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Aligning Graphene in Bulk Copper: Nacre-Inspired Nanolaminated

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Aligning Graphene in Bulk Copper: Nacre-Inspired Nanolaminated This item is the archived peer-reviewed author-version of: Aligning graphene in bulk copper : nacre-inspired nanolaminated architecture coupled with in-situ processing for enhanced mechanical properties and high electrical conductivity Reference: Cao Mu, Xiong Ding-Bang, Tan Zhanqiu, Ji Gang, Amin-Ahmadi Behnam, Guo Qiang, Fan Genlian, Guo Cuiping, Li Zhiqiang, Zhang Di.- Aligning graphene in bulk copper : nacre-inspired nanolaminated architecture coupled w ith in-situ processing for enhanced mechanical properties and high electrical conductivity Carbon - ISSN 0008-6223 - 117(2017), p. 65-74 Full text (Publisher's DOI): https://doi.org/10.1016/J.CARBON.2017.02.089 Institutional repository IRUA Accepted Manuscript Aligning graphene in bulk copper: Nacre-inspired nanolaminated architecture coupled with in-situ processing for enhanced mechanical properties and high electrical conductivity Mu Cao, Ding-Bang Xiong, Zhanqiu Tan, Gang Ji, Behnam Amin-Ahmadi, Qiang Guo, Genlian Fan, Cuiping Guo, Zhiqiang Li, Di Zhang PII: S0008-6223(17)30219-1 DOI: 10.1016/j.carbon.2017.02.089 Reference: CARBON 11793 To appear in: Carbon Received Date: 29 December 2016 Revised Date: 22 February 2017 Accepted Date: 25 February 2017 Please cite this article as: M. Cao, D.-B. Xiong, Z. Tan, G. Ji, B. Amin-Ahmadi, Q. Guo, G. Fan, C. Guo, Z. Li, D. Zhang, Aligning graphene in bulk copper: Nacre-inspired nanolaminated architecture coupled with in-situ processing for enhanced mechanical properties and high electrical conductivity, Carbon (2017), doi: 10.1016/j.carbon.2017.02.089. This is a PDF file of an unedited manuscript that has been accepted for publication. As a service to our customers we are providing this early version of the manuscript. The manuscript will undergo copyediting, typesetting, and review of the resulting proof before it is published in its final form. Please note that during the production process errors may be discovered which could affect the content, and all legal disclaimers that apply to the journal pertain. ACCEPTED MANUSCRIPT Graphical Abstract MANUSCRIPT ACCEPTED ACCEPTED MANUSCRIPT Aligning graphene in bulk copper: nacre-inspired nanolaminated architecture coupled with in-situ processing for enhanced mechanical properties and high electrical conductivity Mu Cao a, Ding-Bang Xiong a, *, Zhanqiu Tan a, Gang Ji b, Behnam Amin-Ahmadi c, Qiang Guo a, Genlian Fan a, Cuiping Guo a, Zhiqiang Li a, and Di Zhang a, ** a State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, Shanghai 200240, China MANUSCRIPT b Unité Matériaux et Transformations (UMET) CNRS UMR 8207, Université Lille1, 59655 Villeneuve d’Ascq, France c Electron Microscopy for Materials Science (EMAT), University of Antwerp, Groenenborgerlaan 171, 2020- Antwerp, Belgium * Corresponding author. E-mail address : [email protected] (Ding-Bang Xiong) ** Corresponding author. E-mail address : [email protected] (Di Zhang) ACCEPTED 1 ACCEPTED MANUSCRIPT Abstract: Methods used to strengthen metals generally also cause a pronounced decrease in ductility and electrical conductivity. In this work a bioinspired strategy is applied to surmount the dilemma. By assembling copper submicron flakes cladded with in-situ grown graphene, graphene/copper matrix composites with a nanolaminated architecture inspired by a natural nacre have been prepared. Owing to a combined effect from the bioinspired nanolaminated architecture and improved interfacial bonding, a synergy has been achieved between mechanical strength and ductility as well as electrical conductivity in the graphene/copper matrix composites. With a low volume fraction of only 2.5% of graphene, the composite shows a yield strength and elastic modulus ~177% and ~25% higher than that of unreinforced copper matrix, respectively, while retains ductility and electrical conductivity comparable to that of pure copper. The bioinspired nanolaminated architecture enhances the efficiencieMANUSCRIPTs of two-dimensional (2D) graphene in mechanical strengthening and electrical conducting by aligning graphene to maximize performance for required loading and carrier transporting conditions, and toughens the composites by crack deflection. Meanwhile, in-situ growth of graphene is beneficial for improving interfacial bonding and structural quality of graphene. The strategy sheds light on the development of composites with good combined structural and functional properties. ACCEPTED 2 ACCEPTED MANUSCRIPT 1. Introduction Analogous to that transforming crystal structure at atomic and molecular scale can lead to change in the properties of a compound, recently tailoring properties by architecture design that changes the spatial distribution of reinforcement in matrix at micro-/nano-scale without changing constituents has attracted intensive attention in the field of composites [1]. Natural biological materials are usually made up of only simple constituents, but show remarkable range of mechanical and functional properties, which can be attributed to multiscale transformation on their architectures [2-6]. Understanding the role that multilevel architectures play in controlling properties of natural materials may serve as inspirations for architecture design in composites. Usually, conventional metal matrix composites (MMCs) containing homogeneously distributed reinforcement exhibit higher strength but compromise ductility and toughness compared to the pure matrix. In nature, the most MANUSCRIPTtypical example that surmounts the conflict between strength and toughness by architecture design is probably the nacreous part of seashells [7]. Nacre is made up of about 95 vol % brittle mineral aragonite (a polymorph of calcium carbonate) and only a few percent of soft organic material, however, it exhibits phenomenal fracture strength and toughness properties thanks to a perfectly ordered “brick-and-mortar” architecture [8]. For example, its work of fracture is three orders of magnitude greater than that of a single crystal of its constituent mineral aragonite [9]. Therefore, mimicking the unique “brick-and-mortar” architecture in nacre might be a promising strategy for producing MMCs with optimum combinationACCEPTED of strength and ductility and toughness. Such bioinspired architecture could be built in MMCs by using high strength reinforcement with high aspect ratio as “brick” combined with ductile metal “mortar”. While “brick” of reinforcement is by no means easy to obtain, some emerging two-dimensional (2D) nanomaterials show great promise as ideal 3 ACCEPTED MANUSCRIPT candidates, such as graphene (Gr) [10,11], hexagonal boron nitride ( h-BN) [12-14] and MXenes (derivatives of layered ternary carbides and nitrides known as MAX phases) [15,16]. They not only have outstanding intrinsic properties, but also are geometrically compatible with lamella in the “brick-and-mortar” structure. Meanwhile, these 2D nanomaterials exhibit high in-plane rigidity while large out-of-plane flexibility, and thus their strengthening efficiencies in composites are strongly affected by the way the individual sheets are arranged. Therefore, in the “brick-and-mortar” structure, 2D nanomaterials are parallel arranged and their strengthening capability could be fully exerted when a load is applied along the direction of their maximum performance [17]. Among the aforementioned 2D nanomaterials, graphene is the most investigated emerging nano-reinforcement for composites. Up to now, most of the studies on Gr/metal composite emphasize the homogeneous dispersion of grapheneMANUSCRIPT and the suppression of its restacking, but the orientation of graphene is random and out of control, such as in the Gr/metal composites fabricated through ball-milling [18-22], molecular-level mixing [23,24], slurry blending [25,26] and electrodeposition [27]. The major difficulties for dispersing graphene in a metal matrix lie in graphene restacking, structural damage as well as poor interfacial bonding. Because of its 2D atomic layer structure, graphene exhibits high surface energy, high aspect ratio and strong Van der Waals interaction, and is prone to agglomerate during its mixing with metal [22,28]. Therefore, graphene is usually dispersed in metal matrix by using a ball-milling method. However, high energyACCEPTED during ball-milling will lead to structural damage of graphene [29] and some adverse reactions at interface [30]. Moreover, wettability of graphene with metal has to be improved to enhance interfacial bonding strength [31]. Beyond above difficulties, for fabricating Gr/metal composites with the “brick-and-mortar” structure, additional bigger challenge is 4 ACCEPTED MANUSCRIPT alignment of graphene in metal matrix, because graphene is flexible and has large aspect ratio. Recently, efforts have been made to fabricate metal matrix composites reinforced with aligned graphene (or reduced graphene oxide, rGO), demonstrating the advantage from the resulting nanolaminated structure in strengthening and toughening the composites, but these fabrication processes are relatively complicated and difficult to be scaled-up [32-34]. To fabricate bulk Gr/metal nanolaminated composites for large-scale applications, flake powder metallurgy has been established in our group in the past few years [35-39]. It is a bottom-up assembly process of composite flaky powders, i.e. nanoflake metal powders covered with rGO were used as building blocks to be orderly assembled together forming composites. This strategy has made a great success in strengthening and toughening lightweight
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