Resulting Nitric Acid Is Stronger Than the Calcium Hydroxide Affect the Ph of a Solution. When Applied to Soil, Urea Is
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Calcium Nitrate Calcium Nitrate Is a Highly Soluble Source of Two Plant Nutrients
No. 27 Calcium Nitrate Calcium nitrate is a highly soluble source of two plant nutrients. Its high solubility makes it popular for supplying an immediately available source of nitrate and calcium directly to soil, through irrigation water, or with foliar applications. Production: Phosphate rock is acidified with nitric acid to form a mixture of phosphoric acid and calcium nitrate during the nitrophosphate fertilizer manufacturing process. Ammonia is then added to neutralize excess acidity. Calcium nitrate crystals precipitate via a temperature gradient and are separated as the mixture is cooled. With the ammonia addition and crystallization, a double salt is formed [5 Ca(NO3)2•NH4NO3•10 H2O, referred to as 5:1:10 double salt] and is considered the commercial grade of calcium nitrate. Hence, small amounts of ammonical N may also be present in this grade of calcium nitrate. Calcium nitrate is also manufactured by reacting nitric acid with crushed limestone forming either the 5:1:10 double salt or calcium nitrate tetrahydrate (Ca(NO3)2•4 H2O). The latter product is often produced as a wet crystal or a mesh and is subject to specific regulation with respect to handling and safety. Prilling and granulating are the most common methods of making particles ready for field use. Calcium nitrate is very hygroscopic (absorbs water from the air), so when intended for soil application, proprietary coatings are applied to minimize moisture uptake. Calcium nitrate intended for hydroponics or fertigation does not contain a conditioner, or it may be sold -
Effects of Different Sources of Fertilizer Nitrogen on Growth and Nutrition of Western Hemlock Seedlings
Effects of Different Sources U.S. Department of Agriculture Forest Service Pacific Northwest Forest of FertiIizer Nitrogen and Range Experiment Station Research Paper PNW-267 on Growth and Nutrition oJ February 1980 Western Hemlock Seedlings ---. --_. ------------------------ , I _J Authors M. A. RADWAN is Principal Plant Physiologist and DEAN S. DeBELL is Principal Silviculturist with the Forest Service, u.S. Department of Agriculture, Pacific Northwest Forest and Range Experiment Station, Forestry Sciences Laboratory, Olympia, Washington. En gl ish Equivalents 1 liter 0.2642 gallon 1 kilogram = 2.2046 pound 1 gram = 0.0353 ounce 1 centimeter = 0.3937 inch 1 kilogram per hectare 1.1206 pounds per acre (9/50C) + 32 = of EFFECTS OF DIFFERENT SOURCES OF FERTILIZER NITROGEN ON GROWTH AND NUTRITION OF WESTERN HEMLOCK Reference Abstract Radwan, M. A. , and Dean S. DeBell. 1980. Effects of different sources of fertilizer nitrogen on growth and nutrition of western hemlock seedlings. USDA For. Servo Res. Pap. PNW-267, 15 p. Pacific Northwest Forest and Range Experiment Station, Portland, Oregon. Twelve different nitrogen (N) fertilizer treatments were tested on potted western hemlock (Tsuga heterophylla (Raf. ) Sarg.) seedlings. Fertilizers affected soil N and pH, and growth and foliar chemical com position of seedlings. Ura plus N-Serve and sulfur-coated urea appear more promising for promoting growth than other fertilizers tested. Results, however, do not explain reported variability in response of hemlock stands to N fertilization. Keywords: Nitrogen fertilizer response, seedling growth, western hemlock, Tsuga heterophylla. RESEARCH SUMMARY Research Paper PNW-267 1980 The following fertilization treatments were applied in the spring to potted, 4-year-old western hemlock (Tsuga heterophylla (Raf. -
Periodic Trends in the Main Group Elements
Chemistry of The Main Group Elements 1. Hydrogen Hydrogen is the most abundant element in the universe, but it accounts for less than 1% (by mass) in the Earth’s crust. It is the third most abundant element in the living system. There are three naturally occurring isotopes of hydrogen: hydrogen (1H) - the most abundant isotope, deuterium (2H), and tritium 3 ( H) which is radioactive. Most of hydrogen occurs as H2O, hydrocarbon, and biological compounds. Hydrogen is a colorless gas with m.p. = -259oC (14 K) and b.p. = -253oC (20 K). Hydrogen is placed in Group 1A (1), together with alkali metals, because of its single electron in the valence shell and its common oxidation state of +1. However, it is physically and chemically different from any of the alkali metals. Hydrogen reacts with reactive metals (such as those of Group 1A and 2A) to for metal hydrides, where hydrogen is the anion with a “-1” charge. Because of this hydrogen may also be placed in Group 7A (17) together with the halogens. Like other nonmetals, hydrogen has a relatively high ionization energy (I.E. = 1311 kJ/mol), and its electronegativity is 2.1 (twice as high as those of alkali metals). Reactions of Hydrogen with Reactive Metals to form Salt like Hydrides Hydrogen reacts with reactive metals to form ionic (salt like) hydrides: 2Li(s) + H2(g) 2LiH(s); Ca(s) + H2(g) CaH2(s); The hydrides are very reactive and act as a strong base. It reacts violently with water to produce hydrogen gas: NaH(s) + H2O(l) NaOH(aq) + H2(g); It is also a strong reducing agent and is used to reduce TiCl4 to titanium metal: TiCl4(l) + 4LiH(s) Ti(s) + 4LiCl(s) + 2H2(g) Reactions of Hydrogen with Nonmetals Hydrogen reacts with nonmetals to form covalent compounds such as HF, HCl, HBr, HI, H2O, H2S, NH3, CH4, and other organic and biological compounds. -
CAN-17 Calcium Ammonium Nitrate 17-0-0 GUARANTEED ANALYSIS TOTAL NITROGEN (N)
Product Data Sheet CAN-17 Calcium Ammonium Nitrate 17-0-0 GUARANTEED ANALYSIS TOTAL NITROGEN (N) ...................................................................................................................................17.00% 5.40% Ammoniacal Nitrogen 11.60% Nitrate Nitrogen Calcium (Ca) ......................................................................................................................................................8.80% Derived from Ammonium Nitrate and Calcium Nitrate. KEEP OUT OF REACH OF CHILDREN 3. This product is a commercial fertilizer used as plant WARNING food in agricultural crop production. For specific CAUSES SKIN IRRITATION. application rates follow the recommendation of a CAUSES SERIOUS EYE IRRITATION. qualified individual or institution, such as, but not PRECAUTIONARY STATEMENTS: Wash thoroughly after limited to, a certified crop advisor, agronomist, handling. Specific treatment see First Aid section on this label. university crop extension publication, or apply PERSONAL PROTECTIVE EQUIPMENT: Wear protective according to recommendations in your approved gloves / protective clothing / eye protection / face protection. Take off nutrient management plan. contaminated clothing and wash before reuse. FIRST AID: IF ON SKIN Wash with plenty of water. If skin ir- ADVANTAGES ritation occurs, get medical advice / attention. IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if 1. Contains two forms of nitrogen– Nitrate nitrogen, fast present and easy to do. Continue rinsing. -
Effect of Calcium Precursor on the Bioactivity and Biocompatibility of Sol-Gel-Derived Glasses
Journal of Functional Biomaterials Article Effect of Calcium Precursor on the Bioactivity and Biocompatibility of Sol-Gel-Derived Glasses Alejandra Ruiz-Clavijo 1,2, Andrew P. Hurt 2, Arun K. Kotha 2 and Nichola J. Coleman 2,* 1 Facultad de Ciencias Químicas, Universidad Complutense de Madrid, Av. Complutense, 28040 Madrid, Spain; [email protected] 2 Faculty of Engineering and Science, University of Greenwich, Chatham Maritime, Kent ME4 4TB, UK; [email protected] (A.P.H.); [email protected] (A.K.K.) * Correspondence: [email protected]; Tel.: +44-208-331-9825 Received: 3 January 2019; Accepted: 20 February 2019; Published: 23 February 2019 Abstract: This study investigated the impact of different calcium reagents on the morphology, composition, bioactivity and biocompatibility of two-component (CaO-SiO2) glasses produced by the Stöber process with respect to their potential application in guided tissue regeneration (GTR) membranes for periodontal repair. The properties of the binary glasses were compared with those of pure silica Stöber particles. The direct addition of calcium chloride (CC), calcium nitrate (CN), calcium methoxide (CM) or calcium ethoxide (CE) at 5 mol % with respect to tetraethyl orthosilicate in the reagent mixture gave rise to textured, micron-sized aggregates rather than monodispersed ~500 nm spheres obtained from the pure silica Stöber synthesis. The broadening of the Si-O-Si band at ~1100 cm−1 in the infrared spectra of the calcium-doped glasses indicated that the silicate network was depolymerised by the incorporation of Ca2+ ions and energy dispersive X-ray analysis revealed that, in all cases, the Ca:Si ratios were significantly lower than the nominal value of 0.05. -
140. Sulphuric, Hydrochloric, Nitric and Phosphoric Acids
nr 2009;43(7) The Nordic Expert Group for Criteria Documentation of Health Risks from Chemicals 140. Sulphuric, hydrochloric, nitric and phosphoric acids Marianne van der Hagen Jill Järnberg arbete och hälsa | vetenskaplig skriftserie isbn 978-91-85971-14-5 issn 0346-7821 Arbete och Hälsa Arbete och Hälsa (Work and Health) is a scientific report series published by Occupational and Enviromental Medicine at Sahlgrenska Academy, University of Gothenburg. The series publishes scientific original work, review articles, criteria documents and dissertations. All articles are peer-reviewed. Arbete och Hälsa has a broad target group and welcomes articles in different areas. Instructions and templates for manuscript editing are available at http://www.amm.se/aoh Summaries in Swedish and English as well as the complete original texts from 1997 are also available online. Arbete och Hälsa Editorial Board: Editor-in-chief: Kjell Torén Tor Aasen, Bergen Kristina Alexanderson, Stockholm Co-editors: Maria Albin, Ewa Wigaeus Berit Bakke, Oslo Tornqvist, Marianne Törner, Wijnand Lars Barregård, Göteborg Eduard, Lotta Dellve och Roger Persson Jens Peter Bonde, Köpenhamn Managing editor: Cina Holmer Jörgen Eklund, Linköping Mats Eklöf, Göteborg © University of Gothenburg & authors 2009 Mats Hagberg, Göteborg Kari Heldal, Oslo Arbete och Hälsa, University of Gothenburg Kristina Jakobsson, Lund SE 405 30 Gothenburg, Sweden Malin Josephson, Uppsala Bengt Järvholm, Umeå ISBN 978-91-85971-14-5 Anette Kærgaard, Herning ISSN 0346–7821 Ann Kryger, Köpenhamn http://www.amm.se/aoh -
Arsine Back up Data Report
NIOSH Manual of Analytical Methods (NMAM) 5th Edition BACKUP DATA REPORT NIOSH Method No. 6001 Title: Arsine Analyte: Arsine Author/developer: Developed under contract Date: 1976 Note: Method 6001 is a combination of two older, previously published methods: S229 and P&CAM 265. Therefore, the backup data report is a combination of the two methods’ reports. The backup data report for method S229 is a regular written report. The backup data report for P&CAM 265, however, is in the form of a published journal article. The written report for S229 follows, the journal article for P&CAM can be seen here as a pdf. Disclaimer: Mention of any company or product does not constitute endorsement by the National Institute for Occupational Safety and Health, Centers for Disease Control and Prevention. In addition, citations to websites external to NIOSH do not constitute NIOSH endorsement of the sponsoring organizations or their programs or products. Furthermore, NIOSH is not responsible for the content of these websites. All web addresses referenced in this document were accessible as of the publication date. NIOSH Manual of Analytical Methods (NMAM), Fifth Edition Backup Data Report Method S229 Substance: Arsine OSHA Standard: 0.2 mg/m3 Chemical Used: Arsine in Nitrogen (14 ppm), Linde Specialty Gases Procedure The general procedure used is described in NIOSH Method 6001. The collection method has been adapted from P&CAM 127. The charcoal used was Lot 105 activated coconut charcoal supplied by SKC, Inc., Pittsburgh, PA. Desorption efficiency tests have not been carried out because the low concentration of the arsine source would require that large volumes of gas (200-800 ml) had to be injected directly into the charcoal tube. -
AMMONIA and NITRIC ACID CONCENTRATIONS · in EQUILIBRIUM with ATMOSPHERIC AEROSOLS: EXPERIMENT VS • THEORY Lynn M
AMMONIA AND NITRIC ACID CONCENTRATIONS · IN EQUILIBRIUM WITH ATMOSPHERIC AEROSOLS: EXPERIMENT VS • THEORY Lynn M. Rildemann,+ Armistead G. Russell,* Glen R. Cass+ California Institute of Technology Pasadena, California 91125 ABSTRACT The equilibrium between gaseous ammonia, nitric acid, and aerosol nitrate is discussed on the basis of a recent field experiment in Southern California. Comparison is drawn between theoretical equilibrium calculations and simultaneous measurements of nitric acid, ammonia, ammonium ion, nitrate ion, sulfate ion, other ionic species, temperature and dewpoint. Particulate .and gaseous pollutant concentrations at some inland sampling sites are readily explained if the aerosol is assumed to exist as an external mixture with all particulate nitrate and ammonium available to form pure NR • At other monitoring sites, especially near the 4No3 coast, aerosol nitrate is found in the presence of NR and RN0 concentrations that 3 3 thermodynamic calculations show are too low to produce pure NR No • This can be 4 3 explained when the amount of aerosol nitrate that can be derived from reaction of nitric acid with sea salt and soil dust is taken into account. A calculation approach that accounts for the presence of mixed sulfate and nitrate salts improves the agreement between predicted and observed pollutant concentrations in the majority of cases studied. Uncertainties in these calculations arise from a number of sources including the thermodynamic quantities, and the effect of these uncertainties on the comparison between -
Nitration of Toluene (Electrophilic Aromatic Substitution)
Nitration of Toluene (Electrophilic Aromatic Substitution) Electrophilic aromatic substitution represents an important class of reactions in organic synthesis. In "aromatic nitration," aromatic organic compounds are nitrated via an electrophilic aromatic substitution mechanism involving the attack of the electron-rich benzene ring on the nitronium ion. The formation of a nitronium ion (the electrophile) from nitric acid and sulfuric acid is shown below. The sulfuric acid is regenerated and hence acts as a catalyst. It also absorbs water to drive the reaction forward. Figure 1: The mechanism for the formation of a nitronium ion. The methyl group of toluene makes it around 25 times more reactive than benzene in electrophilic aromatic substitution reactions. Toluene undergoes nitration to give ortho and para nitrotoluene isomers, but if heated it can give dinitrotoluene and ultimately the explosive trinitrotoluene (TNT). Figure 2: Reaction of nitric acid and sulfuric acid with toluene. Procedure: 1. Place a 5 mL conical vial, equipped with a spin vane, in a crystallizing dish filled with ice-water placed on a stirrer. 2. Pour 1.0 mL of concentrated nitric acid into the vial. While stirring, slowly add 1.0 mL of concentrated sulfuric acid. 3. After the addition of sulfuric acid is complete, add 1.0 mL of toluene dropwise and slowly over a period of 5 minutes (slow down if you see boiling. Reaction produces a lot of heat). 4. While Stirring, allow the contents of the flask to reach the room temperature. Stir at room temperature for another 5 minutes. 5. Add 10 mL of water into a small separatory funnel. -
Effect of a Nitrite/Nitrate-Based Accelerator on the Strength Development and Hydrate Formation in Cold-Weather Cementitious Materials
materials Article Effect of a Nitrite/Nitrate-Based Accelerator on the Strength Development and Hydrate Formation in Cold-Weather Cementitious Materials Akira Yoneyama 1, Heesup Choi 1,* , Masumi Inoue 1, Jihoon Kim 2, Myungkwan Lim 3,* and Yuhji Sudoh 4 1 Department of Civil and Environmental Engineering, Kitami Institute of Technology, Hokkaido 090-8507, Japan; [email protected] (A.Y.); [email protected] (M.I.) 2 Faculty of Environmental Technology, Muroran Institute of Technology, Hokkaido 090-8585, Japan; [email protected] 3 Department of Architectural Engineering, Songwon University, Gwangju 61756, Korea 4 Basic Chemicals Department Chemicals Division, Nissan Chemical Corporation, Tokyo 103-6119, Japan; [email protected] * Correspondence: [email protected] (H.C.); [email protected] (M.L.) Abstract: Recently, there has been increased use of calcium-nitrite and calcium-nitrate as the main components of chloride- and alkali-free anti-freezing agents to promote concrete hydration in cold weather concreting. As the amount of nitrite/nitrate-based accelerators increases, the hydration of tricalcium aluminate (C3A phase) and tricalcium silicate (C3S phase) in cement is accelerated, thereby improving the early strength of cement and effectively preventing initial frost damage. Nitrite/nitrate-based accelerators are used in larger amounts than usual in low temperature areas ◦ below −10 C. However, the correlation between the hydration process and strength development in concrete containing considerable nitrite/nitrate-based accelerators remains to be clearly identified. Citation: Yoneyama, A.; Choi, H.; In this study, the hydrate composition (via X-ray diffraction and nuclear magnetic resonance), pore Inoue, M.; Kim, J.; Lim, M.; Sudoh, Y. -
PB1616-Plant Nutrition and Fertilizers for Greenhouse Production
University of Tennessee, Knoxville TRACE: Tennessee Research and Creative Exchange Commercial Horticulture UT Extension Publications 2-1999 PB1616-Plant Nutrition and Fertilizers for Greenhouse Production The University of Tennessee Agricultural Extension Service Follow this and additional works at: https://trace.tennessee.edu/utk_agexcomhort Part of the Horticulture Commons Recommended Citation "PB1616-Plant Nutrition and Fertilizers for Greenhouse Production," The University of Tennessee Agricultural Extension Service, PB1616-1M-2/99 E12-2015-00-104-99, https://trace.tennessee.edu/ utk_agexcomhort/4 The publications in this collection represent the historical publishing record of the UT Agricultural Experiment Station and do not necessarily reflect current scientific knowledge or ecommendations.r Current information about UT Ag Research can be found at the UT Ag Research website. This Greenhouse Production is brought to you for free and open access by the UT Extension Publications at TRACE: Tennessee Research and Creative Exchange. It has been accepted for inclusion in Commercial Horticulture by an authorized administrator of TRACE: Tennessee Research and Creative Exchange. For more information, please contact [email protected]. Agricultural Extension Service The University of Tennessee PB1616 PlantNutrition &Fertilizers For Greenhouse Production 1 Table of Contents Plant Nutrition: The Basics______________________________________________________________ 3 Fertilizer Salts ______________________________________________________________________ -
Precipitation Reactions 7.3 Precipitation Reactions
312 Chapter 7 An Introduction to Chemical Reactions 7.3 Precipitation Reactions The reaction that forms the scale in hot water pipes, eventually leading to major plumbing bills, belongs to a category of reactions called precipitation reactions. So does the reaction of calcium and magnesium ions with soap to create a solid scum in your bathtub and washing machine. Cadmium hydroxide, which is used in rechargeable batteries, is made from the precipitation reaction between water solutions of cadmium acetate and sodium hydroxide. This section describes the changes that occur in precipitation reactions, shows you how to predict when they take place, and shows you how to describe them using chemical equations. Precipitation Reactions OBJECTIVE 9 Precipitation reactions, such as the ones we will see in this section, belong to a general class of reactions called double‑displacement reactions. (Double displacement reactions are also called double‑replacement, double‑exchange, or metathesis reactions.) Double displacement reactions have the following form, signifying that the elements in two reacting compounds change partners. AB + CD → AD + CB Precipitation reactions take place between ionic compounds in solution. For example, in the precipitation reactions that we will see, A and C represent the cationic (or positively charged) portions of the reactants and products, and B and D represent the anionic (or negatively charged) portions of the reactants and products. The cation of the first reactant (A) combines with the anion of the second reactant (D) to form the product AD, and the cation of the second reactant (C) combines with the anion of the first reactant to form the product CB.