Eastern Mississippi Sound
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~-T-85-001 C2 V 0<'~" SEDIMENTATION,DISPERSALAND PARTITIONING LQAN CO~ OF TRACEMETAI.S IN COASTALMISSISSIPPI- ALAEAMA.ESTUARINE SEDIMENTS F INAL TECHNICAL REPORT gmt'.NIPS<>"': QayneC. Isphording, Ph.D. assQSA! g@QSlLNt Principal Invest igator George M. Lamb Associate Investigator Robert Helton, Sheri George, Robert Brown, Lysi Payne,Gary Slouat, GregoryIsphording Undergraduate Assistants University of South Alabama Mobile, AL 36688 NATIONALSEA GRANT D":P'j~!~OI"Y PELL Lliii .-',-Y !! ',3'..'..':;. URI, NARRA'.'iH:'-lihi Y '-='-;:i~"US January 1980 March 1984 NARRAGANSETT,R l 02882 January 1985 MISSISSIPPI-ALABAMA SEA GRANT CONSORTIUM Grant No.: NASlhh-~0050 Project No.: R/ER-4 MAStP-83-035 This «ork is a result of research sponsored in part by NOhhOffice of SeaGrant, Department of Commerceunder Grant No.: MSlhh-D-00050, the Mississippi-k.labamaSea Grant Consort ium and the University of SouthAlabama. The U,S. Governmentis authorisedto produceand distribute reprinta for governmentalpurposes notwithstandingany copyright notation that Cay appear hereon+ SEDIMENTATION,DISPERSAL ANDPARTITIONING OFTRACE METALS IN COASTALMISSISSIPPI- ALABAMAESTUARINE SEDIMENTS LOAN Cppy ONLy FINAL REPORT @ATION-ALSEA 'RP;8T D PDal108Y PLI ~i I '-' -'ll" Bl ~L", iG .URI, NAI i ni- .>:TT Bile' ii;liPUS HARIiAGnhSETT,R I 0288? PRINCIPALINVESTIGATOR - Wayne C. Isphording ASSOCIATEINVESTIGATOR George M. Lamb UNDERGRADUATEASSISTANTS- Robert Helton, Sheri George, Robert Brown, Lyal Payne, GaryBlount, GregoryIsphording Project NumberR/ER-4 SubmiFinal ttedReport to: Mississippi-Alabama SEAGRANT Consortium Gulf Coast ResearchLaboratory OceanSprings, h1S39564 PURPOSEOF INVESTIGATION Thepurpose of this investigation wasto documentthechemistry, mineralogy andlithology of thebottom sediments of Lake Borgne andMississippi Sound. A secondobjective was to determinethemanner bywhich var ious metals were site partitionedin these sediments. Thelatter is ofparticular importance because a numberof recent studies have shown that, depending uponhow a metal is actuallyincorporated in bottom sediments, it may be in a formthat either 1!allows its laterrelease back into the water column or! is presentin a formthat permits its extractionandsubsequent incorporation intothe tissues of bottomdwelIing, filter-feeding organisms. LOCATION MississippiSound see Fig. 1! is anelongated lagoon separated fromthe Gulf ofMexico bysix barrier islands and,on the southwest, between HalfMoon Grand! Islandand Isle au Pi tre by marshy island remnants of the St. Bernard subdel ta . TheSound has a lengthof 130km, an average width of 15km and encompasses a tota'Iarea of approximately1,400square kilometers Lake Borgne adds an addi- tional430 square kilometers!. Four major estuaries arepresent along the northernmargin of the Sound andinclude St. Louis Bay, Biloxi Bay, and the drownedvalleys of thePearl and Pascagoula Rivers. Pascagoula Harbor and BayouCasotte areheavily industrialized andinclude ship building andrefit facilities,bulk storage and handling facilities, offshore oil andgas support facilities,oil andgas storage and tank farms and seafood processing plants. TheSound receives fresh water from two major rivers the Pearl and Pascagoula! andfour smaller rivers Tchoutacabouffa, Biloxi,Wolf and Jourdan!. These riversdrain watershed areastotalling some 50,000 square kilometers andhave anaverage combined flowrate of approximately 30,000cfs. Othersources of 'N a 0 0 ~ 0 K m rn9 8 Ijl Vl Eh 0 Ol gL Vl I O Ck 0 0 th T3 0 GL.D v /! Q KC e e 0 lh CD D ~ 0 e I L/! c+ W 'D N O yQ IIl Vl Q v C> fb M QP Q 0 8 O M Vl I rt QJ~& ~ m <+ D Q CXIc+ D Q 0 h D +o g r~y n 0 g ! s Rm b b g m 0 C! P C e a g g 0 e freshwater inflow include water entering the eastern end of theSound from MobileBay, via Pass aux Herons, andthat flowing into Lake Borgne from Lake Pontchartrain. METHODOLOGY One-hundredninecores, averaging 1',meters in length were collected at eachof thesites shown onFigure 1. On-sitemeasurements werealso taken for surfaceand bottom pH, Eh, Salinity, Conductivity, temperature anddissolved oxygen.A portable glovebox was used toprovide a nitrogen environment in orderto preserve a surface sediment sample forlater site partitioning analysis. Allsamples werecollected in 7 cmdiameter, polycarbonate coringtubes. These werethen returned to the laboratory, each day, and stored at 40 Celsiusuntil processingwas initiated. Laboratory Analysis p ! thepore water fraction, ! theexchangeable phase,! the easily reducible phase,! the organic/sulfide phase,! the moderately reducible phase and ! theresidual structurally coordinated! phasewas carr~ed outusing the procedureoutlined inthe EPA "Redbook" Plumb,1981!. All site partitioning analysesandanalyses fortotal metal content ofspecific elements werecarried outon a Perkin-Elmer,Model460, Atomic Absorption Spectrophotometer equipped with Auto-sampler and HGAGraphite Furnace. 1 y i «d treatingthe clays according tothe method recommended byCarroll 970!. All diffractionscans were run from 2 to36 degrees, two-theta, using a Philips X-raydiffraction system equipped witha graphite,single crystal monochrometer. Claymineral percentages wereestimated fromintegrated peakheight intensities with backgroundcorrections applied. andorganic carbon using the Wood's Hole procedure developed byHunt 1982,per- sonalcommunication!. A LECO Induction furnace equipped with automatedsulphur titrator was used for each analysis. SizeAnalysis.-- Size frequency distri butions were calculated for eachsample usinga combinationof hydrometer Boyocous! andsieve analyses. Replicate analysesfor somefine grainedsamples were run on a Sedigraph,Model 5000ET, X-rayparticle analyzer. Statistical parameterswere run usinga program developedby the investigator see Isphording, 1970! which calculates Inman, Folk and Ward and MomentMeasure descriptors. ANALYTICAL RESULTS Introduction In orderto comparespatial differences, the area investigated was arbitrarily brokenup into 4 "sub-regions".These are shown on Figure 1 andare defined as follows:Eastern Mississippi Sound - includes the area from the DauphinIsland bridgeto BayouCasotte channel; Central Mississippi Sound - from Bayou Casotte channel,west to theGulfport, Mississippi channel; Western Mississippi Sound- fromthe Gulfport channel to HalfMoon Island; Lake Borgne includes the lake itself andthe areaeastward to Half MoonIsland. Theregion definedas Eastern MississippiSound is thesmallest, in termsof area30 squarekilometers!, and is mostinfluenced by depositional sources from Mobile Bay and inflow from Petit BoisPass. No major rivers enter this portionof theSound. Central Mississippi Sound,in contrast,encompasses some510 square kilometers in areaand is the primarydepositional basin for theBiloxi, Tchoutacabouffa andPascagoula Rivers, Othermaterial is broughtinto this portionof the Soundby tidal currents operatingthrough Horn Island Pass, Dog Keys Pass between Ship and Horn Islands! and,to a lesserextent, the Ship Island Channel. Western Mississippi Sound is thelargest area 43 square kilometers! butis only,indirectly, influenced by riverinedeposition. TheJourdan andWolf Rivers empty into St. Louis Bay and this,in turn,discharges intothe Sound. Other sediment sources include materialcarried eastward fromthe Pearl River, by longshore transport, andthat broughtintothe sound bytidal currents operating through CatIsland Channel/South Passand Ship Island Pass. The Lake Borgne region of thesound is unique, in manyrespects, bothin terms ofits physical parameters, mineralogy andchemistry. Theseaspects will be individually discussed laterin thereport but largely resultfrom the restricted circulation in the lake and the influence of the dischargeof the Pearl River and, to a lesserextent, material carried into LakeBorgne from Lake Pontchartrain through the Rigolets channel. Sediments A numberof factors have acted to controlsediment distribution within MississippiSound. These include thevarious rivers that empty into the Sound, reworkingofalder Pleistocene andHolocene sediments thatform the barrier islandchain, circulation patterns within the Sound, storm events and physico- chemicalconditions existing atthe time of deposition, Referring tothe sediment mapofthe Sound Fig.2! it canbe seen that the Lake Borgne areaconsists largely ofclayey-silt andsand-silt-clay mixtures, using Shepard's 954!classification. Thepredominance ofsilt isa directreflection ofmaterial contributed fromthe PearlRiver whereas clay-size sediment in the lake is derivedfrom not only the PearlRiver, but also reflects a Pontchartrainsourceand material brought into thelake from further east in the Sound bywestward-flowing tidalcurrents. The smallarea of sandy-siltshown bythe vertical bar-dotted pattern may represent remnantsediments froma formerMississippi River distributary source, A number ofother sites are present inthe Sound thatreflect erosion from older, relict Pleistocenefeatures. These include Deer Island atthe mouth ofBiloxi Bay, Round Cl CCJ! S- Cth GL Vl N 'I th 5- o 4- Island,between HornIsland and Pascagoula, GrassyIsland, west of Half Moon Islandand several small islands located inEastern Mississippi Sound. Thedis- similarityofthe Lake Borgne sediments withthose ofthe remainder ofthe Sound mayalso be seen inFigure 3 which showplots of the sand-silt-clay components forall fourregions. Western Mississippi Soundis less complex thanthe Central orFastern Sound portions, interms ofits sediments,andcan be seen tobe domi- natedbysand-silt-clay mixtures andsilty clays. Sands arepresent inthe vicinity of thebarrier