Cree White Paper: White LED and Remote Phosphor Comparison
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Compact Fluorescent Light Bulbs
Compact Fluorescent Light Bulbs What is a compact fluorescent lamp (CFL) bulb? A CFL bulb is a type of fluorescent bulb that screws into a standard light socket, such as a lamp or ceiling light fixture. CFLs use much less energy and last up to 10 times longer than standard light bulbs. What is in a compact fluorescent lamp (CFL) bulb? A CFL bulb is made of glass, a ceramic and metal base, a luminous powder called phosphor, and a small amount of mercury. How much mercury is contained in a CFL bulb? Manufacturers report that the amount of mercury contained in a CFL bulb is five milligrams, which is less than two ten-thousandths of an ounce. The mercury could be in the form of an invisible vapor or in a bead the size of the period at the end of this sentence. A mercury fever thermometer contains about 100 times more mercury than a CFL bulb. Is it harmful is it to be in the room where a CFL bulb has broken? The amount of mercury vapor that is released from one broken bulb is not enough to make anyone sick. However, it is best to avoid any exposure to mercury. We recommend that you ventilate the room air to the outdoors by opening a window or a door and leave the room for a few hours before cleaning up the broken bulb. How should I clean up a broken CFL bulb? It is not necessary to hire a professional to clean up the bulb. By following the directions below, you can safely clean up a broken CFL bulb. -
High Moisture Accelerated Mechanical Behavior Degradation of Phosphor/Silicone Composites Used in White Light-Emitting Diodes
Article High Moisture Accelerated Mechanical Behavior Degradation of Phosphor/Silicone Composites Used in White Light-Emitting Diodes Jiajie Fan 1,2,3,*, Zhen Wang 1,2, Xunwei Zhang 1, Zhentao Deng 4, Xuejun Fan 5 and Guoqi Zhang 3 1 College of Mechanical and Electrical Engineering, Hohai University, Changzhou 213022, China 2 State Key Lab of Solid State Lighting, Changzhou Institute of Technology Research for Solid State Lighting, Changzhou 213164, China 3 Department of Microelectronics, EEMCS Faculty, Delft University of Technology, 2628 Delft, The Netherlands 4 College of Chemistry and Environmental Engineering, Shenzhen University, Shenzhen 518061, China 5 Department of Mechanical Engineering, Lamar University, Beaumont, TX 77710, USA * Correspondence: [email protected] Received: 12 June 2019; Accepted: 21 July 2019; Published: 31 July 2019 Abstract: In a high-power white light emitting diode (LED) package, the phosphor/silicone composite is typically used for photometric and colorimetric conversions, ultimately producing the white light. However, the phosphor/silicone composite is always exposed under harsh environments with high temperature, high blue light irradiation and high moisture when the LED operates. Therefore, its reliability issue has become one of the critical bottlenecks to improve the lifetime of a high-power white LED package. As the curing process and mechanical behavior of phosphor/silicone composite essentially determine its reliability, this paper firstly uses an in situ viscosity monitoring approach combined with Differential Scanning Calorimetry (DSC) and Fourier Transform Infrared Spectroscopy (FTIR) analysis to explain the curing mechanism of a phosphor/silicone composite by taking the effects of temperature and phosphor mass fraction into consideration. -
Phosphor-Free Ingan White Light Emitting Diodes Using Flip-Chip Technology
Article Phosphor-Free InGaN White Light Emitting Diodes Using Flip-Chip Technology Ying-Chang Li 1, Liann-Be Chang 1,2,3,*, Hou-Jen Chen 1, Chia-Yi Yen 1, Ke-Wei Pan 1, Bohr-Ran Huang 4, Wen-Yu Kuo 4, Lee Chow 5, Dan Zhou 6 and Ewa Popko 7 1 Graduate Institute of Electro-Optical Engineering, Chang Gung University, Taoyuan 333, Taiwan; [email protected] (Y.-C.L.); [email protected] (H.-J.C.); [email protected] (C.-Y.Y.); [email protected] (K.-W.P.) 2 Department of Otolaryngology-Head and Neck Surgery, Chang Gung Memorial Hospital, Taoyuan 333, Taiwan 3 Department of Materials Engineering, Ming Chi University of Technology, New Taipei City 243, Taiwan 4 Graduate Institute of Electro-Optical Engineering, National Taiwan University of Science and Technology, Taipei 10607, Taiwan; [email protected] (B.-R.H.); [email protected] (W.-Y.K.) 5 Department of Physics, University of Central Florida, Orlando, FL 32816, USA; [email protected] 6 Department of Materials Science and Engineering, University of Central Florida, Orlando, FL 32816, USA; [email protected] 7 Institute of Physics, Wroclaw University of Technology, 50-370 Wroclaw, Poland; [email protected] * Correspondence: [email protected]; Tel.: +886-3-211-8800 Academic Editor: Durga Misra Received: 9 February 2017; Accepted: 17 April 2017; Published: 20 April 2017 Abstract: Monolithic phosphor-free two-color gallium nitride (GaN)-based white light emitting diodes (LED) have the potential to replace current phosphor-based GaN white LEDs due to their low cost and long life cycle. -
Scintillation Detectors for X-Rays
INSTITUTE OF PHYSICS PUBLISHING MEASUREMENT SCIENCE AND TECHNOLOGY Meas. Sci. Technol. 17 (2006) R37–R54 doi:10.1088/0957-0233/17/4/R01 REVIEW ARTICLE Scintillation detectors for x-rays Martin Nikl Institute of Physics, Academy of Sciences of the Czech Republic, Cukrovarnicka 10, 162 53 Prague, Czech Republic Received 23 March 2005 Published 10 February 2006 Online at stacks.iop.org/MST/17/R37 Abstract Recent research in the field of phosphor and scintillator materials and related detectors is reviewed. After a historical introduction the fundamental issues are explained regarding the interaction of x-ray radiation with a solid state. Crucial parameters and characteristics important for the performance of these materials in applications, including the employed measurement methods, are described. Extended description of the materials currently in use or under intense study is given. Scintillation detector configurations are further briefly overviewed and selected applications are mentioned in more detail to provide an illustration. Keywords: luminescence intensity, luminescence kinetics, light detection, x-ray detection, scintillators, phosphors, traps and material imperfections (Some figures in this article are in colour only in the electronic version) 1. Introduction development of phosphor and scintillator materials to be used in their exploitation. It was 110 years ago in November 1895 that Wilhelm Conrad It is to be noticed that for registration of x-ray the so- Roentgen noticed the glow of a barium platino-cyanide screen, called direct registration principle is widely used, in which the placed next to his operating discharge tube, and discovered new incoming radiation is directly converted into electrical current invisible and penetrating radiation [1], which was named x-ray in a semiconducting material. -
Garnet-Type Nanophosphors for White LED Lighting Alexandra Cantarano, Alain Ibanez, Geraldine Dantelle
Garnet-Type Nanophosphors for White LED Lighting Alexandra Cantarano, Alain Ibanez, Geraldine Dantelle To cite this version: Alexandra Cantarano, Alain Ibanez, Geraldine Dantelle. Garnet-Type Nanophosphors for White LED Lighting. Frontiers in Materials, Frontiers Media, 2020, 7, pp.210. 10.3389/fmats.2020.00210. hal- 02986834 HAL Id: hal-02986834 https://hal.archives-ouvertes.fr/hal-02986834 Submitted on 3 Nov 2020 HAL is a multi-disciplinary open access L’archive ouverte pluridisciplinaire HAL, est archive for the deposit and dissemination of sci- destinée au dépôt et à la diffusion de documents entific research documents, whether they are pub- scientifiques de niveau recherche, publiés ou non, lished or not. The documents may come from émanant des établissements d’enseignement et de teaching and research institutions in France or recherche français ou étrangers, des laboratoires abroad, or from public or private research centers. publics ou privés. 1 Garnet-type nanophosphors for white LED lighting 2 Alexandra Cantarano1, Alain Ibanez1, Géraldine Dantelle1,* 3 1Univ. Grenoble Alpes, CNRS, Grenoble INP, Institut Néel, 38000 Grenoble, France 4 * Correspondence: 5 Corresponding Author 6 [email protected] 7 Keywords: nanocrystals, YAG:Ce, garnet, photoluminescence, LED lighting 8 9 Abstract 10 In this article we present a short review of the main wet chemical methods developed for the preparation 3+ 11 of Ce -doped Y3Al5O12 (YAG:Ce) nanocrystals for their use as nanophosphors in LED lighting 12 technology : combustion, co-precipitation, sol-gel, modified-Péchini and solvothermal routes. We 13 highlight the key synthesis steps and discuss them in the view of the size, crystal quality and 14 agglomeration state of the obtained nanocrystals. -
Design of Phosphor White Light Systems for High-Power Applications † † Kristopher T
Letter pubs.acs.org/journal/apchd5 Design of Phosphor White Light Systems for High-Power Applications † † Kristopher T. Bicanic, Xiyan Li, Randy P. Sabatini, Nadir Hossain, Cai-Feng Wang, Fengjia Fan, Hongyan Liang, Sjoerd Hoogland, and Edward H. Sargent* Department of Electrical and Computer Engineering, University of Toronto, 10 King’s College Road, Toronto, Ontario M5S 3G4, Canada *S Supporting Information ABSTRACT: We developed a strategy that transforms phosphor down-converting white light sources from low- power systems into efficient high-power ones. To incorporate multiple phosphors, we generalized and extended a phosphor layer model, which we term CCAMP (color correction analysis for multiple phosphors). CCAMP describes both the scattering and saturation of phosphor materials and allows modeling of different layered structures. We employed a phosphor mixture 4+ comprising YAG:Ce and K2TiF6:Mn to illustrate the effectiveness of the model. YAG:Ce’s high density and small 4+ particle size produce a large amount of scattering, while the long (4.8 ms) photoluminescent lifetime of K2TiF6:Mn results in saturation at high pump power. By incorporating experimental photophysical results from the phosphors, we modeled our system and chose the design suitable for high-power applications. We report the first solid-state phosphor system that creates warm white light emission at powers up to 5 kW/cm2. Furthermore, at this high power, the system’s emission achieves the digital cinema initiative (DCI) requirements with a luminescence efficacy improvement -
Compact Fluorescent Lighting in America: Lessons Learned on the Way to Market
Compact Fluorescent Lighting in America: Lessons Learned on the Way to Market Prepared by Pacific Northwest National Laboratory for U.S. Department of Energy Office of Energy Efficiency and Renewable Energy Building Technologies Program June 2006 PNNL-15730 Compact Fluorescent Lighting in America: Lessons Learned on the Way to Market LJ Sandahl TL Gilbride MR Ledbetter HE Steward C Calwell(a) June, 2006 Prepared for The U.S. Department of Energy Under Contract DE-AC05-76RLO 1830 Pacific Northwest National Laboratory Richland, Washington 99352 _________________ (a)Ecos Consulting DISCLAIMER This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor Battelle Memorial Institute, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference herein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise does not necessarily constitute or imply its endorsement, recommendation, or favoring by the United States Government or any agency thereof, or Battelle Memorial Institute. The views and opinions of authors expressed herein do not necessarily state or reflect those of the United States Government or any agency thereof. PACIFIC NORTHWEST NATIONAL LABORATORY operated by BATTELLE for the UNITED STATES DEPARTMENT OF ENERGY under Contract DE-AC05-76RL01830 Printed in the United States of America Available to DOE and DOE contractors from the Office of Scientific and Technical Information, P.O. -
The Combustion of Phosphorus
Scholars' Mine Professional Degree Theses Student Theses and Dissertations 1944 The combustion of phosphorus Erwin Charles Hoeman Follow this and additional works at: https://scholarsmine.mst.edu/professional_theses Part of the Chemical Engineering Commons Department: Recommended Citation Hoeman, Erwin Charles, "The combustion of phosphorus" (1944). Professional Degree Theses. 284. https://scholarsmine.mst.edu/professional_theses/284 This Thesis - Open Access is brought to you for free and open access by Scholars' Mine. It has been accepted for inclusion in Professional Degree Theses by an authorized administrator of Scholars' Mine. This work is protected by U. S. Copyright Law. Unauthorized use including reproduction for redistribution requires the permission of the copyright holder. For more information, please contact [email protected]. THE COMBUSTION OF PHOSPHORUS BY ERWIN CHA.RLES HODWt A 'l'HESIS subnitted to the faculty of the SCHOOL OF MINES AND METALLURGY OF THE UNIVERSITY OF MISSOURI 1D partial. fulfillment of the work required tor the Degre. of CBDlICAL gGIIllma Rolla~ II1s80url 1944 Approved by: It;-\/ '~I Cha1rmaD,De.partmant of. Chaistry ind Chea1cal IDg1Deer1ng. i ACKNOWLEDGMJ!JiT The author gratefu1lr acknowledges the experience gained in the production and utilization of phosphorus, through his employ ment in the Department of Chemical Engineering of the United States Tennessee Valley Authority. 'SpecificallY', he acknowledges the supervision of work and inspiration gained through his association with Dr. RaY'Dlond L. Copson, Chief of the Research and ,Development Division; Dr. GradY' Tarbutton, Assistant to the Chief; and Mr. John H. Walthall,. Head of the Developllellt Section. Particular thanks for guidanoe in the selection of the general plaD for this paper are due to Mr. -
The Elements.Pdf
A Periodic Table of the Elements at Los Alamos National Laboratory Los Alamos National Laboratory's Chemistry Division Presents Periodic Table of the Elements A Resource for Elementary, Middle School, and High School Students Click an element for more information: Group** Period 1 18 IA VIIIA 1A 8A 1 2 13 14 15 16 17 2 1 H IIA IIIA IVA VA VIAVIIA He 1.008 2A 3A 4A 5A 6A 7A 4.003 3 4 5 6 7 8 9 10 2 Li Be B C N O F Ne 6.941 9.012 10.81 12.01 14.01 16.00 19.00 20.18 11 12 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 3 Na Mg IIIB IVB VB VIB VIIB ------- VIII IB IIB Al Si P S Cl Ar 22.99 24.31 3B 4B 5B 6B 7B ------- 1B 2B 26.98 28.09 30.97 32.07 35.45 39.95 ------- 8 ------- 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 4 K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr 39.10 40.08 44.96 47.88 50.94 52.00 54.94 55.85 58.47 58.69 63.55 65.39 69.72 72.59 74.92 78.96 79.90 83.80 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 5 Rb Sr Y Zr NbMo Tc Ru Rh PdAgCd In Sn Sb Te I Xe 85.47 87.62 88.91 91.22 92.91 95.94 (98) 101.1 102.9 106.4 107.9 112.4 114.8 118.7 121.8 127.6 126.9 131.3 55 56 57 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 6 Cs Ba La* Hf Ta W Re Os Ir Pt AuHg Tl Pb Bi Po At Rn 132.9 137.3 138.9 178.5 180.9 183.9 186.2 190.2 190.2 195.1 197.0 200.5 204.4 207.2 209.0 (210) (210) (222) 87 88 89 104 105 106 107 108 109 110 111 112 114 116 118 7 Fr Ra Ac~RfDb Sg Bh Hs Mt --- --- --- --- --- --- (223) (226) (227) (257) (260) (263) (262) (265) (266) () () () () () () http://pearl1.lanl.gov/periodic/ (1 of 3) [5/17/2001 4:06:20 PM] A Periodic Table of the Elements at Los Alamos National Laboratory 58 59 60 61 62 63 64 65 66 67 68 69 70 71 Lanthanide Series* Ce Pr NdPmSm Eu Gd TbDyHo Er TmYbLu 140.1 140.9 144.2 (147) 150.4 152.0 157.3 158.9 162.5 164.9 167.3 168.9 173.0 175.0 90 91 92 93 94 95 96 97 98 99 100 101 102 103 Actinide Series~ Th Pa U Np Pu AmCmBk Cf Es FmMdNo Lr 232.0 (231) (238) (237) (242) (243) (247) (247) (249) (254) (253) (256) (254) (257) ** Groups are noted by 3 notation conventions. -
Zinc Silicate Phosphor and Electron Excited Fluorescent Display Device Using the Phosphor
Patentamt JEuropàischesEuropean Patent Office (jj) Publication number: Q "J 23 947 Office européen des brevets Q *] ® EUROPEAN PATENT SPECIFICATION (§) Date of publication of patent spécification: 21.10.87 (Jj) |nt. ci.4: C 09 K 11/54, H 01 J 29/20 (§) Application number: 84103664.3 ® Date offiling: 03.04.84 ® Zinc silicate phosphor and électron excited fluorescent display device using the phosphor. (§) Priority: 04.04.83 JP 58987/83 ® Proprietor: KASEI OPTONIX, LTD. 27.06.83 JP 115396/83 2-7-18 Hamamatsu-cho Minato-ku Tokyo (JP) (§) Date of publication of application: 07.11.84 Bulletin 84/45 ® Inventor: Yaguchi, Masachika Kasei Optonix (§) Publication of the grant of the patent: Ltd. 21.10.87 Bulletin 87/43 Odawara Kojyo No. 1060, Naruta Odawara-shi Kanagawa-ken (JP) ($4) Designated Contracting States: Inventor: Mikami, Tomoki Kasei Optonix Ltd. DEGBITNL Odawara Kojyo No. 1060, Naruta Odawara-shi Kanagawa-ken (JP) (58) Références cited: Inventor: Hase, Takashi Kasei Optonix Ltd. US-A-4315190 Odawara Kojyo No. 1060, Naruta Odawara-shi Kanagawa-ken (JP) PATENT ABSTRACTS OF JAPAN, unexamined applications, C f ield, vol. 7, no. 268, November 30, 1983, THE PATENT OFFICE JAPANESE (74) Représentative: Wâchtershâuser, Gunter, Dr. GOVERNMENT, page 161 C 197 Tal29 PATENT ABSTRACTS OF JAPAN, unexamined D-8000 Mùnchen 2 (DE) applications, C field, vol. 7, no. 122, May 26, 1983, THE PATENT OFFICE JAPANESE GOVERNMENT, page 74 C 168 PATENT ABSTRACTS OF JAPAN, unexamined applications, C field, vol. 7, no. 225, October 6, 1983, THE PATENT OFFICE JAPANESE GOVERNMENT, page 69 C 189 Note: Within nine months from the publication of the mention of the grant of the European patent, any person may give notice to the European Patent Office of opposition to the European patent granted. -
Synthesis and Characterization of Yttrium Aluminium Garnet (YAG
Processing and Application of Ceramics 1 [1–2] (2007) 69–74 Synthesis and characterization of yttrium aluminium garnet (YAG) powders Magdalena Zarzecka-Napierala*, Krzystof Haberko AGH-University of Science and Technology, Faculty of Materials Science and Ceramics, Al. Mickiewicza 30, 30–059 Kraków, Poland Received 17 September 2007; received in revised form 20 November 2007; accepted 24 November 2007 Abstract In this paper synthesis and characterization of YAG powders, prepared by a process based on complexing properties of citric acid, was reported. Infl uence of citric acid estrifi cation induced by 2-propanol or ethylene glycol on the system homogeneity was investigated. These reagents were introduced to aqueous solution of yt- trium and aluminium nitrates. A variety of powders from Al2O3-Y2O3 system with different phase composition were obtained by altering the citrate to nitrate ratio. Evolution of the powders phase composition vs. tempera- ture was investigated using DTA/TG, XRD, and FT-IR methods. The most interesting results were observed in case of the citric acid – propanol – relative nitrates system. The mole ratio of these reagents equal to 1: 2.5: 2.5 (nitrates (Al,Y): citric acid: 2-propanol) allowed to synthesize pure YAG phase powders at temperature as low as 950°C. Keywords: YAG, citric acid, citrate gel method I. Introduction homogeneous YAG or Nd: YAG powder have been ad- opted. YAG powders have been prepared traditionally In the Y2O3 – Al2O3 system, apart from the end-mem- ber phases, three compounds stable at ambient pressure by a solid state reaction [6] from the corresponding ox- ides, which requires prolonged mechanical mixing and are known: Y3Al5O12 (YAG), YAlO3 (YAP) and Y2Al4O9 (YAM), having cubic garnet, orthorombic or hexagonal extensive heat treatment at high temperature to elimi- perovskite and monoclinic symmetry structure, respec- nate intermediate phases. -
Process for Producing a Phosphor
Europa,schesP_ MM M II M MM IN M I M M MM II J European Patent Office _ _ _ © Publication number: 0 372 560 B1 Office_„. europeen des brevets EUROPEAN PATENT SPECIFICATION © Date of publication of patent specification: 08.03.95 © Int. CI.6: C09K 11/02 © Application number: 89122598.9 @ Date of filing: 07.12.89 © Process for producing a phosphor. ® Priority: 08.12.88 JP 310648/88 © Proprietor: KASEI OPTONIX, LTD. 12-7, Shibadaimon 2-chome @ Date of publication of application: Mlnato-ku 13.06.90 Bulletin 90/24 Tokyo 105 (JP) © Publication of the grant of the patent: @ Inventor: Tono, Hideo 08.03.95 Bulletin 95/10 Kasel Optonlx Ltd., 1060 Naruda, Odawara-shl © Designated Contracting States: Kanagawa-ken (JP) DE GB IT NL Inventor: Mlyazakl, Tomohlro Kasel Optonlx Ltd., 1060 Naruda, © References cited: Odawara-shl GB-A- 2 034 910 Kanagawa-ken (JP) US-A- 4 287 257 PATENT ABSTRACTS OF JAPAN, AP-No. © Representative: Wachtershauser, Gunter, Prof. JP860312537, Tokyo, JP; & JP-A-63 284 290 Dr. Patentanwalt Tal 29 D-80331 Munchen (DE) 00 o CO m CM oo Note: Within nine months from the publication of the mention of the grant of the European patent, any person ® may give notice to the European Patent Office of opposition to the European patent granted. Notice of opposition CL shall be filed in a written reasoned statement. It shall not be deemed to have been filed until the opposition fee LU has been paid (Art. 99(1) European patent convention). Rank Xerox (UK) Business Services (3.