Thoroughly clean or destroy contaminated shoes. Inhalation If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately. Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention immediately. Skin In case of contact, immediately flush skin with soap and plenty of water. Get medical attention immediately. Ingestion If swallowed, immediately contact Poison Control Center at 1-800-854-6813. DO NOT induce vomiting unless instructed to do so by medical personnel. Never give anything by mouth to an unconscious person. 4.2. Most important symptoms and effects, both acute and delayed Overview NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. Avoid contact with eyes, skin and clothing. Inhalation Harmful if inhaled. Causes lung irritation. Causes nose and throat irritation. Vapors may affect the brain or nervous system causing dizziness, headache or nausea. Eyes Causes severe eye irritation. Avoid contact with eyes. Skin Causes skin irritation. May be harmful if absorbed through the skin. Ingestion Harmful if swallowed. May cause abdominal pain, nausea, vomiting, diarrhea, or drowsiness. Chronic effects Possible cancer hazard. Contains an ingredient which may cause cancer based on animal data (See Section 2 and Section 15 for each ingredient). Risk of cancer depends on duration and level of exposure.
5. Fire-fighting measures
5.1. Extinguishing media CAUTION: This product has a very low flashpoint. Use of water spray when fighting fire may be inefficient. CAUTION: For mixtures containing alcohol or polar solvent, alcohol-resistant foam may be more effective. SMALL FIRES: Use dry chemical, CO2, water spray or regular foam. LARGE FIRES: Use water spray, fog, or regular foam. Do not use straight streams. Move containers from fire area if you can do so without risk. 5.2. Special hazards arising from the substance or mixture HIGHLY FLAMMABLE MATERIALS: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks) creating a vapor explosion hazard. Runoff to sewers may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water. 5.3. Advice for fire-fighters Cool closed containers exposed to fire by spraying them with water. Do not allow run off water and contaminants from fire fighting to enter drains or water courses. ERG Guide No. 128
6. Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures ELIMINATE ALL IGNITION SOURCES (no smoking, flares, sparks or flames in immediate area). Use only non-sparking equipment to handle spilled material and absorbent. Do not touch or walk through spilled material. Stop leak if you can do so without risk. Prevent entry into waterways, sewers, basements or confined areas. A vapor suppressing foam may be used to reduce vapors. Absorb or cover with dry earth, sand, or other non-combustible material and transfer to containers. Use non-sparking tools to collect absorbed material.
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6.2. Environmental precautions Do not allow spills to enter drains or watercourses. 6.3. Methods and material for containment and cleaning up CALL CHEMTREC at (800)-424-9300 for emergency response. Isolate spill or leak area immediately for at least 50 meters (150 feet) in all directions. Keep unauthorized personnel away. Stay upwind. Keep out of low areas. Ventilate closed spaces before entering. LARGE SPILLS: Consider initial downwind evacuation for at least 300 meters (1000 feet).
7. Handling and storage
7.1. Precautions for safe handling Handling Vapors may cause flash fire or ignite explosively.
In Storage Keep away from heat, sparks and flame.
7.2. Conditions for safe storage, including any incompatibilities Store between 40-100F (4-38C). Do not get in eyes, on skin or clothing. Strong oxidizing agents. Do not smoke. Extinguish all flames and pilot lights, and turn off stoves, heaters, electric motors and other sources of ignition during use and until all vapors are gone.
7.3. Specific end use(s) Close container after each use. Wash thoroughly after handling. Prevent build-up of vapors by opening all windows and doors to achieve cross-ventilation.
8. Exposure controls and personal protection
8.1. Control parameters Exposure CAS No. Ingredient Source Value 0000071-36-3 Butanol OSHA 100 ppm TWA; 300 mg/m3 TWA50 ppm Ceiling; 150 mg/m3 Ceiling ACGIH 20 ppm TWA NIOSH 50 ppm Ceiling; 150 mg/m3 Ceiling1400 ppm IDLH (10% LEL) Supplier OHSA, 20 ppm TWA CAN Mexico Brazil 40 ppm TWA LT; 115 mg/m3 TWA LT 0000095-63-6 1,2,4-Trimethyl benzene OSHA ACGIH NIOSH 25 ppm TWA; 125 mg/m3 TWA Supplier OHSA, CAN Mexico Brazil 0000096-29-7 Methyl ethyl ketoxime OSHA ACGIH NIOSH Supplier OHSA, CAN Mexico
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Brazil 0000108-67-8 1,3,5-Trimethylbenzene OSHA ACGIH NIOSH 25 ppm TWA; 125 mg/m3 TWA Supplier OHSA, CAN Mexico Brazil 0001309-37-1 Iron oxide OSHA 10 mg/m3 TWA (fume); 15 mg/m3 TWA (total dust, listed under Rouge); 5 mg/m3 TWA (respirable fra ACGIH 5 mg/m3 TWA (respirable fraction) NIOSH 5 mg/m3 TWA (dust and fume, as Fe)2500 mg/m3 IDLH (dust and fume, as Fe) Supplier OHSA, 5 mg/m3 TWA (respirable) CAN Mexico 5 mg/m3 TWA LMPE-PPT10 mg/m3 STEL [LMPE-CT] (as Fe) Brazil 0001317-65-3 Limestone OSHA 15 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction) ACGIH NIOSH 10 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable dust) Supplier OHSA, CAN Mexico 10 mg/m3 TWA LMPE-PPT20 mg/m3 STEL [LMPE-CT] Brazil 0001330-20-7 Xylenes (o-, m-, p- isomers) OSHA 100 ppm TWA; 435 mg/m3 TWA150 ppm STEL; 655 mg/m3 STEL ACGIH 100 ppm TWA150 ppm STEL NIOSH Supplier OHSA, 100 ppm TWA150 ppm STEL CAN Mexico 100 ppm TWA LMPE-PPT; 435 mg/m3 TWA LMPE-PPT150 ppm STEL [LMPE-CT]; 655 mg/m3 STEL [LMPE-CT] Brazil 78 ppm TWA LT; 340 mg/m3 TWA LT 0007727-43-7 Barium sulfate OSHA 15 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction) ACGIH 10 mg/m3 TWA NIOSH 10 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable dust) Supplier OHSA, 10 mg/m3 TWA CAN Mexico Brazil 0013983-17-0 Wollastonite (Ca(SiO3)) OSHA ACGIH NIOSH Supplier OHSA, CAN Mexico Brazil
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0064742-95-6 Petroleum naphtha OSHA ACGIH NIOSH Supplier OHSA, CAN Mexico Brazil
Health Data CAS No. Ingredient Source Value 0000071-36-3 Butanol NIOSH Eye and mucous membrane irritation CNS depression 0000095-63-6 1,2,4-Trimethyl benzene NIOSH 0000096-29-7 Methyl ethyl ketoxime NIOSH 0000108-67-8 1,3,5-Trimethylbenzene NIOSH 0001309-37-1 Iron oxide NIOSH Benign pneumoconiosis termed siderosis 0001317-65-3 Limestone NIOSH Eye and skin irritation Physical irritation 0001330-20-7 Xylenes (o-, m-, p- isomers) NIOSH Central nervous system depressant; respiratory and eye irritation 0007727-43-7 Barium sulfate NIOSH Eye nose 0013983-17-0 Wollastonite (Ca(SiO3)) NIOSH 0064742-95-6 Petroleum naphtha NIOSH
Carcinogen Data CAS No. Ingredient Source Value 0000071-36-3 Butanol OSHA Select Carcinogen: No NTP Known: No; Suspected: No IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No; 0000095-63-6 1,2,4-Trimethyl benzene OSHA Select Carcinogen: No NTP Known: No; Suspected: No IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No; 0000096-29-7 Methyl ethyl ketoxime OSHA Select Carcinogen: No NTP Known: No; Suspected: No IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No; 0000108-67-8 1,3,5-Trimethylbenzene OSHA Select Carcinogen: No NTP Known: No; Suspected: No IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No; 0001309-37-1 Iron oxide OSHA Select Carcinogen: No NTP Known: No; Suspected: No IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: Yes; Group 4: No; 0001317-65-3 Limestone OSHA Select Carcinogen: No NTP Known: No; Suspected: No IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No; 0001330-20-7 Xylenes (o-, m-, p- OSHA Select Carcinogen: No isomers) NTP Known: No; Suspected: No IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: Yes; Group 4: No; 0007727-43-7 Barium sulfate OSHA Select Carcinogen: No NTP Known: No; Suspected: No IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No; 0013983-17-0 Wollastonite (Ca(SiO3)) OSHA Select Carcinogen: No
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NTP Known: No; Suspected: No IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: Yes; Group 4: No; 0064742-95-6 Petroleum naphtha OSHA Select Carcinogen: No NTP Known: No; Suspected: No IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No;
8.2. Exposure controls Respiratory Select equipment to provide protection from the ingredients listed in Section 3 of this document. Ensure fresh air entry during application and drying. If you experience eye watering, headache or dizziness or if air monitoring demonstrates dust, vapor, or mist levels are above applicable limits, wear an appropriate, properly fitted respirator (NIOSH approved) during and after application. Follow respirator manufacturer's directions for respirator use. FOR USERS OF 3M RESPIRATORY PROTECTION ONLY: For information and assistance on 3M occupational health and safety products, call OH&ESD Technical Service toll free in U.S.A. 1-800-243-4630, in Canada call 1-800-267-4414. Please do not contact these numbers regarding other manufacturer's respiratory protection products. 3M does not endorse the accuracy of the information contained in this Material Safety Data Sheet. Eyes Avoid contact with eyes. Protective equipment should be selected to provide protection from exposure to the chemicals listed in Section 3 of this document. Depending on the site-specific conditions of use, safety glasses, chemical goggles, and/or head and face protection may be required to prevent contact. The equipment must be thoroughly cleaned, or discarded after each use. Skin Protective equipment should be selected to provide protection from exposure to the chemicals listed in Section 3 of this document. Depending on the site-specific conditions of use, protective gloves, apron, boots, head and face protection may be required to prevent contact. The equipment must be thoroughly cleaned, or discarded after each use. Engineering Controls Depending on the site-specific conditions of use, provide adequate ventilation. Other Work Practices Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. Use good personal hygiene practices. Wash hands before eating, drinking, using toilet facilities, etc. Promptly remove soiled clothing and wash clothing thoroughly before reuse. Shower after work using plenty of soap and water.
9. Physical and chemical properties
Appearance Coloured Liquid Odour threshold Not Measured pH No Established Limit Melting point / freezing point Not Measured Initial boiling point and boiling range 76 (°C) 169 (°F) Flash Point 35 (°C) 95 (°F) Evaporation rate (Ether = 1) Not Measured Flammability (solid, gas) Not Applicable Upper/lower flammability or explosive Lower Explosive Limit: .9 limits Upper Explosive Limit: No Established Limit vapor pressure (Pa) Not Measured Vapor Density Heavier than air Specific Gravity 1.34 Partition coefficient n-octanol/water (Log Not Measured Kow) Auto-ignition temperature Not Measured Decomposition temperature Not Measured Viscosity (cSt) No Established Limit Not Measured Refer to the Technical Data Sheet or label where information is VOC % available.
10. Stability and reactivity
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10.1. Reactivity No data available 10.2. Chemical stability This product is stable and hazardous polymerization will not occur. Not sensitive to mechanical impact. Excessive heat and fumes generation can occur if improperly handled. 10.3. Possibility of hazardous reactions No data available 10.4. Conditions to avoid No data available 10.5. Incompatible materials Strong oxidizing agents. 10.6. Hazardous decomposition products HIGHLY FLAMMABLE MATERIALS: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks) creating a vapor explosion hazard. Runoff to sewers may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.
11. Toxicological information
Acute toxicity
NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal.
Ingredient Oral LD50, Skin LD50, Inhalation Inhalation mg/kg mg/kg Vapor LD50, Dust/Mist LD50, mg/L/4hr mg/L/4hr Petroleum naphtha - (64742-95-6) 6,800.00, Rat - 3,400.00, No data No data available Category: NA Rabbit - available Category: 5 Limestone - (1317-65-3) No data No data No data No data available available available available 1,2,4-Trimethyl benzene - (95-63-6) 3,400.00, Rat - 3,160.00, 18.00, Rat - No data available Category: 5 Rabbit - Category: 4 Category: 5 Wollastonite (Ca(SiO3)) - (13983-17-0) No data No data No data No data available available available available Barium sulfate - (7727-43-7) 3,000.00, No data No data No data available Mouse - available available Category: 5 Xylenes (o-, m-, p- isomers) - 4,299.00, Rat - 1,548.00, 20.00, Rat - No data available (1330-20-7) Category: 5 Rabbit - Category: 4 Category: 4 Butanol - (71-36-3) 2,292.00, Rat - 3,430.00, No data No data available Category: 5 Rabbit - available Category: 5 Iron oxide - (1309-37-1) 10,000.00, Rat No data No data No data available - Category: NA available available
1,3,5-Trimethylbenzene - (108-67-8) No data No data 24.00, Rat - No data available available available Category: NA Methyl ethyl ketoxime - (96-29-7) 930.00, Rat - 2,000.00, 20.00, Rat - No data available Category: 4 Rabbit - Category: 4 Category: 4
Item Category Hazard Acute Toxicity (mouth) Not Classified Not Applicable Acute Toxicity (skin) Not Classified Not Applicable Acute Toxicity (inhalation) Not Classified Not Applicable
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Skin corrosion/irritation 2 Causes skin irritation. Eye damage/irritation 1 Causes serious eye damage. Sensitization (respiratory) Not Classified Not Applicable Sensitization (skin) Not Classified Not Applicable Germ toxicity Not Classified Not Applicable Carcinogenicity Not Classified Not Applicable Reproductive Toxicity Not Classified Not Applicable Specific target organ systemic toxicity Not Classified Not Applicable (single exposure) Specific target organ systemic Not Classified Not Applicable Toxicity (repeated exposure) Aspiration hazard Not Classified Not Applicable
12. Ecological information
12.1. Toxicity No additional information provided for this product. See Section 3 for chemical specific data.
Aquatic Ecotoxicity
96 hr LC50 fish, 48 hr EC50 crustacea, ErC50 algae, Ingredient mg/l mg/l mg/l Petroleum naphtha - 9.22, Oncorhynchus 6.14, Daphnia magna 19.00 (72 hr), Selenastrum (64742-95-6) mykiss capricornutum Limestone - (1317-65-3) Not Available Not Available Not Available 1,2,4-Trimethyl benzene - 7.72, Pimephales 3.60, Daphnia magna Not Available (95-63-6) promelas Wollastonite (Ca(SiO3)) - Not Available Not Available Not Available (13983-17-0) Barium sulfate - (7727-43-7) 59,000.00, Poecilia 32.00, Daphnia Not Available sphenops magna Xylenes (o-, m-, p- isomers) 3.30, Oncorhynchus 8.50, Palaemonetes - (1330-20-7) mykiss pugio 100.00 (72 hr), Chlorococcales
Butanol - (71-36-3) 1,328.00, Daphnia 500.00 (96 hr), Scenedesmus 1,376.00, Pimephales magna subspicatus promelas Iron oxide - (1309-37-1) Not Available Not Available Not Available 1,3,5-Trimethylbenzene - 12.52, Carassius 6.00, Daphnia magna 25.00 (48 hr), Scenedesmus (108-67-8) auratus subspicatus Methyl ethyl ketoxime - 320.00, Leuciscus 500.00, Daphnia 83.00 (72 hr), Scenedesmus (96-29-7) idus magna subspicatus
12.2. Persistence and degradability No data available 12.3. Bioaccumulative potential Not Measured 12.4. Mobility in soil No data available 12.5. Results of PBT and vPvB assessment This product contains no PBT/vPvB chemicals. 12.6. Other adverse effects No data available
13. Disposal considerations
13.1. Waste treatment methods
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Do not allow spills to enter drains or watercourses. Dispose of in accordance with local, state and federal regulations. (Also reference RCRA information in Section 15 if listed).
14. Transport information
14.1. UN number UN 1263 14.2. UN proper shipping name PAINT 14.3. Transport hazard class(es)
DOT (Domestic Surface Transportation) IMO / IMDG (Ocean Transportation) DOT Proper Shipping PAINT IMDG Proper PAINT Name Shipping Name DOT Hazard Class 3 IMDG Hazard Class 3 Sub Class 3 UN / NA Number UN 1263 DOT Packing Group III IMDG Packing Group III CERCLA/DOT RQ 288 gal. / 3204 lbs. System Reference 2 Code
14.4. Packing group III 14.5. Environmental hazards IMDG Marine Pollutant: Yes ( Petroleum naphtha )
14.6. Special precautions for user Not Applicable 14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not Applicable
15. Regulatory information
Regulatory Overview The regulatory data in Section 15 is not intended to be all-inclusive, only selected regulations are represented. All ingredients of this product are listed on the TSCA (Toxic Substance Control Act) Inventory or are not required to be listed on the TSCA Inventory. WHMIS Classification B2 D2B E
DOT Marine Pollutants (10%): (No Product Ingredients Listed) DOT Severe Marine Pollutants (1%): (No Product Ingredients Listed) EPCRA 311/312 Chemicals and RQs (>.1%) : Cumene (5000 lb final RQ; 2270 kg final RQ) Benzene, ethyl- (1000 lb final RQ; 454 kg final RQ) Butanol (5000 lb final RQ; 2270 kg final RQ) Xylenes (o-, m-, p- isomers) (100 lb final RQ; 45.4 kg final RQ) EPCRA 302 Extremely Hazardous (>.1%) : (No Product Ingredients Listed) EPCRA 313 Toxic Chemicals (>.1%) : 1,2,4-Trimethyl benzene Cumene Benzene, ethyl- Butanol Xylenes (o-, m-, p- isomers) Mass RTK Substances (>1%) : 1,2,4-Trimethyl benzene Barium sulfate Iron oxide Limestone
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Butanol 1,3,5-Trimethylbenzene Xylenes (o-, m-, p- isomers) Penn RTK Substances (>1%) : 1,2,4-Trimethyl benzene Barium sulfate Iron oxide Limestone Butanol Xylenes (o-, m-, p- isomers) Penn Special Hazardous Substances (>.01%) : (No Product Ingredients Listed) RCRA Status: (No Product Ingredients Listed) N.J. RTK Substances (>1%) : 1,2,4-Trimethyl benzene Barium sulfate Iron oxide Limestone Butanol Xylenes (o-, m-, p- isomers) N.J. Special Hazardous Substances (>.01%) : Cumene Ethyl alcohol Benzene, ethyl- Isopropyl alcohol Methanol Butanol Quartz Xylenes (o-, m-, p- isomers) N.J. Env. Hazardous Substances (>.1%) : 1,2,4-Trimethyl benzene Cumene Benzene, ethyl- Butanol Xylenes (o-, m-, p- isomers) Proposition 65 - Carcinogens (>0%): Cumene Ethyl alcohol Benzene, ethyl- Methylisobutyl ketone Naphthalene Quartz Proposition 65 - Female Repro Toxins (>0%): (No Product Ingredients Listed) Proposition 65 - Male Repro Toxins (>0%): (No Product Ingredients Listed) Proposition 65 - Developmental Toxins (>0%): Ethyl alcohol Methanol
16. Other information
The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or warranty of any kind, expressed or implied, is made with respect to the information contained herein. We accept no responsibility and disclaim all liability for any harmful effects which may be caused by exposure to our products. Customers/users of this product must comply with all applicable health and safety laws, regulations, and orders.
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The full text of the phrases appearing in section 3 is:
H226 Flammable liquid and vapor. H302 Harmful if swallowed. H304 May be fatal if swallowed and enters airways. H312 Harmful in contact with skin. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H319 Causes serious eye irritation. H332 Harmful if inhaled. H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness. H351 Suspected of causing cancer. H372 Causes damage to organs through prolonged or repeated exposure. H411 Toxic to aquatic life with long lasting effects.
The following sections have changed since the previous revision.
End of Document
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Safety Data Sheet INTERNATIONAL THINNER/EQPT CLEANER
Sales Order: {SalesOrd} Bulk Sales Reference No.: GTA007 SDS Revision Date: 08/28/2015 SDS Revision Number: M3-5
1. Identification of the preparation and company
1.1. Product identifier Product Identity INTERNATIONAL THINNER/EQPT CLEANER Bulk Sales Reference No. GTA007
1.2. Relevant identified uses of the substance or mixture and uses advised against Intended Use See Technical Data Sheet. Application Method See Technical Data Sheet.
1.3. Details of the supplier of the safety data sheet Company Name International Paint LLC 6001 Antoine Drive Houston, Texas 77091
Emergency CHEMTREC (USA) (800) 424-9300 International Paint (713) 682-1711 Poison Control Center (800) 854-6813 Customer Service International Paint (800) 589-1267 Fax No. (800) 631-7481
2. Hazard identification of the product
2.1. Classification of the substance or mixture Flam. Liq. 3;H226 Flammable liquid and vapor. Acute Tox. 4;H312 Harmful in contact with skin. Acute Tox. 4;H332 Harmful if inhaled. Skin Irrit. 2;H315 Causes skin irritation. Eye Irrit. 2;H319 Causes serious eye irritation. STOT RE 2;H373 May cause damage to organs through prolonged or repeated exposure. Aquatic Acute 2;H401 Toxic to aquatic life.
2.2. Label elements Using the Toxicity Data listed in section 11 & 12 the product is labelled as follows.
Warning. H226 Flammable liquid and vapor. H312 Harmful in contact with skin. H315 Causes skin irritation. H319 Causes serious eye irritation.
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H332 Harmful if inhaled. H335 May cause respiratory irritation. H373 May cause damage to organs through prolonged or repeated exposure. H401 Toxic to aquatic life.
P210 Keep away from heat / sparks / open flames / hot surfaces - No smoking. P260 Do not breathe mist / vapors / spray. P271 Use only outdoors or in a well-ventilated area. P273 Avoid release to the environment. P280 Wear protective gloves / eye protection / face protection. P302+352 IF ON SKIN: Wash with soap and water. P303+361+353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P304+312 IF INHALED: Call a POISON CENTER or doctor/physician if you feel unwell. P305+351+338 IF IN EYES: Rinse continuously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing. P314 Get Medical advice / attention if you feel unwell. P337+313 If eye irritation persists: Get medical advice / attention. P340 Remove victim to fresh air and keep at rest in a position comfortable for breathing. P362 Take off contaminated clothing and wash before reuse. P363 Wash contaminated clothing before reuse. P370 In case of fire: Use water spray, fog, or regular foam.. P403+233 Store in a well ventilated place. Keep container tightly closed. P405 Store locked up. P501 Dispose of contents / container in accordance with local / national regulations.
HMIS Rating Health: 2* Flammability: 3 Reactivity: 0
3. Composition/information on ingredients
This product contains the following substances that present a hazard within the meaning of the relevant State and Federal Hazardous Substances regulations. Ingredient/Chemical Weight % GHS Classification Notes Designations Xylenes (o-, m-, p- isomers) 75 - 100 Flam. Liq. 3;H226 [1][2] CAS Number: 0001330-20-7 Acute Tox. 4;H332 Acute Tox. 4;H312 Skin Irrit. 2;H315 Eye Irrit. 2;H319 STOT SE 3;H335 Asp. Tox. 1;H304 Benzene, ethyl- 10 - 25 Flam. Liq. 2;H225 [1][2] CAS Number: 0000100-41-4 Acute Tox. 4;H332 Asp. Tox. 1;H304 Eye Irrit. 2;H319 Skin Irrit. 2;H315 STOT SE 3;H335 STOT RE 2;H373 [1] Substance classified with a health or environmental hazard. [2] Substance with a workplace exposure limit. [3] PBT-substance or vPvB-substance.
*The full texts of the phrases are shown in Section 16.
4. First aid measures
4.1. Description of first aid measures General Remove contaminated clothing and shoes. Get medical attention immediately. Wash clothing before reuse. Thoroughly clean or destroy contaminated shoes. Inhalation If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately. Eyes
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In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention immediately. Skin In case of contact, immediately flush skin with soap and plenty of water. Get medical attention immediately. Ingestion If swallowed, immediately contact Poison Control Center at 1-800-854-6813. DO NOT induce vomiting unless instructed to do so by medical personnel. Never give anything by mouth to an unconscious person. 4.2. Most important symptoms and effects, both acute and delayed Overview NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. Avoid contact with eyes, skin and clothing. Inhalation Harmful if inhaled. May cause allergic respiratory reaction. May cause mucous membrane and respiratory tract irritation, tightness of chest, headache, shortness of breath and dry cough. May cause asthma-like symptoms to occur. Vapors may affect the brain or nervous system causing dizziness, headache or nausea. Eyes Causes severe eye irritation. Avoid contact with eyes. Skin Causes skin irritation. May be harmful if absorbed through the skin. Ingestion Harmful if swallowed. May cause abdominal pain, nausea, vomiting, diarrhea, or drowsiness. Chronic effects Possible cancer hazard. Contains an ingredient which may cause cancer based on animal data (See Section 2 and Section 15 for each ingredient). Risk of cancer depends on duration and level of exposure.
5. Fire-fighting measures
5.1. Extinguishing media CAUTION: This product has a very low flashpoint. Use of water spray when fighting fire may be inefficient. SMALL FIRES: Use dry chemical, CO2, water spray or alcohol-resistant foam. LARGE FIRES: Use water spray, fog, or alcohol-resistant foam. Do not use straight streams. Move containers from fire area if you can do so without risk. Runoff from fire control may cause pollution. Dike fire control water for later disposal. Do not scatter the material. 5.2. Special hazards arising from the substance or mixture FLAMMABLE/COMBUSTIBLE MATERIALS: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks) creating a vapor explosion hazard. Runoff to sewers may create fire or explosion hazard. Containers may explode when heated. 5.3. Advice for fire-fighters Cool closed containers exposed to fire by spraying them with water. Do not allow run off water and contaminants from fire fighting to enter drains or water courses. ERG Guide No. 127
6. Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures ELIMINATE ALL IGNITION SOURCES (no smoking, flares, sparks or flames in immediate area). Use only non-sparking equipment to handle spilled material and absorbent. Do not touch or walk through spilled material. Stop leak if you can do so without risk. Prevent entry into waterways, sewers, basements or confined areas. A vapor suppressing foam may be used to reduce vapors. Absorb or cover with dry earth, sand, or other non-combustible material and transfer to containers. Use non-sparking tools to collect absorbed material. 6.2. Environmental precautions Do not allow spills to enter drains or watercourses. 6.3. Methods and material for containment and cleaning up CALL CHEMTREC at (800)-424-9300 for emergency response. Isolate spill or leak area immediately for at least 25 to 50 meters (80 to 160 feet) in all directions. Keep unauthorized personnel away. Stay upwind. Keep out of low areas. Ventilate closed spaces before entering. LARGE SPILLS: Consider initial downwind evacuation for at least 300 meters (1000 feet).
7. Handling and storage
7.1. Precautions for safe handling
3/9 GTA007_M3
Handling Vapors may cause flash fire or ignite explosively.
In Storage Keep away from heat, sparks and flame.
7.2. Conditions for safe storage, including any incompatibilities Store between 40-100F (4-38C). Avoid contact with eyes, skin and clothing. Strong oxidizing agents. Do not smoke. Extinguish all flames and pilot lights, and turn off stoves, heaters, electric motors and other sources of ignition during use and until all vapors are gone.
7.3. Specific end use(s) Close container after each use. Wash thoroughly after handling. Prevent build-up of vapors by opening all windows and doors to achieve cross-ventilation.
8. Exposure controls and personal protection
8.1. Control parameters Exposure CAS No. Ingredient Source Value 0000100-41-4 Benzene, ethyl- OSHA 100 ppm TWA; 435 mg/m3 TWA125 ppm STEL; 545 mg/m3 STEL ACGIH 20 ppm TWA NIOSH 100 ppm TWA; 435 mg/m3 TWA125 ppm STEL; 545 mg/m3 STEL800 ppm IDLH (10% LEL) Supplier OHSA, 20 ppm TWA CAN Mexico 100 ppm TWA LMPE-PPT; 435 mg/m3 TWA LMPE-PPT125 ppm STEL [LMPE-CT]; 545 mg/m3 STEL [LMPE-CT] Brazil 78 ppm TWA LT; 340 mg/m3 TWA LT 0001330-20-7 Xylenes (o-, m-, p- isomers) OSHA 100 ppm TWA; 435 mg/m3 TWA150 ppm STEL; 655 mg/m3 STEL ACGIH 100 ppm TWA150 ppm STEL NIOSH Supplier OHSA, 100 ppm TWA150 ppm STEL CAN Mexico 100 ppm TWA LMPE-PPT; 435 mg/m3 TWA LMPE-PPT150 ppm STEL [LMPE-CT]; 655 mg/m3 STEL [LMPE-CT] Brazil 78 ppm TWA LT; 340 mg/m3 TWA LT
Health Data CAS No. Ingredient Source Value 0000100-41-4 Benzene, ethyl- NIOSH Eye skin 0001330-20-7 Xylenes (o-, m-, p- isomers) NIOSH Central nervous system depressant; respiratory and eye irritation
Carcinogen Data CAS No. Ingredient Source Value 0000100-41-4 Benzene, ethyl- OSHA Select Carcinogen: Yes NTP Known: No; Suspected: No IARC Group 1: No; Group 2a: No; Group 2b: Yes; Group 3: No; Group 4: No;
4/9 GTA007_M3
0001330-20-7 Xylenes (o-, m-, p- OSHA Select Carcinogen: No isomers) NTP Known: No; Suspected: No IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: Yes; Group 4: No;
8.2. Exposure controls Respiratory Select equipment to provide protection from the ingredients listed in Section 3 of this document. Ensure fresh air entry during application and drying. If you experience eye watering, headache or dizziness or if air monitoring demonstrates dust, vapor, or mist levels are above applicable limits, wear an appropriate, properly fitted respirator (NIOSH approved) during and after application. Follow respirator manufacturer's directions for respirator use. FOR USERS OF 3M RESPIRATORY PROTECTION ONLY: For information and assistance on 3M occupational health and safety products, call OH&ESD Technical Service toll free in U.S.A. 1-800-243-4630, in Canada call 1-800-267-4414. Please do not contact these numbers regarding other manufacturer's respiratory protection products. 3M does not endorse the accuracy of the information contained in this Material Safety Data Sheet. Eyes Avoid contact with eyes. Protective equipment should be selected to provide protection from exposure to the chemicals listed in Section 3 of this document. Depending on the site-specific conditions of use, safety glasses, chemical goggles, and/or head and face protection may be required to prevent contact. The equipment must be thoroughly cleaned, or discarded after each use. Skin Protective equipment should be selected to provide protection from exposure to the chemicals listed in Section 3 of this document. Depending on the site-specific conditions of use, protective gloves, apron, boots, head and face protection may be required to prevent contact. The equipment must be thoroughly cleaned, or discarded after each use. Engineering Controls Depending on the site-specific conditions of use, provide adequate ventilation. Other Work Practices Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. Use good personal hygiene practices. Wash hands before eating, drinking, using toilet facilities, etc. Promptly remove soiled clothing and wash clothing thoroughly before reuse. Shower after work using plenty of soap and water.
9. Physical and chemical properties
Appearance Coloured Liquid Odour threshold Not Measured pH Not Determined Melting point / freezing point Not Measured Initial boiling point and boiling range 137 (°C) 279 (°F) Flash Point 26 (°C) 78 (°F) Evaporation rate (Ether = 1) Not Measured Flammability (solid, gas) Not Applicable Upper/lower flammability or explosive Lower Explosive Limit: 1 limits Upper Explosive Limit: No Established Limit vapor pressure (Pa) Not Measured Vapor Density Heavier than air Specific Gravity 0.86 Solubility in Water Not Measured Partition coefficient n-octanol/water (Log Not Measured Kow) Auto-ignition temperature Not Measured Decomposition temperature Not Measured Viscosity (cSt) No Established Limit Not Measured Refer to the Technical Data Sheet or label where information is VOC % available.
10. Stability and reactivity
10.1. Reactivity
5/9 GTA007_M3
No data available 10.2. Chemical stability This product is stable and hazardous polymerization will not occur. Not sensitive to mechanical impact. Excessive heat and fumes generation can occur if improperly handled. 10.3. Possibility of hazardous reactions No data available 10.4. Conditions to avoid No data available 10.5. Incompatible materials Strong oxidizing agents. 10.6. Hazardous decomposition products FLAMMABLE/COMBUSTIBLE MATERIALS: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks) creating a vapor explosion hazard. Runoff to sewers may create fire or explosion hazard. Containers may explode when heated.
11. Toxicological information
Acute toxicity
NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal.
Ingredient Oral LD50, Skin LD50, Inhalation Inhalation mg/kg mg/kg Vapor LD50, Dust/Mist LD50, mg/L/4hr mg/L/4hr Xylenes (o-, m-, p- isomers) - 4,299.00, Rat - 1,548.00, 20.00, Rat - No data available (1330-20-7) Category: 5 Rabbit - Category: 4 Category: 4 Benzene, ethyl- - (100-41-4) 3,500.00, Rat - 15,433.00, 17.20, Rat - No data available Category: 5 Rabbit - Category: 4 Category: NA
Item Category Hazard Acute Toxicity (mouth) Not Classified Not Applicable Acute Toxicity (skin) 4 Harmful in contact with skin. Acute Toxicity (inhalation) 4 Harmful if inhaled. Skin corrosion/irritation 2 Causes skin irritation. Eye damage/irritation 2 Causes serious eye irritation. Sensitization (respiratory) Not Classified Not Applicable Sensitization (skin) Not Classified Not Applicable Germ toxicity Not Classified Not Applicable Carcinogenicity Not Classified Not Applicable Reproductive Toxicity Not Classified Not Applicable Specific target organ systemic toxicity Not Classified Not Applicable (single exposure) Specific target organ systemic 2 May cause damage to organs through prolonged Toxicity (repeated exposure) or repeated exposure. Aspiration hazard Not Classified Not Applicable
12. Ecological information
12.1. Toxicity No additional information provided for this product. See Section 3 for chemical specific data.
Aquatic Ecotoxicity
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96 hr LC50 fish, 48 hr EC50 crustacea, ErC50 algae, Ingredient mg/l mg/l mg/l Xylenes (o-, m-, p- isomers) 8.50, Palaemonetes 100.00 (72 hr), Chlorococcales - (1330-20-7) 3.30, Oncorhynchus pugio mykiss Benzene, ethyl- - (100-41-4) 2.93, Daphnia magna 4.20, Oncorhynchus 3.60 (96 hr), Pseudokirchneriella mykiss subcapitata
12.2. Persistence and degradability No data available 12.3. Bioaccumulative potential Not Measured 12.4. Mobility in soil No data available 12.5. Results of PBT and vPvB assessment This product contains no PBT/vPvB chemicals. 12.6. Other adverse effects No data available
13. Disposal considerations
13.1. Waste treatment methods Do not allow spills to enter drains or watercourses. Dispose of in accordance with local, state and federal regulations. (Also reference RCRA information in Section 15 if listed).
14. Transport information
14.1. UN number UN 1263 14.2. UN proper shipping name PAINT RELATED MATERIAL 14.3. Transport hazard class(es)
DOT (Domestic Surface Transportation) IMO / IMDG (Ocean Transportation) DOT Proper Shipping PAINT RELATED IMDG Proper PAINT RELATED Name MATERIAL Shipping Name MATERIAL DOT Hazard Class 3 IMDG Hazard Class 3 Sub Class 3 UN / NA Number UN 1263 DOT Packing Group III IMDG Packing Group III CERCLA/DOT RQ 17 gal. / 125 lbs. System Reference 30 Code
14.4. Packing group III 14.5. Environmental hazards IMDG Marine Pollutant: No
14.6. Special precautions for user Not Applicable 14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not Applicable
15. Regulatory information
Regulatory Overview The regulatory data in Section 15 is not intended to be all-inclusive, only selected regulations are represented. All ingredients of this product are listed on the TSCA (Toxic Substance Control Act) Inventory or are not required to be listed on the TSCA Inventory.
7/9 GTA007_M3
WHMIS Classification B2 D2B
DOT Marine Pollutants (10%): (No Product Ingredients Listed) DOT Severe Marine Pollutants (1%): (No Product Ingredients Listed) EPCRA 311/312 Chemicals and RQs (>.1%) : Benzene, ethyl- (1000 lb final RQ; 454 kg final RQ) Xylenes (o-, m-, p- isomers) (100 lb final RQ; 45.4 kg final RQ) EPCRA 302 Extremely Hazardous (>.1%) : (No Product Ingredients Listed) EPCRA 313 Toxic Chemicals (>.1%) : Benzene, ethyl- Xylenes (o-, m-, p- isomers) Mass RTK Substances (>1%) : Benzene, ethyl- Xylenes (o-, m-, p- isomers) Penn RTK Substances (>1%) : Benzene, ethyl- Xylenes (o-, m-, p- isomers) Penn Special Hazardous Substances (>.01%) : (No Product Ingredients Listed) RCRA Status: (No Product Ingredients Listed) N.J. RTK Substances (>1%) : Benzene, ethyl- Xylenes (o-, m-, p- isomers) N.J. Special Hazardous Substances (>.01%) : Benzene, ethyl- Xylenes (o-, m-, p- isomers) N.J. Env. Hazardous Substances (>.1%) : Benzene, ethyl- Xylenes (o-, m-, p- isomers) Proposition 65 - Carcinogens (>0%): Benzene, ethyl- Proposition 65 - Female Repro Toxins (>0%): (No Product Ingredients Listed) Proposition 65 - Male Repro Toxins (>0%): (No Product Ingredients Listed) Proposition 65 - Developmental Toxins (>0%): (No Product Ingredients Listed)
16. Other information
The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or warranty of any kind, expressed or implied, is made with respect to the information contained herein. We accept no responsibility and disclaim all liability for any harmful effects which may be caused by exposure to our products. Customers/users of this product must comply with all applicable health and safety laws, regulations, and orders.
The full text of the phrases appearing in section 3 is:
H225 Highly flammable liquid and vapor. H226 Flammable liquid and vapor. H304 May be fatal if swallowed and enters airways. H312 Harmful in contact with skin. H315 Causes skin irritation. H319 Causes serious eye irritation. H332 Harmful if inhaled.
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H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness. H372 Causes damage to organs through prolonged or repeated exposure. H373 May cause damage to organs through prolonged or repeated exposure.
The following sections have changed since the previous revision.
End of Document
9/9 SUB000_A2
Safety Data Sheet INTERFINE 5703 WHITE
Sales Order: {SalesOrd} Bulk Sales Reference No.: SUB000 SDS Revision Date: 07/24/2015 SDS Revision Number: A2-5
1. Identification of the preparation and company
1.1. Product identifier Product Identity INTERFINE 5703 WHITE Bulk Sales Reference No. SUB000
1.2. Relevant identified uses of the substance or mixture and uses advised against Intended Use See Technical Data Sheet. Application Method See Technical Data Sheet.
1.3. Details of the supplier of the safety data sheet Company Name International Paint LLC 6001 Antoine Drive Houston, Texas 77091
Emergency CHEMTREC (USA) (800) 424-9300 International Paint (713) 682-1711 Poison Control Center (800) 854-6813 Customer Service International Paint (800) 589-1267 Fax No. (800) 631-7481
2. Hazard identification of the product
2.1. Classification of the substance or mixture Flam. Liq. 3;H226 Flammable liquid and vapor. Skin Irrit. 3;H316 Causes mild skin irritation. Skin Sens. 1;H317 May cause an allergic skin reaction. Aquatic Chronic 3;H412 Harmful to aquatic life with long lasting effects.
2.2. Label elements Using the Toxicity Data listed in section 11 & 12 the product is labelled as follows.
Warning. H226 Flammable liquid and vapor. H316 Causes mild skin irritation. H317 May cause an allergic skin reaction. H412 Harmful to aquatic life with long lasting effects.
P210 Keep away from heat / sparks / open flames / hot surfaces - No smoking. P260 Do not breathe mist / vapors / spray.
1/14 SUB000_A2
P261 Avoid breathing dust / fume / gas / mist / vapors / spray. P262 Do not get in eyes, on skin, or on clothing. P272 Contaminated work clothing should not be allowed out of the workplace. P273 Avoid release to the environment. P280 Wear protective gloves / eye protection / face protection. P301+310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P302+352 IF ON SKIN: Wash with soap and water. P303+361+353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P331 Do NOT induce vomiting. P332+313 If skin irritation occurs: Get medical advice/attention. P333 If skin irritation or a rash occurs:. P363 Wash contaminated clothing before reuse. P370 In case of fire: Use water spray, fog, or regular foam.. P403+233 Store in a well ventilated place. Keep container tightly closed. P501 Dispose of contents / container in accordance with local / national regulations.
HMIS Rating Health: 2 Flammability: 3 Reactivity: 0
3. Composition/information on ingredients
This product contains the following substances that present a hazard within the meaning of the relevant State and Federal Hazardous Substances regulations. Ingredient/Chemical Designations Weight % GHS Classification Notes Titanium dioxide 10 - 25 ---- [1][2] CAS Number: 0013463-67-7 Barium sulfate 10 - 25 ---- [1][2] CAS Number: 0007727-43-7 Methyl n-amyl ketone 10 - 25 Flam. Liq. 3;H226 [1][2] CAS Number: 0000110-43-0 Acute Tox. 4;H332 Acute Tox. 4;H302 METHYLOXYDIMETHYLPHENYLSILOXANE 1.0 - 10 ---- [1] - EXPERIMENTAL POLYMER (PROPRIETARY) CAS Number: Proprietary Petroleum naphtha 1.0 - 10 Asp. Tox. 1;H304 [1] CAS Number: 0064742-95-6 Aquatic Chronic 2;H411 (Self Classification) Propylene glycol monomethyl ether acetate 1.0 - 10 Flam. Liq. 3;H226 [1] CAS Number: 0000108-65-6 1,2,4-Trimethyl benzene 1.0 - 10 Flam. Liq. 3;H226 [1] CAS Number: 0000095-63-6 Acute Tox. 4;H332 Eye Irrit. 2;H319 STOT SE 3;H335 Skin Irrit. 2;H315 Aquatic Chronic 2;H411 Xylenes (o-, m-, p- isomers) 1.0 - 10 Flam. Liq. 3;H226 [1][2] CAS Number: 0001330-20-7 Acute Tox. 4;H332 Acute Tox. 4;H312 Skin Irrit. 2;H315 Eye Irrit. 2;H319 STOT SE 3;H335 Asp. Tox. 1;H304 BUTYL ACETATE 1.0 - 10 Flam. Liq. 3;H226 [1][2] CAS Number: 0000123-86-4 STOT SE 3;H336 Bis (1,2,2,6,6-pentamethyl-4-piperidinyl) 0.10 - 1.0 Skin Sens. 1;H317 [1] sebacate Aquatic Chronic CAS Number: 0041556-26-7 1;H410 Aquatic Acute 1;H400 0.10 - 1.0 [1]
2/14 SUB000_A2
Methyl ethyl ketoxime Carc. 2;H351 CAS Number: 0000096-29-7 Acute Tox. 4;H312 Eye Dam. 1;H318 Skin Sens. 1;H317 DECANEDIOIC ACID, METHYL 0.10 - 1.0 Skin Sens. 1;H317 [1] 1,2,2,6,6-PENTAMETHYL-4-P Aquatic Chronic CAS Number: 0082919-37-7 1;H410 Hexanoic acid, 2-ethyl-, cobalt(2+) salt 0.10 - 1.0 Acute Tox. 4;H302 [1] CAS Number: 0000136-52-7 Skin Sens. 1;H317 Repr. 2;H361F Aquatic Acute 1;H400 Aquatic Chronic 1;H410 [1] Substance classified with a health or environmental hazard. [2] Substance with a workplace exposure limit. [3] PBT-substance or vPvB-substance.
*The full texts of the phrases are shown in Section 16.
4. First aid measures
4.1. Description of first aid measures General Remove contaminated clothing and shoes. Get medical attention immediately. Wash clothing before reuse. Thoroughly clean or destroy contaminated shoes. Inhalation If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately. Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention immediately. Skin In case of contact, immediately flush skin with soap and plenty of water. Get medical attention immediately. Ingestion If swallowed, immediately contact Poison Control Center at 1-800-854-6813. DO NOT induce vomiting unless instructed to do so by medical personnel. Never give anything by mouth to an unconscious person. 4.2. Most important symptoms and effects, both acute and delayed Overview NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. Avoid contact with eyes, skin and clothing. Inhalation Harmful if inhaled. Causes nose and throat irritation. Vapors may affect the brain or nervous system causing dizziness, headache or nausea. Eyes Risk of serious damage to eyes. Do not get in eyes. Protective equipment should be selected to provide protection from exposure to the chemicals listed in Section 3 of this document. Depending on the site-specific condition of use, safety glasses, chemical goggles, and/or head and face protection may be required to prevent contact. The equipment must be thouroughly cleaned, or discarded after each use. Skin Causes skin irritation. May cause delayed skin irritation. May be harmful if absorbed through the skin. Ingestion Harmful if swallowed. May cause abdominal pain, nausea, vomiting, diarrhea, or drowsiness. Chronic effects Possible cancer hazard. Contains an ingredient which may cause cancer based on animal data (See Section 2 and Section 15 for each ingredient). Risk of cancer depends on duration and level of exposure.
5. Fire-fighting measures
5.1. Extinguishing media CAUTION: This product has a very low flashpoint. Use of water spray when fighting fire may be inefficient. CAUTION: For mixtures containing alcohol or polar solvent, alcohol-resistant foam may be more effective. SMALL FIRES: Use dry chemical, CO2, water spray or regular foam. LARGE FIRES: Use water spray, fog, or regular foam. Do not use straight streams. Move containers from fire area if you can do so without risk. 5.2. Special hazards arising from the substance or mixture HIGHLY FLAMMABLE MATERIALS: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks)
3/14 SUB000_A2 creating a vapor explosion hazard. Runoff to sewers may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water. 5.3. Advice for fire-fighters Cool closed containers exposed to fire by spraying them with water. Do not allow run off water and contaminants from fire fighting to enter drains or water courses. ERG Guide No. 128
6. Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures ELIMINATE ALL IGNITION SOURCES (no smoking, flares, sparks or flames in immediate area). Use only non-sparking equipment to handle spilled material and absorbent. Do not touch or walk through spilled material. Stop leak if you can do so without risk. Prevent entry into waterways, sewers, basements or confined areas. A vapor suppressing foam may be used to reduce vapors. Absorb or cover with dry earth, sand, or other non-combustible material and transfer to containers. Use non-sparking tools to collect absorbed material. 6.2. Environmental precautions Do not allow spills to enter drains or watercourses. 6.3. Methods and material for containment and cleaning up CALL CHEMTREC at (800)-424-9300 for emergency response. Isolate spill or leak area immediately for at least 50 meters (150 feet) in all directions. Keep unauthorized personnel away. Stay upwind. Keep out of low areas. Ventilate closed spaces before entering. LARGE SPILLS: Consider initial downwind evacuation for at least 300 meters (1000 feet).
7. Handling and storage
7.1. Precautions for safe handling Handling Vapors may cause flash fire or ignite explosively.
In Storage Keep away from heat, sparks and flame.
7.2. Conditions for safe storage, including any incompatibilities Store between 40-100F (4-38C). Do not get in eyes, on skin or clothing. Strong oxidizing agents. Do not smoke. Extinguish all flames and pilot lights, and turn off stoves, heaters, electric motors and other sources of ignition during use and until all vapors are gone.
7.3. Specific end use(s) Close container after each use. Wash thoroughly after handling. Prevent build-up of vapors by opening all windows and doors to achieve cross-ventilation.
8. Exposure controls and personal protection
8.1. Control parameters Exposure CAS No. Ingredient Source Value 0000095-63-6 1,2,4-Trimethyl benzene OSHA ACGIH NIOSH 25 ppm TWA; 125 mg/m3 TWA Supplier OHSA, CAN Mexico Brazil 0000096-29-7 Methyl ethyl ketoxime OSHA ACGIH
4/14 SUB000_A2
NIOSH Supplier OHSA, CAN Mexico Brazil 0000108-65-6 Propylene glycol monomethyl ether acetate OSHA ACGIH NIOSH Supplier OHSA, 50 ppm TWA; 270 mg/m3 TWA CAN Mexico Brazil 0000110-43-0 Methyl n-amyl ketone OSHA 100 ppm TWA; 465 mg/m3 TWA ACGIH 50 ppm TWA NIOSH 100 ppm TWA; 465 mg/m3 TWA800 ppm IDLH Supplier OHSA, 25 ppm TWA; 115 mg/m3 TWA CAN Mexico 50 ppm TWA LMPE-PPT; 235 mg/m3 TWA LMPE-PPT100 ppm STEL [LMPE-CT]; 465 mg/m3 STEL [LMPE-CT] Brazil 0000123-86-4 BUTYL ACETATE OSHA 150 ppm TWA; 710 mg/m3 TWA200 ppm STEL; 950 mg/m3 STEL ACGIH 150 ppm TWA200 ppm STEL NIOSH 150 ppm TWA; 710 mg/m3 TWA200 ppm STEL; 950 mg/m3 STEL1700 ppm IDLH (10% LEL) Supplier OHSA, 150 ppm TWA200 ppm STEL CAN Mexico 150 ppm TWA LMPE-PPT; 710 mg/m3 TWA LMPE-PPT200 ppm STEL [LMPE-CT]; 950 mg/m3 STEL [LMPE-CT] Brazil 0000136-52-7 Hexanoic acid, 2-ethyl-, cobalt(2+) salt OSHA ACGIH NIOSH Supplier OHSA, CAN Mexico Brazil 0001330-20-7 Xylenes (o-, m-, p- isomers) OSHA 100 ppm TWA; 435 mg/m3 TWA150 ppm STEL; 655 mg/m3 STEL ACGIH 100 ppm TWA150 ppm STEL NIOSH Supplier OHSA, 100 ppm TWA150 ppm STEL CAN Mexico 100 ppm TWA LMPE-PPT; 435 mg/m3 TWA LMPE-PPT150 ppm STEL [LMPE-CT]; 655 mg/m3 STEL [LMPE-CT] Brazil 78 ppm TWA LT; 340 mg/m3 TWA LT
5/14 SUB000_A2
0007727-43-7 Barium sulfate OSHA 15 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction) ACGIH 10 mg/m3 TWA NIOSH 10 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable dust) Supplier OHSA, 10 mg/m3 TWA CAN Mexico Brazil 0013463-67-7 Titanium dioxide OSHA 15 mg/m3 TWA (total dust) ACGIH 10 mg/m3 TWA NIOSH 5000 mg/m3 IDLH Supplier OHSA, 10 mg/m3 TWA CAN Mexico 10 mg/m3 TWA LMPE-PPT (as Ti)20 mg/m3 STEL [LMPE-CT] (as Ti) Brazil 0041556-26-7 Bis (1,2,2,6,6-pentamethyl-4-piperidinyl) OSHA sebacate ACGIH NIOSH Supplier OHSA, CAN Mexico Brazil 0064742-95-6 Petroleum naphtha OSHA ACGIH NIOSH Supplier OHSA, CAN Mexico Brazil 0082919-37-7 DECANEDIOIC ACID, METHYL OSHA 1,2,2,6,6-PENTAMETHYL-4-P ACGIH NIOSH Supplier OHSA, CAN Mexico Brazil Proprietary METHYLOXYDIMETHYLPHENYLSILOXANE OSHA - EXPERIMENTAL POLYMER ACGIH (PROPRIETARY) NIOSH Supplier OHSA, CAN Mexico Brazil
Health Data CAS No. Ingredient Source Value 0000095-63-6 1,2,4-Trimethyl benzene NIOSH 0000096-29-7 Methyl ethyl ketoxime NIOSH 0000108-65-6 Propylene glycol monomethyl ether acetate NIOSH 0000110-43-0 Methyl n-amyl ketone NIOSH Irritation; liver kidney
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0000123-86-4 BUTYL ACETATE NIOSH Mucous membrane and eye irritation; high concentrations cause nervous system effects in animals 0000136-52-7 Hexanoic acid, 2-ethyl-, cobalt(2+) salt NIOSH 0001330-20-7 Xylenes (o-, m-, p- isomers) NIOSH Central nervous system depressant; respiratory and eye irritation 0007727-43-7 Barium sulfate NIOSH Eye nose 0013463-67-7 Titanium dioxide NIOSH Lung tumors in animals 0041556-26-7 Bis (1,2,2,6,6-pentamethyl-4-piperidinyl) NIOSH sebacate 0064742-95-6 Petroleum naphtha NIOSH 0082919-37-7 DECANEDIOIC ACID, METHYL NIOSH 1,2,2,6,6-PENTAMETHYL-4-P Proprietary METHYLOXYDIMETHYLPHENYLSILOXANE NIOSH - EXPERIMENTAL POLYMER (PROPRIETARY)
Carcinogen Data CAS No. Ingredient Source Value 0000095-63-6 1,2,4-Trimethyl benzene OSHA Select Carcinogen: No NTP Known: No; Suspected: No IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No; 0000096-29-7 Methyl ethyl ketoxime OSHA Select Carcinogen: No NTP Known: No; Suspected: No IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No; 0000108-65-6 Propylene glycol monomethyl ether acetate OSHA Select Carcinogen: No NTP Known: No; Suspected: No IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No; 0000110-43-0 Methyl n-amyl ketone OSHA Select Carcinogen: No NTP Known: No; Suspected: No IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No; 0000123-86-4 BUTYL ACETATE OSHA Select Carcinogen: No NTP Known: No; Suspected: No IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No; 0000136-52-7 Hexanoic acid, 2-ethyl-, cobalt(2+) salt OSHA Select Carcinogen: No NTP Known: No; Suspected: No IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No; 0001330-20-7 Xylenes (o-, m-, p- isomers) OSHA Select Carcinogen: No NTP Known: No; Suspected: No IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: Yes; Group 4: No; 0007727-43-7 Barium sulfate OSHA Select Carcinogen: No NTP Known: No; Suspected: No IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No; 0013463-67-7 Titanium dioxide OSHA Select Carcinogen: Yes NTP Known: No; Suspected: No IARC Group 1: No; Group 2a: No; Group 2b: Yes; Group 3: No; Group 4: No; 0041556-26-7 Bis (1,2,2,6,6-pentamethyl-4-piperidinyl) OSHA Select Carcinogen: No sebacate NTP Known: No; Suspected: No IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No; 0064742-95-6 Petroleum naphtha OSHA Select Carcinogen: No
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NTP Known: No; Suspected: No IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No; 0082919-37-7 DECANEDIOIC ACID, METHYL OSHA Select Carcinogen: No 1,2,2,6,6-PENTAMETHYL-4-P NTP Known: No; Suspected: No IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No; Proprietary METHYLOXYDIMETHYLPHENYLSILOXANE OSHA Select Carcinogen: No - EXPERIMENTAL POLYMER NTP Known: No; Suspected: No (PROPRIETARY) IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No;
8.2. Exposure controls Respiratory Select equipment to provide protection from the ingredients listed in Section 3 of this document. Ensure fresh air entry during application and drying. If you experience eye watering, headache or dizziness or if air monitoring demonstrates dust, vapor, or mist levels are above applicable limits, wear an appropriate, properly fitted respirator (NIOSH approved) during and after application. Follow respirator manufacturer's directions for respirator use. FOR USERS OF 3M RESPIRATORY PROTECTION ONLY: For information and assistance on 3M occupational health and safety products, call OH&ESD Technical Service toll free in U.S.A. 1-800-243-4630, in Canada call 1-800-267-4414. Please do not contact these numbers regarding other manufacturer's respiratory protection products. 3M does not endorse the accuracy of the information contained in this Material Safety Data Sheet. Eyes Avoid contact with eyes. Protective equipment should be selected to provide protection from exposure to the chemicals listed in Section 3 of this document. Depending on the site-specific conditions of use, safety glasses, chemical goggles, and/or head and face protection may be required to prevent contact. The equipment must be thoroughly cleaned, or discarded after each use. Skin Protective equipment should be selected to provide protection from exposure to the chemicals listed in Section 3 of this document. Depending on the site-specific conditions of use, protective gloves, apron, boots, head and face protection may be required to prevent contact. The equipment must be thoroughly cleaned, or discarded after each use. Engineering Controls Depending on the site-specific conditions of use, provide adequate ventilation. Other Work Practices Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. Use good personal hygiene practices. Wash hands before eating, drinking, using toilet facilities, etc. Promptly remove soiled clothing and wash clothing thoroughly before reuse. Shower after work using plenty of soap and water.
9. Physical and chemical properties
Appearance Coloured Liquid Odour threshold Not Measured pH No Established Limit Melting point / freezing point Not Measured Initial boiling point and boiling range 64 (°C) 148 (°F) Flash Point 39 (°C) 102 (°F) Evaporation rate (Ether = 1) Not Measured Flammability (solid, gas) Not Applicable Upper/lower flammability or explosive Lower Explosive Limit: 1 limits Upper Explosive Limit: No Established Limit vapor pressure (Pa) Not Measured Vapor Density Heavier than air Specific Gravity 1.30 Solubility in Water Not Measured Partition coefficient n-octanol/water (Log Not Measured Kow) Auto-ignition temperature Not Measured Decomposition temperature Not Measured
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Viscosity (cSt) No Established Limit Not Measured Refer to the Technical Data Sheet or label where information is VOC % available. VOHAP content (gm/litre of paint) 88.08 (as supplied) VOHAP content (gm/litre of Solid Coating) 55.48 (as supplied)
10. Stability and reactivity
10.1. Reactivity No data available 10.2. Chemical stability This product is stable and hazardous polymerization will not occur. Not sensitive to mechanical impact. Excessive heat and fumes generation can occur if improperly handled. 10.3. Possibility of hazardous reactions No data available 10.4. Conditions to avoid No data available 10.5. Incompatible materials Strong oxidizing agents. 10.6. Hazardous decomposition products HIGHLY FLAMMABLE MATERIALS: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks) creating a vapor explosion hazard. Runoff to sewers may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.
11. Toxicological information
Acute toxicity
NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal.
Ingredient Oral LD50, Skin LD50, Inhalation Inhalation mg/kg mg/kg Vapor LD50, Dust/Mist LD50, mg/L/4hr mg/L/4hr Titanium dioxide - (13463-67-7) 10,000.00, 10,000.00, No data 6.82, Rat - Rat - Rabbit - available Category: NA Category: Category: NA NA Barium sulfate - (7727-43-7) 3,000.00, No data No data No data available Mouse - available available Category: 5 Methyl n-amyl ketone - (110-43-0) 1,670.00, 12,600.00, No data No data available Rat - Rabbit - available Category: 4 Category: NA
METHYLOXYDIMETHYLPHENYLSILOXANE - No data No data No data No data available EXPERIMENTAL POLYMER (PROPRIETARY) available available available - (Proprietary) Petroleum naphtha - (64742-95-6) 6,800.00, 3,400.00, No data No data available Rat - Rabbit - available Category: Category: 5 NA Propylene glycol monomethyl ether acetate - 8,532.00, 5,000.00, No data No data available (108-65-6) Rat - Rabbit - available Category: Category: 5 NA 1,2,4-Trimethyl benzene - (95-63-6) 3,400.00, 3,160.00, 18.00, Rat - No data available Rat - Rabbit - Category: 4 Category: 5 Category: 5
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Xylenes (o-, m-, p- isomers) - (1330-20-7) 4,299.00, 1,548.00, 20.00, Rat - No data available Rat - Rabbit - Category: 4 Category: 5 Category: 4 BUTYL ACETATE - (123-86-4) 10,700.00, 17,600.00, No data No data available Rat - Rabbit - available Category: Category: NA NA Bis (1,2,2,6,6-pentamethyl-4-piperidinyl) 2,615.00, No data No data No data available sebacate - (41556-26-7) Rat - available available Category: 5 Methyl ethyl ketoxime - (96-29-7) 930.00, Rat - 2,000.00, 20.00, Rat - No data available Category: 4 Rabbit - Category: 4 Category: 4 DECANEDIOIC ACID, METHYL No data No data No data No data available 1,2,2,6,6-PENTAMETHYL-4-P - (82919-37-7) available available available Hexanoic acid, 2-ethyl-, cobalt(2+) salt - 1,220.00, 5,000.00, Rat No data No data available (136-52-7) Rabbit - - Category: 5 available Category: 4
Item Category Hazard Acute Toxicity (mouth) Not Classified Not Applicable Acute Toxicity (skin) Not Classified Not Applicable Acute Toxicity (inhalation) Not Classified Not Applicable Skin corrosion/irritation 3 Causes mild skin irritation. Eye damage/irritation Not Classified Not Applicable Sensitization (respiratory) Not Classified Not Applicable Sensitization (skin) 1 May cause an allergic skin reaction. Germ toxicity Not Classified Not Applicable Carcinogenicity Not Classified Not Applicable Reproductive Toxicity Not Classified Not Applicable Specific target organ systemic toxicity Not Classified Not Applicable (single exposure) Specific target organ systemic Not Classified Not Applicable Toxicity (repeated exposure) Aspiration hazard Not Classified Not Applicable
12. Ecological information
12.1. Toxicity No additional information provided for this product. See Section 3 for chemical specific data.
Aquatic Ecotoxicity
96 hr LC50 fish, 48 hr EC50 crustacea, ErC50 algae, Ingredient mg/l mg/l mg/l Titanium dioxide - (13463-67-7) 1,000.00, Fundulus 5.50, Daphnia magna heteroclitus 5.83 (72 hr), Pseudokirchneriella subcapitata Barium sulfate - (7727-43-7) 59,000.00, Poecilia 32.00, Daphnia Not Available sphenops magna Methyl n-amyl ketone - (110-43-0) Not Available Not Available 131.00, Pimephales promelas METHYLOXYDIMETHYLPHENYLSILOXANE Not Available Not Available 0.00 ( hr), - EXPERIMENTAL POLYMER (PROPRIETARY) - (Proprietary) Petroleum naphtha - (64742-95-6) 6.14, Daphnia magna 19.00 (72 hr), Selenastrum 9.22, Oncorhynchus capricornutum mykiss Not Available
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Propylene glycol monomethyl ether acetate - 100.00, Salmo 500.00, Daphnia (108-65-6) gairdneri magna 1,2,4-Trimethyl benzene - (95-63-6) 7.72, Pimephales 3.60, Daphnia magna Not Available promelas Xylenes (o-, m-, p- isomers) - (1330-20-7) 8.50, Palaemonetes 100.00 (72 hr), Chlorococcales 3.30, Oncorhynchus pugio mykiss BUTYL ACETATE - (123-86-4) 18.00, Pimephales 32.00, Artemia salina 674.70 (72 hr), Scenedesmus promelas subspicatus Bis (1,2,2,6,6-pentamethyl-4-piperidinyl) 1.00, Lepomis 20.00, Daphnia Not Available sebacate - (41556-26-7) macrochirus magna Methyl ethyl ketoxime - (96-29-7) 320.00, Leuciscus 500.00, Daphnia 83.00 (72 hr), Scenedesmus idus magna subspicatus DECANEDIOIC ACID, METHYL Not Available Not Available Not Available 1,2,2,6,6-PENTAMETHYL-4-P - (82919-37-7) Hexanoic acid, 2-ethyl-, cobalt(2+) salt - Not Available Not Available Not Available (136-52-7)
12.2. Persistence and degradability No data available 12.3. Bioaccumulative potential Not Measured 12.4. Mobility in soil No data available 12.5. Results of PBT and vPvB assessment This product contains no PBT/vPvB chemicals. 12.6. Other adverse effects No data available
13. Disposal considerations
13.1. Waste treatment methods Do not allow spills to enter drains or watercourses. Dispose of in accordance with local, state and federal regulations. (Also reference RCRA information in Section 15 if listed).
14. Transport information
14.1. UN number UN 1263 14.2. UN proper shipping name PAINT 14.3. Transport hazard class(es)
DOT (Domestic Surface Transportation) IMO / IMDG (Ocean Transportation) DOT Proper Shipping PAINT IMDG Proper PAINT Name Shipping Name DOT Hazard Class 3 IMDG Hazard Class 3 Sub Class 3 UN / NA Number UN 1263 DOT Packing Group III IMDG Packing Group III CERCLA/DOT RQ 546 gal. / 5896 lbs. System Reference 1 Code
14.4. Packing group III 14.5. Environmental hazards IMDG Marine Pollutant: No
14.6. Special precautions for user Not Applicable
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14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not Applicable
15. Regulatory information
Regulatory Overview The regulatory data in Section 15 is not intended to be all-inclusive, only selected regulations are represented. All ingredients of this product are listed on the TSCA (Toxic Substance Control Act) Inventory or are not required to be listed on the TSCA Inventory. WHMIS Classification B3 D2B
DOT Marine Pollutants (10%): (No Product Ingredients Listed) DOT Severe Marine Pollutants (1%): (No Product Ingredients Listed) EPCRA 311/312 Chemicals and RQs (>.1%) : Benzene, ethyl- (1000 lb final RQ; 454 kg final RQ) BUTYL ACETATE (5000 lb final RQ (listed under Butyl acetate); 2270 kg final RQ (listed under Butyl acetate)) Benzene, 1,2-dimethyl- (1000 lb final RQ; 454 kg final RQ) Styrene (1000 lb final RQ; 454 kg final RQ) Benzene, 1,3-dimethyl- (1000 lb final RQ; 454 kg final RQ) Xylenes (o-, m-, p- isomers) (100 lb final RQ; 45.4 kg final RQ) EPCRA 302 Extremely Hazardous (>.1%) : (No Product Ingredients Listed) EPCRA 313 Toxic Chemicals (>.1%) : 1,2,4-Trimethyl benzene Benzene, ethyl- Benzene, 1,2-dimethyl- Styrene Benzene, 1,3-dimethyl- Xylenes (o-, m-, p- isomers) Mass RTK Substances (>1%) : 1,2,4-Trimethyl benzene Barium sulfate Methyl n-amyl ketone BUTYL ACETATE Titanium dioxide Xylenes (o-, m-, p- isomers) Penn RTK Substances (>1%) : 1,2,4-Trimethyl benzene Barium sulfate Methyl n-amyl ketone BUTYL ACETATE Titanium dioxide Xylenes (o-, m-, p- isomers) Penn Special Hazardous Substances (>.01%) : (No Product Ingredients Listed) RCRA Status: (No Product Ingredients Listed) N.J. RTK Substances (>1%) : 1,2,4-Trimethyl benzene Barium sulfate Methyl n-amyl ketone BUTYL ACETATE Titanium dioxide Xylenes (o-, m-, p- isomers) N.J. Special Hazardous Substances (>.01%) : 2-Butoxyethanol
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Butyl acrylate Cumene Ethyl alcohol Benzene, ethyl- Methanol Methyl methacrylate Methylpropyl ketone BUTYL ACETATE Benzene, 1,2-dimethyl- Quartz Styrene Benzene, 1,3-dimethyl- Xylenes (o-, m-, p- isomers) N.J. Env. Hazardous Substances (>.1%) : 1,2,4-Trimethyl benzene Benzene, ethyl- Benzene, 1,2-dimethyl- Styrene Benzene, 1,3-dimethyl- Xylenes (o-, m-, p- isomers) Proposition 65 - Carcinogens (>0%): Cumene Ethyl alcohol Benzene, ethyl- Quartz Titanium dioxide Proposition 65 - Female Repro Toxins (>0%): (No Product Ingredients Listed) Proposition 65 - Male Repro Toxins (>0%): (No Product Ingredients Listed) Proposition 65 - Developmental Toxins (>0%): Ethyl alcohol Methanol
16. Other information
The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or warranty of any kind, expressed or implied, is made with respect to the information contained herein. We accept no responsibility and disclaim all liability for any harmful effects which may be caused by exposure to our products. Customers/users of this product must comply with all applicable health and safety laws, regulations, and orders.
The full text of the phrases appearing in section 3 is:
H226 Flammable liquid and vapor. H302 Harmful if swallowed. H304 May be fatal if swallowed and enters airways. H312 Harmful in contact with skin. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H319 Causes serious eye irritation. H332 Harmful if inhaled. H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness. H351 Suspected of causing cancer. H361F Suspected of damaging fertility. H372 Causes damage to organs through prolonged or repeated exposure.
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H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. H411 Toxic to aquatic life with long lasting effects.
The following sections have changed since the previous revision. SECTION 9: Physical and chemical properties SECTION 12: Ecological information SECTION 14: Transport information
End of Document
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Material Safety Data Sheet INTERFINE 5703 LIGHT BASE
Sales Order: {SalesOrd} Bulk Sales Reference No.: SUB011 MSDS Revision Date: 01/28/2015 MSDS Revision Number: A0-2
1. Identification of the preparation and company
1.1. Product identifier Product Identity INTERFINE 5703 LIGHT BASE Bulk Sales Reference No. SUB011
1.2. Relevant identified uses of the substance or mixture and uses advised against Intended Use See Technical Data Sheet. Application Method See Technical Data Sheet.
1.3. Details of the supplier of the safety data sheet Company Name International Paint LLC 6001 Antoine Drive Houston, Texas 77091
Emergency CHEMTREC (USA) (800) 424-9300 International Paint (713) 682-1711 Poison Control Center (800) 854-6813 Customer Service International Paint (800) 589-1267 Fax No. (800) 631-7481
2. Hazard identification of the product
2.1. Classification of the substance or mixture Flam. Liq. 3;H226 Flammable liquid and vapor. Skin Irrit. 3;H316 Causes mild skin irritation. Aquatic Chronic 3;H412 Harmful to aquatic life with long lasting effects.
2.2. Label elements Using the Toxicity Data listed in section 11 & 12 the product is labelled as follows.
Warning. H226 Flammable liquid and vapor. H316 Causes mild skin irritation. H412 Harmful to aquatic life with long lasting effects.
P210 Keep away from heat / sparks / open flames / hot surfaces - No smoking. P260 Do not breathe mist / vapors / spray. P262 Do not get in eyes, on skin, or on clothing. P273 Avoid release to the environment.
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P280 Wear protective gloves / eye protection / face protection. P301+310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P303+361+353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P331 Do NOT induce vomiting. P332+313 If skin irritation occurs: Get medical advice/attention. P370 In case of fire: Use water spray, fog, or regular foam.. P403+233 Store in a well ventilated place. Keep container tightly closed. P501 Dispose of contents / container in accordance with local / national regulations.
HMIS Rating Health: 2 Flammability: 3 Reactivity: 0
3. Composition/information on ingredients
This product contains the following substances that present a hazard within the meaning of the relevant State and Federal Hazardous Substances regulations. Ingredient/Chemical Designations Weight % GHS Classification Notes Titanium dioxide 10 - 25 ---- [1][2] CAS Number: 0013463-67-7 Barium sulfate 10 - 25 ---- [1][2] CAS Number: 0007727-43-7 Methyl n-amyl ketone 10 - 25 Flam. Liq. 3;H226 [1][2] CAS Number: 0000110-43-0 Acute Tox. 4;H332 Acute Tox. 4;H302 METHYLOXYDIMETHYLPHENYLSILOXANE 1.0 - 10 ---- [1] - EXPERIMENTAL POLYMER (PROPRIETARY) CAS Number: Proprietary Petroleum naphtha 1.0 - 10 Asp. Tox. 1;H304 [1] CAS Number: 0064742-95-6 Aquatic Chronic 2;H411 (Self Classification) Propylene glycol monomethyl ether acetate 1.0 - 10 Flam. Liq. 3;H226 [1] CAS Number: 0000108-65-6 1,2,4-Trimethyl benzene 1.0 - 10 Flam. Liq. 3;H226 [1] CAS Number: 0000095-63-6 Acute Tox. 4;H332 Eye Irrit. 2;H319 STOT SE 3;H335 Skin Irrit. 2;H315 Aquatic Chronic 2;H411 Xylenes (o-, m-, p- isomers) 1.0 - 10 Flam. Liq. 3;H226 [1][2] CAS Number: 0001330-20-7 Acute Tox. 4;H332 Acute Tox. 4;H312 Skin Irrit. 2;H315 Eye Irrit. 2;H319 STOT SE 3;H335 Asp. Tox. 1;H304 BUTYL ACETATE 1.0 - 10 Flam. Liq. 3;H226 [1][2] CAS Number: 0000123-86-4 STOT SE 3;H336 Bis (1,2,2,6,6-pentamethyl-4-piperidinyl) 0.10 - 1.0 Skin Sens. 1;H317 [1] sebacate Aquatic Chronic CAS Number: 0041556-26-7 1;H410 Aquatic Acute 1;H400 Methyl ethyl ketoxime 0.10 - 1.0 Carc. 2;H351 [1] CAS Number: 0000096-29-7 Acute Tox. 4;H312 Eye Dam. 1;H318 Skin Sens. 1;H317 DECANEDIOIC ACID, METHYL 0.10 - 1.0 Skin Sens. 1;H317 [1] 1,2,2,6,6-PENTAMETHYL-4-P Aquatic Chronic CAS Number: 0082919-37-7 1;H410 Hexanoic acid, 2-ethyl-, cobalt(2+) salt 0.10 - 1.0 Acute Tox. 4;H302 [1] CAS Number: 0000136-52-7 Skin Sens. 1;H317
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Repr. 2;H361F Aquatic Acute 1;H400 Aquatic Chronic 1;H410 [1] Substance classified with a health or environmental hazard. [2] Substance with a workplace exposure limit. [3] PBT-substance or vPvB-substance.
*The full texts of the phrases are shown in Section 16.
4. First aid measures
4.1. Description of first aid measures General Remove contaminated clothing and shoes. Get medical attention immediately. Wash clothing before reuse. Thoroughly clean or destroy contaminated shoes. Inhalation If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately. Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention immediately. Skin In case of contact, immediately flush skin with soap and plenty of water. Get medical attention immediately. Ingestion If swallowed, immediately contact Poison Control Center at 1-800-854-6813. DO NOT induce vomiting unless instructed to do so by medical personnel. Never give anything by mouth to an unconscious person. 4.2. Most important symptoms and effects, both acute and delayed Overview NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. Avoid contact with eyes, skin and clothing. Inhalation Harmful if inhaled. Causes nose and throat irritation. Vapors may affect the brain or nervous system causing dizziness, headache or nausea. Eyes Risk of serious damage to eyes. Do not get in eyes. Protective equipment should be selected to provide protection from exposure to the chemicals listed in Section 3 of this document. Depending on the site-specific condition of use, safety glasses, chemical goggles, and/or head and face protection may be required to prevent contact. The equipment must be thouroughly cleaned, or discarded after each use. Skin Causes skin irritation. May cause delayed skin irritation. May be harmful if absorbed through the skin. Ingestion Harmful if swallowed. May cause abdominal pain, nausea, vomiting, diarrhea, or drowsiness. Chronic effects Possible cancer hazard. Contains an ingredient which may cause cancer based on animal data (See Section 2 and Section 15 for each ingredient). Risk of cancer depends on duration and level of exposure.
5. Fire-fighting measures
5.1. Extinguishing media CAUTION: This product has a very low flashpoint. Use of water spray when fighting fire may be inefficient. CAUTION: For mixtures containing alcohol or polar solvent, alcohol-resistant foam may be more effective. SMALL FIRES: Use dry chemical, CO2, water spray or regular foam. LARGE FIRES: Use water spray, fog, or regular foam. Do not use straight streams. Move containers from fire area if you can do so without risk. 5.2. Special hazards arising from the substance or mixture HIGHLY FLAMMABLE MATERIALS: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks) creating a vapor explosion hazard. Runoff to sewers may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water. 5.3. Advice for fire-fighters Cool closed containers exposed to fire by spraying them with water. Do not allow run off water and contaminants from fire fighting to enter drains or water courses. ERG Guide No. 128
6. Accidental release measures
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6.1. Personal precautions, protective equipment and emergency procedures ELIMINATE ALL IGNITION SOURCES (no smoking, flares, sparks or flames in immediate area). Use only non-sparking equipment to handle spilled material and absorbent. Do not touch or walk through spilled material. Stop leak if you can do so without risk. Prevent entry into waterways, sewers, basements or confined areas. A vapor suppressing foam may be used to reduce vapors. Absorb or cover with dry earth, sand, or other non-combustible material and transfer to containers. Use non-sparking tools to collect absorbed material. 6.2. Environmental precautions Do not allow spills to enter drains or watercourses. 6.3. Methods and material for containment and cleaning up CALL CHEMTREC at (800)-424-9300 for emergency response. Isolate spill or leak area immediately for at least 50 meters (150 feet) in all directions. Keep unauthorized personnel away. Stay upwind. Keep out of low areas. Ventilate closed spaces before entering. LARGE SPILLS: Consider initial downwind evacuation for at least 300 meters (1000 feet).
7. Handling and storage
7.1. Precautions for safe handling Handling Vapors may cause flash fire or ignite explosively.
In Storage Keep away from heat, sparks and flame.
7.2. Conditions for safe storage, including any incompatibilities Store between 40-100F (4-38C). Do not get in eyes, on skin or clothing. Strong oxidizing agents. Do not smoke. Extinguish all flames and pilot lights, and turn off stoves, heaters, electric motors and other sources of ignition during use and until all vapors are gone.
7.3. Specific end use(s) Close container after each use. Wash thoroughly after handling. Prevent build-up of vapors by opening all windows and doors to achieve cross-ventilation.
8. Exposure controls and personal protection
8.1. Control parameters Exposure CAS No. Ingredient Source Value 0000095-63-6 1,2,4-Trimethyl benzene OSHA No Established Limit ACGIH No Established Limit NIOSH 25 ppm TWA; 125 mg/m3 TWA Supplier No Established Limit OHSA, No Established Limit CAN Mexico No Established Limit Brazil No Established Limit 0000096-29-7 Methyl ethyl ketoxime OSHA No Established Limit ACGIH No Established Limit NIOSH No Established Limit Supplier No Established Limit OHSA, No Established Limit CAN Mexico No Established Limit Brazil No Established Limit 0000108-65-6 Propylene glycol monomethyl ether acetate OSHA No Established Limit
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ACGIH No Established Limit NIOSH No Established Limit Supplier No Established Limit OHSA, 50 ppm TWA; 270 mg/m3 TWA CAN Mexico No Established Limit Brazil No Established Limit 0000110-43-0 Methyl n-amyl ketone OSHA 100 ppm TWA; 465 mg/m3 TWA ACGIH 50 ppm TWA NIOSH 100 ppm TWA; 465 mg/m3 TWA800 ppm IDLH Supplier No Established Limit OHSA, 25 ppm TWA; 115 mg/m3 TWA CAN Mexico 50 ppm TWA LMPE-PPT; 235 mg/m3 TWA LMPE-PPT100 ppm STEL [LMPE-CT]; 465 mg/m3 STEL [LMPE-CT] Brazil No Established Limit 0000123-86-4 BUTYL ACETATE OSHA 150 ppm TWA; 710 mg/m3 TWA200 ppm STEL; 950 mg/m3 STEL ACGIH 150 ppm TWA200 ppm STEL NIOSH 150 ppm TWA; 710 mg/m3 TWA200 ppm STEL; 950 mg/m3 STEL1700 ppm IDLH (10% LEL) Supplier No Established Limit OHSA, 150 ppm TWA200 ppm STEL CAN Mexico 150 ppm TWA LMPE-PPT; 710 mg/m3 TWA LMPE-PPT200 ppm STEL [LMPE-CT]; 950 mg/m3 STEL [LMPE-CT] Brazil No Established Limit 0000136-52-7 Hexanoic acid, 2-ethyl-, cobalt(2+) salt OSHA No Established Limit ACGIH No Established Limit NIOSH No Established Limit Supplier No Established Limit OHSA, No Established Limit CAN Mexico No Established Limit Brazil No Established Limit 0001330-20-7 Xylenes (o-, m-, p- isomers) OSHA 100 ppm TWA; 435 mg/m3 TWA150 ppm STEL; 655 mg/m3 STEL ACGIH 100 ppm TWA150 ppm STEL NIOSH No Established Limit Supplier No Established Limit OHSA, 100 ppm TWA150 ppm STEL CAN Mexico 100 ppm TWA LMPE-PPT; 435 mg/m3 TWA LMPE-PPT150 ppm STEL [LMPE-CT]; 655 mg/m3 STEL [LMPE-CT] Brazil 78 ppm TWA LT; 340 mg/m3 TWA LT 0007727-43-7 Barium sulfate OSHA 15 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction) ACGIH 10 mg/m3 TWA NIOSH 10 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable dust) Supplier No Established Limit 10 mg/m3 TWA
5/13 SUB011_A0
OHSA, CAN Mexico No Established Limit Brazil No Established Limit 0013463-67-7 Titanium dioxide OSHA 15 mg/m3 TWA (total dust) ACGIH 10 mg/m3 TWA NIOSH 5000 mg/m3 IDLH Supplier No Established Limit OHSA, 10 mg/m3 TWA CAN Mexico 10 mg/m3 TWA LMPE-PPT (as Ti)20 mg/m3 STEL [LMPE-CT] (as Ti) Brazil No Established Limit 0041556-26-7 Bis (1,2,2,6,6-pentamethyl-4-piperidinyl) OSHA No Established Limit sebacate ACGIH No Established Limit NIOSH No Established Limit Supplier No Established Limit OHSA, No Established Limit CAN Mexico No Established Limit Brazil No Established Limit 0064742-95-6 Petroleum naphtha OSHA No Established Limit ACGIH No Established Limit NIOSH No Established Limit Supplier No Established Limit OHSA, No Established Limit CAN Mexico No Established Limit Brazil No Established Limit 0082919-37-7 DECANEDIOIC ACID, METHYL OSHA No Established Limit 1,2,2,6,6-PENTAMETHYL-4-P ACGIH No Established Limit NIOSH No Established Limit Supplier No Established Limit OHSA, No Established Limit CAN Mexico No Established Limit Brazil No Established Limit Proprietary METHYLOXYDIMETHYLPHENYLSILOXANE OSHA No Established Limit - EXPERIMENTAL POLYMER ACGIH No Established Limit (PROPRIETARY) NIOSH No Established Limit Supplier No Established Limit OHSA, No Established Limit CAN Mexico No Established Limit Brazil No Established Limit
Health Data CAS No. Ingredient Source Value 0000095-63-6 1,2,4-Trimethyl benzene NIOSH No Established Limit 0000096-29-7 Methyl ethyl ketoxime NIOSH No Established Limit 0000108-65-6 Propylene glycol monomethyl ether acetate NIOSH No Established Limit 0000110-43-0 Methyl n-amyl ketone NIOSH Irritation; liver kidney 0000123-86-4 BUTYL ACETATE NIOSH Mucous membrane and eye irritation; high concentrations cause nervous system effects in animals 0000136-52-7 Hexanoic acid, 2-ethyl-, cobalt(2+) salt NIOSH No Established Limit 0001330-20-7 Xylenes (o-, m-, p- isomers) NIOSH Central nervous system depressant; respiratory and eye irritation 0007727-43-7 Barium sulfate NIOSH Eye nose
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0013463-67-7 Titanium dioxide NIOSH Lung tumors in animals 0041556-26-7 Bis (1,2,2,6,6-pentamethyl-4-piperidinyl) NIOSH No Established Limit sebacate 0064742-95-6 Petroleum naphtha NIOSH No Established Limit 0082919-37-7 DECANEDIOIC ACID, METHYL NIOSH No Established Limit 1,2,2,6,6-PENTAMETHYL-4-P Proprietary METHYLOXYDIMETHYLPHENYLSILOXANE NIOSH No Established Limit - EXPERIMENTAL POLYMER (PROPRIETARY)
Carcinogen Data CAS No. Ingredient Source Value 0000095-63-6 1,2,4-Trimethyl benzene OSHA Select Carcinogen: No NTP Known: No; Suspected: No IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No; 0000096-29-7 Methyl ethyl ketoxime OSHA Select Carcinogen: No NTP Known: No; Suspected: No IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No; 0000108-65-6 Propylene glycol monomethyl ether acetate OSHA Select Carcinogen: No NTP Known: No; Suspected: No IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No; 0000110-43-0 Methyl n-amyl ketone OSHA Select Carcinogen: No NTP Known: No; Suspected: No IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No; 0000123-86-4 BUTYL ACETATE OSHA Select Carcinogen: No NTP Known: No; Suspected: No IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No; 0000136-52-7 Hexanoic acid, 2-ethyl-, cobalt(2+) salt OSHA Select Carcinogen: No NTP Known: No; Suspected: No IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No; 0001330-20-7 Xylenes (o-, m-, p- isomers) OSHA Select Carcinogen: No NTP Known: No; Suspected: No IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: Yes; Group 4: No; 0007727-43-7 Barium sulfate OSHA Select Carcinogen: No NTP Known: No; Suspected: No IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No; 0013463-67-7 Titanium dioxide OSHA Select Carcinogen: Yes NTP Known: No; Suspected: No IARC Group 1: No; Group 2a: No; Group 2b: Yes; Group 3: No; Group 4: No; 0041556-26-7 Bis (1,2,2,6,6-pentamethyl-4-piperidinyl) OSHA Select Carcinogen: No sebacate NTP Known: No; Suspected: No IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No; 0064742-95-6 Petroleum naphtha OSHA Select Carcinogen: No NTP Known: No; Suspected: No IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No; 0082919-37-7 DECANEDIOIC ACID, METHYL OSHA Select Carcinogen: No 1,2,2,6,6-PENTAMETHYL-4-P NTP Known: No; Suspected: No IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No;
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Proprietary METHYLOXYDIMETHYLPHENYLSILOXANE OSHA Select Carcinogen: No - EXPERIMENTAL POLYMER NTP Known: No; Suspected: No (PROPRIETARY) IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No;
8.2. Exposure controls Respiratory Select equipment to provide protection from the ingredients listed in Section 3 of this document. Ensure fresh air entry during application and drying. If you experience eye watering, headache or dizziness or if air monitoring demonstrates dust, vapor, or mist levels are above applicable limits, wear an appropriate, properly fitted respirator (NIOSH approved) during and after application. Follow respirator manufacturer's directions for respirator use. FOR USERS OF 3M RESPIRATORY PROTECTION ONLY: For information and assistance on 3M occupational health and safety products, call OH&ESD Technical Service toll free in U.S.A. 1-800-243-4630, in Canada call 1-800-267-4414. Please do not contact these numbers regarding other manufacturer's respiratory protection products. 3M does not endorse the accuracy of the information contained in this Material Safety Data Sheet. Eyes Avoid contact with eyes. Protective equipment should be selected to provide protection from exposure to the chemicals listed in Section 3 of this document. Depending on the site-specific conditions of use, safety glasses, chemical goggles, and/or head and face protection may be required to prevent contact. The equipment must be thoroughly cleaned, or discarded after each use. Skin Protective equipment should be selected to provide protection from exposure to the chemicals listed in Section 3 of this document. Depending on the site-specific conditions of use, protective gloves, apron, boots, head and face protection may be required to prevent contact. The equipment must be thoroughly cleaned, or discarded after each use. Engineering Controls Depending on the site-specific conditions of use, provide adequate ventilation. Other Work Practices Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. Use good personal hygiene practices. Wash hands before eating, drinking, using toilet facilities, etc. Promptly remove soiled clothing and wash clothing thoroughly before reuse. Shower after work using plenty of soap and water.
9. Physical and chemical properties
Appearance Coloured Liquid Odour threshold Not Measured pH No Established Limit Melting point / freezing point Not Measured Initial boiling point and boiling range 64 (C) 147 (F) Flash Point 39 (C) 102 (F) Evaporation rate (Ether = 1) Not Measured Flammability (solid, gas) Not Applicable Upper/lower flammability or explosive Lower Explosive Limit: 1 limits Upper Explosive Limit: No Established Limit vapor pressure (Pa) Not Measured Vapor Density Heavier than air Specific Gravity 1.30 Partition coefficient n-octanol/water (Log Not Measured Kow) Auto-ignition temperature Not Measured Decomposition temperature Not Measured Viscosity (cSt) No Established Limit Not Measured Refer to the Technical Data Sheet or label where information is VOC % available.
9.2. Other information No further information
10. Stability and reactivity
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10.1. Reactivity No data available 10.2. Chemical stability This product is stable and hazardous polymerization will not occur. Not sensitive to mechanical impact. Excessive heat and fumes generation can occur if improperly handled. 10.3. Possibility of hazardous reactions No data available 10.4. Conditions to avoid No data available 10.5. Incompatible materials Strong oxidizing agents. 10.6. Hazardous decomposition products HIGHLY FLAMMABLE MATERIALS: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks) creating a vapor explosion hazard. Runoff to sewers may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.
11. Toxicological information
Acute toxicity
NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal.
Ingredient Oral LD50, Skin LD50, Inhalation Inhalation mg/kg mg/kg Vapor LD50, Dust/Mist LD50, mg/L/4hr mg/L/4hr Titanium dioxide - (13463-67-7) 10,000.00, 10,000.00, No data 6.82, Rat - Rat - Rabbit - available Category: NA Category: Category: NA NA Barium sulfate - (7727-43-7) 3,000.00, No data No data No data available Mouse - available available Category: 5 Methyl n-amyl ketone - (110-43-0) 1,670.00, 12,600.00, No data No data available Rat - Rabbit - available Category: 4 Category: NA
METHYLOXYDIMETHYLPHENYLSILOXANE - No data No data No data No data available EXPERIMENTAL POLYMER (PROPRIETARY) available available available - (Proprietary) Petroleum naphtha - (64742-95-6) 6,800.00, 3,400.00, No data No data available Rat - Rabbit - available Category: Category: 5 NA Propylene glycol monomethyl ether acetate - 8,532.00, 5,000.00, No data No data available (108-65-6) Rat - Rabbit - available Category: Category: 5 NA 1,2,4-Trimethyl benzene - (95-63-6) 3,400.00, 3,160.00, 18.00, Rat - No data available Rat - Rabbit - Category: 4 Category: 5 Category: 5 Xylenes (o-, m-, p- isomers) - (1330-20-7) 4,299.00, 1,548.00, 20.00, Rat - No data available Rat - Rabbit - Category: 4 Category: 5 Category: 4 BUTYL ACETATE - (123-86-4) 10,700.00, 17,600.00, No data No data available Rat - Rabbit - available Category: Category: NA NA Bis (1,2,2,6,6-pentamethyl-4-piperidinyl) 2,615.00, No data No data No data available sebacate - (41556-26-7) Rat - available available Category: 5
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Methyl ethyl ketoxime - (96-29-7) 930.00, Rat - 2,000.00, 20.00, Rat - No data available Category: 4 Rabbit - Category: 4 Category: 4 DECANEDIOIC ACID, METHYL No data No data No data No data available 1,2,2,6,6-PENTAMETHYL-4-P - (82919-37-7) available available available Hexanoic acid, 2-ethyl-, cobalt(2+) salt - 1,220.00, 5,000.00, Rat No data No data available (136-52-7) Rabbit - - Category: 5 available Category: 4
Item Category Hazard Acute Toxicity (mouth) Not Classified Not Applicable Acute Toxicity (skin) Not Classified Not Applicable Acute Toxicity (inhalation) Not Classified Not Applicable Skin corrosion/irritation 3 Causes mild skin irritation. Eye damage/irritation Not Classified Not Applicable Sensitization (respiratory) Not Classified Not Applicable Sensitization (skin) Not Classified Not Applicable Germ toxicity Not Classified Not Applicable Carcinogenicity Not Classified Not Applicable Reproductive Toxicity Not Classified Not Applicable Specific target organ systemic toxicity Not Classified Not Applicable (single exposure) Specific target organ systemic Not Classified Not Applicable Toxicity (repeated exposure) Aspiration hazard Not Classified Not Applicable
12. Ecological information
12.1. Toxicity No additional information provided for this product. See Section 3 for chemical specific data.
Aquatic Ecotoxicity
96 hr LC50 fish, 48 hr EC50 crustacea, ErC50 algae, Ingredient mg/l mg/l mg/l Titanium dioxide - (13463-67-7) 1,000.00, Fundulus 5.50, Daphnia magna heteroclitus 5.83 (72 hr), Pseudokirchneriella subcapitata Barium sulfate - (7727-43-7) 59,000.00, Poecilia 32.00, Daphnia Not Available sphenops magna Methyl n-amyl ketone - (110-43-0) Not Available Not Available 131.00, Pimephales promelas METHYLOXYDIMETHYLPHENYLSILOXANE Not Available Not Available Not Available - EXPERIMENTAL POLYMER (PROPRIETARY) - (Proprietary) Petroleum naphtha - (64742-95-6) 6.14, Daphnia magna 19.00 (72 hr), Selenastrum 9.22, Oncorhynchus capricornutum mykiss Propylene glycol monomethyl ether acetate - 100.00, Salmo 500.00, Daphnia Not Available (108-65-6) gairdneri magna 1,2,4-Trimethyl benzene - (95-63-6) 7.72, Pimephales 3.60, Daphnia magna Not Available promelas Xylenes (o-, m-, p- isomers) - (1330-20-7) 8.50, Palaemonetes 100.00 (72 hr), Chlorococcales 3.30, Oncorhynchus pugio mykiss BUTYL ACETATE - (123-86-4) 18.00, Pimephales 32.00, Artemia salina 674.70 (72 hr), Scenedesmus promelas subspicatus Bis (1,2,2,6,6-pentamethyl-4-piperidinyl) 1.00, Lepomis 20.00, Daphnia Not Available sebacate - (41556-26-7) macrochirus magna
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Methyl ethyl ketoxime - (96-29-7) 320.00, Leuciscus 500.00, Daphnia 83.00 (72 hr), Scenedesmus idus magna subspicatus DECANEDIOIC ACID, METHYL Not Available Not Available Not Available 1,2,2,6,6-PENTAMETHYL-4-P - (82919-37-7) Hexanoic acid, 2-ethyl-, cobalt(2+) salt - Not Available Not Available Not Available (136-52-7)
12.2. Persistence and degradability No data available 12.3. Bioaccumulative potential Not Measured 12.4. Mobility in soil No data available 12.5. Results of PBT and vPvB assessment This product contains no PBT/vPvB chemicals. 12.6. Other adverse effects No data available
13. Disposal considerations
13.1. Waste treatment methods Do not allow spills to enter drains or watercourses. Dispose of in accordance with local, state and federal regulations. (Also reference RCRA information in Section 15 if listed).
14. Transport information
14.1. UN number UN 1263 14.2. UN proper shipping name PAINT 14.3. Transport hazard class(es)
DOT (Domestic Surface Transportation) IMO / IMDG (Ocean Transportation) DOT Proper Shipping PAINT IMDG Proper PAINT Name Shipping Name DOT Hazard Class 3 IMDG Hazard Class 3 Sub Class 3 UN / NA Number UN 1263 DOT Packing Group III IMDG Packing Group III CERCLA/DOT RQ 494 gal. / 5338 lbs. System Reference 1 Code
14.4. Packing group III 14.5. Environmental hazards IMDG Marine Pollutant: No
14.6. Special precautions for user Not Applicable 14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not Applicable
15. Regulatory information
Regulatory Overview The regulatory data in Section 15 is not intended to be all-inclusive, only selected regulations are represented. All ingredients of this product are listed on the TSCA (Toxic Substance Control Act) Inventory or are not required to be listed on the TSCA Inventory. WHMIS Classification B3
11/13 SUB011_A0
DOT Marine Pollutants (10%): (No Product Ingredients Listed) DOT Severe Marine Pollutants (1%): (No Product Ingredients Listed) EPCRA 311/312 Chemicals and RQs (>.1%) : Benzene, ethyl- (1000 lb final RQ; 454 kg final RQ) BUTYL ACETATE (5000 lb final RQ (listed under Butyl acetate); 2270 kg final RQ (listed under Butyl acetate)) Benzene, 1,2-dimethyl- (1000 lb final RQ; 454 kg final RQ) Styrene (1000 lb final RQ; 454 kg final RQ) Benzene, 1,3-dimethyl- (1000 lb final RQ; 454 kg final RQ) Xylenes (o-, m-, p- isomers) (100 lb final RQ; 45.4 kg final RQ) EPCRA 302 Extremely Hazardous (>.1%) : (No Product Ingredients Listed) EPCRA 313 Toxic Chemicals (>.1%) : 1,2,4-Trimethyl benzene Benzene, ethyl- Benzene, 1,2-dimethyl- Styrene Benzene, 1,3-dimethyl- Xylenes (o-, m-, p- isomers) Mass RTK Substances (>1%) : 1,2,4-Trimethyl benzene Barium sulfate Methyl n-amyl ketone BUTYL ACETATE Titanium dioxide Xylenes (o-, m-, p- isomers) Penn RTK Substances (>1%) : 1,2,4-Trimethyl benzene Barium sulfate Methyl n-amyl ketone BUTYL ACETATE Titanium dioxide Xylenes (o-, m-, p- isomers) Penn Special Hazardous Substances (>.01%) : (No Product Ingredients Listed) RCRA Status: (No Product Ingredients Listed) N.J. RTK Substances (>1%) : 1,2,4-Trimethyl benzene Barium sulfate Methyl n-amyl ketone BUTYL ACETATE Titanium dioxide Xylenes (o-, m-, p- isomers) N.J. Special Hazardous Substances (>.01%) : 2-Butoxyethanol Butyl acrylate Cumene Ethyl alcohol Benzene, ethyl- Methanol Methyl methacrylate Methylpropyl ketone BUTYL ACETATE Benzene, 1,2-dimethyl- Quartz
12/13 SUB011_A0
Styrene Benzene, 1,3-dimethyl- Xylenes (o-, m-, p- isomers) N.J. Env. Hazardous Substances (>.1%) : 1,2,4-Trimethyl benzene Benzene, ethyl- Benzene, 1,2-dimethyl- Styrene Benzene, 1,3-dimethyl- Xylenes (o-, m-, p- isomers) Proposition 65 - Carcinogens (>0%): Cumene Ethyl alcohol Benzene, ethyl- Quartz Titanium dioxide Proposition 65 - Female Repro Toxins (>0%): (No Product Ingredients Listed) Proposition 65 - Male Repro Toxins (>0%): (No Product Ingredients Listed) Proposition 65 - Developmental Toxins (>0%): Ethyl alcohol Methanol
16. Other information
The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or warranty of any kind, expressed or implied, is made with respect to the information contained herein. We accept no responsibility and disclaim all liability for any harmful effects which may be caused by exposure to our products. Customers/users of this product must comply with all applicable health and safety laws, regulations, and orders.
The full text of the phrases appearing in section 3 is:
H226 Flammable liquid and vapor. H302 Harmful if swallowed. H304 May be fatal if swallowed and enters airways. H312 Harmful in contact with skin. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H319 Causes serious eye irritation. H332 Harmful if inhaled. H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness. H351 Suspected of causing cancer. H361F Suspected of damaging fertility. H372 Causes damage to organs through prolonged or repeated exposure. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. H411 Toxic to aquatic life with long lasting effects.
This is the first revision of this SDS format, changes from previous revision not applicable.
End of Document
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Material Safety Data Sheet INTERFINE 5703 ULTRA DEEP BASE
Sales Order: {SalesOrd} Bulk Sales Reference No.: SUB044 MSDS Revision Date: 01/28/2015 MSDS Revision Number: A0-2
1. Identification of the preparation and company
1.1. Product identifier Product Identity INTERFINE 5703 ULTRA DEEP BASE Bulk Sales Reference No. SUB044
1.2. Relevant identified uses of the substance or mixture and uses advised against Intended Use See Technical Data Sheet. Application Method See Technical Data Sheet.
1.3. Details of the supplier of the safety data sheet Company Name International Paint LLC 6001 Antoine Drive Houston, Texas 77091
Emergency CHEMTREC (USA) (800) 424-9300 International Paint (713) 682-1711 Poison Control Center (800) 854-6813 Customer Service International Paint (800) 589-1267 Fax No. (800) 631-7481
2. Hazard identification of the product
2.1. Classification of the substance or mixture Flam. Liq. 3;H226 Flammable liquid and vapor. Skin Irrit. 3;H316 Causes mild skin irritation. Aquatic Chronic 3;H412 Harmful to aquatic life with long lasting effects.
2.2. Label elements Using the Toxicity Data listed in section 11 & 12 the product is labelled as follows.
Warning. H226 Flammable liquid and vapor. H316 Causes mild skin irritation. H412 Harmful to aquatic life with long lasting effects.
P210 Keep away from heat / sparks / open flames / hot surfaces - No smoking. P260 Do not breathe mist / vapors / spray. P262 Do not get in eyes, on skin, or on clothing. P273 Avoid release to the environment.
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P280 Wear protective gloves / eye protection / face protection. P301+310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P303+361+353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P331 Do NOT induce vomiting. P332+313 If skin irritation occurs: Get medical advice/attention. P370 In case of fire: Use water spray, fog, or regular foam.. P403+233 Store in a well ventilated place. Keep container tightly closed. P501 Dispose of contents / container in accordance with local / national regulations.
HMIS Rating Health: 2 Flammability: 3 Reactivity: 0
3. Composition/information on ingredients
This product contains the following substances that present a hazard within the meaning of the relevant State and Federal Hazardous Substances regulations. Ingredient/Chemical Designations Weight % GHS Classification Notes Barium sulfate 25 - 50 ---- [1][2] CAS Number: 0007727-43-7 Methyl n-amyl ketone 10 - 25 Flam. Liq. 3;H226 [1][2] CAS Number: 0000110-43-0 Acute Tox. 4;H332 Acute Tox. 4;H302 METHYLOXYDIMETHYLPHENYLSILOXANE 1.0 - 10 ---- [1] - EXPERIMENTAL POLYMER (PROPRIETARY) CAS Number: Proprietary Petroleum naphtha 1.0 - 10 Asp. Tox. 1;H304 [1] CAS Number: 0064742-95-6 Aquatic Chronic 2;H411 (Self Classification) Propylene glycol monomethyl ether acetate 1.0 - 10 Flam. Liq. 3;H226 [1] CAS Number: 0000108-65-6 1,2,4-Trimethyl benzene 1.0 - 10 Flam. Liq. 3;H226 [1] CAS Number: 0000095-63-6 Acute Tox. 4;H332 Eye Irrit. 2;H319 STOT SE 3;H335 Skin Irrit. 2;H315 Aquatic Chronic 2;H411 Xylenes (o-, m-, p- isomers) 1.0 - 10 Flam. Liq. 3;H226 [1][2] CAS Number: 0001330-20-7 Acute Tox. 4;H332 Acute Tox. 4;H312 Skin Irrit. 2;H315 Eye Irrit. 2;H319 STOT SE 3;H335 Asp. Tox. 1;H304 Kaolin 1.0 - 10 ---- [1][2] CAS Number: 0001332-58-7 BUTYL ACETATE 1.0 - 10 Flam. Liq. 3;H226 [1][2] CAS Number: 0000123-86-4 STOT SE 3;H336 Bis (1,2,2,6,6-pentamethyl-4-piperidinyl) 0.10 - 1.0 Skin Sens. 1;H317 [1] sebacate Aquatic Chronic CAS Number: 0041556-26-7 1;H410 Aquatic Acute 1;H400 Methyl ethyl ketoxime 0.10 - 1.0 Carc. 2;H351 [1] CAS Number: 0000096-29-7 Acute Tox. 4;H312 Eye Dam. 1;H318 Skin Sens. 1;H317 DECANEDIOIC ACID, METHYL 0.10 - 1.0 Skin Sens. 1;H317 [1] 1,2,2,6,6-PENTAMETHYL-4-P Aquatic Chronic CAS Number: 0082919-37-7 1;H410 Hexanoic acid, 2-ethyl-, cobalt(2+) salt 0.10 - 1.0 Acute Tox. 4;H302 [1] CAS Number: 0000136-52-7 Skin Sens. 1;H317
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Repr. 2;H361F Aquatic Acute 1;H400 Aquatic Chronic 1;H410 [1] Substance classified with a health or environmental hazard. [2] Substance with a workplace exposure limit. [3] PBT-substance or vPvB-substance.
*The full texts of the phrases are shown in Section 16.
4. First aid measures
4.1. Description of first aid measures General Remove contaminated clothing and shoes. Get medical attention immediately. Wash clothing before reuse. Thoroughly clean or destroy contaminated shoes. Inhalation If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately. Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention immediately. Skin In case of contact, immediately flush skin with soap and plenty of water. Get medical attention immediately. Ingestion If swallowed, immediately contact Poison Control Center at 1-800-854-6813. DO NOT induce vomiting unless instructed to do so by medical personnel. Never give anything by mouth to an unconscious person. 4.2. Most important symptoms and effects, both acute and delayed Overview NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. Avoid contact with eyes, skin and clothing. Inhalation Harmful if inhaled. Causes nose and throat irritation. Vapors may affect the brain or nervous system causing dizziness, headache or nausea. Eyes Risk of serious damage to eyes. Do not get in eyes. Protective equipment should be selected to provide protection from exposure to the chemicals listed in Section 3 of this document. Depending on the site-specific condition of use, safety glasses, chemical goggles, and/or head and face protection may be required to prevent contact. The equipment must be thouroughly cleaned, or discarded after each use. Skin Causes skin irritation. May cause delayed skin irritation. May be harmful if absorbed through the skin. Ingestion Harmful if swallowed. May cause abdominal pain, nausea, vomiting, diarrhea, or drowsiness. Chronic effects Possible cancer hazard. Contains an ingredient which may cause cancer based on animal data (See Section 2 and Section 15 for each ingredient). Risk of cancer depends on duration and level of exposure.
5. Fire-fighting measures
5.1. Extinguishing media CAUTION: This product has a very low flashpoint. Use of water spray when fighting fire may be inefficient. CAUTION: For mixtures containing alcohol or polar solvent, alcohol-resistant foam may be more effective. SMALL FIRES: Use dry chemical, CO2, water spray or regular foam. LARGE FIRES: Use water spray, fog, or regular foam. Do not use straight streams. Move containers from fire area if you can do so without risk. 5.2. Special hazards arising from the substance or mixture HIGHLY FLAMMABLE MATERIALS: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks) creating a vapor explosion hazard. Runoff to sewers may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water. 5.3. Advice for fire-fighters Cool closed containers exposed to fire by spraying them with water. Do not allow run off water and contaminants from fire fighting to enter drains or water courses. ERG Guide No. 128
6. Accidental release measures
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6.1. Personal precautions, protective equipment and emergency procedures ELIMINATE ALL IGNITION SOURCES (no smoking, flares, sparks or flames in immediate area). Use only non-sparking equipment to handle spilled material and absorbent. Do not touch or walk through spilled material. Stop leak if you can do so without risk. Prevent entry into waterways, sewers, basements or confined areas. A vapor suppressing foam may be used to reduce vapors. Absorb or cover with dry earth, sand, or other non-combustible material and transfer to containers. Use non-sparking tools to collect absorbed material. 6.2. Environmental precautions Do not allow spills to enter drains or watercourses. 6.3. Methods and material for containment and cleaning up CALL CHEMTREC at (800)-424-9300 for emergency response. Isolate spill or leak area immediately for at least 50 meters (150 feet) in all directions. Keep unauthorized personnel away. Stay upwind. Keep out of low areas. Ventilate closed spaces before entering. LARGE SPILLS: Consider initial downwind evacuation for at least 300 meters (1000 feet).
7. Handling and storage
7.1. Precautions for safe handling Handling Vapors may cause flash fire or ignite explosively.
In Storage Keep away from heat, sparks and flame.
7.2. Conditions for safe storage, including any incompatibilities Store between 40-100F (4-38C). Do not get in eyes, on skin or clothing. Strong oxidizing agents. Do not smoke. Extinguish all flames and pilot lights, and turn off stoves, heaters, electric motors and other sources of ignition during use and until all vapors are gone.
7.3. Specific end use(s) Close container after each use. Wash thoroughly after handling. Prevent build-up of vapors by opening all windows and doors to achieve cross-ventilation.
8. Exposure controls and personal protection
8.1. Control parameters Exposure CAS No. Ingredient Source Value 0000095-63-6 1,2,4-Trimethyl benzene OSHA No Established Limit ACGIH No Established Limit NIOSH 25 ppm TWA; 125 mg/m3 TWA Supplier No Established Limit OHSA, No Established Limit CAN Mexico No Established Limit Brazil No Established Limit 0000096-29-7 Methyl ethyl ketoxime OSHA No Established Limit ACGIH No Established Limit NIOSH No Established Limit Supplier No Established Limit OHSA, No Established Limit CAN Mexico No Established Limit Brazil No Established Limit 0000108-65-6 Propylene glycol monomethyl ether acetate OSHA No Established Limit
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ACGIH No Established Limit NIOSH No Established Limit Supplier No Established Limit OHSA, 50 ppm TWA; 270 mg/m3 TWA CAN Mexico No Established Limit Brazil No Established Limit 0000110-43-0 Methyl n-amyl ketone OSHA 100 ppm TWA; 465 mg/m3 TWA ACGIH 50 ppm TWA NIOSH 100 ppm TWA; 465 mg/m3 TWA800 ppm IDLH Supplier No Established Limit OHSA, 25 ppm TWA; 115 mg/m3 TWA CAN Mexico 50 ppm TWA LMPE-PPT; 235 mg/m3 TWA LMPE-PPT100 ppm STEL [LMPE-CT]; 465 mg/m3 STEL [LMPE-CT] Brazil No Established Limit 0000123-86-4 BUTYL ACETATE OSHA 150 ppm TWA; 710 mg/m3 TWA200 ppm STEL; 950 mg/m3 STEL ACGIH 150 ppm TWA200 ppm STEL NIOSH 150 ppm TWA; 710 mg/m3 TWA200 ppm STEL; 950 mg/m3 STEL1700 ppm IDLH (10% LEL) Supplier No Established Limit OHSA, 150 ppm TWA200 ppm STEL CAN Mexico 150 ppm TWA LMPE-PPT; 710 mg/m3 TWA LMPE-PPT200 ppm STEL [LMPE-CT]; 950 mg/m3 STEL [LMPE-CT] Brazil No Established Limit 0000136-52-7 Hexanoic acid, 2-ethyl-, cobalt(2+) salt OSHA No Established Limit ACGIH No Established Limit NIOSH No Established Limit Supplier No Established Limit OHSA, No Established Limit CAN Mexico No Established Limit Brazil No Established Limit 0001330-20-7 Xylenes (o-, m-, p- isomers) OSHA 100 ppm TWA; 435 mg/m3 TWA150 ppm STEL; 655 mg/m3 STEL ACGIH 100 ppm TWA150 ppm STEL NIOSH No Established Limit Supplier No Established Limit OHSA, 100 ppm TWA150 ppm STEL CAN Mexico 100 ppm TWA LMPE-PPT; 435 mg/m3 TWA LMPE-PPT150 ppm STEL [LMPE-CT]; 655 mg/m3 STEL [LMPE-CT] Brazil 78 ppm TWA LT; 340 mg/m3 TWA LT 0001332-58-7 Kaolin OSHA 15 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction) ACGIH 2 mg/m3 TWA (particulate matter containing no asbestos and NIOSH 10 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable dust) Supplier No Established Limit
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OHSA, 2 mg/m3 TWA (containing no CAN Asbestos and Mexico 10 mg/m3 TWA LMPE-PPT20 mg/m3 STEL [LMPE-CT] Brazil No Established Limit 0007727-43-7 Barium sulfate OSHA 15 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction) ACGIH 10 mg/m3 TWA NIOSH 10 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable dust) Supplier No Established Limit OHSA, 10 mg/m3 TWA CAN Mexico No Established Limit Brazil No Established Limit 0041556-26-7 Bis (1,2,2,6,6-pentamethyl-4-piperidinyl) OSHA No Established Limit sebacate ACGIH No Established Limit NIOSH No Established Limit Supplier No Established Limit OHSA, No Established Limit CAN Mexico No Established Limit Brazil No Established Limit 0064742-95-6 Petroleum naphtha OSHA No Established Limit ACGIH No Established Limit NIOSH No Established Limit Supplier No Established Limit OHSA, No Established Limit CAN Mexico No Established Limit Brazil No Established Limit 0082919-37-7 DECANEDIOIC ACID, METHYL OSHA No Established Limit 1,2,2,6,6-PENTAMETHYL-4-P ACGIH No Established Limit NIOSH No Established Limit Supplier No Established Limit OHSA, No Established Limit CAN Mexico No Established Limit Brazil No Established Limit Proprietary METHYLOXYDIMETHYLPHENYLSILOXANE OSHA No Established Limit - EXPERIMENTAL POLYMER ACGIH No Established Limit (PROPRIETARY) NIOSH No Established Limit Supplier No Established Limit OHSA, No Established Limit CAN Mexico No Established Limit Brazil No Established Limit
Health Data CAS No. Ingredient Source Value 0000095-63-6 1,2,4-Trimethyl benzene NIOSH No Established Limit 0000096-29-7 Methyl ethyl ketoxime NIOSH No Established Limit 0000108-65-6 Propylene glycol monomethyl ether acetate NIOSH No Established Limit 0000110-43-0 Methyl n-amyl ketone NIOSH Irritation; liver kidney 0000123-86-4 BUTYL ACETATE NIOSH Mucous membrane and eye irritation; high concentrations cause nervous system effects in animals 0000136-52-7 Hexanoic acid, 2-ethyl-, cobalt(2+) salt NIOSH No Established Limit 0001330-20-7 Xylenes (o-, m-, p- isomers) NIOSH
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Central nervous system depressant; respiratory and eye irritation 0001332-58-7 Kaolin NIOSH Skin and mucous membrane injury respiratory effects 0007727-43-7 Barium sulfate NIOSH Eye nose 0041556-26-7 Bis (1,2,2,6,6-pentamethyl-4-piperidinyl) NIOSH No Established Limit sebacate 0064742-95-6 Petroleum naphtha NIOSH No Established Limit 0082919-37-7 DECANEDIOIC ACID, METHYL NIOSH No Established Limit 1,2,2,6,6-PENTAMETHYL-4-P Proprietary METHYLOXYDIMETHYLPHENYLSILOXANE NIOSH No Established Limit - EXPERIMENTAL POLYMER (PROPRIETARY)
Carcinogen Data CAS No. Ingredient Source Value 0000095-63-6 1,2,4-Trimethyl benzene OSHA Select Carcinogen: No NTP Known: No; Suspected: No IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No; 0000096-29-7 Methyl ethyl ketoxime OSHA Select Carcinogen: No NTP Known: No; Suspected: No IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No; 0000108-65-6 Propylene glycol monomethyl ether acetate OSHA Select Carcinogen: No NTP Known: No; Suspected: No IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No; 0000110-43-0 Methyl n-amyl ketone OSHA Select Carcinogen: No NTP Known: No; Suspected: No IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No; 0000123-86-4 BUTYL ACETATE OSHA Select Carcinogen: No NTP Known: No; Suspected: No IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No; 0000136-52-7 Hexanoic acid, 2-ethyl-, cobalt(2+) salt OSHA Select Carcinogen: No NTP Known: No; Suspected: No IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No; 0001330-20-7 Xylenes (o-, m-, p- isomers) OSHA Select Carcinogen: No NTP Known: No; Suspected: No IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: Yes; Group 4: No; 0001332-58-7 Kaolin OSHA Select Carcinogen: No NTP Known: No; Suspected: No IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No; 0007727-43-7 Barium sulfate OSHA Select Carcinogen: No NTP Known: No; Suspected: No IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No; 0041556-26-7 Bis (1,2,2,6,6-pentamethyl-4-piperidinyl) OSHA Select Carcinogen: No sebacate NTP Known: No; Suspected: No IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No; 0064742-95-6 Petroleum naphtha OSHA Select Carcinogen: No NTP Known: No; Suspected: No IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No;
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0082919-37-7 DECANEDIOIC ACID, METHYL OSHA Select Carcinogen: No 1,2,2,6,6-PENTAMETHYL-4-P NTP Known: No; Suspected: No IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No; Proprietary METHYLOXYDIMETHYLPHENYLSILOXANE OSHA Select Carcinogen: No - EXPERIMENTAL POLYMER NTP Known: No; Suspected: No (PROPRIETARY) IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No;
8.2. Exposure controls Respiratory Select equipment to provide protection from the ingredients listed in Section 3 of this document. Ensure fresh air entry during application and drying. If you experience eye watering, headache or dizziness or if air monitoring demonstrates dust, vapor, or mist levels are above applicable limits, wear an appropriate, properly fitted respirator (NIOSH approved) during and after application. Follow respirator manufacturer's directions for respirator use. FOR USERS OF 3M RESPIRATORY PROTECTION ONLY: For information and assistance on 3M occupational health and safety products, call OH&ESD Technical Service toll free in U.S.A. 1-800-243-4630, in Canada call 1-800-267-4414. Please do not contact these numbers regarding other manufacturer's respiratory protection products. 3M does not endorse the accuracy of the information contained in this Material Safety Data Sheet. Eyes Avoid contact with eyes. Protective equipment should be selected to provide protection from exposure to the chemicals listed in Section 3 of this document. Depending on the site-specific conditions of use, safety glasses, chemical goggles, and/or head and face protection may be required to prevent contact. The equipment must be thoroughly cleaned, or discarded after each use. Skin Protective equipment should be selected to provide protection from exposure to the chemicals listed in Section 3 of this document. Depending on the site-specific conditions of use, protective gloves, apron, boots, head and face protection may be required to prevent contact. The equipment must be thoroughly cleaned, or discarded after each use. Engineering Controls Depending on the site-specific conditions of use, provide adequate ventilation. Other Work Practices Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. Use good personal hygiene practices. Wash hands before eating, drinking, using toilet facilities, etc. Promptly remove soiled clothing and wash clothing thoroughly before reuse. Shower after work using plenty of soap and water.
9. Physical and chemical properties
Appearance Coloured Liquid Odour threshold Not Measured pH No Established Limit Melting point / freezing point Not Measured Initial boiling point and boiling range 64 (C) 147 (F) Flash Point 39 (C) 102 (F) Evaporation rate (Ether = 1) Not Measured Flammability (solid, gas) Not Applicable Upper/lower flammability or explosive Lower Explosive Limit: 1 limits Upper Explosive Limit: No Established Limit vapor pressure (Pa) Not Measured Vapor Density Heavier than air Specific Gravity 1.32 Partition coefficient n-octanol/water (Log Not Measured Kow) Auto-ignition temperature Not Measured Decomposition temperature Not Measured Viscosity (cSt) No Established Limit Not Measured Refer to the Technical Data Sheet or label where information is VOC % available.
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9.2. Other information No further information
10. Stability and reactivity
10.1. Reactivity No data available 10.2. Chemical stability This product is stable and hazardous polymerization will not occur. Not sensitive to mechanical impact. Excessive heat and fumes generation can occur if improperly handled. 10.3. Possibility of hazardous reactions No data available 10.4. Conditions to avoid No data available 10.5. Incompatible materials Strong oxidizing agents. 10.6. Hazardous decomposition products HIGHLY FLAMMABLE MATERIALS: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks) creating a vapor explosion hazard. Runoff to sewers may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.
11. Toxicological information
Acute toxicity
NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal.
Ingredient Oral LD50, Skin LD50, Inhalation Inhalation mg/kg mg/kg Vapor LD50, Dust/Mist LD50, mg/L/4hr mg/L/4hr Barium sulfate - (7727-43-7) 3,000.00, No data No data No data available Mouse - available available Category: 5 Methyl n-amyl ketone - (110-43-0) 1,670.00, 12,600.00, No data No data available Rat - Rabbit - available Category: 4 Category: NA
METHYLOXYDIMETHYLPHENYLSILOXANE - No data No data No data No data available EXPERIMENTAL POLYMER (PROPRIETARY) available available available - (Proprietary) Petroleum naphtha - (64742-95-6) 6,800.00, 3,400.00, No data No data available Rat - Rabbit - available Category: Category: 5 NA Propylene glycol monomethyl ether acetate - 8,532.00, 5,000.00, No data No data available (108-65-6) Rat - Rabbit - available Category: Category: 5 NA 1,2,4-Trimethyl benzene - (95-63-6) 3,400.00, 3,160.00, 18.00, Rat - No data available Rat - Rabbit - Category: 4 Category: 5 Category: 5 Xylenes (o-, m-, p- isomers) - (1330-20-7) 4,299.00, 1,548.00, 20.00, Rat - No data available Rat - Rabbit - Category: 4 Category: 5 Category: 4 Kaolin - (1332-58-7) No data No data No data No data available available available available BUTYL ACETATE - (123-86-4) 10,700.00, 17,600.00, No data No data available Rat - Rabbit - available Category: Category: NA
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NA Bis (1,2,2,6,6-pentamethyl-4-piperidinyl) 2,615.00, No data No data No data available sebacate - (41556-26-7) Rat - available available Category: 5 Methyl ethyl ketoxime - (96-29-7) 930.00, Rat - 2,000.00, 20.00, Rat - No data available Category: 4 Rabbit - Category: 4 Category: 4 DECANEDIOIC ACID, METHYL No data No data No data No data available 1,2,2,6,6-PENTAMETHYL-4-P - (82919-37-7) available available available Hexanoic acid, 2-ethyl-, cobalt(2+) salt - 1,220.00, 5,000.00, Rat No data No data available (136-52-7) Rabbit - - Category: 5 available Category: 4
Item Category Hazard Acute Toxicity (mouth) Not Classified Not Applicable Acute Toxicity (skin) Not Classified Not Applicable Acute Toxicity (inhalation) Not Classified Not Applicable Skin corrosion/irritation 3 Causes mild skin irritation. Eye damage/irritation Not Classified Not Applicable Sensitization (respiratory) Not Classified Not Applicable Sensitization (skin) Not Classified Not Applicable Germ toxicity Not Classified Not Applicable Carcinogenicity Not Classified Not Applicable Reproductive Toxicity Not Classified Not Applicable Specific target organ systemic toxicity Not Classified Not Applicable (single exposure) Specific target organ systemic Not Classified Not Applicable Toxicity (repeated exposure) Aspiration hazard Not Classified Not Applicable
12. Ecological information
12.1. Toxicity No additional information provided for this product. See Section 3 for chemical specific data.
Aquatic Ecotoxicity
96 hr LC50 fish, 48 hr EC50 crustacea, ErC50 algae, Ingredient mg/l mg/l mg/l Barium sulfate - (7727-43-7) 59,000.00, Poecilia 32.00, Daphnia Not Available sphenops magna Methyl n-amyl ketone - (110-43-0) Not Available Not Available 131.00, Pimephales promelas METHYLOXYDIMETHYLPHENYLSILOXANE Not Available Not Available Not Available - EXPERIMENTAL POLYMER (PROPRIETARY) - (Proprietary) Petroleum naphtha - (64742-95-6) 6.14, Daphnia magna 19.00 (72 hr), Selenastrum 9.22, Oncorhynchus capricornutum mykiss Propylene glycol monomethyl ether acetate - 100.00, Salmo 500.00, Daphnia Not Available (108-65-6) gairdneri magna 1,2,4-Trimethyl benzene - (95-63-6) 7.72, Pimephales 3.60, Daphnia magna Not Available promelas Xylenes (o-, m-, p- isomers) - (1330-20-7) 8.50, Palaemonetes 3.30, Oncorhynchus pugio 100.00 (72 hr), Chlorococcales mykiss Kaolin - (1332-58-7) Not Available Not Available Not Available BUTYL ACETATE - (123-86-4) 18.00, Pimephales 32.00, Artemia salina 674.70 (72 hr), Scenedesmus promelas subspicatus
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Bis (1,2,2,6,6-pentamethyl-4-piperidinyl) 1.00, Lepomis 20.00, Daphnia Not Available sebacate - (41556-26-7) macrochirus magna Methyl ethyl ketoxime - (96-29-7) 320.00, Leuciscus 500.00, Daphnia 83.00 (72 hr), Scenedesmus idus magna subspicatus DECANEDIOIC ACID, METHYL Not Available Not Available Not Available 1,2,2,6,6-PENTAMETHYL-4-P - (82919-37-7) Hexanoic acid, 2-ethyl-, cobalt(2+) salt - Not Available Not Available Not Available (136-52-7)
12.2. Persistence and degradability No data available 12.3. Bioaccumulative potential Not Measured 12.4. Mobility in soil No data available 12.5. Results of PBT and vPvB assessment This product contains no PBT/vPvB chemicals. 12.6. Other adverse effects No data available
13. Disposal considerations
13.1. Waste treatment methods Do not allow spills to enter drains or watercourses. Dispose of in accordance with local, state and federal regulations. (Also reference RCRA information in Section 15 if listed).
14. Transport information
14.1. UN number UN 1263 14.2. UN proper shipping name PAINT 14.3. Transport hazard class(es)
DOT (Domestic Surface Transportation) IMO / IMDG (Ocean Transportation) DOT Proper Shipping PAINT IMDG Proper PAINT Name Shipping Name DOT Hazard Class 3 IMDG Hazard Class 3 Sub Class 3 UN / NA Number UN 1263 DOT Packing Group III IMDG Packing Group III CERCLA/DOT RQ 494 gal. / 5422 lbs. System Reference 1 Code
14.4. Packing group III 14.5. Environmental hazards IMDG Marine Pollutant: No
14.6. Special precautions for user Not Applicable 14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not Applicable
15. Regulatory information
Regulatory Overview The regulatory data in Section 15 is not intended to be all-inclusive, only selected regulations are represented. All ingredients of this product are listed on the TSCA (Toxic Substance Control Act) Inventory or are not required to be listed on the TSCA Inventory.
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WHMIS Classification B3
DOT Marine Pollutants (10%): (No Product Ingredients Listed) DOT Severe Marine Pollutants (1%): (No Product Ingredients Listed) EPCRA 311/312 Chemicals and RQs (>.1%) : Benzene, ethyl- (1000 lb final RQ; 454 kg final RQ) BUTYL ACETATE (5000 lb final RQ (listed under Butyl acetate); 2270 kg final RQ (listed under Butyl acetate)) Benzene, 1,2-dimethyl- (1000 lb final RQ; 454 kg final RQ) Styrene (1000 lb final RQ; 454 kg final RQ) Benzene, 1,3-dimethyl- (1000 lb final RQ; 454 kg final RQ) Xylenes (o-, m-, p- isomers) (100 lb final RQ; 45.4 kg final RQ) EPCRA 302 Extremely Hazardous (>.1%) : (No Product Ingredients Listed) EPCRA 313 Toxic Chemicals (>.1%) : 1,2,4-Trimethyl benzene Benzene, ethyl- Benzene, 1,2-dimethyl- Styrene Benzene, 1,3-dimethyl- Xylenes (o-, m-, p- isomers) Mass RTK Substances (>1%) : 1,2,4-Trimethyl benzene Barium sulfate Kaolin Methyl n-amyl ketone BUTYL ACETATE Xylenes (o-, m-, p- isomers) Penn RTK Substances (>1%) : 1,2,4-Trimethyl benzene Barium sulfate Kaolin Methyl n-amyl ketone BUTYL ACETATE Xylenes (o-, m-, p- isomers) Penn Special Hazardous Substances (>.01%) : (No Product Ingredients Listed) RCRA Status: (No Product Ingredients Listed) N.J. RTK Substances (>1%) : 1,2,4-Trimethyl benzene Barium sulfate Kaolin Methyl n-amyl ketone BUTYL ACETATE Xylenes (o-, m-, p- isomers) N.J. Special Hazardous Substances (>.01%) : 2-Butoxyethanol Butyl acrylate Cumene Ethyl alcohol Benzene, ethyl- Methanol Methyl methacrylate Methylpropyl ketone BUTYL ACETATE
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Benzene, 1,2-dimethyl- Quartz Styrene Benzene, 1,3-dimethyl- Xylenes (o-, m-, p- isomers) N.J. Env. Hazardous Substances (>.1%) : 1,2,4-Trimethyl benzene Benzene, ethyl- Benzene, 1,2-dimethyl- Styrene Benzene, 1,3-dimethyl- Xylenes (o-, m-, p- isomers) Proposition 65 - Carcinogens (>0%): Cumene Ethyl alcohol Benzene, ethyl- Quartz Proposition 65 - Female Repro Toxins (>0%): (No Product Ingredients Listed) Proposition 65 - Male Repro Toxins (>0%): (No Product Ingredients Listed) Proposition 65 - Developmental Toxins (>0%): Ethyl alcohol Methanol
16. Other information
The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or warranty of any kind, expressed or implied, is made with respect to the information contained herein. We accept no responsibility and disclaim all liability for any harmful effects which may be caused by exposure to our products. Customers/users of this product must comply with all applicable health and safety laws, regulations, and orders.
The full text of the phrases appearing in section 3 is:
H226 Flammable liquid and vapor. H302 Harmful if swallowed. H304 May be fatal if swallowed and enters airways. H312 Harmful in contact with skin. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H319 Causes serious eye irritation. H332 Harmful if inhaled. H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness. H351 Suspected of causing cancer. H361F Suspected of damaging fertility. H372 Causes damage to organs through prolonged or repeated exposure. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. H411 Toxic to aquatic life with long lasting effects.
This is the first revision of this SDS format, changes from previous revision not applicable.
End of Document
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