Ytterby: Where It All Began (For Tantalum, at Least, See Page 4)
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Peaceful Berkelium
in your element Peaceful berkelium The first new element produced after the Second World War has led a rather peaceful life since entering the period table — until it became the target of those producing superheavy elements, as Andreas Trabesinger describes. f nomenclature were transitive, element 97 with the finding that in Bk(iii) compounds would be named after an Irish bishop spin–orbit coupling leads to a mixing of the Iwhose philosophical belief was that first excited state and the ground state. This material things do not exist. But between gives rise to unexpected electronic properties the immaterialist George Berkeley and the not present in analogous lanthanide element berkelium stands, of course, the structures containing terbium. Even more fine Californian city of Berkeley (pictured), recently5, a combined experimental and where the element was first produced in computational study revealed that berkelium December 1949. The city became the eponym can have stabilized +iii and +iV oxidation of element 97 “in a manner similar to that states also under mild aqueous conditions, used in naming its chemical homologue indicating a path to separating it from other terbium […] whose name was derived from lanthanides and actinides. the town of Ytterby, Sweden, where the rare The main use of berkelium, however — earth minerals were first found”1. arguably one that wouldn’t have met with A great honour for the city? The mayor Bishop Berkeley’s approval — remains a of Berkeley at the time reportedly displayed PHOTO STOCK / ALAMY AF ARCHIVE distinctly material one: as the target for “a complete lack of interest when he was the synthesis of other transuranium and called with the glad tidings”2. -
Columbium and Tantalum
Rediscovery of the Elements Columbium and Tantalum Figure 2. Hatchett’s coach-making business was located at 121 Long Acre III (N51° 30.76 W00° 07.52). Charles spent his youth in Belle Vue in Chelsea (owned by his father) and then repurchased the home for his final James L. Marshall, Beta Eta 1971, and years (91-92 Virginia R. Marshall, Beta Eta 2003, Cheyne Walk; N51° 28.92 W00° 10.45). Department of Chemistry, University of Charles Hatchett’s North Texas, Denton, TX 76203-5070, first home after his marriage was at the Lower Mall in Hammersmith at an address today unknown; this [email protected] area was bombed in World War II and is now occupied by Furnival Gardens (N51° 29.42 W00° 13.99); this is where he discovered columbium. Also in Hammersmith may be found today at Hop Poles Inn (17-19 Charles Hatchett (1765–1847), a prosperous King Street, N51° 29.56 W00° 13.55), a favorite haunt of Charles Hatchett. In mid-life his home was London coach-builder and avocational Mount Clare (1808–1819) at Minstead Gardens, Roehampton (N51° 27.11 W00° 15.04). chemist, discovered columbium (niobium) in 1801. The following year, Anders Gufstaf Charles Hatchett 1 (Figure 2) was born at his merit his election to the Royal Society. His work Ekeberg (1767–1813), professor of chemistry at father’s carriage manufactory on Long Acre with bones and shells3b first determined the dif- the University of Uppsala, Sweden, discovered (Figure 3). Charles, being the only son, had ferent compositions of bones and teeth (mostly tantalum. -
Jöns Jacob Berzelius 1 Jöns Jacob Berzelius
Jöns Jacob Berzelius 1 Jöns Jacob Berzelius J. J. Berzelius Jöns Jacob Berzelius (1779–1848) Born 20 August 1779 Väversunda, Östergötland, Sweden Died 7 August 1848 (aged 68) Stockholm, Sweden Nationality Sweden Fields Chemistry Institutions Karolinska Institute Alma mater Uppsala University Doctoral advisor Johann Afzelius Doctoral students James Finlay Weir Johnston Heinrich Rose Known for Atomic weights Chemical notation Silicon Selenium Thorium Cerium Notable awards Copley medal Jöns Jacob Berzelius (Swedish: [jœns ˌjɑːkɔb bæɹˈseːliɵs]; 20 August 1779 – 7 August 1848) was a Swedish chemist. He worked out the modern technique of chemical formula notation, and is together with John Dalton, Antoine Lavoisier, and Robert Boyle considered a father of modern chemistry.[1] He began his career as a physician but his researches in physical chemistry were of lasting significance in the development of the subject. He achieved much in later life as secretary of the Swedish Academy. He is known in Sweden as the Father of Swedish Chemistry. Berzelius Day is celebrated on 20 August in honour of him[2]. Biography Born at Väversunda in Östergötland in Sweden, Berzelius lost both his parents at an early age. Relatives in Linköping took care of him, and there he attended the school today known as Katedralskolan. He then enrolled at Uppsala University where he learned the profession of medical doctor from 1796 to 1801; Anders Gustaf Ekeberg, the discoverer of tantalum, taught him chemistry. He worked as an apprentice in a pharmacy and with a physician in the Medevi mineral springs. During this time he conducted analysis of the spring water. For his medical studies he examined the influence of galvanic current on several diseases and graduated as M.D. -
The Elements.Pdf
A Periodic Table of the Elements at Los Alamos National Laboratory Los Alamos National Laboratory's Chemistry Division Presents Periodic Table of the Elements A Resource for Elementary, Middle School, and High School Students Click an element for more information: Group** Period 1 18 IA VIIIA 1A 8A 1 2 13 14 15 16 17 2 1 H IIA IIIA IVA VA VIAVIIA He 1.008 2A 3A 4A 5A 6A 7A 4.003 3 4 5 6 7 8 9 10 2 Li Be B C N O F Ne 6.941 9.012 10.81 12.01 14.01 16.00 19.00 20.18 11 12 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 3 Na Mg IIIB IVB VB VIB VIIB ------- VIII IB IIB Al Si P S Cl Ar 22.99 24.31 3B 4B 5B 6B 7B ------- 1B 2B 26.98 28.09 30.97 32.07 35.45 39.95 ------- 8 ------- 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 4 K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr 39.10 40.08 44.96 47.88 50.94 52.00 54.94 55.85 58.47 58.69 63.55 65.39 69.72 72.59 74.92 78.96 79.90 83.80 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 5 Rb Sr Y Zr NbMo Tc Ru Rh PdAgCd In Sn Sb Te I Xe 85.47 87.62 88.91 91.22 92.91 95.94 (98) 101.1 102.9 106.4 107.9 112.4 114.8 118.7 121.8 127.6 126.9 131.3 55 56 57 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 6 Cs Ba La* Hf Ta W Re Os Ir Pt AuHg Tl Pb Bi Po At Rn 132.9 137.3 138.9 178.5 180.9 183.9 186.2 190.2 190.2 195.1 197.0 200.5 204.4 207.2 209.0 (210) (210) (222) 87 88 89 104 105 106 107 108 109 110 111 112 114 116 118 7 Fr Ra Ac~RfDb Sg Bh Hs Mt --- --- --- --- --- --- (223) (226) (227) (257) (260) (263) (262) (265) (266) () () () () () () http://pearl1.lanl.gov/periodic/ (1 of 3) [5/17/2001 4:06:20 PM] A Periodic Table of the Elements at Los Alamos National Laboratory 58 59 60 61 62 63 64 65 66 67 68 69 70 71 Lanthanide Series* Ce Pr NdPmSm Eu Gd TbDyHo Er TmYbLu 140.1 140.9 144.2 (147) 150.4 152.0 157.3 158.9 162.5 164.9 167.3 168.9 173.0 175.0 90 91 92 93 94 95 96 97 98 99 100 101 102 103 Actinide Series~ Th Pa U Np Pu AmCmBk Cf Es FmMdNo Lr 232.0 (231) (238) (237) (242) (243) (247) (247) (249) (254) (253) (256) (254) (257) ** Groups are noted by 3 notation conventions. -
From Bedrock to Porcelain a Study Regarding The
Bachelor Thesis Degree Project in Geology 15 hp From Bedrock to Porcelain A study regarding the history of porcelain, Ytterby mine and the discovery of yttrium in Sweden Timmy Kärrström Stockholm 2017 Department of Geological Sciences Stockholm University SE-106 91 Stockholm Sweden Abstract Porcelain is a translucent vitreous material that consists of clay (kaolin), feldspar and quartz which has been mixed and heated together to cause a metamorphic reaction. In Sweden, the Porcelain industry was established in 1726 at Rörstrands castle in Stockholm and is today one of the oldest industries in Europe to produce porcelain. Around the 1790’s Rörstrand got its feldspars and quartz from the Ytterby mine that was located at Resarö in Stockholm’s archipelago making the raw material somewhat easy to access. Rörstrand owned the mine in the 1850’s to 1926. During the time Ytterby mine was active, an amateur geologist by the name of Carl Axel Arrhenius, discovered an unusual black mineral in the quarry ore in 1787 which later led to the discovery of 8 new rare earth elements (REE) with the help of several Swedish chemists throughout time. These elements are Yttrium, Ytterbium, Gadolinium, Terbium, Thulium, Erbium, Holmium and scandium. This study will focus on the Swedish porcelain industry and how it has evolved throughout history and Rörstrand’s role in the discovery of yttrium. PAGE 1 Contents Abstract ........................................................................................................................................... 1 -
Flora Malesiana [Ser
MALAYSIAN PLANT COLLECTORS & COLLECTIONS SUPPLEMENT I BY M. J, VAN STEENIS'KRUSEMAN LIBRARY :;^! U 1968 NEW YORK BOTANICAL GARDEN MALAYSIAN PLANT COLLECTORS AND COLLECTIONS SUPPLEMENT I BY M. J. VAN STEENIS-KRUSEMAN ^S^J V, 5 GENERAL PART : : CHAPTER I LIST OF WORKS PRINCIPALLY CONTAINING ILLUSTRATIONS OF MALAYSIAN PLANTS, AND OF COLLECTIONS OF DRAWINGS AND PHOTOGRAPHS Cyclopaedia p. xxx-xxxiii add shire, Scotland, whose great great uncle was Sir Stamford. A mimeographed report on the collection is 1. Illustrated works. written by E. J. H. Corner, Oct. 1957, giving an Henderson, M. R., Malayan Wild Flowers. 1. alphabetically arranged list. Dicotyledons (Mal.Nat.J. 4, 1949, p. 1-181; ibid. Raffles, Sir St., Sketches of Javanese Scenery 6, 1950, p. 182-399; ibid. 1952, p. 400^72, fig. made for Sir Stamford in about 1814-15. Now 1-424); 2. Monocotyledons. Kuala Lumpur (1954) in the collections of Mrs Drake, see above. p. 1-357, fig. 1-201. A list of the subjects appended to Corner's Line-drawings of selected herbaceous plants report. from Malaya. Roxburgh, W., had over 2500 splendidly coloured drawings made, of which a set is at Calcutta and 2. Collections of non-published drawings and photo- another one at Kew. The latter is numbered and graphs. is valuable for identification of species described Raffles, Sir St., 68 Water-colour paintings of by Roxburgh, specially if the types are not local- Flowering Plants from Sumatra. By unknown ized. The Kew set is carefully listed by J. R. Sealy, painter, dated March 1824; now in the collections The Roxburgh Flora Indica Drawings at Kew (Kew of Mrs Drake, of Inshriach, Aviemore, Inverness- Bull. -
The Rare Earths I
The Mountain Pass rare earth ore body in Southern California, 86 km (54 mi) south-southwest of LasLas Vegas,Vegas, Nevada,Nevada, isis oneone ofof thethe largest,largest, richest,richest, andand mostmost readilyreadily mineablemineable rarerare earthearth depositsdeposits inin thethe worldworld (N35°(N35° 28.7428.74 W115°W115° 31.98).31.98). ItsIts provenproven andand probableprobable reservesreserves exceedexceed 1.31.3 millionmillion metricmetric tonstons ofof rarerare earthearth oxideoxide (REO)(REO) equivalentequivalent containedcontained inin 18.418.4 millionmillion metricmetric tonstons ofof oreore withwith ~8%~8% ore grade and a 5% cut-off grade. ItIt containscontains allall ofof thethe naturallynaturally occurringoccurring rarerare earthearth elements.elements. Photo,Photo, courtesycourtesy ofof Molycorp,Molycorp, Inc.Inc. Rediscovery ...pg 40 2016 Solicitation...pg 52 2015 Awards . ..pg 54 Collegiate News ...pg 57 FALL 2015 THE Rediscovering The Rare Earths A new series starts on page 40. Redis co very of the Elements The Rare Earth s–The Beginnings I I I James L. Marshall, Beta Eta 1971 , and Virginia R. Marshall, Beta Eta 2003 , Department of Chemistry, University of North Texas, Denton, TX 76203-5070, [email protected] 1 Rare earths —introduction. The rare earths Figure 1. The “rare earths” are defined by IUPAC as the 15 lanthanides (green) and the upper two elements include the 17 chemically similar elements of the Group III family (yellow). These elements have similar chemical properties and all can exhibit the +3 occupying the f-block of the Periodic Table as oxidation state by the loss of the highest three electrons (two s electrons and either a d or an f electron, well as the Group III chemical family (Figure 1). -
TIMELINE the Discovery of Elements
TIMELINEThe Discovery of Elements The elements carbon, sulfur, iron, tin, lead, copper, mercury, silver, and Early gold are known to humans. History Pre-a.d. 1600: The elements arsenic, antimony, bismuth, and zinc are known to humans. 1669 German physician Hennig Brand discovers phosphorous. 1735 Swedish chemist Georg Brandt discovers cobalt. c1748 Spanish military leader Don Antonio de Ulloa discovers platinum. 1751 Swedish mineralogist Axel Fredrik Cronstedt discovers nickel. 1766 English chemist and physicist Henry Cavendish discovers hydrogen. 1772 Scottish physician and chemist Daniel Rutherford discovers nitrogen. 1774 Swedish chemist Carl Wilhelm Scheele discovers chlorine. 1774 Swedish mineralogist Johann Gottlieb Gahn discovers manganese. 1774 English chemis Joseph Priestley and Swedish chemist Carl Wilhelm Scheele discover oxygen. 1781 Swedish chemist Peter Jacob Hjelm discovers molybdenum. c1782 Austrian mineralogist Baron Franz Joseph Muller von Reichenstein discovers tellurium. 1783 Spanish scientists Don Fausto D’Elhuyard and Don Juan Jose D’Elhuyard, and Swedish chemist Carl Wilhelm Scheele discover tungsten. 1789 German chemist Martin Klaproth discovers uranium. 1789 German chemist Martin Klaproth discovers zirconium. 1791 English clergyman William Gregor discovers titanium. 1794 Finnish chemist Johan Gadolin discovers yttrium. 1797 French chemist Louis-Nicolas Vauquelin discovers chromium. 1798 French chemist Louis-Nicolas Vauquelin discovers beryllium. 1801 English chemist Charles Hatchett discovers niobium. 1801 Spanish-Mexican metallurgist Andres Manuel del Rio discovers vanadium. 1802 Swedish chemist and mineralogist Anders Gustaf Ekeberg discovers tantalum. 1803 English chemist and physicist William Hyde Wollaston discovers palladium. 1804 Klaproth discover black rock of Bastnas, Sweden, which led to the discovery of several elements. 1804 English chemist and physicist William Hyde Wollaston discovers rhodium. -
The Heaviest Elements in the Universe Cody Folden January 31, 2009 Theytheythey Keepkeepkeep Findingfindingfinding Newnewnew Elements.Elements.Elements
The Heaviest Elements in the Universe Cody Folden January 31, 2009 TheyTheyThey keepkeepkeep findingfindingfinding newnewnew elements.elements.elements. WhereWhereWhere areareare they?they?they? y Ytterby, Sweden is the namesake of four elements: ytterbium, yttrium, erbium, and terbium. TheTheThe Elements:Elements:Elements: 200920092009 y There are 91 naturally occurring elements (but it depends on how you count them). y The heaviest element that occurs in large quantity is uranium (atomic number 92). You can mine it like gold. y Technetium (atomic number 43) does not occur naturally. y Promethium (atomic number 61) does not occur naturally. y Plutonium-244 (244Pu) has been discovered in nature! (This isotope has a half-life of “only” 80 million years). y The artificial elements bring the total to 117. 244244244PuPuPu ininin NatureNatureNature (1971)(1971)(1971) y Sample: 1.0 × 10-18 g 244Pu per gram of sample. y Crust: 5 × 10-25 g 244Pu per gram of Earth. y There is an extremely weak “rain” of 244Pu that falls on the Earth, creating an equilibrium that balances its radioactive decay. TheTheThe PeriodicPeriodicPeriodic TableTableTable 200920092009 The heaviest elements are all produced artificially! WhatWhatWhat areareare allallall thesethesethese newnewnew elementselementselements goodgoodgood for?for?for? y The search for the heaviest elements answers questions like: y What is the heaviest element that can be formed? y What mechanism is involved in their production? y Does the periodicity of the elements continue for very high atomic numbers? y What are their chemical properties? y We also train future nuclear scientists. HowHowHow areareare newnewnew elementselementselements created?created?created? y We build up heavy elements by fusing two lighter elements together. -
Bachelor Thesis
Bachelor Thesis Degree Project in Geology 30 hp The Ytterby mine - A historical review and an evaluation of its suggested spatial coupling to multiple sclerosis (MS) Susanne Sjöberg Stockholm 2012 Department of Geological Sciences Stockholm University SE-106 91 Stockholm ABSTRACT The Ytterby mine is located on Island in the Stockholm archipelago. Mainly feldspars but also quartz were historically quarried in the mine, which is also the place of discovery of seven rare earth elements (REE). During the cold war era, the mine shaft was used as a diesel and jet fuel deposit for the Swedish Armed Forces. Recently, a spatial coupling between multiple sclerosis (MS), a chronic neurodegenerative disease in the central nervous system, prevalence and the quarry has been suggested. Previous studies show that adverse neurological health effects are associated with oral intake of REEs and there is support for a coupling between ionizing radiation and MS. The extent and character of health effects as a result of exposure to petroleum products are still debated. However, a substantial number of scientific reports support a coupling between neurodegenerative health effects and toxic constituents of jet fuels such as benzene, toluene, and n-hexane. My data show that a possible overrepresentation of MS patients within the Ytterby postal code area could be an indication of a spatial coupling between the mine and MS. Such a possible coupling could be associated with the REEs present in the local rocks, with the previous storage of diesel or jet fuel MC-77 in the mine and/or with zones of high natural radioactivity in the area. -
Mats Rehnström Rare Books
MATS REHNSTRÖM RARE BOOKS !is is the complete list of all books we are bringing to the 2016 Olympia Book Fair. !ursday to Saturday, 26–28 May. Stand E04. Containing a total of 170 catalogued items, with prices in GBP.* *Please note that we cannot send invoices in GBP. Invoices will be sent in SEK only. 1. (ANGERSTEIN, REINHOLD) Anmärkningar wid italienska byggnads sättet, til förekommande af eldswådor [Observations on the Italian method of constructing buildings, for the prevention of "res]. Stockholm, Kongl. tryckeriet, 1759. 4:o. Engraved title,(4),52 pp. & 3 folded engraved plates. Contemporary half calf, rather worn, with raised bands and later light brown label. Sprinkled edges. Rear joint cracked at top, publishing year stamped at bottom of spine in later years. Paper on covers heavily worn. Foxing, ink stains and spotting throughout. Signature and bookplate. !e nice plates are engraved by Carl Bergquist, the title-page from an original by Olof Årre. !e latter depicts a "re in the district of Södermalm in Stockholm. !e third plate shows St. Peter’s Basilica and parts of the Vatican in Rome. !e work was published in connection with several devastating "res in Stockholm. Reinhold Angerstein (1718-60) was active at the Department of Mining and made extensive travels abroad, where he visited Italy, among other places. During his travels he made comprehensive economic and technical notes, on which this work is based - the only one printed in the author’s lifetime. £420 2. Apicii coelii de opsoniis et condimentis, sive arte coquinaria, libri decem. Cum annotationibus Martini Lister, è medicis domesticis serenissimæ majestatis reginæ Annæ, et notis selectioribus, variisque lectionibus integris, Humelbergii, Barthii, Reinesii, A. -
Transactinium Isotope Nuclear Data (Tnd)
Reviewa PapeB5 , rMb Status of Transactinium Isotope Evaluated Neutro Energne Datth n yai Range 10"3 eV to 15 MeV S. Yiftah, Y. Gur and M. Caner Department of Nuclear Engineering Technion-Israel Institut Technologf eo y Haifa, Israel and Israel Atomic Energy Commission Soreq Nuclear Research Centre Yavne, Israel Abstract Large amounts of transactinium elements will be produced in the next 2S years in thermal power reactors, fast breeders, test reactors, special purpose reactors, thermonuclear explosions and improved heavy-ion accelerators e ablb o evaluateo t e T . , predict, compute and judge the effects and uses of these elements, the nuclear commu- nity needs fully evaluated nuclea re use b dats nuclea a do t a r input to all computations and evaluations. The sixteen transactinium ele- ments and two hundred isotopes known to-date are divided into three groups eighd an , t main application area e mentionear s d from which needs can be derived for measurements and evaluations. Existing evaluations are tabulated and analysed, and following a WRENDA minus CINDA descriptive equation, nine main conclusion recommendationd an s s are derived, amongst which a "world transactinium nuclear data evaluation program" and other specific items for IAEA future actions in this field. 1. INTRODUCTION Large amounts somn ,i e cases tonhundredd an s f kilogramso s f o , transactinium elements will be produced, whether we like it or not, in 165 the nex year5 t2 therman si l power reactors, fast power reactors, test reactors and special-purpose reactors. These elements will affect the behavior and operation of the reactors, the cost of the power produced, the content and disposal of the radioactive waste, Some of these elements will be used in space missions, cardiac pacemakers, artificial hearts, various industries, and remote unattended sources of power.